CN101175804B - 高流动性聚酯组合物 - Google Patents
高流动性聚酯组合物 Download PDFInfo
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- CN101175804B CN101175804B CN2006800166087A CN200680016608A CN101175804B CN 101175804 B CN101175804 B CN 101175804B CN 2006800166087 A CN2006800166087 A CN 2006800166087A CN 200680016608 A CN200680016608 A CN 200680016608A CN 101175804 B CN101175804 B CN 101175804B
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- 238000010561 standard procedure Methods 0.000 description 1
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- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
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- 229910052719 titanium Inorganic materials 0.000 description 1
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- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 description 1
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- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
Abstract
Description
组分 | 单位 | C1 | C2 | E1 | E2 | E3 | E4 | E5 |
PBT315 | % | 100 | 99.5 | 99.9 | 99.8 | 99.7 | 99.5 | 99.0 |
THAM | % | 0.0 | 0.0 | 0.1 | 0.2 | 0.3 | 0.5 | 1.0 |
季戊四醇 | % | 0.0 | 0.5 | - | - | - | - | - |
性能 | ||||||||
螺线流动 | cm | 27 | 42 | 29 | 33 | 38 | 55 | 90 |
在265℃/2.16Kg/240s下的熔体体积速率(MVR) | cc/10min | 5.6 | 17.5 | 7.5 | 9.9 | 11.5 | 37.0 | 67.0 |
拉伸模量 | GPa | 2.6 | 2.75 | 2.6 | 2.58 | 2.65 | 2.83 | 2.88 |
伸长率% | % | 51 | 21 | 36.1 | 33.4 | 31.2 | 14.7 | 3.2 |
在23℃下的伊佐德无缺口抗冲强度 | kJ/m2 | 210 | 170 | 186 | 180 | 176 | 128 | 43 |
组分 | 单位 | C5 | C6 | E6 | C7 | C8 | E7 |
PBT-315 | % | 75 | 74.75 | 74.75 | 65 | 64.75 | 64.75 |
玻璃 | % | 25 | 25 | 25 | 25 | 25 | 25 |
季戊四醇 | % | 0.25 | 0.25 | ||||
THAM | % | 0.25 | 0.25 | ||||
ABS HRG360 | % | 10 | 10 | 10 | |||
AO1010 | % | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 |
性能 | |||||||
在265℃/2.16Kg/240s下的熔体体积速率(MVR) | cc/10min | 5.2 | 12.7 | 18 | 2.2 | 6.1 | 7.9 |
螺线流动 | cm | 53 | 77 | 91 | 49 | 75 | 89 |
拉伸模量 | GPa | 5.91 | 6.19 | 6.3 | 6.19 | 5.71 | 5.71 |
抗拉强度 | GPa | 94 | 94 | 94.4 | 82 | 79 | 79 |
伸长率% | % | 5.4 | 4.4 | 4.3 | 4.9 | 4.3 | 4.3 |
挠曲模量 | GPa | 5.52 | 5.81 | 5.85 | 5.34 | 5.15 | 5.27 |
挠曲强度 | GPa | 149.8 | 150.7 | 153 | 128.7 | 125.5 | 126.5 |
HDT | ℃ | 148 | 157 | 165 | 154 | 150 | 155 |
伊佐德无缺口抗冲强度(KJ/m2),23℃ | kJ/m2 | 49 | 34 | 28 | 45 | 40 | 40 |
组分 | 单位 | C9 | E8 |
PC100 | % | 75 | 74.75 |
PBT-315 | % | 25 | 25 |
THAM | % | 0.25 | |
性能 | |||
在265℃/2.16Kg/240s下的 熔体体积速率(MVR) | cc/10min | 6 | 28 |
螺线流动 | cm | 34 | 63 |
拉伸模量 | GPa | 2.41 | 2.61 |
伸长率% | % | 79 | 75 |
在23℃下的伊佐德无缺口抗 冲强度 | kJ/2 | 250 | 255 |
组分 | 单位 | C10 | C11 | C12 | E9 | E10 |
PBT-195 | % | 69.7 | 59.7 | 59.2 | 59.2 | 59.2 |
季戊四醇 | % | 0.5 | 0.5 | 0.5 | ||
丙烯酸类抗冲改性剂:Paraloid EXL 3300 | % | 10 | 10 | |||
MBS paraloid EXL2650A | % | 10 | ||||
Metablen S2001硅酮抗冲改性剂 | % | |||||
ABS HRG SG24 | % | 10 | ||||
玻璃:标准结晶玻璃 | % | 30 | 30 | 30 | 30 | 30 |
添加剂 | % | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 |
性能 | ||||||
在265℃/2.16Kg/240s下的熔体体积速率(MVR) | cc/10min | 30 | 7 | 21 | 31 | 32.5 |
280℃下的毛细剪切粘度 | pa-s | 84 | 91 | 46 | 42 | 53 |
(1500/s) | ||||||
伊佐德无缺口(kJ/m2) | kJ/m2 | 40 | 54 | 42 | 46 | 44 |
热老化的伊佐德无缺口(155℃1周) | kJ/m2 | 30 | 50 | 22 | 47 | 22 |
