CN103099577A - Daily-use paper and manufacture method thereof - Google Patents
Daily-use paper and manufacture method thereof Download PDFInfo
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- CN103099577A CN103099577A CN2012105800894A CN201210580089A CN103099577A CN 103099577 A CN103099577 A CN 103099577A CN 2012105800894 A CN2012105800894 A CN 2012105800894A CN 201210580089 A CN201210580089 A CN 201210580089A CN 103099577 A CN103099577 A CN 103099577A
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- heat release
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Abstract
Daily-use paper comprises raw paper. Carriers, substances which are distributed in the carriers and can release heat after contacting water and surface active agent are attached to the raw paper. The invention further provides a manufacture method of the daily-use paper. According to the daily-use paper which can release the heat after contacting the water, the heat released after the paper touches water can bring a feeling of warmth to a user, so that the comfort level in usage can be improved. The daily-used paper is particularly suitable for being used in cold weather when the user uses cold water to touch skin. At the same time of drying the skin, the daily-use paper can provide the heat energy for the skin, so that the feeling of inadaptation of the user can be relieved.
Description
Technical field
The present invention relates to one way of life paper using and manufacture method thereof.
Background technology
Autumn and winter season, temperature reduces, because not all occasion all possesses the condition of washing one's hands with hot water at arctic weather, cold that people arrive at the after sensation of washing one's hands with cold water, make people very inadaptable, this situation shows particularly evidently on child old man women and some weakly crowds.
As the means of the rear drying of washing one's hands, there is at present warm-air drier to dry up with paper handkerchief or rag and the mode such as dries.Only provide such as airport, toilet, hotel etc. in public places yet warm-air drier is general, average family can the choice for use warm-air drier.Though and common paper for daily use or rag can be dried rapidly the globule on hand, can not improve people for the discomfort of cold.
Summary of the invention
In view of this, be necessary to provide one way of life paper using and manufacture method thereof to address the aforementioned drawbacks.
The one way of life paper using comprises body paper, is attached with carrier on this body paper and is dispersed in chance water heat release material and surfactant in carrier.
The manufacture method of one way of life paper using comprises the steps:
Body paper is provided;
Formula according to including carrier, chance water heat release material and surfactant prepares required compounding substances; And
The above-mentioned compounding substances that makes is applied on body paper.
The present invention is by providing a kind of paper for daily use that runs into water can heat release, and this paper for daily use is provided by the heat that provides after water can bring warm sensation to the user, thereby can improve the comfort level when using.This paper for daily use is particularly suitable for after the arctic weather people are with cold water contact skin, in dry skin for skin provides heat, to slow down people for the inadaptable sense of cold.
The specific embodiment
The present invention relates to a kind of paper for daily use that runs into water can heat release, this paper for daily use is provided by the heat that provides after water can bring warm sensation to the user, thereby can improve the comfort level when using.This paper for daily use is particularly suitable for after the arctic weather people wash one's hands with cold water, in dry hand for hand provides heat, to slow down people for the inadaptable sense of cold.Certainly, do not get rid of this paper for daily use other purposes of suitable heat also are provided when other wet environments are used for providing functions/drying.
This paper for daily use comprises body paper and is attached to carrier on body paper.Be dispersed with in this carrier and meet water heat release material and surfactant.The mass ratio of described carrier, chance water heat release material and surfactant is 1-70:0.1-70:0.1-20, and more preferably, the mass ratio of carrier, chance water heat release material and surfactant is 10-50:10-50:1-10.The quality that includes the compounding substances of carrier, chance water heat release material and surfactant is the 2%-40% of original paper quality, is preferably 5%-25%.Body paper can be even more multi-layered for individual layer, bilayer, three layers.
Meet water heat release material:
This type of is met water heat release material and comprises that the exothermic material ⅰ of chemical reaction can occur to run into water, also comprises the material ⅱ that emits heat when being dissolved in water but chemical reaction does not occur.Certainly, can be also the mixture of above two kinds of materials (ⅰ and ⅱ).What need proposition is that above chance water heat release material can produce rapidly heat when running into water, but do not have naked light to produce, and can be so that it to only have warm sensation when the heat production by controlling its consumption, and it is serious localized heat release can not occur, the situation of the consumer's skin that causes burning occurs.
At present, the composition of the heat release of the comparative maturity that uses is solid adsorbent materials, and these solid adsorbent materials are crushed into thinner Powdered.These solid adsorbent materials can with the water exothermic heat of reaction, such as being silica gel, activation aluminium, zeolite etc. or their mixture.Further, what the present invention used is metal metasilicate aluminium salts substances, can be natural also can synthesizing, for example lagoriolite, lithium aluminium silicate.
