CN102851672A - Special antiscaling agent for water heater - Google Patents

Special antiscaling agent for water heater Download PDF

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Publication number
CN102851672A
CN102851672A CN2012103624760A CN201210362476A CN102851672A CN 102851672 A CN102851672 A CN 102851672A CN 2012103624760 A CN2012103624760 A CN 2012103624760A CN 201210362476 A CN201210362476 A CN 201210362476A CN 102851672 A CN102851672 A CN 102851672A
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component
water
scale remover
described component
weight percent
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CN102851672B (en
Inventor
刘萌
李文东
李朝顺
甄志超
刘晓青
杨永生
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China Science Pioneer Engineering Plastics National Engineering Research Center Co ltd
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HKH NATIONAL ENGINEERING RESEARCH CENTER OF PLASTICS Co Ltd
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Abstract

The invention relates to a chemical cleaning material, and in particular to a special chemical cleaning material for removing scale of a water heater. The special antiscaling agent for the water heater is characterized by being formed by mixing components A, B, C and C, wherein the component A is an acidic antiscaling component which is 70 to 95% in percentage by weight; the component B is an adhesive which is 2 to 8% in percentage by weight; the component C includes a metal ion chelating agent and a curing agent, which is 2 to 20% in percentage by weight; and the component D is a corrosion inhibitor, which is 1 to 5% in percentage by weight. With the adoption of the prescription, the special antiscaling agent for the water heater provided by the invention has the advantages of being relatively low corrosion to metal, and high antiscaling performance; and moreover, the special antiscaling agent can be manufactured in a certain shape, and the dimension is in line with that of a sewage draining port of the water heater; and the antiscaling agent can be directly added to the water heater through the sewage draining port; the problem that the powdered material or liquid is hardly added can be solved; the antiscaling agent is convenient and quick to use, and the operation is simple to carry out.

