CN100394619C - Lignt emmitting device for phosphor conversion - Google Patents

Lignt emmitting device for phosphor conversion Download PDF

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Publication number
CN100394619C
CN100394619C CNB2004800028088A CN200480002808A CN100394619C CN 100394619 C CN100394619 C CN 100394619C CN B2004800028088 A CNB2004800028088 A CN B2004800028088A CN 200480002808 A CN200480002808 A CN 200480002808A CN 100394619 C CN100394619 C CN 100394619C
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fluorescent material
light
led
material layer
reflector
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CN1742386A (en
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迈克尔·F·韦伯
安德鲁·J·欧德科克
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42—Wire connectors; Manufacturing methods related thereto
    • H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805—Shape
    • H01L2224/4809—Loop shape
    • H01L2224/48091—Arched
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42—Wire connectors; Manufacturing methods related thereto
    • H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481—Disposition
    • H01L2224/48151—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48245—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
    • H01L2224/48247—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic connecting the wire to a bond pad of the item
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/10—Details of semiconductor or other solid state devices to be connected
    • H01L2924/11—Device type
    • H01L2924/12—Passive devices, e.g. 2 terminal devices
    • H01L2924/1204—Optical Diode
    • H01L2924/12041—LED
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
    • H01L2924/181—Encapsulation

Abstract

A light source including a layer of phosphor material, an LED capable of emitting light that excites the phosphor material, an interference reflector positioned to reflect at least some light emitted by the LED that has not passed through the phosphor material, onto the layer of phosphor material.

Description

The light emitting devices of fluorescent material conversion
Technical field
The present invention relates to light source.More particularly, the present invention relates to a kind of like this light source, wherein the illumination from light-emitting diode (LED) emission is mapped on the fluorescent material and excitation fluorescent material, this fluorescent material and then send visible light.
Technical discussion
Utilize the white light source of light-emitting diode (LED) that two kinds of basic structures can be arranged.In a kind of basic structure that is referred to as direct illuminated LED herein, the LED by different colours is the luminous white light that produces directly.Example comprises the combination of red LED, green LED and blue led, and the combination of blue led and yellow led.Be referred to as in this article in the another kind of basic structure based on the light source (PLED) of LED-excited fluorescence powder, the light beam of single led generation is in the narrower wave-length coverage, this light beam irradiates to fluorescent material and excitation fluorescent material produce visible light.This fluorescent material can comprise the mixture or the compound of different types of fluorescent material, and can comprise many narrow lines of departure that are distributed in whole visible wavelength range by the light that fluorescent material sends, make the light that is sent be white in color basically at the mankind's naked eyes.
The example of PLED is the blue led of irradiation fluorescent material, and described fluorescent material changes blueness into redness and green wavelength.The part blue excitation light can not absorbed by fluorescent material, and ruddiness and green glow that this part remaining blue excitation light and fluorescent material send mix.Another example of PLED is ultraviolet (UV) LED of irradiation fluorescent material, and described fluorescent material absorbs UV light and makes it change red, green and blue light into.
White light PLED is better than direct illuminated white LEDs part and is, it has better the color stability with ageing equipment degree and temperature correlation, and between the better different batches and the color consistency/repeatability between the distinct device.But, PLED can be efficient not as direct illuminated LED, and partly cause is fluorescent material absorbing light and the poor efficiency in the luminescence process again.
White light PLED can comprise that being arranged in reflective heat sink UV launches semiconductor chip (wafer).This reflective heat sink UV light that also can be used for partly calibrating.Described UV light shines the downside of the layer that contains fluorescent material, and this layer that contains fluorescent material absorbs at least a portion UV light and launches the light of a plurality of wavelength in the visible region, it seems the light source that is white in color substantially so that be provided at common beholder.Fig. 1 has shown a kind of structure of this PLED 10.This PLED comprises the semi-conductive LED 12 in the concave well that is installed in conduction heat sink 14, and this is heat sink also to reflections from phosphor particles device assembly 16 some light that send from LED 12 of reflection.This assembly 16 can be present in the optical clear encapsulating material 18, and this optical clear encapsulating material can be made with the shape of lens-shape 20 to adjust the light that is sent by PLED 10.In Fig. 2, show out fluorescent material assembly 16 in greater detail.With adhesive one or more fluorescent materials are mixed and make fluorescent material cambium layer 22.Logical (LP) reflector 24 of the length of reflection UV exciting light and transmission visible radiation can be placed on the upper surface of fluorescence coating 22.Logical (SP) reflector 26 of the weak point of reflect visible light and transmission UV light can be placed on the bottom of layer 22.
For given fluorescent material concentration, the optimum thickness of fluorescence coating is effectively to absorb trading off between UV light (tending to optic thick fluorescence coating) and the effective visible emitting (tending to optic thin fluorescence coating).In addition, because the UV light intensity is in the bottom of fluorescence coating 22 maximum, and using light separates from the top of fluorescence coating 22, so the thickness of fluorescence coating 22 increases to the output and the efficient that will reduce whole PLED above optimum thickness rapidly.
The existence of LP reflector 24 and SP reflector 26 can improve the efficient of PLED 10.LP reflector 24 is the UV light reflected back fluorescence coating 22 that is not absorbed by fluorescence coating 22 and may be wasted.This has increased the effective path length that sees through the UV light of fluorescence coating, has improved the amount of the UV light that is absorbed by fluorescent material for given fluorescence coating thickness.Therefore compare with the structure that does not have LP reflector 24, can reduce best fluorescence coating thickness, improve luminous efficiency.
Among the PLED another significantly loss is that half is led and gets back to LED in the visible light that causes sending in the fluorescence coating 22 owing to direction in the fluorescence coating is uncontrolled luminous.Part in these light can be left heat sink skew wall by reflection and be hunted down, but the major part in these light is scattered, absorption or quality reduce.As shown in the figure, by being placed between LED 12 and the fluorescence coating 22, SP reflector 26 can reduce this loss.
The efficient that further improves the PLED structure is very favourable.It also is very favourable simplifying the manufacturing of PLED and reducing manufacturing cost.
Brief summary of the invention
The present invention discloses the PLED that utilizes the polymer multi-layer blooming at filter element (being LP and SP reflector).These multi-layer optical films comprise independent optical layers, and at least wherein some can be birefringent, is arranged in optical repeat unit at film thickness direction.Adjacent optical layers has such index of refraction relationship, promptly keep reflectivity and avoid in the p-polarised light of high incidence angle leak.The SP reflector comprises the optical repeat unit with thickness gradient, and described thickness gradient produces and can reflect the visible light that sent by fluorescent material and the reflected waveband of transmission UV exciting light.The LP reflector comprises the optical repeat unit with different-thickness gradient, and described thickness gradient produces the reflected waveband that can reflect the visible light that UV exciting light and transmission sent by fluorescent material.As the part of PLED, one or more polymer multi-layer bloomings can be planar structure or at least one film can be molded processing or be made into curved surface, no matter be that sphere, parabola, ellipsoid or other shapes can.
Also disclosed the method for making PLED, these methods comprise that formation has the sheeting of at least one polymer multi-layer blooming and fluorescence coating.Can be clipped between two polymer multi-layer bloomings (is the SP reflector, and another is the LP reflector) at fluorescent material in some cases.Fluorescence coating can only be arranged on the polymer multi-layer blooming in other cases.One or more polymer multi-layer bloomings and fluorescence coating form fluorescence coating-reflector assembly.Each that described sheeting can be cut into fluorescence coating-reflector assembly be small pieces independently, subsequently these small pieces are put into transparent encapsulation material or are injection molded as first optical element, and then with separate the LED combination of elements of making.Sheeting can comprise support membrane, so that the small pieces that keep and store fluorescent material-reflector assembly with roll form easily use until needs.Can make PLED by the lower part that contains LED is coupled together with the upper part that contains fluorescent material-reflector group.Also can carry out mold pressing processing in some cases to described sheeting.
This specification has disclosed the embodiment of PLED, its mean camber LP reflector and fluorescence coating are placed apart, or placed apart with the middle light of this fluorescence coating at least, thereby make not any UV exciting light of being absorbed by fluorescence coating with limited ranges of incidence angles irradiation LP reflector and reflected back fluorescence coating more effectively.
The application has disclosed the PLED embodiment that the approaching air gap of utilization and multi-layer optical film and fluorescence coating promotes total internal reflection.
The application has disclosed the PLED embodiment that utilizes non-imaging convergent component to make up the performance that improves LP and/or SP reflector.
The application has also disclosed another embodiment of PLED, and the arranged of LED, LP reflector and fluorescence coating wherein makes exciting light from LED directly reflex to before the fluorescence coating on the first type surface.
Following detailed description will further be illustrated above-mentioned these aspects and other aspects of disclosed embodiment.But, in no case should be interpreted as restriction to theme required for protection to above summary, this theme is only determined by appended claim, may be made amendment to claim in application process.
Description of drawings
Reference for accompanying drawing runs through specification in full, and wherein identical Reference numeral is represented components identical, wherein:
Fig. 1 is based on the schematic sectional view of the light source (PLED) that is subjected to LED excited fluorescent powder;
Fig. 2 is the sectional view of fluorescent material-reflector assembly of using in light source shown in Figure 1;
Fig. 3 represents to contain and is sheet form and is subdivided into each independently scroll of the fluorescent material-reflector assembly of small pieces;
Fig. 4 is each schematic sectional view of small pieces independently that shows the fluorescent material-reflector assembly be positioned on the support membrane;
Fig. 5-the 7th, the schematic sectional view of optional PLED structure;
Fig. 8 represents the part of another kind of PLED structure;
Fig. 9 is the schematic sectional view of another kind of PLED structure;
Figure 10 is the schematic side elevation of another kind of PLED structure, and wherein the embodiment with Fig. 9 is the same, has utilized the front surface irradiation.
