CN101175804A - 高流动性聚酯组合物 - Google Patents
高流动性聚酯组合物 Download PDFInfo
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- CN101175804A CN101175804A CNA2006800166087A CN200680016608A CN101175804A CN 101175804 A CN101175804 A CN 101175804A CN A2006800166087 A CNA2006800166087 A CN A2006800166087A CN 200680016608 A CN200680016608 A CN 200680016608A CN 101175804 A CN101175804 A CN 101175804A
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- 229920003251 poly(α-methylstyrene) Polymers 0.000 description 1
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- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
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- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 description 1
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- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
Abstract
Description
缩写 | 材料 |
PBT195PBT315PC100季戊四醇THAMAO1010玻璃纤维PEP-QPETSS2001ABS | 获自General Electric Company的聚(对苯二甲酸1,4-丁二酯),其特性粘度为0.7cm3/g,这在60∶40的苯酚/四氯乙烷混合物内测量。获自General Electric Company的聚(对苯二甲酸1,4-丁二酯),其特性粘度为1.2cm3/g,这在60∶40的苯酚/四氯乙烷混合物内测量。获自General Electric Company的PC双酚聚碳酸酯Lexan树脂,通过GPC,相对于聚苯乙烯标样测量的Mn为29Kg/mol。四(羟甲基)甲烷;2,2-双(羟甲基)-1,3-丙二醇购自Aldrich Chemical Company,USA的三羟甲基氨基甲烷受阻酚,季戊四醇四(3,5-二叔丁基-4-羟基氢化肉桂酸酯),由Ciba Geigy以IRAGANOX 1010销售直径为10或13微米的E玻璃纤维。施胶剂涂布的玻璃纤维例如以OCF K长丝玻璃纤维183F形式商购于OwensComing Fiberglass四(2,4-二叔丁基苯基)4,4’-亚联苯二亚膦酸酯,获自Clariant Chemicals的SANDOSTAB PEPQ。季戊四醇四硬脂酸酯具有硅酮-丙烯酸基橡胶的核壳型抗冲改性剂,获自Mitsubishi Rayon的METABLEN S-2001。丙烯腈-丁二烯-苯乙烯共聚物抗冲改性剂,由General |
MBS丙烯酸类抗冲改性剂 | Electric以VHRG或HRG SG24或HRG360形式销售具有核壳结构的甲基丙烯酸酯-丁二烯-苯乙烯乳液共聚物抗冲改性剂,由Rohm&Haas以EXL2691或EXL2650A形式销售。获自Rohm and Haas的丙烯酸类抗冲改性剂EXL3330,具有核壳结构的甲基丙烯酸酯-丙烯酸丁酯的乳液共聚物。 |
组分 | 单位 | C1 | C2 | E1 | E2 | E3 | E4 | E5 |
PBT315 | % | 100 | 99.5 | 99.9 | 99.8 | 99.7 | 99.5 | 99.0 |
THAM | % | 0.0 | 0.0 | 0.1 | 0.2 | 0.3 | 0.5 | 1.0 |
季戊四醇 | % | 0.0 | 0.5 | - | - | - | - | - |
性能 | ||||||||
螺线流动 | cm | 27 | 42 | 29 | 33 | 38 | 55 | 90 |
在265℃/2.16Kg/240s下的熔体体积速率(MVR) | cc/10min | 5.6 | 17.5 | 7.5 | 9.9 | 11.5 | 37.0 | 67.0 |
拉伸模量 | GPa | 2.6 | 2.75 | 2.6 | 2.58 | 2.65 | 2.83 | 2.88 |
伸长率% | % | 51 | 21 | 36.1 | 33.4 | 31.2 | 14.7 | 3.2 |
在23℃下的伊佐德无缺口抗冲强度 | kJ/m2 | 210 | 170 | 186 | 180 | 176 | 128 | 43 |
组分 | 单位 | C5 | C6 | E6 | C7 | C8 | E7 |
PBT-315 | % | 75 | 74.75 | 74.75 | 65 | 64.75 | 64.75 |
玻璃 | % | 25 | 25 | 25 | 25 | 25 | 25 |
季戊四醇 | % | 0.25 | 0.25 | ||||
THAM | % | 0.25 | 0.25 | ||||
ABS HRG360 | % | 10 | 10 | 10 | |||
AO1010 | % | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 |
性能 | |||||||
在265℃/2.16Kg/240s下的熔体体积速率(MVR) | cc/10min | 5.2 | 12.7 | 18 | 2.2 | 6.1 | 7.9 |
螺线流动 | cm | 53 | 77 | 91 | 49 | 75 | 89 |
拉伸模量 | GPa | 5.91 | 6.19 | 6.3 | 6.19 | 5.71 | 5.71 |
抗拉强度 | GPa | 94 | 94 | 94.4 | 82 | 79 | 79 |
