CN100548262C - Multi phase personal care composition - Google Patents

Abstract

The present invention relates to multi phase personal care composition, described compositions comprises at least two visually distinct phases, and wherein at least one comprises granule mutually.These form pattern mutually, and with the packaged of actual contact, keep stable for a long time simultaneously.

Description

Multi phase personal care composition

Invention field

The present invention relates to multi phase personal care composition, described compositions comprises at least two visually distinct phases, and wherein this biphase packaged with actual contact keeps stable simultaneously for a long time.

Background of invention

Personal care composition is to know and widely used.These compositionss have been used for cleaning and wet skin, delivery of active substances for a long time, have been covered up flaw, and are used to reduce the hair oil relevant with sebum/shinny.Personal care composition also has been used to change the color and the outward appearance of skin.

Though prior art combinations and disclosure provide useful progress in the personal care composition field, but still need outward appearance and dermal sensation are sent the improved personal care composition that improves effect at once in addition, it will effectively be deposited on all sites of health.Described compositions also needs not have oil and is easy to coating.Therefore, need provide a kind of personal care composition, its blend of particles that comprises selected content with provide unique luminous reflectance, gamut or decortication to increase all skin types brightness and improve skin clean.In addition, also needing to provide a kind of comprises particulate personal care composition and makes brilliance and gloss maximization on the skin.

Provide heterogeneous compositions to keep a kind of trial of stability to be to use dual compartment package simultaneously by the personal care product.These packings mainly comprise and are included in the different compartments independently Cleasing compositions and care composition, and allow these two kinds of compositionss single or bifilar in distribute jointly.Thereby, independently care composition and Cleasing compositions are between the secular storage life and before using just, kept physically separation and stable, but then mixed between allotment period or after distributing, provide conditioning and cleaning beneficial effect by the system of physically stable.Though compare the conditioning beneficial effect that above-mentioned pair of chamber delivery system can provide improvement with using conventional system, inaccessible one uniform performance of making peace usually is because inhomogeneous from the cleansing phase and the distribution ratio between the conditioning mutually of these dual compartment packages.In addition, these packaging systems have increased sizable cost to finished product.

Also need by means of in the shower or the compositions of using in taking a shower send above-mentioned skin condition, cleaning and outward appearance beneficial effect.Therefore, still need stable multi phase personal care composition, head retention and improved bubbling character and skin beneficiating effect that it provides cleaning to have increase simultaneously, for example, silkiness dermal sensation, improved soft dermal sensation and improved glabrous skin sensation, and provide unique luminous reflectance, gamut and decortication to increase brightness to all skin types.Have now found that, can prepare and comprise the biphase at least of actual contact and can keep stable multi-phase personal cleansing compositions for a long time.

Therefore the purpose of this invention is to provide and comprise at least two multi phase personal care compositions of distinct phase visually, wherein at least one granule that comprises mutually, wherein this biphase packaged with actual contact keeps stable simultaneously, wherein can prepare described compositions in coating process and after the coating, to provide improved cosmetic result and dermal sensation, good skin condition and cleaning beneficial effect also is provided simultaneously, and makes all cortex types have brightness.Find that above-mentioned composition can use enough high-load beneficial agent preparation, and can not influence the foaming effect and the stability of product.

Summary of the invention

The present invention relates to a kind of multi phase personal care composition, described compositions comprises at least two visually distinct phases;

Wherein these form pattern mutually;

Wherein at least one granule that comprises mutually;

Wherein said granule exists with the beauty treatment effective dose; With

Wherein said biphase with actual contact each other packaged and keep stability.

The invention further relates to a kind of biphase at least multi phase personal care composition that comprises, wherein at least one coloring agent that comprises mutually, wherein biphase being contained in makes the macroscopic pattern of biphase formation in the packing.

The invention further relates to a kind of multi phase personal care composition, described compositions comprises at least two visually distinct phases;

Wherein these form pattern mutually;

Wherein at least one granule that comprises mutually;

Wherein first is about 90: 10 to about 10: 90 with second mutually the ratio mutually; With

Wherein said biphase with actual contact each other packaged and keep stability.

The invention further relates to a kind of multi phase personal care composition, described compositions comprises:

A) comprise first phase of cleansing phase, described cleansing phase comprises the surfactant by the weight of described cleansing phase about 1% to about 50%, and described surfactant is selected from anion surfactant, non-ionic surface active agent, zwitterionic surfactant, cationic surfactant, soap and their mixture;

Wherein cleansing phase is the non newtonian shear thinning, and it is about 3 that viscosity is equal to or greater than, 000cps, and/or yield point is at least about 0.1Pa;

B) comprise the useful phase of hydrophobic composition, this useful hydrophobic material that comprises mutually by the weight of described useful phase about 20% to about 100%, described hydrophobic material is selected from lipoid, hydrocarbon, fat, oil, hydrophobicity plant extract, fatty acid, quintessence oil, silicone oil, and their mixture;

It is about 5 to about 15 that wherein said hydrophobic composition has the Vaughan solubility parameter, in addition, wherein cleansing phase is about 1: 9 to about 99: 1 with useful weight ratio mutually, and cleansing phase with useful in same packing actual contact, and under environmental condition, can keep stable at least about 180 days; And wherein cleansing phase and the useful striated pattern that forms mutually, wherein striped is of a size of wide and long at least about 1mm at least about 0.1mm; Wherein at least one granule that comprises mutually, wherein said granule is preferably the coated interference pigment of hydrophobically modified.

The invention still further relates to by as mentioned above compositions being coated on the skin and clean, preserve moisture and send skin benefit agent and granule method to skin.

Detailed Description Of The Invention

Multi phase personal care composition of the present invention comprises at least two visually distinct phases; Wherein these form pattern mutually; Wherein at least one granule that comprises mutually; Wherein said granule exists with the beauty treatment effective dose; And described biphase with actual contact each other packaged and keep stability.

The basic qualifications of these and other said compositions and method of the present invention and be applicable to that the many nonessential composition of this paper will be described in more detail below.

Except as otherwise noted, term used herein " anhydrous " is meant that those comprise by weight less than about 10%, be more preferably less than about 5%, even be more preferably less than about 3%, even the more preferably compositions or the material of 0% water.

Term used herein " environmental condition " is meant at one (1) individual atmospheric pressure, the environmental condition of 50% relative humidity and 25 ℃.

Term used herein " beauty treatment effective dose " produces the content of beneficial effect when being to use compositions.

Term used herein " consistometric value " or " k " are measuring of viscosity, and unite the viscosity of use with the definition material with the shearing index, and the viscosity of this material is the function of shearing force.Measurement is carried out at 25 ℃, and unit is a pool (equaling 100 centipoises).

Term used herein " coated interference pigment of hydrophobically modified " or " HMIP " are meant that the surface of part coated interference pigment has been wrapped with hydrophobic material and are coated with (physics and the chemical adhesion that comprise molecule).

Term used herein " coated interference pigment " is meant to have nacreous pigment, and it is to make by the surface that is coated with granule substrate material (being shaped as small pieces usually) with the thin film bag.Described thin film is the transparent or semitransparent material with high index of refraction.The high index of refraction material demonstrates pearly luster, the mutual interference effect between the incident illumination that the incident illumination that this gloss derives from the reflection of small pieces substrate/bag coating interface and bag coating surface reflect.

Term used herein " heterogenetic " and " heterogeneous " are meant that herein biphase at least occupies independently and distinct real space in storing their packing, but be in direct contact with one another (promptly, they are not separated by interlayer, and they are not by ground emulsifying of any significance degree or mixing).In a preferred embodiment of the invention, comprising biphase at least " heterogeneous " personal care composition is present in the container with distinct pattern visually.This pattern is by the mixing of " heterogeneous " compositions or homogenize produced.These patterns include but not limited to the following example: striated, marblized, collinear, the striped that interrupts, crackle is arranged, mottled, veined, bunch shape, spotted, how much switches, speckle, zonal, spiral helicine, gyrate, marshalling, raggle-taggle, veined, fluted, ridged, wavy, sinusoidal, helix, twisting, crooked, cyclic, band, slice is arranged, contour wire, heterogeneous, lacelike, interweave or weave, the basket weave shape, spotted and tessellated.Preferably, described pattern is selected from striated, geometry, marblized and their combination.

In a preferred embodiment, the striated pattern can be in whole range of packages relatively all even unanimity.Alternatively, system's pattern may be uneven, and is promptly wavy, perhaps inhomogeneous within the specific limits.Candy strip does not need must extend in the whole range of packages.Striped is of a size of at least about the wide and 10mm of 0.1mm long, preferably at least about 1mm wide and at least 20mm grow.These can be various colors mutually, or comprise granule, glitter or Margarita powder.

Term used herein " personal care composition " is meant plans the compositions of local coating on skin or the hair.

Term used herein " phase " is meant the scope or the zone of the compositions that comprises a kind of average group compound, and it is completely different in scope that comprises another kind of average group compound or zone, and wherein said regional naked eyes as seen.This will not get rid of this distinct zone or scope comprises two similar phases, and wherein one will comprise pigment, dyestuff, granule and various nonessential composition mutually, thereby forms the scope or the zone of different average group compounds.

Except as otherwise noted, term used herein " stable " is meant when the actual contact form leaves standstill under environmental condition and keeps at least two " independently " at least about 180 days compositions." independently " be meant the observable mixing mutually of essentially no naked eyes before compositions is distributed.

Term used herein " shearing index " or " n " are measuring of viscosity, and unite the viscosity of use with the definition material with consistometric value, and the viscosity of this material is the function of shearing force.Measurement is carried out in the time of 25 ℃, and unit is nondimensional.

Phrase used herein " is substantially free of " and is meant that compositions comprises and is less than approximately 3% by described composition weight meter, preferably is less than approximately 1%, more preferably less than about 0.5%, even more preferably less than about 0.25%, most preferably is less than about 0.1% predetermined component.

Vaughan solubility parameter used herein (VSP) is the parameter that is used to define the hydrophobic composition dissolubility that comprises hydrophobic material.The Vaughan solubility parameter is that various chemistry and formulation art are known, and typical scope is about 5cal/cm ³To about 25cal/cm ³

Except as otherwise noted, all percentage ratios used herein, umber and ratio are all by the weight of described total composition.The all wt of relevant ingredients listed is all based on content of active substance, and therefore except as otherwise noted, they do not comprise the solvent or the by-product that may be included in the commercially available material.

Multi phase personal care composition of the present invention and method can comprise, by or form by the basis of invention described herein and restriction and as herein described or other any additional or nonessential composition, component or restriction that can be used for being intended in the personal care composition of local coating on hair or the skin basically.

Product form

Multi phase personal care composition of the present invention typically is liquid.Term used herein " liquid " is meant that described compositions can flow usually to a certain extent.Therefore, " liquid " comprises and plans liquid, semiliquid, cream, distillate medicinal water or the gel combination of local coating to the skin.It is about 3 that compositions typical case shows that the viscosity that has is equal to or greater than, and 000cps is to about 1,000,000cps, and described viscosity is measured with hereinafter described " viscosity method ".These compositionss comprise biphase at least, its narration in more detail hereinafter.

When estimating multi phase personal care composition with methods described herein, unless indicate in indivedual methods in addition, preferably each was estimated before mixing separately.If yet these are blended mutually, can by centrifugal, ultrahigh speed is centrifugal, draw, filter, washing is separated each, can estimate isolating phase then.

For all contemplated product forms of explanation the compositions and methods of the invention are the washing-off type preparation, the washing-off type preparation is meant the product local coating on skin or hair, then (promptly in a few minutes) use water wash skin or hair subsequently, or wipe out sedimentary part compositions with substrate or other suitable removal tool in addition.

Phase

Multi phase personal care composition of the present invention comprises biphase at least, can comprise first phase, second in the wherein said compositions and equate.First mutually and second mutually the ratio be about 90: 10 to about 10: 90, preferably about 80: 20 to about 20: 80, more preferably from about 70: 30 to about 30: 70, even more preferably from about 60: 40 to about 40: 60, also more preferably from about 50: 50.Every can be one or more following non-limiting examples mutually, and it comprises: cleansing phase, useful phase and non-bubble structure contain water, it is narration in more detail hereinafter.

1) Cleansing phase

Multi phase personal care composition of the present invention can comprise cleansing phase.Cleansing phase of the present invention comprises the surfactant that is suitable for being coated on skin or the hair.The surfactant that is applicable to this paper comprises any known or other effective cleaning surfactants that are suitable for being coated on the skin, and this surfactant also with aqueous compositions cleansing phase in other bases compatible.These cleansing surfactants comprise anion surfactant, non-ionic surface active agent, cationic surfactant, amphion or amphoteric surfactant, or their combination.Cleansing surfactants among the present invention shows to have non newtonian shear thinning performance mutually.Preferably, the viscosity of cleansing phase is greater than about 3,000 centipoises (" cps "), more preferably greater than about 5, and 000cps, even more preferably greater than about 10,000cps, also more preferably greater than about 20,000cps, described viscosity is measured with hereinafter described " viscosity method ".

