CN101591491B - Full water-borne granite multicolor paint and preparation method thereof - Google Patents
Full water-borne granite multicolor paint and preparation method thereof Download PDFInfo
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- CN101591491B CN101591491B CN2008100380594A CN200810038059A CN101591491B CN 101591491 B CN101591491 B CN 101591491B CN 2008100380594 A CN2008100380594 A CN 2008100380594A CN 200810038059 A CN200810038059 A CN 200810038059A CN 101591491 B CN101591491 B CN 101591491B
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Abstract
The invention provides a full water-borne granite multicolor painting comprising base paint, colloid and synthesized emulsion, wherein the weight ratio of the three components is 30-40:30-40:20-40. The full water-borne granite multicolor painting is a full water-borne product, has low Voc, is environmental-friendly and solvent-free and is an ideal substitute for marble, granite and the like; the properties of the full water-borne granite multicolor painting can satisfy the GB/T9755-2001 synthetic resin exterior wall painting material standard; and the full water-borne granite multicolor painting has good elasticity and can cover small cracks of a wall body.
Description
Technical field
The present invention relates to a kind of inner, external wall coating, specifically, relate to a kind of fully water based granite multicolor paint and preparation method thereof.
Background technology
Coating is a kind of finishing material, comprise a variety of, as interior outer wall building coating, topcoat material, anticorrosion of steel structure material, water-borne wood coating, UV solidify and other functional coatings etc.Trade sales coating is government's new industry of putting forth effort to help in recent years, also is development in recent years industry rapidly.But traditional trade sales coating is main with aqueous latex paint, solvent-borne type synthetic resin coating mainly at present; Product sense organ effect is single, and color is main with single real look, and the decorative effect of product is not good.The raising that Along with people's requires decorative effect adopts a large amount of granite building materials or glass curtain wall as finishing material now on the market, increased dependence and consumption to natural resources greatly; This material own wt is heavier simultaneously, and also there is bigger hidden danger in exterior wall safety.The raising that requires along with energy-saving and environmental protection and to the lifting of wall body decoration effect requirements, the multicolor finish market requirement with grouan texture is very big.
The granite multicolor paint that exterior wall in being applied to is also arranged in the market, but its product all is solvent type, or oil-in-water-type, contain a large amount of organic solvents in the product, have greater environmental impacts in the use.Stability, the durability of products of product look grain are also relatively poor simultaneously.
The production of full-aqueous multicolour paint is also arranged on the existing market, but because its production process is complicated, and technique controlling difficulty is very big, the long and not enough causes for stable of product look grain of production cycle do not have real form commercialization and industrialization.
Summary of the invention
The objective of the invention is to the deficiency to prior art, a kind of fully water based granite multicolor paint is provided, its controllability is strong, and the big I of product look grain is arbitrarily controlled, and look grain stability is high.
Another object of the present invention is to provide a kind of preparation method of fully water based granite multicolor paint, its production technique is simple, controllability is strong.
In order to realize the object of the invention, a kind of fully water based granite multicolor paint of the present invention comprises base paint, colloid and synthetic emulsion, between weight ratio be: 30～40: 30～40: 20～40; The component and the weight part of said base paint are following:
40～50 parts of anionic emulsions,
1～3 part in hydrophilic protection glue,
0.1～0.5 part of wetting agent,
0.1～0.5 part of dispersion agent,
0.1～0.5 part of skimmer,
0.1～0.5 part in sterilant,
10～15 parts of pigment,
20～30 parts in water,
1～2 part of film coalescence aid,
0.1～0.5 part of thickening material.
Weight part according to the invention is this area weight unit commonly used, like gram, kilogram, two, ton etc.As follows.
Said base paint mainly provides the particle of producing color, and this particle is changeable, requires quite stable, can not be dissolved in the colloid,
Said anionic emulsion can be selected one or more mixtures of phenylpropyl alcohol, pure third, elasticity or modification organosilicon crylic acid latex for use.
Said wetting ability protection glue is selected from a kind of of Z 150PH, methyl or TKK 021 or its mixture.
