CA2709920A1

CA2709920A1 - Stretchable, hand-tearable, conformable, and cinchable reinforced adhesive tape articles

Info

Publication number: CA2709920A1
Application number: CA2709920A
Authority: CA
Inventors: Michael J. Ulsh; John J. Rogers; Jon E. Stickrod; John R. Jacobson; Jeffrey J. Schwab; Richard L. Peloquin
Original assignee: Individual
Current assignee: 3M Innovative Properties Co
Priority date: 2007-12-18
Filing date: 2008-12-03
Publication date: 2009-07-02
Anticipated expiration: 2028-12-03
Also published as: WO2009082602A2; AU2008340350B2; US9388329B2; EP2231802A4; CN101939392B; CA2709920C; CN101939392A; BRPI0819556A2; JP2011507733A; EP2231802B1; US20090155565A1; EP2231802A2; WO2009082602A3; JP5302974B2; AU2008340350A1

Abstract

The disclosure relates to reinforced articles particularly adapted for use, in combination, with an adhesive to form reinforced adhesive tape articles that are stretchable as well as hand-tearable along with being highly conformable and cinchable.

Description

STRETCHABLE, HAND-TEARABLE, CONFORMABLE, AND CINCHABLE
REINFORCED ADHESIVE TAPE ARTICLES

Background The present description is related to reinforced articles particularly adapted for use, in combination, with an adhesive to form reinforced adhesive tape articles.
More particularly, the present description is directed to such reinforced articles for use in making reinforced adhesive tape articles that are stretchable as well as hand-tearable along with being highly conformable and cinchable.
Typical reinforced adhesive tape articles, such as a duct tape include, in combination, a backing layer generally coextensive to a reinforcing scrim layer, and a pressure sensitive adhesive layer covering the reinforcing scrim layer. The materials selected for the reinforced adhesive tape articles generally exhibit strength and are normally stretch resistant. Such tapes are also generally conformable and adhere to many different substrates having many different surface textures. Because the tapes possess strength and stretch resistance, they ordinarily are hand-tear resistant as well. In some circumstances, tear-propagating perforations may be added for facilitating hand-tearing properties. While this has proven successful, nonetheless, perforating is, of course, an additional processing step requiring specialized apparatus and processing conditions.
Accordingly, these additional apparatus and processing requirements add to overall time and costs of manufacturing. Moreover, while the reinforced adhesive tape articles have demonstrated a high degree of versatility for countless different uses, there are, nevertheless, situations (e.g., wrapping around small diameter pipes or applications to other odd and uneven surfaces) wherein their physical characteristics limit their ability to be as highly conformable as might otherwise be desirable. For instance, some reinforced adhesive tape articles, when adhered to some uneven substrates, leave spaces or gaps that may compromise benefits of the sealing intended thereby.
While reinforced adhesive tape articles, such as duct tape, provide innumerable benefits, there is, nevertheless, a continuing desire for improvements, particularly with respect to providing even more conformable reinforced adhesive tape articles that are also stretchable, easily hand-tearable, as well as cinchable.

Summary There are needs for continuing improvements with respect to adhesive tapes, such as duct tapes, that are more stretchable, easily-tearable, cinchable as well as conformable compared to known adhesive tapes.
According to one exemplary embodiment of the present description, provision is made for a reinforced article adapted to be used, in combination, in a conformable reinforced adhesive tape. The reinforced article comprises: an elastomeric polymeric backing layer having opposing first and second major surfaces; and, an elastomeric polymeric reinforcing material layer carried along at least one of the first and second major surfaces, wherein the backing layer and the reinforcing material layer of the reinforced article exhibit an elongation extension at break of about at least about 25 to 60%; and, tensile strength greater than about 10 lb/in (17.5 N/cm) at break.
Another exemplary embodiment of the present description is directed to a length of reinforced adhesive tape, wherein the noted reinforced article, as described above, is combined with an adhesive layer in generally covering relationship to the reinforcing material layer on the backing layer. In another exemplary embodiment, the adhesive layer may be a pressure-sensitive adhesive capable of application to a variety of surfaces.

