CN103173800A - Nickel plating brightener and preparation and use method thereof - Google Patents
Nickel plating brightener and preparation and use method thereof Download PDFInfo
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- CN103173800A CN103173800A CN2013100999247A CN201310099924A CN103173800A CN 103173800 A CN103173800 A CN 103173800A CN 2013100999247 A CN2013100999247 A CN 2013100999247A CN 201310099924 A CN201310099924 A CN 201310099924A CN 103173800 A CN103173800 A CN 103173800A
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- nickel plating
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- plating brightener
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- brightener
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Abstract
The invention discloses a nickel plating brightener and a preparation and use method thereof. The nickel plating brightener is formed by adding a major brightening agent, a softening agent and a wetting agent to a working base solution, wherein per liter of the nickel plating brightener contains the major brightening agent: 10-50 g/L of PPS (Pyridinium Propyl Sulfobetaine) and 10-30 g/L of PAP (Propargyl Alcohol Propoxylate), the softening agent: 10-200 g/L of PS (Propargyl Sodium Sulfonate) and 1-10 g/L of S-ATPN (S-Carboxyethyl Isothiourea Thiuronium) and the wetting agent: 20-100 g/L of MA-80 (Butanedioic Acid Diethyl Sodium Sulfonate); and the working base solution contains the following components: 200-320 g/L of nickelous sulfate NiSO4.6H2O, 45-55 g/L of nickel chloride NiCl2.6H2O, 40-50 g/L of boracic acid H3BO3, 0.8-1 g/L of sodium saccharin and the balance of water. The nickel plating brightener disclosed by the invention has the advantages of easiness for raw material obtaining, low cost, easiness for operation, good plating effect and stability in product quality.
Description
Technical field
The present invention relates to the metal finishing auxiliary agent, be specifically related to nickel plating brightener and preparation using method thereof.
Background technology
Nickel plating brightener generally was divided into for four generations at present through the development of many decades.First-generation nickel plating brightener is take metal-salt as main body; The second master that is combined on behalf of 1.4-butynediol and asccharin; The third generation is epoxy compounds and the asccharin of 1.4-butynediol; In the 4th generation, is take the combination of pyridine derivate and ynamine compounds and propiolic alcohol derivative and softening agent as most typical representative.In this several generations nickel plating brightener, third and fourth generation nickel plating brightener and its intermediate in close relations.In fact the intermediate of nickel plating brightener is exactly a kind of certain chemical raw material that can be used for directly preparing nickel plating brightener, as M, the N of preparation acid copper plating brightening agent, SP, P etc.As long as fully realize and skilled usefulness, purposes, using method and the preparation skill of having grasped commercially available all kinds intermediate, intermediate improved just can make the better first kind of performance (elementary) nickel plating brightener and Equations of The Second Kind (secondary) nickel plating brightener.With the first kind, Equations of The Second Kind intermediate, can improve commonly used the 4th generation nickel plating brightener.With the epoxy compounds of 1.4-butynediol (as 791, BE) and asccharin be the third generation brightening agent of Typical Representative, because its cost is low, synthesis technique is the factor such as open basically, is current comparatively widely used secondary nickel plating brightener.Add some intermediates to improve to it, improve the integral level of third generation nickel plating brightener.Elementary brightening agent adds a small amount of intermediate with asccharin to be improved, and second-class brightener also can be by roughly the same method improvement, and Electroplating Production producer just can both reach and improve the quality of products thus, the purpose that reduces production costs again.
Summary of the invention
The object of the invention is to: a kind of nickel plating brightener and preparation using method thereof are provided, not only improve the quality of product, can also reduce production costs, and adjust when component is lacked of proper care, be not controlled by the producer that produces additive.
Technical solution of the present invention is: add key light agent, softening agent, wetting agent composition nickel plating brightener in the work base fluid; Key light agent in every liter of nickel plating brightener: propane sulfonic acid pyridinium salt (PPS) 10-50g/L, propiolic alcohol propoxy-ether (PAP) 10-30g/L; Softening agent: propargyl sodium sulfonate (PS) 10-200g/L, S-propyloic isothiourea salt (ATPN) 1-10g/L; Wetting agent: succinic acid two is ester sodium sulfonate (MA-80) 20-100g/L; The work base fluid comprises following component: single nickel salt NiSO
46H
2O 200-320g/L, nickelous chloride NiCl
26H
2O 45-55g/L, boric acid H
3BO
340-50g/L, soluble saccharin 0.8-1g/L, all the other water.