Carrier:
Meet water heat release material and be dispersed in carrier, so carrier is required to be without water constituent.The material that can be used as carrier comprises straight chain and branched ester, the straight chain with 8-22 carbon atom and side chain ethoxylate, mineral oil, rilanit special and their composition that has the C8-C22 part in glycol, liquid macrogol, ester bond either side each several part.Carrier when running into water not with the biochemical reaction of steeping in water for reconstitution, but because above substance dissolves heat of solution when the water less than zero, also can discharge the part heat, and meet water heat release material and play complementary effect.It is too small that but the heat that discharges during the carrier dissolving is compared with the heat of meeting water heat release substance release, uses separately carrier that the heat of wanting required for the present invention can not be provided.Further, selected carrier must be to human-body safety, to the material of skin without injury.
Meet water heat release material and lack and the functional group that the paper fiber is combined, so be difficult to be adsorbed on paper surface, even can be attached to paper surface by External Force Acting, also be easy to come off from paper.Carrier plays a part Uniform Dispersion and carrying chance water heat release material in the present invention, and mostly contain hydroxyl, carboxyl, ester group etc. in carrier and can form with the paper fiber group of key joint, but make the mixture of meeting the water release heat that has that applies in paper for daily use of the present invention to be applied to equably on paper, and apply complete after, meet water heat release material and also can stably be present on paper.
Surfactant:
That surfactant comprises is cationic, anionic, nonionic and amphoteric ion type.Surfactant plays emulsification and stablizes above-mentioned carrier and the hydrophily of chance water heat release material the inside and the effect of hydrophobicity composition.If there is no surfactant, meet water heat release material and just can't be present in uniformly and stably in carrier, also just can't transfer on paper equably.Nonrestrictive example comprises alkali metal salt, sorbitan alcohol ester fatty acid ester, alkylpolyglucoside, cithrol, the silicone of ether modification and their mixture of polyoxyethylene hardened castor oil, polyoxyethylene alkyl ether, polyxyethylated ester, polyoxyethylene fatty acid glyceride, aliphatic acid.
What need to propose is that in surfactant, cationic surfactant and anionic surfactant can not use simultaneously, because both can produce flocculation, can not play the function of surfactant itself.
Adopt carrier that above-mentioned substance is made into, meet water heat release material and surfactant, performance is gentle, makes this paper for daily use can automatic heat evolution when running into water, and does not have naked light to produce.The more important thing is this carrier, meet water heat release material and surfactant for skin without injury, wait in use without burning sensation, only has gentle warm sensation, provide thus people's daily life to use, particularly in the environment of cold, when absorbing moisture, all right warm user's skin.
The chance water that the present invention relates to can heat release the paper for daily use preparation process as follows:
At first the tissue paper of the low grammes per square metre of preparation, be also body paper.The basic weight of body paper is 10g/m
2-100g/m
2, be preferably 15g/m
2-50g/m
2
Then according to the formula that includes carrier, chance water heat release material and surfactant, prepare required compounding substances.Then, the compounding substances of above-mentioned preparation gained is put at least one face of body paper, the applying method that can adopt comprises spraying, printing, coating, applying glue, perhaps the combination of this several method.Carrier, the composition by the agency of above of meeting water heat release material and surfactant, this does not give unnecessary details.The quality that includes carrier, meets the compounding substances of water heat release material and surfactant that is made by above-mentioned formula of transferring on body paper is the 2%-40% of original paper quality, is preferably 5%-25%.Body paper can be even more multi-layered for individual layer, bilayer, three layers.
The body paper that is applied with said mixture matter can also be done processing further according to real needs, such as embossing etc.
The paper for daily use that the above-mentioned manufacture method of the present invention obtains can be used as health stationery, facial tissue class, paper handkerchief series products, preferably makes the paper handkerchief series products, such as tissue, napkin paper, paper for kitchen etc.
Concrete case study on implementation 1:
At first the fibrous suspension for preparing low concentration adds wet strength agent and CMC(carboxymethyl cellulose in fibrous suspension) stir.When the paper for daily use of the certain wet strength of need of production, generally add a certain proportion of CMC, improve the wet strength agent effect together with wet strength agent.Wherein each material mass is than as follows.The wet strength agent oven-dry weight: the fiber oven-dry weight is 2.25:1000, the CMC oven-dry weight: the fiber oven-dry weight is 0.3:1000.Then will more than contain wet strength agent and CMC fibrous suspension dewater after by the forming net moulding, drying, obtaining basic weight is 43g/m
2Thin slice paper, be also body paper.
