CN102094321A - Cotton cloth processing method adding water diffusion promotion function to cotton cloth - Google Patents
Cotton cloth processing method adding water diffusion promotion function to cotton cloth Download PDFInfo
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- CN102094321A CN102094321A CN2010105859460A CN201010585946A CN102094321A CN 102094321 A CN102094321 A CN 102094321A CN 2010105859460 A CN2010105859460 A CN 2010105859460A CN 201010585946 A CN201010585946 A CN 201010585946A CN 102094321 A CN102094321 A CN 102094321A
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- water diffusion
- water
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Links
- 229920000742 Cotton Polymers 0.000 title claims abstract description 155
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 125
- 238000009792 diffusion process Methods 0.000 title claims abstract description 95
- 238000003672 processing method Methods 0.000 title claims abstract description 23
- 239000004744 fabric Substances 0.000 title abstract description 21
- 150000001875 compounds Chemical class 0.000 claims abstract description 65
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 40
- 239000004094 surface-active agent Substances 0.000 claims abstract description 38
- 239000003960 organic solvent Substances 0.000 claims abstract description 15
- 239000006185 dispersion Substances 0.000 claims abstract description 8
- 238000004945 emulsification Methods 0.000 claims abstract description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 53
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 51
- 239000000203 mixture Substances 0.000 claims description 34
- -1 1-octyl group Chemical group 0.000 claims description 27
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000003623 enhancer Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 29
- 210000004243 sweat Anatomy 0.000 abstract description 6
- 238000001816 cooling Methods 0.000 abstract description 5
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 238000005063 solubilization Methods 0.000 abstract 1
- 230000007928 solubilization Effects 0.000 abstract 1
- 230000035900 sweating Effects 0.000 abstract 1
- 230000006870 function Effects 0.000 description 29
- 239000000835 fiber Substances 0.000 description 19
- 238000012360 testing method Methods 0.000 description 14
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- 238000004140 cleaning Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 7
- 239000002280 amphoteric surfactant Substances 0.000 description 6
- 239000003945 anionic surfactant Substances 0.000 description 6
- 125000002091 cationic group Chemical group 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 230000037303 wrinkles Effects 0.000 description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000009499 grossing Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000005702 oxyalkylene group Chemical group 0.000 description 3
- 125000006353 oxyethylene group Chemical group 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000005213 imbibition Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 230000010148 water-pollination Effects 0.000 description 2
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- SLCCHLCXVOABIB-UHFFFAOYSA-M 3-aminopropyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCN SLCCHLCXVOABIB-UHFFFAOYSA-M 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- GFMIDCCZJUXASS-UHFFFAOYSA-N hexane-1,1,6-triol Chemical compound OCCCCCC(O)O GFMIDCCZJUXASS-UHFFFAOYSA-N 0.000 description 1
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000009992 mercerising Methods 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
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- 150000003141 primary amines Chemical class 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
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- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
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- 239000012209 synthetic fiber Substances 0.000 description 1
- 150000003866 tertiary ammonium salts Chemical class 0.000 description 1
- 125000002769 thiazolinyl group Chemical group 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention relates to a cotton cloth processing method and a water diffusion promoter adding water diffusion promotion function to cotton cloth in a direct contact with skin, wherein the method is advantaged by improving moisture evaporation and dispersion performance, and improving an adhesive feeling caused by sweat or uncomfortable feelings such as a cooling feeling, etc. after sweating. The invention specifically relates to [1] a cotton cloth processing method of a compound (A) represented by the following general formula (1) being adhered to the cotton cloth in a direct contact with skin, thereby adding the water diffusion promotion function to the cotton cloth; [2] a water diffusion promoter containing the above compound (A) represented by the following general formula (1), a surfactant (B) capable of performing emulsification, dispersion, and solubilization of the compound (A) (however, the compound (A) is excluded) and/or an organic solvent (C); and [3] an application of the compound (A) represented by the following formula (1) and as a water diffusion promoter adding water diffusion promotion function to the cotton cloth in a direct contact with the skin. R1-O-[(C3H6O)m-(C2H4O)n]-H (1) [in the formula, R1 representing an alkyl group with 6-20 carbon atoms, m and n representing addition moles, m being 1-120, an ratio of [n/m] being 0/1-1/9].
Description
Technical field
The present invention relates to give the cotton processing method that the water diffusion promotes function to the cotton of direct and contact skin, and water diffusion promoter.
Background technology
Cotton, because it has the characteristic of fast Absorption moisture, be widely used in the clothings such as the underwear that directly contacts with skin or T-shirt, but owing to lack the moisture release function, so there be uncomfortable feeling and the long-time shortcoming that continues that produces the adhesion sense that causes by sweat or soak sense etc.
Therefore, all the time, the cool perceptual cloth of the cool perception when having proposed to improve clothing and wearing etc.
For example, known to hydrophobic fibre cloth that form, that regulated and control the average deviation of cloth surface roughness (with reference to patent documentation 1) such as hydrophilic fibres such as cotton, artificial fibre and polyester; The surface is made of hydrophobic fibre, and the dress material of the sandwich construction that the part in inner face and/or intermediate layer is made of cellulose multi-filament is with cloth (with reference to patent documentation 2); The porous matter inorganic powder grains of interior bag water absorbent polymer is fixed on fibre (with reference to patent documentation 3) that forms on the fibers such as natural fabrics such as cotton or synthetic fiber etc.
