CN102589958A - Device for purifying ozone gas - Google Patents

Device for purifying ozone gas Download PDF

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Publication number
CN102589958A
CN102589958A CN2012100684740A CN201210068474A CN102589958A CN 102589958 A CN102589958 A CN 102589958A CN 2012100684740 A CN2012100684740 A CN 2012100684740A CN 201210068474 A CN201210068474 A CN 201210068474A CN 102589958 A CN102589958 A CN 102589958A
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CN
China
Prior art keywords
ozone
purification
reaction chamber
gas
reagent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012100684740A
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Chinese (zh)
Inventor
王春迎
崔延青
马越超
郑雷玉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HEBEI SAILHERO ENVIRONMENTAL PROTECTION HI-TECH Co Ltd
Original Assignee
HEBEI SAILHERO ENVIRONMENTAL PROTECTION HI-TECH Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by HEBEI SAILHERO ENVIRONMENTAL PROTECTION HI-TECH Co Ltd filed Critical HEBEI SAILHERO ENVIRONMENTAL PROTECTION HI-TECH Co Ltd
Priority to CN2012100684740A priority Critical patent/CN102589958A/en
Publication of CN102589958A publication Critical patent/CN102589958A/en
Pending legal-status Critical Current

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  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)

Abstract

A device for purifying ozone gas belongs to the technical field of atmospheric monitoring equipment, is used to purify ozone gas used in a nitrogen oxide automatic monitor, and adopts technical scheme as follows: the device is composed of a purification reaction chamber, ozone purification reagent and metal meshes, wherein the purification reaction chamber is a hollow chamber, the ozone purification reagent is placed in the chamber of the purification reaction chamber, two ends of the purification reaction chamber are provided with a gas inlet and a gas outlet for purified gas respectively, and the metal meshes are installed between the gas inlet and the ozone purification reagent and between the gas outlet and the ozone purification reagent. According to the invention, fine pored silica gel of the ozone purification reagent in the purification reaction chamber has a larger surface area and small holes, so as to absorb moisture, nitrate, sulfate aerosol and other components in purified ozone gas, further achieve the purpose of purifying ozone, and ensure accurate measurement of NO and NO2. The device disclosed by the invention has the advantages of simple structure, convenience for maintenance and the like, and is particularly suitable for matching with the nitrogen oxide automatic monitor for use.

