CN101328427B - Formula of emulsified mixing oil - Google Patents
Formula of emulsified mixing oil Download PDFInfo
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- CN101328427B CN101328427B CN2007100696520A CN200710069652A CN101328427B CN 101328427 B CN101328427 B CN 101328427B CN 2007100696520 A CN2007100696520 A CN 2007100696520A CN 200710069652 A CN200710069652 A CN 200710069652A CN 101328427 B CN101328427 B CN 101328427B
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Abstract
The invention relates to a formula of emulsified mixed oil. The formula consists of heavy oil, diesel oil, water and an addition agent, wherein the percentages by wight of the compositions of the formula include: 69.9 to 29.9 percent of the heavy oil, 20 to 40 percent of the diesel oil, 10 to 30 percent of the water and 0.1 percent of the addition agent; moreover, the addition agent comprises thefollowing compositions in portion by weight: 6 to 20 portions of manganese iso-octoate, 1 to 10 portions of nickel naphthenate, 35 to 65 portions of sorbitan monooleate, 4 to 8 portions of sorbitan polyoxyethylene monooleate, 1 to 2 portions of nonyl phenol polyoxyethylene (6) ether, 4 to 8 portions of sodium hydroxide, 4 to 6 portions of xylene, 1 to 6 portions of methanol and 1 portion of sunset red. The formula has the advantages that: the formula has reasonable proportioning, advanced technological method, low product price and high stability, and capability of replacing the diesel oil.
Description
Technical field
The present invention relates to a kind of emulsification mixing oil compsn, the invention belongs to a kind of Emulsification of Fuel Oil preparation and utilisation technology in chemical industry, the energy.
Background technology
Present domestic diesel oil short supply, on the high side, stability is low, and the content of oxynitride, oxysulfide and flue dust is high in the flue gas of burning back, is badly in need of a kind of energy that can substitute diesel oil and occurs.Existing diesel oil " fuel-water emulsifying " technology is exactly a fuel economy oil; Reduce and consume; The advanced power-saving technology of environment protection standard, our country researched and developed and uses its technology intermittently from the sixties, but because multiple factor does not become the effective energy-saving form.
Summary of the invention
Technical problem to be solved by this invention provides a kind of reasonable ratio, and process method is advanced, the emulsification mixing oil compsn of low, the stable height of product price, alternative diesel oil.
It is this emulsification mixing oil compsn that the present invention solves the problems of the technologies described above the technical scheme that is adopted; Its prescription characteristics are: be made up of heavy oil, diesel oil, water and additive; Wherein, the weight percent of each component is: heavy oil 69.9%-29.9%, diesel oil 20%-40%, water 10%-30%, additive 0.1%; Additive by manganese iso-octoate, nickel naphthenate, sorbitan monooleate, anhydrous sorbitol Aceonon 300 MO, Nonyl pheno (6) ether, sodium hydroxide, YLENE, methyl alcohol, the setting sun is red forms, wherein, the shared parts by weight of each component are: manganese iso-octoate 6-20 part; Nickel naphthenate 1-10 part; Sorbitan monooleate 35-65 part, anhydrous sorbitol Aceonon 300 MO 4-8 part, Nonyl pheno (6) ether 1-2 part; Sodium hydroxide 4-8 part; YLENE 4-6 part, methyl alcohol 1-6 part, red 1 part of the setting sun.
Contain polyisobutene imide and sodium-alginate in the additive of the present invention, shared parts by weight are: polyisobutene imide 0-10 part, sodium-alginate 0-1 part.
The particle of water of the present invention is less than 2.5 microns, and distributive law is more than 95%.