Preferably, the yield point of cleansing phase is greater than about 0.1 handkerchief (Pa), more preferably greater than about 0.5 handkerchief, even more preferably greater than about 1.0 handkerchiefs, also more preferably greater than about 2.0 handkerchiefs, also even more preferably greater than about 5 handkerchiefs, even also even more preferably greater than about 10 handkerchiefs, described yield point is measured with hereinafter described " yield point method ".

The concentration of the cleansing surfactants that the cleansing phase of multi phase personal care composition preferably comprises counts about 1% to about 50%, more preferably about 4% to about 30% by the weight of described cleansing phase, even more preferably about 5% to about 25%.The preferred pH scope of cleansing phase is about 5 to about 8, more preferably from about 6.

Total foaming volume that the cleansing phase of personal care composition produces is at least about 400ml, be preferably greater than about 500ml, more preferably greater than about 600ml, even more preferably greater than about 800ml, also more preferably greater than about 1000ml, also even more preferably greater than about 1250ml, described total foaming volume is with being filed in " test of the foaming volume " measurement described in 24 days the common unsettled application sequence of December in 2003 number 60/532,798.The quick foaming volume that the foaming cleansing of personal care composition preferably produces mutually is at least about 100ml, be preferably greater than about 200ml, more preferably greater than about 300ml, described total foaming volume is measured by being filed in " test of foaming volume " described in 24 days the common unsettled application sequence of December in 2003 number 60/532,798.

Be applicable to that the anion surfactant in the cleansing phase comprises alkyl sulfate and alkyl ether sulfate and soap.These materials have chemical formula ROSO respectively ₃M and RO (C ₂H ₄O) _xSO ₃M, wherein R is about 8 alkyl or alkenyls to about 24 carbon atoms, and x is 1 to 10, and M is water-soluble cationic such as ammonium ion, sodium ion, potassium ion or triethanolamine ion.This alkyl ether sulfate typically can be used as oxirane and has the about 8 condensation product preparations to the monohydric alcohol of about 24 carbon atoms.Preferably, R has about 10 to about 18 carbon atoms in alkyl sulfate and alkyl ether sulfate.This alcohol can be derived from fat, for example Oleum Cocois or Adeps Bovis seu Bubali, or synthetic.The preferred lauryl alcohol of this paper and derived from the straight chain alcohol of Oleum Cocois.Above-mentioned alcohol can with about 1 to about 10, preferred about 3 to about 5, the reacting ethylene oxide of 3 mol ratios more preferably from about, and with the mixture (for example, every mol of alcohol has average 3 moles of ethylene oxide) of gained molecular species through sulfuric acid treatment and neutralization.

The specific embodiment that can be used for the alkyl ether sulfate in the cleansing phase is the sodium sulfate salt and the ammonium sulfate of the sodium sulfate salt of cocos nucifera oil alkyl 2,2'-ethylenedioxybis(ethanol). ether and ammonium sulfate, tallow alkyl 2,2'-ethylenedioxybis(ethanol). ether, and the sodium sulfate salt and the ammonium sulfate of tallow alkyl six ethylene oxides.Highly preferred alkyl ether sulfate is those of mixture that comprise individualized compound, and the mean alkyl chain length that described mixture has is about 10 to about 16 carbon atoms, and average degree of ethoxylation is about 1 to about 4 moles of ethylene oxide.

Other suitable anion surfactant comprises that general formula is [R ¹-SO ₃-M] the water soluble salt of organic sulfur acid reaction product, R wherein ¹Be selected from and have about 8 to about 24, preferred about 10 saturated aliphatic hydrocarbyls to the straight or branched of about 18 carbon atoms; M is a cation.Suitable embodiment is the salt of the organic sulfur acid reaction product of methane series hydrocarbon, comprise and have about 8 to about 24 carbon atoms, preferred about 10 different, new, outer and normal paraffin hydrocarbons and sulfonating agents to about 18 carbon atoms, for example, according to the SO of known method of sulfonating (comprising bleaching and hydrolysis) gained ₃, H ₂SO ₄And oleum.Sulfonation C preferably _10-18The alkali metal salt of normal paraffin hydrocarbons and ammonium salt.

Other suitable surfactants are described in " Emulsifiers and Detergents " (annual in 1989) and United States Patent (USP) 3,929,678 of the McCutcheon that M.C.Publishing Co. publishes.

The preferred anionic surfactants surfactant that can be used in the cleansing phase comprises: ammonium lauryl sulfate; lauryl polyethenoxy ether sodium sulfate; the lauryl sulfate triethylamine; laureth sulphuric acid triethylamine; triethanolamine lauryl sulfate; laureth sulphuric acid triethanolamine; lauryl sulfate monoethanolamine; laureth sulphuric acid monoethanolamine; lauryl sulfate diethanolamine; laureth sulphuric acid diethanolamine; Glyceryl Monolaurate sodium sulfate; sodium lauryl sulfate; sodium laureth sulfate; laureth ether potassium sulfate; sodium lauryl sarcosinate; sodium lauroyl sarcosine; the sarcosine lauryl; the cocoyl sarcosine; cocoyl ammonium sulfate; lauroyl ammonium sulfate; cocoyl sodium sulfate; lauroyl sodium sulfate; the cocoyl potassium sulfate; lauryl potassium sulfate; cocoyl sulphuric acid monoethanolamine; the tridecyl benzene sulfonic acid sodium salt; dodecylbenzene sodium sulfonate, and their combination.

For example, in some embodiments, preferably has the anion surfactant of branched alkyl chain, as polyoxyethylene tridecyl ether sodium sulfate.Can use the mixture of anion surfactant in some embodiments.

Can be incorporated in the cleansing phase compositions being selected from amphoteric surfactant, zwitterionic surfactant, cationic surfactant and/or the nonionic surfactants additional surfactants in not.

Be applicable to that the amphoteric surfactant in the cleansing phase comprises those that are collectively referred to as aliphatic secondary amine and tertiary amines derived thing, wherein aliphatic group can be a straight or branched, and one of them aliphatic substituent group comprise about 8 to about 18 carbon atoms, and an aliphatic substituent group comprises the anionic water-soluble group, as carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.The embodiment that belongs to the chemical compound of this definition is: the 3-sodium dodecyl aminopropionitrile; 3-dodecyl amino propane sulfonic acid sodium, sodium lauryl sarcosinate, N-alkyl taurine are (as according to United States Patent (USP) 2; 658; proposed in 072; by lauryl amine and sodium isethionate react and make those), N-senior alkyl aspartic acid is (as according to United States Patent (USP) 2; 438; those that the method that is proposed in 091 makes); and at United States Patent (USP) 2; those products described in 528,378.

Be applicable to that the zwitterionic surfactant in the cleansing phase comprises those that are collectively referred to as aliphatic quaternary ammonium, Phosphonium and sulfonium compound derivant, but aliphatic group straight or branched wherein, and one of them aliphatic substituent group comprise about 8 to about 18 carbon atoms, and an aliphatic substituent group comprises anionic group, as carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.Above-mentioned suitable zwitterionic surfactant is shown below:

R wherein ²Comprise alkyl, alkenyl or hydroxyalkyl, this hydroxyalkyl have about 8 to about 18 carbon atoms, 0 to about 10 ethylene oxides part and 0 to about 1 glyceryl; Y is selected from nitrogen, p and s atom; R ³Be to comprise about 1 alkyl or monohydroxy alkyl to about 3 carbon atoms; When Y was sulphur atom, X was 1, and when Y was nitrogen-atoms or phosphorus atoms, X was 2; R ⁴Be to have about 1 alkylidene or hydroxyl alkylidene, and Z is the group that is selected from carboxylate radical, sulfonate radical, sulfate radical, phosphonate radical and phosphate radical to about 4 carbon atoms.

Other is applicable to that the zwitterionic surfactant in the cleansing phase comprises the betanin that contains the senior alkyl betanin, as the coco dimethyl carboxymethyl betaine, cocoamidopropyl, coco betaine, lauramido propyl betaine, the oleyl betanin, lauryl dimethyl base carboxymethyl betaine, lauryl dimethyl base-α-carboxyethyl betanin, cetyl dimethyl carboxymethyl betaine, Laurel is two-(2-ethoxy) carboxymethyl betaine, stearic pair-(2-hydroxypropyl) carboxymethyl betaine, oleyl dimethyl-γ-carboxylic CAB and Laurel be two-(2-hydroxypropyl)-α-carboxyethyl betanin.The representative of sulfobetaines be coco dimethyl sulfopropyl betaine, stearic dimethyl sulfopropyl betaine, lauryl dimethyl sulfoethyl betanin, Laurel two-(2-hydroxyethyl) sulfopropyl betaine etc.; Amido betaine and amino sulfobetaines (RCONH (CH wherein ₂) ₃Group links to each other with nitrogen-atoms in the betanin) also can be used for the present invention.

Also can use both sexes guanidine-acetic acid salt and both sexes base diacetin.

The both sexes acetate

Two both sexes acetates

Both sexes acetate and two both sexes acetates meet this chemical formula (following formula), and wherein R is the aliphatic group that contains 8 to 18 carbon atoms.M is a cation, as the ammonium ion of sodium ion, potassium ion, ammonium ion or replacement.In some embodiments, preferred N-lauroyl amido ethyl-N hydroxyethyl sodium acetate, N-cocamidopropyl ethyl-N hydroxyethyl sodium acetate, N-lauroyl amido ethyl-N hydroxyethyl sodium diacelate and N-cocamidopropyl ethyl-N hydroxyethyl sodium diacelate.

In cleansing phase, also can use cationic surfactant, but more not preferred usually, and by the weight preferred content of described compositions less than about 5%.

Be applicable to that ionic surfactant pack during aqueous cleaning mutually draws together the product of alkylidene oxide group (itself is hydrophilic) and organic hydrophobic compound condensation, this organic hydrophobic compound can reality be aliphatic compounds or Alkylaromatics.

A) Structural agent

Cleansing phase of the present invention not necessarily but preferably also comprise the structural agent of about 0.1% to 10% weight, its effect in compositions is to form the thermokinetics phase, preferred stratiform thermodynamics phase.It is believed that lamellar phase can strengthen the interface stability between the phase of this compositions.

Suitable structural agent comprises that fatty acid or its ester derivant, aliphatic alcohol, three (hydroxy stearic acid) glyceride are (with trade name

R is available from Rheox, and Inc.), or PMAm propyl group chlorination three ammoniums are (with trade name

133 available from Rhodia).Preferably, the layer structure agent is selected from lauric acid or three (hydroxy stearic acid) glyceride.

In a preferred embodiment of the invention, the surfactant that is used for cleansing phase shows to have non newtonian shear thinning behavior (this paper is called free flowing composition), and can be surfactant mixtures.Suitable surfactant mixture comprises water, at least a anion surfactant, electrolyte and at least a alkanolamide.Found to show to have the cleansing phase that the non newtonian shear thinning is released behavior, can improve the stability of gained multi phase personal care composition by using.The formula that alkanolamide (if the words that exist) has is:

Wherein R is C ₈To C ₂₄, or preferably be C in certain embodiments ₈To C ₂₂Or preferably be C in other embodiments ₈To C ₁₈Saturated or undersaturated straight or branched aliphatic group, R ₁And R ₂Be identical or different C ₂-C ₄The aliphatic group of straight or branched, x is 0 to 10; Y is 1 to 10, and wherein x and y sum are less than or equal to 10.

The amount of alkanolamide is typically about 0.1% to about 10% by the weight of described cleansing phase in the compositions, and is preferably about 2% to about 5% by the weight of described cleansing phase in certain embodiments.Suitable alkanolamide comprises Cocamide MEA (cocoyl single ethanol amide) and Cocamide MIPA (the single isopropanol amide of cocoyl).

Electrolyte (if you are using) itself can be joined in the compositions, maybe can form electrolyte on the spot by the counter ion that is included in a kind of raw material.Preferably, electrolyte comprises anion (comprising phosphate radical, chloride ion, sulfate radical or citrate) and cation (comprising sodium ion, ammonium ion, potassium ion, magnesium ion or their mixture).Some preferred electrolyte are sodium chloride or ammonium chloride, or sodium sulfate or ammonium sulfate.Preferred electrolyte is a sodium chloride.

Electrolyte (if present) should exist with the content that is easy to form easy flow composition.Usually, by the weight of described cleansing phase, this amount is for about 0.1% to about 15%, and preferred about 1% to about 6%, but can change (if necessary).