Brief Description of the Drawings The sole FIGURE is a schematic view of a reinforced adhesive tape formed according to the principles of the present description.

Detailed Description Reference is made to the drawing for illustrating one exemplary embodiment of a reinforced article 10 particularly adapted to be used in combination in a reinforced adhesive tape article 12 that possess extensible or stretchable characteristics with sufficient tensile strength that enables hand-tearablilty of the tape article.
As will be described, the properties of the reinforced article 12 enable it to be highly conformable and, due to increased elastic recovery properties, improve its ability to be highly cinchable relative to known reinforced tape articles.
In one exemplary embodiment, the reinforced article 10 includes, in combination, an elastomeric backing layer 14 and an elastomeric reinforcing layer 16. For forming the reinforced adhesive tape article 12, an elastomeric adhesive layer 18 is also provided, in combination, in a substantially covering relationship to the reinforcing layer 16. The reinforced adhesive tape article 12, as will be described, presents advantages over known types of similar articles. The advantages include, but are not limited to, enhanced stretchability, hand-tearability despite being stretchable, as well as having relatively higher conformability and elastic recovery properties than known types of reinforced adhesive tape articles.
The elastomeric backing layer 14 exhibits stretchiness or extensible properties typically exceeding elongation properties of standard types of duct tape, such as those described in U.S. Patent No. 7,056,844 B2 directed to "Transparent Reinforced Tape"
which is commonly assigned herewith and incorporated herein by reference. In one exemplary embodiment, the elongation or stretch characteristics of the materials that may be used include an elongation extension at break of greater than about 200%
and more typically from about 300% to 500%. In addition to possessing the foregoing stretch or elongation properties, the backing layer 14 includes sufficient tensile strength so as to facilitate hand-tearing of the tape 12 despite the stretchiness of the backing layer 14. In one exemplary embodiment, the backing layer 14 may have tensile strength in a range of about at least greater than about 25 lb/in (44 N/cm). In another exemplary embodiment, the backing layer 14 may have tensile strength in a range of about at least about 25 lb/in (44 N/cm)to about 60 lb/in (105 N/cm) at break. It has been determined that tensile strength in excess of about 60 lb/in (105 N/cm) at break presents a reinforced article that is relatively too stiff for successful hand-tearing let alone enabling the degree of conformability otherwise provided by the noted tensile strength ranges.
While the backing layer 14 may be made of a wide variety of materials suitable for backing layers used in particular for adhesive tape articles, it may be made of a polymeric film. The polymeric film may be in a range of materials that include, but are not limited to, a group consisting of polyolefin elastomers, polypropylene elastomers, polyvinyl elastomers, polyurethane elastomers, and blends thereof.
Table 1, below, lists descriptions of polymeric film backing layers 14 that have been used in samples tested. The list includes a description column of the trade names of the resins used to make the film backing layers, an acronym column that lists an acronym of the chemical names of the backing layers, while a third column describes, more completely, the acronym and where such a backing material may be obtained or is described. Film backings were constructed from these resins by use of a 19 mm Brabender extruder with a 6 inch single layer flat die cast extrusion at a temperature of about 190 C.
Additional backing layers used in the samples tested include: 3M oriented polypropylene, such as described in U.S. Patent No. 6,797,375; 3M ScotchcalTM 220-114, plasticized vinyl film product, commercially available from 3M Company, St. Paul, MN; 3M
TagadermTM, polyurethane film product, commercially available from 3M Company, St.
Paul, MN; and, GF- 10 low density polyethylene (LDPE) film commercially available from Pliant Corporation, Schaumberg, IL.

Table 1 Plastic Film Backing Descriptions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
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............TradeName ................... AcrQ]a.y ....................................................................._ Chemistrv...............................................................
Fina Z9470 PP Polypropylene, commercially available from Fina Total Petrochemicals USA, Inc., Houston, TX.