伸长率% | % | 5.4 | 4.4 | 4.3 | 4.9 | 4.3 | 4.3 |
挠曲模量 | GPa | 5.52 | 5.81 | 5.85 | 5.34 | 5.15 | 5.27 |
挠曲强度 | GPa | 149.8 | 150.7 | 153 | 128.7 | 125.5 | 126.5 |
HDT | ℃ | 148 | 157 | 165 | 154 | 150 | 155 |
伊佐德无缺口抗冲强度(KJ/m2),23℃ | kJ/m2 | 49 | 34 | 28 | 45 | 40 | 40 |
组分 | 单位 | C9 | E8 |
PC100 | % | 75 | 74.75 |
PBT-315 | % | 25 | 25 |
THAM | % | 0.25 | |
性能 | |||
在265℃/2.16Kg/240s下的熔体体积速率(MVR) | cc/10min | 6 | 28 |
螺线流动 | cm | 34 | 63 |
拉伸模量 | GPa | 2.41 | 2.61 |
伸长率% | % | 79 | 75 |
在23℃下的伊佐德无缺口抗冲强度 | kJ/2 | 250 | 255 |
组分 | 单位 | C10 | C11 | C12 | E9 | E10 |
PBT-195 | % | 69.7 | 59.7 | 59.2 | 59.2 | 59.2 |
季戊四醇 | % | 0.5 | 0.5 | 0.5 | ||
丙烯酸类抗冲改性剂:Paraloid EXL 3300 | % | 10 | 10 | |||
MBS paraloid EXL2650A | % | 10 | ||||
Metablen S2001硅酮抗冲改性剂 | % | |||||
ABS HRG SG24 | % | 10 | ||||
玻璃:标准结晶玻璃 | % | 30 | 30 | 30 | 30 | 30 |
添加剂 | % | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 |
性能 | ||||||
在265℃/2.16Kg/240s下的熔体体积速率(MVR) | cc/10min | 30 | 7 | 21 | 31 | 32.5 |
280℃下的毛细剪切粘度 | pa-s | 84 | 91 | 46 | 42 | 53 |
(1500/s) | ||||||
伊佐德无缺口(kJ/m2) | kJ/m2 | 40 | 54 | 42 | 46 | 44 |
热老化的伊佐德无缺口(155℃1周) | kJ/m2 | 30 | 50 | 22 | 47 | 22 |
抗拉强度(Mpa) | Mpa | 146 | 121 | 116 | 120 | 116 |
热老化的抗拉强度(155℃1周) | Mpa | 157 | 133 | 119 | 118 | 110 |
拉伸模量(Mpa) | Mpa | 9350 | 8580 | 8600 | 8590 | 8750 |
挠曲强度(Mpa) | Mpa | 217 | 191 | 172 | 182 | 175 |
挠曲模量(Mpa) | Mpa | 8450 | 7700 | 7700 | 7800 | 7900 |
组分 | 单位 | C13 | E11 | E12 | C14 | E13 | E14 |
PBT 195 | % | 49.2 | 48.7 | 48.7 | 49.3 | 48.8 | 48.8 |
季戊四醇 | % | 0.5 | 0.5 | 0.5 | 0.5 | ||
丙烯酸类抗冲改性剂:Paraloid EXL 3300 | % | 5 | 5 | 5 | 5 | ||
MBS | - | - | 5 | - | - | 5 | |
溴化PC低聚物,52%Br | % | 10 | 10 | 10 | |||
溴化丙烯酸酯聚(五溴苄基丙烯酸酯) | % | 10.5 | 10.5 | 10.5 | |||
Sb2O3母炼胶;在PBT 195内80% | % | 4 | 4 | 4 | 4.2 | 4.2 | 4.2 |
包封的PTFE | % | 0.9 | 0.9 | 0.9 | 0.7 | 0.7 | 0.7 |
磷酸锌 | % | 0.6 | 0.6 | 0.6 |
玻璃 | % | 30 | 30 | 30 | 30 | 30 | 30 |
添加剂 | % | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 |
性能 | |||||||
熔体体积速率(250℃,2.16Kg,240s) | cc/min | 4 | 12 | 8 | 6 | 15 | 9 |
伊佐德无缺口 | kJ/m2 | 39 | 34 | 26 | 42 | 38 | 32 |
热老化的伊佐德无缺口(155℃1周) | kJ/m2 | 29 | 26 | 23 | 34 | 26 | 25 |
热老化的伊佐德无缺口(155℃2周) | kJ/m2 | 34 | 35 | 25 | 37 | 28 | 21 |
抗拉强度(Mpa) | Mpa | 122 | 116 | 114 | 124 | 122 | 118 |
拉伸模量(Mpa) | Mpa | 10165 | 10415 | 10489 | 10350 | 10355 | 10307 |
拉伸伸长率 | % | 2.2 | 1.6 | 1.6 | 1.8 | 2.1 | 2.0 |
挠曲强度(Mpa) | Mpa | 185 | 176 | 170 | 188 | 178 | 170 |
挠曲模量(Mpa) | Mpa | 8450 | 8500 | 8700 | 8900 | 8600 | 8600 |
UL燃烧等级1.5mm | V0 | V0 | V0 | V0 | V0 | V0 |
组分 | 单位 | C15 | C16 | E15 | E16 |
PBT 195 | % | 27.1 | 24.6 | 26.975 | 24.475 |
PBT315 | % | 27.1 | 24.6 | 26.975 | 24.475 |
THAM | % | 0.25 | 0.25 | ||
丙烯酸类抗冲改性剂:Paraloid EXL 3300 | % | 5 | 5 | ||
溴化PC低聚物,52%Br | % | 10 | 10 | 10 | 10 |