Yet, because these fibre treatment technique are to implement when the manufacturing of cloth or fibre, can not obtain, so can not be suitable for the general cotton clothing of wearing at ordinary times in the family by the back processing of cloth or fibre.
On the other hand, in patent documentation 4 (smoothing wrinkle composition) and patent documentation 5 (smoothing wrinkle deodorant compositions), the primary alconol that adds compound with molecule inner injection oxyethylene group and oxypropylene group, mean molecule quantity 100～300 in order to improve wrinkle improvement effect or secondary alcohol etc. have been put down in writing.Imagine these smoothing wrinkle compositions for the dry cleanings made from the wool quality such as western-style clothes that are difficult in the family wash, the wrinkle that will dress produces is in the using method of removing in general family after the dress.
Patent documentation 1: Japanese kokai publication hei 4-370251 communique
Patent documentation 2: Japanese kokai publication hei 10-25643 communique
Patent documentation 3: TOHKEMY 2002-235278 communique
Patent documentation 4: TOHKEMY 2006-104648 communique
Patent documentation 5: TOHKEMY 2007-239117 communique
Summary of the invention
Cotton is owing to water imbibition, hygroscopicity are good, comfortable and easy to wear and be suitable for as underwear material, but because cotton fiber has the characteristic that moisture is drawn onto fibrous inside, so cloth of making by cotton fiber, for example, exist a part to be uncomfortable sensations such as the high state of local moisture content, adhesion sense continue, deprive body temperature under cold environment problem in perspiration.
The present invention relates to a kind of original characteristic of cotton that makes full use of, and improve evapotranspiring property of moisture, can improve the adhesion sense that sweat etc. causes or perspire after uncomfortable sensations such as cooling sense, can spread the cotton processing method that promotes function to giving water with the cotton that skin directly contacts, and can be to giving the water diffusion promoter that the water diffusion promotes function with the cotton that skin directly contacts.
The present inventor finds, the compound by will having specific long chain hydrocarbon groups and specific oxyalkylene group attached to cotton that skin directly contacts on, the water diffusivity of raising cotton can solve above-mentioned problem.
That is, the present invention relates to following [1]～[3].
[1] a kind of cotton processing method, wherein, with the compound (A) shown in the following general formula (1) attached to cotton that skin directly contacts on, promote function thereby give this cotton water diffusion.
R
1-O-[(C
3H
6O)
m-(C
2H
4O)
n]-H (1)
[in the formula, R
1The alkyl of expression carbon number 6～20, m and n represent average addition molal quantity, and m is 1～20, and [n/m] is than being 0/1～1/9.]
[2] a kind of water diffusion promoter, wherein, contain the compound (A) shown in the above-mentioned general formula (1), and can be (still with compound (A) emulsification, dispersion or liquefiable surfactant (B), except this compound (A)) and/or organic solvent (C), can promote function to giving the water diffusion with the cotton that skin directly contacts.
[3] compound (A) shown in the following general formula (1) is as promoting the water of function to spread the application of promoter to giving the water diffusion with the cotton that skin directly contacts.
R
1-O-[(C
3H
6O)
m-(C
2H
4O)
n]-H (1)
[in the formula, R
1The alkyl of expression carbon number 6～20, m and n represent average addition molal quantity, and m is 1～20, and [n/m] is than being 0/1～1/9.]
The effect of invention
According to the present invention, a kind of original characteristic of cotton that makes full use of can be provided, and improve evapotranspiring property of moisture, can improve the adhesion sense that sweat etc. causes or perspire after uncomfortable sensations such as cooling sense, to giving the processing method that water diffusion promotes the cotton of function with the cotton that skin directly contacts, and can be to spreading promoter with water that the cotton that skin directly contact is given water diffusion promotion function.
The specific embodiment
＜give the cotton processing method that the water diffusion promotes function to cotton 〉
Of the present inventionly give water diffusion to cotton and promote the cotton processing method of function to be characterised in that, with the compound (A) shown in the above-mentioned general formula (1) attached to cotton that skin directly contacts on.
Here, " cotton " is meant with the general name of multiply (warp thread and weft yarn etc.) cotton thread as fibres such as the cloth of former line and fabrics, and cotton thread set such as is spun and forms through stranding by cotton fiber.In addition, cotton is not only cotton fiber, also can blending part chemical fibre, in order to embody effect of the present invention more, the blending ratio of preferred cotton fiber is more than the 50 quality %, more preferably more than the 80 quality %, most preferably is 100 quality %.
" cotton that directly contacts with skin " is meant and is used on skin the directly cotton of dress, and for example underwear (underpants), T-shirt, jeans etc. have towel or handkerchief etc. to be used for directly contacting employed cotton with skin in addition.
The meaning of " water diffusion " is that the water that contacts with cotton is mobile at a distance from contact portion within a certain period of time, looks it is the phenomenon that water spreads on the cotton surface.
The meaning of " water diffusion promote function " is, the performance that the water that contact with cotton can move within a certain period of time from contact portion, and the meaning of " giving of water diffusion promotion function " is to prolong the displacement of above-mentioned water.
Diffusion promotes the evaluation method of function as water, and it is easier to measure the Method for Area that water spreads in the certain hour on the cotton, particularly, and can be by the method evaluation of embodiment record.
In the present invention, though that above-claimed cpd (A) can be given the reason that water diffusion promotes function to cotton is also not clear and definite, can consider as follows.