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Dupont ElvaloyTM EMA Ethylene-Methyl Acrylate Copolymer, commercially available from 1209AC Dupont Company, Wilmington, DE.
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Dupont ElvaloyTM EEA Ethylene-Butyl Acrylate Copolymer, commercially available from 2112AC Dupont Company, Wilmington, DE.
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EEA Ethylene-Ethyl Acrylate Copolymer, commercially available from Dupont ElvaloyTM Dupont Company, Wilmington, DE.

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EBA Ethylene-Butyl Acrylate Copolymer, commercially available from Dupont ElvaloyTM Dupont Company, Wilmington, DE.

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Dow PrimacorTM EAA Ethylene-Acrylic Acid Copolymer, commercially available from 1410 Dow Chemical Company, Midland, MI.
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Dupont SurlynTM Surlyn Ethylene-Methacrylic Acid Copolymer, commercially available 1701-1 from Dupont Company, Wilmington, DE.
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Dupont ElvaxTM EVA Ethylene-Vinyl Acetate Copolymer, commercially available from 3135B Dupont Company, Wilmington, DE.
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Dow 6109T LLDPE Linear Low Density Polyethylene, commercially available from Dow Chemical Company, Midland, MI.
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Dupont BynelTM EVA/Acrylate Ethylene-Vinyl Acetate, acid/acrylate modified Copolymer, 3101 commercially available from Dupont Company, Wilmington, DE.
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3M ScotchcalTM Cast plasticized Vinyl, commercially available from 3M Company, 220-114 St. Paul, MN.
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Pliant Polyolefin LDPE/LLDP Extruded Low Density / Linear Low Density Polyethylene from Blend E Pliant Corporation, Schaumberg, IL
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3M TagadermTM Polyurethane- available from 3M Company St_Pau12 MN.
----------------------------3M Oriented O-PP Biaxial Oriented Polypropylene,--see US Pat. No. 6,797,375 Poly,propy_ _Qn_Q------------------------------------------------------av_ailable_from 3M_Company_-----------------------------------------------------------------------------------3M Transparent LDPE Low Density Polyethylene, available from 3M Company, St.
Paul, Duct 2120..............................................................
MN:............................................................................
...........................................................

Experimental Results A number of samples were tested according to the present description using the testing machines and methodologies described herein. The experimental data gathered from such tests are recorded in the tables and chart below employing testing methodologies as described herein.

Test Methods The performance properties of films, as related to their utility for a duct tape with higher elongation properties, were measured by the following test procedures at room temperatures:
1) Tensile Strength is a measure of energy to break (measured at break point) and is a characteristic of film toughness. It is the area under the stress-strain curve. Tensile values are obtained with film elongation. Measurements were obtained using an Instron Model 5544 tester, commercially available from Instron Corporation, Norwood, MA, at 73.4 +/-3.6 F (23.0 +/- 2.0 C) according to ASTM D3759.
2) Elongation is film deformation or ductility (measured at break point).
Measurements were obtained using an Instron Model 5544 tester at 73.4 +/- 3.6 F (23.0 +/-2.0 C) according to ASTM D3759. The gauge length and separation speed was set according to the film elongation range:
a. For films having less than 20% elongation, a 5 inch (12.7 cm) gauge length and a separation rate of 5 inches per minute (12.7 cm/min) was used.
b. For films having an elongation between 20% and 100%, a 4 inch (10.2 cm) gauge length and a separation rate of 12 inches per minute (30.5 cm/min) was used.

c. For films having an elongation greater than 100%, a 2 inch (5.1 cm) gauge length and a separation rate of 20 inches per minute (50.8 cm/min) was used.

3) Modulus is a measure of film stiffness. Higher values indicate more resistance to film stretching (deformation). Young's modulus (elasticity) measurements were obtained using an Instron Model 5544 tester at 73.4 +/- 3.6 F (23.0 +/- 2.0 C) according to ASTM D3759, using a 10 inch (25.4 cm) gauge length and a separation rate of 0.5 inches (1.3 cm/min) per minute.

4) Elastic Recovery is a measure of recovery from extension, permanent deformation and stress retention of film. The elastic recovery properties are determined by subjecting the film samples to specified extensions and measuring the quantity of recovery and permanent change with respect to the original sample's dimensions. Elastic recovery values for the samples that were obtained were up to extension at break following ASTM test method D5459-95.