The present invention compares with prior art and has the following advantages and effect: the invention solves present domestic diesel oil short supply, energy problem on the high side.The alternative diesel oil of the present invention uses in equipment such as diesel oil boiler, and effect 0# diesel oil effect is the same, and has high stability; Possess catalysis, combustion-supporting effect, can improve the vaporization rate of gob, make the more fully more even of fuel combustion; In addition; Use rate of economizing gasoline of the present invention can reach 10%-20%, and because incendiary has more fully more evenly reduced the content of oxynitride, oxysulfide and flue dust in the flue gas, thereby reach the energy-conserving and environment-protective purpose.The present invention can be used in heavy oil, residual oil, the diesel oil of the various qualities and the trade mark, and the formulation ratio of each component is reasonable, and preparation technology is reasonable in design.
Embodiment
Below in conjunction with embodiment the present invention is done further detailed description, following examples are to explanation of the present invention and the present invention is not limited to following examples.
Embodiment 1
The preparation process of additive of the present invention has been described with the lower section:
Get 15 kilograms of manganese iso-octoates, 7 kilograms of nickel naphthenates, 38 kilograms of sorbitan monooleates, 6 kilograms of anhydrous sorbitol Aceonon 300 MOs; 1.5 kilograms in Nonyl pheno (6) ether, 8 kilograms of polyisobutene imide, 8 kilograms in sodium hydroxide; 5.5 kilograms of YLENE, 4 kilograms of methyl alcohol, 0.8 kilogram of sodium-alginate; Red 1 kilogram of the setting sun mixes to stir and processes 94.8 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
500 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 300 kilograms of normal temperature then; Stirred 10 minutes, and added 65 degrees centigrade 199 kilograms of hot water and 1 kilogram additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 2
The preparation process of additive of the present invention has been described with the lower section:
Get 20 kilograms of manganese iso-octoates, 4 kilograms of nickel naphthenates, 42 kilograms of sorbitan monooleates, 7.5 kilograms of anhydrous sorbitol Aceonon 300 MOs; 1.2 kilograms in Nonyl pheno (6) ether, 5 kilograms of polyisobutene imide, 6 kilograms in sodium hydroxide; 5.3 kilograms of YLENE, 1 kilogram of methyl alcohol, 0.2 kilogram of sodium-alginate; Red 1 kilogram of the setting sun mixes to stir and processes 93.2 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
450 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 260 kilograms of normal temperature then; Stirred 10 minutes, and added 70 degrees centigrade 289 kilograms of hot water and 1 kilogram 30 degrees centigrade additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 3
The preparation process of additive of the present invention has been described with the lower section:
Get 7 kilograms of manganese iso-octoates, 1 kilogram of nickel naphthenate, 62 kilograms of sorbitan monooleates; 4 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.3 kilograms in Nonyl pheno (6) ether, 7 kilograms in sodium hydroxide; 5.8 kilograms of YLENE, 1.5 kilograms of methyl alcohol, 0.6 kilogram of sodium-alginate; Red 1 kilogram of the setting sun mixes to stir and processes 91.2 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
549 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 200 kilograms of normal temperature then; Stirred 10 minutes, and added 70 degrees centigrade 250 kilograms of hot water and 1 kilogram 30 degrees centigrade additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 4
The preparation process of additive of the present invention has been described with the lower section:
Get 14 kilograms of manganese iso-octoates, 6 kilograms of nickel naphthenates, 60 kilograms of sorbitan monooleates, 6.5 kilograms of anhydrous sorbitol Aceonon 300 MOs; 1 kilogram in Nonyl pheno (6) ether, 3 kilograms of polyisobutene imide, 5 kilograms in sodium hydroxide; 6 kilograms of YLENE, 3 kilograms of methyl alcohol, 0.4 kilogram of sodium-alginate; Red 1 kilogram of the setting sun mixes to stir and processes 105.9 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
