CN101395088A - 轻气体与卤素的分离方法 - Google Patents

轻气体与卤素的分离方法 Download PDF

Info

Publication number
CN101395088A
CN101395088A CNA2007800081079A CN200780008107A CN101395088A CN 101395088 A CN101395088 A CN 101395088A CN A2007800081079 A CNA2007800081079 A CN A2007800081079A CN 200780008107 A CN200780008107 A CN 200780008107A CN 101395088 A CN101395088 A CN 101395088A
Authority
CN
China
Prior art keywords
halogen
lighter
bromine
steam
air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA2007800081079A
Other languages
English (en)
Other versions
CN101395088B (zh
Inventor
S·B·加德沃
P·K·斯托米诺夫
P·格鲁索
E·W·麦克法兰
A·W·布里德
M·J·威斯
M·D·维尔斯塔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GRT Inc
Original Assignee
GRT Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GRT Inc filed Critical GRT Inc
Publication of CN101395088A publication Critical patent/CN101395088A/zh
Application granted granted Critical
Publication of CN101395088B publication Critical patent/CN101395088B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/10—Vacuum distillation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D1/00—Evaporating
    • B01D1/16—Evaporating by spraying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/68—Halogens or halogen compounds
    • B01D53/685—Halogens or halogen compounds by treating the gases with solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C01B21/04—Purification or separation of nitrogen
    • C01B21/0405—Purification or separation processes
    • C01B21/0433—Physical processing only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C01B21/04—Purification or separation of nitrogen
    • C01B21/0405—Purification or separation processes
    • C01B21/0433—Physical processing only
    • C01B21/045—Physical processing only by adsorption in solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/01—Chlorine; Hydrogen chloride
    • C01B7/07—Purification ; Separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/01—Chlorine; Hydrogen chloride
    • C01B7/07—Purification ; Separation
    • C01B7/0743—Purification ; Separation of gaseous or dissolved chlorine
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/09—Bromine; Hydrogen bromide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/09—Bromine; Hydrogen bromide
    • C01B7/096—Bromine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/20—Halogens or halogen compounds
    • B01D2257/202—Single element halogens
    • B01D2257/2022—Bromine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/20—Halogens or halogen compounds
    • B01D2257/202—Single element halogens
    • B01D2257/2025—Chlorine
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00—Purification or separation of specific gases
    • C01B2210/0001—Separation or purification processing
    • C01B2210/0009—Physical processing
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00—Purification or separation of specific gases
    • C01B2210/0001—Separation or purification processing
    • C01B2210/0009—Physical processing
    • C01B2210/0014—Physical processing by adsorption in solids
    • C01B2210/0015—Physical processing by adsorption in solids characterised by the adsorbent

Abstract

提供了将一种或多种轻气体与溴或氯分离的方法，该方法使用一种或多种物理分离，并与化学洗涤剂接触以回收额外的卤素。一方面，本发明包括(a)将含有一种或多种轻气体的卤素进料提供至蒸馏塔或闪蒸蒸发器；(b)操作所述蒸馏塔或闪蒸蒸发器以将所述进料分离成(i)第一液体，其含有主要量的卤素和不多于次要量的一种或多种轻气体和(ii)第一蒸气，其含有主要量的一种或多种轻气体和不多于次要量的卤素；和(c)将所述蒸气提供至化学洗涤塔以从所述蒸气中回收卤素。

Description

轻气体与卤素的分离方法
发明领域
本发明通常涉及将惰性气体和其它化合物与卤素分离的方法。
发明背景
选择空气或氧气作为氧化介质已经为许多工业方法进行了探索。对于可用空气进行氧化而不对反应化学有不利影响的方法来说，空气比纯氧气是优选的，因为投资和操作成本降低。氧气的较高成本来自于将氧气与氮气分离的花销，传统上这使用膜或蒸馏来完成。与空气相比优选使用纯氧气的一个实例是合成气生产，它是使用费托合成从天然气生产液体烃的第一个步骤。除了影响反应化学以外，在合成气生产中使用空气需要将氮气与未转化的天然气分离。将氮气与天然气分离是投资密集型的，传统上这使用膜或变压吸附来进行。
捕集惰性气流中的痕量溴的常规方法是使用碱性洗涤剂(scrubber)，例如NaOH水溶液。从该常规洗涤方法回收所捕集的溴并不容易。其它常规方法包括使用亚硫酸钠、亚硫酸氢钠、或氢氧化钙水溶液等，其中每一种都受困于同一缺点：所捕集的溴难以回收。
由Santa Barbara的GRT，Inc.开发的工艺允许通过在反应器中混合烃和卤素以生成烷基卤化物和卤化氢HX来由甲烷或天然气合成较高级的烃。将所述烷基卤化物和HX引至与金属氧化物或类似物质接触以生成较高级的烃和金属卤化物。该金属卤化物被氧化成金属氧化物和卤素，这二者都可以再循环。当用空气进行氧化时，所生成的卤素含有惰性气体例如氮气和二氧化碳，它们如果不除去，将会穿过卤化区和产生较高级的烃的偶联区。在由GRT，Inc.开发的其它工艺中，通过在催化剂的存在下使烷基卤化物与氢气反应来生成烃，HX作为副产物而生成。为了再生卤素以用于整个工艺的下一次循环，在催化剂的存在下用空气或氧气来氧化HX。对于这两种类型的工艺，希望在将卤素用于下一次工艺循环之前将再生的卤素与N2、CO2和其它轻气体(例如未反应的轻质烃)和水分离。对于循环的或连续的工艺，如果不分离的话，这些气体，特别是氮气，将迅速积累。显然需要将惰性气体和其它化合物与卤素分离的有效率的、成本有效的方法。
发明概述
根据本发明，提供了将一种或多种轻气体与溴或氯分离的方法，该方法使用一种或多种物理分离，并与化学洗涤剂接触以回收额外的卤素。根据本发明的一个方面，所述方法包括(a)将含有一种或多种轻气体的卤素进料提供至蒸馏塔或闪蒸蒸发器；(b)操作所述蒸馏塔或闪蒸蒸发器以将所述进料分离成(i)第一液体，其含有主要量的卤素和不多于次要量的一种或多种轻气体和(ii)第一蒸气，其含有主要量的一种或多种轻气体和不多于次要量的卤素；和(c)将所述蒸气提供至化学洗涤塔以从所述蒸气中回收卤素。
在本发明的第二个方面，使用两个或更多个物理分离，每个分离分别导致卤素在液相中和轻气体在蒸气相中的继续更大的富集。例如，来自蒸馏塔的蒸气(富含一种或多种轻气体)可进料至第二蒸馏塔，该第二蒸馏塔进一步将物料分离成新的蒸气和新的液体，该新蒸气更富含一种或多种轻气体，和该新液体更富含卤素。
本发明中所使用的化学洗涤塔含有一种或多种卤素清除剂(scavenger)，这是能够化学吸收卤素的物质，在某些实施方案中通过与卤素的氧化还原反应来化学吸收。优选的物质是溴化亚铜(I)(CuBr，“溴化亚铜”)，其可以通过转化为溴化铜(II)(CuBr2，“溴化铜”)来吸收溴。
附图简述
当参照以下详细描述并参考以下附图考虑时，本发明的特征和优点将变得更容易理解。
图1是根据本发明的一个方面将轻气体与溴分离的工艺示意图；
图2是图1所示工艺的示意图，增加了溴生成(“溴再生”)和水吸附的环节；
图3是根据本发明的另一方面使用三个串联闪蒸蒸发器将一种或多种轻气体与溴分离的工艺示意图；
图4是将天然气转化为较高级的烃的连续工艺的示意图，并包括根据本发明的一方面将该在工艺中生成的溴与轻气体分离的子工艺；
图5是确定卤素在本发明的一个实施方案中所使用的卤素清除剂中的卤素穿透的实验方法的图解说明；
图6是根据本发明的一个方面已经暴露于溴/氮气料流的CuBr管的照片。
发明详述
在本发明的新方法中，通过将含有一种或多种轻气体的卤素进料物理分离成液体和蒸气来将一种或多种轻气体与溴或氯分离，所述液体含有主要量的卤素和不多于次要量的一种或多种轻气体，和所述蒸气含有主要量的一种或多种轻气体和不多于次要量的卤素。通过使该蒸气穿过含有卤素清除剂的化学洗涤塔来从该蒸气中除去额外的卤素。本文使用的“轻气体”是指与卤素混合在一起的沸点比卤素低的气体。溴和氯的常压沸点分别为约59℃和-34℃。该定义包括诸如氮气(N2)、二氧化碳(CO2)和“轻质烃”即C1-C4烃之类的气体，需要说明的是，如果氯是想要的卤素的话，C4烃(丁烷和丁烯)不认为是“轻气体”，因为氯的沸点低于C4烃的沸点。术语“主要量的”和“次要量的”是相对的；含有主要量的第一组分和次要量的第二组分的液体(或蒸气)含有比第二组分更多的第一组分。通常，在本发明的大多数实施方案中，给定的液相(或蒸气相)将由绝大部分的一种组分(卤素或一种或多种轻气体)和非常少的其它组分组成。
本发明的一个实施方案举例说明于图1，其描述了用于将轻气体(在此例中为氮气和二氧化碳)与溴分离的系统10。将含有N2和CO2的溴进料12提供至具有塔顶16和塔底18的蒸馏塔14中。换热器20和22分别起到部分冷凝器和全回流的作用，使得富含溴的液体“塔底产物”(并含有不多于次要量的轻气体-一般不多于两种气体在溴中的溶解度极限)从该蒸馏塔中引出，并通过换热器24实现额外降温。
在该塔的顶部，通过换热器22来促进来自回流罐的液体的全回流，产生富含轻气体的蒸气(并含有不多于次要量的溴)，将该蒸气引至化学洗涤塔26，在那里除去该次要量的溴，产生轻气体(氮气和二氧化碳输出)。如以下所述，可通过加热该洗涤塔来从洗涤塔中回收溴。
在本发明的另一个实施方案中(未示出)，两个或更多个蒸馏塔串联连接，每个塔的塔顶产物(蒸气)引作下一个塔的进料，以从每个塔中连续地将轻气体富集在蒸气中并将溴富集在“塔底产物”料流中。
对于蒸馏装置，一般的压力未0.1-50巴，更优选5-20巴，温度取决于蒸馏系统的压力，牢记，溴的正常沸点为约59℃。级数可为2-200，更优选5-30。
图2举例说明了图2中所示的实施方案的变型，卤素进料(例如Br2)来自于卤素再生单元28。在该实施方案中，来自28的卤素进料含有水，水在水吸附单元(含有干燥剂)中除去。或者，首先蒸馏该进料以从水中移出溴，至多至所生成的溴-水共沸物的极限，残留的水在具有干燥剂的水吸收塔中除去。
在本发明的备选实施方案中，使用一个或多个蒸气-液体闪蒸分离单元(“闪蒸蒸发器”)来将卤素进料与轻气体分离，然后在化学洗涤塔中进行额外的分离。图3举例说明了一种这样的系统50，其中将含有氮气和二氧化碳的溴进料提供至第一闪蒸蒸发器52中。该蒸发器的内容物被闪蒸，得到富含溴(例如97％的Br2回收率)的第一液体和仅含有次要量的溴的富含轻气体的第一蒸气(N2、CO2)。该第一蒸气进料至第二闪蒸蒸发器并闪蒸其内容物，得到富含溴的第二液体(此处，例如额外回收1.5％的溴)和富含轻气体的第二蒸气，该蒸气穿过第二换热器58并进料至第三闪蒸蒸发器60。然后闪蒸第三闪蒸蒸发器的内容物，得到例如额外0.5％的Br2(液体)和非常高度富含轻气体的蒸气。在溴洗涤塔62中除去该第三蒸气料流中的痕量的溴。
如果希望，可使用额外的闪蒸蒸发器。然而，作为实践主题，存在一个收益递减点(就所回收的额外的溴量而言)，超过该点则增加的资金需求和操作开销有可能不合算。
可使用既采用一个或多个蒸馏塔又采用一个或多个蒸发器的混合系统。
通常，为了将轻气体与溴分离，每个闪蒸蒸发器的操作温度为-60℃至40℃，更优选-20℃至10℃，和压力为0.1-50巴，更优选5-20巴，牢记卤素和所含的轻气体之间的沸点差异。优选1-3个闪蒸器。各个闪蒸器中的压力可以变化；然而，为了降低成本，希望在系统压力下操作这些闪蒸器以避免昂贵的压缩。这些闪蒸器的操作温度取决于压力。例如，高压操作甚至在中等高的温度下可允许良好的溴分离。然而，对于较低的压力，需要致冷剂以冷却闪蒸单元。蒸气-液体闪蒸系列可由一个或多个闪蒸组成。
本发明的一个重要方面是从主要由轻气体组成的非常稀的气流中化学洗涤溴或氯的方法。该方法使用能够吸收卤素的卤素清除剂。优选地，所述清除剂从稀释的气流中吸收溴蒸气，然后可以可逆地定量释放出游离溴。可在室温或升高的温度下进行溴吸附。
通常，能够与溴反应并经加热后释放溴的任何物质可用作溴清除剂。被认为是适合用作卤素清除剂的非限制性实例包括CuBr、CuCl、FeBr2、FeCl2、AuCl、AuBr、InBr、InCl、FeO、Cu2O、Hg2Br2、Cu、Ag、Au、Hg、Pt、Pd、Ru、Rh、Fe、Os和Ir，可单独使用或组合使用。当前，CuBr是优选的。如果使用具有高表面积(在载体上)的溴化亚铜，即便溴化亚铜的总量显著更低，仍观察到高得多的活性。还发现由沉淀方法制备的CuBr优于普通的(stock)CuBr。
溴化亚铜(I)与溴按照以下反应反应生成溴化铜(II)：2CuBr+Br2→2CuBr2。该反应迅速且完全，并有利地在低温下发生。该反应似乎是表面结合的(surface-bound)。当使用块状CuBr时，在穿透发生前使用了约1％的固体。(CuBr和CuBr2的密度密度非常相似，和表面不会良好更新；4.6对4.0g/cm3)。因为CuBr与Br2蒸气的反应是气体与固体的反应，反应速率受到固-气界面的限制，并因此，表面积越高，反应性越高。事实上，纯CuBr的大晶体是效果最差的吸附剂。当发生穿透时(Br2不再被固体所保留)，所消耗的CuBr的量约为固体总体积的0.2％，这意味着仅固体的表面参与了反应。低反应温度消除了离子迁移的可能性，也消除了剩下的现存块状CuBr的使用。
CuBr在低温下吸收Br2的能力是部分有利的，因为从溴分离中出来的惰性气流(含有痕量的溴)处于低温或环境温度下；因此，在环境温度或接近环境温度下操作该洗涤塔不需要额外输入能量。
通过将固体加热至高于250℃，一般为250-275℃，来再生该固体(在本例中为溴化铜(II))，由此来回收所洗下的溴。该再生反应为：2CuBr2(加热)→2CuBr+Br2。当洗涤剂为溴化亚铜时，该再生是热活化的并且不需要氧气。
所述卤素清除剂可作为块状粉末使用，或沉积在载体上。非限制性实例包括氧化硅、氧化锆、氧化钛、WO3、CaO、MgO、Cr2O3、和各种碳化物、氮化物和类似物质。首要要求是该载体的表面积为5-1500M2/g。在我们的实验中，我们已经使用固体Cu(I)Br或沉积在具有高表面积(约300m2/g)的Davicat SiZr4700或Davicat Si1151A(Davidson Corporation)、氧化硅上的Cu(I)Br。Si4700B含有约3wt％的ZrO2。其它载体在溴化亚铜上进行该洗涤反应方面应该是同等有效的。
所述卤素清除剂，或清除剂加上载体，可在填料塔反应器结构或其它结构例如壳管反应器中使用。可使用标准的传热介质来传送所需要的热量以将洗涤塔的活性成份升至再生温度。该工艺方案可包括两个反应器，其中一个进行洗涤，而另一个进行再生。
所述固体洗涤剂能够完全保留来自惰性气流的所有的溴成份(来自洗涤塔的溴损失据估计小于1ppb)。在多次耗尽和再生循环后，负载的溴化亚铜(I)显示出可再生的结果。
当使用载体(例如氧化硅)时，非均匀的表面产生成核点，这导致生成更小的微晶，其具有大得多的表面积。即便在该负载的物质仅含有15wt％的CuBr时，它的较高的CuBr表面积使得它是用于溴蒸气保留的更好的物质。
为了探索溴化亚铜(I)作为卤素清除剂的效果，使用可商购得到的CuBr、负载的CuBr和由沉淀法生成的CuBr进行了一系列实验。原始的洗涤剂(CuBr)通过加热CuBr2来再生。结果示于表1。
表1Br2洗涤结果
Figure A200780008107D00101
注释：
％是由所述清除剂所保留的总Br量。
再生在275℃下在10-15分钟内完成。
测试了数个循环，CuBr/4700B的活性没有降低。
*-生成了痕量的AgBr，但重量经测量<10-4g。
**-再生后，其效果降低至所述商购物质的效果。
图6是在室温下暴露于溴/氮气流中30分钟的沉淀的CuBr的管的照片。暗色物质是CuBr2。经加热，颜色变回CuBr的浅绿色，释放溴。
实验程序(protocol)：将与1.5sccm N2混合的30sccm/min的N2穿过冷却至0℃的Br2鼓泡器。所述固体吸附剂床含于直径为1cm的圆柱形玻璃管内。在室温下暴露于这样产生的在氮气中的稀释的溴的持续时间为40分钟。将该洗涤塔处理过的气体穿过含有1M NaOH的阱鼓泡。
负载的CuBr物质的制备：将载体分散在约20wt％的CuBr2水溶液中并用SO2鼓泡直到溶液颜色变得几乎无色。过滤该悬浮物并在115℃下干燥过夜。
再生：在耗尽后，在275℃下加热具有固体洗涤剂的反应器20分钟，由此再生保留的溴。通过将所释放的溴捕集在1M NaOH溶液阱中来收集所释放的溴并进行定量。有可能近乎完全回收所捕集的溴。
定量：未被洗涤剂保留的溴的量或从耗尽的洗涤剂中再生的溴的量通过在NaOH阱中的吸收来定量，其在最后用HNO3酸化直至pH值降至5或5以下，然后使用过量的0.5M AgNO3来沉淀出AgBr(加入直到不再有沉淀产生)。由用于过滤的玻璃烧结的过滤器的质量增量并干燥AgBr沉淀直至其重量不变来计算所存在的溴的量。
通过使用Br和BrO-与Ag+的沉淀来测定溴穿透，其中，NaOH阱用HNO3酸化直至酸性；加入AgNO3直至不再生成沉淀；允许将该悬浮物老化40分钟，然后在干燥的、预称重的玻璃烧结的漏斗上过滤，干燥直至恒重，质量差是AgBr。
AgNO3+Br-→AgBr↓+NO3 -
AgNO3+BrO-→AgBrO↓+NO3 -
AgBrO→AgBr+O2
AgBr的溶解度常数Ksp为5×10-13mol21-2。加入到总共约20-25ml酸化的NaOH阱中的AgNO3溶液为0.5M-3ml(或更多)。最终的Ag+浓度为约0.06M。Br-的最低的可检测浓度为约8×10-12M，对应于约0.6ppb。即便假定为非理想情况(高离子强度，离子活度不等于1)，灵敏度仍处于ppb范围。
实施例
根据在当前实施方案中所述的方法，对含有约25体积％的溴的流量为40sccm(标准立方厘米每分钟)的氮气惰性气体流进行测试。将该料流冷却至25℃，这在工业上可通过使用空气冷却的换热器来实现。然后将该料流，其压力为25巴，在单一的在5℃下操作的蒸气液体闪蒸单元中闪蒸。来自该闪蒸的液体出口含有大于98％的初始进料中的溴，以及溶解在该溴料流中的一些惰性气体。然后使含有惰性气体和痕量溴的蒸气料流在室温下流过负载的溴化亚铜(I)的床层。从该惰性气体料流中捕集溴是完全的，和所述洗涤床层实现完全的溴捕集40分钟时间。将含有溴化铜(II)和溴化亚铜(I)的耗尽的洗涤床层加热到275℃，并在15分钟的期间内观察到几乎完全的溴回收。
本发明应该在许多使用卤素作为原料或中间体用于化学品生产的工业过程中具有实用性，其中卤素回收或提纯通过除去惰性气体或轻气体而得以改进，导致显著降低的资金和操作成本。这其中有在美国专利6,486,368、6,472,572、6,472,572、6,465,696、6,462,243、6,403,840中所述的用于制造醇、酯、烯烃和烷氧基化物的方法，和在刚好与本申请同一天提交的标题为“Continuous Process forConverting Hydrocarbon Foodstocks into Higher Hydrocarbons andOlefins＂(代理人备案号56987/G506)”的美国专利申请中所述的用于制备较高级的烃的方法，将它们的全部内容通过该引用并入本文。例如，在由天然气制备汽油范围的烃的方法中，当用空气来再生时，氮气和二氧化碳进入溴化区和复分解(metathesis)区。为了再循环未转化的甲烷，需要将氮气与甲烷分离，这是高成本的。而且，在再生过程中产生的二氧化碳必须与未转化的甲烷分离，要么使用变压吸附要么使用胺基体系来分离，二者都是高成本的。将轻气体与溴分离不仅降低了反应器尺寸而且简化了轻气体与产物和未转化的反应物的分离。本文所述的分离方法提供了成本有效的将轻气体(包括氮气和二氧化碳)与卤素例如溴分离的方法。
本发明已经用多个实施方案和实施例来描述，但不限于此。所附权利要求的其它修改以及等价物落在本发明的范围内。