The physical properties (tensile, elongation and modulus) of the above backing layer films, as related to their utility for a duct tape with higher elongation properties than known duct tapes, were measured by the test procedures previously described, and are shown in Table 2 below. The data demonstrate that some of the films, such as polyolefin, samples 2-10, and the polyurethane film, sample 12, were less stiff and are exemplary of materials that might be good as a backing layer that would make a duct tape article more conformable than known duct tape articles. The tensile properties of the various films were equal to or better than the sample C2.

Table 2 Physical Properties of Plastic Film Backing:
Tensile, Elongation and Young's Modulus . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
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Sample Film Caliper Tensile at Break Elon- Young's mils (cm) lb/in (N/cm) ga- Modulus tion psi (MPa) at 37039,000õ(2691__.
2 Dupont 1209AC4;4_(0;031)2,5 3______________DupontElyaloy_TM 2112AC_____4 4 (0 011)____________ .............. .............. __DupontElvaloyTM 2116AC_______4 2_(0;011_____________10 6_(18 6)............ 51_.................
72000_~48~_____ _5______Dont ElvaloyTM 3217AC_______A.0_(0;010)............. 12.6 (22 ___600__________________9=0..00 ...
._____________6_______________ PrimacorTM
1410,,___________________________4.5__ 0 011, ,,,,,,,,,,,,15.7õ 27,5 ,,,,,,,,,,,, 3A0,,,,,......,,,16z000õ 110 __DUponv SurlynTM 1701=1___________6.1__(0;015 ____________22.1__(47 .......
320_______________39=000 (269 __ ............$______________DupontElyaxTM 313SB______________5.6 (0 14)___________22Ø38.5)_________11000_(26 ............. 9 ................
Dow_61093......................................_ 3Ø.(0; 008)............._ 6..(15.1)..............260.................12z000..(83.) ..._ ............. 0_____ont Bvne1TM
3101___________________6.6.40;017)............. 19.9 (34;8 ___540_________________6=000 (41)_____ _ 11______________ ScotchcalTM_ 8220-114 1;9 (0; 005............._ (10;0............._ 130 _66,000(455) ... agadermTM Urethane ___________________ 10__(0;003).........
_____~.9_(13.g)______________410_________________ 5z000- 3A) C1 3M Oriented Polypropylene 1.3 (0.003) 30.7 (53.8) 50 191,000 ............. Z4................ f 13171________________ C2 Pliant GF-10 low density 2.5 (0.006) 10.3 (18.0) 160 25,000 (172) Note: Tensile and Elongation test at 2 inch (5.1 cm) gauge length and 20 inch/min (50.8 cm/min)separation rate. Modulus test at 5 inch (12.7 cm) gauge length at 0.5 in/min (1.3 cm/min) separation rate.