299 kilograms of heavy oil are heated to 60 degrees centigrade; The diesel oil that in heavy oil, adds 400 kilograms of normal temperature then; Stirred 10 minutes, and added 60 degrees centigrade 300 kilograms of hot water and 1 kilogram additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 5
The preparation process of additive of the present invention has been described with the lower section:
Get 12 kilograms of manganese iso-octoates, 8 kilograms of nickel naphthenates, 57 kilograms of sorbitan monooleates; 4.2 kilograms of anhydrous sorbitol Aceonon 300 MOs, 2 kilograms in Nonyl pheno (6) ether, 7 kilograms of polyisobutene imide; 4 kilograms in sodium hydroxide, 5.1 kilograms of YLENE, 2 kilograms of methyl alcohol; Red 1 kilogram of the setting sun mixes to stir and processes 102.3 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
649 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 250 kilograms of normal temperature then; Stirred 10 minutes, and added 70 degrees centigrade 100 kilograms of hot water and 1 kilogram 30 degrees centigrade additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 6
The preparation process of additive of the present invention has been described with the lower section:
Get 8 kilograms of manganese iso-octoates, 5 kilograms of nickel naphthenates, 65 kilograms of sorbitan monooleates; 4.7 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.6 kilograms in Nonyl pheno (6) ether, 9 kilograms of polyisobutene imide; 4.5 kilograms in sodium hydroxide, 4.8 kilograms of YLENE, 1.2 kilograms of methyl alcohol; 1 kilogram of sodium-alginate, red 1 kilogram of the setting sun mix to stir and processes 105.8 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
699 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 200 kilograms of normal temperature then; Stirred 10 minutes, and added 75 degrees centigrade 100 kilograms of hot water and 1 kilogram additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 7
The preparation process of additive of the present invention has been described with the lower section:
Get 6 kilograms of manganese iso-octoates, 3 kilograms of nickel naphthenates, 52 kilograms of sorbitan monooleates; 5.2 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.9 kilograms in Nonyl pheno (6) ether, 4 kilograms of polyisobutene imide; 6.5 kilograms in sodium hydroxide, 4.5 kilograms of YLENE, 3.5 kilograms of methyl alcohol; 0.9 kilogram of sodium-alginate, red 1 kilogram of the setting sun mix to stir and processes 88.5 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
400 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 349 kilograms of normal temperature then; Stirred 10 minutes, and added 70 degrees centigrade 250 kilograms of hot water and 1 kilogram additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 8
The preparation process of additive of the present invention has been described with the lower section:
Get 9 kilograms of manganese iso-octoates, 7 kilograms of nickel naphthenates, 57 kilograms of sorbitan monooleates; 7.8 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.8 kilograms in Nonyl pheno (6) ether, 6 kilograms of polyisobutene imide; 7.5 kilograms in sodium hydroxide, 4.2 kilograms of YLENE, 6 kilograms of methyl alcohol; 0.7 kilogram of sodium-alginate, red 1 kilogram of the setting sun mix to stir and processes 108 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
450 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 270 kilograms of normal temperature then; Stirred 10 minutes, and added 60 degrees centigrade 279 kilograms of hot water and 1 kilogram 30 degrees centigrade additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 9
The preparation process of additive of the present invention has been described with the lower section:
Get 11 kilograms of manganese iso-octoates, 10 kilograms of nickel naphthenates, 48 kilograms of sorbitan monooleates; 7.3 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.7 kilograms in Nonyl pheno (6) ether, 2 kilograms of polyisobutene imide; 5.5 kilograms in sodium hydroxide, 4 kilograms of YLENE, 5.5 kilograms of methyl alcohol; 0.5 kilogram of sodium-alginate, red 1 kilogram of the setting sun mix to stir and processes 96.5 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
