CN102876171A - Energy-saving paint and preparation method thereof - Google Patents
Energy-saving paint and preparation method thereof Download PDFInfo
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- CN102876171A CN102876171A CN2012103187059A CN201210318705A CN102876171A CN 102876171 A CN102876171 A CN 102876171A CN 2012103187059 A CN2012103187059 A CN 2012103187059A CN 201210318705 A CN201210318705 A CN 201210318705A CN 102876171 A CN102876171 A CN 102876171A
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Abstract
The invention discloses energy-saving paint and a preparation method thereof. The energy-saving paint comprises the following components of cellulose, 2-amino-2-methyl-1-propanol-95 (AMP-95), a temperature-regulating, phase-changing, energy-storing and heat-preserving material, pure acrylic emulsion, a dispersing agent, a wetting agent, a defoaming agent, rutile titanium dioxide, glycol, a film forming aid, a preservative, a mildew prevention agent, a flattening agent, a thickening agent and deionized water. According to the energy-saving paint, the novel temperature-regulating, phase-changing, energy-storing and heat-preserving material is adopted, so that effects of saving energy by using latent heat, storing and releasing heat energy and making the room temperature be relatively balanced are achieved; and the energy-saving paint has sound absorbing, noise lowering, sterilizing, toxicity preventing, odor removing and fire and mildew preventing functions, and alkali can be prevented from being separated out.
Description
Technical field
The invention belongs to paint field, be specifically related to a kind of energy-saving paint and preparation method thereof.
Background technology
The energy consumption of buildings refers to buildings energy consumption in use, mainly comprise the energy consumptions such as heating, ventilation, air-conditioning, illumination, cooking fuel, household electrical appliance and hot water service, wherein take heating and air conditioning energy consumption as main, therefore, the emphasis of building energy-saving is exactly the energy consumption that reduces heating and cooling.The effect of thermal insulation coatings is exactly that the building enclosure of buildings is implemented insulation, to reduce the power loss of interior of building, reaches energy-conservation purpose.
In AND ENERGY RESOURCES CONSUMPTION IN CHINA, building energy consumption accounts for the 30-40% of human energy consumption, and improving the building heat preserving heat-proof quality is the important channel of save energy, raising buildings use function.Thermal insulating coating is applied over building surface can effectively reduce building surface and inner temperature.In recent years, along with the popularization of building energy conservation, thermal insulating coating more and more receives people's concern because of advantages such as economic, convenient and good heat-insulation effect.Existing insulating mold coating mainly adopts the heat insulation color stuffings such as organic polymer emulsion, cenosphere, porous filler and heat-reflecting material to reach the purpose of heat insulating, water proof anti-soil.
CN 1249321 discloses a kind of radioresistant insulating water paint that is applied to skin or metallic surface, formed by vinylformic acid synthetic emulsion, counter radiation ceramic packing, heat insulation silicate cavity filling, color stuffing, coatings additive(s), diluent water, have strong adhesion, coating is thin, nontoxic, pollution-free, heat-proof quality is good advantage.
CN 101108931 discloses a kind of aquosity elastic heat preserving insulating paint and preparation method thereof, has adopted the third two kinds of emulsions of elasticity pure third and silicon as film forming matter, has also adopted the materials such as lagging material, Rutile type Titanium Dioxide.
CN 101555377 discloses a kind of insulating mold coating, mixed by water, Mierocrystalline cellulose, dispersion agent, SPA202 defoamer, wetting agent, multifunctional assistant, propylene glycol, titanium dioxide, diatomite, hollow glass microbead, elastic water-proof emulsion, F111 defoamer, thickening material and anticorrosion and bactericidal agent raw material, have the effect of insulation, heat insulation, radioprotective, slip-off preventing, waterproof, fire prevention, anti-be full of cracks, antifreeze, washability, anti-contamination.
CN 1800283 disclosed a kind of thermal insulating coatings, its composition comprises: film forming matter 15-65 weight part; Nanoporous SiO
2The 3-20 weight part; Nano iron oxide yellow 1-12 weight part; Pigment 5-30 weight part; Filler 3-22 weight part; Auxiliary agent 0.4-8 weight part; Solvent 6-30 weight part.This thermal insulating coating to solar heat and ir radiation high-reflectivity is arranged, heat-insulating efficiency is high, anti-uv-ray is strong, and has super-weathering resistance, strong adhesive force and high self-cleaning performance.
CN 101121858 discloses a kind of thermal insulating coating that reflects the solar heat ray, it is made of bottom-coating and painting coating two portions, solids quality per-cent is in the described bottom-coating: hollow beads lagging material 5-40%, heat-reflecting material 10-50%, tackiness agent macromolecule resin 10-70%; Solids quality per-cent is in the painting coating; The surface coats reverberation ray matrix material 5-40%, heat-reflecting material 10-50%, tackiness agent macromolecule resin 10-70%.Coating of the present invention can reach 85-90% to the specular reflectance included of invisible heat.Can effectively prevent the thermal radiation of the sun.Particularly, primary coat adopts hollow beads lagging material, heat-reflecting material and macromolecule resin to make; Face is coated with and adopts surface coating reverberation ray matrix material, heat-reflecting material and macromolecule resin to make, since contain in the organic polymer a large amount of-C=O ,-C-O-C ,-the extinction groups such as OH, degree of absorption to sunlight will be higher than inorganic color stuffing, so when the addition of organic polymer emulsion is larger, it is also larger to the absorbed dose of sunlight to film, the thermal conductivity of filming also can correspondingly improve, and can reduce the effect of heat insulation of coating.