Description

A kind of device of purification ozone gas
Technical field
The present invention relates to a kind of device of purification ozone gas, relate in particular to the purification plant of the employed ozone gas of oxides of nitrogen automonitor, belong to the atmospheric surveillance equipment technical field.
Background technology
Ozone is that pollutant chemistry is poisoned the main participator who develops and urged power in the air, is the main monitoring target of pollutant harm in the prediction air.Because the physics and the chemical property of ozone itself make ozone standard gas can not adopt the method for traditional gas standard material to prepare, store and transport.Prepare the method that ozone standard gas must adopt " promptly join promptly and use ", this has just increased the difficulty of ozone standard gas preparation and storage.
At present, the on-line monitoring appearance of chemoluminescence method is adopted in the oxides of nitrogen monitoring usually, needs to use excessive ozone (O 3) reacting with airborne nitrogen monoxide (NO) generates the nitrogen dioxide (NO of excited state 2*), the nitrogen dioxide (NO of excited state 2*) molecule is got back to low-energy state through ballistic phonon to discharge unnecessary energy, and its luminous intensity is directly proportional with the concentration of NO, through detecting the concentration that luminous intensity obtains NO.Wherein need adopt ozone generator to produce excessive O 3If but the air dried inadequate words that get into ozone generator, the O of generation 3Just impure, contain small gasoloid impurity such as a large amount of nitrate, sulfate, on the optical filter of reaction chamber, form one deck wax, seeing through of block light influences the accurate monitoring of NO, and serious words also can the corrosion reaction chamber and pipeline etc.Therefore, ozone gas is purified accuracy rate that just becomes raising NO and the requisite measure of protecting monitoring equipment.
Summary of the invention
Technical matters to be solved by this invention is the deficiency that overcomes prior art, and the device of the purification ozone gas of impurity such as a kind of nitrate that is used for purifying impure ozone, sulfate is provided.
The technical scheme that solves the problems of the technologies described above is:
A kind of device of purification ozone gas; It is formed by purifying reaction chamber, ozone purification reagent and wire netting; Purifying reaction chamber is the chamber of hollow; Ozone purification reagent is positioned in the chamber that purifies reaction chamber, and the two ends that purify reaction chamber have the air intake opening and the gas outlet of Purge gas respectively, between air intake opening and the ozone purification reagent, between gas outlet and the ozone purification reagent wire netting is housed respectively.
The device of above-mentioned purification ozone gas, said ozone purification reagent are the Kiselgel As of some.
The device of above-mentioned purification ozone gas, the aluminium that said purification reaction chamber is stainless steel or special processing etc. not with the material of ozone reaction.
Usefulness of the present invention is:
Ozone purification reagent Kiselgel A in the purification reaction chamber of the present invention has bigger surface area and aperture, can to reach the purpose of purification ozone, guarantee NO and NO to absorption such as the moisture in the ozone gas that is cleaned, nitrate, sulfate aerosol 2The accurate measurement of concentration is for the monitoring of environmental atmospheric condition provides reference.The present invention has advantages such as simple in structure, easy to maintenance, is specially adapted to the supporting use of oxides of nitrogen automonitor.
Description of drawings
Fig. 1 is an one-piece construction synoptic diagram of the present invention.
Mark is following among the figure: purify reaction chamber 1, ozone purification reagent 2, wire netting 3, air intake opening 4, gas outlet 5.
Embodiment
The present invention forms by purifying reaction chamber 1, ozone purification reagent 2 and wire netting 3.
Purifying reaction chamber 1 is the chamber of hollow; Ozone purification reagent 2 is positioned in the chamber that purifies reaction chamber 1; The two ends that purify reaction chamber 1 have the air intake opening 4 and gas outlet 5 of Purge gas respectively, between air intake opening 4 and the ozone purification reagent 2, between gas outlet 5 and the ozone purification reagent 2 wire netting 3 is housed respectively.
Show among the figure that the purification reaction chamber 1 of one embodiment of the present of invention is two cylinder shape structures, the upper end of two cylinders is respectively equipped with import and export 4 and gas outlet 5, and the lower end has communicating pipe to be connected.
Show among the figure; Being filled in the ozone purification reagent 2 that purifies in the reaction chamber 1 is Kiselgel As of some; Kiselgel A has bigger surface area and aperture, can be absorption such as the moisture in the ozone gas that is cleaned, nitrate, sulfate aerosol, to reach the purpose of purification ozone.
Show among the figure, the aluminium etc. that purifies reaction chamber 1 and be stainless steel or special processing not with the material of ozone reaction, can not produce other impurity, to guarantee the purity and the reliability of purification.
The present invention places between the ozone generator and reaction chamber of oxides of nitrogen automonitor in use, air intake opening 4, gas outlet 5 respectively with the oxides of nitrogen automonitor in ozone generator be connected with reaction chamber.Its course of work is following: air gets into ozone generator through exsiccator; In ozone generator, produce ozone through effluve; Ozone gets into reaction chamber through behind the present invention; In reaction chamber, carry out chemical reaction, the monitoring personnel are according to the concentration value of nitrogen monoxide, nitrogen dioxide and oxides of nitrogen in the chemiluminescence reaction principle monitoring atmosphere.

Claims (3)

1. the device of a purification ozone gas; It is characterized in that: it is formed by purifying reaction chamber (1), ozone purification reagent (2) and wire netting (3); Purifying reaction chamber (1) is the chamber of hollow; Ozone purification reagent (2) is positioned in the chamber that purifies reaction chamber (1); The two ends that purify reaction chamber (1) have air intake opening (4) and gas outlet (5) of Purge gas respectively, between air intake opening (4) and the ozone purification reagent (2), between gas outlet (5) and the ozone purification reagent (2) wire netting (3) is housed respectively.
2. the device of purification ozone gas according to claim 1 is characterized in that: said ozone purification reagent (2) is Kiselgel A.
3. the device of purification ozone gas according to claim 2 is characterized in that: said purification reaction chamber (1) for the aluminium of stainless steel or special processing etc. not with the material of ozone reaction.
CN2012100684740A 2011-12-08 2012-03-15 Device for purifying ozone gas Pending CN102589958A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012100684740A CN102589958A (en) 2011-12-08 2012-03-15 Device for purifying ozone gas