330 kilograms of heavy oil are heated to 78 degrees centigrade; The diesel oil that in heavy oil, adds 390 kilograms of normal temperature then; Stirred 10 minutes, and added 75 degrees centigrade 279 kilograms of hot water and 1 kilogram 30 degrees centigrade additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 10
The preparation process of additive of the present invention has been described with the lower section:
Get 17 kilograms of manganese iso-octoates, 2 kilograms of nickel naphthenates, 45 kilograms of sorbitan monooleates; 6.8 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.4 kilograms in Nonyl pheno (6) ether, 10 kilograms of polyisobutene imide; 6 kilograms in sodium hydroxide, 4.1 kilograms of YLENE, 5.2 kilograms of methyl alcohol; 0.3 kilogram of sodium-alginate, red 1 kilogram of the setting sun mix to stir and processes 98.8 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
370 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 370 kilograms of normal temperature then; Stirred 10 minutes, and added 70 degrees centigrade 259 kilograms of hot water and 1 kilogram additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 11
The preparation process of additive of the present invention has been described with the lower section:
Get 19 kilograms of manganese iso-octoates, 9 kilograms of nickel naphthenates, 35 kilograms of sorbitan monooleates; 8 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.1 kilograms in Nonyl pheno (6) ether, 1 kilogram of polyisobutene imide; 7 kilograms in sodium hydroxide, 4.6 kilograms of YLENE, 4.8 kilograms of methyl alcohol; 0.1 kilogram of sodium-alginate, red 1 kilogram of the setting sun mix to stir and processes 90.6 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
420 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 320 kilograms of normal temperature then; Stirred 10 minutes, and added 70 degrees centigrade 259 kilograms of hot water and 1 kilogram additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 12
The preparation process of additive of the present invention has been described with the lower section:
Get 15 kilograms of manganese iso-octoates, 7 kilograms of nickel naphthenates, 38 kilograms of sorbitan monooleates, 6 kilograms of anhydrous sorbitol Aceonon 300 MOs; 1.5 kilograms in Nonyl pheno (6) ether, 8 kilograms of polyisobutene imide, 8 kilograms in sodium hydroxide; 5.5 kilograms of YLENE, 4 kilograms of methyl alcohol, 0.8 kilogram of sodium-alginate; Red 1 kilogram of the setting sun mixes to stir and processes 94.8 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
519 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 360 kilograms of normal temperature then; Stirred 10 minutes, and added 70 degrees centigrade hot water 120 kg and 1 kilogram 30 degrees centigrade additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 13
The preparation process of additive of the present invention has been described with the lower section:
Get 20 kilograms of manganese iso-octoates, 4 kilograms of nickel naphthenates, 42 kilograms of sorbitan monooleates, 7.5 kilograms of anhydrous sorbitol Aceonon 300 MOs; 1.2 kilograms in Nonyl pheno (6) ether, 5 kilograms of polyisobutene imide, 6 kilograms in sodium hydroxide; 5.3 kilograms of YLENE, 1 kilogram of methyl alcohol, 0.2 kilogram of sodium-alginate; Red 1 kilogram of the setting sun mixes to stir and processes 93.2 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
509 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 350 kilograms of normal temperature then; Stirred 10 minutes, and added 70 degrees centigrade 140 kilograms of hot water and 1 kilogram 30 degrees centigrade additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 14
The preparation process of additive of the present invention has been described with the lower section:
Get 7 kilograms of manganese iso-octoates, 1 kilogram of nickel naphthenate, 62 kilograms of sorbitan monooleates; 4 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.3 kilograms in Nonyl pheno (6) ether, 7 kilograms in sodium hydroxide; 5.8 kilograms of YLENE, 1.5 kilograms of methyl alcohol, 0.6 kilogram of sodium-alginate; Red 1 kilogram of the setting sun mixes to stir and processes 91.2 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
530 kilograms of heavy oil are heated to 60 degrees centigrade; The diesel oil that in heavy oil, adds 300 kilograms of normal temperature then; Stirred 10 minutes, and added 60 degrees centigrade 169 kilograms of hot water and 1 kilogram additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 15