抗拉强度(Mpa) | Mpa | 146 | 121 | 116 | 120 | 116 |
热老化的抗拉强度(155℃1周) | Mpa | 157 | 133 | 119 | 118 | 110 |
拉伸模量(Mpa) | Mpa | 9350 | 8580 | 8600 | 8590 | 8750 |
挠曲强度(Mpa) | Mpa | 217 | 191 | 172 | 182 | 175 |
挠曲模量(Mpa) | Mpa | 8450 | 7700 | 7700 | 7800 | 7900 |
组分 | 单位 | C13 | E11 | E12 | C14 | E13 | E14 |
PBT 195 | % | 49.2 | 48.7 | 48.7 | 49.3 | 48.8 | 48.8 |
季戊四醇 | % | 0.5 | 0.5 | 0.5 | 0.5 | ||
丙烯酸类抗冲改性剂:Paraloid EXL 3300 | % | 5 | 5 | 5 | 5 | ||
MBS | - | - | 5 | - | - | 5 | |
溴化PC低聚物,52%Br | % | 10 | 10 | 10 | |||
溴化丙烯酸酯聚(五溴苄基丙烯酸酯) | % | 10.5 | 10.5 | 10.5 | |||
Sb2O3母炼胶;在PBT 195内80% | % | 4 | 4 | 4 | 4.2 | 4.2 | 4.2 |
包封的PTFE | % | 0.9 | 0.9 | 0.9 | 0.7 | 0.7 | 0.7 |
磷酸锌 | % | 0.6 | 0.6 | 0.6 |
玻璃 | % | 30 | 30 | 30 | 30 | 30 | 30 |
添加剂 | % | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 |
性能 | |||||||
熔体体积速率(250℃,2.16Kg,240s) | cc/min | 4 | 12 | 8 | 6 | 15 | 9 |
伊佐德无缺口 | kJ/m2 | 39 | 34 | 26 | 42 | 38 | 32 |
热老化的伊佐德无缺口(155℃1周) | kJ/m2 | 29 | 26 | 23 | 34 | 26 | 25 |
热老化的伊佐德无缺口(155℃2周) | kJ/m2 | 34 | 35 | 25 | 37 | 28 | 21 |
抗拉强度(Mpa) | Mpa | 122 | 116 | 114 | 124 | 122 | 118 |
拉伸模量(Mpa) | Mpa | 10165 | 10415 | 104 89 | 1035 0 | 1035 5 | 1030 7 |
拉伸伸长率 | % | 2.2 | 1.6 | 1.6 | 1.8 | 2.1 | 2.0 |
挠曲强度(Mpa) | Mpa | 185 | 176 | 170 | 188 | 178 | 170 |
挠曲模量(Mpa) | Mpa | 8450 | 8500 | 870 0 | 8900 | 8600 | 8600 |
UL燃烧等级1.5mm | V0 | V0 | V0 | V0 | V0 | V0 |
组分 | 单位 | C15 | C16 | E15 | E16 |
PBT 195 | % | 27.1 | 24.6 | 26.975 | 24.475 |
PBT315 | % | 27.1 | 24.6 | 26.975 | 24.475 |
THAM | % | 0.25 | 0.25 | ||
丙烯酸类抗冲改性剂:Paraloid EXL 3300 | % | 5 | 5 | ||
溴化PC低聚物,52%Br | % | 10 | 10 | 10 | 10 |
Sb2O3母炼胶;在PBT 195内80% | % | 4 | 4 | 4 | 4 |
包封的PTFE | % | 0.9 | 0.9 | 0.9 | 0.9 |
磷酸锌 | % | 0.6 | 0.6 | 0.6 | 0.6 |
玻璃 | % | 30 | 30 | 30 | 30 |
PETS | % | 0.2 | 0.2 | 0.2 | 0.2 |
AO1010 | % | 0.1 | 0.1 | 0.1 | 0.1 |
性能 | |||||
螺线流动 | cm | 52 | 42.5 | 64 | 63.5 |
250℃下的毛细剪切粘度(1500/s) | pa-s | 233 | 23 1 | 151 | 143 |
伊佐德无缺口(起始) | kJ/m2 | 49.08 | 51.20 | 37.88 | 44.79 |
伊佐德无缺口(在155℃下热老化1周之后) | kJ/m2 | 36.08 | 42.50 | 18.63 | 27.13 |
UL-94(1.5mm) | V0 | V0 | V0 | V0 |
Claims (9)
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US11/216,792 US7825176B2 (en) | 2005-08-31 | 2005-08-31 | High flow polyester composition |
US11/216,792 | 2005-08-31 | ||
PCT/US2006/031119 WO2007027390A1 (en) | 2005-08-31 | 2006-08-10 | High flow polyester composition |
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CN101175804B true CN101175804B (zh) | 2013-06-19 |
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US (3) | US7825176B2 (zh) |
EP (3) | EP1963416B1 (zh) |
JP (1) | JP4829304B2 (zh) |
CN (1) | CN101175804B (zh) |
AT (2) | ATE430778T1 (zh) |
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Families Citing this family (97)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8188172B2 (en) * | 2003-12-17 | 2012-05-29 | Sabic Innovative Plastics Ip B.V. | Polyester compositions, method of manufacture, and uses thereof |
US8034870B2 (en) * | 2003-12-17 | 2011-10-11 | Sabic Innovative Plastics Ip B.V. | Flame-retardant polyester composition |
US20060287494A1 (en) | 2005-06-17 | 2006-12-21 | Crawford Emmett D | Polyester compositions containing high amounts of cyclobutanediol and articles made therefrom |