Figure 11 is the schematic side elevation that is provided with the another kind of PLED structure of non-imaging convergent component;
Figure 12 is the close up view of the part of Figure 11;
Figure 13 is the schematic sectional view of another embodiment of PLED structure;
Figure 14 is a schematic top view embodiment illustrated in fig. 13;
Figure 15 is the schematic sectional view of another embodiment of PLED structure;
Figure 16 is the luminous intensity of example 1 and example 2 line chart of setting a song to music;
Figure 17 is the luminous intensity of example 3, example 4 and example 5 line chart of setting a song to music;
Figure 18 is the luminous intensity of example 6, example 7 and example 8 line chart of setting a song to music; And
Figure 19 is the luminous intensity of example 9 and example 10 line chart of setting a song to music.
Embodiment
Although use one of LP reflector 24 and SP reflector 26 both or both can improve system effectiveness shown in Fig. 1-2, because the spectral selection difference of some reflectors and low at the reflectivity of oblique incidence angle, this raising is limited.LP speculum or filter based on scattering process can obtain the metastable performance relevant with incidence angle, but spectral selection is low.Piling up the LP and the SP speculum that constitute by Inorganic Dielectric Material can have good spectral selection in narrow ranges of incidence angles, but exist take place along with incidence angle the spectrum blue shift and in the problem of the reflectivity low (transmissivity height) of p-polarised light on the high incident angle.Because phosphor particles scattering UV exciting light, and in wide angular range their light of emission, so traditional LP and SP speculum can not be efficiently photocontrol in fluorescent material-reflector assembly.
The performance of PLED can improve by using the polymer multi-layer blooming, this multi-layer optical film has tens of, hundreds of or thousands of alternately overlapped layers of at least the first and second polymeric materials, the thickness of described first and second polymeric materials and refractive index are selected obtaining the ideal reflectivity in required spectral region, be defined as the UV wavelength or reflected waveband is defined as visible wavelength such as reflected waveband.For example, referring to U.S. Patent No. 5882774 (Jonza etc.).Similar with the relevant blue shift that produces by inorganic isotropic material laminated construction, blue shift also takes place in the reflected waveband that these films produce along with the increase of incidence angle, but can handle the polymer multi-layer blooming like this, make a pair of adjacent layer on the z axle, have coupling or approaching coupling or have a mind to unmatched refractive index in membrane process, thereby each interface between adjacent layer is reduced lentamente along with incidence angle to the reflectivity of p-polarised light, perhaps irrelevant with incidence angle basically, perhaps depart from normal direction and increase along with incidence angle.Therefore, even this polymer multi-layer blooming also can keep high reflectance for the p-polarised light on the incident angle of high inclination, pile up reflector with traditional inorganic isotropism and compare the p-polarised light that has reduced the penetration film.In order to obtain these characteristics, selective polymer material and process conditions, make each be not more than along the mark of the refringence of x or y (in the plane) axle the refringence of adjacent optical layers along z axle (being parallel to thickness), this mark is 0.5,0.25 or even 0.1.In addition, along the axial refringence of z can also with the opposite in sign of refringence in the plane.
Use the polymer multi-layer blooming also to make various novel PLED embodiment and building method become possibility, because these films have pliability and formability, no matter whether they also have above-mentioned index of refraction relationship.For example, shaping can be processed, heat to the polymer multi-layer blooming by mold pressing or other known methods for good and all are deformed into 3D shape, such as the part of parabola, sphere or ellipsoid.See also the common US2002/0154406 (Merrill etc.) that openly applies for.About the embodiment of other polymer multi-layer films, also see also U.S. Patent No. 5540978 (Schrenk).Connect one deck ground evaporation to the frangible substrate of rigidity and the traditional inorganic isotropism stacked structure that forms is different with common one deck, the polymer multi-layer blooming can be made into the scroll of large volume, also can be laminated on other films and coated with coating, and can be stamped or be subdivided into small pieces so as to join optical system such as PLED in, as hereinafter will further specifying.The sequence number that the method for segmentation polymer multi-layer blooming was submitted on October 10th, 2002 is No.10/268, has disclosed in 118 the U. S. application that awaits the reply.
The multiple polymers material all is suitable for being used in the multi-layer optical film at PLED.But, particularly in the PLED that contains the white emitting fluorescent powder reflector that combines with UV LED excitaton source, multi-layer optical film preferably comprises the overlapping polymeric layer that is made of the material that is exposed to UV light energy of following time degeneration.About this respect, especially preferred polymer is to being polyethylene terephthalate (PET)/copolymerization methyl methacrylate (co-PMMA).The UV stability of polymer reflectors also can improve by adding non-UV absorbability light stabilizer such as hindered amine as light stabilizer (HALS).Can also comprise transparent metal or metal oxide layer at polymer multi-layer blooming in some cases.Referring to the open WO97/01778 (Ouderkirk etc.) of for example PCT.Very high strength UV light even can make hard polymeric material composite that unacceptable degeneration takes place, in the application of using this very high strength UV light, it may be useful using inorganic material to form the multiple-level stack structure.This inorganic material layer can be isotropic, perhaps can be made with birefringence, as described in the open WO01/75490 (Weber) of PCT, thereby has the aforesaid useful index of refraction relationship that can produce the p-polarised light reflectivity that strengthens.But, under most of situation multi-layer optical film to make without inorganic material with polymer fully basically be the most convenient cost of also saving most.
Fig. 3 represents the volume that sheeting 30 forms, and this material comprises at least one polymer multi-layer blooming and is coated in basic fluorescence coating uniformly on this multi-layer optical film.Sheeting also can comprise the second polymer multi-layer blooming that applies in the following manner thereon, that is, fluorescence coating is clipped between the first and second polymer multi-layer bloomings, as shown in Figure 2.Can also comprise additional layer and coating that desirable machinery, chemistry and/or optical characteristics are provided.Referring to U.S. Patent No. 6,368,699 (Gilbert etc.).Sheeting 30 also preferably includes support membrane.Sheeting by mechanical means (for example, cutter), accurate punching or by as the above-mentioned application No.10/268 that awaits the reply, 118 described scan laser rays come the flanging cutting.The flanging the line of cut defines small pieces discrete on the sheeting 32, but support membrane is kept perfectly.Small pieces 32 can have the cross-sectional structure that is similar to as shown in Figure 2, and can be arbitrarily small sizes.They are being supported easily by the support membrane as shown in Figure 4 34 that is positioned under it.In the manufacture process (this process is independent of the construction process of led light source) of PLED, small pieces 32 can be removed and are placed on each independent mould from support membrane, and will add or add in advance encapsulating material in this mould, so that form PLED as shown in Figure 1, but wherein reflector element uses the polymer multi-layer blooming.
Fig. 5-7 expression utilizes the optional structure of the PLED of spill multi-layer optical film LP reflector.LP reflector and fluorescent material branch are arranged and make it bend towards fluorescent material and LED 12 helps to reduce to be radiated at the incidence angle of the exciting light on the LP reflector, leak thereby reduce the UV light that sees through the LP reflector that above-mentioned hypsochromic effect causes.Putting into before the transparent medium 18, preferably multi-layer optical film for good and all is being deformed into the concave surface of suitable shape by mold pressing processing or other suitable technologies.Multi-layer optical film, no matter LP or SP are their specular reflectors in the reflected waveband separately.Usually ignore from the diffuse reflection of multi-layer optical film.
Among Fig. 5, PLED 40 comprises the fluorescence coating 42 than small size, on the SP reflector 44 that this fluorescence coating is arranged on is dispensable, be made up of the polymer multi-layer blooming.LP reflector 46 has been molded and has been processed into spill and is arranged near other elements (42,44) of fluorescent material-reflector assembly.LED 12 and heat sink 14 is arranged to make the mid portion of the UV exciting light guiding fluorescence coating 42 that LED sends.Preferably, UV light has the greatest impact near the middle part of fluorescence coating 42 or its.When it passes fluorescence coating 42 for the first time, do not have absorbed UV light before by LP46 reflected back fluorescence coating earlier by the zone 48 between LP reflector 46 and the fluorescence coating 42.This zone 48 can be made of transparent encapsulation material 18, or alternatively by other polymeric materials or air (or other gases) or glass formation.Preferably LP reflector 46 is made certain shape, so that the UV of reflected back fluorescent material excites the light quantity maximization.
Fig. 6 representation class is similar to the PLED 50 of PLED 40, but the size of fluorescence coating 52, SP reflector 54 and LP reflector 56 has increased among the PLED 50.For giving set a distance and identical heat sink 14 geometry from LED 12 to fluorescence coating, LP reflector 56 is big more, and light is just high more in the convergence degree at fluorescence coating middle part.The more little representative in luminous zone of fluorescence coating central authorities is more little to the ranges of incidence angles of LP reflector surface from the light that fluorescent material sends, thereby has improved the efficient of whole PLED.As previously mentioned, zone 58 can be by encapsulating material 18 or other polymeric materials or air (or other gases) or glass formation.
As shown in Figure 7, PLED 60 is similar to PLED 50, but LP reflector 66 also becomes the outer surface of light source among the PLED 60.Encapsulating material 18 or other transparent mediums can be filled in zone 68.
Fluorescence coating shown in Fig. 5-7 can be continuous, perhaps is made into fluorescent material is limited to the pattern of effective coverage.In addition, shown in Fig. 1 and Fig. 5-7 and among other embodiment, fluorescent material-reflector assembly is arranged on the LED top and is arranged with the LED branch, thereby PLED can make by separated into two parts: a part comprises and has heat sink LED, and another part comprises fluorescence coating and mattress reflector.These two parts can be made respectively, connect then or tighten together.This manufacturing technology helps to simplify processing and increase the total yield.