Can think, in case cotton contacts with water, then glassware for drinking water has (i) to the soaking into of the cotton fiber inside that forms cotton, and (ii) between the slit between the cotton thread that constitutes cotton move and this two class that moves in slit between the cotton fiber that forms this cotton thread moves.
Here, can think that above-claimed cpd (A) the limit appropriateness in the water of the present invention diffusion promoter keeping the hydrophily on cotton fiber surface, the limit makes the inner all or part hydrophobization of cotton fiber, so suppressing water soaks into to the inside of cotton fiber, make water become easy the mobile of slit between the cotton thread and the slit between the cotton fiber, that is, make water on the cotton surface, be more prone to diffusion.Its result, compare with the cotton that does not have to handle, the cotton of handling with above-claimed cpd (A) evapotranspires moisture on bigger area, can not damage water imbibition that cotton had originally, hygroscopicity, characteristic such as comfortable and easy to wear and significantly improve the adhesion sense that causes by sweat or perspire after cooling sense etc.
The fabric integer that patent documentation 1～3 so existing method will form cloth becomes hydrophobicity or hydrophily, relative therewith, processing method of giving water diffusion promotion function of the present invention is to promote water to move in the lip-deep diffusion of cotton by making cotton fiber inside become hydrophobicity, is and the diverse brand-new idea of existing method.
[compound (A) that general formula (1) is represented]
Employed compound (A) is represented with following general formula (1) among the present invention.
R
1-O-[(C
3H
6O)
m-(C
2H
4O)
n]-H (1)
[in the formula, R
1The alkyl of expression carbon number 6～20, m and n represent average addition molal quantity, and m is 1～20, and [n/m] is than being 0/1～1/9.]
In general formula (1), as R
1The suitable example of alkyl, can enumerate various hexyls, various heptyl, various octyl groups, various nonyls, various decyls, various dodecyls, various myristyls, various cetyls, the alkyl of the straight or branched of carbon numbers such as various octadecyls 6～20.Wherein, from making the viewpoint of the inner appropriate hydrophobization of cotton fiber, as R
1Alkyl, be preferably carbon number 7～20, more preferably carbon number 8～18, more preferably carbon number 8～16, more preferably carbon number 8～14, more preferably carbon number 8～12, the alkyl of the straight or branched of carbon number 8～10 more preferably.
Average addition molal quantity m promotes functional point of view from giving the water diffusion, is preferably 1～18, more preferably 1～12, more preferably 2～10, more preferably 2～8, more preferably 2.5～8, more preferably 2.7～7.
In addition, [n/m] is preferably 0/1～1/15 than being 0/1～1/9, and more preferably 0/1～1/20.That is, in general formula (1), under the degree of not damaging the function of giving water diffusion promotion function, preferably contain small amounts ethene, and the content of propylene oxide is many.Most preferably be, n is 0.
In the compound (A) shown in the general formula (1), (C
3H
6O) and (C
2H
4O) combination is unqualified, can random addition also can the block addition, be preferably the block addition.
Compound (A) shown in the general formula (1) can be by having R with propylene oxide and/or ethylene oxide with the known method addition
1The alcohol of alkyl on and obtain.In addition, (the C of institute's addition
3H
6O) and (C
2H
4O) average addition molal quantity can be measured by known method such as NMR.
As preferred compound, can be set forth in R in the general formula (1)
1Be the straight chained alkyl of carbon number 8～10, m is 2～12, and particularly m is 2～7, and n is 0 compound, perhaps R
1Be the branched alkyl of carbon number 8～14, m is 1～12, and particularly m is 1～8, and n is 0 compound.Particularly preferred compound is, in general formula (1), and R
1Be the 1-octyl group, m is 2～7, and particularly m is 2.1～7, and n is 0 compound, perhaps R
1Be the 2-ethylhexyl, m is 2～5 compound.Most preferred is, in general formula (1), and R
1Be the 1-octyl group, m is 2.7～3, and n is 0 compound, perhaps R
1Be the 2-ethylhexyl, m is 2～2.7, and n is 0 compound.
[giving the processing method that the water diffusion promotes the cotton of function]
As giving the processing method that the water diffusion promotes the cotton of function, the method that preferably that the compound (A) shown in the above-mentioned general formula (1) is preceding with respect to dress cotton adheres to 0.1～50 quality %.
Here, the meaning of " dress before " is, from contain begin when the composition of detergent that cleans composition cleans to be about to dress preceding during.
The meaning of " dress " generally speaking is through on one's body behavior with clothes such as underwear, T-shirts, in this specification, in addition, also comprise for wipe in the back that washes one's face, after the balneation or when perspiring etc. attached to the moisture on the skin with the behavior of cotton such as towel, handkerchief and contact skin.
Particularly, preferably shown in following in arbitrary operation of operation 1～operation 5, with following (i), method (ii) etc. are handled cotton.
Operation 1 (matting): with the operation that contains the cotton after the cleaning fluid cleaning of cleaning composition is worn.
Operation 2 (rinsing process): after operation 1, reduce the operation of the amount of the cleaning solution that adheres on the cotton.
For example, in using the washing procedure of washing machine, after the above-mentioned matting, provide to cotton not contain the new water that cleans composition, the operation of the amount of the cleaning fluid that adheres on the minimizing cotton.Wherein, for the high efficiency rinsing, also be included in above-mentioned matting reduces the amount of the cleaning fluid that adheres on the cotton afterwards by centrifugally operated operation (dehydration procedure).