In addition, the backing layer 14 may have thicknesses in the range of about 1 mil (0.0025 cm) to about 7 mils (0.0178 cm). In another exemplary embodiment, the thickness range may be about 2-3 mils (0.005-0.007 cm). In general, the thickness range is determined by the type of properties the reinforced adhesive tape is to possess. As such, the materials and thicknesses of the backing layer 14 may be selected to be used in any suitable combination with the reinforcing layer 16 so as to produce the advantages that have been and will be described herein. Clearly, with thicknesses that are too thick or too thin, the reinforced adhesive tape might not be able to perform in the intended manner, such as by being too hard to hand tear or too easily tearable during application to substrates. While a polymeric backing layer 14 has been noted above, the present description envisions other suitable materials, such as non-woven materials in a composite backing construction.
Reference is made to the reinforcing material or layer 16. The reinforcing layer should be extensible, and possess sufficient tensile strength, which when used in combination with the backing material or layer, noted above, provides a reinforced article having the physical characteristics of the present description. According to the present description, the reinforcing layer is directed to, at least, providing: a suitable balance between elongation so that it may elongate sufficiently to work in combination with the backing layer 14, whereby it exceeds the stretchiness of conventional duct tape, but has strength for performing as a reinforcing layer without distorting or breaking;
as well as is able to be torn manually in straight or transverse directions with respect to the length of the tape, as well as is cinchable and highly conformable as will be described below.
It will be appreciated that a variety of materials may be used that are consistent with the teachings of the present description. The reinforcing layer 16 may be more extensible than scrim that may have typically been used for reinforced adhesive tape. In one exemplary embodiment, warp drawn yams may be used. These may be prepared from partially oriented yam (POY) made of, for example, polyester. POY may be made using a variety of known techniques including being spun at predetermined speeds.
Besides polyester, other natural, synthetic, or blends thereof, such as described in U.S. 7,056,844, may be used. These other suitable materials include, without limitation, fiberglass, acetate, acrylic, modacrylics, rayon, nylon, cotton, polyethylene, polypropylene, polyamine, and Kevlar.
In addition, the reinforcing layer 16 may have a construction similar to that described in the noted United States Patent No. 7,056,844. In this regard, fiber used to make the polyester POY reinforcing layer may be individual or in bundles, and those fibers and/or bundles of fibers may be randomly disposed to form a non-woven reinforcing layer, or may be disposed in a rectangular pattern with space between the fibers or bundles to form a reinforcing layer that may be manually broken at the intersections between the woven fibers or bundles when the backing layer is torn to guide straight line tearing of the tape in either of two directions at right angles to each other. When the fibers are in bundles they may be disposed so that they can easily be wetted by an adhesive (i.e., fibers in bundles that are twisted, knitted, tacked at close intervals or are in non-woven layers have been found to be more difficult to wet than when the fibers are loosely laid in the bundles) and may have diameters that are sufficiently small so that almost all of the fibers in the bundles may be wetted by the adhesive when the tape is applied to a substrate.
The deniers of the individual fibers in bundles of fibers forming the scrim may generally be in the range of about 0.10 to 15 denier, about 0.75 to 10 denier, and about 1 to 5 denier; and the total of the deniers of the individual fibers in the bundles may generally be less than about 500, may be less than about 300 and may be about 100. It will be appreciated that many different materials, denier, and other thread constructions may be selected for other reinforcing layers that are equivalent, as is known, by one having ordinary skill in the textile arts to the foregoing description of reinforcing layer materials, physical characteristics and constructions.
In one exemplary embodiment of the present disclosure, a 25x7 threads per inch (cross web by down web) 115x150 denier (cross web by down web) polyester partial oriented yam (POY) scrim from American Fiber and Finishing, Inc., Newberry SC
had a warp drawn elongation value of 60% was used for the samples 25-31. It will be understood that a drawn down elongation value of about 60% provides a sufficiently stretchy elongation for a scrim. Such an elongation value is higher than that provided by known scrims used in reinforced adhesive duct tape articles, such as the scrim described in U.S. Patent No. 7,056,844. The polyester scrim described in the last noted patent may have had drawn down elongation value of about between to 20-25%. In contrast, the present disclosure envisions the use of POY scrim that may have greater elongation characteristics, for example, the polyester POY may have drawn down elongation values of greater than 30% to about 60% and, more typically, from about 40-60%
elongation. It is believed that the polyester POY scrim being drawn down to about 60%
elongation approaches an upper limit to the amount of extension permitted by a polyester POY scrim, of the type described above, and yet retains sufficient tensile strength to function as a scrim in an adhesive tape article, such as a duct tape while providing the advantages of the present invention.
According to the present description, whatever materials are selected and whatever processes are used to make the reinforcing layer, they should produce a reinforcing layer having the physical characteristics, described herein, for use in combination with a backing layer, as described herein, to produce the reinforced article having the characteristics of the present description.
In the present description, use may be made of a coated adhesive layer 18 that may substantially cover the reinforcing scrim layer 16. The thinner the fabric profile and the more space occupied by the fabric yams, the less adhesive covers the fabric spaces and surfaces. In one exemplary embodiment, the adhesive layer 18 is envisioned to be releasably securable to a substrate (not shown) to which the reinforced adhesive tape article 12 is to be attached. A variety of adhesives systems may be used for the adhesive layer in the present description. Given the intended use in a reinforced adhesive tape article 12 product, the present exemplary embodiment envisions use of a pressure-sensitive adhesive for adhesive layer 18. The pressure-sensitive adhesive may be of the type typically used with a duct tape. Accordingly, a wide variety of pressure-sensitive adhesive formulations exist. However, given the stretchy nature of the reinforced adhesive tape article 12, the thickness of the adhesive layer 18 should be adequate to allow for such stretching without losing the adhesive characteristics when applied.
In this regard, the adhesive layer 18 used in the following samples described in Table 3 may be a pressure sensitive adhesive comprised of a Kraton asymmetric block copolymer with a tackifier and plasticizer, dissolved to 45% solids in toluene. The procedure utilized to prepare the samples listed in Table 3 is as follows: (1) coat the above noted pressure sensitive adhesive solution to about 6 mils (0.015 cm) thick onto a siliconized release liner and dry for 10 minutes at 150 F (65 C) in a forced air oven, (2) laminate the scrim material by hand with the use of a six inch rubber ink pad roller to the dried pressure sensitive adhesive, (3) coat the noted pressure sensitive adhesive solution, that is 6 mils (0.015 cm) thick, onto the scrim composite from step (2)and dry for 10 minutes at 150 F (65 C) in a forced air oven, (4) corona treat the plastic film backing material samples with a hand held high frequency spark tester Model BD-20 available from Electro-Technic Products, Inc., Chicago, IL, and laminate to a pressure sensitive adhesive composite from step (3) with a 2 roll rubber squeeze laminator at about 20 psi (138 kPa).
It will be appreciated that exemplary pressure-sensitive adhesives may include removable and permanent adhesives. The pressure-sensitive adhesives contemplated for use may be selected from a group consisting of organic solvent based acrylics, waterborne acrylics, silicone adhesives, natural rubber based adhesives, and thermoplastic resin based adhesives. While the adhesive layer is coated it may be applied by other suitable approaches.
Table 3 illustrates experimental results comparing data of two different reinforced article constructions envisioned to be usable for a reinforced adhesive tape, such as a duct tape. One of the types of reinforced articles, see samples 17-23, include a listing of different backing materials, each of which has been laminated to a polyester scrim as described in U.S. Patent No. 7,056,844. The scrim used had an elongation value of about 20-25%. The other reinforced article type, see samples 25-31, includes the identified backing layer materials, as used in samples 17-23, but with a different reinforcing scrim layer made in accordance with the present description. As noted, in one exemplary embodiment of the present disclosure, a 25x7 threads per inch (cross web by down web) 115x150 denier (cross web by down web) polyester partial oriented yam scrim from American Fiber and Finishing, Inc. having a drawn elongation of about 60% was utilized.
Reference is made to U.S. Patent No. 6,211,099 for a description of the construction of such a scrim.
The present disclosure envisions use of a POY scrim having elongation values in the range of from about 30-60%, and from about 40-55%. The physical properties of the two reinforced articles listed in samples 17-23 were evaluated by measuring their tensile strength, modulus (Young's) of elasticity, and elongation properties. The results of this testing are shown by the data in the appropriate columns of Table 3, which columns also include the corresponding thicknesses (caliper total in mils) of the samples.

