CN101124282A - 光学透明聚碳酸酯聚酯组合物 - Google Patents
光学透明聚碳酸酯聚酯组合物 Download PDFInfo
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- CN101124282A CN101124282A CNA2005800484850A CN200580048485A CN101124282A CN 101124282 A CN101124282 A CN 101124282A CN A2005800484850 A CNA2005800484850 A CN A2005800484850A CN 200580048485 A CN200580048485 A CN 200580048485A CN 101124282 A CN101124282 A CN 101124282A
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- polyester
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- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- ILMRJRBKQSSXGY-UHFFFAOYSA-N tert-butyl(dimethyl)silicon Chemical group C[Si](C)C(C)(C)C ILMRJRBKQSSXGY-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 description 1
- 125000005497 tetraalkylphosphonium group Chemical group 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 238000009757 thermoplastic moulding Methods 0.000 description 1
- 125000002813 thiocarbonyl group Chemical group *C(*)=S 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium(II) oxide Chemical compound [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/445—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences
- C08G77/448—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences containing polycarbonate sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
Abstract
Description
组成 | 对比例1 | 对比例2 | 对比例3 | 对比例4 | 对比例5 | 对比例6 |
聚碳酸酯 | 41.7 | 16.7 | 46.1 | 20 | - | - |
PCCD | - | - | 46.1 | 21.7 | 41.7 | 16.7 |
硅氧烷改性的聚碳酸酯 | 58 | 83 | - | 58 | 58 | 83 |
ABS415 | - | - | 7 | - | - | - |
性能 | ||||||
MVR@265℃,2.16kg -4min[cm3/10min] | 8.5 | 6.2 | 14.3 | 10.8 | 12.9 | 7.6 |
伊佐德缺口冲击@23℃[kJ/m2] | 59.0 | 56.2 | 63.0 | 63.3 | 67.1 | 58.8 |
伊佐德缺口冲击@0℃[kJ/m2] | 50.8 | 50.1 | 56.2 | 44.8 | 13.0 | 49.0 |
伊佐德缺口冲击@-10℃[kJ/m2] | 46.2 | 46.7 | 50.9 | 16.8 | 12.6 | 41.1 |
伊佐德缺口冲击@-20℃[kJ/m2] | 31.2 | 41.5 | 19.4 | 14.3 | 10.7 | 17.6 |
伊佐德缺口冲击@-25℃[kJ/m2] | 22.4 | 38.7 | 17.4 | 13.5 | 10.0 | 17.0 |
刺穿冲击强度(4.4m/s)@23℃[J] | 124.9 | 122.2 | 121.0 | 123.5 | 122.1 | 120.5 |
刺穿冲击强度(4.4m/s)@-30℃[J] | 92.4 | 93.2 | 60.5 | 100.1 | 99.1 | 97.5 |
透射率@2.5mm,[%] | 86.0 | 86.1 | 88.4 | 89.2 | 90.8 | 88.8 |
雾度 | 2.2 | 2.3 | 4.2 | 1.1 | 1.0 | 1.3 |
透射,YI@2.5mm | 7.4 | 7.9 | 4.6 | 4.3 | 2.5 | 4.9 |
反射,YI@2.5mm | -7 | -8.1 | 0.5 | -2.7 | -1.5 | -3.2 |
B-Y跨度 | 14.4 | 16 | 4.1 | 7 | 4 | 8.1 |
组成 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 |
聚碳酸酯 | 21.1 | 6.1 | 31.1 | 18.1 | 10.7 |
PCCD | 46.6 | 46.6 | 46.6 | 46.6 | 42.0 |
硅氧烷改性的聚碳酸酯 | 25 | 42 | 17 | 30 | 42 |
ABS415 | 7 | 5 | 5 | 5 | 5 |
性能 | |||||
MVR@265℃,2.16kg -4min[cm3/10min] | 11.8 | 12.1 | 15.2 | 13.8 | 11.7 |