Operation 3 (dewatered operation from cotton): after above-mentioned operation 1 or the operation 2, reduce operation attached to the amount of the moisture on the cotton.
For example, reduce operation with washing machine by centrifugally operated etc. attached to the amount of the moisture on the cotton.
Operation 4 (drying process): after arbitrary operation of above-mentioned operation 1～operation 3, make the operation of cotton drying.
For example, make the operation of its air dry at ambient temperature, or make its dry operation by dryer etc.
Operation 5 (keeping operation): from preceding paragraph operation 4 after to being about to the preceding operation of dress.
For above-claimed cpd (A) is adsorbed on the cotton expeditiously, preferably in arbitrary operation of above-mentioned operation 2～operation 5, with above-claimed cpd (A) or the water diffusion promoter of containing above-claimed cpd (A) attached on the cotton.
(i) method that cotton (fibre) is handled in bath of liquid
When implementing the method in the family, following by using (a), method (b) etc.
(a) with washbowl etc., in water-bath, add above-claimed cpd (A) or contain after the water diffusion promoter of above-claimed cpd (A), cotton (fibre) is carried out the method for impregnation process, or in the water-bath that is impregnated with cotton (fibre), add above-claimed cpd (A) or contain the method for the water diffusion promoter of above-claimed cpd (A).
(b) in the water-bath of washing machine, add above-claimed cpd (A) or contain the water diffusion promoter of above-claimed cpd (A) and the method handled, the water diffusion promoter that maybe will contain above-claimed cpd (A) directly adds the method for in the water-bath of washing machine cotton (fibre) being carried out impregnation process.
When in bath of liquid, handling cotton (fibre), can carry out suitable stirring or married operation, so that above-claimed cpd (A) is equably attached on the cotton (fibre).The cotton (fibre) that is attached with the above-claimed cpd (A) of ormal weight uses after drying.
When using washing machine, use can be easier than method use amount, that be called water-saving drum-type washing machine of existing automatic washing machine minimizing water.When using washing machine, can in the rinsing process after cleaning with composition of detergent, use.
At this moment, from above-claimed cpd (A) expeditiously attached to the viewpoint on the cotton (fibre), bath raio (mass ratio of the quality/fibre of bath of liquid) is preferably 0.8～15, more preferably 1～13.
(ii) make it attached to the method on the cotton (fibre) with sprayer.
When implementing the method, can use commercially available spray bottle or trigger-type sprayer.The liquid that employed sprayer 1 time can spray in spraying be preferably 0.1～3.0g, more preferably 0.2～3.0g, more preferably 0.3～2.0g's is more suitable.As trigger-type sprayer,, open that disclosed pressure accumulation type is relatively to be fit in the flat 4-37554 communique in that Japan is real from the inhomogeneity viewpoint of spraying.
According to above-mentioned (i), method (ii) etc. is handled, make above-claimed cpd (A) adhere to 0.1～50 quality %, preferably make it adhere to 0.6～40 quality %, more preferably make it adhere to 1～30 quality % and relatively be fit in the per unit mass of cotton (fibre).
＜can give the water diffusion promoter that the water diffusion promotes function to cotton 〉
Above-claimed cpd (A) has himself be difficult to emulsification, dispersion or liquefiable character in water.In order to improve the action effect of above-claimed cpd (A), preferred uniform treatment compound (A) on cotton.For this reason, in water diffusion promoter, preferred also using can be with compound (A) emulsification, dispersion or liquefiable surfactant (B) and/or organic solvent (C).
Promptly, of the present invention can being characterised in that giving the water diffusion promoter that water diffusion promotes function with the cotton that skin directly contacts contained the compound (A) shown in the above-mentioned general formula (1) and can be with compound (A) emulsification, dispersion or liquefiable surfactant (B) and/or organic solvent (C).
Here, the meaning that " can give the water diffusion promoter that the water diffusion promotes function to cotton " is, in " the water diffusion promotes the evaluation of function " of embodiment record, if when not using the water diffusion area of the cotton of compound (A) processing to be 100 (with reference to comparative examples 11 described later), the relative value that can make diffusion area is the diffusion of the water more than 105 promoter.The relative value of preferred diffusion area is more than 110, more preferably more than 115, most preferably is more than 120.
＜surfactant (B) 〉
Surfactant (B) for example can be in " surfactant is crossed the threshold " (Sanyo Chemical Industries, Ltd.'s distribution, the 1st printing: select in the classes of compounds of being put down in writing on June 11st, 2007).But, except with the identical compound of compound (A).
Surfactant (B) is to be selected from anionic surfactant, cationic surface active agent, amphoteric surfactant and the nonionic surface active agent except that compound (A) more than one.Preferred cationic type surfactant, the nonionic surface active agent except that compound (A), the more preferably nonionic surface active agent except that compound (A).
(anionic surfactant)
As anionic surfactant, can enumerate (i) alkylbenzenesulfonate, (ii) alkyl sulfate salt, (iii) polyoxyalkylenes alkyl ether sulphate salts, (iv) alpha-alkene sulfonate, (v) alpha-sulfo-fatty acid alkyl ester salt, (vi) soap etc.