Table 3 Film Backing + Scrim Physical Properties: Tensile, Elongation & Young's Modulus . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . .
Sample Film + Scrim Caliper Tensile at Elon- Young's Total Break gation Modulus Mils cm lb/in ern at Break lb/ins MPa) ....................................
SCrim..........................................................................
...............................................................................
..........................................
0 (214)______ ............... 1................. Fina Z9470___________________________________________7_i_(0 018)_____________22 2 (3 __________ 22% 0 3100 .............:...
______________........................... uEont ElyaloyTM 1209AC________ 7.4( 0; 019 ____________ 14 7 (25 ) ....... 20%____________ 19=000 (131 ......
19_______________Dunont ,ElvaloyTM 3217AC_________~.0_~0 ------------------------------........... "I'll" ..... ............. 6 0__(0 015)............. 18 4__(32 ____________________ 22% 21 000 (145 ..........
00.303)______ .............. 1___________...... ScotchcalTM_8220-114........
(0;013____________23.1 (40;4___________________ 25%0... 44... .
..................
..............22 ................. 3M
SBOPP_________________________________________ 4 3_(0 011 ____________37 __________ 69% 71 000 (490)______ ................
--,""23 Pliant Pliant GF,10 LDPE _______________________ 5 5__(0;
014)__________ 18 3__(3 2Ø ___________________ 23 % 23 000 (15 8)______.
Partial Oriented Scrim .............25..............._Fina 29470...............
.........................._......~0;018 ..........._21.2.~36_9~.....................42% .......... ...59... .
00..(407)....._ .........
.............. 26__________...... Dupont E1valoyTM 1209AC_____7 4 019)_____________ 19 4. ........... 45%_________412090_(283)---.............. 27 Dupont ElvaloyTM 3217AC 7.0 (0;918)____________ 18.3_(32 6~
41% 35,000 (241 ____________2g________________Dow6109T
_______________________________________1116-101,(q-,q!5) ____________ 19,2 X33, __________45 0 48,000031 _29________________ScotchaTM,8220-114 23,2 (40;6____________________53%0 73 000 (503 .............. 30........... ..._3M_SBOPP...............
............................
..........._49.9.~g7.4)...................._59%0................_124,000 (855)...._ 31 Pliant GF,10 LOPE 5.5 (0;014 21; 6 (37 8) 52% 54 000 (372 z..
........ . . ....... .....................
Note: Tensile and Elongation test at 5 inch (12.7 cm) gauge length and 5 inch/min (12.7 cm/min) separation rate. Modulus properties of the duct tape utilized a 5 inch (12.7 cm) gauge at 0.5 in/min (1.3 cm/min) separation rate.