Description

A kind of water-heater Special scale remover
Technical field
The present invention relates to a kind of matting material, especially relate to a kind of matting material of water-heater scale removal special use.
Background technology
The incrustation scale of water-heater inside is very complicated, usually incrustation scale is divided into four classes by its main chemical compositions: carbonate deposit, silicate scale, sulfate scale and mixing incrustation scale.Contain calcium, magnesium ion and carbonate, bicarbonate radical, sulfate radical etc. in the water.When water reached certain temperature, calcium wherein, magnesium ion were combined with acid group, generated calcium carbonate, magnesiumcarbonate, calcium sulfate etc. and separated out precipitation, thereby form incrustation scale.
Incrustation scale can have a strong impact on thermal conduction, and the calcium carbonate in the incrustation scale, magnesiumcarbonate a large amount of depositions in human body easily form calculus.With the serious water face-washing of incrustation scale, have a bath, can form the calcium magnesium soap, stick on the face, on the skin, make dirt be not easy to remove.So no matter from water heater arrangement aspect or life aspect regularly scale removal be necessary.Scale removal product category in the market is various, mainly contains industrial scale remover, such as the scale remover of boiler detergent, eliminating sludge in pipe agent and other heat-exchange equipments.Along with growth in the living standard, people are also more and more higher to the requirement of quality of life now, so the share of market of household descaling agent is also more and more higher, household descaling agent mainly contains deincrustant of water dispenser, water-heater scale remover etc.
Chinese invention patent application specification sheets CN1213649A discloses a kind of compound method of descaling agent for gas water heater, the chemical substance and the weight percent thereof that adopt are: the incrustation scale solvating agent uses citric acid or the tartrate of 2-8%, permeate agent uses polyoxyethylenated alcohol sodium sulfate or the sodium lauryl sulphate of 0.4-1%, inhibiter uses the benzotriazole of 0.008-0.03%, sequestering agent uses the thiocarbamide of 0.3-0.8%, suspension agent uses carboxymethyl cellulose or the sodium polyacrylate of 0.2-1%, all the other content are water, above-mentioned various chemical substances stirring and dissolving in water.Although this scale remover prescription is better to the effect of metal protection, actual because incrustation scale solvating agent content is lower, descale effect is relatively poor.
Chinese invention patent application monologue story-telling with gestures CN1301809A discloses a kind of household descaling agent, mainly contains concentration and be 31% hydrochloric acid, gelatin, hexamethylenetetramine, oxalic dialdehyde, and water.This scale remover adopts the stronger hydrochloric acid of molten dirty ability as scale-dissolving agent, but hydrochloric acid acidity is stronger, and is relatively poor to the protective capability of metal.
In addition; the sewage draining exit direction of hanging electric water heater down; Powdered or liquid scale remover is difficult to be added in the water heater liner, so the patent of invention of scale remover not only needs to consider descale effect and to the protection of water heater liner, more needs to consider to use feasibility and the accessibility of operation.
Summary of the invention
Technical problem to be solved by this invention provides a kind ofly can effectively remove incrustation scale, can effectively protect the uncorroded water-heater Special scale remover of metal again.
In order to solve the problems of the technologies described above, the technical solution used in the present invention is: a kind of water-heater Special scale remover is characterized in that: mixed by component A, B, C, D, described component A is acids scale removal composition, and its weight percent is 70%~95%; Described component B is binding agent, and its weight percent is 2%~8%; Described component C is metal ion chelation agent and solidifying agent, and its weight percent is 2%~20%; Described component D is inhibiter, and its weight percent is 1%~5%.
As a further improvement on the present invention, described component A is selected from one or both in citric acid, thionamic acid, oxysuccinic acid, tartrate, toxilic acid, ethylenediamine tetraacetic acid (EDTA), the trichoroacetic acid(TCA); Described component B is selected from one or both in macromolecular water-soluble gelatin powder, Starso, Xylo-Mucine, the cohesiveness polyvinyl alcohol; Component C is selected from one or both in disodium EDTA (being EDETATE DISODIUM), the trisodium phosphate; Component D is selected from one or both in urotropine, the Sodium dodecylbenzene sulfonate.
As a further improvement on the present invention, described component A is thionamic acid, and described component B is Starso, and described component C is trisodium phosphate, and described component D is Sodium dodecylbenzene sulfonate.
As a further improvement on the present invention, the weight percent of described component A is 80%~90%; The weight percent of described component B is 4%~6%; The weight percent of described component C is 4%~10%; The weight percent of described component D is 2%~4%.
As a further improvement on the present invention, the purity of component A is 95-99.5%; The purity of component B is 90%~99%; The purity of component C is 95%~99%.
As a further improvement on the present invention, according to a kind of water-heater Special scale remover with definite shape of above-mentioned prescription manufacturing.
As a further improvement on the present invention, described scale remover is right cylinder, and its diameter is in 3mm~20mm scope, and height is in 10mm~100mm scope.
As a further improvement on the present invention, described scale remover is rectangular parallelepiped, and its face diagonal is in 3mm~20mm scope, and height is in 10mm~100mm scope.