Fig. 8 has showed the design that can be applied to valuably among other embodiment as herein described: between LED and fluorescence coating air gap is set, and/or near one or more elements of fluorescence coating-reflector assembly air gap is set.For the purpose of simplified illustration, only show some elements of PLED in the drawings.Show among the figure that air gap 70 is between LED 12 and fluorescence coating 72, and is contiguous with multi-layer optical film SP reflector 74.This air gap is minimum for the adverse effect of the UV light that arrives fluorescence coating from LED, because UV light is less relatively from the angle that LED arrives fluorescence coating.But for light with the transmission of big incidence angle, the light that in SP reflector, fluorescence coating and LP reflector, transmits for example, this air gap can make light experiences total internal reflection (TIR).The efficient of SP reflector improves by the TIR that reflector 74 is produced on lower surface in the embodiment shown in fig. 8.Alternatively, can remove SP reflector 74 and below fluorescence coating 72, directly form air gap.This air gap can also form above fluorescence coating 72, or the upper surface of contiguous LP reflector or lower surface formation.A kind of method that air gap is provided relates to the use of known microstructure film.This class film has the basically flat surface staggered relatively with micro-structure surface.This micro-structure surface is characterised in that: single one group of linear V-shaped groove or prism, constitute a plurality of crossing group of the V-shaped groove of miniature cone array, and one or more groups narrow ridge, or the like.When the micro-structure surface of this film when another flat film is placed, between the highest part of micro-structure surface, form air gap.
When changing the light of a wavelength (excitation wavelength) into other wavelength (emission wavelength), fluorescent material can generate heat.Near fluorescent material air gap can significantly reduce the heat conduction from fluorescent material to the material around.The heat conduction that reduces can compensate by other modes, such as by the laterally glassy layer or the transparent ceramic layer of heat extraction are set near fluorescence coating.
The another kind of method that improves the efficient of PLED is that LED, fluorescence coating and LP reflector are set, so that at least a portion directly reflexes on top (visual) face of fluorescence coating by the LP reflector from the UV light of LED, rather than all UV light all is directed on the bottom surface of fluorescence coating.Fig. 9 has represented this PLED 80.Heat sink 14 ' relative the foregoing description has carried out revising so that LED 12 and fluorescence coating 82 are installed on coplane ground substantially.The SP reflector is shown as below fluorescence coating, but does not need so in many cases.This is that this surface is in the face of the front of PLED 80 because the LP reflector 86 that is processed into recessed oval shape or analogous shape that is molded directly is directed to the UV exciting light on the upper surface of fluorescence coating 82 from LED.LED and fluorescence coating preferably are arranged on the described ellipsoidal focus.The visible light that fluorescence coating sends is assembled the form or visible (preferably white) light of wishing to form by 86 transmissions of LP reflector and by the circular front end of PLED body.
The front surface that exciting light directly is directed at fluorescence coating has a lot of benefits.The part that fluorescence coating is the brightest--here exciting light is the strongest--can be exposed to now device the front and can be not smudgy because of the thickness that passes fluorescence coating.Fluorescence coating can make thicker so that absorb all basically UV exciting lights basically, and need not to consider the compromise of above mentioned thickness/brightness.Fluorescent material can be arranged on the metallic mirror of broadband, and this metallic mirror comprises silver or reinforced aluminum.
Figure 10 schematically shows another PLED embodiment, the front surface of LED rayed fluorescence coating wherein, but some of them LED light also shines the rear surface.In this embodiment, a part of rayed that LED12 sends is on the rear surface of fluorescence coating 92, but the light of some LED does not see through fluorescence coating from 96 reflections of spill LP reflector with the front surface of irradiation fluorescence coating 92 yet.Then, the object penetration that maybe will throw light on towards the beholder of the visible light that sends of fluorescence coating 92 is crossed LP reflector 96.LED, fluorescence coating and LP reflector can insert or be connected in as in the previous examples the transparent encapsulation material medium.
Figure 11 schematically shows another PLED embodiment, wherein is provided with non-imaging convergent component combination so that improve the operating characteristics of multi-layer optical film.Specifically, as shown in the drawingly between LED 12, SP reflector 104, fluorescence coating 102 and LP reflector 106, be provided with convergent component 100a, 100b, 100c.Thereby this convergent component has the effect that the angle that shines the light on the mattress reflector is distributed reduce the blue shift that reduces above-mentioned reflected waveband, and described blue shift was above being described in conjunction with Fig. 5-7.This convergent component can be the form with simple cone of flat sidewall, and perhaps sidewall can have the known more complicated curve form that can strengthen collimation or focussing force according to the transmission direction of light.Under any circumstance the sidewall of convergent component is reflective, and two ends (end is little, and an end is big) then is not.In Figure 11, LED 12 is arranged on the small end of convergent component 100a.Convergent component 100a collects the light of the wide range of being sent by LED, and this scope can be dwindled when light propagates into the big end of convergent component 100a, at this big end place SP reflector 104 is installed.The UV exciting light sees through the SP reflector and arrives convergent component 100b, and this convergent component (distributes) optical convergence though increased the angle of light to fluorescence coating 102.The visible light of the wide range that fluorescence coating 102 sends is downwards changed into narrow angular range by convergent component 100b on SP reflector 104, on this SP reflector 104 by reflected back fluorescence coating 102 upwards.Therebetween, the UV light that sees through fluorescence coating 102 and leak and by fluorescence coating 102 upwards visible light emitted have wide angle at first and distribute, but being changed into less angle by convergent component 100c distributes, as a result, LP reflector 106 makes by the fluorescent material visible light emitted and sees through better and with UV light reflected back fluorescence coating.
For catching the LED exciting light as much as possible, the small end of convergent component 100a can have depression so that catch the light that some are sent by the LED side at least, as shown in figure 12.
The embodiment of Pi Luing can use various fluorescent materials herein.Fluorescent material is the combination of inorganic constituents normally, has excitation wavelength and the interior wavelength of transmitted light of visible wavelength range in the 300-450 nanometer range.Have at fluorescent material under the situation of narrow emission wavelength ranges, can prepare the fluorescent material mixture, so that obtain the color balance of the hope that the beholder felt, for example the preparation glows, the mixture of the fluorescent material of green glow and blue light.Fluorescent material with the luminous wave band of broad for the phosphor mixture that obtains to have higher relatively color rendering rate of great use.Ideally, fluorescent material should have attenuation speed fast.Phosphor mixture can comprise and (for example is dispersed in adhesive, epoxy resin, adhesive, polysiloxanes, fluorocarbon or polymeric matrix) in 1-25 micron magnitude range in phosphor particles, and described adhesive can be coated in substrate for example on LED or the film.Being transformed into the light in about 300 to 470nm scopes more, the fluorescent material of long wavelength's light is commonly known in the art.For example, the fluorescent material series that provides referring to fluorescent material technology Co., Ltd (Phosphor Technology Ltd.) by Essex, Britain.Fluorescent material comprises garnet, silicate and other ceramic materials of the rare earth that mixed.Term used herein " fluorescent material " can also comprise organic fluorescence materials, comprises fluorescent dye and pigment.The material, the especially inorganic fluorescent powder that preferably under the radiation of 300-470nm, have high stability.
The part nomenclature
LED: no matter light-emitting diode is visible light, ultraviolet light or infrared light, and no matter coherent light or incoherent light.Term used herein comprises the semiconductor device as " LED " commercially available irrelevant (and usually cheap) epoxy encapsulation, no matter is traditional or the superradiance type.This term used herein also comprises semiconductor laser diode.
Visible light: the light that can be discovered by human eye is general in about wave-length coverage of 400 to 700nm.
Optical repeat unit (" ORU "): the stacked structure that at least two independent stratums that repeat at the thickness direction of vertical multi-layer optical film form, and corresponding repeat layer does not need identical thickness.
Optical thickness: the physical thickness of given main body multiply by its refractive index.Generally speaking, this is the function of wavelength and polarization state.
Reflected waveband: the SPECTRAL REGION of high reflectance, its both sides are lower reflectivity regions.
Ultraviolet light (UV): wavelength is at about 300 light to about 400nm scope.
White light: stimulate redness, green and the blue sensor in the human eye and make general viewers can feel to present the light of " white ".This light can be partially red (typically referring to warm white) or blueness (typically referring to cold white light) partially.This light can have 100 the color rendering rate that reaches.
Further discuss
Described herein interference reflector comprises the reflector that the compound by organic material, inorganic material or organic and inorganic material forms.Term used herein " interference reflector " and " interference filter " can exchange.Thereby interference reflector comprises any reflector that has a plurality of thin layers or have the structure of the reflection characteristic that other long mutually or destructive interferences that can produce light influence reflector.Interference reflector can be the multi-coated interference reflector.Interference reflector can be flexible interference reflector.Flexible interference reflector can be made of polymeric material, non-cohesive material or polymerization and non-cohesive material.Exemplary film comprises U.S. Patent No. 6,010,751 and No.6,172,810 and EP733, and polymerization that 919A2 is disclosed and non-cohesive material.
Described herein interference reflector can be made of flexibility, plasticity or deformable material, self can be flexible, plasticity or deformable.These interference reflectors can bend to has the radius that can use with traditional LED, that is, radius is to 5mm from 0.5.These flexible interference reflectors can crookedly also still keep its crooked preceding optical characteristics.
Can consider to use known self assembly periodic structure (such as, cholesteric reflective polarizer and some block copolymer) to make the multilayer optical interferometer that is used for this application purpose.The cholesteric speculum can utilize the combination of left and right chirality pitch composition to make.
In illustrative embodiment, part sees through the long pass filter of all blue light wavelengths can unite use with thin yellow fluorescence layer, so that the part blue light that LED is sent is led again after seeing through fluorescent material is for the first time getting back on the fluorescence coating.
Except reflection UV light, a function of multi-layer optical film is to stop the UV optical transmission, thereby prevents in the LED assembly or the degeneration of the subsequent element outside the LED assembly, comprises preventing to injure human eye.In certain embodiments, adding that away from the side of LED the UV absorber may be favourable from the UV reflector.This UV absorber can be positioned at the inside of multi-layer optical film, top or next door.
Although various method known in the state of the art is made interference filter, the all-polymer structure can provide a lot of benefits of manufacturing and cost aspect.If in interference filter, use optical transmission height and the big high temperature polymer of refringence, so just can produce not only thin not only very pliable and tough but also anti-all-environment filter, lead to the optics needs of (LP) filter to meet short logical (SP) and length.Specifically, US6, the coextruded multilayer interference filter of 531,230 (Weber etc.) instruction can provide accurate wavelength to select, and can carry out the manufacturing of large-area economy.It is right that use has the polymer of big refringence, can make free-standing speculum very thin but that reflectivity is high, promptly do not have the speculum of substrate, and this speculum also is easy to processing.Even heating is shaped or bends to when having little radius of curvature to 1mm, this interference structure can not break yet, broken or degenerate.