The preparation process of additive of the present invention has been described with the lower section:
Get 14 kilograms of manganese iso-octoates, 6 kilograms of nickel naphthenates, 60 kilograms of sorbitan monooleates, 6.5 kilograms of anhydrous sorbitol Aceonon 300 MOs; 1 kilogram in Nonyl pheno (6) ether, 3 kilograms of polyisobutene imide, 5 kilograms in sodium hydroxide; 6 kilograms of YLENE, 3 kilograms of methyl alcohol, 0.4 kilogram of sodium-alginate; Red 1 kilogram of the setting sun mixes to stir and processes 105.9 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
659 kilograms of heavy oil are heated to 75 degrees centigrade; The diesel oil that in heavy oil, adds 220 kilograms of normal temperature then; Stirred 10 minutes, and added 65 degrees centigrade hot water 120 kg and 1 kilogram 30 degrees centigrade additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 16
The preparation process of additive of the present invention has been described with the lower section:
Get 12 kilograms of manganese iso-octoates, 8 kilograms of nickel naphthenates, 57 kilograms of sorbitan monooleates; 4.2 kilograms of anhydrous sorbitol Aceonon 300 MOs, 2 kilograms in Nonyl pheno (6) ether, 7 kilograms of polyisobutene imide; 4 kilograms in sodium hydroxide, 5.1 kilograms of YLENE, 2 kilograms of methyl alcohol; Red 1 kilogram of the setting sun mixes to stir and processes 102.3 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
369 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 400 kilograms of normal temperature then; Stirred 10 minutes, and added 65 degrees centigrade 230 kilograms of hot water and 1 kilogram 30 degrees centigrade additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 17
The preparation process of additive of the present invention has been described with the lower section:
Get 8 kilograms of manganese iso-octoates, 5 kilograms of nickel naphthenates, 65 kilograms of sorbitan monooleates; 4.7 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.6 kilograms in Nonyl pheno (6) ether, 9 kilograms of polyisobutene imide; 4.5 kilograms in sodium hydroxide, 4.8 kilograms of YLENE, 1.2 kilograms of methyl alcohol; 1 kilogram of sodium-alginate, red 1 kilogram of the setting sun mix to stir and processes 105.8 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
360 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 390 kilograms of normal temperature then; Stirred 10 minutes, and added 75 degrees centigrade 249 kilograms of hot water and 1 kilogram 30 degrees centigrade additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 18
The preparation process of additive of the present invention has been described with the lower section:
Get 6 kilograms of manganese iso-octoates, 3 kilograms of nickel naphthenates, 52 kilograms of sorbitan monooleates; 5.2 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.9 kilograms in Nonyl pheno (6) ether, 4 kilograms of polyisobutene imide; 6.5 kilograms in sodium hydroxide, 4.5 kilograms of YLENE, 3.5 kilograms of methyl alcohol; 0.9 kilogram of sodium-alginate, red 1 kilogram of the setting sun mix to stir and processes 88.5 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
430 kilograms of heavy oil are heated to 60 degrees centigrade; The diesel oil that in heavy oil, adds 340 kilograms of normal temperature then; Stirred 10 minutes, and added 60 degrees centigrade 229 kilograms of hot water and 1 kilogram 30 degrees centigrade additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 19
The preparation process of additive of the present invention has been described with the lower section:
Get 9 kilograms of manganese iso-octoates, 7 kilograms of nickel naphthenates, 57 kilograms of sorbitan monooleates; 7.8 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.8 kilograms in Nonyl pheno (6) ether, 6 kilograms of polyisobutene imide; 7.5 kilograms in sodium hydroxide, 4.2 kilograms of YLENE, 6 kilograms of methyl alcohol; 0.7 kilogram of sodium-alginate, red 1 kilogram of the setting sun mix to stir and processes 108 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
479 kilograms of heavy oil are heated to 60 degrees centigrade; The diesel oil that in heavy oil, adds 310 kilograms of normal temperature then; Stirred 10 minutes, and added 60 degrees centigrade 210 kilograms of hot water and 1 kilogram additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 20
