CN100335519C - 含有聚氨酯分散体和高度交联的聚合物颗粒的涂料组合物 - Google Patents
含有聚氨酯分散体和高度交联的聚合物颗粒的涂料组合物 Download PDFInfo
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- CN100335519C CN100335519C CNB038115220A CN03811522A CN100335519C CN 100335519 C CN100335519 C CN 100335519C CN B038115220 A CNB038115220 A CN B038115220A CN 03811522 A CN03811522 A CN 03811522A CN 100335519 C CN100335519 C CN 100335519C
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- methyl
- acrylate
- acid
- prepolymer
- ester
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- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
- C08G18/0866—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being an aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4288—Polycondensates having carboxylic or carbonic ester groups in the main chain modified by higher fatty oils or their acids or by resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
- C08G18/765—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group alpha, alpha, alpha', alpha', -tetraalkylxylylene diisocyanate or homologues substituted on the aromatic ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31554—Next to second layer of polyamidoester
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31605—Next to free metal
Abstract
Description
实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 | 实施例7 | |
装料1 | |||||||
去离子水 | 991.8 | 592.5 | 592.5 | 592.5 | 596.9 | 596.9 | 596.9 |
丁二酸二辛基酯磺酸盐1 | 1.5 | 0.9 | 0.9 | 0.9 | 0.9 | 0.9 | 0.9 |
进料A | |||||||
甲基丙烯酸甲酯 | 15.6 | 9.3 | 9.3 | 9.3 | 9.3 | 9.3 | 9.3 |
丙烯酸丁酯 | 8.2 | 4.9 | 4.9 | 4.9 | 4.9 | 4.9 | 4.9 |
乙二醇二甲基丙烯酸酯 | 12.0 | 7.2 | 7.2 | 7.2 | 7.2 | 7.2 | 7.2 |
进料B | |||||||
去离子水 | 39.2 | 29.5 | 29.5 | 29.5 | 29.5 | 29.5 | 29.5 |
4,4’-偶氮双(4-氰基戊酸) | 4.0 | 2.4 | 2.4 | 2.4 | 2.4 | 2.4 | 2.4 |
二甲基乙醇胺 | 3.6 | 2.2 | 2.2 | 2.2 | 2.2 | 2.2 | 2.2 |
进料C | |||||||
甲基丙烯酸甲酯 | 296.4 | 194.7 | 211.4 | 228.1 | 186.2 | 194.6 | 203.0 |
丙烯酸丁酯 | 279.9 | 183.7 | 200.4 | 217.0 | 175.1 | 183.5 | 191.9 |
乙二醇二甲基丙烯酸酯 | 222.4 | 100.0 | 66.6 | 33.3 | 133.8 | 133.8 | 133.8 |
丙烯酰胺(50%水溶液) | 155.6 | 93.0 | 93.0 | 93.0 | 67.1 | 33.6 | |
去离子水 | 668.6 | 419.0 | 419.0 | 419.0 | 419.0 | 419.0 | 419 |
乙氧基化壬基苯酚硫酸铵2 | 8.1 | 4.8 | 4.8 | 4.8 | 4.8 | 4.8 | 4.8 |
进料D | |||||||
去离子水 | 247.6 | 148.0 | 148.0 | 148.0 | 148.0 | 148.0 | 148.0 |
4,4’-偶氮双(4-氰基戊酸) | 4.0 | 2.4 | 2.4 | 2.4 | 2.4 | 2.4 | 2.4 |
二甲基乙醇胺 | 3.6 | 2.2 | 2.2 | 2.2 | 2.2 | 2.2 | 2.2 |
进料E | |||||||
生物杀伤剂3 | 3.3 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 |
去离子水 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | |
物理性能 | |||||||
固体4(wt%) | 30.0 | 30.0 | 30.0 | 30.0 | 30.0 | 30.0 | 30.0 |
粒度5(微米) | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
组分 | 重量份(g) |
丙二醇单丁基醚 | 7.4 |
铝粉浆16 | 5.1 |
Tinuvin 1130 | 1.6 |
CYMEL303 | 3.7 |
铝钝化剂 | 1.6 |
组分 | 实施例14 | 实施例15(对比) |
实施例8的聚氨酯分散体 | 13.1 | 13.1 |
50%DIPA水溶液 | 0.7 | 0.7 |
实施例1的分散体 | 18.5 | |
聚氨酯分散体17 | 25.7 | |
石油溶剂油(Mineral Spirits) | 1.5 | 1.5 |
去离子水 | 7.2 | |
预混合料A | 19.4 | 19.4 |
实施例13的聚酯 | 5.3 | 5.3 |
增稠剂水溶液18 | 33.7 | 33.7 |
50%DIPA水溶液 | 0.6 | 0.6 |
侧视色指数-BC | 15.8 | 14.1 |
侧视色指数-BC/CC | 14.3 | 11.5 |
组分 | 重量份(g) |
丙二醇单丁基醚 | 60 |
铝粉浆19 | 56.3 |
Tinuvin 113020 | 6 |
CYMEL 30321 | 40 |
铝钝化剂22 | 2 |
50%DMEA水溶液23 | 13.8 |
聚(丙二醇),M.W.425 | 10 |
Byk 34824 | 0.4 |
Surfynol 104E25 | 8 |
辛醇 | 16 |
组分 | (g) | (g) |
实施例16 | 实施例17 | |
Shell Sol 7126 | 20 | 20 |
实施例12的分散体 | 232.6 | |
实施例11的分散体 | 232.0 | |
Daotan 646227 | 138.9 | 138.9 |