In one embodiment of the invention, cleansing phase comprises anion surfactant (as, tridecyl polyethenoxy ether sodium sulfate), both sexes acetate surfactant (as, N-lauroyl amido ethyl-N hydroxyethyl sodium acetate), and alkanolamide (as, fruit coconut oleoyl amine MEA).The cleansing phase of the present embodiment preferably also comprises electrolyte (as sodium chloride).

B) Homogenizing

The cleansing phase of this compositions not necessarily comprises the thermodynamics phase of homogenizing.The thermodynamics of homogenizing comprises the surfactant solution of being made up of complete easily molten component mutually, and its microstructure does not change with distance in the solution or direction.Preferably, the surfactant of the thermodynamics that is present in homogenizing in mutually and front mention in mutually at the stratiform thermodynamics those are identical.The viscosity that the homogenizing thermodynamics of multi phase personal care composition preferably has mutually is about 3,000 centipoise (cps) is to about 100, in the scope of 000 centipoise (cps), described viscosity is used is furnished with the tachometric survey of the Brookfield cone and plate viscometer of S41 rotor with 0.5RPM.More preferably viscosity is about 10, and 000cps is to about 100, and 000cps, even more preferably viscosity is about 20,000cps be to about 80,000cps.

C) The organic cation deposited polymer

Multi phase personal care composition of the present invention can comprise organic cationic deposition polymer conduct deposition aid of beneficial agent hereinafter described in addition in cleansing phase.The concentration of cationic deposition polymer is preferably about 0.025% to about 3% by the weight of described cleansing phase compositions, and more preferably from about 0.05% to about 2%, even more preferably from about 0.1% to about 1%.

Be applicable to that the cationic deposition polymer in the multi phase personal care composition of the present invention comprises the cationic nitrogenous part, as quaternary ammonium ion or the protonated amino part of cation.The protonated amine of cation can be primary amine, secondary amine or tertiary amine (preferred secondary amine or tertiary amine), and it depends on the Special Category of personal cleaning compositions and the pH value of selection.The mean molecule quantity of cationic deposition polymer between about 5,000 to about 1,000 ten thousand, preferably at least about 100,000, more preferably at least about 200,000, but preferably be no more than about 200 ten thousand, more preferably no more than about 1.5 hundred ten thousand.And, under the pH value that the personal cleaning compositions desire is used, the cationic charge density that this polymer had is that about 0.2meq/gm is to about 5meq/gm, preferably at least about 0.4meq/gm, more preferably at least about 0.6meq/gm, wherein this pH value is generally about pH4 to about pH9, preferably between about pH5 and about pH8.

Can and regulate charge density according to technology control known in the art." charge density " of term cationic polymer used herein is defined as every gram-automic weight (molecular weight) cationic number of sites that polymer had, and meq/gram that can cationic charge is unit representation.Usually with regard to amine, the adjusting of amine or quaternary ammonium part ratio in the polymer, and the adjusting of multi phase personal care composition pH value will influence charge density.

Any anionic counter ion can use with the cationic deposition combination with polymers, as long as this polymer in water, in multi phase personal care composition or the coacervate of multi phase personal care composition mutually in the maintenance water solublity, and as long as the basis of this counter ion and this personal cleaning compositions is at physics with chemically be compatible, or not performance, the stability or attractive in appearance of other undue weakening product.The non-limiting example of above-mentioned counter ion comprises halide ion (as chloride ion, fluorion, bromide ion, iodide ion), sulfate radical and methyl ester sulfate radical.

The non-limiting example that is used for the cationic deposition polymer of multi phase personal care composition comprises polysaccharide polymer, as cationic cellulose derivative.The preferred cation cellulosic polymer is the salt of the epoxide reaction gained of hydroxyethyl-cellulose and trimethyl ammonium replacement, in industry (CTFA), be called as Polyquaternium 10, can be available from AmercholCorp. (Edison, N.J., USA) Polymer KG, JR and LR series of polymers, wherein KG-30M most preferably.

Other suitable cationic deposition polymer comprises cation melon ear derivant, as Rhaball Gum CG-M 8M, its specific embodiment comprises Jaguar series (preferred Jaguar C-17) that is commercially available in Rhodia Inc. and the N-Hance series of polymers that is commercially available in Aqualon.

The cationic polymer of this paper is dissolved in cleansing phase, perhaps preferably is dissolved in the complex coacervate phase in the multi phase personal care composition, and this complex coacervate is that by mentioned earlier cationic deposition polymer and anion surfactant component is formed mutually.The complex coacervate of cationic deposition polymer also can be formed by other charge species in the multi phase personal care composition.

Various standards are depended in the formation of coacervate, charge density, pH value and temperature as the ratio of molecular weight, concentration of component and interactional ion component, ionic strength (comprising the change of ionic strength), cation and anionic group for example by adding salt.The influence of coacervate system and these parameters is described in, people's such as J.Caelles " AnionicandCationic Compounds in Mixed Systems " for example, Cosmetics﹠amp; Toiletries, the 106th volume, in April, 1991, the the 49th to 54 page, " Coacervation, the Complex-Coacervation and Flocculation " of C.J.van Oss, J.Dispersion Science and Technology, the 9th (5,6) volume, 1988-89, the the 561st to 573 page, with " the Practical Analysis of ComplexCoacervate Systems " of D.J.Burgess, " J.of Colloid anti Interface Science ", the 140th volume, the 1st phase, in November nineteen ninety, the 227th to 238 page, its description is incorporated herein by reference.

In it is believed that coacervate that the cationic deposition polymer is present in multi phase personal care composition is mutually, or to coating cleaning compositions on the skin or to form coacervate during the drip washing Cleasing compositions from skin be especially favourable mutually.It is believed that complex coacervate is easier to be deposited on the skin, this has produced the deposition effect that benefit materials improves.Therefore, usually the preferred cationic deposited polymer with coacervate mutually or the form that forms the coacervate phase when the dilution be present in the multi phase personal care composition.If coacervate is not arranged in multi phase personal care composition as yet, then the cationic deposition polymer will preferably be present in the complex coacervate that forms in multi phase personal care composition when water-soluble.

It is known in the art being used to analyze the technology that complex coacervate forms.For example, in any selected dilution stage, can utilize the centrifugal analysis of multi phase personal care composition to discern and form the coacervate phase whether.

2) Useful phase

Multi phase personal care composition of the present invention can comprise useful phase.Useful phase of the present invention is preferably anhydrous.The described useful hydrophobic composition that comprises mutually, described hydrophobic composition comprises hydrophobic material.Usefully be included as about 20% mutually, preferably at least about 35%, most preferably at least about 50% hydrophobic material to about 100%.Be applicable to that the Vaughan solubility parameter that hydrophobic composition of the present invention has is about 5 to about 15.This hydrophobic composition is preferably selected from those with specified flow change nature as mentioned below, comprises selected consistometric value (k) and shears index (n).These preferred rheological properties especially help to provide for the multi-phase personal care composition deposition of hydrophobic material on skin of improvement.

A) Vaughan solubility parameter value (VSP)

Be used for Vaughan solubility parameter (VSP) that the useful hydrophobic material mutually of multi phase personal care composition had for about 5 to about 15, preferred about 5 to less than about 10, more preferably from about 6 to about 9.These solubility parameters are known in formulation art, and by Vaughan at " Cosmetics and Toiletries ", the 103rd volume, in the 47th to 69 page (in October, 1988) define.

The VSP value that has comprises following for the non-limiting example of about 5 to about 15 hydrophobic material:

V _AUGHAN Solubility parameter ^*

Ring-type polymethyl siloxane (Cyclomethicone) 5.92

Squalene 6.03

Vaseline 7.33

Isopropyl palmitate 7.78

Isopropyl myristate 8.02

Oleum Ricini 8.90

Cholesterol 9.55

As Solubility, Effects in Product, Package, Penetration And Preservation, C.D.Vaughan, Cosmetics and Toiletries, the 103rd volume is reported in 1988 10 months.

B) Rheological behavior

The useful hydrophobic composition mutually that is used for compositions has the preferred rheological charactristics of using consistometric value (k) and shearing index (n) defined.Preferred consistometric value scope is about 1-10,000 pool/(1/ second) (inverse of pool per second), preferably about 10-5000 pool/(1/ second), more preferably from about 50-4000 pool/(1/ second).Shear exponential scope and be about 0.025-0.9, preferably about 0.05-0.5, more preferably from about 0.09-0.4.

The feature of hydrophobic composition can characterize with the consistometric value (k) and shearing index (n) value of above-mentioned scope defined, the scope of wherein selecting these regulations provides the viscosity of enhanced deposition effect and reduction so that in multi phase personal care composition being coated to hair or skin process or afterwards.

Shearing index (n) and denseness (k) value is the industrial standard of knowing and generally acknowledging of viscosity (μ) feature of recording materials, and the viscosity of described material changes with the shear rate that is applied.

The viscosity of hydrophobic composition (μ) can apply with the sequencing pattern that shear rate is measured the shear stress of gained then or vice versa characterizes by using flow graph such as TA instrument AR2000 (DE, USA 19720 for TA Instruments, New Castle).In following modes, measure viscosity with different shear rates.At first, obtain hydrophobic composition, it has compositions and the character that is present in the multi phase personal care composition.In other words, treatment compositions in a similar manner, if make that so for example sample comprises crystal, then it is with approximately identical speed crystallization.Obtained the aliquot of hydrophobic composition before can be in being mixed in heterogeneous compositions, this is common skill for a person skilled in the art.Equally, hydrophobic composition can reclaim from multi phase personal care composition, for example utilizes centrifugal, absorption, screening, rinsing or additive method to reclaim hydrophobic composition.The AR2000 flow graph is programmed with about 1 by stress being increased to from about 0.1Pa in 5 minutes 25 degrees centigrade the time, and 000Pa comes shear sample.4cm parallel-plate shape with 1mm gap is general, although the gap can increase or reduce as required, if for example hydrophobic composition comprises bulky grain, then the gap may need bigger.Reach at least 1001/ second shear rate in test, perhaps the sequencing speed that keeps stress to increase simultaneously with bigger final stress value retest is about 1.25 minutes of per ten stress.These results are with following universally recognized power law model match.By viscosity and shear rate data are depicted on the log-log graph, and only use shear rate to increase and data in the zone that viscosity stabilization reduces, in the data of shear zone are included in.For example, low shear stress is not considered in a small amount of mobile original flat of appearance district down.Typically, the shear rate of about 0.1-10.01/ between second is useful, and choosing enough data points comes the universally recognized power law model of match (referring to for example: " ChemicalEngineering " of Coulson and Richardson, Pergamon, 1982 or " the Transport Phenomena " of Bird, Stewart and Lightfoot, Wiley, 1960):

μ＝k(γ’) ^(n-1)

The value that obtains from the slope of double logarithmic curve be (n-1), and wherein n is for shearing index, and the k value that obtains is a consistometric value, and unit is for mooring/(1/ second).For example, (Super WhiteProtopet, consistometric value Witco) are about 2,000 pool/(1/ seconds) to vaseline, and shearing index is about 0.2; The consistometric value of 50% vaseline and 50%Hydrobrite 1000 mineral oil (Witco) mixture is about 400 pool/(1/ seconds), and shearing index is about 0.25.

Described hydrophobic composition comprises hydrophobic material.The non-limiting example that is applicable to the hydrophobic material of this paper can comprise multiple hydrocarbon, oil and wax, siloxanes, derivative of fatty acid, cholesterol, cholesterol derivative, diglyceride, triglyceride, vegetable oil, vegetable oil derivatives, acetin, Arrcostab, alkenyl ester, polyglyceryl fatty acid ester, lanoline and derivant thereof, wax ester, Cera Flava derivant, sterol and phospholipid, and their combination.

Be applicable to that the hydrocarbon ils of this paper and the non-limiting example of wax comprise vaseline, mineral oil, microwax, polyolefin, paraffin, cerasine, ceresine, polyethylene, perhydro-squalene, and their combination.

The non-limiting example that is suitable for the silicone oil of making this paper hydrophobic material comprises: dimethicone copolyol, dimethyl polysiloxane, diethyl polysiloxanes, blended C1-C30 alkyl polysiloxane, phenyl polydimethylsiloxane, dimethiconol, and their combination.Non-volatile siloxane preferably, it is selected from polydimethylsiloxane, dimethiconol, blended C1-C30 alkyl polysiloxane and their combination.The non-limiting example that can be used for the silicone oil of this paper is described in United States Patent (USP) 5,011, among 681 (people such as Ciotti).