FR2889537B1 (fr) * | 2005-08-08 | 2007-09-28 | Nexans Sa | Composition resistante au feu notamment pour materiau de cable d'energie et/ou de telecommunication |
US8586701B2 (en) * | 2005-10-28 | 2013-11-19 | Eastman Chemical Company | Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
US7612130B2 (en) * | 2006-10-16 | 2009-11-03 | Sabic Innovative Plastics Ip B.V. | Composition of polyester, aromatic epoxy compound and epoxy-functional polyolefin and/or copolyester |
JP2008280503A (ja) * | 2007-04-12 | 2008-11-20 | Toray Ind Inc | 熱可塑性樹脂組成物およびそれからなる成形品 |
JP5131088B2 (ja) * | 2007-08-31 | 2013-01-30 | 東レ株式会社 | 難燃性熱可塑性ポリエステル樹脂組成物 |
JP5187088B2 (ja) * | 2007-09-27 | 2013-04-24 | 東レ株式会社 | 熱可塑性ポリエステル樹脂組成物 |
WO2009070238A2 (en) | 2007-11-21 | 2009-06-04 | Eastman Chemical Company | Plastic baby bottles, other blow molded articles, and processes for their manufacture |
US8501287B2 (en) | 2007-11-21 | 2013-08-06 | Eastman Chemical Company | Plastic baby bottles, other blow molded articles, and processes for their manufacture |
JP5272715B2 (ja) * | 2007-12-26 | 2013-08-28 | 東レ株式会社 | 熱可塑性ポリエステル樹脂組成物 |
US8642699B2 (en) * | 2008-03-11 | 2014-02-04 | Mitsubishi Rayon Co., Ltd. | Fluidity improver for aromatic polycarbonate resin, process for producing the fluidity improver for aromatic polycarbonate resin, aromatic polycarbonate resin composition, and molded product |
KR100962387B1 (ko) * | 2008-06-05 | 2010-06-10 | 제일모직주식회사 | 폴리유산 수지 조성물 |
US8198371B2 (en) * | 2008-06-27 | 2012-06-12 | Eastman Chemical Company | Blends of polyesters and ABS copolymers |
JP5470532B2 (ja) * | 2008-07-04 | 2014-04-16 | 株式会社高木化学研究所 | 難燃性原着ポリエステル繊維、これを用いた難燃材および難燃性原着ポリエステル繊維の製造方法 |
CN102112545A (zh) * | 2008-07-30 | 2011-06-29 | 纳幕尔杜邦公司 | 共聚醚酯组合物和由其制成的制品 |
US20110180300A1 (en) * | 2008-09-30 | 2011-07-28 | Polyone Corporation | Flame retardant thermoplastic elastomers |
JP5310484B2 (ja) * | 2008-10-31 | 2013-10-09 | 東レ株式会社 | 熱可塑性樹脂組成物 |
US20100159176A1 (en) * | 2008-12-18 | 2010-06-24 | Eastman Chemical Company | Miscible blends of terephthalate polyesters containing 1,4-cyclohexanedimethanol and 2,2,4,4-tetramethylcyclobutane-1,3-diol |
US8895654B2 (en) * | 2008-12-18 | 2014-11-25 | Eastman Chemical Company | Polyester compositions which comprise spiro-glycol, cyclohexanedimethanol, and terephthalic acid |
CN102272216A (zh) * | 2008-12-29 | 2011-12-07 | 巴斯夫欧洲公司 | 环氧树脂中的dopo阻燃剂 |
US8138244B2 (en) * | 2008-12-30 | 2012-03-20 | Sabic Innovative Plastics Ip B.V. | Reinforced polyester compositions, method of manufacture, and articles thereof |
US7829614B2 (en) * | 2008-12-30 | 2010-11-09 | Sabic Innovative Plastics Ip B.V. | Reinforced polyester compositions, methods of manufacture, and articles thereof |
JP5144601B2 (ja) * | 2009-07-17 | 2013-02-13 | ダイセルポリマー株式会社 | 難燃性樹脂組成物 |
US20110147998A1 (en) * | 2009-12-17 | 2011-06-23 | E.I. Du Pont De Nemours And Company | Polyester Compositions with Good Melt Rheological Properties |
JP5607443B2 (ja) * | 2010-05-14 | 2014-10-15 | 帝人株式会社 | カード用基材シートおよび樹脂組成物 |
US8686072B2 (en) | 2010-06-29 | 2014-04-01 | Sabic Innovative Plastics Ip B.V. | Flame resistant polyester compositions, method of manufacture, and articles therof |