50%DMEA水溶液 | 6 | 6 |
丙二醇单丁基醚 | 20 | 20 |
预混合料B | 212.4 | 212.4 |
去离子水 | 231.6 | 80 |
实施例16PCC9711 | 实施例16BASF2K | 实施例17PCC9711 | 实施例17BASF2K | BASF TSPCC9711 | BASF TSBASF2K | |
OEM性能 | ||||||
DOI28 | 90 | 90 | 89 | |||
在湿度试验之后的DOI29 | 72 | 77 | 41 | |||
粘合力30 | 5 | 5 | 5 | 5 | 4 | 5 |
在湿度试验之后的粘合力 | 4 | 1 | 0 | |||
L1531 | 128 | 123 | 132 | 127 | 116 | 112 |
L11032 | 33 | 34 | 34 | 35 | 37 | 38 |
低温烘干修补性能 | ||||||
粘合力30 | 5 | 0 | 0 |
(g) | (g) | |
组分 | 预混合料A | 预混合料B |
丙二醇单丁基醚 | 3.5 | 3.3 |
铝粉浆33 | 5.0 | 4.8 |
Tinuvin 113034 | 0.2 | 0.2 |
CYMEL30335 | 3.5 | 3.3 |
铝钝化剂36 | 1.5 | 1.4 |
DIPA37 | 0.3 | 0.3 |
(g) | (g) | |
组分 | 实施例18 | 实施例19 |
DDBSA/DIPA溶液38 | 0.2 | 0.2 |
聚氨酯分散体39 | 12.6 | 4.0 |
50%DIPA水溶液 | 0.3 | 0.3 |
实施例1的分散体 | 16.8 | 16.1 |
实施例8的分散体 | 7.8 | |
石油溶剂油40 | 1.4 | 1.4 |
丙二醇单丁基醚 | 3.5 | 3.3 |
预混合料A | 14.0 | |
预混合料B | 13.3 | |
实施例13的聚酯 | 5.0 | 4.8 |
Laponite Solution41 | 8.7 | 8.3 |
Acrysol ASE-60 | 1.9 | 1.8 |
去离子水 | 34.5 | 37.4 |
50%DIPA水溶液 | 1.1 | 1.3 |
底基涂料 | 透明涂料 | 侧视色指数 | 短波 | 在湿度试验44之后的粘合力43 | 在湿度试验44之后的DOI45 |
实施例18 | TKU 1050 | 12.1 | 22 | ||
实施例19 | TKU 1050 | 12.7 | 15 | ||
实施例18 | HiTech | 12.9 | 0 | 58 | |
实施例19 | HiTech | 13.6 | 3 | 77 |
说明 | 实施例22对比 | 实施例23 | 实施例24 |
组分1 | |||
Propasol B46 | 27.65 | 27.65 | 27.65 |
Dowanol DPW47 | 7.45 | 7.45 | 7.45 |
HEQ-934648 | 0.97 | 0.97 | 0.97 |
Resimene 75049 | 22.51 | 22.51 | 22.51 |
HP-68-666550 | 9.40 | ||
实施例20的聚氨酯分散体 | 111.17 | ||
实施例21的聚氨酯分散体 | 111.97 | ||
组分2 | |||
石油溶剂油51 | 7.84 | 7.84 | 7.84 |
去离子水 | 29.41 | 29.41 | 29.41 |
聚酯/丙烯酸胶乳52 | 91.02 | ||
Setalux 6802 AQ-2453 | 42.26 | 42.26 | 42.26 |
DMEA溶液54 | 0.98 | 0.98 | 0.98 |
86T-755 | 182.39 | 182.39 | 182.39 |
Witcobond W-24256 | 24.66 | 24.66 | 24.66 |
总计 | 446.54 | 457.29 | 458.09 |
底基涂料 | 实施例23 | 实施例24 |
色移到蓝色的程度 | 0.68 | 0.65 |
Claims (129)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US10/126,903 US7001952B2 (en) | 2002-04-19 | 2002-04-19 | Coating compositions containing polyurethane dispersions and highly crosslinked polymer particles |
US10/126,903 | 2002-04-19 |
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CN1656134A CN1656134A (zh) | 2005-08-17 |
CN100335519C true CN100335519C (zh) | 2007-09-05 |
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US (1) | US7001952B2 (zh) |
EP (1) | EP1497349B1 (zh) |
JP (2) | JP4411407B2 (zh) |
KR (1) | KR20040103982A (zh) |
CN (1) | CN100335519C (zh) |
AU (1) | AU2003234123B2 (zh) |
BR (2) | BRPI0309378B1 (zh) |
CA (1) | CA2482599C (zh) |
ES (1) | ES2767930T3 (zh) |
WO (1) | WO2003089487A1 (zh) |
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US7997037B2 (en) * | 2003-06-23 | 2011-08-16 | Ppg Industries Ohio, Inc. | Integrated window sash with groove for desiccant material |
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US7910634B2 (en) * | 2004-03-25 | 2011-03-22 | Ppg Industries Ohio, Inc. | Aqueous dispersions of polymer-enclosed particles, related coating compositions and coated substrates |
US8563212B2 (en) | 2004-07-16 | 2013-10-22 | Transitions Optical, Inc. | Methods for producing photosensitive microparticles, non-aqueous dispersions thereof and articles prepared therewith |
US8563213B2 (en) | 2004-07-16 | 2013-10-22 | Transitions Optical, Inc. | Methods for producing photosensitive microparticles |
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WO2006094227A2 (en) * | 2005-03-03 | 2006-09-08 | South Dakota Soybean Processors, Llc | Novel polyols derived from a vegetable oil using an oxidation process |
