CN102924835B - High-strength high-inflaming-retardant rubber sheath material of mine cable and preparation process - Google Patents

Abstract

The invention discloses a high-strength high-inflaming-retardant rubber sheath material of a mine cable and a preparation process. The prescription of the material includes 38% of chlorinated polyethylene, 4% of magnesium oxide, 1.2% of dibasic lead sulfate, 1% of tribasic lead sulfate, 0.8% of lead stearate, 3.3% of dioctyl phthalate, 4% of chlorcosane, 17% of carbon black, 4% of antimonous oxide, 11% of magnesium hydrate, 3.5% of tri(2-chloroethyl)phosphate, 4% of precipitation white carbon black, 6% of calcium carbonate, 0.3% of surfactant gama-thiopropyl triethoxy silane, 1% of curing agent dicumyl peroxide and 0.9% of cocuring agent tri-allyl cyanuric acid ester. Inflaming-retarding performance of the rubber sheath material is improved by synergistic effect of fire retardant antimonous oxide, chlorinated paraffin, magnesium hydrate and tri(2-chloroethyl)phosphate, physical mechanical performance of the rubber sheath material is improved by adding reinforcing agent carbon black and the precipitation white carbon black. The material is simple in preparation process and strong in operability.

Description

High-intensity high combustion mining cable rubber sheath material and preparation technology

Original applying number 201110299112.8, on 09 29th, 2011 applying date, denomination of invention is: fire-retardant anti-tear mining cable rubber sheath material and preparation method.

Technical field

The present invention relates to the eraser sheath material for mineral products cable, also relate to the preparation technology of this material.

Background technology

Along with the development of open coal mine and Underground Mine electric coal winning machine tool, also more strict to the performance requriements of mine cable, not only require the insulation layer of cable to have excellent electric property, require sheath material to gather around good physical and mechanical properties simultaneously, as high in tensile strength, elongation at break; Furthermore, in mine, inevitably there is methane gas, have combustion explosion danger, mining needs to lay large numbers of various cables in well and electric energy is provided, controls signal and monitoring, requires cable sheath to have difficult combustion and flame-retarding power energy not.

Summary of the invention

First object of the present invention is to provide physical and mechanical properties and the good high-intensity high combustion mining cable rubber sheath material of flame retardant properties, has preferably physical and mechanical properties;

Second object of the present invention is to provide the preparation technology of above-mentioned mining cable rubber sheath material.

For achieving the above object, the technical solution used in the present invention is: for the eraser sheath material of mineral products cable, its material component and content are by weight percentage:

Chlorinatedpolyethylene 38%,

Magnesium oxide 4%,

Second base lead sulfate 1.2%,

Lead sulfate tribasic 1%,

Lead stearate 0.8%,

Dioctyl phthalate (DOP) 3.3%,

Clorafin 4%,

High wear-resistant carbon black 17%,

Antimonous oxide 4%,

Magnesium hydroxide 11%,

Trichloroethyl phosphate 3.5%,

Precipitated silica 4%,

Calcium carbonate 6%,

Tensio-active agent γ-mercaptopropyltriethoxysilane 0.3%,

Vulcanizing agent dicumyl peroxide 1%,

Cocuring agent iso-cyanuric acid triallyl ester 0.9%.

The preparation technology of the above-mentioned eraser sheath material for mineral products cable, comprises the following steps:

Step 1. 2min ~ 3min plasticates described chlorinatedpolyethylene 38% in 70 ℃ ~ 80 ℃ Banbury mixeies;

Step 2. in described Banbury mixer, add again described high wear-resistant carbon black 17%, described second base lead sulfate 1.2%, described lead sulfate tribasic 1%, described lead stearate 0.8%, described magnesium oxide 4%, described trichloroethyl phosphate 3.5%, described antimonous oxide 4%, described calcium carbonate 6%, mixing 2min ~ 3min;

Step 3. in described Banbury mixer, finally add described dioctyl phthalate (DOP) 3.3%, described clorafin 4%, described magnesium hydroxide 11%, described precipitated silica 4%, described tensio-active agent γ-mercaptopropyltriethoxysilane 0.3%, mixing 3min ~ 4min, form glue stuff compounding, this glue stuff compounding is discharged in the time that temperature reaches 90 ℃ ~ 100 ℃ from described Banbury mixer;

Step 4. the described glue stuff compounding of discharge thin-pass 1 ~ 2 time in mill, and carry out backswing glue 2 ~ 3 times, and then on tri-roll press machine, roll, do not open bar slice;

Step 5. the glue stuff compounding room temperature after calendering is deposited 8h, then put into mixer mixing, melting temperature adds described vulcanizing agent dicumyl peroxide 1%, described cocuring agent iso-cyanuric acid triallyl ester 0.9% while reaching 100 ℃, follow mixing 1min, then discharges glue stuff compounding;

Step 6. this glue stuff compounding thin-pass 1 ~ 2 time in mill, and carry out backswing glue 2 ~ 3 times, and then on tri-roll press machine, open bar slice, the rubber page of output is cooling through cooling roller, crosses after talcum powder case, makes finished product.