Wherein, in the record, used " alkyl " this term above, but this " alkyl " is to use for simplicity, not only refers to alkyl, also has the meaning of " alkyl " of broad sense.Its carbon number is preferably 8～18, and more preferably 10～16.Following (i)～(also be same in the explanation of anionic surfactant vi).
(i) as alkylbenzenesulfonate, the average carbon atom number that can be set forth on the detergent use surfactant market alkyl chain of general circulation is 8～16 a alkylbenzenesulfonate etc., more preferably has carbon number 10～14, particularly has an alkylbenzenesulfonate of the alkyl of carbon number 12.For example, can enumerate the trade name of Kao Corp's system: NEOPELEX F25, the trade name of Shell Co. Ltd's system: Dobs102 etc.
(ii), preferably has the sulfuric acid of the alkyl of carbon number 10～16, preferred carbon number 10～14, preferred especially carbon number 12 as alkyl sulfate salt.
(iii) as the polyoxyalkylene alkyl sulfuric acid, be preferably alkyl and contain average 0.5～10 mole sulfuric acid of oxyethylene group at molecule with carbon number 10～18.The average carbon atom number of preferred alkyl is 10～16, and more preferably carbon number is 10～14, and preferred especially carbon number is 12, and preferred molecule contains average 0.5～6 mole of oxyethylene group.
(iv) alpha-alkene sulfonate can be by with the SO3 sulfonation of the alpha-olefin of carbon number 8～18, then hydration/neutralization and obtaining.As alpha-alkene sulfonate, be preferably compound that has hydroxyl in the alkyl and the mixture that has the compound of unsaturated bond.
(v) as alpha-sulfo-fatty acid lower alkyl esters salt, the carbon number that is preferably alkyl is 10～16, more preferably its methyl esters or ethyl ester.
(vi) as soap, preferred carbon number is 12～16 soap, as salt, can enumerate alkali metal salt, alkali salt, pure amine salt, ammonium salt etc.Wherein, particular certain cancers, sylvite, magnesium salts, calcium salt, pure amine salt, ammonium salt.
In the above-mentioned anionic surfactant, from the dissolving or the viewpoint of disperseing above-claimed cpd (A), more preferably (i) alkylbenzenesulfonate, (ii) alkyl sulfate salt, (iii) polyoxyalkylenes alkyl ether sulphate salts and (vi) soap.
(cationic surface active agent)
As cationic surface active agent, can enumerate primary amine～tertiary ammonium salt type surfactant, quaternary ammonium salt cationic surfactant.
More specifically, can be set forth in the cationic surface active agent etc. that molecule contains the alkyl of 1～3 carbon number 10～20 that can be separated by ester group or amide groups.Wherein, be preferably quaternary ammonium salt or the amine salt that contains the alkyl such as alkyl of 1～2 carbon number 10～18 at molecule.As the counter ion of quaternary ammonium salt, the alkylsurfuric acid ion of preferred halogen ion, carbon number 1～2, more preferably chlorion, methyl sulfate ion, ethyl sulfate ion.Amine salt can obtain this amines with inorganic acid or organic acid neutralization.
(amphoteric surfactant)
As amphoteric surfactant, preferred amino acid type amphoteric surfactant, have the alkyl betaine-type or the sulfobetaines type amphoteric surfactant of alkyl of the alkyl etc. of carbon number 10～18.
(nonionic surface active agent)
As nonionic surface active agent, can enumerate alkyl such as alkyl, the nonionic surface active agent except that compound (A) with carbon number 8～20.
As the suitable example of nonionic surface active agent, can enumerate polyoxyethylene alkyl ether, polyoxyethylene fatty acid ester, polyoxyalkylene alkylamine, polyoxyethylene sorbitan fatty acid ester etc.Wherein, more preferably following polyoxyethylene alkyl ether, promptly, this polyoxyethylene alkyl ether has the alkyl of 1 carbon number 8～14, preferred carbon number 10～14, preferred especially carbon number 12 in molecule, contain average 10～60 moles, preferred 12～30 moles carbon number 6～20, the polyoxyethylene thiazolinyl of preferred carbon number 8～12 at molecule.
[organic solvent (C)]
As organic solvent (C), mean meltage for 100g water, be water-miscible organic solvent more than the 50g at 25 ℃, this meltage is preferably more than the 60g, and saturated vapor pressure (20 ℃) is preferably 0.001～1kPa.
As the object lesson of water-miscible organic solvent, can enumerate preferred carbon number 1～8 such as methyl alcohol, ethanol, propyl alcohol, butanols, hexanol, more preferably carbon number 2～6 unary alcohols; Ethylene glycol, propylene glycol, diethylene glycol (DEG), dipropylene glycol, triethylene glycol, tripropylene glycol, tetraethylene glycol, 1,2-hexylene glycol, 1,6-hexylene glycol, 1,2, preferred carbon number 2～10 such as 6-hexanetriol, glycerine, trimethylolpropane, the more preferably polyalcohols etc. of carbon number 2～6.
Wherein, from the viewpoint that makes above-claimed cpd (A) dissolving or disperse, be preferably the monobasic～tetrahydroxylic alcohol of carbon number 2～5, more preferably the monohydric alcohol of carbon numbers 2～4 such as ethanol, isopropyl alcohol, butanols, from the smell aspect, special preferred alcohol, isopropyl alcohol.