Claims (12)

1.将一种或多种轻气体与溴或氯分离的方法，包括：
(a)将含有一种或多种轻气体的卤素进料提供至蒸馏塔或闪蒸蒸发器；
(b)操作所述蒸馏塔或闪蒸蒸发器以将所述进料分离成(i)第一液体，其含有主要量的卤素和不多于次要量的一种或多种轻气体和(ii)第一蒸气，其含有主要量的一种或多种轻气体和不多于次要量的卤素；和
(c)将所述蒸气提供至化学洗涤塔以从所述蒸气中回收卤素。
2.权利要求1的方法，还包括将所述第一液体提供至蒸馏塔或闪蒸蒸发器以将所述第一液体分离成(i)第二液体，其含有主要量的卤素和不多于次要量的一种或多种轻气体和(ii)第二蒸气，其含有主要量的一种或多种轻气体和不多于次要量的卤素；和
(c)将所述第二蒸气提供至化学洗涤塔以从所述蒸气中回收卤素。
3.权利要求1的方法，其中所述卤素是溴。
4.权利要求1的方法，其中所述卤素是氯。
5.权利要求1的方法，其中所述一种或多种轻气体包括氮气。
6.权利要求1的方法，其中所述一种或多种轻气体包括氮气和一种或多种选自由二氧化碳和C1-C4烃组成的组的其它气体。
7.权利要求1的方法，其中所述化学洗涤塔包含负载的或非负载的化学清除剂的床层。
8.权利要求1的方法，其中所述卤素清除剂包括选自由CuBr、CuCl、FeBr2、FeCl2、AuCl、AuBr、InBr、InCl、FeO、Cu2O、Hg2Br2、Cu、Ag、Au、Hg、Pt、Pd、Ru、Rh、Fe、Os、Ir及其混合物组成的组的材料。
9.权利要求1的方法，其中所述卤素清除剂包括CuBr。
10.权利要求1的方法，其中将所述卤素清除剂负载在选自由金属氧化物、金属碳化物、金属氮化物、碳、粘土及其混合物组成的组的材料上。
11.权利要求1的方法，其中将所述卤素清除剂负载在选自由Al2O3、SiO2、ZrO2、TiO2、WO3、CaO、MgO、Cr2O、SiC、Mo4C、TiN、W2N、碳、沸石、蛭石及其混合物组成的组的材料上。
12.权利要求1的方法，还包括加热所述化学洗涤塔以从中释放卤素。
CN2007800081079A 2006-02-03 2007-02-05 轻气体与卤素的分离方法 Expired - Fee Related CN101395088B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US76547306P 2006-02-03 2006-02-03
US60/765,473 2006-02-03
PCT/US2007/003090 WO2007092410A2 (en) 2006-02-03 2007-02-05 Separation of light gases from halogens

Publications (2)

Publication Number Publication Date
CN101395088A true CN101395088A (zh) 2009-03-25
CN101395088B CN101395088B (zh) 2012-04-04

Family

ID=38345723

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2007800081079A Expired - Fee Related CN101395088B (zh) 2006-02-03 2007-02-05 轻气体与卤素的分离方法

Country Status (17)

Country Link
US (1) US7883568B2 (zh)
EP (1) EP1993951B1 (zh)
JP (1) JP5275817B2 (zh)
KR (1) KR101335397B1 (zh)
CN (1) CN101395088B (zh)
AU (1) AU2007212493B2 (zh)
BR (1) BRPI0707490A2 (zh)
CA (1) CA2641426C (zh)
EA (1) EA013629B1 (zh)
EC (1) ECSP088711A (zh)
HK (1) HK1130758A1 (zh)
MY (1) MY153701A (zh)
NO (1) NO20083776L (zh)
SG (1) SG187456A1 (zh)
UA (1) UA95943C2 (zh)
WO (1) WO2007092410A2 (zh)
ZA (1) ZA200807230B (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105478000A (zh) * 2015-12-30 2016-04-13 沈阳三聚凯特催化剂有限公司 一种用于净化重整再生气的脱氯剂及其制备方法

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
WO2005021468A1 (en) 2003-07-15 2005-03-10 Grt, Inc. Hydrocarbon synthesis
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US20060229228A1 (en) * 2005-04-11 2006-10-12 Zachary John Anthony Komon Method of making alkoxylates
EA020442B1 (ru) 2006-02-03 2014-11-28 ДжиАрТи, ИНК. Способ превращения углеводородного сырья (варианты) и система для его осуществления
NZ581216A (en) 2007-05-24 2011-06-30 Grt Inc Zone reactor incorporating reversible hydrogen halide capture and release
AU2009270801B2 (en) 2008-07-18 2014-04-24 Reaction 35, Llc Continuous process for converting natural gas to liquid hydrocarbons
JP5671550B2 (ja) * 2009-11-13 2015-02-18 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 塩素供給物を精製する方法
JP5617623B2 (ja) * 2010-12-28 2014-11-05 株式会社島津製作所 全有機体炭素測定装置
US8940954B2 (en) 2011-05-23 2015-01-27 Reaction35, LLC Conversion of propane to propylene
WO2013006427A1 (en) * 2011-07-01 2013-01-10 Sun Catalytix Corporation Methods and systems useful for solar energy storage
MY156181A (en) * 2011-10-11 2016-01-15 Hong In Chemical Co Ltd Method and system for producing high-purity hydrogen chloride
WO2014193957A1 (en) * 2013-05-30 2014-12-04 Reaction 35, Llc Recovery of halogens by partial condensation
DE112014002973T5 (de) 2013-06-24 2016-05-19 Reaction 35, Llc Kopplung von leichten Alkanen an flüssige Brennstoffe
EP3154921B1 (en) 2014-06-12 2020-02-26 Reaction 35, LLC Production of 1,3-butadiene