US8716378B2 (en) | 2010-06-29 | 2014-05-06 | Sabic Innovative Plastics Ip B.V. | Flame resistant polyester compositions, method of manufacture, and articles thereof |
CN102382438A (zh) | 2010-09-01 | 2012-03-21 | E.I.内穆尔杜邦公司 | 具有改进的熔体流动性的热塑性组合物 |
US8420869B2 (en) | 2010-12-09 | 2013-04-16 | Eastman Chemical Company | Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
US8420868B2 (en) | 2010-12-09 | 2013-04-16 | Eastman Chemical Company | Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
JP5538198B2 (ja) * | 2010-12-09 | 2014-07-02 | 三菱エンジニアリングプラスチックス株式会社 | 難燃性熱可塑性ポリエステル樹脂組成物 |
US8394997B2 (en) | 2010-12-09 | 2013-03-12 | Eastman Chemical Company | Process for the isomerization of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
CN102051038A (zh) * | 2011-01-18 | 2011-05-11 | 华南理工大学 | 高流动改性聚苯醚塑料及其生产方法 |
US8961834B2 (en) | 2011-03-23 | 2015-02-24 | Sabic Global Technologies B.V. | Carbon nanotube masterbatch, preparation thereof, and use in forming electrically conductive thermoplastic composition |
US20120322934A1 (en) | 2011-06-17 | 2012-12-20 | Sabic Innovative Plastics | Process for Preparing Amine-Modified Polyester Resins with Improved Melt Flow |
CN102888086A (zh) * | 2011-07-22 | 2013-01-23 | 纳幕尔杜邦公司 | 具有改进的溶体流动性的阻燃性组合物 |
WO2013032967A1 (en) | 2011-08-29 | 2013-03-07 | Ticona Llc | Cast molded parts formed form a liquid crystalline polymer |
US9057016B2 (en) | 2011-08-29 | 2015-06-16 | Ticona Llc | Melt polymerization of low melt viscosity liquid crystalline polymers |
WO2013032973A1 (en) | 2011-08-29 | 2013-03-07 | Ticona Llc | Aromatic amide compound |
US9074133B2 (en) | 2011-08-29 | 2015-07-07 | Ticona Llc | Thermotropic liquid crystalline polymer with improved low shear viscosity |
TW201313884A (zh) | 2011-08-29 | 2013-04-01 | Ticona Llc | 液晶聚合物之固態聚合 |
US9051514B2 (en) | 2011-08-29 | 2015-06-09 | Ticona Llc | High flow liquid crystalline polymer composition |
WO2013032977A1 (en) | 2011-08-29 | 2013-03-07 | Ticona Llc | Heat-resistant liquid crystalline polymer composition having a low melting temperature |
US9096794B2 (en) | 2011-08-29 | 2015-08-04 | Ticona Llc | High flow liquid crystalline polymer composition |
WO2013032971A1 (en) | 2011-08-29 | 2013-03-07 | Ticona Llc | Melt-extruded substrate for use in thermoformed articles |
JP5616532B2 (ja) | 2011-09-30 | 2014-10-29 | ウィンテックポリマー株式会社 | ポリブチレンテレフタレート樹脂組成物及び溶着体 |
JP2014533325A (ja) | 2011-11-15 | 2014-12-11 | ティコナ・エルエルシー | 低ナフテン系液晶ポリマー組成物 |
KR101996106B1 (ko) | 2011-11-15 | 2019-07-03 | 티코나 엘엘씨 | 치수 공차가 작은 성형 부품에 사용하기 위한 저-나프텐 액정 중합체 조성물 |
US8646994B2 (en) | 2011-11-15 | 2014-02-11 | Ticona Llc | Compact camera module |
TWI534253B (zh) | 2011-11-15 | 2016-05-21 | 堤康那責任有限公司 | 具有改良可燃性效能之富含環烷之液晶聚合物組合物 |
WO2013074470A2 (en) | 2011-11-15 | 2013-05-23 | Ticona Llc | Fine pitch electrical connector and a thermoplastic composition for use therein |
MX357976B (es) | 2011-12-13 | 2018-08-01 | Dow Global Technologies Llc | Composicion de interpolimero de etileno-propileno-dieno. |
CN104662091A (zh) | 2012-06-13 | 2015-05-27 | 纳幕尔杜邦公司 | 具有聚醚醇热稳定剂的热塑性熔融混合组合物 |
US8871874B2 (en) | 2012-06-13 | 2014-10-28 | E I Du Pont De Nemours And Company | Thermoplastic melt-mixed composition with epoxy-amino acid compound heat stabilizer and processes for their preparation |
