Semi-crisp corundum fine grinding abrasive band
Technical field
The present invention relates to a kind of abrasive band, specifically semi-crisp corundum fine grinding abrasive band.
Background technology
The high speed development of mechanical industry, more and more higher to the requirement of coated abrasive tool product, consumption is also increasing.In the grinding of hardware surface-treated, to also having been proposed many-sided requirement by the grinding of buffing work-piece.
External as developed countries such as Japan, Korea S have produced and can prevent grinding workpiece surface tear and the higher fine grinding abrasive band product of machining accuracy.Precision Machining is carried out on the metal product surface, the fine grinding abrasive band of domestic manufacturer's production at present all exists substrate surface moist relatively, the resin heat radiation is unhappy, abrasive dust is difficult for breaking away from abrasive particle, the defective of abrasive particle self-sharpening difference, and easily surface of the work is scratched during operation, sand grains upgrades with the frequency of grinding lower, the not high defective of operating efficiency.The domestic user still uses from external import fine grinding abrasive band mostly.
The abrasive band product is made up of three parts: fabricbase, adhesive, removing material, removing material is bonded on the fabricbase by adhesive.At present, the adhesive of fine grinding abrasive band is by phenolic resins, dispersant, diluent etc. on the domestic market, phenolic resins has the shortcoming that self can't overcome: fragility is big, pliability is poor, thereby make adhesive intensity in grinding process of existing fine grinding abrasive band not high, hear resistance and poor in flexibility, it is unhappy to dispel the heat, make abrasive dust be difficult for breaking away from abrasive particle, cause the abrasive particle self-sharpening poor.Therefore, existing fine grinding abrasive band exists service life short, inefficiency, and the frequency of sand grains renewal and grinding is lower during operation, easily with shortcomings such as surface of the work scuffings.
Summary of the invention
It is good to the objective of the invention is to propose a kind of adhesive intensity height, hear resistance pliability in grinding process, and the grinding efficiency height can not scratch the semi-crisp corundum fine grinding abrasive band of surface of the work.
Purpose of the present invention can be achieved through the following technical solutions:
Semi-crisp corundum fine grinding abrasive band is made up of fabricbase, adhesive, removing material, and removing material is a semi-crisp corundum, and removing material is bonded on the fabricbase by adhesive, and adhesive is made up of following components in weight percentage:
Single order thermosetting phenolic resin 36%~40%
Propane type epoxy resin of di phenolic group 4%~5.5%
Melmac 1.8%~2.8%
Boron 0.1%~0.6%
Dispersant 0.1%~0.3%
Coupling agent 0.1%~0.3%
Diluent 2%~6%
Calcium carbonate 18%~26%
Fluoride salt 18%~26%
Inert gas fluoride 0.1%~0.5%.
Purpose of the present invention can also further realize by following technical measures:
Aforesaid semi-crisp corundum fine grinding abrasive band, wherein said dispersant is the sorbitol monostearate that anhydrates (SPAN-60), polyoxyethylene anhydrate sorbitol monostearate (Tween-60), polyglycerol ester.
Aforesaid semi-crisp corundum fine grinding abrasive band, wherein said coupling agent is: silane coupler, titanate coupling agent, aluminate coupling agent.
Aforesaid semi-crisp corundum fine grinding abrasive band, wherein said diluent are ethylene glycol ethyl ether, methyl alcohol, ethanol, distilled water.
Aforesaid semi-crisp corundum fine grinding abrasive band, wherein said fluoride salt are cryolite, sodium fluoborate, calcirm-fluoride, sodium fluoride, aluminum fluoride.
Aforesaid semi-crisp corundum fine grinding abrasive band, wherein said inert gas fluoride are xenon difluoride (XeF2), xenon tetrafluoride (XeF4), xenon hexafluoride (XeF6).
Advantage of the present invention is: hybrid resin of the present invention adopts the mixing of single order thermosetting phenolic resin and propane type epoxy resin of di phenolic group and melmac, can make adhesive can have the advantage of three kinds of resins concurrently, improve their shortcomings separately, reach the purpose of modification, make the adhesive of semi-crisp corundum fine grinding abrasive band of the present invention have the resistance to water of good caking property of epoxy resin and melmac, improved the fragility of phenolic resins, keep the good hear resistance of phenolic resins simultaneously, overcome the relatively poor shortcoming of epoxy resin hear resistance.Add boron, fluoride salt, inert gas fluoride again, can guarantee that adhesive has enough intensity, good hear resistance and necessary pliability in grinding process, when mill was pressed temperature greater than 600 ℃, abrasive material can not come off, when mill was pressed temperature greater than 800 ℃, adhesive can not decompose yet.The fine grinding abrasive band of the new abrasive material be combined into of new adhesive and semi-crisp corundum, abrasive particle is microcrystalline state division<crystal size 2-3um 〉, remain sharpness and higher hardness preferably, the fineness and the precision of workpiece to be machined have been improved, guaranteed that all kinds of effective chemical analysis of abrasive material can fully combine with bonding agent, and under the effect of certain external condition, produce new chemical substance, help the abrasive material cutting workpiece.
The present invention can be widely used in various metal materials, and the especially correct grinding of stainless steel materials and metallic circuit and polishing has the high efficient grinding performance, can strengthen the grinding-polishing ability, stops to scratch, and increases the service life, and increases work efficiency.Tensile strength of the present invention and longitudinal tensile strain rate such as table 1 are as showing:
Table 1
As shown in Table 1, semi-crisp corundum fine grinding abrasive band of the present invention, its tensile strength has reached higher requirement.