[mixed proportion of each composition]
Water of the present invention diffusion promoter, be contain above-claimed cpd (A), surfactant (B) and/or organic solvent (C), can give the composition that the water diffusion promotes function to cotton.
The content of compound (A) promotes functional point of view from the water diffusion, is preferably 0.1～40 quality % in water diffusion enhancer compositions, and more preferably 0.2～20 quality % is preferably 0.5～15 quality % especially.
The content of surfactant (B) and/or organic solvent (C) is given water diffusion promotion functional effect so long as have to cotton, and compound (A) emulsification in water diffusion promoter, dispersion or liquefiable amount can be got final product.Usually, the content of surfactant (B) is preferably 0.01～25 quality %, more preferably 0.02～10 quality %, more preferably 0.03～5 quality %, more preferably 0.04～0.2 quality %.
The content of organic solvent (C) is preferably 0.1～70 quality %, more preferably 1～60 quality %, more preferably 1～40 quality %.
Surfactant (B), from the action effect that improves compound (A), with the viewpoint of compound (A) uniform treatment on cotton shown in the above-mentioned general formula (1), the mass ratio [compound (A)/surfactant (B)] of compound (A) and surfactant (B) is preferably more than 1, smaller or equal to 100, more preferably 1.1～90, more preferably 5～80, more preferably 10～50.
In water of the present invention diffusion promoter, preferably contain the decentralized medium of water as above-claimed cpd (A) and dispersant (B), this moment, the pH of composition was preferably 2～8, and more preferably 3～8, more preferably 4～7.5.
[embodiment]
In following example, " % " is " quality % " when not having signalment.In addition, the pressure during mensuration is 101kPa (atmospheric pressure).
As shown in table 1, (A) composition of having prepared to use in embodiment and the comparative example and (A ') composition [(A) comparative compound of composition].
Table 1
*1: with the suitable compound of general formula (1) of record in the claim 1 of TOHKEMY 2006-104648 communique, perhaps
The suitable compound of general formula (b1) with the record of the claim 2 of TOHKEMY 2007-239117 communique.
Particularly, the addition propylene oxide is 12.2 moles on the 1-palmityl alcohol,
The compound of following 3.6 moles of addition ethylene oxides and obtaining.
*2:Softanol 50 (Nippon Shokubai Co., Ltd's system)
*3:Softanol 70 (Nippon Shokubai Co., Ltd's system)
*4:Softanol 90 (Nippon Shokubai Co., Ltd's system)
In addition, as (B) composition, prepared following medicine.
(b-1): lauryl sodium sulfate (anionic surfactant)
(b-2): N-dodecane acyl group aminopropyl-N, N, N-trimethyl ammonium chloride (cationic surface active agent)
(b-3): N-lauryl-N, N-dimethyl-N-(2-hydroxyl sulfo group propyl group) betaine ammonium (amphoteric surfactant)
(b-4): the average 6 moles oxyalkylene group of addition on laruyl alcohol and the nonionic surface active agent that obtains.
(b-5): the average 20 moles oxyalkylene group of addition on laruyl alcohol and the nonionic surface active agent that obtains.
In addition, as (C) composition, prepared following medicine.
(c-1): ethanol
(c-2): the 2-propyl alcohol
Embodiment 1～35, and comparative example 1～15 (preparation of water diffusion promoter)
In the sample bottle (sale of AS ONE Co., Ltd.) of the PYREX of the volume 250mL that can seal (registration mark), each composition shown in mixture table 2 or the table 3, add 1 powerful stirrer (cylindric, diameter 8mm * long 25mm) and airtight, the quality that makes final product is 200g.
Above-mentioned sample bottle is put into the water-bath of temperature adjustment to 50 ℃, placed 20 minutes.Then, adjust the warm water amount in the water-bath, make the liquid level of the interior composition of liquid level and sample bottle consistent, under 300rpm, stirred 30 minutes with magnetic stir bar.Afterwards, put into the water-bath of temperature adjustment to 20 ℃, stirred again 30 minutes, obtain water diffusion promoter.
Prepare the cotton test film with following method, resulting water diffusion promoter is estimated.The result represents in table 2～table 4.
＜utilize the preparation of the test film that cotton handles 〉
As underwear etc. directly and the cotton of contact skin, with cotton knitted cloth (Co., Ltd.'s valley head shop system, dyeing examination material, mercerising is handled knitted cotton) 2kg with commercially available clothing with washing agent (Kao Corp's system, Attack particulate) with washing machine cleaning (Panasonic system, automatic washing machine NA-F702P, washing agent 34.3g makes water consumption set 47L (20 ℃ of water temperatures), washes 9 minutes, rinsing 2 times was dewatered 3 minutes).After this cleaning operation repeated 5 times, at 25 ℃, the environment of 40%RH was placed down and was made its drying in 24 hours.This cotton is cut into test film and the weighing (quality (W of 5cm * 5cm (area (V))
1), put into the glass dish of diameter 8cm, for this test film, it is immersed in contain in the composition of the table 2 of (A) composition or table 3 record, to reach the adhesion amount of ormal weight.Bath raio (quality of the quality/composition of cotton) is 5, and whole amounts of composition are attached on the cotton.Directly under 25 ℃, the environment of 40%RH, place and made its drying in 24 hours, prepared the cotton test film.
The adhesion amount of (A) composition is calculated by following formula on the cotton.