Said wetting agent is selected nonionic block polyether type tensio-active agent for use, and such as block polyoxyethylene polyoxypropylene ether (X-405), it all has good wetting effect to all pigment.
Said dispersion agent is selected the non-ionics class for use, and such as nonionic polyurethane dispersion agent (TCP-8030N), it has good divergent function to the pigment class white titanium pigment.
It is major ingredient that said skimmer can be selected hydrophobically modified silicon-dioxide and MO for use, and such as skimmer RF-202, defoaming effect is obvious, has no side effect.
Pigment can select for use proportion little, and the filler that contains the small-amount free metals ion is as weighting material, and it can obviously improve particulate fullness ratio and stability.Color can be selected monochrome or secondary color for use, generally being advisable with the mineral dye preparation.Be preferably white titanium pigment.
Said sterilant can be selected the benzisothiazole ketone for use, such as 2-benzisothiazole-3-ketone (BIT), good broad spectrum is arranged.
Said film coalescence aid is an alkoxide, such as HY-1800, good film-formation result is arranged.
Said thickening material is an alkali swelling associative thickener, such as TT-615.
Said colloidal major function is that base paint is wrapped up by colloid, and base paint acts on polar material in the colloid mutually, forms a reticulated structure, firm the wrapping of base paint, forms stable one by one particle, and it comprises following component and weight proportion:
10～20 parts of cationic synthetic resins,
2～4 parts of retardant,
1～2 part of film coalescence aid,
80～90 parts in water.
Said cationic synthetic resin solution can be selected one or more mixtures of cationic SEPIGEL 305 and fluorine modified copolymer emulsion for use.
Said retardant can be selected the salt of calcium, magnesium, aluminium or ammonium etc. for use.
A kind of or its mixture of the optional spent glycol butyl ether of said film coalescence aid, Ucar 35,2-Butoxyethyl acetate.
Said synthetic emulsion can be selected one or more mixtures in phenylpropyl alcohol, pure third, elasticity or the fluorine modified emulsion for use.
The present invention is owing to the different in nature particle on colloidal polar material and base paint look grain surface absorbs each other; Colloid is attracted to the surface of look grain; The emulsion of polar component in the colloid and base paint particle surface and pigment reaction; Form the hard layer of half gel state, stablize gluey protection system thereby form one.This system can not interpenetrate, and stably is suspended in the transparent emulsion, can not sink to the bottom.This gelatinization reaction generally needs 2-3 hour.
The preparation method of fully water based granite multicolor paint of the present invention, it comprises the steps:
1) elder generation mixes each composition of base paint, and viscosity controller is at 100-105ku;
2) will protect each composition of glue to mix then;
3) at last base paint is joined in the protection glue, stir, gelatinization reaction 1-2 hour, add synthetic emulsion again, and the continuation reaction formed in 1-2 hour.
Concrete production technique is following:
1, the preparation of base paint
Partly water, hydrophilic protection glue, wetting agent, dispersion agent, skimmer mix, and are stirred to uniform state, slowly add pigment again, and middling speed is dispersed to fineness≤50um and gets final product.Add anionic emulsion, water, film coalescence aid at last, with thickening material adjustment viscosity to 100 ± 5ku.Subsequent use.
2, the toning of base paint
The base paint for preparing is added in the paint cylinder, and middling speed stirs, and slowly adds aqueous color paste (can allocate by this area mill base commonly used), is mixed to uniform state, is adjusted to the color of design in advance, and is subsequent use.
3, the preparation of protection glue
Retardant is added in the water, and middling speed is dispersed to dissolving fully, adds cationic synthetic resin again, and the middling speed dispersion extremely was dissolved to colourless transparent solution in about 30 minutes fully, and then added film coalescence aid, mixes to get final product.
4, the preparation of look grain lacquer
Base paint after will mixing colours through granulating equipment respectively adds in the granulating equipment; Can make particle by setting size of particles joins in the protective colloid; Stirring at low speed mixes, look seed lac reaction 1-2 hour; Add the negatively charged ion synthetic emulsion, and continue to react the stable look grain lacquer of formation after 1-2 hour.