CN100358930C (zh) * | 2005-10-11 | 2008-01-02 | 东华大学 | 一种用于人造毛皮底布涂层的复合乳液的制备方法及应用 |
US7662461B2 (en) | 2006-03-31 | 2010-02-16 | Milliken & Company | Synthetic leather articles and methods for producing the same |
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2002
- 2002-04-19 US US10/126,903 patent/US7001952B2/en not_active Expired - Lifetime
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2003
- 2003-04-17 JP JP2003586206A patent/JP4411407B2/ja not_active Expired - Fee Related
- 2003-04-17 AU AU2003234123A patent/AU2003234123B2/en not_active Ceased
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- 2003-04-17 CN CNB038115220A patent/CN100335519C/zh not_active Expired - Lifetime
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JP2005523353A (ja) | 2005-08-04 |
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AU2003234123B2 (en) | 2006-02-16 |
JP4411407B2 (ja) | 2010-02-10 |
KR20040103982A (ko) | 2004-12-09 |
WO2003089487A1 (en) | 2003-10-30 |
US7001952B2 (en) | 2006-02-21 |
US20030220446A1 (en) | 2003-11-27 |
CN1656134A (zh) | 2005-08-17 |
BRPI0309378B1 (pt) | 2017-06-27 |
AU2003234123A1 (en) | 2003-11-03 |
CA2482599C (en) | 2010-02-02 |
CA2482599A1 (en) | 2003-10-30 |
JP2007197732A (ja) | 2007-08-09 |
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Assignee: PPG COATINGS (TIANJIN) Co.,Ltd. Assignor: PPG INDUSTRIES OHIO, Inc. Contract record no.: 2012990000336 Denomination of invention: Coating compositions containing polyurethane dispersions and highly crosslinked polymer particles Granted publication date: 20070905 License type: Common License Open date: 20050817 Record date: 20120521 |
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Assignee: Czech coatings (Wuhu) Co., Ltd. Assignor: PPG INDUSTRIES OHIO, Inc. Contract record no.: 2015990000200 Date of cancellation: 20170228 Assignee: PPG industrial coatings (Suzhou) Co.,Ltd. Assignor: PPG INDUSTRIES OHIO, Inc. Contract record no.: 2012990000290 Date of cancellation: 20170228 |
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Application publication date: 20050817 Assignee: Czech coatings (Wuhu) Co., Ltd. Assignor: PPG INDUSTRIES OHIO, Inc. Contract record no.: 2017990000079 Denomination of invention: Coating compositions containing polyurethane dispersions and highly crosslinked polymer particles Granted publication date: 20070905 License type: Common License Record date: 20170310 Application publication date: 20050817 Assignee: PPG coatings (Zhangjiagang) Co., Ltd. Assignor: PPG INDUSTRIES OHIO, Inc. Contract record no.: 2017990000077 Denomination of invention: Coating compositions containing polyurethane dispersions and highly crosslinked polymer particles Granted publication date: 20070905 License type: Common License Record date: 20170310 |
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Assignee: PPG COATINGS (TIANJIN) Co.,Ltd. Assignor: PPG INDUSTRIES OHIO, Inc. Contract record no.: 2012990000336 Date of cancellation: 20170320 |
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Application publication date: 20050817 Assignee: PPG COATINGS (TIANJIN) Co.,Ltd. Assignor: PPG INDUSTRIES OHIO, Inc. Contract record no.: 2017990000096 Denomination of invention: Coating compositions containing polyurethane dispersions and highly crosslinked polymer particles Granted publication date: 20070905 License type: Common License Record date: 20170329 |
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