With the coating of this individual layer body paper according to the compounding substances of meeting mild formulation that water can heat release and making.This formula is: lagoriolite 35%, and butanediol 40%, rilanit special 3%, mineral oil 10%, polyoxyethylene alkyl ether 8%, cithrol 4%, above-mentioned each ratio is mass ratio.Coating weight is 10% of original paper quality.Wherein, lagoriolite is as meeting water heat release material, and butanediol, rilanit special, mineral oil are as carrier, and polyoxyethylene alkyl ether and cithrol are as surfactant.
Place about a week at the outer coating plastic film of coated body paper paper roll.Then can with more than the paper for daily use that makes carry out follow-up processing, for example embossing namely can be made the paper for daily use with warm hand effect.For example when this paper for daily use as tissue, the user, can be with on hand water stain of this tissue wiping after washing one's hands with cold water, this paper for daily use namely can provide appropriate heat, allows user's hand feel warm.
Just coated paper is wetter, should not directly process, therefore need to be in coated body paper paper roll outer coating standing a period of time of film.Process a period of time and namely do not carry out following process if coat film, may man-hour can occur disconnected paper phenomenon and cause and to process smoothly adding.In addition, standing a period of time can also make the mixture that the is applied in abundant balance in paper in paper, because original paper layer is usually all thinner, therefore not only on the body paper surface, the compounding substances that is applied in is arranged, these compounding substances also can be penetrated in body paper between fibrage.
Concrete case study on implementation 2:
At first the fibrous suspension for preparing low concentration adds wet strength agent and CMC to stir in fibrous suspension.Wet strength agent oven-dry weight wherein: the fiber oven-dry weight is 2.25:1000, the CMC oven-dry weight: the fiber oven-dry weight is 0.3:1000.Then will more than contain wet strength agent and CMC fibrous suspension dewater after by the forming net moulding, drying, obtaining basic weight is 43g/m
2Body paper.
The mild formulation that water can heat release is met in the coating of this individual layer body paper.Fill a prescription specific as follows: lagoriolite 65%, butanediol 10%, rilanit special 1%, mineral oil 5%, alkylpolyglucoside 7%, cithrol 12%.Coating weight is 10% of original paper quality.Wherein, lagoriolite is as meeting water heat release material, and butanediol, rilanit special, mineral oil are as carrier, and alkylpolyglucoside and cithrol are as surfactant.
Place about a week at the outer coating plastic film of coated body paper paper roll.Then the paper product that above step is made carries out embossing, namely can make the tissue with warm hand effect.After washing one's hands with cold water, the hand temperature reduces suddenly as the user, then uses on hand water stain of this tissue wiping, and warm sensation can be arranged.
Concrete case study on implementation 3:
At first the fibrous suspension for preparing low concentration adds wet strength agent and CMC to stir in fibrous suspension.Wet strength agent oven-dry weight wherein: the fiber oven-dry weight is 2.25:1000, the CMC oven-dry weight: the fiber oven-dry weight is 0.3:1000.Then will more than contain wet strength agent and CMC fibrous suspension dewater after by the forming net moulding, drying, obtaining basic weight is 43g/m
2The thin slice body paper.
The mild formulation that water can heat release is met in the coating of this individual layer body paper.Formula is specially: lithium aluminium silicate 20%, glycerine 50%, rilanit special 5%, mineral oil 14%, polyoxyethylene alkyl ether 5%, alkylpolyglucoside 6%.Coating weight is 10% of original paper quality.Wherein, lagoriolite is as meeting water heat release material, and glycerine, rilanit special, mineral oil are as carrier, and alkylpolyglucoside and polyoxyethylene alkyl ether are as surfactant.
Place about a week at the outer coating plastic film of coated body paper paper roll.Then the paper for daily use that above step is made carries out embossing, namely can make the tissue with warm hand effect.After washing one's hands with cold water, the hand temperature reduces suddenly as the user, then uses on hand water stain of this tissue wiping, and warm sensation can be arranged.
Paper for daily use with chance water exothermic effect provided by the invention, cold sensation is not being arranged after making people wash one's hands with cold water in the cold snap environment, thereby the mental handicape that has when reducing contact cold water, and the effect such as the hand poor blood circulation that causes because washing one's hands with cold water of prevention is logical.