5, the preparation of fully water based granite multicolor paint
By colour table requirement or requirement of client look grain lacquer not of the same race and ratio is mixed, and stirring at low speed is even.
Fully water based granite multicolor paint of the present invention is full aqueous product; Voc is low, environmental protection, solvent-free; Be ideal substitutes such as marble, grouan, its product performance can be according to GB/T9755-2001, synthetic resins exterior coating standard; And good elasticity is arranged, can cover the slight crack of body of wall.Concrete performance is following:
| Interventions Requested | Technical requirements | Detection method |
| Condition in container | No lump stirs the back uniform state | Range estimation |
| Cryostatic stabilization matter | Never degenerate | GB/T9268-1988 |
| Time of drying (hour) | 2 | GB/T1728-1979 second method |
| Water tolerance (96h) | No abnormal | GB/T1733-1993 |
| Alkali resistance (48h) | No abnormal | GB/T9265-1988 |
| Contamination resistance | ≤15 | GB/T9780-2005 |
| Artificial ageing resistance | 800h is non-foaming, does not come off efflorescence<=1 grade, variable color<=1 grade | GB/T1865--1997 |
| Tension set (normal temperature) | ≥200 | JG/T172-2005 |
Embodiment
Cooperate appended graphic explanation in detail by specific embodiment below, so that the effect that is easier to understand the object of the invention, technology contents, characteristics and is reached.
Embodiment 1
The fully water based granite multicolor paint of present embodiment comprises base paint, colloid and benzene emulsion, between weight ratio be: 30: 40: 30.
The component and the weight part of base paint are following: 40 parts of anionic emulsions (benzene emulsion 296DS), 3 parts in hydrophilic protection glue (methylcellulose gum), 0.2 part of wetting agent (block polyoxyethylene polyoxypropylene ether X-405); 0.1 part of nonionic polyurethane dispersion agent TCP-8030N, 0.3 part of skimmer RF-202,0.5 part of sterilant BIT; 12 parts of pigment R-902 titanium whites; 30 parts in water, 2 parts of film coalescence aid HY-1800,0.1 part of thickening material TT-615.
Colloidal component and weight proportion: 15 parts of cationic synthetic resins (SEPIGEL 305), 4 parts in retardant lime carbonate, 1 part of film coalescence aid butyl glycol ether, 90 parts in water.
The production technique of the fully water based granite multicolor paint of present embodiment is following:
1, the preparation of base paint
Partly water, hydrophilic protection glue, wetting agent, dispersion agent, skimmer mix, and are stirred to uniform state, slowly add pigment again, and middling speed is dispersed to fineness≤50um and gets final product.Add anionic emulsion, water at last, film coalescence aid is with thickening material adjustment viscosity to 100 ± 5ku.Subsequent use.
2, the toning of base paint
The base paint for preparing is added in the paint cylinder, and middling speed stirs, and slowly adds aqueous color paste, is mixed to uniform state, is adjusted to the color of design in advance, and is subsequent use.
The consumption of aqueous color paste is the 0.1-20% of base paint amount, and the prescription of general mill base is: water 30-68%, Mierocrystalline cellulose 1-3%, sanitas 0.1-0.15%, pigment 30-68%.
Mill base prepares process: earlier water and Mierocrystalline cellulose are stirred, Mierocrystalline cellulose is fully expanded, add sanitas and pigment, stir.The selection of each composition of mill base and preparation process all are well known to those skilled in the art.
3, the preparation of protection glue
Retardant is added in the water, and middling speed is dispersed to dissolving fully, adds cationic synthetic resin again, and the middling speed dispersion extremely was dissolved to colourless transparent solution in about 30 minutes fully, and then added film coalescence aid, mixes to get final product.
4, the preparation of look grain lacquer
Through granulating equipment each colored paint is added in the granulating equipment respectively, made particle by setting size of particles and joined in the protective colloid stirring at low speed; Mix; Look seed lac reaction 2 hours adds the negatively charged ion synthetic emulsion, and continues to react the stable look grain lacquer of formation after 1 hour.