CN 102399483A discloses a kind of organic/inorganic composite heat-insulating heat-preserving water-based building coating and preparation method thereof, and coating of the present invention comprises following component: organic polymer emulsion, silicon sol, infrared ceramic powder, titanium dioxide, hollow glass micropearl, ceramic microsphere, wood fibre, talcum powder, kaolin, wetting agent, dispersion agent, film coalescence aid, frostproofer, silane coupling agent, fluorine-containing auxiliary agent, thickening material, biocide mildewcide, defoamer, pH adjusting agent and deionized water.The present invention utilizes the reflex action of ceramic microsphere and hollow glass micro-ball, the low thermal conductivity of silicon sol and low absorbance, make sunlight reflectivity height, the hemispherical emissivity of coating high, heat-proof quality is excellent, also have simultaneously excellent weathering resistance, water tolerance and contamination resistance energy, can be widely used in the heat-insulation and heat-preservation application of building, vehicle, oil product storage tank.
And in the modern life, because a lot of residential building is all built in the downtown area in city, noise is also very serious on people's life impact.People more and more expect a quiet environment, therefore how can make building coating have the effect of sound insulation, also are an exploitation of paint field directions.Existing deadener need to apply thicker outstanding mostly, and soundproof effect is just relatively good.
Since the eighties; in order to adapt to building industry to the various special requirements of superior development; Functional Architectural Coatings in China has obtained rapidly development; this class coating is except the protection and decorative effect with common building coating; also has some special function, such as waterproof paint, frie retardant coating, corrosion-proof paint, mould-repellant coating, insecticidal coating, deadener, anti-wave interference coating etc.
In existing functional paint, the functional majority of coating only possesses a kind of, how to develop a kind of collection insulation, sound insulation, sterilization, deodorizing, anti-ly analyse alkali, and can prevent fires, the environment-friendly type coating of mildew-resistant is a technical barrier of this area.
Summary of the invention
For the deficiencies in the prior art, one of purpose of the present invention is to provide a kind of energy-saving paint, and described energy-saving paint comprises following component: Mierocrystalline cellulose, AMP-95, temperature adjustment phase-change energy-storing thermal insulation material, pure-acrylic emulsion, dispersion agent, wetting agent, defoamer, rutile titanium white powder, ethylene glycol, film coalescence aid, sanitas, mould inhibitor, defoamer, flow agent, thickening material, deionized water; And the temperature adjustment phase-change energy-storing thermal insulation material occupies 40 ~ 80 weight parts in energy-saving paint, such as 41 weight parts, 48 weight parts, 58 weight parts, 70 weight parts, 77 weight parts etc.Preferably, described energy-saving paint comprises following component by weight:
Preferably, described Mierocrystalline cellulose is selected from cellulose acetate butyrate, carboxymethyl cellulose, methylcellulose gum, Vltra tears, Natvosol, Walocel MT 20.000PV, the combination of any a kind or at least 2 kinds in ethyl cellulose or the lignocellulose, described combination is cellulose acetate butyrate/carboxymethyl cellulose for example, cellulose acetate butyrate/Natvosol, methylcellulose gum/Walocel MT 20.000PV/ethyl cellulose, cellulose acetate butyrate/methylcellulose gum/Natvosol etc., preferred cellulose acetate butyrate, carboxymethyl cellulose, the combination of any a kind or at least 2 kinds in Natvosol or the Walocel MT 20.000PV.
Mierocrystalline cellulose can play thickening, water conservation, prevent that pigment and filler from precipitating, increasing effect, especially the ether of cellulose compounds of sticking power and cohesive strength in energy-saving paint of the present invention; Also play simultaneously effect, the especially cellulose acetate butyrate of the water tolerance that strengthens energy-saving paint of the present invention, weathering resistance, film-forming flexibility, heigh clarity, fire line.Mierocrystalline cellulose of the present invention all can be by commercially available.
Preferably, described temperature adjustment phase-change energy-storing thermal insulation material is selected from the polystyrene board heat-insulatation material, the polyphenyl plate heat preserving material, the combination of any a kind or at least 2 kinds in FTC self-temperature-adjusting phase change energy-saving and heat-insulating material or the HY-09 self-temperature-adjusting phase change energy-saving and heat-insulating material, described combination is polystyrene board heat-insulatation material/polyphenyl plate heat preserving material for example, FTC phase-transition heat-preserving material/polystyrene board heat-insulatation material, energy-conservation energy-storing thermal insulation material/the polyurethane heat insulation material of HY-09 self-temperature-adjusting phase change/FTC phase-transition heat-preserving material etc., preferably any a kind in FTC self-temperature-adjusting phase change energy-saving and heat-insulating material or the HY-09 self-temperature-adjusting phase change energy-saving and heat-insulating material.
The temperature adjustment phase-changing energy storage material in energy-saving paint of the present invention, play make energy-saving paint can self-temperature-adjusting phase change insulation, latent heat energy-conservation, thermal energy storage and release, make the effect of room temperature relative equilibrium, can also play the effect of absorbing sound and lowering noise simultaneously.Temperature adjustment phase-change energy-storing thermal insulation material of the present invention all can be by commercially available.
