CN103131481A - Biosynthetic fuel - Google Patents
Biosynthetic fuel Download PDFInfo
- Publication number
- CN103131481A CN103131481A CN2011102717890A CN201110271789A CN103131481A CN 103131481 A CN103131481 A CN 103131481A CN 2011102717890 A CN2011102717890 A CN 2011102717890A CN 201110271789 A CN201110271789 A CN 201110271789A CN 103131481 A CN103131481 A CN 103131481A
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- CN
- China
- Prior art keywords
- fuel
- raw materials
- biosynthesizing
- making method
- normal temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000446 fuel Substances 0.000 title claims abstract description 18
- 230000001851 biosynthetic effect Effects 0.000 title abstract 4
- 238000000034 method Methods 0.000 claims abstract description 28
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 11
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 9
- 230000003197 catalytic effect Effects 0.000 claims abstract description 6
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000007789 gas Substances 0.000 claims abstract description 6
- 239000001257 hydrogen Substances 0.000 claims abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 6
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 15
- 230000003570 biosynthesizing effect Effects 0.000 claims description 11
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 claims description 9
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 5
- -1 Hydrogen Chemical class 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims description 5
- 238000009472 formulation Methods 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 abstract description 4
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002551 biofuel Substances 0.000 abstract 1
- 239000004359 castor oil Substances 0.000 abstract 1
- 235000019438 castor oil Nutrition 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 239000006184 cosolvent Substances 0.000 abstract 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 abstract 1
- 239000011874 heated mixture Substances 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 abstract 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 abstract 1
- 238000005303 weighing Methods 0.000 abstract 1
- 150000001896 cresols Chemical class 0.000 description 3
- 238000007599 discharging Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Abstract
The invention provides biosynthetic fuel which comprises the following raw materials by weight: 42.97% of methanol, 42.97% of ethanol, 11.73% of castor oil, 1.46% of sodium hydrogen sulfate, 0.29% of ion emulsifiers, 0.29% of cosolvents, and 0.29% of methylphenol; the method comprises the following steps: 1) weighing the raw materials according to the weight percents, putting the raw materials into a stirring tank, stirring and well mixing; 2) putting the well mixed mixture into a reaction vessel, heating to 350 DEG C; 3) removing gas from the heated mixture by a gas-liquid separator, adding the mixture into a catalytic tower, injecting 4 m3 hydrogen per 1000 kg, then cooling to normal temperature by a column tube device; 4) adding the mixture cooled to normal temperature into a finished product pot, adding ferrocene with an amount of 5% of the total amount, and reaching an octane number of 10% to obtain the biosynthetic fuel. According to the invention, the bio-fuel is synthesized by methanol and ethanol through a scientific method; the biosynthetic fuel has several advantages of high heat value, low pollution discharge, reasonable cost, easily-available raw materials, and the like, and is regenerable ideal synthetic energy.
Description
Technical field
The present invention relates to a kind of synthol, specifically a kind of biosynthesizing fuel.
Background technology
Along with improving constantly of economy and standard of living; energy consumption constantly enlarges; non-renewable petroleum resources are day by day exhausted; its energy dilemma on the horizon; will affect and restrict the development of world economy; in order to satisfy the growing material life of people and Economic development needs; develop and develop new renewable energy source and become the task of top priority; countries in the world are being all that the reply energy dilemma strengthens input in science and technology and development research, particularly calorific value are high, the low renewable new forms of energy of discharging have become the urgent major issue that the mankind face.
Summary of the invention
The object of the invention is to solve the day by day exhausted present situation of the current energy, a kind of biosynthesizing fuel is provided, have that calorific value is high, low, the rational distinguishing feature of cost of discharging, is a kind of scientific and reasonable renewable synthol.
The present invention includes the methyl alcohol, ethanol, Viscotrol C and the hydrogen sulfate that use in synthol and receive, the technical scheme that adopts is:
Its formulation weight per-cent is as follows:
Another object of the present invention is to provide a kind of making method of above-mentioned biosynthesizing fuel, mainly divide following a few step to carry out:
1) above-mentioned raw materials being put into stirred pot together by weight feeding mixes;
2) compound that stirs is put into reactor and be heated to 350 ℃;
3) compound after heating is got rid of gas through gas-liquid separator, and liquid directly enters catalytic tower, then injects 4m by every 1000Kg
3Hydrogen, then be down to normal temperature by the tubulation device;
4) compound that will be down to normal temperature is sent into finished pot, add by 5% of total amount ferrocene and 10% octane value for biological synthol.