Be suitable for and make the diglyceride of this paper hydrophobic material and the non-limiting example of triglyceride comprises: Oleum Ricini, soybean oil, the soybean oil of deriving (as the maleic acid soybean oil), safflower oil, Oleum Gossypii semen, Semen Maydis oil, Oleum Juglandis, Oleum Arachidis hypogaeae semen, olive oil, cod liver oil, almond oil, American Avocado Tree oil, Petiolus Trachycarpi oil and Oleum sesami, vegetable oil, sunflower seed oil and vegetable oil derivatives, Oleum Cocois and the Oleum Cocois of deriving, Oleum Gossypii semen and the Oleum Gossypii semen of deriving, Jojoba oil, Oleum Cocois, and their combination.

The non-limiting example that is suitable for the aceto-glyceride of making this paper hydrophobic material comprises acetylizad monoglyceride.

The non-limiting example that is suitable for the Arrcostab of making this paper hydrophobic material comprises: isopropyl fatty acid ester and long-chain (are C ₁₀-C ₂₄) long-chain ester (as the castor oil acid cetyl) of fatty acid, its non-limiting example comprises: isopropyl palmitate, isopropyl myristate, castor oil acid cetyl and castor oil acid stearyl.Other embodiment are: lauric acid hexyl ester, lauric acid dissident ester, myristic acid myristyl ester, Palmic acid dissident ester, decyl oleate, Ceraphyl 140A, cetyl stearic, stearic acid ester in the last of the ten Heavenly stems, isostearic acid isopropyl ester, diisopropyl adipate, adipic acid two dissident's esters, adipic acid dihexyl decyl ester, Dermol DIPS, the different pelargonate of acyl group, Lauryl lactate, lactic acid tetradecane ester, lactic acid cetyl, and their combination.

The non-limiting example that is suitable for the alkenyl ester of making this paper hydrophobic material comprises: myristic acid oil alkene ester, stearic acid oil alkene ester, oleic oil alkene ester, and their combination.

The non-limiting example that is suitable for the polyglycerol fatty acid ester of making this paper hydrophobic material comprises: distearyl acid ten glyceride, two isostearic acids, ten glyceride, a myristic acid ten glyceride, a lauric acid ten glyceride, monooleate six glyceride, and their combination.

Being suitable for the lanoline of making this paper hydrophobic material comprises with mao non-limiting example of fat derivant: lanoline, lanolin oil, lanolin wax, lanolin alcohol, lanolin fatty acid, isopropyl lanolate, acetylated lanolin, Acetylated lanolin alcohols., linoleic acid lanoline alcohol ester, castor oil acid lanoline alcohol ester, and their combination.

Other suitable hydrophobic material also comprises milk triglyceride (as hydroxylated milk glyceride) and polyol fatty acid polyesters.

Other suitable hydrophobic material also comprises wax ester, and its non-limiting example comprises Cera Flava and Cera Flava derivant, spermaceti, myristic acid myristyl ester, stearic acid stearyl and their combination.Useful vegetable wax such as Brazil wax and candelilla wax in addition; Sterol such as cholesterol, fatty acid cholesterol ester; Phospholipid such as lecithin and derivant, sphingolipid, ceramide, glycosphingolipid; And their combination.

The useful of compositions preferably can comprise one or more hydrophobic materials mutually; wherein by described hydrophobic material weight; at least 20% is selected from vaseline; mineral oil; sunflower seed oil; microwax; paraffin; ceresine; polyethylene; polybutene; poly decene and perhydro-squalene polydimethylsiloxane; the ring-type polymethyl siloxane; alkylsiloxane; polymethyl siloxane and methyl phenyl silicone; lanoline; lanolin oil; lanolin wax; lanolin alcohol; lanolin fatty acid; isopropyl lanolate; acetylated lanolin; Acetylated lanolin alcohols.; linoleic acid lanoline alcohol ester; castor oil acid lanoline alcohol ester; Oleum Ricini; soybean oil; the maleic acid soybean oil; safflower oil; Oleum Gossypii semen; Semen Maydis oil; Oleum Juglandis; Oleum Arachidis hypogaeae semen; olive oil; cod liver oil; almond oil; American Avocado Tree oil; Petiolus Trachycarpi oil and Oleum sesami, and their combination.More preferably, by the weight of described hydrophobic material, be selected from vaseline, mineral oil, paraffin, polyethylene, polybutene, poly decene, polydimethylsiloxane, alkylsiloxane, ring-type polymethyl siloxane, lanoline, lanolin oil, lanolin wax at least about 50%.The hydrophobicity skin conditioning agent of remainder is preferably selected from: isopropyl palmitate, castor oil acid cetyl, different octyl pelargonate, octyl palmitate, stearic acid isocetyl ester, hydroxylated milk glyceride, and their combination.

3) The structured aqueous phase of non-foaming

Multi phase personal care composition of the present invention can comprise the water that contains of non-bubble structure.Structured aqueous water-bound agent and the water of comprising mutually of the non-foaming of the present composition.Non-foaming is structured aqueous can be hydrophilic mutually, and in a preferred embodiment, described non-foaming is structured aqueous to be the hydrophilic gel water mutually.In addition, the structured aqueous phase of non-foaming of the present invention typically comprises by the weight of the structured aqueous phase of described non-foaming less than about 5%, preferably less than about 3%, is more preferably less than about 1% surfactant.In one embodiment of the invention, the structured aqueous phase of described non-foaming does not contain surfactant.

The structured aqueous preferred mutually total foaming volume that produces of the non-foaming of personal care composition is not more than about 350ml, more preferably no more than about 330ml, even more preferably no more than about 300ml, described total foaming volume is measured by being filed in " test of foaming volume " described in 24 days the common unsettled application sequence of December in 2003 number 60/532,798.The structured aqueous preferred mutually quick foaming volume that produces of the non-foaming of personal care composition is not more than about 150ml, preferably be not more than about 130ml, even more preferably no more than about 100ml, described total foaming volume is measured by being filed in " test of foaming volume " described in 24 days the common unsettled application sequence of December in 2003 number 60/532,798.

Preferably, described non-foaming is structured aqueous to show that mutually the yield point that has is at least about 0.1Pa, and preferably at least about 1Pa, more preferably at least about 10Pa, described yield point is measured with hereinafter described " yield point method ".Preferably, the structured aqueous water mobility that has that shows mutually of described non-foaming is more preferably less than about 2 seconds, even is more preferably less than about 1 second for less than about 2.5 seconds, as be filed in 24 days common unsettled application sequence of December in 2003 number 60/532,798 described " water mobility method " and measure.

Preferably, the structured aqueous relative turbidity that has that shows mutually of described non-foaming is less than about 50% relative turbidity, be more preferably less than about 30% relative turbidity, even be more preferably less than about 20% relative turbidity, also be more preferably less than about 10% relative turbidity, described turbidity is measured with hereinafter described " muddy relatively index method ".

The structured aqueous preferred rheological behavior that has mutually by consistometric value (k) and shearing index (n) defined of non-foaming.The preferred consistometric value of the structured aqueous phase of non-foaming is about 10 pools/(1/s) to about 100,000 pools/(1/s), and preferred about 10 pools/(1/s) are to about 10,000 pools/(1/s), and more preferably from about 100 pools/(1/s) are to about 1,000 pool/(1/s).The shearing index of the structured aqueous phase of non-foaming is typically from about 0.1 to about 0.8, and preferred about 0.1 to about 0.5, and more preferably from about 0.20 to about 0.4.

Shearing index (n) and consistometric value (k) is the industrial standard of knowing and generally acknowledging of the viscosity characteristics of record compositions, and the viscosity of described compositions is the function of the shear rate that applies.The method front that is used to obtain these values is narrated in more detail.

The structured aqueous weight by the structured aqueous phase of described non-foaming of non-foaming of the present invention comprises about 30% to about 99% water.Non-foaming is structured aqueous to be comprised by the weight of the structured aqueous phase of described non-foaming mutually usually greater than about 50%, be preferably greater than about 60%, even more preferably greater than about 70%, also more preferably greater than about 80% water.

The structured aqueous pH that the typical case is had of non-foaming is about 5 to about 8, more preferably from about 7.The structured aqueous phase of non-foaming not necessarily comprises the pH regulator agent to help obtaining suitable pH scope.

The structured aqueous phase of non-foaming can have clean cationic charge, clean anionic charge or neutral charge.In a preferred embodiment, non-foaming is structured aqueous has clean anionic charge mutually.

The non-foaming of this compositions is structured aqueous also can to comprise as mentioned below those of nonessential composition mutually.The preferred nonessential composition of non-foaming aqueous phase comprises pigment, pH regulator agent and antiseptic.In one embodiment, structured aqueous water-bound agent (as acrylate/vinyl isodecyl acid esters cross linked polymer), water, pH regulator agent (as triethanolamine) and the antiseptic of comprising mutually of non-foaming is (as 1,3-dimethyl-5,5-dimethyl hydantoin (" DMDMH ", available from Lonza, commodity are by name

)).

A) The water-bound agent

By the weight of the structured aqueous phase of described non-foaming, non-foaming of the present invention is structured aqueous to comprise about 0.1% to about 30%, preferred about 0.5% mutually to about 20%, and more preferably from about 0.5% to about 10%, even more preferably from about 0.5% to about 5% water-bound agent.

The water-bound agent typically is selected from inorganic water-bound agent, charged polymer water structural agent, water-soluble polymer structural agent, associating water-bound agent and their mixture.

The non-limiting example that is used for the inorganic water-bound agent of personal cleaning compositions comprises silicon dioxide, clay such as synthetic silicate (Laponite XLG and Laponite XLS are available from Southern Clay) or their mixture.

The non-limiting example that is used for the charged polymer water structural agent of personal cleaning compositions comprises that acrylate/(Stabylen 30 for vinyl isodecyl acid esters cross linked polymer; available from 3V); acrylate/C10-30 alkyl acrylate cross-linked polymer (Pemulen TR1 and TR2); carbomer; acryloyl group dimethyl taurine ammonium/VP copolymer (Aristoflex AVC; available from Clariant); acryloyl group dimethyl taurine ammonium/Beheneth-25 methacrylate cross linked polymer (Aristoflex HMB; available from Clariant); (Structure 3001 for acrylate/Ceteth-20 itaconate copolymeric; available from NationalStarch); polyacrylamide (Sepigel 305, available from SEPPIC); or their mixture.

The non-limiting example that is used for the water-soluble polymer structural agent of personal cleaning compositions comprises cellulosic gel, hydroxypropyl starch phosphate (Structured XL is available from National Starch), polyvinyl alcohol or their mixture.

The non-limiting example that is used for the associating water-bound agent of personal cleaning compositions comprises yellow polysaccharide glue, gellum glue, pectin, alginate or their mixture.

Granule

Multi phase personal care composition of the present invention can comprise granule.The water insoluble solid granule of different shape and density is available.In preferred embodiments, it is sphere, ellipse, irregular shape or any other shape that granule tends to, and wherein the ratio of full-size and minimum dimension (being defined as aspect ratio) is less than about 10.More preferably particulate aspect ratio is less than about 8, and also more preferably particulate aspect ratio is less than about 5.

Less than about 100 μ m, preferably less than about 80 μ m, more preferably granularity is less than about 60 μ m for the particulate granularity of the present invention (based on hereinafter described granulometry result's volume averaging value).

Granule preferred size of the present invention is greater than about 0.1 μ m, and preferred size is greater than about 0.5 μ m, and more preferably granularity is greater than about 1 μ m, and also more preferably granularity is greater than about 2 μ m, even more preferably granularity is greater than about 3 μ m, and also even more preferably granularity is greater than about 4 μ m.

Particulate diameter is about 1 μ m to about 70 μ m, and more preferably from about 2 μ m are to about 65 μ m, even more preferably diameter is that about 2 μ m are to about 60 μ m.

Multi phase personal care composition of the present invention comprises granule with the beauty treatment effective dose.Preferably, particulate content is at least about 0.1% by described composition weight meter, more preferably is at least about 0.2% by composition weight meter, even more preferably at least about 0.5%, also more preferably at least about 1%, even also more preferably presses composition weight meter at least 2%.In multi phase personal care composition of the present invention, preferred particulates content is no more than about 50% by composition weight meter, more preferably no more than about 30%, also more preferably no more than about 20%, even more preferably be no more than about 10% by composition weight meter.

Preferably, granule also will have the physical property of the typical process appreciable impact of the compositions of not being subjected to.Preferably, use fusing point greater than about 70 ℃ granule, more preferably fusing point is greater than about 80 ℃, even more preferably uses fusing point greater than about 95 ℃.Fusing point used herein is to instigate granule to change the temperature of liquid or fluid state or experience significant deformation or change in physical into.In addition, many granules of the present invention are crosslinked or have crosslinked skin covering of the surface.These granules do not show to have definite fusing point.As long as cross-linked particles is stable under processing that is used to make compositions and condition of storage, they also are useful.