The all-polymer filter can heat and is configured as various 3D shapes such as hemispherical dome (as described below).But, carefully the process of control attenuation makes the amount on whole dome surface reach an appropriate level, so that produce the angular characteristics of wishing.Filter with simple two-dimensional curve shape is than the easier manufacturing of the filter of 3 D complex shape.Especially, any thin and flexible filter can bend to the such two-dimensional shapes of a for example cylindrical part, does not need the all-polymer filter in this case.Can make certain shape to the inorganic filter of multilayer on thin polymeric substrates in this way, also can be making certain shape less than the inorganic multilayer on 200 microns the substrate of glass at thickness.The latter may must be heated near glass transition temperature to obtain the permanent deformation of low stress.
The best band border of long logical and short bandpass filter can determine that design has filter to work therein in the described system according to the emission spectrum of LED in the system and fluorescent material.In illustrative embodiment, for short bandpass filter, all basically LED radiation see through filter with excitated fluorescent powder, and the filtered device reflection of all basically fluorescent material radiation, thereby they do not enter LED or its underlying structure, and they may be absorbed at this underlying structure place.Therefore, short logical determined wave band border is located between the average radiation wavelength of the average radiation wavelength of LED and fluorescent material.In illustrative embodiment, filter is between LED and fluorescent material.But, if filter is the plane, the radiant light that sends from common LED will shine filter in various angles so, and filtered device reflection also can't arrive fluorescent material in the time of on some incidence angle.Unless filter bends to the almost constant incidence angle of maintenance, people may wish the wave band border of above-mentioned expectation is arranged to greater than the mid point of fluorescent material and LED radiation curve to optimize the performance of whole system.Especially, almost there is not fluorescent material radiation meeting on incidence angle, to be directed on the filter, because included solid angle is very little near zero degree.
In another illustrative embodiment, LED is placed on the fluorescence coating opposite improves system effectiveness so that the LED exciting light comes back on the fluorescent material thereby long logical reflecting filter leaves.In another illustrative embodiment, by seeing through the spectrum angular displacement of more blue lights on greater than the angle of normal incidence, the permeation parts short wavelength light for example long pass filter of blue light can be used to optimize the angular properties of blueness-LED/ yellow-fluorescent material system.Long pass reflector can be designed on all incident angles the effectively light of transmission fluorescent material emission, and perhaps it can be designed to the difference of incidence angle the desirable output of exciting light to obtain to change with angle after the reflection conversion by different way.Long logical speculum can be configured to the primary light or the exciting light of any polarization state of transmission comparably, and perhaps it can be such as the partial polarization device at the reflection type polarizer of exciting light or primary light or any structure between them.Final result is the original light of a transmission part.Long logical reflection multilayer formula polarizer is known in the prior art, and is as described herein.Some examples are that plurality of layers of double refraction polymer is interfered filter and cholesteric reflection type polarizer.
In another illustrative embodiment, the LP filter is bent, so that the incidence angle that makes LED be transmitted into the light on the filter keeps near constant.In this embodiment, fluorescent material and LED both are towards a side of LP filter.On big incidence angle, the LP filter can not reflect short wavelength light.Therefore, the long wave band border of LP filter can be set in long as far as possible wavelength and stop the fluorescent material radiation as few as possible.In addition, can change the setting on wave band border to optimize whole system efficient.
Defined herein term " vicinity " or " near " be meant the relative position relation between two close objects.Contiguous object can be in contact with one another, or isolates mutually by one or more materials being placed between the adjacent objects.
The LED exciting light can be any light that led light source can send.The LED exciting light can be UV or blue light.Blue light also can comprise purple light and indigo light.LED comprises spontaneous emission device and that be used to excite or superradiance ballistic device, comprises the laser diode of laser diode and vertical cavity surface emitting.
Described herein fluorescence coating can be continuous or discontinuity layer.Fluorescent material layer can be even or inhomogeneous form.Fluorescent material layer can be a plurality of zones with little cross-sectional area, for example has less than 10000 microns 2Or from 500 to 10000 microns 2A plurality of " points " of overlooking area.In illustrative embodiment, each in a plurality of points can be formed by the fluorescent material of the visible light of launching one or more different wave lengths, for example, and the point that glows, the point of blue light-emitting and the point of green light.Can arrange and construct the point of the visible light of a plurality of wavelength of emission in any even or inhomogeneous mode of wanting.For example, a plurality of points that fluorescent material layer can be along the surface or the zone has the nonhomogeneous density gradient.Described " point " can be any regular or irregularly shaped, need not on vertical view rounded.Fluorescent material can be in the co-extrusion pressure superficial layer of multi-layer optical film.
As described below, structurized fluorescence coating can be constructed in several ways, so that the benefit of aspect of performance to be provided.Export when the spectrum that multiple fluorescent material type is used to provide wideer or more complete, can be reuptaked by other fluorescent material from the light of shortwave fluorescent material so.Comprise that the isolated point, line of each fluorescent material type or the form in isolated zone have reduced the light quantity of reuptaking.This is effective especially for the cavity type structure, and non-absorption-type pump light is reflected back toward fluorescent material in these structures.
The multilayer phosphor structure also can reduce absorption.For example, like this can be more favourable, promptly by each fluorescent material cambium layer in order, and the longest the most close excitation source of wavelength transmitter.The light that more close reflector sends, on average the multiple scattering degree that in whole fluorescence coating, is experienced can than close output surface send wide.Because the minimal wave length of being launched is tended to scattering most, therefore advantageously that wavelength is the shortest fluorescent material is placed on the position of close output surface.In addition, advantageously different to each layer usefulness thickness compensates the intensity that it reduces gradually when propagating by sandwich construction with convenient exciting light.Also advantageously short bandpass filter is placed between the different fluorescence coatings in addition, reduces the scattering backward of the fluorescence that is sent and reduce it and reuptaked by the forward fluorescence coating in position.
Forming technology with membrane structure of fluoresent coating also can be used for making the minor structure array that is suitable for cutting into the separate unit that is used for diode.For example, can impress out little dome or hemisphere array, wherein each can be used for reducing " halo effect " (as described below) that occurs sometimes among the PLED.
Non-scattering fluorescence coating combines with multi-layer optical film and can improve light output.The adhesive that non-scattering fluorescence coating can contain the adhesive that mates substantially in refractive index or refractive index approximate match (for example, the particle of the conventional fluorescent powder the adhesive with inertia nano particle of high index of refraction), the nanometer size of conventional fluorescent composition (for example, wherein the size of particle is very little and can ignore scattering of light), or by using the quantum dot fluorescent powder.The quantum dot fluorescence powder is based on for example optical transmitting set of cadmium sulfide of semiconductor, and particle wherein is enough little so that electronic structure is subjected to the influence and the control of particle size.Therefore, absorption and emission spectrum are controlled by particle size.Quantum dot is in U.S. Patent No. 6,501, has in 091 disclosed.
Among the embodiment of Pi Luing, first optical element that comprises fluorescent material/reflector assembly can be connected in the LED substrate afterwards herein; Heat sinkly can randomly comprise transparent heat sink, fluorescence coating and interference filter can be connected on this transparent heat sink.Transparent heat sink can be the sapphire layer that is placed between fluorescence coating/interference filter and the LED substrate.The thermal conductivity of most of glass also can be used as this function than polymerization object height.The thermal conductivity of many other crystalline materials is higher than most of glass, also can be with in the present invention.Sapphire layer can contact in the marginal portion with metal heat sink.
In illustrative embodiment, before, can improve the processing of coating viscosity to the surface of filter at coating interference filter (that is the polymer interference filter that, has fluorescence coating).Best processing is according to the top layer of filter and especially be used for making phosphor particles to remain on lip-deep adhesive according to the material in the fluoresent coating determining.Surface treatment can be the Corona discharge Treatment of standard, perhaps brushes priming coat behind corona discharge subsequently again.Priming coat is usually less than 1 micron thickness.Useful priming coat material be PVDC, sulfonated polyester and other amorphous polyesters such as Vitel, maleic copolymer is such as Bynel (Du Pont (Dupont)) and Admer (Mitsui Chemicals (Mitsui Chemicals)), and EVA is such as Elvax (Du Pont).The adhesive that is used for fluorescence coating can be thermoplastic and/or can add thermal deformation, and can be fluoropolymer for example, or silica-base material.
Other optional priming coats comprise, for example, vacuum coating, preferably from high-energy source such as ion beam or plasma (orifice) gas body source, its intermediate ion or plasma composition bombardment polymer surfaces be deposition of primer layer simultaneously.This priming coat normally inorganic material layer such as titanium dioxide or silicon dioxide layer.
Be converted to visible light although paid close attention to fluorescent material is used to make under the short wavelength light morely, also may make and be converted to visible light on the infrared radiation.The fluorescent material of last conversion is known in the prior art, and produces an optical photon with two or more infrared photons usually.Be used for that the infrared LED of these fluorescent material of pumping has been verified and very effective.Use the visible light source of this technology to become more effective by adding long wave (LP) and shortwave (SP) filter, although in this case the function of each filter with in the fluorescent material system of down conversion, compare just in time opposite.The SP filter can be used to an IR photoconduction to fluorescent material, makes visible light transmissive simultaneously, and the LP filter can be placed between fluorescent material and the LED so that a visible light that sends outwards lead reservation system or user.
The life-span of SP or LP filter is preferably more than or equals the life-span of the LED in the same system.Polymer interferes the degeneration of filter to be owing to overheatedly cause material generation creep, and this can change the layer thickness value, thereby changes the wavelength of filter reflection.In the worst case, overheated meeting makes polymeric material fusing, causes material to flow rapidly and change wavelength selecting and causing filter inhomogeneous.