Family Cites Families (732)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3172915A (en) 1965-03-09 Preparation of oxygenated methane derivatives
GB156122A (en) 1919-12-08 1922-03-30 Otto Traun S Forschungslaborat Process for the manufacture of diolefines and derivatives thereof
GB294100A (en) 1927-07-16 1929-06-27 Curt Epner Improvements in and relating to the production of liquid polymerisation products from gases containing hydrocarbons
GB363009A (en) 1930-09-19 1931-12-17 John Philip Baxter Production of acetylene and vinyl chloride from ethylene dichloride
FR745544A (zh) 1931-11-11 1933-05-12
DE698778C (de) 1934-11-11 1941-07-10 I G Farbenindustrie Akt Ges Verfahren zur Herstellung von organischen Monochlor- oder Monobromverbindungen
GB474922A (en) 1936-05-14 1937-11-15 Ig Farbenindustrie Ag Process for chlorinating and brominating hydrocarbons
US2246082A (en) 1939-08-22 1941-06-17 Shell Dev Preparation of alkyl halides
GB536491A (en) 1939-09-28 1941-05-16 Bataafsche Petroleum A process for the production of aromatic hydrocarbons from unsaturated hydrocarbons
GB553950A (en) 1941-09-09 1943-06-11 Du Pont Improvements in or relating to the manufacture of halogenated hydrocarbons
GB586483A (en) 1944-07-05 1947-03-20 Standard Oil Dev Co Process for the conversion of normally gaseous olefins to liquid hydrocarbons
US2488083A (en) 1946-06-18 1949-11-15 Socony Vacuum Oil Co Inc Manufacture of liquid hydrocarbons
US2677598A (en) 1953-01-19 1954-05-04 Dow Chemical Co Oxidation of ferrous halides to form ferric halides
GB775590A (en) 1953-11-27 1957-05-29 Standard Oil Co Improvements in or relating to production of ethyl toluenes
US2941014A (en) 1954-08-06 1960-06-14 Hoechst Ag Manufacture of alkyl chlorination products
GB793214A (en) 1955-02-18 1958-04-09 Bataafsche Petroleum Process for the conversion of hydrocarbons containing acyclic carbon atoms
US2822889A (en) * 1955-09-26 1958-02-11 Diamond Alkali Co Chlorine purification
GB796085A (en) 1955-12-22 1958-06-04 Bataafsche Petroleum Hydrocarbon conversion process
GB796048A (en) 1956-02-06 1958-06-04 Bataafsche Petroleum Conversion of hydrocarbons
DE1037137B (de) * 1957-01-25 1958-08-21 Bayer Ag Verfahren zur Herstellung halogenhaltiger, aromatisch-aliphatischer Polyaether
GB883256A (en) 1958-05-02 1961-11-29 Columbia Southern Chem Corp Halogenation process
US3029575A (en) * 1958-11-03 1962-04-17 Exxon Research Engineering Co Chlorine separation process
US3562321A (en) * 1961-10-10 1971-02-09 Sun Oil Co Preparation of oxygenated hydrocarbons
GB950976A (en) 1961-10-13 1964-03-04 British Hydrocarbon Chem Ltd Improvements in and relating to the production of olefines
BE623466A (zh) 1961-10-13
GB991303A (en) 1962-07-26 1965-05-05 British Hydrocarbon Chem Ltd The production of olefines by the dehydrochlorination of alkyl chlorides
US3294846A (en) 1962-10-10 1966-12-27 Dow Chemical Co Process for preparing metaaryloxy phenols
US3246043A (en) 1962-12-12 1966-04-12 Universal Oil Prod Co Preparation of olefinic hydrocarbons
GB1015033A (en) 1963-01-31 1965-12-31 Shell Int Research Preparation of olefin oxides
US4011278A (en) 1963-02-27 1977-03-08 Mobil Oil Corporation Conversion of polar compounds using a zsm-5 zeolite catalyst
NL125428C (zh) 1963-02-27
US3273964A (en) 1963-02-28 1966-09-20 Universal Oil Prod Co Process for producing bromine from a mixture of hydrogen bromide and olefinic hydrocarbon
GB1104294A (en) 1963-12-10 1968-02-21 Ralph William King Production of lower alkanols and lower alkyl bromides
US3310380A (en) * 1964-02-13 1967-03-21 Universal Oil Prod Co Bromine recovery
US3923913A (en) 1964-05-12 1975-12-02 Pechiney Saint Gobain Process for obtaining chlorinated derivatives of ethylene
US3353919A (en) 1964-07-23 1967-11-21 Air Preheater Apparatus for the elimination of odors from noxious gases
BE672377A (zh) 1964-11-24 1966-05-16
US3353916A (en) 1966-04-25 1967-11-21 Universal Oil Prod Co Quantitative recovery of bromine by two stage catalytic oxidation of hydrogen bromide
DE1618686B1 (de) 1966-04-28 1971-08-26 Marathon Oil Co Tieftemperatur-Verfahren für die Chlorierung oder Bromierung von Kohlenwasserstoffen
US3346340A (en) 1966-08-11 1967-10-10 Universal Oil Prod Co Production of bromine by oxidation of hydrogen bromide
DE1807780B2 (de) 1968-11-08 1976-11-04 Henkel & Cie GmbH, 4000 Düsseldorf Verfahren zur herstellung von aether- und polyaetheralkoholen
DE1618254B1 (de) 1967-06-29 1971-07-08 Kalk Chemische Fabrik Gmbh Verfahren zur Herstellung von Bromverbindungen aus Alkoholen aus Brom
US3496242A (en) * 1967-08-30 1970-02-17 Fmc Corp Oxychlorination of mixed hydrocarbons
US3598876A (en) 1967-11-13 1971-08-10 Universal Oil Prod Co Selective halogenation of hydrocarbons
US3879480A (en) 1967-12-07 1975-04-22 Lummus Co Vinyl chloride process
US3679758A (en) 1968-02-05 1972-07-25 Sun Oil Co Dihalogenation of branched alkanes
GB1253618A (en) 1968-03-28 1971-11-17 Perstorp Ab Process for the production of dry semi-formals
CA920775A (en) 1968-05-13 1973-02-13 Vadekar Mohan Oxidation of hydrogen chloride using molecular sieve catalysts
US3673264A (en) 1968-05-21 1972-06-27 Dow Chemical Co Method of preparing optically active propylene chlorohydrins and propylene oxides
US3920764A (en) 1968-10-23 1975-11-18 Lummus Co Dehydrogenation process
US3657367A (en) 1968-10-31 1972-04-18 Stauffer Chemical Co Oxychlorination of saturated and unsaturated hydrocarbons in the presence of a fluidized catalyst containing lanthanum and didymium
US3670037A (en) 1969-02-19 1972-06-13 Exxon Research Engineering Co Catalyst system
US3883651A (en) 1969-08-08 1975-05-13 Boehringer Sohn Ingelheim Pharmaceutical compositions containing a 2-(aminoalkylamino)-4-amino-thieno{8 3,2-d{9 pyrimidine and method of use
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3705196A (en) 1969-10-31 1972-12-05 Sun Oil Co Synthesis of aliphatic and alicyclic ethers
US3875293A (en) * 1970-12-07 1975-04-01 Dow Chemical Co Recovery of bromine from organic bromides
US3799997A (en) 1971-11-08 1974-03-26 Universal Oil Prod Co Preparation of alkenynes
US3968200A (en) 1972-03-27 1976-07-06 The Lummus Company Reactor effluent quench system
US4172099A (en) 1972-05-30 1979-10-23 Stauffer Chemical Company Process for chlorination of ethylene
GB1395926A (en) 1972-07-27 1975-05-29 Bp Chem Int Ltd Process for the production of isoprene by the chlorination/ dehydrochlorination of 2-methylbutene-2
JPS5231022B2 (zh) 1972-10-06 1977-08-12
US3876715A (en) * 1972-12-01 1975-04-08 Gulf Research Development Co Process for preparing 2,3-dibromo-2-alkylalkanes
IT982662B (it) 1973-03-30 1974-10-21 Montedison Spa Procedimento di bromofluorurazio ne del metano
US4347391A (en) 1973-06-11 1982-08-31 Stauffer Chemical Company Process for preparing ethylene dichloride
US3865886A (en) * 1973-06-20 1975-02-11 Lummus Co Production of allyl chloride
US3894105A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Production of durene
US3894104A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization of hetero-atom substituted hydrocarbons
US3894107A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Conversion of alcohols, mercaptans, sulfides, halides and/or amines
US3894103A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization reactions
US3879473A (en) 1973-08-14 1975-04-22 Phillips Petroleum Co Preparation of ethers from alcohols and olefins catalyzed by iodine
US3987119A (en) 1973-10-23 1976-10-19 Allied Chemical Corporation Production of vinyl chloride from ethane
US3919336A (en) 1973-10-23 1975-11-11 Allied Chem Method of preparing vinyl chloride from liquid ethylene dichloride
US4092368A (en) 1974-03-13 1978-05-30 General Electric Company Vapor phase transesterification
US4117251A (en) 1974-05-15 1978-09-26 Chemische Werke Huls Ag Method for preparing straight chain primary alcohols from 1-bromoalkanes
US4046825A (en) 1974-05-15 1977-09-06 Mobil Oil Corporation Conversion of oxygenated compounds to gasoline
US4035285A (en) 1974-05-28 1977-07-12 Mobil Oil Corporation Hydrocarbon conversion process
US3965205A (en) 1974-06-10 1976-06-22 Mobil Oil Corporation Conversion of low octane hydrocarbons to high octane gasoline
US4169862A (en) 1974-07-22 1979-10-02 The B. F. Goodrich Company Low temperature catalytic combustion of chlorohydrocarbons
US4058576A (en) 1974-08-09 1977-11-15 Mobil Oil Corporation Conversion of methanol to gasoline components
US4138440A (en) * 1974-08-14 1979-02-06 Mobil Oil Corporation Conversion of liquid alcohols and ethers with a fluid mass of ZSM-5 type catalyst
US3928483A (en) 1974-09-23 1975-12-23 Mobil Oil Corp Production of gasoline hydrocarbons
US4044061A (en) 1974-09-23 1977-08-23 Mobil Oil Corporation Preheating methanol effects steady state operation of conversion to gasoline
US3974062A (en) 1974-10-17 1976-08-10 Mobil Oil Corporation Conversion of full range crude oils with low molecular weight carbon-hydrogen fragment contributors over zeolite catalysts
US4071753A (en) * 1975-03-31 1978-01-31 Gte Laboratories Incorporated Transducer for converting acoustic energy directly into optical energy
US4025576A (en) 1975-04-08 1977-05-24 Mobil Oil Corporation Process for manufacturing olefins
US4025575A (en) 1975-04-08 1977-05-24 Mobil Oil Corporation Process for manufacturing olefins
US4049734A (en) 1975-04-08 1977-09-20 Mobil Oil Corporation Conversion of coal to high octane gasoline
US4133838A (en) * 1975-05-15 1979-01-09 Pearson Research Corp. Process for preparing hydrocarbons from methanol and phosphorus pentoxide
US4039600A (en) 1975-07-02 1977-08-02 Mobil Oil Corporation Conversion of synthesis gas to aromatic hydrocarbons
ZA763551B (en) 1975-07-02 1978-01-25 Mobil Oil Corp Manufacture of gasoline
US4087475A (en) 1975-07-03 1978-05-02 Robert Kenneth Jordan Carbonyl fluorination process
US4052471A (en) 1975-08-06 1977-10-04 Pearsall Chemical Corporation Process for chlorinating C8 to C30 linear hydrocarbons
US3992466A (en) 1975-08-13 1976-11-16 Mobil Oil Corporation Hydrocarbon conversion
DE2545342A1 (de) * 1975-10-09 1977-04-21 Bayer Ag Verfahren zur absorption von chlor
US4052472A (en) 1976-01-16 1977-10-04 Mobil Oil Corporation Mordenite conversion of alkanols to penta- and hexamethyl benzenes
US4049573A (en) 1976-02-05 1977-09-20 Mobil Oil Corporation Zeolite catalyst containing oxide of boron or magnesium
US4006169A (en) * 1976-02-26 1977-02-01 Smithkline Corporation Epoxidation of α,β-ethylenic ketones
US4060568A (en) 1976-03-31 1977-11-29 Mobil Oil Corporation Silica-modified zeolite catalyst and conversion therewith
US4072733A (en) * 1976-04-02 1978-02-07 Ethyl Corporation Conversion of methanol and dimethyl ether
US4110180A (en) 1976-04-28 1978-08-29 Diamond Shamrock Technologies S.A. Process for electrolysis of bromide containing electrolytes
IT1075503B (it) 1976-05-08 1985-04-22 Basf Ag Processo per la preparazione di glicolesteri
US4025572A (en) 1976-05-12 1977-05-24 Mobil Oil Corporation Manufacture of hydrocarbons
US4025571A (en) 1976-05-12 1977-05-24 Mobil Oil Corporation Manufacture of hydrocarbons
GB1542112A (en) 1976-06-11 1979-03-14 Shell Int Research Process for the preparation of 2-phenylethanol or derivatives thereof
US4035430A (en) 1976-07-26 1977-07-12 Mobil Oil Corporation Conversion of methanol to gasoline product
US4194990A (en) 1977-02-11 1980-03-25 Allied Chemical Corporation Catalyst and process for the production of chlorofluorinated hydrocarbons
US4380682A (en) 1977-03-30 1983-04-19 Diamond Shamrock Corporation Balanced chlorination process
US4156698A (en) 1977-05-05 1979-05-29 Mobil Oil Corporation Conversion of alcohols or ethers using rare earth crystalline aluminosilicate in an alumina matrix
IT1077342B (it) 1977-07-18 1985-05-04 Snam Progetti Processo per la produzione di oligomeri da alfaolefine lineari,successiva idrogenazione degli stessi e prodotti saturi cosi' ottenuti
NL7710901A (nl) 1977-10-05 1979-04-09 Esmil B V Stationsstraat 48 Werkwijze voor het gelijktijdig verwerken van gebruikt metaal en/of metaalafval van gehaloge- neerde koolwaterstoffen.
US4300005A (en) 1977-12-02 1981-11-10 Monsanto Co. Preparation of vinyl chloride
US4133966A (en) * 1977-12-23 1979-01-09 Gulf Research & Development Company Selective formation of ethanol from methanol, hydrogen and carbon monoxide
US4282159A (en) 1978-06-19 1981-08-04 Wisconsin Alumni Research Foundation Preparation of alkylene oxides
DE2832532A1 (de) 1978-07-25 1980-02-07 Hoechst Ag Verfahren zur gewinnung von reinen 2-(perfluoralkyl)-aethanolen aus ihren gemischen mit 2-(perfluoralkyl)-aethylenen und gegebenenfalls 2-(perfluoralkyl)- aethylestern
US4187255A (en) * 1978-08-21 1980-02-05 Conoco, Inc. Process for methylating naphthalene
FR2434861A1 (fr) 1978-08-31 1980-03-28 Inst Francais Du Petrole Procede de production d'essence a haut indice d'octane et en particulier d'essence utilisable sans plomb
US4849573A (en) 1978-09-05 1989-07-18 Mobil Oil Corporation Process for manufacturing light olefins
US4300009A (en) 1978-12-28 1981-11-10 Mobil Oil Corporation Conversion of biological material to liquid fuels
US4311865A (en) * 1979-04-04 1982-01-19 Mobil Oil Corporation Manufacture of hydrocarbons from oxygenates
NL7902886A (nl) * 1979-04-12 1980-10-14 Shell Int Research Werkwijze voor de bereiding van een koolwaterstof- mengsel.
US4443620A (en) 1979-05-03 1984-04-17 The Lummus Company Production of epoxy compounds from olefinic compounds
US4496752A (en) * 1979-05-03 1985-01-29 The Lummus Company Production of epoxy compounds from olefinic compounds
US4410714A (en) 1979-05-03 1983-10-18 The Lummus Company Production of epoxy compounds from olefinic compounds
US4272338A (en) 1979-06-06 1981-06-09 Olin Corporation Process for the treatment of anolyte brine
EP0021497A1 (en) 1979-06-21 1981-01-07 THE PROCTER &amp; GAMBLE COMPANY Synthesis of polyoxyalkylene glycol monoalkyl ethers
US4371716A (en) * 1979-09-04 1983-02-01 Shell Oil Company β-(Sec-alkoxy) ethanol process
US4462814A (en) 1979-11-14 1984-07-31 Koch Process Systems, Inc. Distillative separations of gas mixtures containing methane, carbon dioxide and other components
US4307261A (en) 1980-02-19 1981-12-22 Vulcan Materials Company Process for separating ferric iron from chlorinated hydrocarbons
US4412086A (en) 1980-02-19 1983-10-25 Vulcan Materials Company Process for separating ferric iron from chlorinated hydrocarbons
US4350511A (en) 1980-03-18 1982-09-21 Koch Process Systems, Inc. Distillative separation of carbon dioxide from light hydrocarbons
DE3164837D1 (en) 1980-05-01 1984-08-23 Ici Plc Halogenation process using a halide carrier and process for regeneration of the halide carrier
US4302619A (en) 1980-06-04 1981-11-24 Mobil Oil Corporation Control of CO emissions in a process for producing gasoline from methanol
US4317934A (en) 1980-08-15 1982-03-02 Ethyl Corporation Preparation of carbonyl compounds
US4320241A (en) 1980-08-28 1982-03-16 Occidental Research Corporation Process for converting oxygenated hydrocarbons into hydrocarbons
US4317943A (en) 1980-09-12 1982-03-02 Texaco Inc. Process for preparing glycol ethers
US4308403A (en) 1980-09-12 1981-12-29 Texaco Inc. Process for preparing glycol ethers
US4333852A (en) 1980-09-25 1982-06-08 Union Carbide Corporation Catalyst for the selective production of ethanol and methanol directly from synthesis gas
US4301253A (en) 1980-09-25 1981-11-17 Union Carbide Corporation Process for the selective production of ethanol and methanol directly from synthesis gas
US4431856A (en) * 1980-09-29 1984-02-14 Mobil Oil Corporation Fluid zeolite catalyst conversion of alcohols and oxygenated derivatives to hydrocarbons
DE3037093C1 (de) 1980-10-01 1981-11-12 Chemische Werke Hüls AG, 4370 Marl Verfahren zur Herstellung von Cycloocten-4-ol-1 aus Cyclooctadien-1,5
US4543434A (en) 1981-01-28 1985-09-24 Mobil Oil Corporation Process for producing liquid hydrocarbon fuels
US4690903A (en) 1981-02-02 1987-09-01 Mobil Oil Corporation Process for preparing organic fuels and chemicals from biomass
GB2095245A (en) 1981-03-19 1982-09-29 Ici Plc Chlorination of alkanes
GB2095243A (en) 1981-03-19 1982-09-29 Ici Plc Production of methylene chloride
IN157669B (zh) 1981-03-23 1986-05-17 Pfizer
DE3117135A1 (de) 1981-04-30 1982-11-18 Bayer Ag, 5090 Leverkusen Kristallines alumosilicat, verfahren zu dessen herstellung sowie dessen verwendung zur katalytischen umwandlung von methanol und/oder dimethylether in kohlenwasserstoffe
US4389391A (en) 1981-06-28 1983-06-21 Dunn Jr Wendell E Process for beneficiating titaniferous ores
US4373109A (en) * 1981-08-05 1983-02-08 Olah George A Bifunctional acid-base catalyzed conversion of hetero-substituted methanes into olefins
DE3132692A1 (de) 1981-08-19 1983-03-17 Bayer Ag, 5090 Leverkusen Verfahren zur halogenierung von organischen verbindungen
US4465893A (en) 1982-08-25 1984-08-14 Olah George A Oxidative condensation of natural gas or methane into gasoline range hydrocarbons
WO1983000859A1 (en) 1981-09-01 1983-03-17 George Andrew Olah Methyl halides and methyl alcohol from methane
US4513164A (en) 1981-09-01 1985-04-23 Olah George A Condensation of natural gas or methane into gasoline range hydrocarbons
US4523040A (en) 1981-09-01 1985-06-11 Olah George A Methyl halides and methyl alcohol from methane
US4433192A (en) * 1981-09-01 1984-02-21 Olah George A Condensation of natural gas or methane into gasoline range hydrocarbons