The grinding life-span and the work piece surface accuracy of all size of the present invention are as shown in table 2:
Table 2
As shown in Table 2, the grinding life-span of the present invention is longer, and the surface to be machined precision is higher.
The specific embodiment
Embodiment one
Present embodiment is a kind of semi-crisp corundum fine grinding abrasive band, is made up of fabricbase, adhesive, removing material, and removing material is a semi-crisp corundum, and removing material is bonded on the fabricbase by adhesive, and adhesive is made up of following components in weight percentage:
Single order thermosetting phenolic resin 36%
Propane type epoxy resin of di phenolic group 4%
Melmac 1.8%
Boron 0.1%
SPAN-60 0.3%
Silane coupler 0.3%
Ethylene glycol ethyl ether 5%
Calcium carbonate 26%
Cryolite 26%
XeF2 0.5%。
During concrete preparation adhesive of the present invention, earlier the single order thermosetting phenolic resin of 36kg, the propane type epoxy resin of di phenolic group of 4kg, the melmac of 1.8kg are mixed into the modified synthetic resin of 41.8kg, after mixing, the XeF2 of cryolite, 0.5kg of calcium carbonate, 26kg of ethylene glycol ethyl ether, 26kg of silane coupler, 5kg of SPAN-60,0.3kg that adds boron, the 0.3kg of 0.1kg again mixed the back and crossed screen cloth, the adhesive of 100kg.With adhesive of the present invention semi-crisp corundum is bonded on the fabricbase, promptly makes semi-crisp corundum fine grinding abrasive band of the present invention.
Embodiment two
Present embodiment is a kind of semi-crisp corundum fine grinding abrasive band, is made up of fabricbase, adhesive, removing material, and removing material is a semi-crisp corundum, and removing material is bonded on the fabricbase by adhesive, and adhesive is made up of following components in weight percentage:
Single order thermosetting phenolic resin 39%
Propane type epoxy resin of di phenolic group 5%
Melmac 2%
Boron 0.3%
Tween-60 0.2%
Titanate coupling agent 0.1%
Methyl alcohol 4%
Calcium carbonate 24%
Sodium fluoborate 25%
XeF4 0.4%。
During concrete preparation adhesive of the present invention, earlier the single order thermosetting phenolic resin of 39kg, the propane type epoxy resin of di phenolic group of 5kg, the melmac of 2kg are mixed into the modified synthetic resin of 46kg, after mixing, the XeF4 of sodium fluoborate, 0.4kg of calcium carbonate, 25kg of methyl alcohol, 24kg of titanate coupling agent, 4kg of Tween-60,0.1kg that adds boron, the 0.2kg of 0.3kg again mixed the back and crossed screen cloth, the adhesive of 100kg.With adhesive of the present invention semi-crisp corundum is bonded on the fabricbase, promptly makes semi-crisp corundum fine grinding abrasive band of the present invention.
Embodiment three
Present embodiment is a kind of semi-crisp corundum fine grinding abrasive band, is made up of fabricbase, adhesive, removing material, and removing material is a semi-crisp corundum, and removing material is bonded on the fabricbase by adhesive, and adhesive is made up of following components in weight percentage:
Single order thermosetting phenolic resin 40%
Propane type epoxy resin of di phenolic group 4.5%
Melmac 2.6%
Boron 0.5%
Polyglycerol ester 0.1%
Aluminate coupling agent 0.2%
Ethanol 6%
Calcium carbonate 23%
Calcirm-fluoride 23%
XeF6 0.1%。
During concrete preparation adhesive of the present invention, earlier the single order thermosetting phenolic resin of 40kg, the propane type epoxy resin of di phenolic group of 4.5kg, the melmac of 2.6kg are mixed into the modified synthetic resin of 47.1kg, after mixing, the XeF6 that adds calcirm-fluoride, the 0.1kg of calcium carbonate, the 23kg of ethanol, the 23kg of aluminate coupling agent, the 6kg of polyglycerol ester, the 0.2kg of boron, the 0.1kg of 0.5kg again mixed the back and crossed screen cloth, the adhesive of 100kg.With adhesive of the present invention semi-crisp corundum is bonded on the fabricbase, promptly makes semi-crisp corundum fine grinding abrasive band of the present invention.
Embodiment four
Present embodiment is a kind of semi-crisp corundum fine grinding abrasive band, is made up of fabricbase, adhesive, removing material, and removing material is a semi-crisp corundum, and removing material is bonded on the fabricbase by adhesive, and adhesive is made up of following components in weight percentage:
Single order thermosetting phenolic resin 40%
Propane type epoxy resin of di phenolic group 5.5%
Melmac 2.8%
Boron 0.6%
SPAN-60 0.3%
Silane coupler 0.3%
Distilled water 6%
Calcium carbonate 18%
Sodium fluoride 26%
XeF2 0.5%。
During concrete preparation adhesive of the present invention, earlier the single order thermosetting phenolic resin of 40kg, the propane type epoxy resin of di phenolic group of 5.5kg, the melmac of 2.8kg are mixed into the modified synthetic resin of 48.3kg, after mixing, the XeF2 of sodium fluoride, 0.5kg of calcium carbonate, 26kg of distilled water, 18kg of silane coupler, 6kg of SPAN-60,0.3kg that adds boron, the 0.3kg of 0.6kg again mixed the back and crossed screen cloth, the adhesive of 100kg.With adhesive of the present invention semi-crisp corundum is bonded on the fabricbase, promptly makes semi-crisp corundum fine grinding abrasive band of the present invention.
The present invention can also have other embodiment, and the technical scheme that equal replacement of all employings or equivalent transformation form all drops within the scope of protection of present invention.