The degeneration of polymeric material also may depend on self material by shortwave (photochemical) radiation such as due to blue, purple or the UV radiation respectively.The speed of degenerating had not only depended on the actinic light flux but also had depended on the temperature of polymer.Temperature and luminous flux generally all can reduce along with the increase of the distance of leaving LED.Thereby under the situation of high-brightness LED, especially ultraviolet LED, advantageously the polymer filter is placed away from LED in the scope that designing institute can allow as far as possible.The polymer filter is placed on the aforesaid transparent heat sink also can improves the filter life-span.For the dome filter, the actinic radiation flux according to the distance of leaving LED square and reduce.For example, be provided with 1 watt of unidirectional LED at the center of its sweep and be provided with the hemisphere MOF reflector that radius is 1cm, mean flow rate is 1/ (2 π) W/cm 2(dome surface area=2 π cm 2).For the radius of 0.5cm, the mean flow rate on the dome is four times of this value, i.e. 2 π W/cm 2Can consider luminous flux and temperature control when design LED, fluorescent material and multi-layer optical film system.
Reflection type polarizer can be adjacent to mattress reflector and/or be adjacent to phosphor material powder and place.Reflection type polarizer sends preferred polarised light and reflects other polarised lights.Fluorescence coating well known in the prior art and other thin film compositions can make the polarised light depolarization by the reflection type polarizer reflection, and by from the reflection of fluorescence coating or by the reflection from the fluorescence coating that combines with mattress reflector, light can be recycling and the polarised light brightness that increases solid-state light device (LED).Suitable reflection type polarizer comprises, for example, and cholesteric reflection type polarizer, cholesteric reflection type polarizer, the DBEF reflection type polarizer that can obtain from 3M company or the DRPF reflection type polarizer that can obtain from 3M company equally with 1/4 wavelength retarder.Preferred reflection type polarizer makes the auroral polesization by the fluorescent material emission in big wavelength and angular range, and under the situation of LED emission blue light, the radiation wavelength scope that also can reflect LED.
Suitable mattress reflector film is the birefringence multi-layer optical film, and wherein two adjacent layers mate substantially and have very big or do not have Brewster angle (reflectivity of p-polarised light is zero on this angle) in the refractive index on the thickness direction.This makes the incidence angle of the multilayer mirror slowly reduce along with to(for) the reflectivity of p-polarised light and the structure of polarizer have nothing to do with incidence angle, or along with incidence angle departs from normal direction and increases.Therefore, can obtain having the multilayer film of (under the situation of speculum, for two planes, and under the situation of polarizer) high reflectance for selected direction at any incident direction polarization in broadband.These polymeric multilayer reflector comprise the layer that first and second thermoplastic polymers overlap and are provided with.This alternating layer has been determined local coordinate system, and this coordinate system has and is parallel to perpendicular x that described aspect extends and y axle and perpendicular to the z axle of x and y axle, and wherein at least some layer be birefringent.For the polarised light along first, second and the 3rd mutually perpendicular axle, the absolute value of the refringence between first and second layers is respectively Δ x, Δ y and Δ z.The 3rd perpendicular to thin film planar, and wherein Δ x is greater than about 0.05, and Δ z is less than about 0.05.These films such as U.S. Patent No. 5,882,774 is described.
On-plane surface is defined as uneven surface.On-plane surface can be by for example being that flat object is bent to form curved face object.For the useful reflector of the present invention can be the plane or nonplanar.The on-plane surface mattress reflector can form by the object that directly is cast as molded non-planar or plane mattress reflector heating is configured as the on-plane surface mattress reflector.The on-plane surface mattress reflector can be a spill.In illustrative embodiment, the on-plane surface mattress reflector can be the hemisphere face concave shape.LED can be located on or near in the center of on-plane surface mattress reflector sweep.In illustrative embodiment, the on-plane surface mattress reflector is the hemisphere face concave shape of opening towards LED.The lateral dimension of the light-emitting zone of LED can be less than 1/3 of the least radius of the sweep of on-plane surface mattress reflector, or less than 1/6.
Figure 13 is the schematic sectional view of another embodiment PLED structure 210.In this illustrative embodiment, fluorescent material layer 222 and LED 212 copline settings.Fluorescent material layer 222 has first first type surface or sightingpiston 220 and opposite second first type surface or non-sightingpiston 221.Sightingpiston 220 is meant above interference reflector 224 and/or light source output from the sightingpiston of observer in the face of the visual angle of PLED structure 210.
Interference reflector 224 can be arranged between observer and the fluorescent material layer 222.Non-sightingpiston 221 can place the top of substrate or reflector 223 or contiguous with it.As mentioned above, this substrate or reflector 223 can reflect back emission light towards sightingpiston 220.Alternatively or additionally, PLED 210 can be towards first direction, LED 212 can be towards first direction, and first first type surface 220 of fluorescent material layer 222 can be towards first direction.
Be reflected back toward fluorescent material layer 222 at least in part from the light of LED 212 emissions, or be reflected back toward first first type surface or the sightingpiston 220 of fluorescent material layer 222.The radiative at least a portion irradiation interference reflector 224 of LED also is being reflected on the fluorescent material layer 222 under the situation of not passing fluorescent material layer 222.
Reflector 224 can at random be the plane or nonplanar.Shown reflector 224 is the curved shapes that are suitable for making LED emission light to reflect back towards first first type surface or the sightingpiston 220 of fluorescent material layer 222.A kind of exemplary shape is a surface of revolution, and this surface of revolution is launched light reflection resilience on the fluorescent material layer 222 of LED 212 with LED.Can pass LED212 at the axis of symmetry of surface of revolution in some cases, as shown in the figure.The light of reflector 224 reflection LED also allows to pass and appear PLED structure 210 from the light of the fluorescence coating 222 that is excited.In some embodiments, LED emission light can at first shine long pass reflector 224, and the radiative at least a portion of LED can be reflected back on the fluorescent material layer 222 and at first do not pass fluorescent material layer 222.
Figure 14 is the schematic top view of embodiment shown in Figure 13.Show among the figure that the fluorescent material layer 322 with first first type surface or sightingpiston 320 is round LED 312.Fluorescent material layer 322 can be constructed as described above.First first type surface of LED 312 and fluorescent material layer 322 or sightingpiston 320 are all towards observer and/or light source output and towards identical direction (outside paper).
Fluorescence coating 322 can be by inner rim 324 and neighboring 325 determined annulars.In the drawings in the example of Xian Shiing fluorescent material layer 322 along the contour segmentation of annulus fluorescent layer 322.Fluorescent material layer 322 can be divided into different color regions on demand.Fluorescent material layer 322 can have first area 322A, second area 322B, and the 3rd regional 322C and the 4th regional 322D, or more or less, wherein the light of different colours is launched in each zone.Each zone has continuous or discrete fluorescent material layer independently.Each zone has independently even or uneven " point " pattern, as mentioned above.
Figure 15 is the schematic sectional view of another embodiment PLED structure 410.In this example, fluorescent material layer 422 is set to the copline not with LED 412.Fluorescent material layer 422 has first first type surface or sightingpiston 420 and opposite second first type surface or non-sightingpiston 421.This non-sightingpiston 421 can place on substrate or the reflector.As mentioned above, this substrate or reflector can make emission light reflect back towards sightingpiston 420.The light that sends from LED 412 reflects back towards the sightingpiston 420 of fluorescent material layer 422 at least in part and does not at first pass fluorescent material layer 422.
Reflector 424 can at random be the plane or nonplanar.Shown reflector 424 is to be suitable for LED is launched the curved shape that light reflects back towards first first type surface or the sightingpiston 420 of fluorescent material layer 422.A kind of example shapes is a spill, and this spill reflects back into the light of LED emission can be on the fluorescent material layer 422 of LED 412.Reflector 424 reflection LED light also allow to pass and appear PLED structure 410 from the light of the fluorescence coating 422 that is excited.
Embodiment
The measurement of fluorescence herein utilizes spectroradiometer (specifying the Optronic Laboratories in Fla. Orlando city, the OL 770-LED of Inc.) cooperation to carry out with integrating sphere (specifying the OL IS-670-LED of Optronic Laboratories) and high accuracy LED supporter (specifying the OL700-80-20 of Optronic Laboratories).The calibration spectroradiometer, in order to be reported in the integrated radiant emittance that input port enters integrating sphere (with watt/nanometer is a unit).Use the customization stamping machine to make the disk of an inch diameter from the sample that applies fluorescent material.This disk is assembled in the customization film adapter that is used for being installed on the high accuracy LED supporter.The adapter of customization is supported on about one inch place in the substrate of packaged LED to film sample.Measure by LED is installed in the supporter, the film that will have fluorescent coating is put into adapter, makes adapter attached on the light-emitting diode base, then the diode base assembly is inserted the inlet of integrating sphere.If necessary, adjust the optical power level of the detector that arrives spectroradiometer with calibrated neutral density filters.
Unless otherwise specified, be used in the light that multi-layer optical film in the following example reflects two kinds of polarization states of normal incidence equally (that is, each independently optical layers have the refractive index that equates along normal axis direction nominal in the plane).
For wherein given following all examples of fluorescence coating thickness, the thickness that deducts substrate film by the gross thickness from fluorescence coating and substrate film is determined fluorescence coating thickness.Utilization has and is installed in dial gauge support (the Fred V.Fowler Co. in newton city, Zhu Sai state, U.S. Marseille, Inc., catalog number (Cat.No.) 52-580-020) the flat contact on is (equally from Fowler, catalog number (Cat.No.) 52-525-035) dials indicating device (equally from Fowler, catalog number (Cat.No.) 52-520-140) is measured thickness.The thickness of substrate film is the mean value of three measurements of the random position on substrate film.The thickness of fluorescence coating and substrate film is the mean value of six measurements of the random position on fluorescence coating.
Example 1
Yttrium-aluminium-garnet (YAG:Ce) fluorescent material that to mix cerium by following operation is coated in single-layer and transparent poly-(terephthalic acids second diester) (PET) on the film.
(specify State of Arizona, US Qian De to rein in " the Phosphor Ink Part A:Resin Solution " of the Durel company in city the fluoropolymer resin of 12.00 grams, piece number: 1NR001, rev:AA, lot number: KY4-035) put into 40 milliliters of vials.In the scale pan, weigh up the YAG:Ce fluorescent material (specifying the Phosphor Technology of Britain Stevenage, the QMK58/F-U1Lot#13235 of Ltd.) of 15.02 grams.At first in resin, add half fluorescent material and use hand to stir, add second half then and also manually stir, so that fluorescent material is sneaked into resin with the stainless steel spatula.Manually stir fluorescent material and resin and have smooth quality and uniform outward appearance up to mixture.To bottle that gained fluorescent material sticks with paste be housed with cap covers and be placed on the rolling bottle device about 30 minutes.