Wherein, the preparation using method of nickel plating brightener: get single nickel salt NiSO
46H
2O, nickelous chloride NiCl
26H
2O, boric acid H
3BO
3, soluble saccharin is made into the work base fluid; Add the key light agent, add softening agent, add wetting agent according to 1ml/L according to 6ml/L according to 1ml/L in the work base fluid, add water and be made into 1 liter of nickel plating brightener; Adjust pH value 4-5; Plating temperature 50-60 ℃, current density 0.1-10A/dm
2
The raw material of nickel plating brightener of the present invention is easy to get, and is with low cost, simple to operate, and plating is effective, constant product quality.
Embodiment
Further illustrate technical solution of the present invention below in conjunction with specific embodiment, these embodiment can not be interpreted as it is restriction to technical scheme.
Embodiment 1:
Get single nickel salt NiSO
46H
2O 200g, nickelous chloride NiCl
26H
2O 45g, boric acid H
3BO
340g, soluble saccharin 0.8g are made into the work base fluid; Add key light agent propane sulfonic acid pyridinium salt (PPS) 10g, propiolic alcohol propoxy-ether (PAP) 10g according to 1ml/L in the work base fluid; Add softening agent propargyl sodium sulfonate (PS) 10g, S-propyloic isothiourea salt (ATPN) 1g according to 6ml/L; Add wetting agent succinic acid two ester sodium sulfonate (MA-80) 20g according to 1ml/L; Add water and be made into 1 liter of nickel plating brightener; Adjust pH value 4; 50 ℃ of plating temperatures, current density 10A/dm
2
Key light agent consumption 330ml/KAH; Softening agent consumption 1000ml/KAH; Wetting agent consumption 140ml/KAH.
Embodiment 2:
Get single nickel salt NiSO
46H
2O 260g, nickelous chloride NiCl
26H
2O 50g, boric acid H
3BO
345g, soluble saccharin 0.9g are made into the work base fluid; Add key light agent propane sulfonic acid pyridinium salt (PPS) 30g, propiolic alcohol propoxy-ether (PAP) 20g according to 1ml/L in the work base fluid; Add softening agent propargyl sodium sulfonate (PS) 105g, S-propyloic isothiourea salt (ATPN) 5.5g according to 6ml/L; Add wetting agent succinic acid two ester sodium sulfonate (MA-80) 60g according to 1ml/L; Add water and be made into 1 liter of nickel plating brightener; Adjust pH value 4.5; 55 ℃ of plating temperatures, current density 5.0A/dm
2,Key light agent consumption 330ml/KAH; Softening agent consumption 1000ml/KAH; Wetting agent consumption 140ml/KAH.
Embodiment 3:
Get single nickel salt NiSO
46H
2O 320g, nickelous chloride NiCl
26H
2O 55g, boric acid H
3BO
350g, soluble saccharin 1g are made into the work base fluid; Add key light agent propane sulfonic acid pyridinium salt (PPS) 50g, propiolic alcohol propoxy-ether (PAP) 30g according to 1ml/L in the work base fluid; Add softening agent propargyl sodium sulfonate (PS) 200g, S-propyloic isothiourea salt (ATPN) 10g according to 6ml/L; Add wetting agent succinic acid two ester sodium sulfonate (MA-80) 100g according to 1ml/L; Add water and be made into 1 liter of nickel plating brightener; Adjust pH value 5; 60 ℃ of plating temperatures, current density 0.1A/dm
2,Key light agent consumption 330ml/KAH; Softening agent consumption 1000ml/KAH; Wetting agent consumption 140ml/KAH.
Claims (2)
1. nickel plating brightener, is characterized in that: add key light agent, softening agent, wetting agent composition nickel plating brightener in the work base fluid; Key light agent in every liter of nickel plating brightener: propane sulfonic acid pyridinium salt (PPS) 10-50g/L, propiolic alcohol propoxy-ether (PAP) 10-30g/L; Softening agent: propargyl sodium sulfonate (PS) 10-200g/L, S-propyloic isothiourea salt (ATPN) 1-10g/L; Wetting agent: succinic acid two is ester sodium sulfonate (MA-80) 20-100g/L; The work base fluid comprises following component: single nickel salt NiSO
46H
2O 200-320g/L, nickelous chloride NiCl
26H
2O 45-55g/L, boric acid H
3BO
340-50g/L, soluble saccharin 0.8-1g/L, all the other water.