The preparation process of additive of the present invention has been described with the lower section:
Get 11 kilograms of manganese iso-octoates, 10 kilograms of nickel naphthenates, 48 kilograms of sorbitan monooleates; 7.3 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.7 kilograms in Nonyl pheno (6) ether, 2 kilograms of polyisobutene imide; 5.5 kilograms in sodium hydroxide, 4 kilograms of YLENE, 5.5 kilograms of methyl alcohol; 0.5 kilogram of sodium-alginate, red 1 kilogram of the setting sun mix to stir and processes 96.5 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
580 kilograms of heavy oil are heated to 75 degrees centigrade; The diesel oil that in heavy oil, adds 230 kilograms of normal temperature then; Stirred 10 minutes, and added 65 degrees centigrade 189 kilograms of hot water and 1 kilogram 30 degrees centigrade additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 21
The preparation process of additive of the present invention has been described with the lower section:
Get 17 kilograms of manganese iso-octoates, 2 kilograms of nickel naphthenates, 45 kilograms of sorbitan monooleates; 6.8 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.4 kilograms in Nonyl pheno (6) ether, 10 kilograms of polyisobutene imide; 6 kilograms in sodium hydroxide, 4.1 kilograms of YLENE, 5.2 kilograms of methyl alcohol; 0.3 kilogram of sodium-alginate, red 1 kilogram of the setting sun mix to stir and processes 98.8 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
600 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 249 kilograms of normal temperature then; Stirred 10 minutes, and added 70 degrees centigrade 150 kilograms of hot water and 1 kilogram 30 degrees centigrade additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 22
The preparation process of additive of the present invention has been described with the lower section:
Get 19 kilograms of manganese iso-octoates, 9 kilograms of nickel naphthenates, 35 kilograms of sorbitan monooleates; 8 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.1 kilograms in Nonyl pheno (6) ether, 1 kilogram of polyisobutene imide; 7 kilograms in sodium hydroxide, 4.6 kilograms of YLENE, 4.8 kilograms of methyl alcohol; 0.1 kilogram of sodium-alginate, red 1 kilogram of the setting sun mix to stir and processes 90.6 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
620 kilograms of heavy oil are heated to 70 degrees centigrade; The diesel oil that in heavy oil, adds 219 kilograms of normal temperature then; Stirred 10 minutes, and added 60 degrees centigrade 160 kilograms of hot water and 1 kilogram additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
Embodiment 23
The preparation process of additive of the present invention has been described with the lower section:
Get 19 kilograms of manganese iso-octoates, 9 kilograms of nickel naphthenates, 35 kilograms of sorbitan monooleates; 8 kilograms of anhydrous sorbitol Aceonon 300 MOs, 1.1 kilograms in Nonyl pheno (6) ether, 1 kilogram of polyisobutene imide; 7 kilograms in sodium hydroxide, 4.6 kilograms of YLENE, 4.8 kilograms of methyl alcohol; 0.1 kilogram of sodium-alginate, red 1 kilogram of the setting sun mix to stir and processes 90.6 kilograms additive, and is subsequent use.
The preparation process of emulsification mixing oil of the present invention has been described with the lower section:
680 kilograms of heavy oil are heated to 80 degrees centigrade; The diesel oil that in heavy oil, adds 209 kilograms of normal temperature then; Stirred 10 minutes, and added 70 degrees centigrade 110 kilograms of hot water and 1 kilogram additive again, continuously stirring is 10 minutes again; Use mulser to cut emulsification 50 minutes, prepare the emulsification mixing oil.This emulsification mixing oil at normal temperatures one month stationary phase not stratified, no oily water separation phenomenon.
In above embodiment, be suitable for heavy oil, residual oil and each number diesel oil of the various qualities and the trade mark.
The emulsification mixing oil that above embodiment obtains only needs at former use diesel oil pipeline and storage tank place heating and heat-insulating device to be installed in use, the emulsification mixing oil is heated to 70 degree entering burners gets final product, and effect 0# diesel oil effect is the same, and more environmental protection.