Adhesion amount (quality the %)=[(W of (A) composition on the test film
2)-(W
1)] * (X)/(W
1)
W
1(g): the quality of the test film before handling
W
2(g): the quality of the test film that in table 2 or table 3, floods in the composition of record
X (quality %): the content of (A) composition in the composition of record in table 2 or the table 3
The diffusion of＜water promotes the evaluation of function 〉
To eat blue No. 1 aqueous solution (0.001 quality %, water uses deionized water) 0.1mL with the liquid-transfering gun P-1000 of the Gilson company system of producing and drip to central authorities' (diameter 5 ± 1mm) of the glass dish of diameter 8cm.So that the mode that the photo tint solution on the plate contacts with the middle body of test film is placed the cotton test film of above-mentioned preparation, placed 24 hours.With the test film after placing, calculate the diffusion area of the water of coloured part according to following formula.
Diffusion area (cm
2)=(V) * (W)/(Z)
V: the area (25cm that test film is all
2)
W: all quality (g) of test film that obtain in above-mentioned " utilizing the preparation of the test film of cotton processing "
Z: the quality (g) of the coloured part that cuts from experiment slice
If the diffusion area of the water of the cotton underwear of handling with water of the present invention diffusion promoter is not 100 (comparative examples 11), calculate relative value.
If the relative value of diffusion area more than 105, just can real experiences promote function to water diffusion of the present invention.
From table 2～table 4 as can be known, compare with the water diffusion promoter of comparative example, the water diffusion facilitation effect of the water diffusion promoter of embodiment is superior.In addition, at the compound (1 '-5) of table 1 record (comparative compound of (A) composition (A ') composition) be the compound of record in patent documentation 4 and 5, but be to use the comparative example 5 (table 2) of these compounds and comparative example 12 (table 3) not to play effect of the present invention.
Utilizable energy on the industry
According to cotton processing method of the present invention, can take full advantage of the original characteristic of cotton, and improve the evapotranspiring property of moisture, improve the adhesion sense that sweat etc. causes or perspire after uncomfortable sensations such as cooling sense. In addition, water diffusion promoter of the present invention can be suitable as giving the domestic water diffusion promoter use that water spreads promotion functions with the cotton that skin directly contacts.
Claims (21)
1. give the cotton processing method that water diffusion promotes function to cotton for one kind, it is characterized in that:
With the compound (A) shown in the following general formula (1) attached to cotton that skin directly contacts on,
R
1-O-[(C
3H
6O)
m-(C
2H
4O)
n]-H (1)
In the formula, R
1The alkyl of expression carbon number 6～20, m and n represent average addition molal quantity, and m is 1～20, and [n/m] is than being 0/1～1/9.
2. as claimed in claim 1ly give the cotton processing method that water diffusion promotes function, it is characterized in that cotton:
In general formula (1), R
1It is the alkyl of carbon number 7～20.
3. as claimed in claim 1 or 2ly give the cotton processing method that water diffusion promotes function, it is characterized in that cotton:
In general formula (1), n is 0.
4. as claimed in claim 1ly give the cotton processing method that water diffusion promotes function, it is characterized in that cotton:
In general formula (1), R
1Be the straight chained alkyl of carbon number 8～10, m is 2～7, and n is 0.
5. as claimed in claim 4ly give the cotton processing method that water diffusion promotes function, it is characterized in that cotton:
In general formula (1), R
1Be the 1-octyl group, m is 2.7～3, and n is 0.
6. as claimed in claim 1ly give the cotton processing method that water diffusion promotes function, it is characterized in that cotton:
In general formula (1), R
1Be the branched alkyl of carbon number 8～14, m is 1～8, and n is 0.
7. as claimed in claim 6ly give the cotton processing method that water diffusion promotes function, it is characterized in that cotton:
In general formula (1), R
1Be the 2-ethylhexyl, m is 2～2.7, and n is 0.
8. as claimed in claim 1 or 2ly give the cotton processing method that water diffusion promotes function, it is characterized in that cotton:
Cotton is the preceding cotton of dress.
9. as claimed in claim 1 or 2ly give the cotton processing method that water diffusion promotes function, it is characterized in that cotton:
With the compound (A) shown in the general formula (1) with 0.1～50 quality % attached on the cotton.
10. a water spreads promoter, it is characterized in that:
Contain the compound (A) shown in the following general formula (1) and compound (A) emulsification, dispersion or liquefiable surfactant (B) and/or organic solvent (C) can be promoted function to giving the water diffusion with the cotton that skin directly contacts,
R
1-O-[(C
3H
6O)
m-(C
2H
4O)
n]-H (1)
In the formula, R
1The alkyl of expression carbon number 6～20, m and n represent average addition molal quantity, and m is 1～20, and [n/m] is than being 0/1～1/9.
11. water diffusion promoter as claimed in claim 10 is characterized in that:
Compound (A) shown in the general formula (1) is R
1For alkyl, the m of carbon number 8～10 is 2～8, n is 0 compound, surfactant (B) is the nonionic surface active agent with alkyl of carbon number 8～20, and organic solvent (C) is the monohydric alcohol of carbon number 2～6.
12. water diffusion promoter as claimed in claim 10 is characterized in that:
In water diffusion enhancer compositions, the content of the compound (A) shown in the general formula (1) is 0.1～40 quality %, and the content of surfactant (B) is 0.01～25 quality %, and the content of organic solvent (C) is 0.1～70 quality %.