6 inches wide of 3M company (Sao Paulo, Minnesota State city) be multiply by 10 inches (250 microns) are long to be multiply by the thick a slice single-layer and transparent PET film of 1.5 mils (40 microns) and be placed on the clean plane.Two sides with the lint-free cotton wiping PET film that soaked methyl alcohol.To be equipped with from the rolling bottle device that bottle that fluorescent material sticks with paste is lifted down and about 5 pastel that restrain will be put into pitting on the PET film.Utilize 5 mils (130 microns) slit of square many gaps coater (specifying the PAR-5357 of the BYK-Gardner USA in Maryland, USA Colombia city) that the fluorescent material paste is pulled into coating.Wet film solidified 30 minutes under about 130 ℃ temperature in gravity convection stove (specifying the VWR International in Pennsylvania, United States west chester city, the Model 1350G of Inc.).After the curing, fluorescent material/resin-coated thickness is 1.6 mils (40 microns).
Be ready to scribble 1 inch (25mm) diameter disk of the film of YAG:Ce, and in the aforesaid spectroradiometer of packing into.With disk be orientated scribble fluorescent material a side in integrating sphere.With the blue led with about 463nm peak wavelength (specifying the Hosfelt Electronics in Shi Tuoyiben Weir city, Ohio, the piece number 25-365 of Inc.) excitated fluorescent powder.Revise assembly so that flat exit surface to be provided to blue light by dispose domed lens at the top of the 5mm of blue led standard package.Removed the components of about 0.18 inch (4.6mm) from the top of assembly.LED is provided the electric energy of 20 milliamperes and 3.46 volts by constant-current source.With the emission spectrum of the fluorescence coating of spectroradiometer record, in Figure 16 to be labeled as the curve representation of " example 1 ".The luminous flux of injecting in the integrating sphere that the computed in software of utilizing spectroradiometer to provide is total is 0.068 lumen.
Example 2
A slice had the alternating layer of PET and co-PMMA and have multi-layer optical film (MOF) (according to U.S. Patent No. 6 from about 600nm to the about normal incidence reflected waveband of 1070nm (measuring) in half maximum, 531,230 make) in the film adapter, be placed between the PET film that scribbles fluorescent material of example 1 and the blue led of example 1 (20 milliamperes of operating currents).Spectra re-recorded, in Figure 16 to be labeled as the curve representation of " example 2 ".It is 0.118 lumen that the total luminous flux of injecting in the integrating sphere of computed in software that provides in the spectroradiometer is provided.This shows that luminous intensity has increased 73%.
Example 3
By following operation zinc sulphide (ZnS) fluorescent material is coated in poly-(terephthalic acids second diester) (PET) on the film.
(specify State of Arizona, US Qian De to rein in " the Phosphor Ink Part A:Resin Solution " of the Durel company in city the fluoropolymer resin of 20.04 grams, piece number: 1NR001, rev:AA, lot number: KY4-035) put into 2 ounces of vials.In the scale pan, weigh up the ZnS fluorescent material (specifying the Phosphor Technology of Britain Stevenage, the GL29A/N-C1 of Ltd., lot number 11382) of 20.06 grams.At first in resin, add half fluorescent material and use hand to stir, add second half then and also manually stir, so that fluorescent material is sneaked into resin with the stainless steel spatula.Manually stir fluorescent material and resin and have smooth quality and uniform outward appearance up to mixture.To bottle that gained fluorescent material sticks with paste be housed with cap covers and be placed on the rolling bottle device about 24 hours.
6 inches wide of 3M company (Sao Paulo, Minnesota State city) be multiply by 10 inches long be multiply by the thick a slice clear PET film of 1.5 mils (45 microns) and is placed on the clean plane.Two sides with the lint-free cotton wiping PET film that soaked methyl alcohol.The bottle that fluorescent material sticks with paste will be housed from the rolling bottle device to be lifted down and about 3 pastel that restrain is put on the PET film.Utilize 2 mils (50 microns) slit of square many gaps coater (specifying the PAR-5353 of the BYK-GardnerUSA in Maryland, USA Colombia city) that the fluorescent material paste is pulled into coating.Wet film solidified 30 minutes under about 130 ℃ temperature in gravity convection stove (specifying the VWRInternational in Pennsylvania, United States west chester city, the Model 1350G of Inc.).After the curing, fluorescent material/resin-coated thickness is 0.7 mil (18 microns).
Be ready to scribble 1 inch (25mm) diameter disk of the film of ZnS, and in the aforesaid spectroradiometer of packing into.With disk be orientated scribble fluorescent material a side in integrating sphere.With the UV LED with about 395nm peak wavelength (specifying the Hosfelt Electronics in Shi Tuoyiben Weir city, Ohio, the piece number 25-495 of Inc.) excitated fluorescent powder.Revise assembly to provide flat exit surface by dispose dome at the top of the 5mm of UV LED standard package to UV light.Removed the components of about 0.18 inch (5mm) from the top of assembly.LED is provided the electric energy of 20 milliamperes and 3.7 volts by constant-current source.With the emission spectrum of the fluorescence coating of spectroradiometer record in Figure 17, to be labeled as the curve representation of " example 3 ".The luminous flux of injecting in the integrating sphere that the computed in software of utilizing spectroradiometer to provide is total is 0.052 lumen.
Example 4
A slice had the alternating layer of PET and co-PMMA and have multi-layer optical film (MOF) (according to U.S. Patent No. 6 from about 320nm to the about normal incidence reflected waveband of 490nm (measuring) in half maximum, 531,230 make), in the film adapter, be placed on the fluorescence coating top of example 3, and the UV LED of example 3 (20 milliamperes of operating currents) is as excitaton source.Spectra re-recorded, in Figure 17 to be labeled as the curve representation of " example 4 ".It is 0.062 lumen that the total luminous flux of injecting in the integrating sphere of computed in software that provides in the spectroradiometer is provided.This shows that comparing luminous intensity with example 3 has increased 19%.
Example 5
By the superimposed broadband visible light reflector of making of two multi-layer optical films (MOF).Utilize optically clear adhesive to be folded on the alternating layer with PET and co-PMMA from about 490nm to the about MOF layer of the normal incidence reflected waveband of 610nm (measuring) (the 3M company by Sao Paulo, Minnesota State city makes) and to have on the MOF layer from about 590nm to the about normal incidence reflected waveband of 710nm (measuring) in half maximum in half maximum having the alternating layer of PET and co-PMMA and having.In the film adapter, the gained lamination layer is placed between the PET film that scribbles fluorescent material of example 3 and the UV LED of example 3 (20 milliamperes of operating currents).In the film adapter, a slice had the alternating layer of PET and co-PMMA and have and be placed on from about 320nm to the about multi-layer optical film (MOF) of the normal incidence reflected waveband of 490nm (measuring in half maximum) (the 3M company by Sao Paulo, Minnesota State city makes) on the fluorescence coating top to produce cavity, wherein fluorescence coating is clipped at the visible light speculum of LED one side and between the UV/ of opposite side blu-ray reflection mirror.Spectra re-recorded, in Figure 17 to be labeled as the curve representation of " example 5 ".It is 0.106 lumen that the total luminous flux of injecting in the integrating sphere of computed in software that provides in the spectroradiometer is provided.This shows that comparing luminous intensity with example 3 has increased about 104%.
Example 6
By following operation zinc sulphide (ZnS) fluorescent material is coated in poly-(terephthalic acids second diester) (PET) on the film.
Example 3 described fluorescent material muddles are overlayed on 6 inches wide be multiply by 10 inches long and multiply by on the thick a slice clear PET film of 1.5 mils (40 microns).PET is placed on the clean plane.Two sides with the lint-free cotton wiping PET film that soaked methyl alcohol.The pastel of about 3 grams is put on the PET film.Utilize 4 mils (100 microns) slit of square many gaps coater (specifying the PAR-5353 of the BYK-Gardner USA in Maryland, USA Colombia city) that the fluorescent material paste is pulled into coating.Wet film solidified 30 minutes under about 130 ℃ temperature in gravity convection stove (specifying the VWR International in Pennsylvania, United States west chester city, the Model 1350G of Inc.).After the curing, fluorescent material/resin-coated thickness is 1.3 mils (33 microns).
Be ready to scribble 1 inch (25.4mm) diameter disk of the film of ZnS, and in the aforesaid spectroradiometer of packing into.With disk be orientated scribble fluorescent material a side in integrating sphere.With the UV LED with about 395nm peak wavelength (specifying the Hosfelt Electronics in Shi Tuoyiben Weir city, Ohio, the piece number 25-495 of Inc.) excitated fluorescent powder.Revise assembly to provide flat exit surface by dispose domed lens at the top of the 5mm of UV LED standard package to UV light.Removed the components of about 0.18 inch (5mm) from the top of assembly.LED is provided the electric energy of 20 milliamperes and 3.7 volts by constant-current source.With the emission spectrum of the fluorescence coating of spectroradiometer record in Figure 18 to be labeled as the curve representation of " example 6 ".The luminous flux of injecting in the integrating sphere that the computed in software of utilizing spectroradiometer to provide is total is 0.066 lumen.
Example 7
In the film adapter, a slice had the alternating layer of PET and co-PMMA and have and be placed between the PET film that scribbles fluorescent material of example 6 and the UV LED of example 6 (20 milliamperes of operating currents) from about 490nm to the about multi-layer optical film (MOF) of the normal incidence reflected waveband of 610nm (measuring) (the 3M company by Sao Paulo, Minnesota State city makes) in half maximum.Spectra re-recorded, in Figure 18 to be labeled as the curve representation of " example 7 ".It is 0.095 lumen that the total luminous flux of injecting in the integrating sphere of computed in software that provides in the spectroradiometer is provided.This shows that comparing luminous intensity with example 6 has increased about 44%.