During burning, the emulsification mixing oil that the present invention makes can improve the vaporization rate of gob, makes the more fully more even of fuel combustion, thereby reaches the energy-conserving and environment-protective purpose.The rate of economizing gasoline that the emulsification mixing oil uses can reach 10%-20%, and because incendiary has more fully more evenly reduced the content of oxynitride, oxysulfide and flue dust in the flue gas.Therefore promote the emulsification mixing oil for solving energy shortage, particularly diesel oil shortage improves environment, all has crucial meaning.
Instance:
The former use GB of Hangzhou associating meat group company's boiler 0# diesel oil, outlet dust concentration 98.2mg/m
3, sulfur dioxide emissioning concentration 384mg/m
3, discharged nitrous oxides concentration is 665.4mg/m
3
After Hangzhou associating meat group company boiler uses this emulsification mixing oil, outlet dust concentration 93.3mg/m
3, sulfur dioxide emissioning concentration 244.5mg/m
3, discharged nitrous oxides concentration is 365.4mg/m
3Above data are by Zhejiang Province Environmental Monitoring Center's station test.
Claims (2)
1. emulsification mixing oil compsn, it consists of: be made up of heavy oil, diesel oil, water and additive, the weight percent of each component is: heavy oil 29.9%-69.9%, diesel oil 20%-40%, water 10%-30%, additive 0.1%; Additive by manganese iso-octoate, nickel naphthenate, sorbitan monooleate, anhydrous sorbitol Aceonon 300 MO, Nonyl pheno 6 ethers, sodium hydroxide, YLENE, methyl alcohol, the setting sun is red forms, wherein, the shared parts by weight of each component are: manganese iso-octoate 6-20 part; Nickel naphthenate 1-10 part; Sorbitan monooleate 35-65 part, anhydrous sorbitol Aceonon 300 MO 4-8 part, Nonyl pheno 6 ether 1-2 parts; Sodium hydroxide 4-8 part; YLENE 4-6 part, methyl alcohol 1-6 part, red 1 part of the setting sun.
2. emulsification mixing oil compsn according to claim 1 is characterized in that: the particle of described water is less than 2.5 microns, and distributive law is more than 95%.
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| CN101328427B true CN101328427B (en) | 2012-06-20 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5120428A (en) * | 1991-06-06 | 1992-06-09 | Energy Mines & Resources Canada | Deashing of heavy hydrocarbon residues |
| JP2002155286A (en) * | 2000-11-20 | 2002-05-28 | Mitsubishi Materials Corp | Method for modifying heavy carbonaceous resource |
| CN1504545A (en) * | 2002-12-04 | 2004-06-16 | 蔡坤穆 | Emulsion synthetic fuel oil and manufacturing method thereof |
| CN1566279A (en) * | 2003-06-13 | 2005-01-19 | 洪星南 | Environmental protection water-based diesel oil emulsifier |
| CN1660972A (en) * | 2004-02-23 | 2005-08-31 | 彭一铸 | Environmental protection diesel oil |
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2007
- 2007-06-22 CN CN2007100696520A patent/CN101328427B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5120428A (en) * | 1991-06-06 | 1992-06-09 | Energy Mines & Resources Canada | Deashing of heavy hydrocarbon residues |
| JP2002155286A (en) * | 2000-11-20 | 2002-05-28 | Mitsubishi Materials Corp | Method for modifying heavy carbonaceous resource |
| CN1504545A (en) * | 2002-12-04 | 2004-06-16 | 蔡坤穆 | Emulsion synthetic fuel oil and manufacturing method thereof |
| CN1566279A (en) * | 2003-06-13 | 2005-01-19 | 洪星南 | Environmental protection water-based diesel oil emulsifier |
| CN1660972A (en) * | 2004-02-23 | 2005-08-31 | 彭一铸 | Environmental protection diesel oil |
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