The granule that can be present among the present invention can be natural, synthetic or semisynthetic.In addition, also can there be hybrid particles.Synthetic granule can be made by cross linked polymer or non-cross-linked polymer.Granule among the present invention can have surface charge or their surperficial available organic or inorganic material such as surfactant, polymer and inorganic substances modification.Also can there be particle composites.

Natural particulate limiting examples comprises the precipitated silica granule of various hydrophilic or hydrophobic form, with trade name Sipernet available from Degussa-Huls.With trade name Sipernet D11 ^TMPrecipitated available from Degussa ^TMHydrophobic synthetic amorphous silicon dioxide is preferred granule.The Snowtex colloidal silica particle is available from NissanChemical America Corporation.

Synthetic particulate non-limiting example comprises nylon, silicone resin, poly-(methyl) acrylate, polyethylene, polyester, polypropylene, polystyrene, polyurethane, polyamide, epoxy resin, urea resin and acrylic clear powder.Available particulate non-limiting example is Microease 110S, 114S, 116 (micronized synthetic wax), Micropoly 210,250S (micronized polyethylene), Microslip (micronized politef) and Microsilk (combination of polyethylene and politef), all these are all available from MicroPowder, Inc..Additional embodiments comprise Luna (slick silica dioxide granule) granule available from Phenomenex, MP-2200 (polymethyl methacrylate), EA-209 (ethene/acrylic ester copolymer), SP-501 (PA-12), ES-830 (poly methyl methacrylate), BPD-800, BPD-500 (polyurethane) granule available from Kobo Products, Inc. and silicone resin are sold by GE Silicones with trade name Tospearl granule.Ganzpearl GS-0605 crosslinked polystyrene (available from Presperse) also is useful.

The limiting examples of hybrid particles comprises Ganzpearl GSC-30SR (sericite and crosslinked polystyrene mixed-powder) and SM-1000, SM-200 (Muscovitum and silicon dioxide mixed-powder are available from Presperse).

The cracking-off agent granule

The cracking-off agent granule is selected from polyethylene, microwax, jojoba esters, amorphous silicon di-oxide, Talcum, tricalcium orthophosphate or their mixture etc.The cracking-off agent granule is about 100 microns to about 600 microns along the size of particulate major axis, preferred about 100 microns to about 300 microns.The particulate hardness of cracking-off agent is less than about 4Mohs, preferably less than about 3Mohs.So the hardness of being surveyed is the judgment criteria that the certain material resistance to compression is ground.It is considered to the goodish indication of particulate component abrasive characteristic.As follows according to the Moh grade: h (hardness)-1: Talcum with the material embodiment that hardness increases ordering; H-2: Gypsum Fibrosum, rock salt, common crystal salt, barite, Chalk, sulfur; H-4: fluorite, soft phosphate, magnesite, limestone; H-5: apatite, hard phosphate, admant lime stone, chromite, Alumina; H-6: Anhydrite, ilmenite, hornblend; H-7: quartzy, granite; H-8: citrine; H-9: corundum, corundum; And h-10: diamond.

Preferably, described cracking-off agent granule has the color that is different from clear base fully.The content that the cracking-off agent granule preferably exists by described composition weight meter less than about 10%, preferably less than about 5%.

Claimed flare pellet

Multi phase personal care composition of the present invention can comprise claimed flare pellet in mutually at least one of this multi phase personal care composition.The non-limiting example of claimed flare pellet comprise following these: coated interference pigment, multi-layer pigments, metallic particles, solid and liquid crystal or their combination.

Coated interference pigment is to have nacreous pigment, and it is to make by the surface that is coated with the granule substrate material with the thin film bag.The shape of granule substrate material is generally strip.Described thin film is the transparent or semitransparent material with high index of refraction.The high index of refraction material demonstrates pearly luster, the mutual interference effect between the incident illumination that the incident illumination that this gloss derives from the reflection of small pieces substrate/bag coating interface and bag coating surface reflect.The content of the coated interference pigment of multi phase personal care composition preferably is no more than about 20% weight of compositions, more preferably no more than about 10% weight, even more preferably no more than about 7% weight, also more preferably no more than about 5% weight of described multi phase personal care composition.The content of the coated interference pigment of multi phase personal care composition is preferably about 0.1% weight of multi phase personal care composition at least, more preferably at least about 0.2% weight, even, also more preferably press described composition weight meter at least about 1% weight more preferably at least about 0.5% weight.When as to be filed in " the measuring the sedimentary adhesive tape stripping of pigment bar method " described in the common unsettled application sequence number 60/469,075 on May 8th, 2003 described, also after the drip washing, sedimentary pigment optimization is at least 0.5 μ g/cm on skin with the pigment coating ², more preferably at least 1 μ g/cm ², even more preferably at least 5 μ g/cm ²

Coated interference pigment of the present invention is the strip granule.The particulate thickness of the strip of multi phase personal care composition preferably is no more than about 5 μ m, more preferably no more than about 2 μ m, also more preferably no more than about 1 μ m.The particulate thickness of the strip of multi phase personal care composition is preferably at least about 0.02 μ m, more preferably at least about 0.05 μ m, even more preferably at least about 0.1 μ m, also more preferably at least about 0.2 μ m.

Granularity decision opacity and gloss.Measure granularity by the diameter thickness of measuring particulate matter.Term used herein " diameter " is meant the longest distance of particulate matter long axis direction.Diameter can be measured with any suitable method known in the art, as the Particle Size Analyzer Mastersizer 2000 of Malvern Instruments production.The average diameter of the coated interference pigment of multi phase personal care composition preferably is not more than about 200 μ m, more preferably no more than 100 μ m, even more preferably no more than about 80 μ m, also more preferably no more than about 60 μ m.The diameter of the coated interference pigment of multi phase personal care composition is preferably at least about 0.1 μ m, more preferably at least about 1.0 μ m, even more preferably at least about 2.0 μ m, also more preferably at least about 5.0 μ m.

The coated interference pigment of multi phase personal care composition comprises multiple structure.Particulate central authorities are that refractive index (RI) generally is lower than 1.8 planar substrate.Various granule substrates can be used for the present invention.Non-limiting example is natural mica, synthetic mica, graphite, Talcum, Kaolin, Alumina bits, bismuth oxychloride, silicon dioxide bits, chips of glass, pottery, titanium dioxide, CaSO ₄, CaCO ₃, BaSO ₄, borosilicate and their mixture, preferred Muscovitum, silicon dioxide and Alumina bits.

Thin film or plural layers are coated on the surface of above-mentioned substrate by bag.Thin film is made by the refractive material of height.The refractive index of these materials is generally greater than 1.8.

Various thin film can be used for the present invention.Non-limiting example is TiO ₂, Fe ₂O ₃, SnO ₂, Cr ₂O ₃, ZnO, ZnS, ZnO, SnO, ZrO ₂, CaF ₂, Al ₂O ₃, BiOCl and their mixture, or be the form of stratum disjunctum, preferred TiO ₂, Fe ₂O ₃, Cr ₂O ₃, SnO ₂For multiple structure, described thin film can all be made up of high-index material, or alternately is made up of the material of high and low RI, and high RI thin film is as top layer.

Interference colours are functions of film thickness, and for different materials, the thickness of particular color may be different.For TiO ₂, one deck 40nm to 60nm or its whole multilamellar are sent silver color, 60nm to 80nm yellow, 80nm to 100nm redness, 100nm to 130nm blueness, 130nm to 160nm green.Except interference colours, other transparent absorption pigment is also precipitable on top layer or and TiO ₂Layer is precipitation simultaneously.Material commonly used is red or Black Rouge, ferric ferrocyanide, chromium oxide or carmine.The color that it is found that coated interference pigment also feels that to people's the colour of skin appreciable impact is arranged except its brightness.Usually, preferred color is silver-colored, golden, red, green and their mixing.

The non-limiting example that can be used for coated interference pigment of the present invention comprises Persperse, and the commodity that Inc. supplies with are by name

Those; EMD Chemicals, the commodity that Inc. supplies with are by name

With Those; The commodity that Engelhard Co. supplies with are by name

Those.

In embodiments of the invention, the coated interference pigment surface is hydrophobic or hydrophobically modified.Use is filed in the contact angle that coated interference pigment is measured in " test of granule contact angle " described in the common unsettled application sequence number 60/469,075 on May 8th, 2003.Contact angle is big more, and the hydrophobicity of coated interference pigment is big more.The contact angle that coated interference pigment of the present invention has is at least 60 degree, more preferably greater than 80 degree, even more preferably greater than 100 degree, also more preferably greater than 100 degree.In the coated interference pigment of hydrophobically modified or HMIP can allow to be clipped in HMIP mutually, and HMIP is more deposited.Preferred HMIP is 1: 1 to about 1: 70 with mutually ratio, more preferably 1: 2 to about 1: 50, and also more preferably 1: 3 to about 1: 40, most preferably 1: 7 to about 1: 35.

In one embodiment of the invention, HMIP preferably be sandwiched in useful mutually in.This makes that the granularity of useful phase usually must be greater than HMIP.In a preferred embodiment of the invention, useful phase granule only each useful phase granule comprise a spot of HMIP.The amount that preferably comprises is more preferably less than 10 less than 20, most preferably less than 5.These parameters, useful phase droplet can utilize the optical microscopy use to measure with relative size and the particulate about quantity of HMIP in each useful granule mutually of HMIP.

HMIP with useful mutually can be or be mixed in the compositions respectively by pre-composition.For the situation of adding respectively, hydrophobic pigment in the preparation processing procedure, disperse to enter useful mutually in.HMIP of the present invention preferably has hydrophobic bag coating, and described bag coating levels is no more than about 20% weight of total particle weight, more preferably no more than about 15% weight, even more preferably no more than about 10% weight.HMIP of the present invention preferably has hydrophobic bag coating, and described bag coating levels is about 0.1% weight of total particle weight at least, more preferably at least about 0.5% weight, even more preferably at least about 1% weight.The non-limiting example that can be used for hydrophobic surface processing of the present invention comprises siloxanes, acrylate-silicone copolymers, acrylate polymer, alkyl silane, isopropyl three isostearic acid titaniums, sodium stearate, magnesium myristate, perfluor ethanol phosphate ester, the poly-methyl isopropyl ether of perfluor, lecithin, Carlow crust wax, polyethylene, chitosan, lauroyl lysine, cerolipoid extract and their mixture, preferred siloxanes, silane and stearate.Surface disposal facility comprises US Cosmetics, KOBO Products Inc. and Cardre Inc..

Nonessential composition

Multiple suitable nonessential composition can be used in the multi phase personal care composition.These nonessential compositions typically are those most and are used for cosmetics by approval and are described in handbook as " CTFACosmetic Ingredient Handbook ", second edition (The Cosmetic, Toiletries, and Fragrance Association, Inc.1988,1992) in material.These nonessential materials can be used to any aspect of the present composition, comprise each phase as described herein.

Nonrestrictive nonessential composition comprises wetting agent and solute.Can use multiple wetting agent and solute, and their content of existing counts about 0.1% to about 50%, preferred about 0.5% to about 35% by the weight of described personal care composition, more preferably from about 2% to about 20%.Preferred humectants is a glycerol.

Preferred water soluble organic substance is selected from the polyhydric alcohol with following structure:

R1-O(CH ₂-CR2HO) _nH

Wherein R1=H, C1-C4 alkyl; R2=H, CH ₃, and n=1 to 200; Derivant (as oxyalkylated glucose), pantothenylol (comprising D-, L-and D, the L-configuration), 2-pyrrolidone-5-carboxylic acid, hyaluronic acid, lactamide monoethanolamine, acetamide monoethanolamine, carbamide and the general formula of the alkanediol of C2-C10, guanidine, glycolic and glycol hydrochlorate (as ammonium salt and tetraalkylammonium salt), lactic acid and lactate (as ammonium salt and tetraalkylammonium salt), polyhydroxy-alcohol (as sorbitol, glycerol, hexanetriol, propylene glycol, hexanediol etc.), Polyethylene Glycol, sugar and starch, sugar and starch are (HOCH ₂CH ₂) _xNH _yEthanolamine (x=1 to 3 wherein; Y=0 to 2, and x+y=3), and their mixture.Most preferred polyhydric alcohol is selected from glycerol, polyoxypropylene (1) glycerol and polyoxypropylene (3) glycerol, sorbitol, butanediol, propylene glycol, sucrose, carbamide and triethanolamine.