5, the preparation of fully water based granite multicolor paint
By colour table requirement or requirement of client look grain lacquer not of the same race and ratio is mixed, and stirring at low speed is even.
The Performance Detection of fully water based granite multicolor paint of the present invention is following:
| Interventions Requested | Technical requirements | Measured data |
| Condition in container | No lump stirs the back uniform state | Meet |
| Cryostatic stabilization matter | Never degenerate | Meet |
| Time of drying | ≤2h | ?1.5h |
| Water tolerance (96h) | No abnormal | No abnormal |
| Alkali resistance (48h) | No abnormal | No abnormal |
| Contamination resistance | ≤15 | ?10 |
| Artificial ageing resistance | 800h is non-foaming, does not come off efflorescence<=1 grade, variable color<=1 grade | 1000h is non-foaming, does not come off 1 grade of efflorescence, 1 grade of variable color |
| Tension set (normal temperature) | ≥200 | ?300 |
The colorful elastic exterior coating material of fully water based granite is full aqueous product; Voc is low, environmental protection, solvent-free; Be ideal substitutes such as marble, grouan, its product performance can be according to GB/T9755-2001, synthetic resins exterior coating standard; And good elasticity is arranged, can cover the slight crack of body of wall.
Embodiment 2
Present embodiment primary process is with embodiment 1, and different is, fully water based granite multicolor paint comprises base paint, colloid and pure-acrylic emulsion, between weight ratio be: 40: 30: 20.
The component and the weight part of base paint are following: 50 parts of anionic emulsions (pure-acrylic emulsion AD-2), 1 part in hydrophilic protection glue (TKK 021), 0.5 part of wetting agent (block polyoxyethylene polyoxypropylene ether X-405); 0.3 part of nonionic polyurethane dispersion agent TCP-8030N, 0.5 part of skimmer RF-202,0.1 part of sterilant BIT; 10 parts of pigment R-902 white titanium pigments, 10 parts of fillers (600 order coarse whiting and talcum powder), 25 parts in water; 1 part of film coalescence aid HY-1800,0.5 part of thickening material TT-615.
Colloidal component and weight proportion: 10 parts of cationic synthetic resins (SEPIGEL 305), 2 parts in retardant magnesiumcarbonate, 2 parts of film coalescence aid 2-Butoxyethyl acetates, 80 parts in water.
Embodiment
Present embodiment primary process is with embodiment 1, and different is, fully water based granite multicolor paint comprises base paint, colloid and fluorine modified emulsion, between weight ratio be: 35: 40: 40.
The component and the weight part of base paint are following: 45 parts of anionic emulsions (modification organosilicon crylic acid latex BD-309), 2 parts in hydrophilic protection glue (Z 150PH), 0.1 part of wetting agent (block polyoxyethylene polyoxypropylene ether X-405); 0.5 part of nonionic polyurethane dispersion agent TCP-8030N, 0.1 part of skimmer RF-202,0.2 part of sterilant BIT; 15 parts of pigment R-902 white titanium pigments, 10 parts of fillers (600 order coarse whiting), 20 parts in water; Film coalescence aid HY-18002 part, 0.3 part of thickening material TT-615.
Colloidal component and weight proportion: 20 parts of cationic synthetic resins (fluorine modified copolymer emulsion PF919), 2 parts in retardant ammonium sulfate, 1 part of film coalescence aid Ucar 35,86 parts in water.
The above is merely preferred embodiment of the present invention, is not to be used for limiting the scope that the present invention implements.So all doing according to the described shape of application range of the present invention, structure, characteristic and spirit all is equivalent variations or modification, all should be included within the claim of the present invention.