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN201110405937 2011-12-08
CN201110405937.3 2011-12-08
CN2012100684740A CN102589958A (en) 2011-12-08 2012-03-15 Device for purifying ozone gas

Publications (1)

Publication Number Publication Date
CN102589958A true CN102589958A (en) 2012-07-18

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CN (1) CN102589958A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104991028A (en) * 2015-07-31 2015-10-21 北京市药品检验所 Method for reducing content of nonvolatile buffer salts in LC-MS test substance

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2872397A (en) * 1955-01-10 1959-02-03 Union Carbide Corp Method and apparatus for producing ozone-carrier gas mixture
US3579305A (en) * 1968-07-25 1971-05-18 Beckman Instruments Inc Scrubber apparatus
US4046014A (en) * 1975-06-20 1977-09-06 Boehringer John R Sealable activated charcoal gas sampler
US4127386A (en) * 1977-01-26 1978-11-28 Meloy Laboratories, Inc. Process and system for measuring sulfur dioxide pollution
US4236895A (en) * 1979-06-11 1980-12-02 Meloy Laboratories, Inc. Analytical apparatus and method employing purified ozone
EP0042683A1 (en) * 1980-06-24 1981-12-30 National Research Development Corporation Process for the production of adsorptive gas traps
DE102004027354A1 (en) * 2004-06-01 2006-02-02 Siegfried Dr. Langhein Filter system for purifying air comprises a filter cassette containing a particle filter, a heat and ozone generator, a superoxidation unit, a fine filter, a nonwoven material and a sensor system
EP1726258A2 (en) * 2005-05-25 2006-11-29 Hitachi, Ltd. Exhaled-air filter, collecting apparatus, analyzing system and method
CN201187847Y (en) * 2008-06-27 2009-01-28 华东理工大学 Multifunctional combined type air purifier of environment preserving cultural relics in the collection of cultural institution
US20110123430A1 (en) * 2008-07-23 2011-05-26 Iwatani Corporation Method of concentrating ozone gas and apparatus therefor
JP2011121805A (en) * 2009-12-09 2011-06-23 Iwatani Internatl Corp Method for removing nitrogen oxide and moisture contained in ozone gas

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2872397A (en) * 1955-01-10 1959-02-03 Union Carbide Corp Method and apparatus for producing ozone-carrier gas mixture
US3579305A (en) * 1968-07-25 1971-05-18 Beckman Instruments Inc Scrubber apparatus
US4046014A (en) * 1975-06-20 1977-09-06 Boehringer John R Sealable activated charcoal gas sampler
US4127386A (en) * 1977-01-26 1978-11-28 Meloy Laboratories, Inc. Process and system for measuring sulfur dioxide pollution
US4236895A (en) * 1979-06-11 1980-12-02 Meloy Laboratories, Inc. Analytical apparatus and method employing purified ozone
EP0042683A1 (en) * 1980-06-24 1981-12-30 National Research Development Corporation Process for the production of adsorptive gas traps
DE102004027354A1 (en) * 2004-06-01 2006-02-02 Siegfried Dr. Langhein Filter system for purifying air comprises a filter cassette containing a particle filter, a heat and ozone generator, a superoxidation unit, a fine filter, a nonwoven material and a sensor system
EP1726258A2 (en) * 2005-05-25 2006-11-29 Hitachi, Ltd. Exhaled-air filter, collecting apparatus, analyzing system and method
CN201187847Y (en) * 2008-06-27 2009-01-28 华东理工大学 Multifunctional combined type air purifier of environment preserving cultural relics in the collection of cultural institution
US20110123430A1 (en) * 2008-07-23 2011-05-26 Iwatani Corporation Method of concentrating ozone gas and apparatus therefor
JP2011121805A (en) * 2009-12-09 2011-06-23 Iwatani Internatl Corp Method for removing nitrogen oxide and moisture contained in ozone gas

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104991028A (en) * 2015-07-31 2015-10-21 北京市药品检验所 Method for reducing content of nonvolatile buffer salts in LC-MS test substance
CN104991028B (en) * 2015-07-31 2017-10-31 北京市药品检验所 The reduction method of fixedness buffer salt content in LC MS testers

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Application publication date: 20120718