CN104350096B (zh) | 2012-06-13 | 2017-02-22 | 纳幕尔杜邦公司 | 具有氨基酸热稳定剂的熔融混合的热塑性组合物 |
KR102246137B1 (ko) | 2012-10-16 | 2021-04-28 | 티코나 엘엘씨 | 대전방지성 액체 결정질 중합체 조성물 |
US9493649B2 (en) * | 2012-10-24 | 2016-11-15 | Lg Chem, Ltd. | Polycarbonate resin composition |
WO2014088700A1 (en) | 2012-12-05 | 2014-06-12 | Ticona Llc | Conductive liquid crystalline polymer composition |
KR101539954B1 (ko) * | 2012-12-31 | 2015-07-28 | 제일모직주식회사 | 발광장치 리플렉터용 폴리에스테르 수지 조성물 및 이를 이용한 성형품 |
US9624346B2 (en) * | 2013-01-18 | 2017-04-18 | Kaneka Corporation | Resin composition, resin molded article, and methods respectively for producing these products |
WO2014130275A2 (en) | 2013-02-22 | 2014-08-28 | Ticona Llc | High performance polymer composition with improved flow properties |
WO2014143176A1 (en) | 2013-03-13 | 2014-09-18 | Ticona Llc | Compact camera module |
US9206300B2 (en) | 2013-06-07 | 2015-12-08 | Ticona Llc | High strength thermotropic liquid crystalline polymer |
US20150028247A1 (en) | 2013-07-23 | 2015-01-29 | Sabic Innovative Plastics Ip B.V. | Rigid foam and associated article and method |
CN103351595A (zh) * | 2013-07-30 | 2013-10-16 | 深圳市兴盛迪新材料有限公司 | 一种改进的高流动性聚碳酸酯和abs合金及其制备方法 |
US9175160B2 (en) | 2013-08-28 | 2015-11-03 | Sabic Global Technologies B.V. | Blend of poly(phenylene ether) particles and polyoxymethylene, article thereof, and method of preparation |
US9447227B2 (en) | 2013-10-03 | 2016-09-20 | Sabic Global Technologies B.V. | Flexible polyurethane foam and associated method and article |
JPWO2015114719A1 (ja) * | 2014-01-30 | 2017-03-23 | 株式会社カネカ | ポリエステル樹脂組成物の製造方法およびポリエステル樹脂成形体 |
CN114989431A (zh) | 2014-04-09 | 2022-09-02 | 提克纳有限责任公司 | 抗静电聚合物组合物 |
JP6616322B2 (ja) | 2014-04-09 | 2019-12-04 | ティコナ・エルエルシー | カメラモジュール |
WO2016057680A1 (en) * | 2014-10-07 | 2016-04-14 | Mba Polymers, Inc. | Method for controlling the properties and emission of volatiles from plastics recovered from durable goods |
WO2016077536A1 (en) | 2014-11-14 | 2016-05-19 | Gala Industries, Inc. | Film for bagging tacky materials |
WO2016144309A1 (en) | 2015-03-09 | 2016-09-15 | Sabic Global Technologies B.V. | Compositions and articles of manufacture containing branched polycarbonate |
EP3271419B1 (en) | 2015-03-16 | 2022-08-03 | SHPP Global Technologies B.V. | Fibrillated polymer compositions and methods of their manufacture |
US10920070B2 (en) * | 2015-05-26 | 2021-02-16 | Sabic Global Technologies B.V. | Poly(butylene terephthalate) composition and associated article |
CN105315629A (zh) * | 2015-11-06 | 2016-02-10 | 东华大学 | 一种高流动聚酯组合物及其制备方法 |
WO2017087438A1 (en) | 2015-11-20 | 2017-05-26 | Ticona Llc | High flow polyaryletherketone composition |
FR3053349B1 (fr) | 2016-06-29 | 2020-06-19 | Arkema France | Composition comprenant un polymere thermoplastique, un polymere a phases multiples et un polymere (meth)acrylique, son procede de preparation et son utilisation |
WO2018060155A1 (en) * | 2016-09-30 | 2018-04-05 | Sabic Global Technologies B.V. | Polymer composition comprising poly(butylene terephthalate). |
CN107459783B (zh) * | 2016-12-12 | 2018-07-27 | 金发科技股份有限公司 | 一种聚对苯二甲酸酯-共-癸二酸酯树脂组合物 |
CN106751537A (zh) * | 2016-12-26 | 2017-05-31 | 广东伟的新材料股份有限公司 | 一种纤维增强阻燃塑料及其制备方法 |