US4467130A (en) 1981-09-01 1984-08-21 Olah George A Condensation of natural gas or methane into gasoline-range hydrocarbons
DE3137751A1 (de) 1981-09-23 1983-03-31 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zum erzeugen von benzinkohlenwasserstoffen aus methanol
US4605803A (en) 1981-11-21 1986-08-12 Mobil Oil Corporation Acid-catalyzed organic compound conversion
CA1186345A (en) 1981-12-14 1985-04-30 Martin M.Y. Chang Hydrocarbon production
US4568660A (en) * 1982-01-25 1986-02-04 Hercules Incorporated Cycloolefin polymerization catalyst composition
US4489211A (en) 1982-02-04 1984-12-18 Onoda Cement Co., Ltd. Process for producing 2,2,2-trifluoroethanol
US4538014A (en) 1982-03-08 1985-08-27 Mobil Oil Corporation Catalysis over activated zeolites
US4538015A (en) 1982-03-08 1985-08-27 Mobil Oil Corporation Catalysis over activated zeolites
IT1150678B (it) 1982-03-12 1986-12-17 Anic Spa Procedimento per la produzione di eteri alchil terbutilici in presenza di butadiene
US4384159A (en) 1982-03-12 1983-05-17 The Dow Chemical Company Catalytic dehydrohalogenation process
US4433189A (en) * 1982-03-18 1984-02-21 Mobil Oil Corporation Catalytic conversion of methanol to light olefins
US4588835A (en) 1982-03-29 1986-05-13 Otsuka Kagaku Yakuhin Kabushiki Kaisha Process for preparing alkoxyphenols
US4499314A (en) * 1982-03-31 1985-02-12 Imperial Chemical Industries Plc Methanol conversion to hydrocarbons with zeolites and cocatalysts
DE3216722A1 (de) * 1982-05-05 1983-11-10 Hoechst Ag, 6230 Frankfurt 4-halomethylbenzoesaeure-alkylester-imine und verfahren zu deren herstellung
GB2120249B (en) 1982-05-15 1985-11-27 British Petroleum Co Plc Process for the production of methyl or ethyl mono-halide
US4467133A (en) 1982-06-21 1984-08-21 Mobil Oil Corporation Conversion of alcohols and ethers to distillate range hydrocarbons
FR2529883A1 (fr) 1982-07-06 1984-01-13 Ugine Kuhlmann Procede de fabrication de chlorure de vinyle
US4440871A (en) 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4509955A (en) 1982-08-09 1985-04-09 The Lubrizol Corporation Combinations of carboxylic acylating agents substituted with olefin polymers of high and low molecular weight mono-olefins, derivatives thereof, and fuels and lubricants containing same
US4465884A (en) 1982-08-17 1984-08-14 Mobil Oil Corporation Olefin processing
US4814527A (en) 1982-10-18 1989-03-21 The Dow Chemical Company Catalytic process for ethylene dichloride
US4654449A (en) 1982-12-09 1987-03-31 Mobil Oil Corporation Formation of halogenated hydrocarbons from hydrocarbons
US4655893A (en) 1983-02-07 1987-04-07 Battelle Development Corporation Cubic boron nitride preparation utilizing a boron and nitrogen bearing gas
US4788377A (en) 1983-04-22 1988-11-29 Mobil Oil Corporation Process for manufacturing olefins
US4720600A (en) * 1983-06-29 1988-01-19 Mobil Oil Corporation Production of middle distillate range hydrocarbons by light olefin upgrading
US4547612A (en) 1984-09-25 1985-10-15 Mobil Oil Corporation Production of lubricant and/or heavy distillate range hydrocarbons by light olefin upgrading
US4675410A (en) 1983-07-11 1987-06-23 Nepera Inc. Process for the production of pyridine or alkyl substituted pyridines
US4540826A (en) 1983-08-12 1985-09-10 Phillips Petroleum Company Process for preparing olefinic aldehydes
CA1202610A (en) 1983-08-15 1986-04-01 Ralph M. Dessau Activity enhancement of high silica zeolites
DE3470527D1 (en) 1983-08-25 1988-05-26 Huels Chemische Werke Ag Process for the preparation of 3,3- or 2,3-dimethyl butene and 2,3- dimethyl butadiene or for the simultaneous preparation of these olefins and glycol or polyglycol-n-alkyl-3,3- or 2,3-dimethyl butyl ether from mono- and dichloro-dimethyl butane
US5175382A (en) 1983-09-22 1992-12-29 Werner Hebgen Preparation of 1,2-Dichloroethane
US4524227A (en) 1983-09-29 1985-06-18 Mobil Oil Corporation Coproduction of durene and gasoline from synthesis gas and alcohols and separation of durene-gasoline mixtures
US4524231A (en) 1983-09-29 1985-06-18 Mobil Oil Corporation Production of durene from alcohols and ethers
US4524228A (en) 1983-09-29 1985-06-18 Mobil Oil Corporation Production of durene and gasoline from synthesis gas
US4599474A (en) 1983-10-31 1986-07-08 Chevron Research Company Conversions of low molecular weight hydrocarbons to higher molecular weight hydrocarbons using a metal-containing catalyst
US4704488A (en) 1983-10-31 1987-11-03 Chevron Research Company Conversions of low molecular weight hydrocarbons to higher molecular weight hydrocarbons using a metal compound-containing catalyst (111-A)
US4709108A (en) 1983-10-31 1987-11-24 Chevron Research Company Conversions of low molecular weight hydrocarbons to higher molecular weight hydrocarbons using a metal compound-containing catalyst
US4704493A (en) 1983-10-31 1987-11-03 Chevron Corporation Conversions of low molecular weight hydrocarbons to higher molecular weight hydrocarbons using a metal compound-containing catalyst (II-A)
GB8331982D0 (en) 1983-11-30 1984-01-04 British Petroleum Co Plc Hydrocarbons from c1 to c4 alkyl monohalides
EP0150594B1 (en) 1983-12-16 1988-03-23 The British Petroleum Company p.l.c. Process for the production of hydrocarbons from hetero-substituted alkanes
JPS60136525A (ja) 1983-12-26 1985-07-20 Agency Of Ind Science & Technol エタノ−ルの製造法
US4513092A (en) 1984-01-04 1985-04-23 Mobil Oil Corporation Composite catalyst for halogenation and condensation of alkanes
US4621161A (en) 1984-01-23 1986-11-04 Mobil Oil Corporation Oxygenate conversion over activated zeolite catalyst
US4642404A (en) * 1984-01-23 1987-02-10 Mobil Oil Corporation Conversion of olefins and paraffins to higher hydrocarbons
US4550218A (en) 1984-03-05 1985-10-29 Mobil Oil Corporation Hydrocarbon synthesis with zeolite catalyst of improved hydrothermal stability
LU85285A1 (fr) 1984-04-03 1985-11-27 Labofina Sa Procede d'isomerisation d'olefines
US4634800A (en) * 1984-04-16 1987-01-06 Atlantic Richfield Company Methane conversion process
GB8410479D0 (en) 1984-04-24 1984-05-31 British Petroleum Co Plc Conversion process
US4497967A (en) * 1984-06-15 1985-02-05 The Halcon Sd Group, Inc. Process for the preparation of ethanol from methanol, carbon monoxide _and hydrogen
US4590310A (en) 1984-08-02 1986-05-20 The Boc Group, Inc. Process for the preparation of 2,2,2-trifluoroethanol
US4550217A (en) 1984-08-29 1985-10-29 Mobil Oil Corporation Conversion of methanol to olefins using large size catalyst particles
US4696985A (en) 1984-11-16 1987-09-29 Hercules Incorporated Catalyst composition for polymerization of cycloolefins
GB8429007D0 (en) * 1984-11-16 1984-12-27 British Petroleum Co Plc Aromatics from ethane/ethylene
US4579977A (en) 1984-12-20 1986-04-01 Phillips Petroleum Company Process for the oxidation of organic halides to organic aldehydes
US4764356A (en) * 1984-12-21 1988-08-16 Exxon Research & Engineering Co. Process for synthesizing a zeolite catalyst on a pH controlled basis to improve catalyst life
US4544781A (en) 1985-01-09 1985-10-01 Mobil Oil Corporation Control of temperature exotherms in the conversion of methanol to gasoline hydrocarbons
DE194931T1 (de) 1985-03-14 1987-02-26 Societe Nationale Elf Aquitaine (Production), Courbevoie, Fr Verfahren und vorrichtung zur photochemischen sulfochlorinierung von gasfoermigen alkanen.
US4658077A (en) 1985-06-07 1987-04-14 Phillips Petroleum Company Composition of matter and method of oxidative conversion of organic compounds therewith
US5210357A (en) 1985-06-07 1993-05-11 Phillips Petroleum Company Composition of matter and method of oxidative conversion of organic compounds therewith
JPS61242901A (ja) * 1985-04-17 1986-10-29 Toyo Soda Mfg Co Ltd 臭素回収用吸着剤及び臭素回収方法
US5093542A (en) 1985-05-24 1992-03-03 Atlantic Richfield Company Methane conversion process
US5959170A (en) 1985-05-24 1999-09-28 Atlantic Richfield Company Methane conversion process
US5146027A (en) 1985-05-24 1992-09-08 Atlantic Richfield Co. Methane conversion process
US5105045A (en) 1985-06-07 1992-04-14 Phillips Petroleum Company Method of oxidative conversion
US4774216A (en) 1985-06-07 1988-09-27 Phillips Petroleum Company Composition of matter for oxidative conversion of organic compounds
US4724275A (en) * 1985-07-01 1988-02-09 National Distillers And Chemical Corporation Crystalline aluminosilicates and their use in the conversion of methanol to low molecular weight hydrocarbons
GB8518820D0 (en) 1985-07-25 1985-08-29 British Petroleum Co Plc Chemical process
GB8520977D0 (en) 1985-08-21 1985-09-25 British Petroleum Co Plc Production of aromatics
US4795843A (en) * 1985-08-26 1989-01-03 Uop Inc. Conversion of methane into larger organic hydrocarbons
US4665259A (en) 1985-08-28 1987-05-12 The Standard Oil Company Methane conversion process using phosphate-containing catalysts
US4633027A (en) 1985-09-23 1986-12-30 Mobil Oil Corporation Process for converting olefins to gasoline, distillate and alkylate liquid hydrocarbons
US4658073A (en) 1985-09-23 1987-04-14 Mobil Oil Corporation Control system for multistage chemical upgrading
CA1322768C (en) 1988-12-29 1993-10-05 John E. Stauffer Process for the chlorination of ethane
US4788369A (en) 1985-12-31 1988-11-29 Mobil Oil Corporation Conversion of methanol to gasoline
LU86280A1 (fr) 1986-01-29 1987-09-03 Labofina Sa Procede de production d'essence
GB8613673D0 (en) 1986-06-05 1986-07-09 Bp Benzin Und Petroleum Ag Chemical process
ZA874948B (en) * 1986-07-07 1989-02-22 Mobil Oil Corp Aromatisation of aliphatics over gallium-containing zeolites
US4781733A (en) 1986-07-23 1988-11-01 Bend Research, Inc. Semipermeable thin-film membranes comprising siloxane, alkoxysilyl and aryloxysilyl oligomers and copolymers
US4814532A (en) 1986-08-04 1989-03-21 Chemical Company, Ltd. Asahi Process for producing alkylcyclopentadiene derivatives
US5082816A (en) * 1986-08-28 1992-01-21 The Standard Oil Company Lead-zirconate catalysts
US4795848A (en) * 1986-08-28 1989-01-03 The Standard Oil Company Method for upgrading a low molecular weight alkane with a lead-zirconate catalyst
US4720602A (en) * 1986-09-08 1988-01-19 Mobil Oil Corporation Process for converting C2 to C12 aliphatics to aromatics over a zinc-activated zeolite
US5120332A (en) 1986-11-06 1992-06-09 The Haser Company Limited Gas resonance device
US5160502A (en) 1986-12-22 1992-11-03 Phillips Petroleum Company Composition of matter and method of oxidative conversion of organic compounds therewith
US5118899A (en) 1986-12-22 1992-06-02 Phillips Petroleum Company Composition of matter and method of oxidative conversion of organic compounds therewith
US5087787A (en) * 1986-12-29 1992-02-11 Phillips Petroleum Company Method of oxidative conversion
DE3700132A1 (de) 1987-01-03 1988-07-14 Dow Chemical Gmbh Verfahren zum herstellen von ethylendichlorid
US4769504A (en) 1987-03-04 1988-09-06 The United States Of America As Represented By The United States Department Of Energy Process for converting light alkanes to higher hydrocarbons
US4792642A (en) 1987-03-25 1988-12-20 Eastman Kodak Company Process for preparing iodinated aromatic compounds
US4795737A (en) * 1987-03-25 1989-01-03 Eastman Kodak Company Process for the iodination of aromatic compounds over solid catalysts
US4886932A (en) 1987-03-30 1989-12-12 Atlantic Richfield Company Thin bed cofeed reaction system for methane conversion
CA1322769C (en) 1988-12-30 1993-10-05 John E. Stauffer Process for the chlorination of ethane
US4777321A (en) 1987-04-29 1988-10-11 Mobil Oil Corporation Feedstock preparation and conversion of oxygenates to olefins
US4775462A (en) 1987-06-22 1988-10-04 Uop Inc. Non-oxidative method of sweetening a sour hydrocarbon fraction
US4808763A (en) * 1987-08-05 1989-02-28 Amoco Corporation Process for upgrading light paraffins
US4804797A (en) * 1987-08-24 1989-02-14 Gas Research Institute Production of commodity chemicals from natural gas by methane chlorination
US4783566A (en) 1987-08-28 1988-11-08 Uop Inc. Hydrocarbon conversion process
GB8724373D0 (en) 1987-10-17 1987-11-18 British Petroleum Co Plc Chemical process
US5157189A (en) 1987-10-19 1992-10-20 Karra Sankaram B Conversion of light hydrocarbons to higher hydrocarbons
US4973786A (en) 1987-10-19 1990-11-27 Karra Sankaram B Process for the pyrolytic oxidation of methane to higher molecular weight hydrocarbons and synthesis gas
US4814535A (en) 1987-12-15 1989-03-21 Mobil Oil Corporation Conversion of oxygenates to gasoline at variable inlet temperature
US4814536A (en) 1987-12-15 1989-03-21 Mobil Oil Corporation Conversion of oxygenates to gasoline at variable space velocity
GB8802731D0 (en) 1988-02-06 1988-03-09 British Petroleum Co Plc Chemical process
JPH01212202A (ja) * 1988-02-17 1989-08-25 Mitsui Toatsu Chem Inc 塩素の工業的分離回収方法
US5254323A (en) * 1988-02-16 1993-10-19 Mitsui Toatsu Chemicals, Incorporated Industrial process for the separation and recovery of chlorine
CN1017414B (zh) * 1988-02-16 1992-07-15 三井东圧化学株式会社 分离回收氯的工业方法
US5059744A (en) 1988-03-03 1991-10-22 Mobil Oil Corporation Reactor and recovery system for upgrading lower olefins
GB8806675D0 (en) 1988-03-21 1988-04-20 Shell Int Research Process for preparing liquid hydrocarbons
US4851602A (en) 1988-04-11 1989-07-25 Mobil Oil Corporation Alkanes and alkenes conversion to high octane gasoline
US4851606A (en) 1988-04-25 1989-07-25 Mobil Oil Corporation Control of waste water chemical oxygen demand in an oxygenate to hydrocarbon conversion process
US4886925A (en) 1988-05-02 1989-12-12 Mobil Oil Corp Olefins interconversion and etherification process
JPH07106998B2 (ja) 1988-05-17 1995-11-15 ダイキン工業株式会社 １，１，１−トリフルオロ−２，２−ジクロロエタンの製造方法
US5013793A (en) 1990-07-26 1991-05-07 Exxon Chemical Patents Inc. Dynamically cured thermoplastic olefin polymers and process for producing the same
US4990711A (en) * 1988-06-23 1991-02-05 Mobil Oil Corporation Synthetic polyolefin lubricant blends having high viscosity indices
US4950822A (en) 1988-06-27 1990-08-21 Ethyl Corporation Olefin oligomer synlube process
US4899002A (en) * 1988-07-25 1990-02-06 Mobil Oil Corp. Integrated staged conversion of methanol to gasoline and distillate
FR2635101B1 (fr) 1988-08-05 1990-09-28 Rhone Poulenc Chimie Procede de preparation du trifluoroethanol par hydrolyse, en phase gazeuse, du chlorotrifluoroethane
US4939311A (en) 1988-08-17 1990-07-03 Amoco Corporation Catalysts for the oxidative conversion of methane to higher hydrocarbons
US5055633A (en) 1988-10-06 1991-10-08 Uop Adsorption and isomerization of normal and mono-methyl paraffins
US5055634A (en) 1988-10-06 1991-10-08 Uop Adsorption and isomerization of normal and mono-methyl paraffins
US4956521A (en) 1988-10-06 1990-09-11 Uop Adsorption and isomerization of normal and mono-methyl paraffins
US5215648A (en) 1988-10-20 1993-06-01 Chevron Research And Technology Company Hydrocarbon conversion processes using SSZ-31
US4899001A (en) * 1988-11-21 1990-02-06 Uop Process for the simultaneous hydroconversion of a first feedstock comprising unsaturated, halogenated organic compounds and a second feedstock comprising saturated, halogenated organic compounds
US5194244A (en) 1988-11-23 1993-03-16 Shell Oil Company Basic alkali metal-zeolite compositions
US4929781A (en) 1988-11-30 1990-05-29 Uop Process for the simultaneous hydroconversion of a first feedstock comprising unsaturated, halogenated organic compounds and a second feedstock comprising saturated, halogenated organic compounds
US4895995A (en) * 1988-12-02 1990-01-23 Uop Process for the simultaneous hydroconversion of a first feedstock comprising unsaturated, halogenated organic compounds and a second feedstock comprising saturated, halogenated organic compounds
US5034566A (en) 1988-12-07 1991-07-23 Sumitomo Chemical Company, Limited Process for the production of 2,3-dimethylbutenes
US5178748A (en) * 1988-12-22 1993-01-12 Imperial Chemical Industries Catalytic reactions using zeolites
CA1304419C (en) 1988-12-22 1992-06-30 Raj N. Pandey Conversion of methane to gasoline-range hydrocarbons via isobutene
GB8829923D0 (en) 1988-12-22 1989-02-15 Ici Plc Zeolites
US4990696A (en) * 1988-12-29 1991-02-05 Stauffer John E Methyl alcohol process
US4899000A (en) * 1989-01-27 1990-02-06 Stauffer John E Production of allyl chloride
US5436378A (en) 1989-02-16 1995-07-25 Atochem Drying of hydrocarbon/hydrochloric acid/water admixtures
US5107051A (en) 1989-03-14 1992-04-21 Exxon Chemical Patents Inc. Halogen resistant hydrotreating process and catalyst
US4945175A (en) 1989-05-26 1990-07-31 Uop Dehydrocyclodimerization process start-up procedure
US5202511A (en) 1989-08-16 1993-04-13 The Dow Chemical Company Catalyst diluent for oxychlorination process
US5071815A (en) 1989-09-01 1991-12-10 British Columbia Research Corporation Method for producing catalysts
AU6259890A (en) 1989-09-19 1991-03-28 Union Carbide Chemicals And Plastics Company Inc. Low temperature catalysts for oxidative coupling processes
US5073656A (en) 1989-09-19 1991-12-17 Union Carbide Chemicals And Plastics Company, Inc. High ethylene to ethane processes for oxidative coupling
EP0418974A1 (en) 1989-09-19 1991-03-27 Union Carbide Chemicals And Plastics Company, Inc. Silver-containing catalysts for oxidative coupling
US5073657A (en) 1989-09-19 1991-12-17 Union Carbide Chemicals And Plastics Company Inc. Vapor phase modifiers for oxidative coupling