As a further improvement on the present invention, described scale remover is rule or irregular multiedge cylinder, and its longest face diagonal is in 3mm~20mm scope, and height is in 10mm~100mm scope.
Owing to having used above-mentioned prescription, water-heater Special scale remover of the present invention has metallic corrosion less, the advantage that the scale removal ability is stronger, in addition, the present invention can make certain shape with scale remover, the size of its size conforms water-heater sewage draining exit directly is added to scale remover in the water-heater by sewage draining exit.Overcome Powdered or the difficult reinforced problem of liquid, be easy to use quick, simple to operate.
Embodiment
The below specifies embodiments of the present invention:
A kind of water-heater Special scale remover is mixed by component A, B, C, D, wherein:
Component A is acids scale removal composition, be selected from citric acid, thionamic acid, oxysuccinic acid, tartrate, toxilic acid, ethylenediamine tetraacetic acid (EDTA), the trichoroacetic acid(TCA) one or both, preferred thionamic acid, its weight percent is 70%~95%, preferred 80%~90%, purity is 95-99.5%.
Component B is binding agent, is selected from macromolecular water-soluble gelatin powder, Starso, Xylo-Mucine, the cohesiveness polyvinyl alcohol one or both, preferred Starso, and its weight percent is 2%~8%, and is preferred 4%~6%, purity is 90%~99%.
Component C is metal ion chelation agent and solidifying agent, be selected from disodium EDTA (being EDETATE DISODIUM), the trisodium phosphate one or both, be preferably trisodium phosphate, its weight percent is 2%~20%, preferred 4%~10%, purity is 95%~99%.
Component D is inhibiter, is selected from urotropine, the Sodium dodecylbenzene sulfonate one or both, is preferably Sodium dodecylbenzene sulfonate, and its weight percent is 1%~5%, and is preferred 2%~4%,
Make a kind of water-heater Special scale remover with definite shape, the size of its scale remover is less than or equal to the size of water-heater sewage draining exit, the shape and size of scale remover are solidified used mould by it and are determined, ultimate range is in 3mm~20mm scope on the general closed planar, height is in 10mm~100mm scope, and such size can directly be added to scale remover in the water-heater by sewage draining exit easily, has overcome Powdered or the difficult reinforced problem of liquid, be easy to use quick, simple to operate.Such as, the shape of scale remover can be right cylinder or the regular or irregular multiedge cylinder of rectangular parallelepiped, and its diameter or the longest face diagonal are in 3mm~20mm scope, such as being 3mm, 5mm, 10mm, 15mm or 20mm; Height is in 10mm~100mm scope, such as 10mm, 20mm, 50mm, 70mm or 100mm.
Following examples are all take four kinds of components together 100g as example:
Embodiment 1: a kind of water-heater Special scale remover, formed by A, B, C, four kinds of components of D, and wherein component A is citric acid 90g, purity is 99.5%; B component is Starso 5g, and purity is 99%; Component C is trisodium phosphate 4g, and purity is 99%; Component D is Sodium dodecylbenzene sulfonate 1g.The scale remover that will have above-mentioned four kinds of components is made diameter 12mm, the right cylinder of high 60mm.This scale remover is carried out following test:
(1) descale effect is measured:
Take by weighing by the good scale remover 10g of above-mentioned formulation cured, put into the beaker that fills the 500ml clear water, right cylinder is disintegration immediately, take by weighing again the incrustation scale that 6g scrapes off from water heater liner, put into beaker, can see having a large amount of bubbles to emerge, reaction is violent, after at least 15 minutes, incrustation scale is thoroughly decomposed fully.The scale remover features high scale-removing effect of this prescription is described, disintegration rate is fast.
(2) corrosion rate is measured:
The mensuration of corrosive nature is that the standard according to the general water-base metal detergent of QB/T2117-95 detects, and its etching extent test result all satisfies standard-required, and is smaller to corrosion of metal, within the acceptable range.
For the ease of giving an example, the below enumerates extra embodiment with the form of form, wherein, component A is acids scale removal composition, A1---citric acid, A2---thionamic acid, A3---oxysuccinic acid, A4---tartrate, A5---toxilic acid, A6---ethylenediamine tetraacetic acid (EDTA), A7---trichoroacetic acid(TCA), its purity can be selected arbitrarily in 95%~99.5% scope, such as being 95%, 97%, 99% or 99.5%; Component B is binding agent, B1---macromolecular water-soluble gelatin powder, B2---Starso, B3---Xylo-Mucine, B4---cohesiveness polyvinyl alcohol, its purity can be selected arbitrarily in 90%~99% scope, such as being 90%, 93%, 97% or 99%; Component C is metal ion chelation agent and solidifying agent, C1---disodium EDTA (being EDETATE DISODIUM), C2---trisodium phosphate, its purity can be selected arbitrarily in 95%~99% scope, such as being 95%, 97% or 99%; Component D is inhibiter, D1---urotropine, D2---Sodium dodecylbenzene sulfonate.In order to simplify, following table is not listed the purity of component A, B, C, and its purity is as long as all can select arbitrarily in the scope of the present invention's regulation, and its effect all can reach experiment effect of the present invention.
Figure BDA00002190435300051
Scale remover by above-described embodiment is carried out descale effect test and corrosion rate mensuration, and its detection method is all identical with embodiment 1 with test result, gives unnecessary details no longer one by one at this.
Need to prove, the enforceable mode of the present invention that provides of limit not in above-described embodiment, for the present invention, the selection of component A, B, its concrete material of C, D and weight percent can be optional, as long as its scope is in the scope that the present invention provides, its effect that is combined into all can reach and realize purpose of the present invention.