US10633535B2 (en) | 2017-02-06 | 2020-04-28 | Ticona Llc | Polyester polymer compositions |
MX2020003338A (es) * | 2017-09-27 | 2020-10-28 | Trinseo Europe Gmbh | Estructuras poliméricas multicapa. |
CN111417681B (zh) | 2017-12-05 | 2023-08-22 | 提克纳有限责任公司 | 用于摄像模组的芳族聚合物组合物 |
WO2019122318A1 (en) * | 2017-12-22 | 2019-06-27 | Sabic Global Technologies B.V. | Tape of a plurality of sheathed continous multifilament strands |
EP3749710A1 (en) | 2018-02-08 | 2020-12-16 | Celanese Sales Germany GmbH | Polymer composite containing recycled carbon fibers |
CN109021567A (zh) * | 2018-07-18 | 2018-12-18 | 长纤(厦门)新材料科技有限公司 | 一种pps树脂长玻纤及其制备方法 |
EP3904097B1 (en) * | 2018-12-26 | 2023-10-25 | Mitsubishi Chemical Corporation | Powder for powder lamination molding, its manufacturing method and use |
EP3786226A1 (en) * | 2019-08-27 | 2021-03-03 | Trinseo Europe GmbH | Stabilized compositions of polycarbonates and vinylidene substituted aromatic compounds |
US11729908B2 (en) | 2020-02-26 | 2023-08-15 | Ticona Llc | Circuit structure |
CN115151414A (zh) | 2020-02-26 | 2022-10-04 | 提克纳有限责任公司 | 用于电子器件的聚合物组合物 |
WO2021173408A1 (en) | 2020-02-26 | 2021-09-02 | Ticona Llc | Electronic device |
US11728065B2 (en) | 2020-07-28 | 2023-08-15 | Ticona Llc | Molded interconnect device |
CN114149676A (zh) * | 2021-12-27 | 2022-03-08 | 常州威材新材料科技有限公司 | 一种薄壁用耐热阻燃增强pc材料及其制备方法 |
CN116948380B (zh) * | 2023-09-20 | 2023-11-24 | 河北华密新材科技股份有限公司 | 一种耐高温型工程塑料及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4338245A (en) * | 1981-08-12 | 1982-07-06 | Borg-Warner Chemicals, Inc. | Intumescent flame retardant thermoplastic polyester compositions |
EP0069297A1 (en) * | 1981-07-08 | 1983-01-12 | General Electric Company | Melt viscosity control in flame retarded polybutylene terephthalate |
US5681879A (en) * | 1994-07-07 | 1997-10-28 | Mitsubishi Chemical Corporation | Flame-retardant polyester resin composition |
US20030004244A1 (en) * | 1999-04-29 | 2003-01-02 | Sahar Al-Malaika | Thermoplastic molding compositions and polymer additives |
US20030032737A1 (en) * | 1999-06-30 | 2003-02-13 | Stephen Andrews | Polyester compositions of low residual aldehyde content |
Family Cites Families (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2465319A (en) * | 1941-07-29 | 1949-03-22 | Du Pont | Polymeric linear terephthalic esters |
US3078254A (en) * | 1959-07-20 | 1963-02-19 | Phillips Petroleum Co | High molecular polymers and method for their preparation |
BE627652A (zh) * | 1962-01-29 | |||
US3297793A (en) * | 1962-12-21 | 1967-01-10 | Phillips Petroleum Co | Continuous process for producing block copolymers of dienes and vinyl aromatic compounds |
US3402159A (en) * | 1963-12-20 | 1968-09-17 | Phillips Petroleum Co | Process for polymerizing butadiene and styrene terminated in short blocks of polystyrene |
US3635895A (en) * | 1965-09-01 | 1972-01-18 | Gen Electric | Process for preparing thermoplastic polycarbonates |
DE1273193C2 (de) * | 1965-11-25 | 1976-03-18 | Enko Glanzstoff AG, 5600 Wuppertal | Verwendung von formmassen aus polyaethylenterephthalat und polymeren olefinen fuer spritzgussmassen |
US3594452A (en) * | 1968-02-06 | 1971-07-20 | Shell Oil Co | Polymers prepared from monolithiumterminated block copolymers and certain diesters |