DE3933656A1 (de) 1989-10-09 1991-04-11 Basf Ag Verdunstungsarme polyesterharze
US5302187A (en) * 1989-12-16 1994-04-12 Mitsui Toatsu Chemicals, Incorporated Concentration process of gaseous chlorine
US5026944A (en) 1989-12-20 1991-06-25 Energy Mines And Resources Canada Synthesis of isobutene from methane and acetylene
US4982024A (en) * 1989-12-26 1991-01-01 Ethyl Corporation Process for the selective dehydrohalogenation of an admixture of alkylhalides
US5004847A (en) 1989-12-27 1991-04-02 Ethyl Corporation Recovery of hexabromocyclododecane particles
US5026937A (en) 1989-12-29 1991-06-25 Uop Aromatization of methane using zeolite incorporated in a phosphorus-containing alumina
US4982041A (en) * 1990-01-10 1991-01-01 Union Carbide Chemicals And Plastics Company Inc. Double perovskite catalysts for oxidative coupling
US5026934A (en) 1990-02-12 1991-06-25 Lyondell Petrochemical Company Method for converting light hydrocarbons to olefins, gasoline and methanol
US5043502A (en) 1990-03-16 1991-08-27 Uop Production of xylenes from light aliphatic hydrocarbons via dehydrocyclodimerization and methylation
US5228888A (en) 1990-03-23 1993-07-20 The Boc Group, Inc. Economical air separator
US5107061A (en) 1990-04-06 1992-04-21 Exxon Chemical Patents Inc. Removal of organochlorides from hydrocarbon feed streams
US5087786A (en) * 1990-04-25 1992-02-11 Amoco Corporation Halogen-assisted conversion of lower alkanes
US5087779A (en) * 1990-04-25 1992-02-11 Amoco Corporation Hydrocarbon halogenation
US5001293A (en) 1990-04-25 1991-03-19 Amoco Corporation Halocarbon conversion
US5019652A (en) 1990-04-30 1991-05-28 The United States As Represented By The United States Department Of Energy Catalysts and method
US5139991A (en) 1990-04-30 1992-08-18 The United States Of American As Represented By The United States Department Of Energy Oxyhydrochlorination catalyst
US5068478A (en) 1990-05-25 1991-11-26 Energia Andina, Ltd. Producing alkenes and alkynes from alkanes and alkenes
GB9013859D0 (en) 1990-06-21 1990-08-15 Ici Plc Zeolites
GB9013916D0 (en) 1990-06-22 1990-08-15 Ici Plc Zeolites
US4988660A (en) * 1990-06-25 1991-01-29 Union Carbide Chemicals And Plastics Company Inc. Double perovskite catalysts for oxidative coupling
US5082473A (en) * 1990-07-23 1992-01-21 Keefer Bowie Extraction and concentration of a gas component
US5096469A (en) 1990-07-23 1992-03-17 Keefer Bowie Adsorptive gas separator with inertial energy exchange
US5401890A (en) 1990-07-30 1995-03-28 Albemarle Corporation Process and apparatus for heat treating halogenated compounds
US5013424A (en) 1990-07-30 1991-05-07 Uop Process for the simultaneous hydrogenation of a first feedstock comprising hydrocarbonaceous compounds and having a non-distillable component and a second feedstock comprising halogenated organic compounds
US5138112A (en) 1990-08-31 1992-08-11 Uop Process for converting a C2 -C6 aliphatic hydrocarbon to high octane transportable fuel
DE4029875A1 (de) 1990-09-21 1992-03-26 Hoechst Ag Verfahren zur inhibierung und zerstoerung von peroxiden in dialkylethern
JP2970683B2 (ja) 1990-10-12 1999-11-02 日石三菱株式会社 水素化脱アルキル触媒を用いた水素化脱アルキル法
US5085674A (en) * 1990-10-25 1992-02-04 Union Carbide Industrial Gases Technology Corporation Duplex adsorption process
US5071449A (en) 1990-11-19 1991-12-10 Air Products And Chemicals, Inc. Gas separation by rapid pressure swing adsorption
US5107032A (en) 1990-11-20 1992-04-21 Noramco, Inc. Process for the preparation of o-phthalaldehydes
KR100220114B1 (ko) * 1990-12-06 1999-09-01 퓨어를 리챠드 디. 에틸렌 또는 에틸렌과 비닐클로라이드와의 혼합물의 제조방법
US5223471A (en) 1990-12-12 1993-06-29 Amoco Corporation Fluorine-containing materials
US5055235A (en) 1990-12-12 1991-10-08 Ethyl Corporation Bromination process
US5105046A (en) 1990-12-12 1992-04-14 Amoco Corporation Oxidative conversion of lower alkanes to higher hydrocarbons via fluorine-containing materials
US5306855A (en) 1991-02-15 1994-04-26 Catalytica, Inc. Catalytic process for converting lower alkanes to esters, alcohols, and to hydrocarbons
US5233113A (en) 1991-02-15 1993-08-03 Catalytica, Inc. Process for converting lower alkanes to esters
GB9105167D0 (en) 1991-03-12 1991-04-24 Ici Plc Chemical process
US5188725A (en) * 1991-03-15 1993-02-23 Mobil Oil Corporation Fluidized catalyst process for production and etherification of olefins
US5237115A (en) 1991-03-15 1993-08-17 Phillips Petroleum Company Integrated olefin processing
FR2674769B1 (fr) 1991-04-04 1994-04-29 Inst Francais Du Petrole Catalyseur du type galloaluminosilicate contenant du gallium, un metal noble de la famille du platine et au moins un metal additionnel, et son utilisation en aromatisation des hydrocarbures.
EP0510238A1 (en) 1991-04-26 1992-10-28 NOVAMONT S.p.A. Process for producing lower poliols and mixtures thereof
US5288677A (en) 1991-06-28 1994-02-22 Exxon Chemical Patents Inc. Immobilized Lewis acid catalysts
GB9116172D0 (en) 1991-07-26 1991-09-11 Thames Water Utilities A method of and apparatus for treating a fluid
US5399258A (en) 1991-08-15 1995-03-21 Mobil Oil Corporation Hydrocarbon upgrading process
MY108348A (en) 1991-08-16 1996-09-30 Exxon Chemical Patents Inc Ester free ethers.
WO1993006037A1 (en) 1991-09-16 1993-04-01 Catalytica, Inc. Process and catalyst for producing bromine
US5264635A (en) 1991-10-03 1993-11-23 Mobil Oil Corporation Selective cracking and etherification of olefins
US5245109A (en) 1991-10-11 1993-09-14 Amoco Corporation Hydrocarbon conversion
US5276240A (en) * 1991-10-18 1994-01-04 Board Of Regents, The University Of Texas System Catalytic hydrodehalogenation of polyhalogenated hydrocarbons
JP3120292B2 (ja) 1991-10-18 2000-12-25 イハラケミカル工業株式会社 脂肪族カルボン酸ハロメチルエステル類の製造法
US5268518A (en) 1991-11-15 1993-12-07 The Dow Chemical Company Reactor feed pipe design
US5191142A (en) 1991-12-23 1993-03-02 Amoco Corporation Process for converting methanol to olefins or gasoline
JPH07503404A (ja) 1992-02-04 1995-04-13 カタリティカ，インコーポレイテッド ＣｅＢｒ↓３触媒，および臭素生成のプロセス
US6169218B1 (en) * 1992-02-10 2001-01-02 Catalytic Distillation Technologies Selective hydrogenation of highly unsaturated compounds in hydrocarbon streams
US5354916A (en) 1992-03-10 1994-10-11 Exxon Research And Engineering Company Low temperature conversion of alkanes
CA2088939A1 (en) 1992-03-10 1993-09-11 Istvan T. Horvath Low temperature conversion of alkanes
US5202506A (en) 1992-04-02 1993-04-13 E. I. Du Pont De Nemours And Company Oxidative drown process for 2-perfluoroalkylethyl alcohols
US5185479A (en) * 1992-04-21 1993-02-09 Stauffer John E Process for methyl alcohol
CA2097090A1 (en) 1992-06-02 1993-12-03 Quang N. Le Process for the production of tertiary alkyl ether rich fcc gasoline
US5395981A (en) 1992-06-22 1995-03-07 Uop Hydrocarbon conversion by catalytic distillation
US5254790A (en) 1992-07-01 1993-10-19 Phillips Petroleum Company Integrated process for producing motor fuels
US5284990A (en) * 1992-07-16 1994-02-08 Stratco, Inc. Method for converting a hydrogen fluoride alkylation unit to a sulfuric acid alkylation unit
US5276242A (en) * 1992-08-26 1994-01-04 Phillips Petroleum Company Alkylation process
US5243114A (en) 1992-09-08 1993-09-07 Mobil Oil Corporation Oligomerization of alpha-olefins over layered silicate compositions containing pillars of silica and group VIB metal oxide
US5430214A (en) 1992-10-01 1995-07-04 The Dow Chemical Company Hydrodehalogenation process and catalyst for use therein
IT1255710B (it) 1992-10-01 1995-11-10 Snam Progetti Procedimento integrato per produrre olefine da miscele gassose contenenti metano
US5453557A (en) 1992-10-01 1995-09-26 The Dow Chemical Company Processes for converting chlorinated byproducts and waste products to useful materials
US5276226A (en) * 1992-10-05 1994-01-04 Exxon Research & Engineering Company Low temperature halogenation of alkanes
US5300126A (en) 1992-10-19 1994-04-05 Mobil Oil Corporation Process for improving olefin etherification catalyst life
US5243098A (en) 1992-11-04 1993-09-07 Energia Andina Ltd. Conversion of methane to methanol
US5744669A (en) 1992-11-25 1998-04-28 Uop Process for the conversion of a halogenated organic stream containing trace quantities of organic nitrates
US5817904A (en) 1992-12-11 1998-10-06 Repsol Petroleo S.A. Method for the conversion of methane into longer chain hydrocarbons
TW291486B (zh) * 1992-12-17 1996-11-21 Exxon Chemical Patents Inc
US5470377A (en) * 1993-03-08 1995-11-28 Whitlock; David R. Separation of solutes in gaseous solvents
US5354931A (en) 1993-03-10 1994-10-11 Uop Process for hydrotreating an organic feedstock containing oxygen compounds and a halogen component
US5994604A (en) 1993-03-17 1999-11-30 Lockheed Martin Idaho Technologies Company Method and apparatus for low temperature destruction of halogenated hydrocarbons
GB9407257D0 (en) 1993-04-22 1994-06-08 Ici Plc Vaporisation of liquids
US5382743A (en) * 1993-04-26 1995-01-17 Mobil Oil Corporation Skeletal isomerization of n-pentenes using ZSM-35 in the presence of hydrogen
US5465699A (en) 1993-06-01 1995-11-14 Volkswagen Ag Intake pipe arrangement for an internal combustion engine having individual arc-shaped cylinder intake pipes
US5308383A (en) * 1993-06-21 1994-05-03 Occidental Chemical Corporation Method for separating chlorine from a mixture of gases
US5382704A (en) * 1993-06-30 1995-01-17 E. I. Du Pont De Nemours And Company Fluorinated methyl ethers
US5382744A (en) * 1993-07-12 1995-01-17 Phillips Petroleum Company Control of synthetic isopentane production during alkylation of amylenes
US5510525A (en) 1993-07-22 1996-04-23 Gas Research Institute Direct catalytic oxidative carbonylation of lower alkanes to acids
IT1265051B1 (it) 1993-08-06 1996-10-28 Eniricerche Spa Processo per l'alchilazione di idrocarburi alifatici con olefine
US5500297A (en) 1993-08-09 1996-03-19 The Trustees Of Princeton University Electron acceptor compositions technical field
US5376164A (en) * 1993-08-09 1994-12-27 Uop Pressure swing adsorption process for chlorine plant offgas
US5695890A (en) 1993-08-09 1997-12-09 The Trustees Of Princeton University Heterolamellar photoelectrochemical films and devices
US5906892A (en) * 1993-08-09 1999-05-25 The Trustees Of Princeton University Electron acceptor compositions on polymer templates
US5430210A (en) 1993-08-27 1995-07-04 Mobil Oil Corporation Selective hydrogen combustion processes
GB9318505D0 (en) 1993-09-07 1993-10-20 Evc Tech Ag By-product recycling in oxychlorination process
GB9318507D0 (en) 1993-09-07 1993-10-20 Evc Tech Ag Vinyl chloride production process
US5371313A (en) 1993-11-24 1994-12-06 Polysar Rubber Corporation Purification of hydrocarbon streams
US5600045A (en) * 1993-12-02 1997-02-04 The Dow Chemical Company Process for conversion of crude hydrocarbon mixtures
US5414173A (en) 1993-12-22 1995-05-09 The Dow Chemical Company Process of preparing cyclopentadiene and substituted derivatives thereof
GB9400569D0 (en) 1994-01-13 1994-03-09 Rhone Poulenc Chemicals Process for the production of substituted aromatic hydrocarbons from corresponding anilines by dediazoniation
DE69514333T2 (de) 1994-02-18 2000-10-12 Chevron Chem Co Zeolith ssz-42
US5565092A (en) 1994-03-16 1996-10-15 Exxon Chemical Patents Inc. Halogen resistant hydrogenation process and catalyst
US5780703A (en) 1994-05-02 1998-07-14 Mobil Oil Corporation Process for producing low aromatic diesel fuel with high cetane index
US5565616A (en) 1994-05-09 1996-10-15 Board Of Regents, The University Of Texas System Controlled hydrothermal processing
US5444168A (en) 1994-05-16 1995-08-22 Mobil Oil Corporation Process for the production of symmetrical ethers from secondary alcohols
US5401894A (en) 1994-06-07 1995-03-28 Uop Process for the treatment of halogenated organic feedstocks
US5591421A (en) 1994-07-11 1997-01-07 Chevron U.S.A. Inc. Zeolite SSZ-41
US5523503A (en) 1994-07-13 1996-06-04 Uop Cocurrent simulated moving bed hydrocarbon alkylation process
GB9414972D0 (en) 1994-07-26 1994-09-14 Bnfl Fluorchem Ltd Halogenation reactions
US5661097A (en) 1994-08-12 1997-08-26 The Dow Chemical Company Supported olefin polymerization catalyst
US6015867A (en) * 1994-09-28 2000-01-18 Showa Denko K.K. 3-alkoxypropionic ester derivative, olefin polymerization catalyst, and process for preparation of polyolefin
US6117371A (en) 1994-10-05 2000-09-12 Great Lakes Chemical Corporation Continuous bromination process and products thereof
EP0784648B2 (en) 1994-10-05 2010-10-27 Great Lakes Chemical Corporation Continuous bromination process and products thereof
GB2294262B (en) * 1994-10-20 1998-07-08 Evc Tech Ag Single stage fixed bed oxychlorination of ethylene
CA2203115C (en) 1994-10-20 2006-09-19 Pierluigi Fatutto Single stage fixed bed oxychlorination of ethylene
US5489727A (en) * 1994-10-28 1996-02-06 Phillips Petroleum Company Isopentane disproportionation
US5693191A (en) 1994-11-23 1997-12-02 The Dow Chemical Company Process for recovery of anhydrous hydrogen chloride from mixtures with non-condensable gases
US5821394A (en) 1994-11-24 1998-10-13 Solvay Process for converting a chlorinated alkane into a less chlorinated alkene
US5486627A (en) * 1994-12-02 1996-01-23 The Dow Chemical Company Method for producing epoxides
US5639930A (en) 1995-01-04 1997-06-17 Penick; Joe E. Process of producing alkylates
DK171707B1 (da) 1995-02-03 1997-04-01 Topsoe Haldor As Fremgangsmåde til fremstilling af dimetylæter i brændstofkvalitet
US5905169A (en) 1995-03-20 1999-05-18 E. I. Du Pont De Nemours And Company Process for producing polyfluoroacyl compositions
US5600043A (en) * 1995-03-27 1997-02-04 The Geon Company Oxychlorination process
EP0821579B1 (en) 1995-04-21 2001-08-29 The Procter & Gamble Company Shampoos with insoluble silicone conditioning agent and cationic polymer
FR2734172B1 (fr) 1995-05-19 1997-06-20 Air Liquide Dispositif et procede de separation de gaz par adsorption
DE19520612A1 (de) 1995-06-06 1996-12-12 Bayer Ag Verfahren zur Herstellung von Benzylalkohol
US5847224A (en) 1995-06-23 1998-12-08 Global Octanes Corporation Method for improving the color of MTBE, ETBE and TAME
FR2736911A1 (fr) 1995-07-20 1997-01-24 Inst Francais Du Petrole Catalyseur liquide d'alkylation aliphatique
US5977402A (en) 1995-07-20 1999-11-02 Sumitomo Chemical Company, Limited Processes for preparing 4-tert.-butylcyclohexanol and 4-tert.-butylcyclohexyl acetate
US5675052A (en) 1995-09-15 1997-10-07 The Boc Group, Inc. Hydrocarbon alkylation process
US5705712A (en) * 1995-10-05 1998-01-06 Uop Integrated process for producing diisopropyl ether, an isopropyl tertiary alkyl ether and isopropyl alcohol
US5705729A (en) * 1995-11-22 1998-01-06 Mobil Oil Corporation Isoparaffin-olefin alkylation process
FR2743079B1 (fr) 1995-12-27 1998-02-06 Inst Francais Du Petrole Procede et dispositif d'hydrogenation selective par distillation catalytique comportant une zone reactionnelle a co-courant ascendant liquide-gaz
DE19548876A1 (de) 1995-12-27 1997-07-03 Bayer Ag Verfahren zur kontinuierlichen Herstellung von Benzylalkohol
FR2743510B1 (fr) 1996-01-11 1998-04-03 Total Raffinage Distribution Nouveau catalyseur d'alkylation, son procede de preparation et son utilisation dans des procedes d'alkylation
US5788243A (en) * 1996-01-23 1998-08-04 Harshaw; Bob F. Biodegradable target
US6090312A (en) 1996-01-31 2000-07-18 Ziaka; Zoe D. Reactor-membrane permeator process for hydrocarbon reforming and water gas-shift reactions
AU692723B2 (en) * 1996-02-01 1998-06-11 Phillips Petroleum Company Catalyst composition and process for selecting hydrogenation of diolefins
US6096933A (en) 1996-02-01 2000-08-01 Phillips Petroleum Company Hydrocarbon hydrogenation and catalyst therefor
DE19603901A1 (de) 1996-02-03 1997-08-07 Krupp Uhde Gmbh Verfahren zur Gewinnung von Reinaromaten aus Reformatbenzin und Vorrichtung zur Durchführung des Verfahrens
SE517561C2 (sv) 1996-03-04 2002-06-18 Aga Ab Förfarande och anordning för framställning av en gas genom separation från en gasblandning
US5663474A (en) 1996-03-07 1997-09-02 Alliedsignal Inc. Alkylation process using hydrogen fluoride-containing alkylation catalysts
US5684213A (en) 1996-03-25 1997-11-04 Chemical Research & Licensing Company Method for the preparation of dialkyl ethers
US5675046A (en) 1996-04-10 1997-10-07 Showa Denko K.K. Process for producing perfluorocarbon
US5898086A (en) 1996-04-19 1999-04-27 Henkel Corporation Process for making alkyl ether glycerols
US6191324B1 (en) 1996-04-24 2001-02-20 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing unsaturated alcohols
USRE38493E1 (en) 1996-04-24 2004-04-13 Questair Technologies Inc. Flow regulated pressure swing adsorption system
CN1078194C (zh) 1996-05-29 2002-01-23 埃克森美孚化学专利公司 从脂族烃制备芳族化合物的方法
AU3232997A (en) 1996-06-07 1998-01-05 Chevron U.S.A. Inc. Zeolite me-utd-1
US5720858A (en) * 1996-07-17 1998-02-24 The United States Of America As Represented By The United States Department Of Energy Method for the photocatalytic conversion of methane
US5708246A (en) * 1996-08-28 1998-01-13 Battelle Memorial Institute Method of photocatalytic conversion of C-H organics
HU220573B1 (hu) 1996-11-18 2002-03-28 AGRO-CHEMIE Növényvédőszer Gyártó, Értékesítő és Forgalmazó Kft. Eljárás benzil-éterek előállítására
CA2273333C (en) 1996-11-27 2007-05-01 Akzo Nobel Nv Process for alkylating hydrocarbons
US5895831A (en) 1996-12-04 1999-04-20 Uop Llc Solid catalyst alkylation process