13. water diffusion promoter as claimed in claim 10 is characterized in that:
In water diffusion enhancer compositions, the content of the compound (A) shown in the general formula (1) is 0.5～15 quality %, and the content of surfactant (B) is 0.03～5 quality %, and the content of organic solvent (C) is 1～40 quality %.
14. water diffusion promoter as claimed in claim 10 is characterized in that:
The mass ratio [compound (A)/surfactant (B)] of the compound (A) shown in the general formula (1) and surfactant (B) is greater than 1, smaller or equal to 100.
15. the compound (A) shown in the following general formula (1) is as to giving the application that the water of water diffusion function spreads promoter with the cotton that skin directly contacts,
R
1-O-[(C
3H
6O)
m-(C
2H
4O)
n]-H (1)
In the formula, R
1The alkyl of expression carbon number 6～20, m and n represent average addition molal quantity, and m is 1～20, and [n/m] is than being 0/1～1/9.
16. conduct as claimed in claim 15 promotes the water of function to spread the application of promoter to giving the water diffusion with the cotton that skin directly contacts, and it is characterized in that:
In general formula (1), n is 0.
17. conduct as claimed in claim 15 promotes the water of function to spread the application of promoter to giving the water diffusion with the cotton that skin directly contacts, and it is characterized in that:
In general formula (1), R
1Be the straight chained alkyl of carbon number 8～10, m is 2～7, and n is 0.
18. conduct as claimed in claim 15 promotes the water of function to spread the application of promoter to giving the water diffusion with the cotton that skin directly contacts, and it is characterized in that:
In general formula (1), R
1Be the 1-octyl group, m is 2.7～3, and n is 0.
19. conduct as claimed in claim 15 promotes the water of function to spread the application of promoter to giving the water diffusion with the cotton that skin directly contacts, and it is characterized in that:
In general formula (1), R
1Be the branched alkyl of carbon number 8～14, m is 1～8, and n is 0.
20. conduct as claimed in claim 15 promotes the water of function to spread the application of promoter to giving the water diffusion with the cotton that skin directly contacts, and it is characterized in that:
In general formula (1), R
1Be the 2-ethylhexyl, m is 2～2.7, and n is 0.
21. conduct as claimed in claim 15 promotes the water of function to spread the application of promoter to giving the water diffusion with the cotton that skin directly contacts, and it is characterized in that:
Cotton is the preceding cotton of dress.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009-278704 | 2009-12-08 | ||
| JP2009278704 | 2009-12-08 |
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| Publication Number | Publication Date |
|---|---|
| CN102094321A true CN102094321A (en) | 2011-06-15 |
| CN102094321B CN102094321B (en) | 2015-04-01 |
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| CN201010585946.0A Expired - Fee Related CN102094321B (en) | 2009-12-08 | 2010-12-08 | Cotton cloth processing method adding water diffusion promotion function to cotton cloth |
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| JP (1) | JP5685067B2 (en) |
| CN (1) | CN102094321B (en) |
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| CN111279031B (en) * | 2017-10-30 | 2023-08-01 | 海科材料有限公司 | Functional temperature regulating textile additive and use thereof |
| JP7208784B2 (en) * | 2017-12-27 | 2023-01-19 | 花王株式会社 | Method for producing micronized hydrophobically modified cellulose fiber |
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| JP5231888B2 (en) * | 2008-07-25 | 2013-07-10 | 松本油脂製薬株式会社 | Water permeability imparting agent, water permeable fiber to which it is attached, and method for producing nonwoven fabric |
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- 2010-12-08 CN CN201010585946.0A patent/CN102094321B/en not_active Expired - Fee Related
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| US3203955A (en) * | 1962-10-09 | 1965-08-31 | Wyandotte Chemicals Corp | Surface active mixtures of polyoxyalkylene compounds having a single heteric polyoxypropylene-polyoxyethylene chain |
| US3340309A (en) * | 1965-06-28 | 1967-09-05 | Wyandotte Chemicals Corp | Biodegradable, liquid, water-miscible alkylene oxide condensation products |
| US3504041A (en) * | 1966-02-14 | 1970-03-31 | Wyandotte Chemicals Corp | Nonionic condensation products having enhanced activity |
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| CN1109930A (en) * | 1994-01-26 | 1995-10-11 | 花王株式会社 | Oil composition used in fibre |
| US5705476A (en) * | 1994-05-09 | 1998-01-06 | Bayer Aktiengesellschaft | Low-foaming wetting agent consisting of various alkoxylated alcohol mixtures |
| CN1214724A (en) * | 1996-12-02 | 1999-04-21 | 花王株式会社 | Surfactant composition |
| JP2004270076A (en) * | 2003-03-10 | 2004-09-30 | Sanyo Chem Ind Ltd | Disperser for papermaking |
| CN1950141A (en) * | 2004-04-30 | 2007-04-18 | 巴斯福股份公司 | Rapid low-foam wetting agents for hydrophobic surfaces |
| JP2007056421A (en) * | 2005-08-26 | 2007-03-08 | Wakayama Prefecture | Spray product for sweat treatment, and sweat treatment method |
| JP2007239122A (en) * | 2006-03-07 | 2007-09-20 | Kao Corp | Wrinkle-removing, deodorizing agent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2011140739A (en) | 2011-07-21 |
| JP5685067B2 (en) | 2015-03-18 |
| CN102094321B (en) | 2015-04-01 |
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