BE747591A (fr) | 1969-04-01 | 1970-09-21 | Shell Int Research | Blokcopolymeren met eindstandige statistische copolymeerblokkenvan styreen en alfa-methylstyreen |
US3769260A (en) * | 1972-06-13 | 1973-10-30 | Allied Chem | Impact-resistant polyethylene terephthalate compositions |
JPS559435B2 (zh) * | 1972-08-30 | 1980-03-10 | ||
US4001184A (en) * | 1975-03-31 | 1977-01-04 | General Electric Company | Process for preparing a branched polycarbonate |
US4172859A (en) * | 1975-05-23 | 1979-10-30 | E. I. Du Pont De Nemours And Company | Tough thermoplastic polyester compositions |
DE2712171C2 (de) * | 1977-03-19 | 1984-09-27 | Bayer Ag, 5090 Leverkusen | Thermoplastische Formmassen |
US4119607A (en) * | 1977-05-05 | 1978-10-10 | Shell Oil Company | Multicomponent polyester- block copolymer- polymer blends |
US4154775A (en) | 1977-09-06 | 1979-05-15 | General Electric Company | Flame retardant composition of polyphenylene ether, styrene resin and cyclic phosphate |
US4364280A (en) * | 1979-05-08 | 1982-12-21 | Kutsay Ali U | Double shear beam strain gage load cell |
DE2927576A1 (de) * | 1979-07-07 | 1981-01-15 | Bayer Ag | Hochschlagzaehes polybutylenterephthalat |
US4264487A (en) * | 1979-09-07 | 1981-04-28 | Rohm And Haas Company | Acrylate rubber modification of aromatic polyesters |
US4327764A (en) * | 1980-05-21 | 1982-05-04 | Superpressure, Inc. | Float valve assembly for a liquid drain trap |
WO1985003718A1 (en) | 1984-02-24 | 1985-08-29 | E. I. Du Pont De Nemours And Company | Toughened thermoplastic polyester compositions |
US4739012A (en) * | 1986-02-21 | 1988-04-19 | E. I. Du Pont De Nemours And Company | Elastomer blends |
JPH0726008B2 (ja) * | 1987-03-31 | 1995-03-22 | 住友化学工業株式会社 | 熱可塑性樹脂組成物の製造法 |
DE69120732T2 (de) * | 1990-04-26 | 1996-12-05 | Mitsubishi Chem Corp | Polyethylenterephthalatzusammensetzung |
AU658436B2 (en) | 1991-07-18 | 1995-04-13 | General Electric Company | Stabilization of polyesters using epoxy compounds in combination with a catalyst |
CA2103420A1 (en) * | 1992-12-22 | 1994-06-23 | Eileen B. Walsh | Stabilization of low molecular weight polybutylene terephthalate/polyester blends with phosphorus compounds |
US5354791A (en) * | 1993-10-19 | 1994-10-11 | General Electric Company | Epoxy-functional polyester, polycarbonate with metal phosphate |
US5424344A (en) * | 1994-01-05 | 1995-06-13 | E. I. Dupont De Nemours And Company | Flame retardant polyamide compositions |
EP0682057A1 (en) | 1994-05-09 | 1995-11-15 | Dsm N.V. | Process for improvement of the processing characteristics of a polymer composition and polymer compositions obtained therefrom |
JP3451799B2 (ja) * | 1994-07-07 | 2003-09-29 | 三菱化学株式会社 | 難燃性ポリエステル樹脂組成物 |
FR2733504A1 (fr) * | 1995-04-28 | 1996-10-31 | Gen Elec Plastics Abs Euro Bv | Nouveaux alliages polymeres a base de polymerisat comprenant des motifs de derives de tetrafluoroethylene, procede de fabrication, articles obtenus a partir de tels alliages et utilisation de ces alliages dans des compositions polymeres |
US6025419A (en) * | 1997-04-07 | 2000-02-15 | E. I. Du Pont De Nemours And Company | Flame retardant resin compositions |