US7182871B2 (en) 1996-12-17 2007-02-27 Global Biosciences, Inc. Wastewater treatment with alkanes
US6669846B2 (en) 1996-12-17 2003-12-30 Global Biosciences, Inc. Wastewater treatment with alkanes
US5952538A (en) 1996-12-31 1999-09-14 Exxon Chemical Patents Inc. Use of short contact time in oxygenate conversion
EP0973708A1 (de) 1997-03-07 2000-01-26 Basf Aktiengesellschaft Verbessertes verfahren zur herstellung von cyclopropylacetylen
SG74047A1 (en) 1997-04-30 2000-07-18 Mitsubishi Chem Corp Process for producing alkylene glycol
US6018088A (en) * 1997-05-07 2000-01-25 Olah; George A. Superacid catalyzed formylation-rearrangement of saturated hydrocarbons
DE19721301C1 (de) 1997-05-21 1998-10-01 Basf Ag Verfahren zur Hydrolyse von Alkylmonohalogeniden
US6056804A (en) 1997-06-30 2000-05-02 Questor Industries Inc. High frequency rotary pressure swing adsorption apparatus
EP1004143B1 (en) 1997-07-11 2012-09-05 University of Southern California Charge generators in heterolamellar multilayer thin films
US5856584A (en) 1997-08-06 1999-01-05 The Nutrasweet Company Preparation of 3,3-dimethylbutyraldehyde by oxidation of 3, 3-dimethylbutanol
DK128697A (da) 1997-11-12 1999-05-13 Niels J Bjerrum Katalyseproces
DE19755636A1 (de) 1997-12-15 1999-06-17 Bayer Ag Verfahren zur elektrochemischen Aufarbeitung von HCl-Gas zu hochreinem Chlor
FR2773496B1 (fr) 1998-01-14 2000-03-03 Inst Francais Du Petrole Procede de separation par decantation dans plusieurs zones distinctes
US5968236A (en) 1998-02-20 1999-10-19 Bassine; Stuart Valve free oxygen concentrator
US6187983B1 (en) * 1998-04-29 2001-02-13 Exxon Chemical Patents Inc Converting oxygenates to olefins in the presence of electromagnetic energy
US5998679A (en) 1998-05-20 1999-12-07 Jlm Technology, Ltd. Methods for converting lower alkanes and alkanes to alcohols and diols
US5983476A (en) 1998-06-09 1999-11-16 Uop Llc Conversion of an HF alkylation unit
US6096932A (en) 1999-07-27 2000-08-01 E. I. Du Pont De Nemours And Company Fluorocarbon manufacturing process
EP0976705A1 (en) 1998-07-30 2000-02-02 Ube Industries, Ltd. Method of producing a phenolalkylether compound
IT1302003B1 (it) 1998-08-05 2000-07-20 Enitecnologie Spa Procedimento per la trasformazione selettiva di idrocarburi.
US6087294A (en) 1998-08-12 2000-07-11 Kansas State University Research Foundation Dispersion and stabilization of reactive atoms on the surface of metal oxides
FR2782280B1 (fr) 1998-08-12 2000-09-22 Inst Francais Du Petrole Catalyseurs supportes utilisables dans des reactions de transformation de composes organiques
US6921597B2 (en) 1998-09-14 2005-07-26 Questair Technologies Inc. Electrical current generation system
US6903171B2 (en) 1998-10-05 2005-06-07 Promerus, Llc Polymerized cycloolefins using transition metal catalyst and end products thereof
AU6291999A (en) 1998-10-05 2000-04-26 B.F. Goodrich Company, The Catalyst and methods for polymerizing cycloolefins
US6528693B1 (en) 1998-10-12 2003-03-04 Great Lakes (Uk) Limited Preparation of cyclopropylethyne and intermediates for preparation of cyclopropylethyne
US6127588A (en) 1998-10-21 2000-10-03 Phillips Petroleum Company Hydrocarbon hydrogenation catalyst and process
US6002059A (en) 1998-10-28 1999-12-14 Mobil Oil Corporation Process for upgrading natural gas
DE69907849T2 (de) * 1998-11-02 2003-12-24 Inst Francais Du Petrole Verfahren zur Herstellung eines Zeoliths des EUO-Typs mittels zeolithischen Keimen und dessen Verwendung als Isomerisierungskatalysator von Aromaten mit acht Kohlenstoffatomen
EP0999183B1 (fr) * 1998-11-02 2003-06-18 Institut Francais Du Petrole Procédé de préparation d'une zéolithe de type structural EUO a l'aide de precurseurs du structurant et son utilisation comme catalyseur d'isomerisation des AC8
US6130260A (en) 1998-11-25 2000-10-10 The Texas A&M University Systems Method for converting natural gas to liquid hydrocarbons
US6936565B2 (en) * 1999-01-12 2005-08-30 Hyperion Catalysis International, Inc. Modified carbide and oxycarbide containing catalysts and methods of making and using thereof
US6239057B1 (en) 1999-01-15 2001-05-29 Uop Llc Catalyst for the conversion of low carbon number aliphatic hydrocarbons to higher carbon number hydrocarbons, process for preparing the catalyst and process using the catalyst
US6114593A (en) * 1999-01-27 2000-09-05 Phillips Petroleum Company Method for reducing organic fluoride levels in hydrocarbons
AU3601900A (en) 1999-02-22 2000-09-04 Symyx Technologies, Inc. Compositions comprising nickel and their use as catalyst in oxidative dehydrogenation of alkanes
US6143939A (en) 1999-02-26 2000-11-07 The United States Of America As Represented By The United States Department Of Energy Method of dehalogenation using diamonds
US7220391B1 (en) 1999-03-25 2007-05-22 University Of Central Florida Research Foundation, Inc. UV photochemical option for closed cycle decomposition of hydrogen sulfide
US6248218B1 (en) 1999-03-25 2001-06-19 Clovis A. Linkous Closed cycle photocatalytic process for decomposition of hydrogen sulfide to its constituent elements
US7273957B2 (en) 1999-05-04 2007-09-25 Catalytic Distillation Technologies Process for the production of gasoline stocks
US6545192B2 (en) 1999-05-11 2003-04-08 Shell Oil Company Process for separating olefins from saturated hydrocarbons
FR2793706B1 (fr) * 1999-05-18 2001-08-03 Total Raffinage Distribution Support catalytique a base d'oxyde d'un metal du groupe ivb de la classification periodique des elements, sa preparation et ses utilisations
US6444223B1 (en) 1999-05-28 2002-09-03 Alkermes Controlled Therapeutics, Inc. Method of producing submicron particles of a labile agent and use thereof
US6727400B2 (en) 1999-06-08 2004-04-27 Triosyn Holdings, Inc. Deactivation of toxic chemical agents
AU5381200A (en) 1999-06-09 2001-01-02 Questair Technologies, Inc. Rotary pressure swing adsorption apparatus
US6248931B1 (en) 1999-06-30 2001-06-19 Uop Llc Membrane process for the recovery of halides from hydrocarbon-containing streams
SE520971C2 (sv) 1999-08-20 2003-09-16 Perstorp Ab Förfarande för tillverkning av en eteralkohol
US6309453B1 (en) 1999-09-20 2001-10-30 Xerox Corporation Colorless compounds, solid inks, and printing methods
FR2798922B1 (fr) 1999-09-29 2001-12-14 Inst Francais Du Petrole Procede de preparation d'une zeolithe de type structural mtt utilisant des germes de materiaux zeolithiques
FR2798923B1 (fr) 1999-09-29 2001-12-14 Inst Francais Du Petrole Procede de preparation d'une zeolithe de type structural mtt utilisant des precurseurs specifiques du structurant
US20020102672A1 (en) 1999-10-04 2002-08-01 Joseph Mizrahi Process for producing a purified lactic acid solution
DE19949211A1 (de) 1999-10-13 2001-05-31 Veba Oel Ag Verfahren zur Herstellung von n-Alkanen aus Mineralölfraktionen und Katalysator zur Durchführung des Verfahrens
US6372949B1 (en) 1999-10-15 2002-04-16 Mobil Oil Corporation Single stage process for converting oxygenates to gasoline and distillate in the presence of undimensional ten member ring zeolite
US6380328B1 (en) 1999-12-10 2002-04-30 Univation Technologies, Llc Catalyst systems and their use in a polymerization process
US6265505B1 (en) 1999-11-18 2001-07-24 Univation Technologies, Llc Catalyst system and its use in a polymerization process
US6518474B1 (en) 1999-10-29 2003-02-11 Huntsman International Llc Process for producing isobutylene from tertiary butyl alcohol
CN1623659B (zh) 1999-11-22 2010-05-05 陶氏环球技术公司 将乙烯转化成氯乙烯的生产方法中使用的新催化剂组合物
US6909024B1 (en) 1999-11-22 2005-06-21 The Dow Chemical Company Process for the conversion of ethylene to vinyl chloride and novel catalyst compositions useful for such process
US6797845B1 (en) 1999-11-22 2004-09-28 Dow Global Technologies Inc. Process for vinyl chloride manufacture from ethane and ethylene with immediate HCl recovery from reactor effluent
US6680415B1 (en) 1999-11-22 2004-01-20 Dow Global Technologies Inc. Oxyhalogenation process using catalyst having porous rare earth halide support
US6933417B1 (en) 1999-11-22 2005-08-23 Dow Global Technologies Inc. Process for vinyl chloride manufacture from ethane and ethylene with partial CHl recovery from reactor effluent
US6514319B2 (en) 1999-12-09 2003-02-04 Questair Technologies Inc. Life support oxygen concentrator
KR100715637B1 (ko) 1999-12-14 2007-05-08 다이셀 가가꾸 고교 가부시끼가이샤 케톤, 알코올 및 하이드로과산화물의 제조 방법
US6956140B2 (en) 1999-12-14 2005-10-18 Halocarbon Products Corporation Hydrothermal hydrolysis of halogenated compounds
US6376731B1 (en) 2000-01-14 2002-04-23 Arco Chemical Technology, L.P. Selective olefin oligomerization
KR100744982B1 (ko) 2000-02-02 2007-08-02 다이낑 고오교 가부시키가이샤 수소함유 플루오르화 탄화수소의 제조방법
IT1317757B1 (it) 2000-02-03 2003-07-15 Enitecnologie Spa Metodo per la preparazione di idrocarburi idrogenati.
FR2805255B1 (fr) 2000-02-21 2002-04-12 Inst Francais Du Petrole Zeolithe mtt comprenant des cristaux et des agregats de cristaux de granulometries specifiques et son utilisation comme catalyseur d'isomerisation des paraffines lineaires
US6566572B2 (en) 2000-03-06 2003-05-20 Wako Pure Chemical Industries, Ltd. Process for producing 9,10-diphenylanthracene
US6475463B1 (en) 2000-03-07 2002-11-05 Chevron U.S.A. Inc. Zeolite SSZ-55
US6710213B2 (en) 2000-03-31 2004-03-23 Showa Denko K.K. Production process and use for propargyl alcohol and its intermediate
US6395945B1 (en) 2000-03-31 2002-05-28 Phillips Petroleum Company Integrated hydroisomerization alkylation process
CA2306311C (en) 2000-04-20 2007-04-10 Quest Air Gases Inc. Absorbent laminate structures
US6472345B2 (en) 2000-05-03 2002-10-29 Solvias Ag Catalytic halogenation of activated methylene and methine compounds
ATE374731T1 (de) * 2000-05-31 2007-10-15 Chevron Usa Inc Zeolith ssz-53
FR2812301B1 (fr) 2000-07-26 2003-04-04 Inst Francais Du Petrole Procede flexible de production de bases huiles et de distillats moyens a partir de charge contenant des heteroatomes
IT1318680B1 (it) 2000-08-11 2003-08-27 Enichem Spa Processo per la produzione in continuo di ossidi olefinici.
IT1318682B1 (it) 2000-08-11 2003-08-27 Enichem Spa Procedimento integrato per la preparazione di ossidi olefinici.
US6495484B1 (en) 2000-08-28 2002-12-17 Univation Technologies, Llc Catalyst system and its use in a polymerization process
EP1315689A1 (en) 2000-09-07 2003-06-04 Wisconsin Alumni Research Foundation Synthesis of 17f labeled fluoroalkanes
FR2813809B1 (fr) * 2000-09-11 2003-07-25 Air Liquide Colonne a garnissage d'echange de chaleur et/ou de matiere
US6518476B1 (en) 2000-09-18 2003-02-11 Union Carbide Chemicals & Plastics Technology Corporation Methods for manufacturing olefins from lower alkans by oxidative dehydrogenation
ZA200108461B (en) 2000-10-27 2002-06-06 Celanese Chem Europe Gmbh Process of telomerizing conjugated dienes.
US6552241B1 (en) 2000-10-31 2003-04-22 Conocophillips Company Alkylation process
CN1173905C (zh) * 2000-11-29 2004-11-03 芬诺利特技术两合公司 提纯1,2-二氯乙烷的方法
WO2002045821A2 (en) 2000-12-08 2002-06-13 Questair Technologies Inc. Methods and apparatuses for gas separation by pressure swing adsorption with partial gas product feed to fuel cell power source
CA2329475A1 (en) 2000-12-11 2002-06-11 Andrea Gibbs Fast cycle psa with adsorbents sensitive to atmospheric humidity
FR2818284B1 (fr) 2000-12-15 2006-08-04 Inst Francais Du Petrole Procede flexible ameliore de production de bases huiles et distillats moyens avec une conversion-hydroisomerisation suivie d'un deparaffinage catalytique
US6511526B2 (en) 2001-01-12 2003-01-28 Vbox, Incorporated Pressure swing adsorption gas separation method and apparatus
US6538162B2 (en) 2001-01-30 2003-03-25 Exxonmobil Chemical Patents Inc. Method for converting alkanes to oxygenates
US6509485B2 (en) * 2001-02-22 2003-01-21 Sri International Preparation of epoxides from alkanes using lanthanide-promoted silver catalysts
KR100519140B1 (ko) 2001-02-23 2005-10-04 쇼와 덴코 가부시키가이샤 퍼플루오로탄소의 제조방법 및 그 용도
US20030196680A1 (en) * 2002-04-19 2003-10-23 Dielectric Systems, Inc Process modules for transport polymerization of low epsilon thin films
US7230150B2 (en) 2001-04-18 2007-06-12 Grt, Inc. Zone reactor
US6472572B1 (en) 2001-06-20 2002-10-29 Grt, Inc. Integrated process for synthesizing alcohols and ethers from alkanes
US7019182B2 (en) 2001-04-18 2006-03-28 Grt, Inc. Method of hydrocarbon preservation and environmental protection
US6525230B2 (en) 2001-04-18 2003-02-25 Grt, Inc. Zone reactor
US6452058B1 (en) 2001-05-21 2002-09-17 Dow Global Technologies Inc. Oxidative halogenation of C1 hydrocarbons to halogenated C1 hydrocarbons and integrated processes related thereto
US20050027084A1 (en) 2001-05-23 2005-02-03 Clarke William D. Production of vinyl halide from single carbon feedstocks
US6984763B2 (en) 2001-05-23 2006-01-10 Dow Global Technologies Inc. Oxidative halogenation and optional dehydrogenation of c3+hydrocarbons
CN1511128A (zh) 2001-05-23 2004-07-07 陶氏环球技术公司 采用空气进料从乙烷和乙烯的氯乙烯制造方法和可选的HCl处理方法
ES2536971T3 (es) 2001-06-08 2015-06-01 Albemarle Netherlands B.V. Procedimiento continuo para la alquilación de hidrocarburos
US7001872B2 (en) 2001-06-11 2006-02-21 Halliburton Energy Services, Inc. Subterranean formation treating fluid and methods of fracturing subterranean formations
US20030078456A1 (en) 2001-06-20 2003-04-24 Aysen Yilmaz Integrated process for synthesizing alcohols, ethers, aldehydes, and olefins from alkanes
US7161050B2 (en) 2001-06-20 2007-01-09 Grt, Inc. Method and apparatus for synthesizing olefins, alcohols, ethers, and aldehydes
US6486368B1 (en) 2001-06-20 2002-11-26 Grt, Inc. Integrated process for synthesizing alcohols, ethers, and olefins from alkanes
US20050192468A1 (en) 2001-06-20 2005-09-01 Sherman Jeffrey H. Hydrocarbon conversion process improvements
US6465699B1 (en) 2001-06-20 2002-10-15 Gri, Inc. Integrated process for synthesizing alcohols, ethers, and olefins from alkanes
US20030069452A1 (en) 2001-06-20 2003-04-10 Sherman Jeffrey H. Method and apparatus for synthesizing from alcohols and ethers from alkanes, alkenes, and aromatics
US6440894B1 (en) 2001-06-25 2002-08-27 Exxonmobil Chemical Patents, Inc. Methods of removing halogen from non-zeolitic molecular sieve catalysts
US6518471B1 (en) 2001-06-25 2003-02-11 Exxonmobil Chemical Patents Inc. Selective production of meta-diisopropylbenzene
CN100496706C (zh) 2001-06-28 2009-06-10 霍尼韦尔国际公司 氟化催化剂的制备方法
US20030065239A1 (en) 2001-06-29 2003-04-03 Peter Zhu Non-hazardous basic neutralization of aldehydes
US6646102B2 (en) 2001-07-05 2003-11-11 Dow Global Technologies Inc. Process for manufacturing an alpha-dihydroxy derivative and epoxy resins prepared therefrom
US6540905B1 (en) 2001-07-13 2003-04-01 Chevron U.S.A. Inc. Hydrocarbon conversion using zeolite SSZ-58
US6616830B2 (en) 2001-07-13 2003-09-09 Chevron U.S.A. Inc. Hydrocarbon conversion using zeolite SSZ-57
US6547958B1 (en) 2001-07-13 2003-04-15 Chevron U.S.A. Inc. Hydrocarbon conversion using zeolite SSZ-59
US6867302B2 (en) 2001-07-13 2005-03-15 Board Of Trustees Of Michigan State University Process for the catalytic synthesis of biaryls and polymers from aryl compounds
US7094936B1 (en) 2001-07-20 2006-08-22 Great Lakes Chemical Corporation Process for preparing halogenated alkanes
FR2828193B1 (fr) 2001-08-03 2004-04-02 Atofina Nouveau procede de preparation du 1,1,1,-trifluoro-2,2-dichloroethane
EP1414777A1 (en) 2001-08-03 2004-05-06 Eastman Chemical Company Vapor phase carbonylation process using iridium-gold co-catalysts
US6858770B2 (en) 2001-08-21 2005-02-22 Catalytic Distillation Technologies Paraffin alkylation
US6797851B2 (en) 2001-08-30 2004-09-28 Exxonmobil Chemical Patents Inc. Two catalyst process for making olefin
US6632971B2 (en) 2001-08-30 2003-10-14 Exxonmobil Chemical Patents Inc. Process for converting natural gas to higher value products using a methanol refinery remote from the natural gas source
US6552238B1 (en) 2001-08-31 2003-04-22 Vulcan Chemicals Separation of heavy ends from streams of halogenated alkanes
WO2003022827A1 (en) 2001-09-11 2003-03-20 Grt, Inc. Process for synthesizing olefin oxides
EP1426351B1 (en) 2001-09-14 2013-06-19 Tosoh F-Tech, Inc. Process for preparation of 2,2,2-trifluoroethanol
JP4014856B2 (ja) 2001-11-14 2007-11-28 株式会社トクヤマ ジハロゲン化アダマンタンの製造方法
EP1448788A4 (en) 2001-11-19 2006-03-29 Merck & Co Inc SYNTHESIS PROCESS FOR (R) -1- (3,5-BIS (TRIFLUOROMETHYL) -PHENYL) ETHAN-1-OL AND ITS ESTER WITH DYNAMIC-KINETIC RESOLUTION
ZA200209011B (en) 2001-11-20 2003-05-26 Rohm & Haas Electroactive catalysis.
DE10159615A1 (de) 2001-12-05 2003-06-12 Basf Ag Verfahren zur Herstellung von 1,2-Dichlorethan
US6897338B2 (en) 2001-12-18 2005-05-24 Metabolix, Inc. Methods of making intermediates from polyhydroxyalkanoates
US7199255B2 (en) 2001-12-18 2007-04-03 Univation Technologies, Llc Imino-amide catalysts for olefin polymerization
CN1271020C (zh) 2002-01-24 2006-08-23 Grt公司 由烷烃合成醇、醚和烯烃的综合工艺
CN1301210C (zh) 2002-01-25 2007-02-21 科学与工业技术研究委员会 非危险溴化试剂的制备
US7091270B2 (en) 2002-01-31 2006-08-15 Bromine Compounds Ltd. Pentabromobenzyl alkyl ethers and their use as fire retardants
US6770789B2 (en) 2002-03-13 2004-08-03 University Of Florida Research Foundation Process for trifluoromethylation of sulfates
CA2477262A1 (en) 2002-03-14 2003-09-18 Questair Technologies Inc. Gas separation by combined pressure swing and displacement purge
US20040152929A1 (en) 2002-05-08 2004-08-05 Clarke William D Process for vinyl chloride manufacture from ethane and ethylene with air feed and alternative hcl processing methods