Nonionic polyethylene/polypropylene glycol polymers can be preferably used as skin conditioning agent.The especially preferred polymer that can be used for this paper is: PEG-2M, wherein x equals 2, and the meansigma methods of n is that about 2,000 (PEG 2-M also is called as Polyox

N-10 (available from UnionCarbide) and PEG-2,000); PEG-5M, wherein x equals 2, and the meansigma methods of n is that about 5,000 (PEG 5-M also is called as Polyox

35 and Polyox

N-80 (both are all available from Union Carbide) and PEG-5,000 and PolyethyleneGlycol 200,000); PEG-7M, wherein x equals 2, and the meansigma methods of n is that about 7,000 (PEG7-M also is called as Polyox

N-750 is available from Union Carbide); PEG-9M, wherein x equals 2, and the meansigma methods of n is that about 9,000 (PEG 9-M also is called as Polyox

N-3333 is available from Union Carbide); PEG-14M, wherein x equals 2, and the meansigma methods of n is that about 14,000 (PEG 14-M also is called as Polyox WSR-205 and Polyox

N-3000, both are all available from UnionCarbide); And PEG-90M, wherein x equals 2, and the meansigma methods of n is that about 90,000 (PEG-90M also is called as Polyox

-301, available from Union Carbide).

Other non-limiting examples of these nonessential compositions comprise: vitamin and derivant thereof are (as ascorbic acid, vitamin E, tocopherol acetas etc.), sunscreen, thickening agent is (as the polyhydric alcohol alkoxy ester, with trade name Crothix available from Croda), the antiseptic of compositions antimicrobial integrity is used to keep clean, anti-acne medicament (resorcinol, salicylic acid etc.), antioxidant, skin console and rehabilitation agent (as Aloe extract, allantoin etc.), chelating agen and sequestering agent, and be suitable for aesthetic purposes reagent (as aromatic, quintessence oil, the skin sensitizer, pigment, pearling agent (as Muscovitum and titanium dioxide), the color lake, coloring agent, or the like (as Oleum Caryophylli, menthol, Camphora, Eucalyptus oil and acetaminol)).

The viscosity method

Can use model to measure structured aqueous phase of the non-foaming of this paper and foaming cleansing viscosity mutually as the Wells-Brookfield awl/plate viscometer of DV-II+.Use 2.4cm 2 down at 25 ℃ ⁰The bevel-type measuring system is measured, and wherein the gap between two little pins that lay respectively at cone and flat board is 0.013mm.Measurement is performed such: injection 0.5ml sample, and then to set the speed rotating cone of 1rpm.The resistance of cone rotation produces the moment of torsion that is directly proportional with the shear stress of fluid sample.The numerical value of moment of torsion is adding that load sample was read by viscometer after 2 minutes and is being counted as absolute centipoise unit (mPa*s) according to geometric constant, the speed of rotation and the torquemeter relevant with stress of cone.

The yield point method

Can use the controlled stress rheometer of TA Instruments AR2000 to measure structured aqueous phase of non-foaming and foaming cleansing yield point mutually.For this paper, yield point is to produce 1% the needed stress value of strain at the structured aqueous phase of the non-foaming of liquid or foaming cleansing on mutually.Measure with the parallel-plate measuring system of 4cm diameter down at 25 ℃, and the gap is 1mm.Measurement is to apply shear stress (typical case is from about 0.1Pa to about 500Pa) by follow procedure in 5 minutes interval to carry out.This is the stress value that causes the sample distortion, the curve of can draw shear stress and strain stress relation.From this curve, can determine the yield point of the structured aqueous phase of the non-foaming of liquid.With liquid structured aqueous phase of non-foaming or foaming cleansing measure them before being mixed into compositions mutually, measure again after perhaps after being mixed into compositions, compositions being separated by suitable physical separation method (as centrifugal, absorption, machine cuts, drip washing, filtration or other separation method).

Relevant muddy index method

Use Macbeth color measurement system-Gretag Macbeth model 7000 (dribbling geometric optics head) to carry out " relevant muddy index method ".Appliance requires is calibrated under reflection and transmission mode.These calibrations all are used for obtaining muddy relatively index.

If will prepare sample, compositions with centrifugal about 3 minutes of 3000rpm to remove any bubble that may exist.Then, slowly compositions is poured into the light ware and avoided being entrained into air.If air is carried secretly, then allow sample at room temperature leave standstill 30 minutes to remove bubble.If still have bubble, the light ware of at first turning cleans this light ware then and makes it dry, and then as before reloading sample.Remove the compositions of any spilling on light ware outer surface by methods such as for example wipings.The sample of compositions must be in the 2C of initial calibration temperature.

In case prepared sample, instrument just should be in the Routine Test Lab setting, uses the C illumination, 2 degree view angles, and do not have average.Then the instrument setting being configured to CRIOLL is provided with.This mirror image composition that comprises by change, the ultraviolet of repulsion and the measurement pattern of reflectance are finished.Under the situation without any the planchet holder in instrument, carry out these changes.Then, the large sample ware of n.s is put into instrument, according to the screen prompt calibration instrument.Measurement pattern is switched to emission, and instrument will show that BTIOLL is provided with then.Abide by the screen prompt calibration instrument.

Then, instrument is switched to measurement pattern--relative turbidity.It will be XHIOLL at present that instrument is provided with.Abide by the screen prompt calibration instrument.New instrument is provided with and will be CHIOLL.The operator clicks index icon on the tool bar and accesses the display screen that shows relevant muddy result then.Test as standard with empty ware.

The composition sample that will the analyze light ware of packing into is guaranteed not have air and is carried secretly.As the on-test operation, and the relevant muddy result of record percentage ratio.The calibration of instrument must be carried out once in per at least 8 hours.

The granulometry method:

The granulometry method be known in the art typical those.And use band to use the standard Nikon optical microscope of the standard transillumination of x10 object lens.For focusing accurately, Lucia G software (Nikon product) and the following step are used simultaneously.The first step of analyzing needs user scanning and selects one represent whole zone-for for the purpose of accurately, this step typical need repeatedly precision adjustment.Observed image is sent on the standard monitor by the JVC video camera, and measures each granule with the canonical measure macro-instruction; Thereby promptly click particulate each limit--measure diameter.Be the explanation aspherical particle, always level is crossed monitor and is come assessment " diameter ".By measuring in a plane, this technology can compensate aspheric surface geometry automatically, and owing to measured a large amount of granules, has obtained the equivalent average diameter.Though equivalent diameter can be by measuring major axis and minor axis and calculating equivalent diameter by the aspect ratio formula and determine, top technology provides same accurate result.

Since at first calculate maximum granule and thereby to guarantee to have calculated and measured all granules be typical human nature, putting on each granule that calculated with a point (typical case uses erasable pen) on the monitor.Continue this computational process each single visible particle in the zone all by calculating.For very little particle size distribution, this can cause the calculating more than 400 times.For bigger granularity, can estimate about 100 calculating in each zone, yet in this case, should select extra zone to guarantee calculating 200 independent granules at least.In a word, with regard to all situations, should measure at least 200 independent granules, and in all cases, calculate all granules (being limited to 400 to 500 in fact) in the zone.On an average, by the embodiment of all observations of this paper, each sample should be measured about 300 granules.Analysis can (with hands basis of calculation volume averaging value to prove this technology) or more typically, uses the canonical measure grand (based on the above sphere that is assumed to be of surveying diameter) of automatically data of recording volume meansigma methods being classified.

Using method

The preferred local coating of multi-phase personal cleansing compositions of the present invention presents in an amount at least sufficient to send skin cleaner, hydrophobic material and granule effectively to coated surface at the desired zone of skin or hair.By using cleaning powder puff, towel, sponge or other utensil, said composition is coated on the skin directly or indirectly.Before the local coating, during or afterwards, preferred dilute with water said composition, then drip washing or wiping skin or hair then, the combination of preferred water or water-insoluble substrate and water, the surface that drip washing is coated.

Therefore, the invention still further relates to by above-mentioned coating compositions of the present invention, the method for coming cleaning skin.Method of the present invention also relates to the coating by the invention described above compositions, provides required skin active agent effectively to send and provide the method for effectively sending the beneficial effect of gained by described herein to coated surface.

Preparation method

Multi-phase personal cleansing compositions of the present invention can be suitable for making and preparing the preparation of the known of required heterogeneous product form or other effective technologies by any.It is effective that the dentifrice tube filling technique is combined with the turntable design.In addition, disclosed method and apparatus prepares among the also available US 6,213,166 of the present invention.Described method and apparatus can make two or more compositionss be filled in the container with helical configuration.This method need use at least two nozzles to come filling containers.Container is placed in the static mixer, this container rotation when compositions is introduced in the container.

Alternatively, to mix biphase at least also be effective by at first composition isolated being placed the storage tank that separates that is connected with pump and flexible pipe.These are pumped in the hydrid component with predetermined amount then.Then, these are moved to the hydrid component from hydrid component, and these mix in hydrid component so that the demonstration of single products obtained therefrom has distinct phase pattern then.Described pattern is selected from streaky, marblized, geometry and their mixing.Next step relates to blended product in hydrid component is pumped to a nozzle by flexible pipe, then this nozzle is placed container, with the product filling containers of gained.When they are applied to specific embodiments of the present invention, describe among the described hereinafter embodiment of the concrete non-limiting example of these class methods.

If multi-phase personal cleansing compositions comprises the pattern of changes colour, then may need these compositionss are contained in the transparent or semitransparent packing, so that seeing through packing, consumer sees pattern.Because the viscosity of the present composition also needs to comprise operation instruction, consumption guidance person is inverted in packing box on its lid and stores, to promote distribution.

Should be appreciated that each higher limit that provides in this manual comprises each lower limit, is also conclusivelyed show in this article as this lower limit.Each lower limit that provides in this manual comprises each higher limit, is also clearly represented in this article as this higher limit.Each numerical range that provides in this manual comprises all less numerical rangies that are contained in this bigger numerical scope, is all clearly represented as this less numerical range herein.

Except as otherwise noted, in the description of this paper, embodiment and claims all umber, ratio and percent all by weight, and all numerical rangies conventional degree of accuracy of all using this area to provide.

Embodiment

The following example has further described and has proved the embodiment in the scope of the invention.These embodiment that given only are illustrative, and are unintelligible for being limitation of the present invention, because can carry out multiple change under the condition that does not deviate from spirit and scope of the invention.

Each following embodiment is a multi phase personal care composition, described compositions comprise by described personal care composition weight 50% first mutually with by described personal care composition weight 50% second mutually.The amount of each component is to provide with the percentage by weight form based on the specific phase weight that comprises this component in the specific phase.

Embodiment 1 to 5

Described the following example is the non-limiting example of heterogeneous compositions.

Composition	Embodiment 1	Embodiment 2	Embodiment 3	Embodiment 4	Embodiment 5
						I. the first combined thing	Percentage by weight (%)	Percentage by weight (%)	Percentage by weight (%)	Percentage by weight (%)	Percentage by weight (%)
Miracare SLB-365 (available from Rhodia) (polyoxyethylene tridecyl ether sodium sulfate, N-lauroyl amido ethyl-N hydroxyethyl sodium acetate, cocoyl single ethanol amide)	47.4	47.4	47.4	47.4	47.4
						Rhaball Gum CG-M 8M (N-Hance 3196, available from Aqualon)	0.7	0.7	0.7	0.7	0.7
PEG 90M (Polyox WSR 301 is available from Dow Chemical)	0.2	0.2	0.2	0.2	0.2
						Sodium chloride	3.5	3.5	3.5	3.5	3.5
Antiseptic	0.84	0.84	0.84	0.84	0.84
						Citric acid	0.4	0.4	0.4	0.4	0.4
Spice	2.0	2.0	2.0	2.0	2.0
						Expancel 091 DE 40d 30 is (available from Expancel, Inc.)	0.4	0.4	0.4	0.4	0.4
Water	In right amount	In right amount	In right amount	In right amount	In right amount
						(pH)	(6.0)	(6.0)	(6.0)	(6.0)	(6.0)
II. the second combined thing
						Vaseline (SuperWhite Protopet is available from WITCO)	57.0	58.5	57.75	58.5	57.0
Mineral oil (Hydrobrite 1000PO White MO is available from WITCO)	38.0	39.0	38.5	39.0	38.0
						Muscovitum/titanium dioxide/stannum oxide/triethoxy caprylyl silane (Kobopearl Interval Gold-11S2 is available from Kobo Products Inc.)	1.25	1.875
Muscovitum/titanium dioxide/triethoxy caprylyl silane (Kobopearl Stellar White-11S 2 is available from Kobo Products Inc.)	2.50
						Titanium dioxide/Muscovitum/silicon dioxide/polydimethylsiloxane (SAT-Timiron Splendid Red is available from US Cosmetics)			1.875
Muscovitum/titanium dioxide/triethoxy caprylyl silane/ferrum oxide/stannum oxide (Kobopearl Vibrant Gold-11S2 is available from Kobo Products Inc.)	1.25	0.625
						Muscovitum/titanium dioxide/stannum oxide/triethoxy caprylyl silane (Kobopearl Interval Red-11S2 is available from Kobo Products Inc.)				1.75
Muscovitum/mineral/titanium dioxide/ferrum oxide/lecithin (LT-Colorona Red Gold is available from US Cosmetics)					2.50
						Muscovitum/titanium dioxide/polydimethylsiloxane (SAT-Timiron Super Green is available from US Cosmetics)
Muscovitum/polydimethylsiloxane (SA-M-M is available from US Cosmetics)
						Muscovitum/titanium dioxide/polydimethylsiloxane (SAT-Flamenco Ult ra Silk 2500 is available from US Cosmetics)
(Helicone HC Maple is available from Kobo Products, Inc.) for polyacrylate-4
						Muscovitum/titanium dioxide/polydimethylsiloxane (SAT-Timiron MP115Starluster is available from US Cosmetics)			1.875	1.75	2.50

Above-mentioned composition can prepare by routine preparation and hybrid technology.Form the citric acid pre-composition by at first citric acid being added to the water with 1: 3 ratio, prepare the first combined thing.Then, in the following order, following ingredients is joined in the main mixer: water, MiracareSLB-365, sodium chloride, sodium benzoate, disodiumedetate, 1,3-dihydroxymethyl-5,5-dimethyl hydantoin.Start the stirring of main mixer.In another mixer, polymer (poly-quaternary amine 10, Jaguar C-17 or N-Hance 3196) with in the ratios diverge entry in 1: 10, and is formed the polymer pre-composition.Under the continuous stirring, fully decentralized polymer pre-composition is joined in the main mixer.Polyox WSR 301 is distributed in the water, joins then in the main mixer.Then, remaining water and spice are joined in the batch of material.Continue to stir, until forming homogeneous solution.