2. the preparation using method of nickel plating brightener, is characterized in that preparing using method as follows: get single nickel salt NiSO
46H
2O, nickelous chloride NiCl
26H
2O, boric acid H
3BO
3, soluble saccharin is made into the work base fluid; Add the key light agent, add softening agent, add wetting agent according to 1ml/L according to 6ml/L according to 1ml/L in the work base fluid, add water and be made into 1 liter of nickel plating brightener; Adjust pH value 4-5; Plating temperature 50-60 ℃, current density 0.1-10A/dm
2
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100999247A CN103173800A (en) | 2013-03-27 | 2013-03-27 | Nickel plating brightener and preparation and use method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100999247A CN103173800A (en) | 2013-03-27 | 2013-03-27 | Nickel plating brightener and preparation and use method thereof |
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| CN103173800A true CN103173800A (en) | 2013-06-26 |
Family
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| CN2013100999247A Pending CN103173800A (en) | 2013-03-27 | 2013-03-27 | Nickel plating brightener and preparation and use method thereof |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103911635A (en) * | 2014-03-21 | 2014-07-09 | 复旦大学 | Copper electroplating solution |
| CN105088288A (en) * | 2015-08-31 | 2015-11-25 | 武汉吉和昌化工科技股份有限公司 | Brightener for direct nickel plating of steel and iron elements and nickel plating solution thereof |
| CN105463520A (en) * | 2016-01-11 | 2016-04-06 | 湖北德美科技有限公司 | Barrel nickel plating softening agent and preparation method thereof |
| CN105463518A (en) * | 2016-01-11 | 2016-04-06 | 湖北德美科技有限公司 | Full bright nickel plating softening agent and preparation method thereof |
| CN105463519A (en) * | 2016-01-11 | 2016-04-06 | 湖北德美科技有限公司 | Barrel nickel plating major brightening agent and preparation method thereof |
| CN105648480A (en) * | 2016-01-11 | 2016-06-08 | 湖北德美科技有限公司 | Full-bright nickel plating major brightening agent and preparing method thereof |
| CN106086947A (en) * | 2016-08-11 | 2016-11-09 | 太仓市凯福士机械有限公司 | A kind of holding limpid additive of plating solution |
| TWI674341B (en) * | 2017-06-15 | 2019-10-11 | 美商羅門哈斯電子材料有限公司 | Environmentally friendly nickel electroplating compositions and methods |
| CN110484945A (en) * | 2019-09-03 | 2019-11-22 | 福建南平南孚电池有限公司 | Electroplate liquid and use its shell electric plating method to battery |
| CN111748830A (en) * | 2020-07-22 | 2020-10-09 | 六安市金安区宝德龙科技创新有限公司 | High-speed barrel nickel plating brightener and preparation method thereof |
| CN112251740A (en) * | 2020-10-21 | 2021-01-22 | 广州三孚新材料科技股份有限公司 | Chemical nickel plating brightener for heterojunction solar cell and preparation method thereof |
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| CN102161639A (en) * | 2011-02-21 | 2011-08-24 | 湖北吉和昌化工科技有限公司 | Method for synthesizing pyridinium hydroxy propyl sulfobetaine |
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| US2986500A (en) * | 1959-04-21 | 1961-05-30 | Metal & Thermit Corp | Electrodeposition of bright nickel |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103911635A (en) * | 2014-03-21 | 2014-07-09 | 复旦大学 | Copper electroplating solution |
| CN103911635B (en) * | 2014-03-21 | 2016-02-24 | 复旦大学 | A kind of copper electroplating solution |
| CN105088288A (en) * | 2015-08-31 | 2015-11-25 | 武汉吉和昌化工科技股份有限公司 | Brightener for direct nickel plating of steel and iron elements and nickel plating solution thereof |
| CN105463520A (en) * | 2016-01-11 | 2016-04-06 | 湖北德美科技有限公司 | Barrel nickel plating softening agent and preparation method thereof |
| CN105463518A (en) * | 2016-01-11 | 2016-04-06 | 湖北德美科技有限公司 | Full bright nickel plating softening agent and preparation method thereof |
| CN105463519A (en) * | 2016-01-11 | 2016-04-06 | 湖北德美科技有限公司 | Barrel nickel plating major brightening agent and preparation method thereof |
| CN105648480A (en) * | 2016-01-11 | 2016-06-08 | 湖北德美科技有限公司 | Full-bright nickel plating major brightening agent and preparing method thereof |
| CN106086947A (en) * | 2016-08-11 | 2016-11-09 | 太仓市凯福士机械有限公司 | A kind of holding limpid additive of plating solution |
| TWI674341B (en) * | 2017-06-15 | 2019-10-11 | 美商羅門哈斯電子材料有限公司 | Environmentally friendly nickel electroplating compositions and methods |
| CN110484945A (en) * | 2019-09-03 | 2019-11-22 | 福建南平南孚电池有限公司 | Electroplate liquid and use its shell electric plating method to battery |
| CN111748830A (en) * | 2020-07-22 | 2020-10-09 | 六安市金安区宝德龙科技创新有限公司 | High-speed barrel nickel plating brightener and preparation method thereof |
| CN112251740A (en) * | 2020-10-21 | 2021-01-22 | 广州三孚新材料科技股份有限公司 | Chemical nickel plating brightener for heterojunction solar cell and preparation method thereof |
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Application publication date: 20130626 |