Due to the utilization of technique scheme, the present invention compared with prior art has following advantages:

The present invention is in high-intensity high combustion mining cable rubber sheath material, make base-material with chlorinatedpolyethylene, act synergistically to improve the flame retardant properties of rubber sheath material by adding fire retardant antimonous oxide, clorafin and magnesium hydroxide, trichloroethyl phosphate, improve the physical and mechanical properties of rubber sheath material by adding strengthening agent carbon black and precipitated silica, confirm through experiment, there is preferably physical and mechanical properties, there is good flame retardant properties, and preparation technology is simple, workable.

Embodiment

Further set forth the present invention below.

At the eraser sheath material for mineral products cable, make base-material with chlorinatedpolyethylene, by adding fire retardant antimonous oxide, clorafin and magnesium hydroxide, trichloroethyl phosphate acts synergistically to improve the flame retardant properties of rubber sheath material, specifically, antimonous oxide and clorafin carry out chemical reaction, generate butter of antimony, butter of antimony can be served as the free radical catcher in gaseous combustion district, can effectively flutter and catch the free radical that polymer combustion produces, play fire retardation, and trichloroethyl phosphate absorb magnesium hydroxide decompose discharge large quantity of moisture be heated generate phosphoric acid, metaphosphoric acid, these aerobic acids such as poly-metaphosphoric acid impel chlorinatedpolyethylene dehydration carbonization to form liquid film charcoal layer can be by oxygen and flammable volatile matter, hot and inner superpolymer matrix separates, weaken or interrupt burning.The water vapor that magnesium hydroxide decomposes generation more easily discharges and will absorb certain heat, reduce the temperature of system, the oxide compound charcoal layer that decomposes generation also can cover the surface of material equably, thereby heat and polymer materials are separated, improve filler fire retardation, in sheath material, improve the physical and mechanical properties of rubber sheath material by adding strengthening agent carbon black and precipitated silica, and magnesium hydroxide above-mentioned also there is certain strengthening action.In the other materials component of sheath material, magnesium oxide, except having certain flame retardant effect, mainly absorbs the hydrogen chloride gas producing in processing and sulfidation, or cheap and good-quality thermo-stabilizer.(in rubber compounding, should not use acid Synergist S-421 95, prevent the destruction of acid Synergist S-421 95 on superoxide and affect the sulfuration of chlorinated polyethylene rubber.Itself has alkalescence magnesium oxide, is again the important thermo-stabilizer of chlorinated polyethylene rubber).Calcium carbonate also plays absorbing hydrogen chloride effect, the hydrogenchloride that assurance decomposites is thoroughly removed, calcium carbonate is also as filler, reduce material cost, second base lead sulfate, lead sulfate tribasic, lead stearate is as stablizer, stop chlorinatedpolyethylene decomposes to produce hydrogenchloride, dioctyl phthalate (DOP) is as softening agent, be convenient to materials processing moulding, tensio-active agent can improve the consistency between organic substance and inorganic substance in material component, make each material component mixing full and uniform, improve the physical and mechanical properties of goods, the white carbon black that adopts the precipitator method to prepare, particle diameter is large, easily be uniformly dispersed, guarantee melting effect, vulcanizing agent makes material generation vulcanization crosslinking, make macromolecular material change tridimensional network into from linearity, improve machinery and the physicals of material, cocuring agent can increase cross-linking efficiency and thermotolerance.

Specific embodiment:

38 kilograms of chlorinatedpolyethylenees, 4 kilograms, magnesium oxide, 1.2 kilograms of second base lead sulfates, 1 kilogram of lead sulfate tribasic, 0.8 kilogram of lead stearate, 3.3 kilograms of dioctyl phthalate (DOP)s, 4 kilograms of clorafins, 17 kilograms of high wear-resistant carbon blacks, 4 kilograms of antimonous oxides, 11 kilograms of magnesium hydroxides, 3.5 kilograms of trichloroethyl phosphates, 4 kilograms of precipitated silicas, 6 kilograms, calcium carbonate, 0.3 kilogram of tensio-active agent γ-mercaptopropyltriethoxysilane, 1 kilogram of vulcanizing agent dicumyl peroxide, 0.9 kilogram of cocuring agent iso-cyanuric acid triallyl ester.