Claims (13)
1. the one way of life paper using, comprise body paper, it is characterized in that: be attached with carrier on this body paper and be dispersed in chance water heat release material and surfactant in carrier.
2. paper for daily use as claimed in claim 1, it is characterized in that: the mass ratio of described carrier, chance water heat release material and surfactant is 1-70:0.1-70:0.1-20.
3. paper for daily use as claimed in claim 1, it is characterized in that: the mass ratio of described carrier, chance water heat release material and surfactant is 10-50:10-50:1-10.
4. paper for daily use as claimed in claim 1 is characterized in that: described surfactant is cationic, anionic, nonionic or amphoteric ion type.
5. paper for daily use as claimed in claim 1, it is characterized in that: the quality sum of described carrier, chance water heat release material and surfactant is the 2%-40% of original paper quality.
6. paper for daily use as claimed in claim 1, it is characterized in that: the quality sum of described carrier, chance water heat release material and surfactant is the 5%-25% of original paper quality.
7. paper for daily use as claimed in claim 1, it is characterized in that: described carrier is any one in straight chain and the branched ester, the straight chain with 8-22 carbon atom and the side chain ethoxylate that have C8-C22 part in glycol, liquid macrogol, ester bond either side each several part, mineral oil, rilanit special, perhaps their mixture.
8. paper for daily use as claimed in claim 1 is characterized in that: described chance water heat release material is any one in silica gel, activation aluminium, zeolite, perhaps their mixture.
9. the manufacture method of one way of life paper using, comprise the steps:
Body paper is provided;
Formula according to including carrier, chance water heat release material and surfactant prepares required compounding substances; And
This compounding substances is applied on body paper.
10. the manufacture method of paper for daily use as claimed in claim 9 is characterized in that: carrier, the quality sum of meeting water heat release material and surfactant are the 2%-40% of original paper quality.
11. the manufacture method of paper for daily use as claimed in claim 9 is characterized in that: the quality sum of carrier, chance water heat release material and surfactant is the 5%-25% of original paper quality.
12. the manufacture method of paper for daily use as claimed in claim 9 is characterized in that: this compounding substances is applied to one side or the two sides of body paper.
13. the manufacture method of paper for daily use as claimed in claim 9 is characterized in that: the method that applies comprises spraying, printing, coating, applying glue, perhaps the combination of this several method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210580089.4A CN103099577B (en) | 2012-12-27 | 2012-12-27 | Paper for daily use and manufacture method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210580089.4A CN103099577B (en) | 2012-12-27 | 2012-12-27 | Paper for daily use and manufacture method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103099577A true CN103099577A (en) | 2013-05-15 |
| CN103099577B CN103099577B (en) | 2015-08-19 |
Family
ID=48308017
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210580089.4A Active CN103099577B (en) | 2012-12-27 | 2012-12-27 | Paper for daily use and manufacture method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103099577B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1954749A (en) * | 2005-10-27 | 2007-05-02 | 强生消费者公司 | Exothermic cleansing article |
| CN101588785A (en) * | 2006-12-01 | 2009-11-25 | 强生消费者公司 | Self-warming moisturizing lotion in the double chamber bottle |
| US20090297586A1 (en) * | 2008-05-30 | 2009-12-03 | Kimberly-Clark Worldwide, Inc. | Tissue Products Having A Cooling Sensation When Contacted With Skin |
| CN102076325A (en) * | 2008-06-30 | 2011-05-25 | 金伯利-克拉克环球有限公司 | Polysensorial personal care cleanser |
| CN102525861A (en) * | 2012-02-09 | 2012-07-04 | 金红叶纸业集团有限公司 | Cool body lotion and household paper |
-
2012
- 2012-12-27 CN CN201210580089.4A patent/CN103099577B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1954749A (en) * | 2005-10-27 | 2007-05-02 | 强生消费者公司 | Exothermic cleansing article |
| CN101588785A (en) * | 2006-12-01 | 2009-11-25 | 强生消费者公司 | Self-warming moisturizing lotion in the double chamber bottle |
| US20090297586A1 (en) * | 2008-05-30 | 2009-12-03 | Kimberly-Clark Worldwide, Inc. | Tissue Products Having A Cooling Sensation When Contacted With Skin |
| CN102076325A (en) * | 2008-06-30 | 2011-05-25 | 金伯利-克拉克环球有限公司 | Polysensorial personal care cleanser |
| CN102525861A (en) * | 2012-02-09 | 2012-07-04 | 金红叶纸业集团有限公司 | Cool body lotion and household paper |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103099577B (en) | 2015-08-19 |
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