Claims (6)
1. a fully water based granite multicolor paint is characterized in that, comprises base paint, colloid and synthetic emulsion, between weight ratio be: 30～40: 30～40: 20～40; The component and the weight part of said base paint are following:
40～50 parts of anionic emulsions,
1～3 part in hydrophilic protection glue,
0.1～0.5 part of wetting agent,
0.1～0.5 part of dispersion agent,
0.1～0.5 part of skimmer,
0.1～0.5 part in sterilant,
10～15 parts of color stuffings,
20～30 parts in water,
1～2 part of film coalescence aid,
0.1～0.5 part of thickening material;
Said anionic emulsion is selected one or more mixtures of phenylpropyl alcohol, pure third, elasticity or modification organosilicon crylic acid latex for use; Said wetting ability protection glue is selected from a kind of of Z 150PH, methyl or TKK 021 or its mixture;
Said colloid comprises following component and weight proportion:
10～20 parts of cationic synthetic resins,
2～4 parts of retardant,
1～2 part of film coalescence aid,
80～90 parts in water.
2. according to the said fully water based granite multicolor paint of claim 1, it is characterized in that said cationic synthetic resin is selected one or more mixtures of cationic SEPIGEL 305 and fluorine modified copolymer emulsion for use.
3. according to the said fully water based granite multicolor paint of claim 1, it is characterized in that said retardant is selected the salt of calcium, magnesium, aluminium or ammonium for use.
4. according to any said fully water based granite multicolor paint of claim 1-3, it is characterized in that said film coalescence aid is selected a kind of or its mixture of butyl glycol ether, Ucar 35,2-Butoxyethyl acetate for use.
5. according to any said fully water based granite multicolor paint of claim 1-3, it is characterized in that said synthetic emulsion is selected one or more mixtures in phenylpropyl alcohol, pure third, elasticity or the fluorine modified emulsion for use.
6. prepare the method for any said fully water based granite multicolor paint of claim 1-5, it is characterized in that, comprise the steps:
1, the preparation of base paint
Partly water, hydrophilic protection glue, wetting agent, dispersion agent, skimmer mix, and are stirred to uniform state, slowly add pigment again, and middling speed is dispersed to fineness≤50um and gets final product; Add anionic emulsion, water, film coalescence aid at last,, subsequent use with thickening material adjustment viscosity to 100-105ku;
2, the toning of base paint
The base paint for preparing is added in the paint cylinder, and middling speed stirs, and slowly adds aqueous color paste, allocates by the mill base that this area is commonly used, is mixed to uniform state, is adjusted to the color of design in advance, and is subsequent use;
3, the preparation of protection glue
Retardant is added in the water, and middling speed is dispersed to dissolving fully, adds cationic synthetic resin again, and the middling speed dispersion extremely was dissolved to colourless transparent solution in about 30 minutes fully, and then added film coalescence aid, mixes to get final product;
4, the preparation of look grain lacquer
Base paint after will mixing colours through granulating equipment respectively adds in the granulating equipment, has made particle by setting size of particles and has joined in the protective colloid stirring at low speed; Mix; Look seed lac reaction 1-2 hour adds synthetic emulsion, and continues to react the stable look grain lacquer of formation after 1-2 hour;
5, the preparation of fully water based granite multicolor paint
By colour table requirement or requirement of client look grain lacquer not of the same race and ratio is mixed, and stirring at low speed is even.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2008100380594A CN101591491B (en) | 2008-05-26 | 2008-05-26 | Full water-borne granite multicolor paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100380594A CN101591491B (en) | 2008-05-26 | 2008-05-26 | Full water-borne granite multicolor paint and preparation method thereof |
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| CN101591491A CN101591491A (en) | 2009-12-02 |
| CN101591491B true CN101591491B (en) | 2012-06-13 |
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| CN106566345A (en) * | 2016-10-31 | 2017-04-19 | 四川泓川美居新材料科技有限公司 | Preparation method for granite imitation paint |
| CN106634340A (en) * | 2016-12-08 | 2017-05-10 | 安徽省阜阳闽安建材有限公司 | Water-based multicolor rock slice paint added with lanthanum-zinc antibacterial silicon dioxide |
| CN107938962A (en) * | 2017-10-20 | 2018-04-20 | 贵州中亚高科涂料有限公司 | A kind of production method of artificial granite paint |
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