Preferably, described dispersion agent is the sodium salt dispersion agent, the ammonium salt dispersion agent, polycarboxylate sodium's dispersion agent, poly carboxylic acid ammonium salt dispersion agent, the SN-5040 dispersion agent, fast easily dispersion agent 1288, the combination of any a kind or at least 2 kinds in fast easily dispersion agent SE9300 or the Sodium hexametaphosphate 99 dispersion agent, described combination is sodium salt dispersion agent/SN-5040 dispersion agent for example, fast easily dispersion agent 1288/ fast easily dispersion agent SE9300/ Sodium hexametaphosphate 99 dispersion agent, poly carboxylic acid ammonium salt dispersion agent/fast easily dispersion agent 1288/SN-5040 dispersion agent etc., the particular certain cancers dispersion agent, the ammonium salt dispersion agent, the SN5040 dispersion agent, the Sodium hexametaphosphate 99 dispersion agent, the combination of any a kind or at least 2 kinds among the SE9300, further particular certain cancers dispersion agent and/or ammonium salt dispersion agent.
The effect of dispersion agent in environmental protection paint provided by the invention is the suspended particle of stablizing in the environmental protection paint, prevents the effect of its sedimentation and cohesion.Similarly, dispersion agent of the present invention all can be by commercially available.
Preferably, described wetting agent is selected from tensio-active agent, ethanol, propylene glycol, glycerine, methyl-sulphoxide, the PEG(polyoxyethylene glycol) combination of any a kind or at least 2 kinds in the class wetting agent, described tensio-active agent is selected from the AES(polyoxyethylenated alcohol sodium sulfate), the LAS(sodium branched alkyl benzene sulfonate), AEO-9(aliphatic alcohol polyethenoxy (9) ether), AEO-7(aliphatic alcohol polyethenoxy (7) ether), the AESA(AESA), OP-10(alkylphenol-polyethenoxy (10) ether), PE100(ethoxylation Voranol EP 2001) type wetting agent, Arlacel-80, sapn-90, the combination of any a kind or at least 2 kinds in Tween-60 or the tween-70; Described wetting agent is further preferably from AES, LAS, AEO-9, AEO-7, AESA, OP-10, PE100 type wetting agent, propylene glycol, glycerine, methyl-sulphoxide, ethanol, Arlacel-80, sapn-90, Tween-60, tween-70, PEG-200, the combination of wantonly a kind or at least 2 kinds among PEG-300 or the PEG-400, described combination is propylene glycol/PE100 type wetting agent for example, AESA/ ethanol, AES/AEO-9/ sapn-90, Tween-60/PEG-200/OP-10 etc. are particularly preferably from PE-100 type wetting agent, AEO-9, OP-10, Arlacel-80, Tween-60, the combination of any a kind or at least 2 kinds in propylene glycol or the methyl-sulphoxide.
The effect of wetting agent in environmental protection paint provided by the invention is be used to the surface tension of improving coating and perviousness, wetting ground better, thus improve the sticking power of coating; Simultaneously, wetting agent can also assist filler and pigment to disperse in coating, and certain anti-settling effect is arranged simultaneously.Similarly, wetting agent of the present invention all can be by commercially available.
Preferably, described defoamer is the combination of any a kind or at least 2 kinds in mineral oil antifoam agent and/or the silicone antifoam agent, wherein mineral oil antifoam agent is selected from the combination of any a kind or at least 2 kinds in the metallic soap of stearic acid defoamer, and wherein silicone antifoam agent is selected from the combination of any a kind or at least 2 kinds in polydimethylsiloxane defoamer, the dimethyl-silicon defoamer; Further preferably, described defoamer is selected from the combination of any a kind or at least 2 kinds in BASF 4200 defoamers, standing grain large SRE CN silicone antifoam agent or the Central Asia NXZ type defoamer.
The effect of defoamer in environmental protection paint provided by the invention is the effect that can play froth breaking in the use procedure of coating, press down bubble, can also reduce the probability that shrinkage cavity and flake produce simultaneously.Similarly, defoamer of the present invention all can be by commercially available.
Preferably, described film coalescence aid is selected from propylene glycol monomethyl ether, propandiol butyl ether, dipropylene glycol methyl ether, Diethylene Glycol butyl ether or 2,2,4-trimethylammonium-1, a kind or at least 2 kinds combination in the 3-pentanediol mono isobutyrate; Described combination is propylene glycol monomethyl ether/propandiol butyl ether, dipropylene glycol methyl ether/Diethylene Glycol butyl ether, 2,2 for example, 4-trimethylammonium-1, and 3-pentanediol mono isobutyrate/propandiol butyl ether/propylene glycol monomethyl ether etc., preferred 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate.The effect of membrane-forming agent in environmental protection paint provided by the invention is to obtain after coating is applied that the transparency is good, the paint film of good springiness, can prevent the generation of analysing the alkali phenomenon in the coating film process simultaneously.Similarly, membrane-forming agent of the present invention all can be by commercially available.
Preferably, described sanitas is selected from Kathon CG class sanitas, phenylformic acid, the combination of any a kind or at least 2 kinds in pentachlorophenol or the Salicylanlide, described combination is phenylformic acid/pentachlorophenol for example, Salicylanlide/phenylformic acid, 2-methyl-4 isothiazoline-3 ketone/5-chloro-2 methyl-4 isothiazoline-3 ketone/benzothiazolinone etc., the combination of any a kind or at least 2 kinds in preference card conifer sanitas or the phenylformic acid, further preferred 5-chloro-2 methyl-4 isothiazoline-3 ketone, 2-methyl-4 isothiazoline-3 ketone, the combination of any a kind or at least 2 kinds in benzothiazolinone or the phenylformic acid.