Sb2O3母炼胶;在PBT 195内80% | % | 4 | 4 | 4 | 4 |
包封的PTFE | % | 0.9 | 0.9 | 0.9 | 0.9 |
磷酸锌 | % | 0.6 | 0.6 | 0.6 | 0.6 |
玻璃 | % | 30 | 30 | 30 | 30 |
PETS | % | 0.2 | 0.2 | 0.2 | 0.2 |
AO1010 | % | 0.1 | 0.1 | 0.1 | 0.1 |
性能 | |||||
螺线流动 | cm | 52 | 42.5 | 64 | 63.5 |
250℃下的毛细剪切粘度(1500/s) | pa-s | 233 | 23 1 | 151 | 143 |
伊佐德无缺口(起始) | kJ/m2 | 49.08 | 51.20 | 37.88 | 44.79 |
伊佐德无缺口(在155℃下热老化1周之后) | kJ/m2 | 36.08 | 42.50 | 18.63 | 27.13 |
UL-94(1.5mm) | V0 | V0 | V0 | V0 |
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US11/216,792 US7825176B2 (en) | 2005-08-31 | 2005-08-31 | High flow polyester composition |
PCT/US2006/031119 WO2007027390A1 (en) | 2005-08-31 | 2006-08-10 | High flow polyester composition |
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- 2006-08-10 EP EP09154722A patent/EP2088168B1/en not_active Not-in-force
- 2006-08-10 EP EP06789648A patent/EP1963416B1/en not_active Not-in-force
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- 2006-10-16 US US11/581,245 patent/US7405249B2/en active Active
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CN102382438A (zh) * | 2010-09-01 | 2012-03-21 | E.I.内穆尔杜邦公司 | 具有改进的熔体流动性的热塑性组合物 |
CN102051038A (zh) * | 2011-01-18 | 2011-05-11 | 华南理工大学 | 高流动改性聚苯醚塑料及其生产方法 |
CN102888086A (zh) * | 2011-07-22 | 2013-01-23 | 纳幕尔杜邦公司 | 具有改进的溶体流动性的阻燃性组合物 |
CN103814079A (zh) * | 2011-09-30 | 2014-05-21 | 胜技高分子株式会社 | 聚对苯二甲酸丁二醇酯树脂组合物和熔接体 |
US9434839B2 (en) | 2011-09-30 | 2016-09-06 | Wintech Polymer Ltd. | Polybutylene terephthalate resin composition and welded body |
CN103930465A (zh) * | 2011-11-15 | 2014-07-16 | 提克纳有限责任公司 | 用于具有小尺寸公差的模塑部件的低环烷液晶聚合物组合物 |
TWI686441B (zh) * | 2014-11-14 | 2020-03-01 | 美商葛拉工業公司 | 黏性物質裝袋用的膜 |
US11383496B2 (en) | 2014-11-14 | 2022-07-12 | Maag Gala, Inc. | Film for bagging tacky materials |
CN105315629A (zh) * | 2015-11-06 | 2016-02-10 | 东华大学 | 一种高流动聚酯组合物及其制备方法 |
CN116948380A (zh) * | 2023-09-20 | 2023-10-27 | 河北华密新材科技股份有限公司 | 一种耐高温型工程塑料及其制备方法 |
CN116948380B (zh) * | 2023-09-20 | 2023-11-24 | 河北华密新材科技股份有限公司 | 一种耐高温型工程塑料及其制备方法 |
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JP2009506191A (ja) | 2009-02-12 |
ATE430778T1 (de) | 2009-05-15 |
US7405250B2 (en) | 2008-07-29 |
ATE515531T1 (de) | 2011-07-15 |
JP4829304B2 (ja) | 2011-12-07 |
EP2287243A1 (en) | 2011-02-23 |
US20070049701A1 (en) | 2007-03-01 |
CN101175804B (zh) | 2013-06-19 |
EP2088168B1 (en) | 2011-07-06 |
EP1963416A1 (en) | 2008-09-03 |
WO2007027390A1 (en) | 2007-03-08 |
EP2088168A1 (en) | 2009-08-12 |
US20070049702A1 (en) | 2007-03-01 |
US7405249B2 (en) | 2008-07-29 |
DE602006006720D1 (de) | 2009-06-18 |
EP1963416B1 (en) | 2009-05-06 |
EP2287243B1 (en) | 2014-10-29 |
US7825176B2 (en) | 2010-11-02 |
US20070049667A1 (en) | 2007-03-01 |
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