Example 8
By following operation zinc sulphide (ZnS) fluorescent material is coated in poly-(terephthalic acids second diester) (PET) on the film.
On example 3 described fluorescent material muddles being overlayed on the alternating layer with PET and co-PMMA and having from about 490nm to the about MOF layer of the normal incidence reflected waveband of 610nm (measuring) (the 3M company by Sao Paulo, Minnesota State city makes) in half maximum.MOF is placed on the clean plane.Two sides with the lint-free cotton wiping MOF film that soaked methyl alcohol.The pastel of about 3 grams is put on the MOF film.Utilize 4 mils (100 microns) slit of square many gaps coater (specifying the PAR-5353 of the BYK-Gardner USA in Maryland, USA Colombia city) that the fluorescent material paste is pulled into coating.Wet film solidified 30 minutes under about 130 ℃ temperature in gravity convection stove (specifying the VWR International in Pennsylvania, United States west chester city, the Model 1350G of Inc.).After the curing, fluorescent material/resin-coated thickness is 1.3 mils (33 microns).
Be ready to scribble 1 inch diameter disk of the film of ZnS, and in the aforesaid spectroradiometer of packing into.With disk be orientated scribble fluorescent material a side in integrating sphere.With the UV LED with about 395nm peak wavelength (specifying the Hosfelt Electronics in Shi Tuoyiben Weir city, Ohio, the piece number 25-495 of Inc.) excitated fluorescent powder.Revise assembly to provide flat exit surface by dispose dome at the top of the 5mm of UVLED standard package to UV light.Removed the components of about 0.180 inch (5mm) from the top of assembly.LED is provided the electric energy of 20 milliamperes and 3.7 volts by constant-current source.With the emission spectrum of the fluorescence coating of spectroradiometer record in Figure 18 to be labeled as the curve representation of " example 8 ".The luminous flux of injecting in the integrating sphere that the computed in software of utilizing spectroradiometer to provide is total is 0.107 lumen.This shows that comparing luminous intensity with example 6 has increased about 62%.
Example 9
By following operation with the silk screen printing of zinc sulphide (ZnS) fluorescent coating on example 5 described multi-layer optical film (MOF) compressing tablets.
(specify State of Arizona, US Qian De to rein in " the Phosphor Ink Part A:Resin Solution " of the Durel company in city, piece number: 1NR001, rev:AA, lot number: KY4-035) put into 16 ounces of vials the fluoropolymer resin of 150 grams.In the scale pan, weigh up the ZnS fluorescent material (specifying the Phosphor Technology of Britain Stevenage, the GL29A/N-C1 of Ltd., lot number 11382) of 150 grams.Utilization is mixed in the resin fluorescent material by the glass impeller-agitator that air motor drives lentamente.Mix fluorescent material and resin and have smooth quality and uniform outward appearance up to mixture.To bottle that gained fluorescent material sticks with paste be housed with cap covers and be placed on the rolling bottle device about 10 minutes.
(on 11/mm) the PET web plate, use to have per inch 28 lines (1.1 lines/mm) the net mode transfer formula of resolution is printed being installed on 280 of per inch on the screen process press (specifying the SSM type of the Svecia SilkscreenMaskiner AB of Stockholm, SWE).Net mode transfer formula is made up of three zones with 10%, 50% and 90% coverage.By at a slice rolling required mode that once prints out on the MOF film of two-layer lamination layer as described in Example 5.
In the air-supply baking oven, printed layers was solidified 15 minutes under about 138 ℃ temperature.After the curing, fluorescent material/resinous coat thickness is 0.8 mil (20 microns).
The diameter of ZnS silk screen printing film that is ready to that part of pattern making with 50% coverage is the disk of an inch (25mm), and in the aforesaid spectroradiometer of packing into.With disk be orientated scribble fluorescent material a side in integrating sphere.With the UV LED with about 395nm peak wavelength (specifying the HosfeltElectronics in Shi Tuoyiben Weir city, Ohio, the piece number 25-495 of Inc.) excitated fluorescent powder.Revise assembly to provide flat exit surface by dispose dome at the top of the 5mm of UV LED standard package to UV light.Removed the components of about 0.180 inch (5mm) from the top of assembly.LED is provided the electric energy of 20 milliamperes and 3.7 volts by constant-current source.With the emission spectrum of the fluorescence coating of spectroradiometer record in Figure 19 to be labeled as the curve representation of " example 9 ".The luminous flux of injecting in the integrating sphere that the computed in software of utilizing spectroradiometer to provide is total is 0.052 lumen.
Example 10
In the film adapter, a slice had the alternating layer of PET and co-PMMA and have and be placed on the fluorescence coating top of example 9, and the UV LED of example 9 (20 milliamperes of operating currents) is as excitation source from about 320nm to the about multi-layer optical film (MOF) of the normal incidence reflected waveband of 490nm (measuring) (the 3M company by Sao Paulo, Minnesota State city makes) in half maximum.Spectra re-recorded, in Figure 19 to be labeled as the curve representation of " example 10 ".It is 0.078 lumen that the total luminous flux of injecting in the integrating sphere of computed in software that provides in the spectroradiometer is provided.This shows that comparing luminous intensity with example 9 has increased about 50%.
Example 11
Make the heating that is coated with zinc sulphide (ZnS) fluorescent material by following operation and be configured as dome-shaped multi-layer optical film (MOF).
Have the alternating layer of PET and co-PMMA and have and be adhered on poly-(vinyl chloride) thin slice to form flexible complex from about 590nm to the about MOF layer of the normal incidence reflected waveband of 710nm (measuring) in half maximum.This compound is called as MOF-PVC.
Be placed on MOF-PVC on the clean plane and MOF faces up.Upper surface with the lint-free cotton wiping MOF-PVC that soaked methyl alcohol.The example 9 described ZnS fluorescent material pastes of about 3 grams are put on the MOF-PVC.Utilize 4 mils (100 microns) slit of square many gaps coater (specifying the PAR-5353 of the BYK-Gardner USA in Maryland, USA Colombia city) that the fluorescent material paste is pulled into coating.Wet film solidified 30 minutes under about 130 ℃ temperature in gravity convection stove (specifying the VWR International in Pennsylvania, United States west chester city, the Model 1350G of Inc.).
The MOF-PVC compound that scribbles fluorescent material is installed in the heating forming machine.Under 270 ℃ temperature, layered thing was heated 23 seconds.The plate that utilization has circular open (diameter about 1/2 inch (13mm)) makes the MOF-PVC that scribbles fluorescent material be configured as the hemisphere of about 1/2 inch (13mm), and wherein fluorescent material is on projection one side of this hemisphere.Range estimation hemisphere, this hemisphere is thicker and at the thinner thickness of hemisphere interior zone near the thickness of hemisphere perimeter as can be known.Fluorescence coating is smooth and do not break continuously or lamination.
Example 12
Make the heating that is coated with zinc sulphide (ZnS) fluorescent material by following operation and be configured as dome-shaped multi-layer optical film (MOF).
Be placed on example 11 described MOF-PVC sheets on the clean plane and MOF faces up.Upper surface with the lint-free cotton wiping MOF-PVC that soaked methyl alcohol.The example 9 described ZnS fluorescent material pastes of about 3 grams are put on the MOF-PVC.Utilize 2 mils (50 microns) slit of square many gaps coater (specifying the PAR-5353 of the BYK-Gardner USA in Maryland, USA Colombia city) that the fluorescent material paste is pulled into coating.Wet film solidified 30 minutes under about 130 ℃ temperature in gravity convection stove (specifying the VWR International in Pennsylvania, United States west chester city, the Model 1350G of Inc.).
The MOF-PVC compound that scribbles fluorescent material is installed in the heating forming machine.Under 270 ℃ temperature, layered thing was heated 21 seconds.The plate that utilization has circular open (diameter about 1/2 inch (13mm)) makes the MOF-PVC that scribbles fluorescent material be configured as the hemisphere of about 1/2 inch (13mm), and wherein fluorescent material is on projection one side of this hemisphere.Range estimation hemisphere, this hemisphere is thicker and at the thinner thickness of hemisphere interior zone near the thickness of hemisphere perimeter as can be known.Fluorescence coating is smooth and do not break continuously or lamination.
Example 13
Make the heating that is coated with yttrium-aluminium-garnet (YAG:Ce) fluorescent material of mixing cerium by following operation and be configured as dome-shaped multi-layer optical film (MOF).
(specify State of Arizona, US Qian De to rein in " the Phosphor Ink Part A:Resin Solution " of the Durel company in city the fluoropolymer resin of 20.01 grams, piece number: 1NR001, rev:AA, lot number: KY4-035) put into 2 ounces of vials.In the scale pan, weigh up the YAG:Ce fluorescent material (specifying the Phosphor Technology of Britain Stevenage, the QMK58/F-U1 Lot#13235 of Ltd.) of 19.98 grams.At first in resin, add half fluorescent material and use hand to stir, add second half then and also manually stir, so that fluorescent material is sneaked into resin with the stainless steel spatula.Manually stir fluorescent material and resin and have smooth quality and uniform outward appearance up to mixture.To bottle that gained fluorescent material sticks with paste be housed with cap covers and be placed on the rolling bottle device about 30 minutes.
Be placed on example 11 described MOF-PVC sheets on the clean plane and MOF faces up.Upper surface with the lint-free cotton wiping MOF-PVC that soaked methyl alcohol.The YAG:Ce fluorescent material paste of about 3 grams is put on the MOF-PVC.Utilize 4 mils (100 microns) slit of square many gaps coater (specifying the PAR-5353 of the BYK-Gardner USA in Maryland, USA Colombia city) that the fluorescent material paste is pulled into coating.Wet film solidified 30 minutes under about 130 ℃ temperature in gravity convection stove (specifying the VWR International in Pennsylvania, United States west chester city, the Model1350G of Inc.).