Preferably, described mould inhibitor is selected from the combination of any a kind or at least 2 kinds in derosal, organic iodine, iodo propinyl butyl carbamate, mould inhibitor IPBC, mould inhibitor OBPA, the Nordes EPW film preservative, described combination such as derosal/organic iodine, iodo propinyl butyl carbamate/mould inhibitor IPBC, Nordes EPW film preservative/mould inhibitor OBPA etc., preferred how clever bacterium and/or organic iodine.The effect of mould inhibitor in environmental protection paint provided by the invention is sterilization gas defence, sterilization, deodorization.Mould inhibitor of the present invention all can be by commercially available.
Preferably, described flow agent is selected from polyurethanes flow agent, polyacrylic flow agent, GSK-588 series flow agent, optimization polyurethane class flow agent, further the optimization polyurethane aqueous solution.The effect of flow agent in energy-saving paint of the present invention be impel coating in the drying and forming-film process, form one smooth, smooth, film uniformly.Flow agent of the present invention all can be by commercially available.
Preferably, described thickening material is selected from a kind or at least 2 kinds combination in Natvosol, hydroxypropylcellulose, polyurethanes thickening material or the alkali swelling type thickening material, described alkali swelling type thickening material is ASE-60 type thickening material and/or DR-72 type thickening material, preferred Natvosol, AES-60 type thickening material.Thickening material of the present invention all can be by commercially available.
Preferably, described energy-saving paint comprises following component by weight:
Further preferably, described energy-saving paint comprises following component by weight:
Alternatively, described energy-saving paint comprises following component by weight:
" comprising " of the present invention, mean it except described component, can also comprise other components, these other components give described energy-saving paint different characteristics.In addition, " comprising " of the present invention, can also replace with enclosed " being " or " by ... form ".
Two of purpose of the present invention is to provide a kind of preparation method of energy-saving paint, comprises the steps:
(1) deionized water that takes by weighing 160 ~ 220 weight parts drops in the reactor, then starts high speed dispersor control rotating speed 300-500r/min;
(2) Mierocrystalline cellulose and the AMP-95 that take by weighing formula ratio drop into reactor, and rotating speed is brought up to 700-1000r/min to being uniformly dispersed into pasty state, and temperature is controlled at below 40 ℃, and dispersion agent, wetting agent and the defoamer that takes by weighing formula ratio drops into successively and stir 8-20min;
(3) take by weighing the Rutile type Titanium Dioxide of formula ratio and the deionized water of temperature adjustment phase-change energy-storing thermal insulation material and 30-60 weight part, drop in the reactor, rotating speed is brought up to 1100-1400r/min, high speed dispersion 20-60min, temperature of reaction is controlled at below 40 ℃, gets final product when the fineness of materials in the reactor≤70 μ m;
(4) rotating speed is reduced to ethylene glycol, film coalescence aid, sanitas, mould inhibitor, the defoamer that 600r/min takes by weighing formula ratio, drops into successively and stir 8-20min in the reactor, temperature is controlled at below 40 ℃;
(5) take by weighing the deionized water and stirring 8-20min of pure-acrylic emulsion and 10-100 weight part;
(6) take by weighing flow agent drop into stir in the reactor after, take by weighing thickening material and regulate the viscosity that is fit to.
Preferably, the preparation method of described energy-saving paint comprises the steps:
(1) deionized water that takes by weighing 160 ~ 220 weight parts drops in the reactor, then starts high speed dispersor control rotating speed 300-500r/min;
(2) Mierocrystalline cellulose and the AMP-95 that take by weighing formula ratio drop into reactor, and rotating speed is brought up to 700-1000r/min to being uniformly dispersed into pasty state, and temperature is controlled at below 40 ℃, and dispersion agent, wetting agent and the defoamer that takes by weighing formula ratio drops into successively and stir 8-20min;
(3) take by weighing the deionized water of Rutile type Titanium Dioxide, temperature adjustment phase-change energy-storing thermal insulation material and the 30-60 weight part of formula ratio, drop in the reactor, rotating speed is brought up to 1100-1400r/min, high speed dispersion 20-60min, temperature of reaction is controlled at below 40 ℃, gets final product when the fineness of materials in the reactor≤70 μ m;
(4) rotating speed is reduced to ethylene glycol, film coalescence aid, sanitas, mould inhibitor, the defoamer that 600r/min takes by weighing formula ratio, drops into successively and stir 8-20min in the reactor, temperature is controlled at below 40 ℃;
(5) take by weighing the deionized water and stirring 8-20min of pure-acrylic emulsion and 10-100 weight part;
(6) take by weighing flow agent drop into stir in the reactor after, take by weighing thickening material and regulate the viscosity that is fit to.
Compared with prior art, the present invention has following beneficial effect:
(1) adopts the insulation of lagging material self-temperature-adjusting phase change, reach that latent heat is energy-conservation, thermal energy storage and release, make the effect of room temperature relative equilibrium;
(2) the present invention is by the effect of each component synergy of energy-saving paint, make the energy-saving paint that provides have sqouynd absorption lowering noise, reduction noise decibels, sterilization gas defence, sterilization, deodorization, has simultaneously the anti-alkali function of analysing, can improve the living environment hygienic requirements, the effect that also has fire prevention, mildew-resistant, be a kind of collection insulation, sound insulation, sterilization, deodorizing, anti-ly analyse alkali, and can prevent fires, the environment-friendly type coating of mildew-resistant;
(3) energy-saving paint provided by the invention pollution-free without burn into, without radiation, free from extraneous odour, without the environmentally friendly machine of any murder by poisoning.
Embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art should understand that described embodiment helps to understand the present invention, should not be considered as concrete restriction of the present invention.
Embodiment 1
A kind of energy-saving paint comprises following component by weight:
Cellulose acetate butyrate 7, Gutian, AMP-95(Nanjing chemical industry company limited) 0.5, FTC self-temperature-adjusting phase change energy-saving and heat-insulating material (Beijing industrial development in science and technology of huge energy company limited) 180, pure-acrylic emulsion (BASF) 180, SN-5040 dispersion agent (Central Asia, Taiwan chemical company limited) 10, Arlacel-80 (DOW Chemical) 1, OP-10(DOW Chemical 1, the large SRE CN of standing grain silicone antifoam agent 0.5, Rutile type Titanium Dioxide 50, ethylene glycol 30,2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 38, Kathon CG class sanitas KF-882.5, NordesEPW film preservative 0.8, GSK-588 series flow agent 4, ASE-60 type thickening material (ROHM AND HAAS) 12, deionized water 200;
The preparation method of described energy-saving paint is as follows:
(1) deionized water that takes by weighing 160 weight parts drops in the reactor, then starts high speed dispersor control rotating speed 300r/min;
(2) Mierocrystalline cellulose and the AMP-95 that take by weighing formula ratio drop into reactor, and rotating speed is brought up to 700r/min to being uniformly dispersed into pasty state, and temperature is controlled at below 40 ℃, and dispersion agent, wetting agent and the defoamer that takes by weighing formula ratio drops into successively and stir 8min;
(3) take by weighing the Rutile type Titanium Dioxide of formula ratio and the deionized water of temperature adjustment phase-change energy-storing thermal insulation material and 30 weight parts, drop in the reactor, rotating speed is brought up to 1100r/min, high speed dispersion 20min, temperature of reaction is controlled at below 40 ℃, gets final product when the fineness of materials in the reactor≤70 μ m;
(4) rotating speed is reduced to ethylene glycol, film coalescence aid, sanitas, mould inhibitor, the defoamer that 600r/min takes by weighing formula ratio, drops into successively and stir 8min in the reactor, temperature is controlled at below 40 ℃;
(5) take by weighing the deionized water and stirring 8min of pure-acrylic emulsion and 10 weight parts;
(6) take by weighing flow agent drop into stir in the reactor after, take by weighing thickening material and regulate the viscosity that is fit to.
Embodiment 2
A kind of energy-saving paint comprises following component by weight:
Natvosol 0.8, Walocel MT 20.000PV 0.2, AMP-952, HY-09 self-temperature-adjusting phase change energy-saving and heat-insulating material (the great space development in science and technology in Langfang company limited) 40, pure-acrylic emulsion (BASF) 380, fast easily dispersion agent 1288(ROHM AND HAAS) 0.8, fast easily dispersion agent SE9300(ROHM AND HAAS) 1.2, glycerine 2, PE100 type wetting agent 6, NXZ type defoamer (Central Asia, Taiwan chemical company limited) 6, Rutile type Titanium Dioxide 280, ethylene glycol 8, Diethylene Glycol butyl ether 5,2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 3, MIT 0.5, mould inhibitor OBPA(likes in Shandong general chemical company limited) 10, aqueous polyurethane 1, DR-72 type thickening material (ROHM AND HAAS) 1, deionized water 380;
The preparation method of described energy-saving paint is as follows:
(1) deionized water that takes by weighing 220 weight parts drops in the reactor, then starts high speed dispersor control rotating speed 500r/min;
(2) Mierocrystalline cellulose and the AMP-95 that take by weighing formula ratio drop into reactor, and rotating speed is brought up to 1000r/min to being uniformly dispersed into pasty state, and temperature is controlled at below 40 ℃, and dispersion agent, wetting agent and the defoamer that takes by weighing formula ratio drops into successively and stir 20min;
(3) take by weighing the Rutile type Titanium Dioxide of formula ratio and the deionized water of temperature adjustment phase-change energy-storing thermal insulation material and 60 weight parts, drop in the reactor, rotating speed is brought up to 1400r/min, high speed dispersion 60min, temperature of reaction is controlled at below 40 ℃, gets final product when the fineness of materials in the reactor≤70 μ m;
(4) rotating speed is reduced to ethylene glycol, film coalescence aid, sanitas, mould inhibitor, the defoamer that 600r/min takes by weighing formula ratio, drops into successively and stir 20min in the reactor, temperature is controlled at below 40 ℃;
(5) take by weighing the deionized water and stirring 20min of pure-acrylic emulsion and 100 weight parts;
(6) take by weighing flow agent drop into stir in the reactor after, take by weighing thickening material and regulate the viscosity that is fit to.