Preparation technology:

Step 1. 2min ~ 3min plasticates described chlorinatedpolyethylene 38% in 70 ℃ ~ 80 ℃ Banbury mixeies;

Step 2. in described Banbury mixer, add again described high wear-resistant carbon black 17%, described second base lead sulfate 1.2%, described lead sulfate tribasic 1%, described lead stearate 0.8%, described magnesium oxide 4%, described trichloroethyl phosphate 3.5%, described antimonous oxide 4%, described calcium carbonate 6%, mixing 2min ~ 3min;

Step 3. in described Banbury mixer, finally add described dioctyl phthalate (DOP) 3.3%, described clorafin 4%, described magnesium hydroxide 11%, described precipitated silica 4%, described tensio-active agent γ-mercaptopropyltriethoxysilane 0.3%, mixing 3min ~ 4min, form glue stuff compounding, this glue stuff compounding is discharged in the time that temperature reaches 90 ℃ ~ 100 ℃ from described Banbury mixer;

Step 4. the described glue stuff compounding of discharge thin-pass 1 ~ 2 time in mill, and carry out backswing glue 2 ~ 3 times, and then on tri-roll press machine, roll, do not open bar slice;

Step 5. the glue stuff compounding room temperature after calendering is deposited 8h, then put into mixer mixing, melting temperature adds described vulcanizing agent dicumyl peroxide 1%, described cocuring agent iso-cyanuric acid triallyl ester 0.9% while reaching 100 ℃, follow mixing 1min, then discharges glue stuff compounding;

Step 6. this glue stuff compounding thin-pass 1 ~ 2 time in mill, and carry out backswing glue 2 ~ 3 times, and then on tri-roll press machine, open bar slice, the rubber page of output is cooling through cooling roller, crosses after talcum powder case, makes finished product.

High-intensity high combustion mining cable rubber sheath material prepared by this example, the detection data of performance are as follows:

Aging condition: 80 ± 2 ℃ × 240 hours

To sum up, high-intensity high combustion mining cable rubber sheath of the present invention has preferably physical and mechanical properties, and oxygen index reaches 43, has good flame retardant properties, and preparation technology is simple, workable.

Above-described embodiment is only explanation technical conceive of the present invention and feature, and its object is to allow person skilled in the art can understand content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalences that spirit is done according to the present invention change or modify, within all should being encompassed in protection scope of the present invention.

Claims (2)

1. a high-intensity high combustion mining cable rubber sheath material, is characterized in that: its material component and content are by weight percentage:

Chlorinatedpolyethylene 38%,

Magnesium oxide 4%,

Second base lead sulfate 1.2%,

Lead sulfate tribasic 1%,

Lead stearate 0.8%,

Dioctyl phthalate (DOP) 3.3%,

Clorafin 4%,

High wear-resistant carbon black 17%,

Antimonous oxide 4%,

Magnesium hydroxide 11%,

Trichloroethyl phosphate 3.5%,

Precipitated silica 4%,

Calcium carbonate 6%,

Tensio-active agent γ-mercaptopropyltriethoxysilane 0.3%,

Vulcanizing agent dicumyl peroxide 1%,

Cocuring agent iso-cyanuric acid triallyl ester 0.9%.

2. the preparation technology of mining cable rubber sheath material as claimed in claim 1, is characterized in that: comprise the following steps:

Step 1. 2min ~ 3min plasticates described chlorinatedpolyethylene 38% in 70 ℃ ~ 80 ℃ Banbury mixeies;

Step 2. in described Banbury mixer, add again described high wear-resistant carbon black 17%, described second base lead sulfate 1.2%, described lead sulfate tribasic 1%, described lead stearate 0.8%, described magnesium oxide 4%, described trichloroethyl phosphate 3.5%, described antimonous oxide 4%, described calcium carbonate 6%, mixing 2min ~ 3min;

Step 3. in described Banbury mixer, finally add described dioctyl phthalate (DOP) 3.3%, described clorafin 4%, described magnesium hydroxide 11%, described precipitated silica 4%, described tensio-active agent γ-mercaptopropyltriethoxysilane 0.3%, mixing 3min ~ 4min, form glue stuff compounding, this glue stuff compounding is discharged in the time that temperature reaches 90 ℃ ~ 100 ℃ from described Banbury mixer;

Step 4. the described glue stuff compounding of discharge thin-pass 1 ~ 2 time in mill, and carry out backswing glue 2 ~ 3 times, and then on tri-roll press machine, roll, do not open bar slice;

Step 5. the glue stuff compounding room temperature after calendering is deposited 8h, then put into mixer mixing, melting temperature adds described vulcanizing agent dicumyl peroxide 1%, described cocuring agent iso-cyanuric acid triallyl ester 0.9% while reaching 100 ℃, follow mixing 1min, then discharges glue stuff compounding;

Step 6. this glue stuff compounding thin-pass 1 ~ 2 time in mill, and carry out backswing glue 2 ~ 3 times, and then on tri-roll press machine, open bar slice, the rubber page of output is cooling through cooling roller, crosses after talcum powder case, makes finished product.