Claims (9)

1. water-heater Special scale remover, it is characterized in that: mixed by component A, B, C, D, described component A is acids scale removal composition, and its weight percent is 70%~95%; Described component B is binding agent, and its weight percent is 2%~8%; Described component C is metal ion chelation agent and solidifying agent, and its weight percent is 2%~20%; Described component D is inhibiter, and its weight percent is 1%~5%.
2. a kind of water-heater Special scale remover according to claim 1, it is characterized in that: described component A is selected from one or both in citric acid, thionamic acid, oxysuccinic acid, tartrate, toxilic acid, ethylenediamine tetraacetic acid (EDTA), the trichoroacetic acid(TCA); Described component B is selected from one or both in macromolecular water-soluble gelatin powder, Starso, Xylo-Mucine, the cohesiveness polyvinyl alcohol; Component C is selected from one or both in disodium EDTA, the trisodium phosphate; Component D is selected from one or both in urotropine, the Sodium dodecylbenzene sulfonate.
3. a kind of water-heater Special scale remover according to claim 2, it is characterized in that: described component A is thionamic acid, and described component B is Starso, and described component C is trisodium phosphate, and described component D is Sodium dodecylbenzene sulfonate.
4. a kind of water-heater Special scale remover according to claim 1, it is characterized in that: the weight percent of described component A is 80%~90%; The weight percent of described component B is 4%~6%; The weight percent of described component C is 4%~10%; The weight percent of described component D is 2%~4%.
5. each described a kind of water-heater Special scale remover in 4 according to claim 1, it is characterized in that: the purity of component A is 95-99.5%; The purity of component B is 90%~99%; The purity of component C is 95%~99%.
6. according to a kind of water-heater Special scale remover with definite shape of the described prescription manufacturing of each claim in the claim 1 to 5.
7. a kind of water-heater Special scale remover with definite shape according to claim 6, it is characterized in that: described scale remover is right cylinder, and its diameter is in 3mm~20mm scope, and height is in 10mm~100mm scope.
8. a kind of water-heater Special scale remover with definite shape according to claim 6, it is characterized in that: described scale remover is rectangular parallelepiped, and its face diagonal is in 3mm~20mm scope, and height is in 10mm~100mm scope.
9. a kind of water-heater Special scale remover with definite shape according to claim 6, it is characterized in that: described scale remover is rule or irregular multiedge cylinder, its the longest face diagonal is in 3mm~20mm scope, and height is in 10mm~100mm scope.
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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103264609A (en) * 2013-05-09 2013-08-28 广州大学 Chemical composition and drawing method
CN103469236A (en) * 2013-09-22 2013-12-25 西北机器有限公司 Copper base material cleaning agent and preparation method thereof
CN103773639A (en) * 2014-01-23 2014-05-07 南通苏通分离工程科技有限公司 Equipment descaling agent and preparation method thereof
CN103773616A (en) * 2013-11-18 2014-05-07 蚌埠天光传感器有限公司 Dedicated antiscaling agent for plate developing machine and preparation method of antiscaling agent
CN104445646A (en) * 2014-11-25 2015-03-25 苏州佑君环境科技有限公司 Scale removal and prevention agent for boiler and preparation method of scale removal and prevention agent
CN104761065A (en) * 2015-04-24 2015-07-08 张萍 Descaling agent
CN104906961A (en) * 2015-06-05 2015-09-16 宁波市川宁环保科技有限公司 Novel reverse-osmosis scale inhibitor
CN105647696A (en) * 2016-02-27 2016-06-08 柳州市够旺贸易有限公司 Descaling method for water heating device
CN105695169A (en) * 2016-01-19 2016-06-22 马鞍山纽泽科技服务有限公司 Anti-scaling agent for water heater
CN105753181A (en) * 2016-02-27 2016-07-13 柳州市够旺贸易有限公司 Water-heating apparatus scale remover
CN106318664A (en) * 2016-07-25 2017-01-11 启东市林海制衣厂 Scale remover for gas water heater
CN107164104A (en) * 2017-05-25 2017-09-15 滕晓明 Universal efficient scale remover
CN108300605A (en) * 2018-02-07 2018-07-20 合肥嘉仕诚能源科技有限公司 A kind of heating boiler and pipeline scale remover
CN110093613A (en) * 2019-06-05 2019-08-06 福州大学 A kind of outdoor machine of air-conditioner cleaning anti-rust agent
CN110921853A (en) * 2019-11-12 2020-03-27 北京杰信越发制冷设备安装工程有限公司 Anticorrosive environment-friendly scale remover capable of rapidly removing scale and preparation method and application thereof
CN111849660A (en) * 2020-07-31 2020-10-30 中车青岛四方机车车辆股份有限公司 Descaling agent and application thereof
CN112980593A (en) * 2021-02-08 2021-06-18 辽宁大学 Active descaling powder
CN113005461A (en) * 2019-12-20 2021-06-22 齐鲁工业大学 Carbon steel descaling and cleaning corrosion inhibitor and cleaning agent