Embodiment 3
A kind of energy-saving paint comprises following component by weight:
Methylcellulose gum 3.2, AMP-951.7, HY-09 self-temperature-adjusting phase change energy-saving and heat-insulating material (the great space development in science and technology in Langfang company limited) 121, pure-acrylic emulsion (BASF) 214, Sodium hexametaphosphate 99 dispersion agent 4.2, AEO-92, AEO-72.1,4200 defoamers (BASF) 3.3, Rutile type Titanium Dioxide 101, ethylene glycol 18, propylene glycol monomethyl ether 28, phenylformic acid 1.5, organic iodine 3.2, aqueous polyurethane 3, Natvosol 4.8, deionized water 300;
The preparation method of described energy-saving paint is as follows:
(1) deionized water that takes by weighing 195 weight parts drops in the reactor, then starts high speed dispersor control rotating speed 400r/min;
(2) Mierocrystalline cellulose and the AMP-95 that take by weighing formula ratio drop into reactor, and rotating speed is brought up to 900r/min to being uniformly dispersed into pasty state, and temperature is controlled at below 40 ℃, and dispersion agent, wetting agent and the defoamer that takes by weighing formula ratio drops into successively and stir 17min;
(3) take by weighing the Rutile type Titanium Dioxide of formula ratio and the deionized water of temperature adjustment phase-change energy-storing thermal insulation material and 35 weight parts, drop in the reactor, rotating speed is brought up to 1300r/min, high speed dispersion 30min, temperature of reaction is controlled at below 40 ℃, gets final product when the fineness of materials in the reactor≤70 μ m;
(4) rotating speed is reduced to ethylene glycol, film coalescence aid, sanitas, mould inhibitor, the defoamer that 600r/min takes by weighing formula ratio, drops into successively and stir 14min in the reactor, temperature is controlled at below 40 ℃;
(5) take by weighing the deionized water and stirring 16min of pure-acrylic emulsion and 70 weight parts;
(6) take by weighing flow agent drop into stir in the reactor after, take by weighing thickening material and regulate the viscosity that is fit to.
Applicant's statement, the present invention illustrates detailed process equipment and process flow process of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned detailed process equipment and process flow process, does not mean that namely the present invention must rely on above-mentioned detailed process equipment and process flow process and could implement.The person of ordinary skill in the field should understand, any improvement in the present invention to the interpolation of the equivalence replacement of each raw material of product of the present invention and ancillary component, the selection of concrete mode etc., all drops within protection scope of the present invention and the open scope.
Claims (10)
1. energy-saving paint, it is characterized in that described energy-saving paint comprises following component: Mierocrystalline cellulose, AMP-95, temperature adjustment phase-change energy-storing thermal insulation material, pure-acrylic emulsion, dispersion agent, wetting agent, defoamer, rutile titanium white powder, ethylene glycol, film coalescence aid, sanitas, mould inhibitor, defoamer, flow agent, thickening material, deionized water;
And the temperature adjustment phase-change energy-storing thermal insulation material occupies 40 ~ 80 weight parts in energy-saving paint.
2. energy-saving paint as claimed in claim 1 is characterized in that, described energy-saving paint comprises following component by weight:
3. energy-saving paint as claimed in claim 1 or 2, it is characterized in that, preferably, described Mierocrystalline cellulose is selected from the combination of any a kind or at least 2 kinds in cellulose acetate butyrate, carboxymethyl cellulose, methylcellulose gum, Vltra tears, Natvosol, Walocel MT 20.000PV, ethyl cellulose or the lignocellulose, the combination of any a kind or at least 2 kinds in preferred cellulose acetate butyrate, carboxymethyl cellulose, Natvosol or the Walocel MT 20.000PV;
Preferably, described temperature adjustment phase-change energy-storing thermal insulation material is selected from the combination of any a kind or at least 2 kinds in polystyrene board heat-insulatation material, polyphenyl plate heat preserving material, polyurethane heat insulation material, FTC self-temperature-adjusting phase change energy-saving and heat-insulating material or the HY-09 self-temperature-adjusting phase change energy-saving and heat-insulating material, in preferred FTC self-temperature-adjusting phase change energy-saving and heat-insulating material or the HY-09 self-temperature-adjusting phase change energy-saving and heat-insulating material any a kind.
4. energy-saving paint as claimed in claim 1 or 2, it is characterized in that, described dispersion agent is the combination of any a kind or at least 2 kinds in sodium salt dispersion agent, ammonium salt dispersion agent, polycarboxylate sodium's dispersion agent, poly carboxylic acid ammonium salt dispersion agent, SN-5040 dispersion agent, fast easily dispersion agent 1288, fast easily dispersion agent SE9300 or the Sodium hexametaphosphate 99 dispersion agent, the combination of any a kind or at least 2 kinds among particular certain cancers dispersion agent, ammonium salt dispersion agent, SN5040 dispersion agent, Sodium hexametaphosphate 99 dispersion agent, the SE9300, further particular certain cancers dispersion agent and/or ammonium salt dispersion agent;
Preferably, described wetting agent is selected from the combination of any a kind or at least 2 kinds in tensio-active agent, ethanol, propylene glycol, glycerine, methyl-sulphoxide, the PEG class wetting agent, and described tensio-active agent is selected from the combination of any a kind or at least 2 kinds in AES, LAS, AEO-9, AEO-7, AESA, OP-10, PE100 type wetting agent, Arlacel-80, sapn-90, Tween-60 or the tween-70; Described wetting agent is the combination of preferred wantonly a kind or at least 2 kinds in AES, LAS, AEO-9, AEO-7, AESA, OP-10, PE100 type wetting agent, propylene glycol, glycerine, methyl-sulphoxide, ethanol, Arlacel-80, sapn-90, Tween-60, tween-70, PEG-200, PEG-300 or PEG-400 further, particularly preferably the combination of any a kind or at least 2 kinds in PE-100 type wetting agent, AEO-9, OP-10, Arlacel-80, Tween-60, propylene glycol or methyl-sulphoxide;
Preferably, described defoamer is the combination of any a kind or at least 2 kinds in mineral oil antifoam agent and/or the silicone antifoam agent, wherein mineral oil antifoam agent is selected from the combination of any a kind or at least 2 kinds in the metallic soap of stearic acid defoamer, and wherein silicone antifoam agent is selected from the combination of any a kind or at least 2 kinds in polydimethylsiloxane defoamer, the dimethyl-silicon defoamer; Further preferably, described defoamer is selected from the combination of any a kind or at least 2 kinds in BASF 4200 defoamers, standing grain large SRE CN silicone antifoam agent or the Central Asia NXZ type defoamer.