By vaseline is joined in the mixer, can prepare second phase.Container is heated to 190 °F (88 ℃).Then, add mineral oil and granule.This batch of material of high shear is to guarantee good Dispersion of Particles.Continue to stir this batch of material, thereby slowly this batch of material is cooled to room temperature.

By at first these isolating placing mutually being connected with separating storage tank and can mixing these phases of pump and flexible pipe.These are pumped in the hydrid component with predetermined amount then.Then, these are moved to the hydrid component from hydrid component, and these mix in hydrid component so that the demonstration of single products obtained therefrom has distinct phase pattern then.Described pattern is selected from streaky, marblized, geometry and their mixing.Next step relates to blended product in hydrid component is pumped to a nozzle by flexible pipe, then this nozzle is placed container, with the product filling containers of gained.Striped is of a size of the wide and 100mm length of about 6mm.Under environmental condition, this product can keep stable 180 days at least.

Embodiment 6 to 10

Described the following example is the non-limiting example of heterogeneous compositions.

Above-mentioned composition can prepare by routine preparation and hybrid technology.Form the citric acid pre-composition by at first citric acid being added to the water with 1: 3 ratio, prepare the first combined thing.Then, in the following order, following ingredients is joined in the main mixer: water, MiracareSLB-365, sodium chloride, sodium benzoate, disodiumedetate, 1,3-dihydroxymethyl-5,5-dimethyl hydantoin.Start the stirring of main mixer.In another mixer, polymer (poly-quaternary amine 10, Jaguar C-17 or N-Hance 3196) with in the ratios diverge entry in 1: 10, and is formed the polymer pre-composition.Under the continuous stirring, fully decentralized polymer pre-composition is joined in the main mixer.Polyox WSR 301 is distributed in the water, and joins in the main mixer.Then, remaining water and spice are joined in the batch of material.Continue to stir, until forming homogeneous solution.

By vaseline is joined in the mixer, can prepare second phase.Container is heated to 190 °F (88 ℃).Then, add mineral oil and granule.This batch of material of high shear is to guarantee good Dispersion of Particles.Continue to stir this batch of material, thereby slowly this batch of material is cooled to room temperature.

By at first these isolating placing mutually being connected with separating storage tank and can mixing these phases of pump and flexible pipe.These are pumped in the hydrid component with predetermined amount then.Then, these are moved to the hydrid component from hydrid component, and these mix in hydrid component so that the demonstration of single products obtained therefrom has distinct phase pattern then.Described pattern is selected from streaky, marblized, geometry and their mixing.Next step relates to blended product in hydrid component is pumped to a nozzle by flexible pipe, then this nozzle is placed container, with the product filling containers of gained.Striped is of a size of the wide and 100mm length of about 6mm.Under environmental condition, this product can keep stable 180 days at least.

Embodiment 11 to 13

Described the following example is the non-limiting example of heterogeneous compositions.

	Embodiment 11	Embodiment 12	Embodiment 13
				Composition	Percentage by weight (%)	Percentage by weight (%)	Percentage by weight (%)
I. the first combined thing
				Laureth-3 ammonium sulfate	3.0	3.0	3.0
N-lauroyl amido ethyl-N hydroxyethyl sodium acetate (Miranol L-32Ultra is available from Rhodia)	16.7	16.7	16.7
				Ammonium lauryl sulfate	1.0	1.0	1.0
Lauric acid	0.9	0.9	0.9
				Three (hydroxy stearic acid) glyceride (Thixcin R)	2.0	2.0	2.0
Rhaball Gum CG-M 8M (N-Hance 3196, available from Aqualon)	0.17	0.75	0.75
				Rhaball Gum CG-M 8M (Jaguar C-17 is available from Rhodia)	0.58	-	-
Polyquaternary amine 10 (UCARE polymer JR-30M is available from Amerchol)	0.45	-	-
				PMAm oxypropyl trimethyl ammonium chloride (Polycare 133, available from Rhodia)	-	0.24	-
Polyquaternary amine-39 (Merqurt Plus 3300 is available from Calgon)	-	0.81	-
				PEG 90M (Polyox WSR 301 is available from Union Carbide)	0.25	-	-
PEG-14M (Polyox WSR N-3000H is available from Union Carbide)	0.45	2.45	2.45
				Inferior oleamide propyl group PG-phospholipid ammonium chloride polydimethylsiloxane (Monasil PLN is available from Uniqema)	-	1.0	4.0
Glycerol	1.4	4.9	4.9
				Sodium chloride	0.3	0.3	0.3
Sodium benzoate	0.25	0.25	0.25
				Disodiumedetate	0.13	0.13	0.13
1,3-dihydroxymethyl-5,5-dimethyl hydantoin	0.37	0.37	0.37
				Citric acid	1.6	0.95	0.95
Titanium dioxide	0.5	0.5	0.5
				Spice	0.5	0.5	0.5
Water	In right amount	In right amount	In right amount
II. the second combined thing
				Vaseline (SuperWhite Protopet is available from WITCO)	60	60	60
Mineral oil (Hydrobrite 1000White MO is available from WITCO)	38	28	28
				Tospearl 2000 (available from GE)	-	10	-
Dry-Flo AF (available from National Starch)	-	-	10
				Colorona carmetta beauty treatment pigment (available from Rona)	2	2	2

The first combined thing can prepare by routine preparation and hybrid technology.Can prepare by at first preparing following pre-composition as embodiment 11 described first combined things: citric acid with 1: 3 ratio premix in water, melon ear polymer and Jaguar C-17 and N-Harce3196 with 1: 10 ratio premix in water, UCARE and JR-30M with about 1: 30 ratio premix in water, and Polyox and PEG-90M and PEG-14M with about 1: 2 ratio premix in glycerol.Then, following ingredients is joined in the main mixer: ammonium lauryl sulfate, polyoxyethylene lauryl ether-3 ammonium sulfate, citric acid pre-composition, Miranol L-32ultra, sodium chloride, sodium benzoate, disodiumedetate, lauric acid, ThixcinR, melon ear pre-composition, UCARE pre-composition, Polyox pre-composition and remaining water.Stir this container of heating down, reach 190 °F (88 ℃) until it.It was mixed about 10 minutes.Under slowly stirring, cool off batch of material with psychrolusia, reach 110 °F (43 ℃) until it.Add following ingredients: 1,3-dihydroxymethyl-5,5-dimethyl hydantoin, spice, titanium dioxide.Continue to stir, until forming homogeneous solution.

Can prepare by at first preparing following pre-composition as embodiment 12 described compositionss: citric acid with 1: 3 ratio premix in water, melon ear polymer and N-Hance 3196 with 1: 10 ratio premix in water, and Polyox and PEG-14M with about 1: 2 ratio premix in glycerol.Then, following ingredients is joined in the main mixer: ammonium lauryl sulfate, polyoxyethylene lauryl ether-3 ammonium sulfate, citric acid pre-composition, Miranol L-32ultra, sodium chloride, sodium benzoate, disodiumedetate, lauric acid, Thixcin R, melon ear pre-composition, Polyox pre-composition, Polycare 133, Merquat Plus 3300, Monosil PLN and remaining water.Stir this container of heating down, reach 190 °F (88 ℃) until it.It was mixed about 10 minutes.Under slowly stirring, cool off batch of material with psychrolusia, reach 110 °F (43 ℃) until it.Add following ingredients: 1,3-dihydroxymethyl-5,5-dimethyl hydantoin, spice, titanium dioxide.Continue to stir, until forming homogeneous solution.

Can prepare by at first preparing following pre-composition as embodiment 13 described compositionss: citric acid with 1: 3 ratio premix in water, melon ear polymer and N-Hance 3196 with 1: 10 ratio premix in water, and Polyox and PEG-14M with about 1: 2 ratio premix in glycerol.Then, following ingredients is joined in the main mixer: ammonium lauryl sulfate, polyoxyethylene lauryl ether-3 ammonium sulfate, citric acid pre-composition, Miranol L-32ultra, sodium chloride, sodium benzoate, disodiumedetate, lauric acid, ThixcinR, melon ear pre-composition, Polyox pre-composition, Monasil PLN and remaining water.Stir this container of heating down, reach 190 °F (88 ℃) until it.It was mixed about 10 minutes.Under slowly stirring, cool off batch of material with psychrolusia, reach 110 °F (43 ℃) until it.Add following ingredients: 1,3-dihydroxymethyl-5,5-dimethyl hydantoin, spice, titanium dioxide.Continue to stir, until forming homogeneous solution.

By vaseline is joined in the mixer, can prepare second phase.Container is heated to 190 °F (88 ℃).Then, stir adding mineral oil, beauty treatment pigment and Dry-Flo AF or Tospearl down.Slowly stir down, make the container cooling.

By at first these isolating placing mutually being connected with separating storage tank and can mixing these phases of pump and flexible pipe.These are pumped in the hydrid component with predetermined amount then.Then, these are moved to the hydrid component from hydrid component, and these mix in hydrid component so that the demonstration of single products obtained therefrom has distinct phase pattern then.Described pattern is selected from streaky, marblized, geometry and their mixing.Next step relates to blended product in hydrid component is pumped to a nozzle by flexible pipe, then this nozzle is placed container, with the product filling containers of gained.Striped is of a size of the wide and 100mm length of about 6mm.Under environmental condition, this product can keep stable 180 days at least.

Embodiment 14 to 16

Following examples are non-limiting examples of heterogeneous compositions of the present invention.

	Embodiment 14	Embodiment 15	Embodiment 16
				Composition	Percentage by weight (%)	Percentage by weight (%)	Percentage by weight (%)
I. the first combined thing
				Miracare SLB-365 (available from Rhodia) (polyoxyethylene tridecyl ether sodium sulfate, N-lauroyl amido ethyl-N hydroxyethyl sodium acetate, cocoyl single ethanol amide)	47.4	47.4	47.4
Sodium chloride	3.5	3.5	3.5
				Disodiumedetate	0.05	0.05	0.05
1,3-dihydroxymethyl-5,5-dimethyl hydantoin	0.67	0.67	0.67
				Citric acid	0.4	0.4	0.4
Spice	2.0	2.0	2.0
				Water	In right amount	In right amount	In right amount
(pH)	(6.0)	(6.0)	(6.0)
				II. the second combined thing
Acrylate/vinyl isodecyl acid esters cross linked polymer (Stayblen 30, available from 3V)	0.8	1.0	1.2
				Triethanolamine	0.8	1.0	1.2
1,3-dihydroxymethyl-5,5-dimethyl hydantoin	0.37	0.37	0.37
				Unispheres NT-2806 (pink) (mannitol, cellulose, hydroxypropyl cellulose are available from Induchem)	5	5	5
Water and microcomponent	93.03	92.63	92.23
				(pH)	(7.0)	(7.0)	(7.0)

Above-mentioned composition can prepare by routine preparation and hybrid technology.Form the citric acid pre-composition by at first citric acid being added to the water with 1: 3 ratio, prepare the first combined thing.Then, in the following order, following ingredients is joined in the main mixer: water, MiracareSLB-354, sodium chloride, sodium benzoate, disodiumedetate, 1,3-dihydroxymethyl-5,5-dimethyl hydantoin.Start the stirring of main mixer.In another mixer, polymer (N-Hance 3196) with in the ratios diverge entry in 1: 10, and is formed the polymer pre-composition.Under the continuous stirring, fully decentralized polymer pre-composition is joined in the main mixer.Polyox WSR 301 is distributed in the water, and joins in the main mixer.Then, remaining water and spice are joined in the batch of material.Continue to stir, until forming homogeneous solution.