In above-mentioned making method:
Making method 1) time of stirring in is 5～10 minutes.
Making method 2) be heated to 350 ℃ in, its air pressure should reach 4 pressure.
Technique scheme that the present invention passes through, because the main component in raw material has adopted reproducible methyl alcohol and ethanol, and allocate a small amount of industrial chemicals into, synthesize by simple making of science again, produce thing fuel after testing, its fuel value can reach 1.1 ten thousand kilocalories, the quantity discharged of hydrocarbon polymer and an oxidation is extremely low, calorific value is with existing suitable with gasoline, can be applied directly in existing motor car engine and use as power fuel, raw material required for the present invention easily obtains, and making processes is simple, has fabulous popularizing application prospect.
Description of drawings
The invention will be further described below in conjunction with drawings and Examples.
Accompanying drawing is process flow diagram of the present invention.
Embodiment
Embodiment 1: calculate to make 500Kg biosynthesizing fuel, desired raw material precentagewise meter weight is as follows: methyl alcohol 42.97% 214.85Kg, ethanol 42.97% 214.85Kg, Viscotrol C 11.73% 58.65Kg, hydrogen sulfate are received 1.46% 7.3Kg, ionic emulsifying agent 0.29% 1.45Kg, solubility promoter 0.29% 1.45Kg, cresols 0.29% 1.45Kg
Making method is as follows:
1) above-mentioned raw materials being put into stirred pot together by weight feeding mixes;
2) compound that stirs is put into reactor and be heated to 350 ℃;
3) compound after heating is got rid of gas through gas-liquid separator, and liquid directly enters catalytic tower, then injects 4m by every 1000Kg
3Hydrogen, then be down to normal temperature by the tubulation device;
4) compound that will be down to normal temperature is sent into finished pot, add by 5% of total amount 500Kg ferrocene 25Kg and 10% octane value 50Kg for biological synthol.
In above-mentioned making processes, method 1) churning time in is 5 minutes, the method formula) in heating after press exhausted 4 pressure that reach.
Embodiment 2: calculate to make 1000Kg biosynthesizing fuel, desired raw material precentagewise meter weight is as follows: methyl alcohol 42.97% 429.7Kg, ethanol 42.97% 429.7Kg, Viscotrol C 11.73% 117.3Kg, hydrogen sulfate are received 1.46% 14.6Kg, ionic emulsifying agent 0.29% 2.9Kg, solubility promoter 0.29% 2.9Kg, cresols 0.29% 2.9Kg
Making method is as follows:
1) above-mentioned raw materials being put into stirred pot together by weight feeding mixes;
2) compound that stirs is put into reactor and be heated to 350 ℃;
3) compound after heating is got rid of gas through gas-liquid separator, and liquid directly enters catalytic tower, then injects 4m by every 1000Kg
3Hydrogen, then be down to normal temperature by the tubulation device;
4) compound that will be down to normal temperature is sent into finished pot, add by 5% of total amount 500Kg ferrocene 50Kg and 10% octane value 100Kg for biological synthol.
In above-mentioned making processes, method 1) churning time in is 8 minutes, the method formula) in heating after press exhausted 4 pressure that reach.
Embodiment 3: calculate to make 2000Kg biosynthesizing fuel, desired raw material precentagewise meter weight is as follows: methyl alcohol 42.97% 859.4Kg, ethanol 42.97% 859.4Kg, Viscotrol C 11.73% 234.6Kg, hydrogen sulfate are received 1.46% 29.2Kg, ionic emulsifying agent 0.29% 5.8Kg, solubility promoter 0.29% 5.8Kg, cresols 0.29% 5.8Kg
Making method is as follows:
1) above-mentioned raw materials being put into stirred pot together by weight feeding mixes;
2) compound that stirs is put into reactor and be heated to 350 ℃;
3) compound after heating is got rid of gas through gas-liquid separator, and liquid directly enters catalytic tower, then injects 4m by every 1000Kg
3Hydrogen, then be down to normal temperature by the tubulation device;
4) compound that will be down to normal temperature is sent into finished pot, add by 5% of total amount 500Kg ferrocene 100Kg and 10% octane value 200Kg for biological synthol.
In above-mentioned making processes, method 1) churning time in is 10 minutes, the method formula) in heating after press exhausted 4 pressure that reach.
The various device that the present invention uses in making processes all can adopt traditional chemical industry equipment to produce, related back-pressure still, and it is good should adopting autoclave.