5. energy-saving paint as claimed in claim 1 or 2, it is characterized in that described film coalescence aid is selected from propylene glycol monomethyl ether, propandiol butyl ether, dipropylene glycol methyl ether, Diethylene Glycol butyl ether or 2,2,4-trimethylammonium-1, a kind or at least 2 kinds combination in the 3-pentanediol mono isobutyrate; Preferred 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate;
Preferably, described sanitas is selected from the combination of any a kind or at least 2 kinds in Kathon CG class sanitas, phenylformic acid, pentachlorophenol or the Salicylanlide, the combination of any a kind or at least 2 kinds in preference card conifer sanitas or the phenylformic acid, the combination of any a kind or at least 2 kinds in further preferred 5-chloro-2 methyl-4 isothiazoline-3 ketone, 2-methyl-4 isothiazoline-3 ketone, benzothiazolinone or the phenylformic acid;
Preferably, described mould inhibitor is selected from the combination of any a kind or at least 2 kinds in derosal, organic iodine, iodo propinyl butyl carbamate, mould inhibitor IPBC, mould inhibitor OBPA, the Nordes EPW film preservative, preferred how clever bacterium and/or organic iodine;
Preferably, described flow agent is selected from polyurethanes flow agent, polyacrylic flow agent, GSK-588 series flow agent, optimization polyurethane class flow agent, further the optimization polyurethane aqueous solution;
Preferably, described thickening material is selected from a kind or at least 2 kinds combination in Natvosol, hydroxypropylcellulose, polyurethanes thickening material or the alkali swelling type thickening material, described alkali swelling type thickening material is ASE-60 type thickening material and/or DR-72 type thickening material, preferred Natvosol, AES-60 type thickening material.
6. such as the described energy-saving paint of one of claim 1-5, it is characterized in that described energy-saving paint comprises following component by weight:
7. such as the described energy-saving paint of one of claim 1-6, it is characterized in that described energy-saving paint comprises following component by weight:
8. such as the described energy-saving paint of one of claim 1-7, it is characterized in that described energy-saving paint comprises following component by weight:
9. such as the preparation method of one of claim 1-8 described energy-saving paint, it is characterized in that the preparation method of described energy-saving paint comprises the steps:
(1) deionized water that takes by weighing 160 ~ 220 weight parts drops in the reactor, then starts high speed dispersor control rotating speed 300-500r/min;
(2) Mierocrystalline cellulose and the AMP-95 that take by weighing formula ratio drop into reactor, and rotating speed is brought up to 700-1000r/min to being uniformly dispersed into pasty state, and temperature is controlled at below 40 ℃, and dispersion agent, wetting agent and the defoamer that takes by weighing formula ratio drops into successively and stir 8-20min;
(3) take by weighing the deionized water of Rutile type Titanium Dioxide, temperature adjustment phase-change energy-storing thermal insulation material and the 30-60 weight part of formula ratio, drop in the reactor, rotating speed is brought up to 1100-1400r/min, high speed dispersion 20-60min, temperature of reaction is controlled at below 40 ℃, gets final product when the fineness of materials in the reactor≤70 μ m;
(4) rotating speed is reduced to ethylene glycol, film coalescence aid, sanitas, mould inhibitor, the defoamer that 600r/min takes by weighing formula ratio, drops into successively and stir 8-20min in the reactor, temperature is controlled at below 40 ℃;
(5) take by weighing the deionized water and stirring 8-20min of pure-acrylic emulsion and 10-100 weight part;
(6) take by weighing flow agent drop into stir in the reactor after, take by weighing thickening material and regulate the viscosity that is fit to.
10. the preparation method of energy-saving paint as claimed in claim 9 is characterized in that, the preparation method of described energy-saving paint comprises the steps:
(1) deionized water that takes by weighing 160 ~ 220 weight parts drops in the reactor, then starts high speed dispersor control rotating speed 300-500r/min;
(2) Mierocrystalline cellulose and the AMP-95 that take by weighing formula ratio drop into reactor, and rotating speed is brought up to 700-1000r/min to being uniformly dispersed into pasty state, and temperature is controlled at below 40 ℃, and dispersion agent, wetting agent and the defoamer that takes by weighing formula ratio drops into successively and stir 8-20min;
(3) take by weighing the deionized water of Rutile type Titanium Dioxide, temperature adjustment phase-change energy-storing thermal insulation material and the 30-60 weight part of formula ratio, drop in the reactor, rotating speed is brought up to 1100-1400r/min, high speed dispersion 20-60min, temperature of reaction is controlled at below 40 ℃, gets final product when the fineness of materials in the reactor≤70 μ m;
(4) rotating speed is reduced to ethylene glycol, film coalescence aid, sanitas, mould inhibitor, the defoamer that 600r/min takes by weighing formula ratio, drops into successively and stir 8-20min in the reactor, temperature is controlled at below 40 ℃;
(5) take by weighing the deionized water and stirring 8-20min of pure-acrylic emulsion and 10-100 weight part;
(6) take by weighing flow agent drop into stir in the reactor after, take by weighing thickening material and regulate the viscosity that is fit to.