The MOF-PVC compound that scribbles fluorescent material is installed in the heating forming machine.Under 270 ℃ temperature, layered thing was heated 23 seconds.The plate that utilization has circular open (diameter about 1/2 inch (13mm)) makes the MOF-PVC that scribbles fluorescent material be configured as the hemisphere of about 1/2 inch (13mm), and wherein fluorescent material is on projection one side of this hemisphere.Range estimation hemisphere, this hemisphere is thicker and at the thinner thickness of hemisphere interior zone near the thickness of hemisphere perimeter as can be known.Fluorescence coating is smooth and do not break continuously or lamination.
Example 14
Make the heating that is coated with yttrium-aluminium-garnet (YAG:Ce) fluorescent material of mixing cerium by following operation and be configured as dome-shaped multi-layer optical film (MOF).
Be placed on example 11 described MOF-PVC sheets on the clean plane and MOF faces up.Upper surface with the lint-free cotton wiping MOF-PVC that soaked methyl alcohol.The about 3 YAG:Ce fluorescent material pastes that restrain that example 13 is described are put on the MOF-PVC.Utilize 2 mils (50 microns) slit of square many gaps coater (specifying the PAR-5353 of the BYK-Gardner USA in Maryland, USA Colombia city) that the fluorescent material paste is pulled into coating.Wet film solidified 30 minutes under about 130 ℃ temperature in gravity convection stove (specifying the VWRInternational in Pennsylvania, United States west chester city, the Model 1350G of Inc.).
The MOF-PVC compound that scribbles fluorescent material is installed in the heating forming machine.Under 270 ℃ temperature, layered thing was heated 21 seconds.The plate that utilization has circular open (diameter about 1/2 inch (13mm)) makes the MOF-PVC that scribbles fluorescent material be configured as the hemisphere of about 1/2 inch (13mm), and wherein fluorescent material is on projection one side of this hemisphere.Range estimation hemisphere this hemisphere as can be known is thicker and at the thinner thickness of hemisphere interior zone near the thickness of hemisphere perimeter.Fluorescence coating is smooth and do not break continuously or lamination.
Example 15
In above-mentioned heating former, example 11 described MOF-PVC sheets were heated 16 seconds under 270 ℃ temperature.Heated MOF-PVC sheet is coated under vacuum-assisted on the hemispherical lens of the commercial 5mm LED assembly of buying.MOF-PVC obtains the net shape corresponding to the hemispherical lens shape.
Utilize the transmitted spectrum of Pa Jin-Ai Ermo (Perkin-Elmer) Lambda 19 spectrophotometer measurement shaping MOF-PVC.The spectrum of the middle body of shaping MOF-PVC is the wave band border at 360nm and 460nm place, and peak reflectivity appears at 400nm.For the wavelength more than the 500nm should shaping MOF-PVC transmissivity greater than 75%.The spectral displacement of the shaping MOF-PVC that this records is to be caused by the Optical stack structure thin that occurs in the shaping processing procedure.
For those skilled in the art, it is evident that, under the prerequisite that does not deviate from the scope and spirit of the present invention, can carry out various modifications and changes, and should be understood that the present invention is not limited to listed illustrative embodiment herein the present invention.

Claims (18)

1. light source comprises:
Fluorescent material layer;
LED, it can launch the light that excites described fluorescent material; And
Polymer is interfered reflector, and it is placed with at least a portion is reflexed on the described fluorescent material layer by the light that does not also see through described fluorescent material layer that described LED sends,
Wherein, described fluorescent material layer and described LED branch is arranged.
2. according to the light source of claim 1, wherein said fluorescent material layer has first type surface, light is launched to the light source output from this first type surface, and the light that does not also see through described fluorescent material layer that is wherein sent by described LED is reflected on the first type surface of this fluorescent material layer.
3. according to the light source of claim 1, wherein said reflector reflects the light of being launched by described fluorescent material by the light of described LED emission and transmission.
4. according to the light source of claim 1, wherein said reflector has flat shape.
5. according to the light source of claim 1, wherein said reflector has molded non-planar.
6. according to the light source of claim 5, wherein said molded non-planar is the elliposoidal curved surface, and wherein said LED and described fluorescent material layer are set on the focus of described elliposoidal curved surface.
7. according to the light source of claim 1, wherein the first's light by described LED emission is reflexed on first first type surface of described fluorescent material layer by described reflector, and is mapped on second first type surface opposite with described first first type surface of this fluorescent material layer by the second portion illumination of this LED emission.
8. according to the light source of claim 1, wherein said fluorescent material layer surrounds LED.
9. according to the light source of claim 1, wherein said fluorescent material layer is divided into different color regions.
10. according to the light source of claim 1, wherein said fluorescent material layer and described LED coplane.
11. according to the light source of claim 1, wherein said fluorescent material layer is discontinuous fluorescent material layer.
12. according to the light source of claim 11, wherein said discontinuous fluorescent material layer is a plurality of points of fluorescent material.
13. according to the light source of claim 12, the area of each in a plurality of points of wherein said fluorescent material is less than 10000 microns 2
14. according to the light source of claim 12, wherein said a plurality of points comprise the fluorescent material of red-emitting, green glow and blue light when being subjected to excitation light irradiation.
15. according to the light source of claim 1, wherein said polymer reflectors comprises the alternating layer of first and second thermoplastic polymers, and at least some layers in the wherein said alternating layer are birefringent.
16. according to the light source of claim 1, wherein said polymer interferes the shape of reflector to make the exciting light that is reflected leave described LED.
17. a method of shining fluorescent material comprises:
Fluorescent material layer and the LED that can launch the light that excites this fluorescent material are provided;
Launch light to polymer reflectors emission light to produce LED from described LED; And
The light by described LED emission that at least a portion is wherein also seen through described fluorescent material layer reflexes on the described fluorescent material layer,
Wherein, described fluorescent material layer and described LED branch are arranged.
18. the method for irradiation fluorescent material according to claim 17 is wherein made described polymer reflectors the shape that makes the exciting light that is reflected leave described LED.
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Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070267646A1 (en) * 2004-06-03 2007-11-22 Philips Lumileds Lighting Company, Llc Light Emitting Device Including a Photonic Crystal and a Luminescent Ceramic
JP5216384B2 (en) * 2008-03-19 2013-06-19 株式会社東芝 Light emitting device
US8697458B2 (en) 2009-04-22 2014-04-15 Shat-R-Shield, Inc. Silicone coated light-emitting diode
CN102449761A (en) * 2009-04-22 2012-05-09 萨特-R-盾公司 Silicone coated light-emitting diode
JP2011040494A (en) 2009-08-07 2011-02-24 Koito Mfg Co Ltd Light emitting module
CN103316815A (en) * 2010-02-12 2013-09-25 亿光电子工业股份有限公司 Dispensing device
JP5459092B2 (en) * 2010-06-17 2014-04-02 セイコーエプソン株式会社 Light source device and projector
EP2402648A1 (en) * 2010-07-01 2012-01-04 Koninklijke Philips Electronics N.V. TL retrofit LED module outside sealed glass tube
BR112014008846A2 (en) * 2011-10-14 2017-04-25 3M Innovative Properties Co remote phosphor led device lens assembly, and method of manufacturing a remote phosphor led device
KR102062046B1 (en) * 2012-07-30 2020-01-03 쓰리엠 이노베이티브 프로퍼티즈 캄파니 Uv stable assemblies comprising multi-layer optical film
CN105185894B (en) * 2014-06-05 2018-09-04 昆山科技大学 Light-emitting device and its filtering method
WO2018083953A1 (en) * 2016-11-07 2018-05-11 東レ株式会社 Light source unit
WO2019220377A1 (en) * 2018-05-18 2019-11-21 3M Innovative Properties Company Shaped optical film
CN111509113B (en) * 2020-03-13 2021-04-27 纳晶科技股份有限公司 LED packaging structure, light emitting method thereof and light emitting device

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5813753A (en) * 1997-05-27 1998-09-29 Philips Electronics North America Corporation UV/blue led-phosphor device with efficient conversion of UV/blues light to visible light
US5813752A (en) * 1997-05-27 1998-09-29 Philips Electronics North America Corporation UV/blue LED-phosphor device with short wave pass, long wave pass band pass and peroit filters
EP1119058A1 (en) * 1999-07-29 2001-07-25 Citizen Electronics Co., Ltd. Light-emitting diode
GB2373368A (en) * 2001-03-12 2002-09-18 Arima Optoelectronics Corp White light emitting LED devices
US20020154406A1 (en) * 1998-01-13 2002-10-24 3M Innovative Properties Company Post-formable multilayer optical films and methods of forming
US20030002272A1 (en) * 2001-06-28 2003-01-02 Yoshinobu Suehiro Light-emitting diode

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1106937C (en) * 1995-06-26 2003-04-30 美国3M公司 Multilayer polymer film with additional coatings or layers
GB2311166A (en) * 1996-03-13 1997-09-17 Sharp Kk An optoelectronic semiconductor device
US6155699A (en) * 1999-03-15 2000-12-05 Agilent Technologies, Inc. Efficient phosphor-conversion led structure
GB2356713A (en) * 1999-11-26 2001-05-30 Seiko Epson Corp Distributed Bragg reflector
JP2002076434A (en) * 2000-08-28 2002-03-15 Toyoda Gosei Co Ltd Light emitting device
US6686676B2 (en) * 2001-04-30 2004-02-03 General Electric Company UV reflectors and UV-based light sources having reduced UV radiation leakage incorporating the same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5813753A (en) * 1997-05-27 1998-09-29 Philips Electronics North America Corporation UV/blue led-phosphor device with efficient conversion of UV/blues light to visible light
US5813752A (en) * 1997-05-27 1998-09-29 Philips Electronics North America Corporation UV/blue LED-phosphor device with short wave pass, long wave pass band pass and peroit filters
US20020154406A1 (en) * 1998-01-13 2002-10-24 3M Innovative Properties Company Post-formable multilayer optical films and methods of forming
EP1119058A1 (en) * 1999-07-29 2001-07-25 Citizen Electronics Co., Ltd. Light-emitting diode
GB2373368A (en) * 2001-03-12 2002-09-18 Arima Optoelectronics Corp White light emitting LED devices
US20030002272A1 (en) * 2001-06-28 2003-01-02 Yoshinobu Suehiro Light-emitting diode

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