JPH10310690A (ja) | 1997-05-08 | 1998-11-24 | Kanebo Ltd | 熱可塑性樹脂組成物 |
DE19854170A1 (de) * | 1998-11-24 | 2000-05-25 | Basf Ag | Thermoplastische Nanocomposites |
JP4284808B2 (ja) | 1999-03-30 | 2009-06-24 | 宇部興産株式会社 | 射出溶着用材料 |
DE19933901A1 (de) | 1999-07-22 | 2001-02-01 | Clariant Gmbh | Flammschutzmittel-Kombination |
JP2001040191A (ja) * | 1999-07-28 | 2001-02-13 | Polyplastics Co | 難燃性ポリエステル樹脂組成物 |
US6444737B1 (en) * | 2000-04-05 | 2002-09-03 | 3M Innovative Properties Company | Water-dispersed polymer stabilizer |
JP5177931B2 (ja) * | 2002-01-24 | 2013-04-10 | 東レ株式会社 | 脂肪族ポリエステル樹脂組成物およびそれからなる成形品 |
US6822025B2 (en) * | 2002-11-27 | 2004-11-23 | General Electric Company | Flame retardant resin compositions |
JP2005133039A (ja) * | 2003-10-31 | 2005-05-26 | Toray Ind Inc | 脂肪族ポリエステル樹脂組成物成形体 |
-
2005
- 2005-08-31 US US11/216,792 patent/US7825176B2/en active Active
-
2006
- 2006-08-10 EP EP06789648A patent/EP1963416B1/en not_active Not-in-force
- 2006-08-10 JP JP2008529063A patent/JP4829304B2/ja not_active Expired - Fee Related
- 2006-08-10 AT AT06789648T patent/ATE430778T1/de not_active IP Right Cessation
- 2006-08-10 EP EP09154722A patent/EP2088168B1/en not_active Not-in-force
- 2006-08-10 DE DE602006006720T patent/DE602006006720D1/de active Active
- 2006-08-10 EP EP10190933.1A patent/EP2287243B1/en not_active Not-in-force
- 2006-08-10 CN CN2006800166087A patent/CN101175804B/zh not_active Expired - Fee Related
- 2006-08-10 AT AT09154722T patent/ATE515531T1/de not_active IP Right Cessation
- 2006-08-10 WO PCT/US2006/031119 patent/WO2007027390A1/en active Application Filing
- 2006-10-16 US US11/581,245 patent/US7405249B2/en active Active
- 2006-10-16 US US11/581,730 patent/US7405250B2/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0069297A1 (en) * | 1981-07-08 | 1983-01-12 | General Electric Company | Melt viscosity control in flame retarded polybutylene terephthalate |
US4338245A (en) * | 1981-08-12 | 1982-07-06 | Borg-Warner Chemicals, Inc. | Intumescent flame retardant thermoplastic polyester compositions |
US5681879A (en) * | 1994-07-07 | 1997-10-28 | Mitsubishi Chemical Corporation | Flame-retardant polyester resin composition |
US20030004244A1 (en) * | 1999-04-29 | 2003-01-02 | Sahar Al-Malaika | Thermoplastic molding compositions and polymer additives |
US20030032737A1 (en) * | 1999-06-30 | 2003-02-13 | Stephen Andrews | Polyester compositions of low residual aldehyde content |
Non-Patent Citations (1)
Title |
---|
JP特开平10-310690A 1998.11.24 |
Also Published As
Publication number | Publication date |
---|---|
EP2287243B1 (en) | 2014-10-29 |
EP1963416A1 (en) | 2008-09-03 |
EP2287243A1 (en) | 2011-02-23 |
EP1963416B1 (en) | 2009-05-06 |
EP2088168B1 (en) | 2011-07-06 |
US20070049667A1 (en) | 2007-03-01 |
CN101175804A (zh) | 2008-05-07 |
EP2088168A1 (en) | 2009-08-12 |
US20070049701A1 (en) | 2007-03-01 |
ATE430778T1 (de) | 2009-05-15 |
WO2007027390A1 (en) | 2007-03-08 |
DE602006006720D1 (de) | 2009-06-18 |
JP2009506191A (ja) | 2009-02-12 |
JP4829304B2 (ja) | 2011-12-07 |
US7405250B2 (en) | 2008-07-29 |
US7405249B2 (en) | 2008-07-29 |
ATE515531T1 (de) | 2011-07-15 |
US20070049702A1 (en) | 2007-03-01 |
US7825176B2 (en) | 2010-11-02 |
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