By preparing second phase in the water that slowly Stabylen 30 is added mixer.Then, stirring adding triethanolamine, 1,3-dihydroxymethyl-5,5-dimethyl hydantoin, Unisphere NT-2806 (pink).Be mixed to evenly.

By at first these isolating placing mutually being connected with separating storage tank and can mixing these phases of pump and flexible pipe.These are pumped in the hydrid component with predetermined amount then.Then, these are moved to the hydrid component from hydrid component, and these mix in hydrid component so that the demonstration of single products obtained therefrom has distinct phase pattern then.Described pattern is selected from streaky, marblized, geometry and their mixing.Next step relates to blended product in hydrid component is pumped to a nozzle by flexible pipe, then this nozzle is placed container, with the product filling containers of gained.Striped is of a size of the wide and 100mm length of about 6mm.Under environmental condition, this product can keep stable 180 days at least.

The relevant portion of all documents of quoting in detailed Description Of The Invention is incorporated herein by reference; It is to its approval as prior art of the present invention that the quoting of any document not can be regarded as.

Although illustrated and described the present invention with specific embodiments, it will be apparent to those skilled in the art that many other variations and modifications may be made in the case of without departing from the spirit and scope of protection of the present invention.Therefore in additional claims, comprise all such changes and modifications in the scope of the invention consciously.

Claims (30)

1. multi phase personal care composition, described compositions comprises:

A) comprise the first visually different phase of cleansing phase, described cleansing phase comprises the surfactant by the weight 1% to 50% of described cleansing phase, and described surfactant is selected from anion surfactant, non-ionic surface active agent, zwitterionic surfactant, cationic surfactant and their mixture;

Wherein said cleansing phase is the non newtonian shear thinning, and viscosity is equal to or greater than 3, and 000cps and/or yield point are 0.1Pa at least;

B) comprise the second visually different phase of useful phase, the described useful hydrophobic composition that comprises mutually, described hydrophobic composition comprises the hydrophobic material by the weight 20% to 100% of described useful phase, and described hydrophobic material is selected from lipoid, hydrocarbon, fat, hydrophobicity plant extract, fatty acid, quintessence oil, silicone oil and their mixture;

The Vaughan solubility parameter that wherein comprises the described useful phase of hydrophobic composition is 5 to 15;

The wherein said pattern that forms mutually;

Wherein at least one granule that comprises mutually;

Wherein said granule exists with the beauty treatment effective dose; With

Wherein said with actual contact each other packaged and keep stability.

2. multi phase personal care composition as claimed in claim 1, wherein said pattern are selected from striated, how much shapes, marbling shape and their combinations.

3. multi phase personal care composition as claimed in claim 2, wherein said pattern are striated, and described striated pattern is of a size of the wide and 10mm length of 0.1mm at least.

4. multi phase personal care composition as claimed in claim 1, described multi phase personal care composition comprise the described granule by the weight at least 0.1% of described compositions.

5. multi phase personal care composition as claimed in claim 1, described multi phase personal care composition comprise the described granule by composition weight meter at least 0.2%.

6. multi phase personal care composition as claimed in claim 1, wherein said particulate granularity is less than 100 μ m.

7. multi phase personal care composition as claimed in claim 1, wherein said particulate diameter are 1 μ m to 70 μ m.

8. multi phase personal care composition as claimed in claim 1, wherein said granule are selected from natural granule, synthetic granule, semi-synthetic granule, sericite and crosslinked polystyrene mixed-powder, Muscovitum and silicon dioxide mixed-powder and their combination.

9. multi phase personal care composition as claimed in claim 1, wherein said granule are selected from cracking-off agent granule, claimed flare pellet and their combination.

10. multi phase personal care composition as claimed in claim 9, wherein said claimed flare pellet is a coated interference pigment; Wherein said coated interference pigment is the coated interference pigment of hydrophobically modified; And wherein said compositions comprises the coated interference pigment by the described hydrophobically modified of described composition weight meter at least 0.1%.

11. multi phase personal care composition as claimed in claim 10, wherein said compositions is with at least 0.5 μ g/cm ²The coated interference pigment of described hydrophobically modified deposit on the skin.

12. multi phase personal care composition as claimed in claim 1, wherein at least one is described cleansing phase mutually, and described cleansing phase comprises:

(i) at least a anion surfactant;

(ii) at least a electrolyte;

(iii) at least a alkanolamide;

(iv) not necessarily additional conventional surfactants; With

(v) water;

Wherein said cleansing phase is the non newtonian shear thinning; With

The viscosity of described cleansing phase is equal to or greater than 3000cps.

13. multi phase personal care composition as claimed in claim 12, wherein said electrolyte comprises:

I) anion, described anion be selected from phosphate radical, chloride ion, sulfate radical, citrate and their mixture and

Ii) cation, described cation is selected from sodium ion, ammonium ion, potassium ion, magnesium ion and their mixture; And the content that wherein said electrolyte exists counts 0.1% to 15% by the weight of described cleansing phase.

14. multi phase personal care composition as claimed in claim 12, wherein said cleansing phase comprises the layer structure agent in addition; Wherein said layer structure agent is selected from fatty acid, fatty acid ester, three (hydroxy stearic acid) glyceride, aliphatic alcohol and their mixture.

15. multi phase personal care composition as claimed in claim 12, described multi phase personal care composition also comprises the cationic deposition polymer.

16. a multi phase personal care composition, described compositions comprise at least two visually distinct phases;

A) comprise first phase of cleansing phase, described cleansing phase comprises the surfactant by the weight 1% to 50% of described cleansing phase, and described surfactant is selected from anion surfactant, non-ionic surface active agent, zwitterionic surfactant, cationic surfactant and their mixture;

Wherein said cleansing phase is the non newtonian shear thinning, and viscosity is equal to or greater than 3, and 000cps and/or yield point are 0.1Pa at least;

B) comprise second phase of useful phase, the described useful hydrophobic composition that comprises mutually, described hydrophobic composition comprises the hydrophobic material by the weight 20% to 100% of described useful phase, and described hydrophobic material is selected from lipoid, hydrocarbon, fat, hydrophobicity plant extract, fatty acid, quintessence oil, silicone oil and their mixture;

The Vaughan solubility parameter that wherein comprises the described useful phase of hydrophobic composition is 5 to 15;

The wherein said pattern that forms mutually;

Wherein at least one granule that comprises mutually;

Wherein first is 90: 10 to 10: 90 with second mutually the ratio; With

Wherein said with actual contact each other packaged and keep stability.

17. multi phase personal care composition as claimed in claim 16, wherein said pattern are selected from striated, how much shapes, marbling shape and their combinations.

18. multi phase personal care composition as claimed in claim 16, described multi phase personal care composition comprise the described granule by the weight at least 0.1% of described compositions.

19. multi phase personal care composition as claimed in claim 16, wherein said granule are selected from natural granule, synthetic granule, semi-synthetic granule, sericite and crosslinked polystyrene mixed-powder, Muscovitum and silicon dioxide mixed-powder and their combination.

20. multi phase personal care composition as claimed in claim 16, wherein said granule are selected from cracking-off agent granule, claimed flare pellet and their combination.

21. multi phase personal care composition as claimed in claim 20, wherein said claimed flare pellet is a coated interference pigment; Wherein said coated interference pigment is the coated interference pigment of hydrophobically modified; And wherein said compositions comprises the coated interference pigment by the described hydrophobically modified of the weight at least 0.1% of described compositions.

22. a multi phase personal care composition, described multi phase personal care composition comprises:

A) comprise first phase of cleansing phase, described cleansing phase comprises the surfactant by the weight 1% to 50% of described cleansing phase, and described surfactant is selected from anion surfactant, non-ionic surface active agent, zwitterionic surfactant, cationic surfactant and their mixture;

Wherein said cleansing phase is the non newtonian shear thinning, has to be equal to or greater than 3 the viscosity of 000cps and/or the yield point of 0.1Pa at least;

B) comprise the useful phase of hydrophobic composition, the described useful hydrophobic material that comprises mutually by the weight 20% to 100% of described useful phase, described hydrophobic material is selected from lipoid, hydrocarbon, fat, hydrophobicity plant extract, fatty acid, quintessence oil, silicone oil and their mixture;

The Vaughan solubility parameter that wherein comprises the described useful phase of hydrophobic composition is 5 to 15, wherein said in addition cleansing phase is 1: 9 to 99: 1 with described useful weight ratio mutually, and described cleansing phase with useful in same packing actual contact, and under environmental condition, can keep stable at least 180 days; And wherein said cleansing phase and the useful striated pattern that forms mutually, it is wide and 1mm is long at least that wherein striped is of a size of at least 0.1mm; And wherein at least one granule that comprises mutually, wherein said granule is the coated interference pigment of hydrophobically modified.

23. multi phase personal care composition as claimed in claim 22, wherein said useful containing mutually is less than 3% surfactant.

24. multi phase personal care composition as claimed in claim 22, described multi phase personal care composition comprise the coated interference pigment by the described hydrophobically modified of weight at least 0.1% weight of described compositions.

25. multi phase personal care composition as claimed in claim 22, wherein said hydrophobic material is selected from vaseline; mineral oil; microwax; paraffin; ceresine; polyethylene; polybutene; poly decene and perhydro-squalene; polydimethylsiloxane; the ring-type polymethyl siloxane; alkylsiloxane; polymethyl siloxane and methyl phenyl silicone; lanoline; lanolin oil; lanolin wax; lanolin alcohol; lanolin fatty acid; isopropyl lanolate; acetylated lanolin; Acetylated lanolin alcohols.; linoleic acid lanoline alcohol ester; castor oil acid lanoline alcohol ester; Oleum Ricini; soybean oil; sunflower seed oil; the maleic acid soybean oil; safflower oil; Oleum Gossypii semen; Semen Maydis oil; Oleum Juglandis; Oleum Arachidis hypogaeae semen; olive oil; cod liver oil; almond oil; American Avocado Tree oil; Petiolus Trachycarpi oil and Oleum sesami; and their combination.

26. multi phase personal care composition as claimed in claim 1, wherein at least one coloring agent that comprises mutually.

27. multi phase personal care composition as claimed in claim 26, wherein said compositions is packaged in the transparent vessel.

28. multi phase personal care composition as claimed in claim 1, wherein said compositions comprises the skin care active material in addition, and wherein said skin care active material is selected from vitamin and derivant thereof; Sunscreen; Antiseptic; The anti-acne medicine; Antioxidant; Skin is consoled and therapeutic agent; Chelating agen; Quintessence oil; The skin sensitizer; And their mixture.

29. a multi phase personal care composition, described compositions comprises:

A) comprise first phase of cleansing phase, weight by described cleansing phase, described cleansing phase comprises 1% to 50% surfactant, and described surfactant is selected from anion surfactant, non-ionic surface active agent, zwitterionic surfactant, cationic surfactant and their mixture;

Wherein said cleansing phase is the non newtonian shear thinning, and it has and is equal to or greater than 3, the viscosity of 000cps and/or the yield point of 0.1Pa at least; With

B) at least one additional phase, the described additional independent structured aqueous phase of non-foaming that comprises mutually, the described consistometric value that contains water at least 10 moor/(1/s), yield point is 0.1Pa at least; With

Wherein at least one granule that comprises mutually; Wherein said granule is the coated interference pigment of hydrophobically modified; Wherein said cleansing phase is 10: 1 to 1: 10 with the structured aqueous ratio mutually of described non-foaming;

Wherein said cleansing phase exists with the structured aqueous form with pattern of non-foaming; Wherein said pattern is the striated pattern; It is wide and 1mm is long at least that wherein said striped is of a size of at least 0.1mm.

30. send the method for skin beneficiating effect to skin or hair for one kind, described method comprises the following steps:

A) compositions as claimed in claim 1 with effective dose is assigned on the utensil, and described utensil is selected from cleaning powder puff, towel, sponge and people's hands;

B) use described utensil to described skin or the described compositions of hair local coating; With

C) by described compositions being removed from described skin or hair with water wash skin or hair.