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CN101586058A (en) * 2009-04-16 2009-11-25 谢建武 Decontamination emulsion and production method thereof
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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103264609A (en) * 2013-05-09 2013-08-28 广州大学 Chemical composition and drawing method
CN103469236A (en) * 2013-09-22 2013-12-25 西北机器有限公司 Copper base material cleaning agent and preparation method thereof
CN103773616A (en) * 2013-11-18 2014-05-07 蚌埠天光传感器有限公司 Dedicated antiscaling agent for plate developing machine and preparation method of antiscaling agent
CN103773639A (en) * 2014-01-23 2014-05-07 南通苏通分离工程科技有限公司 Equipment descaling agent and preparation method thereof
CN104445646A (en) * 2014-11-25 2015-03-25 苏州佑君环境科技有限公司 Scale removal and prevention agent for boiler and preparation method of scale removal and prevention agent
CN104761065A (en) * 2015-04-24 2015-07-08 张萍 Descaling agent
CN104906961B (en) * 2015-06-05 2019-02-12 宁波市川宁环保科技有限公司 Reverse osmosis antisludging agent
CN104906961A (en) * 2015-06-05 2015-09-16 宁波市川宁环保科技有限公司 Novel reverse-osmosis scale inhibitor
CN105695169A (en) * 2016-01-19 2016-06-22 马鞍山纽泽科技服务有限公司 Anti-scaling agent for water heater
CN105647696A (en) * 2016-02-27 2016-06-08 柳州市够旺贸易有限公司 Descaling method for water heating device
CN105753181A (en) * 2016-02-27 2016-07-13 柳州市够旺贸易有限公司 Water-heating apparatus scale remover
CN106318664A (en) * 2016-07-25 2017-01-11 启东市林海制衣厂 Scale remover for gas water heater
CN107164104A (en) * 2017-05-25 2017-09-15 滕晓明 Universal efficient scale remover
CN108300605A (en) * 2018-02-07 2018-07-20 合肥嘉仕诚能源科技有限公司 A kind of heating boiler and pipeline scale remover
CN110093613A (en) * 2019-06-05 2019-08-06 福州大学 A kind of outdoor machine of air-conditioner cleaning anti-rust agent
CN110921853A (en) * 2019-11-12 2020-03-27 北京杰信越发制冷设备安装工程有限公司 Anticorrosive environment-friendly scale remover capable of rapidly removing scale and preparation method and application thereof
CN110921853B (en) * 2019-11-12 2022-05-27 北京杰信越发制冷设备安装工程有限公司 Anticorrosive environment-friendly scale remover capable of rapidly removing scale and preparation method and application thereof
CN113005461A (en) * 2019-12-20 2021-06-22 齐鲁工业大学 Carbon steel descaling and cleaning corrosion inhibitor and cleaning agent
CN111849660A (en) * 2020-07-31 2020-10-30 中车青岛四方机车车辆股份有限公司 Descaling agent and application thereof
CN112980593A (en) * 2021-02-08 2021-06-18 辽宁大学 Active descaling powder

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Patentee before: HKH NATIONAL ENGINEERING RESEARCH CENTER OF PLASTICS Co.,Ltd.

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Denomination of invention: A special scale remover for water heater

Effective date of registration: 20210528

Granted publication date: 20140709

Pledgee: Haidian Beijing science and technology enterprise financing Company limited by guarantee

Pledgor: China Science Pioneer Engineering Plastics National Engineering Research Center Co.,Ltd.

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Date of cancellation: 20230413

Granted publication date: 20140709

Pledgee: Haidian Beijing science and technology enterprise financing Company limited by guarantee

Pledgor: China Science Pioneer Engineering Plastics National Engineering Research Center Co.,Ltd.

Registration number: Y2021990000483

PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: A special scale remover for water heaters

Effective date of registration: 20230417

Granted publication date: 20140709

Pledgee: Haidian Beijing science and technology enterprise financing Company limited by guarantee

Pledgor: China Science Pioneer Engineering Plastics National Engineering Research Center Co.,Ltd.

Registration number: Y2023110000161