Claims (4)
1. biosynthesizing fuel comprises that the methyl alcohol, ethanol, Viscotrol C and the hydrogen sulfate that use in synthol receive, and it is characterized in that:
Its formulation weight per-cent is as follows:
2. the making method of a biosynthesizing fuel claimed in claim 1, its feature is being: described method minute following steps are carried out:
1) above-mentioned raw materials being put into stirred pot together by weight feeding mixes;
2) compound that stirs is put into reactor and be heated to 350 ℃;
3) compound after heating is got rid of gas through gas-liquid separator, and liquid directly enters catalytic tower, then injects 4m by every 1000Kg
3Hydrogen, then be down to normal temperature by the tubulation device;
4) compound that will be down to normal temperature is sent into finished pot, add by 5% of total amount ferrocene and 10% octane value for biological synthol.
3. the making method of biosynthesizing fuel according to claim 2, its feature is being: the time of stirring making method 1) is 5～10 minutes.
4. the making method of biosynthesizing fuel according to claim 2, its feature is being: be heated to 350 ℃ making method 2), its air pressure should reach 4 pressure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110271789.0A CN103131481B (en) | 2011-11-22 | 2011-11-22 | A kind of biosynthesizing fuel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110271789.0A CN103131481B (en) | 2011-11-22 | 2011-11-22 | A kind of biosynthesizing fuel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103131481A true CN103131481A (en) | 2013-06-05 |
| CN103131481B CN103131481B (en) | 2016-03-30 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110271789.0A Active CN103131481B (en) | 2011-11-22 | 2011-11-22 | A kind of biosynthesizing fuel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103131481B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107629823A (en) * | 2016-07-18 | 2018-01-26 | 任卫国 | A kind of environmentally friendly synthetic liquid fuel |
| CN108070411A (en) * | 2016-11-18 | 2018-05-25 | 黄运国 | A kind of novel energy-saving environment-friendly fuel |
| CN113186005A (en) * | 2021-03-29 | 2021-07-30 | 叁久国际新能源科技有限公司 | Civil energy-saving environment-friendly fuel and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1928035A (en) * | 2006-10-23 | 2007-03-14 | 姜彬 | Environmental protection energy-saving diesel oil |
| US20100037513A1 (en) * | 2006-04-27 | 2010-02-18 | New Generation Biofuels, Inc. | Biofuel Composition and Method of Producing a Biofuel |
-
2011
- 2011-11-22 CN CN201110271789.0A patent/CN103131481B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100037513A1 (en) * | 2006-04-27 | 2010-02-18 | New Generation Biofuels, Inc. | Biofuel Composition and Method of Producing a Biofuel |
| CN1928035A (en) * | 2006-10-23 | 2007-03-14 | 姜彬 | Environmental protection energy-saving diesel oil |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107629823A (en) * | 2016-07-18 | 2018-01-26 | 任卫国 | A kind of environmentally friendly synthetic liquid fuel |
| CN108070411A (en) * | 2016-11-18 | 2018-05-25 | 黄运国 | A kind of novel energy-saving environment-friendly fuel |
| CN113186005A (en) * | 2021-03-29 | 2021-07-30 | 叁久国际新能源科技有限公司 | Civil energy-saving environment-friendly fuel and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103131481B (en) | 2016-03-30 |
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Addressee: Xiangfan Tongkang Industrial Co.,Ltd. Document name: the First Notification of an Office Action |
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Owner name: BAI FUJUN Free format text: FORMER OWNER: XIANGFAN TONGKANG INDUSTRIALS CO., LTD. Effective date: 20150430 |
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Effective date of registration: 20150430 Address after: 441500 No. 21-12 Nursery Road, Chengguan Town, Nanzhang County, Hubei Applicant after: Bai Fujun Address before: 441004 Fukang Road East, Xiangyang hi tech Development Zone, Hubei Applicant before: Xiangfan Tongkang Industrial Co.,Ltd. |
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Application publication date: 20130605 Assignee: Cai Yongzong Assignor: Bai Fujun Contract record no.: X2022980017724 Denomination of invention: A kind of bio synthetic fuel Granted publication date: 20160330 License type: Exclusive License Record date: 20221011 |
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Application publication date: 20130605 Assignee: Cai Yongzong Assignor: Bai Fujun Contract record no.: X2023980042305 Denomination of invention: A Biosynthetic Fuel Granted publication date: 20160330 License type: Common License Record date: 20230926 |
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Application publication date: 20130605 Assignee: Xiangyang Fuzi Chemical Synthetic Fuel Co.,Ltd. Assignor: Bai Fujun Contract record no.: X2023980043349 Denomination of invention: A Biosynthetic Fuel Granted publication date: 20160330 License type: Common License Record date: 20231018 |