伊佐德缺口冲击@23℃[kJ/m2] | 71.7 | 78.6 | 79.3 | 80.9 | 71.1 |
伊佐德缺口冲击@0℃[kJ/m2] | 62.9 | 67.5 | 67.9 | 70.1 | 61.9 |
伊佐德缺口冲击@-10℃[kJ/m2] | 58.8 | 61.4 | 62.9 | 62.2 | 58.5 |
伊佐德缺口冲击@-20℃[kJ/m2] | 49.4 | 46.6 | 19.1 | 46.7 | 50.0 |
伊佐德缺口冲击@-25℃[kJ/m2] | 33.4 | 23.8 | 19.3 | 19.3 | 39.4 |
刺穿冲击强度(4.4m/s)@23℃[J] | 118.4 | 113.3 | 119.9 | 127.1 | 113.8 |
刺穿冲击强度(4.4m/s)@-30℃[J] | 103.7 | 113.0 | 118.1 | 116.3 | 115.0 |
透射率@2.5mm,[%] | 90.0 | 90.1 | 89.8 | 90.4 | 89.6 |
雾度 | 1.8 | 1.8 | 2.3 | 1.7 | 2.4 |
透射,YI@2.5mm | 4.4 | 4.0 | 4.0 | 3.9 | 4.4 |
反射,YI@2.5mm | 0.4 | 0.1 | -0.1 | 0.1 | -0.3 |
B-Y跨度 | 4 | 3.9 | 4.1 | 3.8 | 4.7 |
Claims (30)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/017,555 US7718733B2 (en) | 2004-12-20 | 2004-12-20 | Optically clear polycarbonate polyester compositions |
US11/017,555 | 2004-12-20 | ||
PCT/US2005/045528 WO2006073728A2 (en) | 2004-12-20 | 2005-12-15 | Optically clear polycarbonate polyester compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101124282A true CN101124282A (zh) | 2008-02-13 |
CN101124282B CN101124282B (zh) | 2013-01-09 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN2005800484850A Active CN101124282B (zh) | 2004-12-20 | 2005-12-15 | 光学透明聚碳酸酯聚酯组合物 |
Country Status (8)
Country | Link |
---|---|
US (1) | US7718733B2 (zh) |
EP (1) | EP1831309B1 (zh) |
JP (1) | JP5490992B2 (zh) |
KR (2) | KR20130079621A (zh) |
CN (1) | CN101124282B (zh) |
AT (1) | ATE417079T1 (zh) |
DE (1) | DE602005011674D1 (zh) |
WO (1) | WO2006073728A2 (zh) |
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- 2005-12-15 JP JP2007546921A patent/JP5490992B2/ja not_active Expired - Fee Related
- 2005-12-15 CN CN2005800484850A patent/CN101124282B/zh active Active
- 2005-12-15 KR KR1020137013971A patent/KR20130079621A/ko not_active Application Discontinuation
- 2005-12-15 DE DE602005011674T patent/DE602005011674D1/de active Active
- 2005-12-15 AT AT05857085T patent/ATE417079T1/de not_active IP Right Cessation
- 2005-12-15 WO PCT/US2005/045528 patent/WO2006073728A2/en active Application Filing
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Also Published As
Publication number | Publication date |
---|---|
ATE417079T1 (de) | 2008-12-15 |
WO2006073728A3 (en) | 2006-08-31 |
DE602005011674D1 (de) | 2009-01-22 |
JP2008524397A (ja) | 2008-07-10 |
JP5490992B2 (ja) | 2014-05-14 |
KR101341719B1 (ko) | 2013-12-16 |
EP1831309B1 (en) | 2008-12-10 |
EP1831309A2 (en) | 2007-09-12 |
KR20130079621A (ko) | 2013-07-10 |
US7718733B2 (en) | 2010-05-18 |
KR20070100747A (ko) | 2007-10-11 |
CN101124282B (zh) | 2013-01-09 |
US20060135690A1 (en) | 2006-06-22 |
WO2006073728A2 (en) | 2006-07-13 |
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