CN1310851C (zh) 2002-05-10 2007-04-18 威斯康星旧生研究基金会 由氧化烃低温生产烃
US6545191B1 (en) 2002-06-13 2003-04-08 John E. Stauffer Process for preparing ethanol
EP1386664B1 (en) 2002-07-31 2016-05-11 Ineos Technologies (Vinyls) Limited A hollow parallelepiped pellet suitable as carrier of catalysts for selective exothermic reactions
US6946566B2 (en) 2002-07-31 2005-09-20 Daiso Co., Ltd. Process for preparation of optically active halogeno hydroxypropyl compound and glycidyl compound
US7238846B2 (en) 2002-08-14 2007-07-03 Exxonmobil Chemical Patents Inc. Conversion process
US6831032B2 (en) 2002-08-19 2004-12-14 Novolen Technology Holdings C.V. Ziegler-Natta catalyst and methods of making and using same
WO2004018093A2 (en) 2002-08-22 2004-03-04 E.I. Du Pont De Nemours And Company Cobalt-substituted chromium oxide compositions, their preparation, and their use as catalysts and catalyst precursors
US6753390B2 (en) 2002-09-04 2004-06-22 Univation Technologies, Llc Gas phase polymerization process
DE10242223A1 (de) 2002-09-12 2004-03-25 Clariant Gmbh Verfahren zur Hydrodechlorierung von kernchlorierten ortho-Xylolen
US6740146B2 (en) 2002-09-12 2004-05-25 Edward L. Simonds Oxygen concentrator
KR100531128B1 (ko) 2002-09-26 2005-11-28 한국화학연구원 분리막 반응기를 이용한 디메틸에테르의 제조방법
FR2845077A1 (fr) 2002-09-26 2004-04-02 Atofina Procede d'abaissement de la teneur en matieres organiques et produits azotes contenus dans des effluents bromures
US6852896B2 (en) 2002-10-11 2005-02-08 John E. Stauffer Concerted process for the production of an alkenyl substituted aromatic compound
US6869903B2 (en) 2002-11-07 2005-03-22 Univation Technologies, Llc Synthesis of polymerization catalyst components
US7060865B2 (en) 2002-11-12 2006-06-13 Exxonmobil Chemical Patents Inc. Recovery of C4 olefins from a product stream comprising C4 olefins, dimethyl ether and C5+ hydrocarbons
CN1203032C (zh) 2002-11-12 2005-05-25 石油大学(北京) 以复合离子液体为催化剂制备烷基化油剂的方法
US7199083B2 (en) 2002-12-06 2007-04-03 Self Generating Foam Incoporated Self-generating foamed drilling fluids
DE10257499A1 (de) 2002-12-10 2004-07-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Olefinen durch katalytische Spaltung von 1-Alkoxyalkanen
CA2509267C (en) 2002-12-20 2010-04-06 Exxonmobil Chemical Patents Inc. Polymerization process utilizing hydrofluorocarbons as diluents
EP1572752B1 (en) 2002-12-20 2014-08-13 ExxonMobil Chemical Patents Inc. Polymerization processes
EP1440939A1 (en) 2003-01-07 2004-07-28 Humboldt-Universität zu Berlin Method for the preparation of amorphous metal fluorides
DE10303304A1 (de) 2003-01-28 2004-07-29 Ruhrgas Ag Verfahren zum Herstellen nichtaromatischer Kohlenwassersstoffe
US7265193B2 (en) 2003-01-31 2007-09-04 Exxonmobil Chemical Patents Inc. Polymerization process
US20040158108A1 (en) 2003-02-06 2004-08-12 Snoble Karel A.J. Purification of alcohol
KR100501922B1 (ko) 2003-02-19 2005-07-18 에스케이 주식회사 메탄올로부터 디메틸에테르의 제조방법
US6875339B2 (en) 2003-03-07 2005-04-05 Conocophillips Company Octane improvement of a hydrocarbon stream
US7091391B2 (en) 2003-03-19 2006-08-15 Stauffer John E Methane to olefins
FR2852866B1 (fr) 2003-03-25 2006-07-14 Bp Lavera Snc Compose metallique fixe sur un support, procede de preparation et utilisation du compose dans des reactions de metathese d'hydrocarbure
US7083714B2 (en) 2003-03-26 2006-08-01 Chevron U.S.A. Inc. Hydrocarbon conversion using molecular sieve SSZ-65
US7011811B2 (en) 2003-03-26 2006-03-14 Chevron U.S.A. Inc. Molecular sieve SSZ-65 composition of matter and synthesis thereof
US20040187684A1 (en) 2003-03-26 2004-09-30 Saleh Elomari Using molecular sieve SSZ-65 for reduction of oxides of nitrogen in a gas stream
US7301060B2 (en) 2003-03-28 2007-11-27 Ab-Cwt, Llc Process for conversion of organic, waste, or low-value materials into useful products
JP4111035B2 (ja) 2003-03-31 2008-07-02 日本ゼオン株式会社 重合トナーの製造方法
US6822123B2 (en) 2003-04-02 2004-11-23 John E. Stauffer Formaldehyde process
WO2004089866A1 (en) 2003-04-09 2004-10-21 Shell Internationale Research Maatschappij B.V. Process for the preparation of alkanediol
US7057081B2 (en) 2003-05-09 2006-06-06 Conocophillips Company Method for treating alkanes
US6953868B2 (en) 2003-06-05 2005-10-11 Dow Global Technologies Inc. Oxyfunctionalization of polyolefins
US7282603B2 (en) 2003-06-21 2007-10-16 Richards Alan K Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds
US7193093B2 (en) 2003-06-30 2007-03-20 Shell Oil Company Process for producing alkylene oxide
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
WO2005021468A1 (en) 2003-07-15 2005-03-10 Grt, Inc. Hydrocarbon synthesis
UA84436C2 (ru) 2003-08-08 2008-10-27 Солвей (Сосьетэ Аноним) Способ регенерации катализатора гидрирования и способ получения мономера винилхлорида
DE10338581A1 (de) 2003-08-22 2005-03-17 Oxeno Olefinchemie Gmbh Verfahren zur Erzeugung von tert.-Butanol
US6958306B2 (en) 2003-08-28 2005-10-25 Univation Technologies, Llc Activated catalyst systems from substituted dialuminoxane complexes
GB0320684D0 (en) * 2003-09-03 2003-10-01 Bp Chem Int Ltd Process
US7045670B2 (en) 2003-09-03 2006-05-16 Synfuels International, Inc. Process for liquid phase hydrogenation
US6825383B1 (en) 2003-09-22 2004-11-30 Council Of Scientific And Industrial Research Catalytic process for regiospecific chlorination of alkanes, alkenes and arenes
US7105710B2 (en) 2003-09-26 2006-09-12 Shell Oil Company Process of preparing an alkylene glycol
PT1675813E (pt) 2003-10-13 2008-01-10 Serono Lab Método de preparação de para-fenil-alcinil-benzaldeídos
US7335802B2 (en) 2003-10-15 2008-02-26 Shell Oil Company Methods of preparing branched aliphatic alcohols
WO2005035121A2 (en) 2003-10-16 2005-04-21 Universiteit Gent Schiff base metal complexes for use as catalysts in organic synthesis
US6838576B1 (en) 2003-10-23 2005-01-04 3M Innovative Properties Company Process for preparing functional group-containing olefinic compounds
US7196239B2 (en) 2003-11-19 2007-03-27 Exxonmobil Chemical Patents Inc. Methanol and ethanol production for an oxygenate to olefin reaction system
DE602004005890T2 (de) 2003-11-28 2008-01-17 Firmenich S.A. Moschus-geruchsstoffe
WO2005054120A2 (en) 2003-12-05 2005-06-16 Idaho Research Foundation, Inc. Polymer-supported metal nanoparticles and method for their manufacture and use
US7244795B2 (en) 2003-12-08 2007-07-17 Univation Technologies, Llc Polymerization process using metallocene catalyst systems
WO2005056525A2 (en) 2003-12-09 2005-06-23 Bio-Technical Resources Deacetylation of n-acetylglucosamine
EP1697287B1 (en) 2003-12-18 2015-08-26 ExxonMobil Chemical Patents Inc. Improvements in or relating to hydrogenation
US7064238B2 (en) 2004-01-02 2006-06-20 Marathon Oil Company Conversion of alkanes to oxygenates
FR2865731B1 (fr) 2004-01-30 2007-09-07 Solvay Procede de fabrication d'un hydrofluoroalcane
FR2866023B1 (fr) 2004-02-05 2007-10-12 Rhodia Chimie Sa Procede de preparation d'un compose fluoaromatique a partir d'un compose aminoaromatique
JP5102613B2 (ja) 2004-03-12 2012-12-19 ユニバーシティ オブ ユタ サイクロンリアクターおよび関連の方法
WO2005095310A2 (en) 2004-03-23 2005-10-13 Shell Internationale Research Maatschappij B.V. The utilization of zirconium and zirconium based alloys for the containment of halogen containing environments used in the production of olefins, alcohols, ethers, ethoxylates glycols, and olefin oxides from alkanes
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
WO2005113440A1 (en) 2004-04-20 2005-12-01 Uop Llc Crystalline aluminosilicate zeolitic composition: uzm-15
US7091387B2 (en) 2004-04-21 2006-08-15 Shell Oil Company Process to convert alkanes into primary alcohols
US7462752B2 (en) 2004-04-21 2008-12-09 Shell Oil Company Process to convert linear alkanes into alpha olefins
DE602004028766D1 (de) 2004-04-23 2010-09-30 Uop Llc Siliciumreiche zeolithe uzm-5hs
WO2005110953A1 (en) 2004-04-30 2005-11-24 Shell Internationale Research Maatschappij B.V. Derivatives of alcohols and olefins
US7435760B2 (en) 2004-05-14 2008-10-14 Battelle Memorial Institute Method of generating hydrocarbon reagents from diesel, natural gas and other logistical fuels
JP2008503602A (ja) 2004-06-16 2008-02-07 ダウ グローバル テクノロジーズ インコーポレイティド チーグラー・ナッタ研究のための装置および方法
JP4611984B2 (ja) 2004-06-23 2011-01-12 株式会社トクヤマ ポリハロゲン化ジアマンタン類及びその誘導体の製造方法
DE102004030943B4 (de) 2004-06-26 2013-10-02 Evonik Oxeno Gmbh Verfahren zur Herstellung von tert.-Butanol aus Isobuten-haltigen Kohlenwasserstoffgemischen
ATE454370T1 (de) 2004-07-21 2010-01-15 Dow Global Technologies Inc Umwandlung eines mehrfach hydroxylierten aliphatischen kohlenwasserstoffes oder esters daraus in ein chlorhydrin
US7429683B2 (en) 2004-07-27 2008-09-30 Eastman Kodak Company Process of maing naphthacene from propargyl alcohol
ATE455741T1 (de) 2004-08-13 2010-02-15 Exxonmobil Chem Patents Inc Verfahren zur herstellung von sek.-butylbenzol
US7371916B1 (en) 2004-09-16 2008-05-13 Uop Llc Conversion of an alcoholic oxygenate to propylene using moving bed technology and an etherification step
US7271303B1 (en) 2004-09-22 2007-09-18 Uop Llc Multi-zone process for the production of diesel and aromatic compounds
JP2008514540A (ja) 2004-09-30 2008-05-08 シェブロン ユー．エス．エー． インコーポレイテッド モレキュラーシーブｓｓｚ−６５
US7645897B2 (en) 2004-10-15 2010-01-12 Xinlin Tu Process for producing metal oxide catalyst
GB0423586D0 (en) 2004-10-22 2004-11-24 United States Borax Inc Selective oxidation of organic compounds
US9150494B2 (en) 2004-11-12 2015-10-06 Velocys, Inc. Process using microchannel technology for conducting alkylation or acylation reaction
TWI332418B (en) 2004-11-18 2010-11-01 Rohm & Haas Hybrid catalyst systems and hybrid process for converting alkanes to alkenes and to their corresponding oxygenated products
WO2006067155A2 (en) 2004-12-21 2006-06-29 Albemarle Netherlands Bv Attrition-resisitant catalyst, a process for its preparation and its use
US7943015B2 (en) 2004-12-22 2011-05-17 E. I. Du Pont De Nemours And Company Use of copolymers of perfluoro(alkyl vinyl ether) for photochemical reactions
PL1827644T3 (pl) 2004-12-22 2019-05-31 Chemtor Lp Zastosowanie reaktorów z warstewką na włóknach do prowadzenia ekstrakcji pomiędzy dwoma niemieszającymi się składnikami
DE602005026987D1 (de) 2004-12-23 2011-04-28 Solvay Verfahren zur herstellung von 1,2-dichlorethan
EP1831140A1 (en) 2004-12-23 2007-09-12 Solvay SA Process for the manufacture of 1,2-dichloroethane
US7537685B2 (en) 2004-12-23 2009-05-26 Chevron U.S.A. Inc. Hydrocarbon conversion using molecular sieve SSZ-71
US7550073B2 (en) 2004-12-23 2009-06-23 Chevron U.S.A., Inc. Hydrocarbon conversion using molecular sieve SSZ-70
CA2591094A1 (en) 2004-12-23 2006-06-29 Solvay (Societe Anonyme) Process for the manufacture of 1,2-dichloroethane
JP2008525377A (ja) 2004-12-23 2008-07-17 ソルヴェイ（ソシエテ アノニム） １，２−ジクロロエタンの製造方法
EP1843975B1 (en) 2004-12-23 2014-06-11 Chevron U.S.A. Inc. Molecular sieve ssz-70 composition of matter and synthesis thereof
DE102005003109B4 (de) 2005-01-22 2015-02-12 Air Liquide Global E&C Solutions Germany Gmbh Verfahren zur Herstellung von synthetischen Kraftstoffen aus Oxigenaten
US7253328B2 (en) 2005-01-24 2007-08-07 John Stauffer Method for producing vinyl chloride monomer
WO2006104909A2 (en) 2005-03-28 2006-10-05 Shell Internationale Research Maatschappij B.V. Catalytic distillation process for primary haloalkanes
US20060229475A1 (en) 2005-04-11 2006-10-12 Weiss Michael J Synthesis of hydroxylated hydrocarbons
US20060229228A1 (en) 2005-04-11 2006-10-12 Zachary John Anthony Komon Method of making alkoxylates
EP1869720A4 (en) 2005-04-15 2011-09-21 Du Pont SUBSTITUTED ARYL-ETHYLENE AROMATIC COMPOUNDS AND USE AS ORGANIC SEMICONDUCTORS
ITMI20050723A1 (it) 2005-04-21 2006-10-22 Consiglio Nazionale Ricerche Metodo di produzione del biodiesel
ZA200708923B (en) 2005-05-04 2009-02-25 Dow Global Technologies Inc Oxidative halogenation of C1 hydrocarbons to halogenated C1 hydrocarbons
CN101052606B (zh) 2005-05-20 2011-12-21 索尔维公司 从多羟基脂肪烃开始制备氯醇的方法
WO2007017900A2 (en) 2005-05-26 2007-02-15 Sisir Kumar Mandal Preparation of para dichlorobenzene from benzene or mono chlorobenzene
US20060270863A1 (en) 2005-05-27 2006-11-30 Amyris Biotechnologies Conversion of amorpha-4,11-diene to artemisinin and artemisinin precursors
CA2510093C (en) 2005-06-16 2009-09-29 Apotex Pharmachem Inc. Novel process for the preparation of.alpha.-chlorovinyl, .alpha.,.alpha.-dichloro, and acetylenes from ketones
US7442354B2 (en) 2005-06-23 2008-10-28 Chevron U.S.A. Inc. Treatment of engine exhaust using molecular sieve SSZ-56
WO2007001934A2 (en) 2005-06-23 2007-01-04 Chevron U.S.A. Inc. Molecular sieve ssz-56 composition of matter and synthesis thereof
US7390395B2 (en) 2005-06-23 2008-06-24 Saleh Elomari Hydrocarbon conversion using molecular sieve SSZ-56
ZA200800650B (en) 2005-06-23 2009-04-29 Chevron Usa Inc Molecular sieve SSZ-56 composition of matter and synthesis thereof
US7226569B2 (en) 2005-06-23 2007-06-05 Chevron U.S.A. Inc. Reduction of oxides of nitrogen in a gas stream using molecular sieve SSZ-56
US7084308B1 (en) 2005-07-29 2006-08-01 Stauffer John E Manufacture of formaldehyde from methyl bromide
US8957259B2 (en) 2005-09-30 2015-02-17 Battelle Memorial Institute Dimethyl ether production from methanol and/or syngas
US8039679B2 (en) 2005-10-07 2011-10-18 Badger Licensing Llc Bisphenol-A plant yield enhancement
US7683230B2 (en) 2005-10-27 2010-03-23 Stauffer John E Methyl bromide to olefins
EP1951646A1 (en) 2005-10-28 2008-08-06 Shell Internationale Research Maatschappij B.V. Process for preparing internal olefins
US7888520B2 (en) 2005-12-21 2011-02-15 University Of Saskatchewan Process for the preparation of biodiesel
US20070213545A1 (en) 2005-12-22 2007-09-13 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070197801A1 (en) 2005-12-22 2007-08-23 Bolk Jeroen W Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process
ZA200806549B (en) 2005-12-28 2009-11-25 Chevron Usa Inc Molecular sieve SSZ-74 composition of matter and synthesis thereof
US7762059B2 (en) 2005-12-28 2010-07-27 Chevron U.S.A. Inc. Treatment of engine exhaust using molecular sieve SSZ-74
US7510697B2 (en) 2005-12-28 2009-03-31 Chevron U.S.A. Inc. Molecular sieve SSZ-74 composition of matter and synthesis thereof
US7422732B2 (en) 2005-12-28 2008-09-09 Chevron U.S.A. Inc Synthesis of amines using molecular sieve SSZ-74
US20080115666A1 (en) 2005-12-28 2008-05-22 Chevron U.S.A. Inc. Gas separation using molecular sieve ssz-74
US7473807B2 (en) 2005-12-28 2009-01-06 Chevron Usa, Inc. Acylation using molecular sieve SSZ-74
CN101389582B (zh) 2005-12-28 2013-07-24 雪佛龙美国公司 分子筛ssz-74组合物及其合成
US7357904B2 (en) 2005-12-28 2008-04-15 Chevron Corporation Reduction of oxides of nitrogen in a gas stream using molecular sieve SSZ-74
US20070149778A1 (en) 2005-12-28 2007-06-28 Chevron U.S.A. Inc. Beckmann rearrangement using molecular sieve ssz-74
EA020442B1 (ru) 2006-02-03 2014-11-28 ДжиАрТи, ИНК. Способ превращения углеводородного сырья (варианты) и система для его осуществления
GB0602424D0 (en) 2006-02-07 2006-03-22 Sinclair Pharmaceuticals Ltd Compounds
EP1837320A1 (en) 2006-03-23 2007-09-26 ETH Zürich Production of saturated C2 to C5 hydrocarbons
CN102836675B (zh) 2006-03-23 2016-06-15 万罗赛斯公司 一种装置
JP2007269708A (ja) 2006-03-31 2007-10-18 Sumitomo Chemical Co Ltd 第３級オレフィンおよび脂肪族アルコールの製造方法
US20070238905A1 (en) 2006-04-05 2007-10-11 Victor Manuel Arredondo Processes for converting glycerol to glycerol ethers
BRPI0601460B1 (pt) 2006-04-26 2015-11-10 Petroleo Brasileiro Sa processo para hidroconversão de mistura de óleos orgânicos de diferentes origens
CN101437783B (zh) 2006-05-08 2012-12-12 埃克森美孚化学专利公司 有机化合物转化方法
CN101437611B (zh) 2006-05-08 2015-04-22 埃克森美孚化学专利公司 改进的催化剂组合物
US7268263B1 (en) 2006-05-18 2007-09-11 Uop Llc Integrated process for aromatics production
US7304193B1 (en) 2006-05-18 2007-12-04 Uop Llc Integrated process for aromatics production
EP2029507A1 (en) 2006-06-08 2009-03-04 High Point Pharmaceuticals, LLC Process for preparing phenoxy acetic acid derivatives
CA2653928C (en) 2006-06-08 2014-09-09 Chevron U.S.A. Inc. Molecular sieve ssz-75 composition of matter and synthesis thereof
US7906099B2 (en) 2006-06-09 2011-03-15 Exxonmobil Chemical Patents Inc. Intergrown molecular sieve, its synthesis and its use in the conversion of oxygenates to olefins
WO2008036562A1 (en) 2006-09-21 2008-03-27 Albemarle Corporation Methods for conversion of methane to useful hydrocarbons, catalysts for use therein, and regeneration of the catalysts
US20090247804A1 (en) 2006-09-21 2009-10-01 Albemarle Corporation Methods for conversion of methane to useful hydrocarbons and catalysts for use therein
JP2010520211A (ja) 2007-02-28 2010-06-10 アルベマール・コーポレーシヨン メタンおよび臭素からの高級炭化水素の生成方法
WO2008157045A1 (en) 2007-06-14 2008-12-24 Albemarle Corporation Processes for producing higher hydrocarbons from hydrocarbon feed sources
WO2008157047A1 (en) 2007-06-14 2008-12-24 Albemarle Corporation Processes for producing hydrogen from hydrocarbon feed sources
WO2008157044A1 (en) 2007-06-14 2008-12-24 Albemarle Corporation Processes for producing higher hydrocarbons from methane
WO2008157046A1 (en) 2007-06-14 2008-12-24 Albemarle Corporation Processes for producing higher hydrocarbons from methane
WO2008157043A1 (en) 2007-06-14 2008-12-24 Albemarle Corporation Processes for producing higher hydrocarbons from methane