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| CN2012103187059A CN102876171A (en) | 2012-08-31 | 2012-08-31 | Energy-saving paint and preparation method thereof |
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| CN2012103187059A CN102876171A (en) | 2012-08-31 | 2012-08-31 | Energy-saving paint and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104496269A (en) * | 2014-12-17 | 2015-04-08 | 亚士漆(上海)有限公司 | Heat insulating real stone paint and preparation method thereof |
| CN106013865A (en) * | 2016-06-03 | 2016-10-12 | 国网河南南召县供电公司 | Noise reduction and protection device for outdoor power transformer |
| CN107474651A (en) * | 2017-08-23 | 2017-12-15 | 重庆索利特涂料有限公司 | A kind of engineering external wall energy-saving paint and preparation method thereof |
| CN110157177A (en) * | 2018-02-06 | 2019-08-23 | 重庆熵臻科技有限公司 | A kind of formula and preparation method thereof for the water-proof environmental protection air filtrate that heat insulation effect is good |
| CN112592625A (en) * | 2021-01-06 | 2021-04-02 | 成都途伊棠涂料科技有限公司 | Preparation method of reflective heat-insulation heat-preservation composite building coating |
| CN114672198A (en) * | 2022-04-02 | 2022-06-28 | 重庆禾维科技有限公司 | Temperature-sensitive composition and preparation method and application thereof |
| CN115193374A (en) * | 2022-07-06 | 2022-10-18 | 安徽银客松新材料科技有限公司 | Preparation method of easy-drying water-based sound insulation coating |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4118437A (en) * | 1976-04-08 | 1978-10-03 | American Cyanamid Company | Cross linkable powder coating compositions |
| CN1844269A (en) * | 2006-05-08 | 2006-10-11 | 清华大学深圳研究生院 | Phase-transition energy-storage microcapsules and their preparing process |
| CN1927952A (en) * | 2006-09-28 | 2007-03-14 | 成都新柯力化工科技有限公司 | Energy-saving building coating and preparation method |
| CN101348626A (en) * | 2008-09-17 | 2009-01-21 | 中国建筑材料科学研究总院 | Temperature adjustment coating and preparation thereof |
| CN102504666A (en) * | 2011-11-23 | 2012-06-20 | 唐国军 | Environment-friendly interior wall coating material |
-
2012
- 2012-08-31 CN CN2012103187059A patent/CN102876171A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4118437A (en) * | 1976-04-08 | 1978-10-03 | American Cyanamid Company | Cross linkable powder coating compositions |
| CN1844269A (en) * | 2006-05-08 | 2006-10-11 | 清华大学深圳研究生院 | Phase-transition energy-storage microcapsules and their preparing process |
| CN1927952A (en) * | 2006-09-28 | 2007-03-14 | 成都新柯力化工科技有限公司 | Energy-saving building coating and preparation method |
| CN101348626A (en) * | 2008-09-17 | 2009-01-21 | 中国建筑材料科学研究总院 | Temperature adjustment coating and preparation thereof |
| CN102504666A (en) * | 2011-11-23 | 2012-06-20 | 唐国军 | Environment-friendly interior wall coating material |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104496269A (en) * | 2014-12-17 | 2015-04-08 | 亚士漆(上海)有限公司 | Heat insulating real stone paint and preparation method thereof |
| CN106013865A (en) * | 2016-06-03 | 2016-10-12 | 国网河南南召县供电公司 | Noise reduction and protection device for outdoor power transformer |
| CN106013865B (en) * | 2016-06-03 | 2018-06-22 | 国网河南省电力公司南召县供电公司 | A kind of outdoor electric transformer noise reduction protective device |
| CN107474651A (en) * | 2017-08-23 | 2017-12-15 | 重庆索利特涂料有限公司 | A kind of engineering external wall energy-saving paint and preparation method thereof |
| CN110157177A (en) * | 2018-02-06 | 2019-08-23 | 重庆熵臻科技有限公司 | A kind of formula and preparation method thereof for the water-proof environmental protection air filtrate that heat insulation effect is good |
| CN112592625A (en) * | 2021-01-06 | 2021-04-02 | 成都途伊棠涂料科技有限公司 | Preparation method of reflective heat-insulation heat-preservation composite building coating |
| CN114672198A (en) * | 2022-04-02 | 2022-06-28 | 重庆禾维科技有限公司 | Temperature-sensitive composition and preparation method and application thereof |
| CN115193374A (en) * | 2022-07-06 | 2022-10-18 | 安徽银客松新材料科技有限公司 | Preparation method of easy-drying water-based sound insulation coating |
| CN115193374B (en) * | 2022-07-06 | 2023-07-07 | 安徽银客松新材料科技有限公司 | Preparation method of easy-to-dry water-based sound-insulation coating |
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Application publication date: 20130116 |