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105478000A (zh) * 2015-12-30 2016-04-13 沈阳三聚凯特催化剂有限公司 一种用于净化重整再生气的脱氯剂及其制备方法

Also Published As

Publication number Publication date
ECSP088711A (es) 2008-11-27
US20070251382A1 (en) 2007-11-01
UA95943C2 (ru) 2011-09-26
AU2007212493B2 (en) 2012-09-27
EA200870229A1 (ru) 2009-02-27
CA2641426A1 (en) 2007-08-16
BRPI0707490A2 (pt) 2011-05-03
CA2641426C (en) 2015-06-09
MY153701A (en) 2015-03-13
HK1130758A1 (en) 2010-01-08
JP2009525257A (ja) 2009-07-09
JP5275817B2 (ja) 2013-08-28
KR20080089515A (ko) 2008-10-06
KR101335397B1 (ko) 2013-12-02
AU2007212493A1 (en) 2007-08-16
NO20083776L (no) 2008-11-03
WO2007092410A2 (en) 2007-08-16
EP1993951A2 (en) 2008-11-26
WO2007092410A3 (en) 2007-12-27
EP1993951B1 (en) 2014-07-30
EP1993951A4 (en) 2011-10-19
US7883568B2 (en) 2011-02-08
EA013629B1 (ru) 2010-06-30
CN101395088B (zh) 2012-04-04
ZA200807230B (en) 2009-11-25
SG187456A1 (en) 2013-02-28

Similar Documents

Publication Publication Date Title
CN101395088B (zh) 轻气体与卤素的分离方法
EP0794240B1 (en) Mercury adsorbent
JP3194095B2 (ja) 水銀および／または砒素の捕集物質の存在下における、流体中の水銀または砒素の除去方法
US5419884A (en) Regenerative mercury removal process
US3754074A (en) Removal of nitrogen oxides and other impurities from gaseous mixtures
JPH05168912A (ja) 水銀捕集固体物質の調製方法
EA022995B1 (ru) Непрерывный способ превращения природного газа в жидкие углеводороды
CN86102838A (zh) 高效吸附剂及其制备方法和应用
EP0659101A4 (en) Method and device for simultaneously drying and removing metallic and organic mercury from fluids.
CN110548479A (zh) 一种高强度液相脱氯剂及其制备方法和应用
TW200808440A (en) Absorption composition and process for purifying streams of substances
CN100491329C (zh) 一种生产碳酸二甲酯的方法
JPS6041988B2 (ja) 一酸化炭素の吸着分離方法
EA017772B1 (ru) Способ снижения количества сернистых соединений, цианистого водорода и муравьиной кислоты в синтез-газе
JPS6049022B2 (ja) 混合ガスより一酸化炭素を分離する方法
CN1074758C (zh) 氟甲基-1,1,1,3,3,3-六氟异丙醚的精制方法
CN105566054A (zh) 一种芳烃氯化生产过程中副产物氯化氢循环利用方法和系统
CN105517692A (zh) 用于从氯化烃中纯化co2的催化剂
JPH07179377A (ja) エタノールおよびイソプロパノールの製造方法
JPH0617203B2 (ja) 塩素の製造方法
JPS60156548A (ja) 一酸化炭素捕集剤及びその製法
CN106311133A (zh) 固体净化剂及其制备方法
JPS6135128B2 (zh)
JP3017855B2 (ja) プロピレン中に含有される硫化カルボニルと一酸化炭素を同時に除去する方法
CS239820B1 (en) Method of fractioning of pyrolitic gas

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1130758

Country of ref document: HK

C14 Grant of patent or utility model
GR01 Patent grant
REG Reference to a national code

Ref country code: HK

Ref legal event code: GR

Ref document number: 1130758

Country of ref document: HK

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120404

Termination date: 20220205