The results of tensile, modulus, and elongation testing demonstrate that the physical properties of the polyester partial oriented yam (POY) scrim having a drawn down elongation of about 60% effected control over the elongation properties of the reinforced article. As noted, the backing layer 14 had significant elongation values, but were far less extensive when used in combination with the reinforcing scrim layer 16. The reinforcing scrim layer may be used to provide a reinforced article that exhibits the degree of elongation provided by the present description along with tensile strength to enable hand tearability, conformability, and elastic recovery.
From the data of Table 3, the elongation at break values for the known scrim (see samples 17-23) and the backing layers using polyolefin was in a range of about 18 to 25 %, with tensile at break from about 13 to 25 pounds/inch (31 to 44 N/cm). In contrast, the range of elongation at break values for samples 25-31 using the partial oriented polyester scrim (POY) being drawn down to 60% elongation and polyolefin backing layers was about 60%, with tensile at break values from about 13 to 25 pounds/inch (31 to 44 N/cm).
It will be noted that while the reinforced article 10 (sample 30) exhibited twice as much elongation as sample 22, the biaxial oriented polypropylene (3M O-PP) film is considered too stiff to be useful in a reinforced adhesive article due its significantly higher modulus of elasticity (Young's) values.
As observed, the reinforced article comprising a backing layer and a partial oriented polyester scrim (POY) layer combination exhibited twice the degree of elongation as the combination of the known scrim and the backing layers without diminishing other physical properties useful in forming an adhesive article, such as a duct tape.
When the materials of the backing layer were combined with the POY reinforcing scrim layer in a reinforced article 12, the significantly higher elongation values of the backing layer decreased markedly from about 300-500% to 20-50%. It has been determined that the composition of the plastic backing film and the reinforcing layer influence both tensile strength and elongation properties of the reinforced article. As evident, the reinforced article constructions with a scrim made of partial oriented yam using a 60% elongation (i.e., samples 25-31), demonstrated approximately two (2) times greater elongation compared to constructions with the known scrim, samples 17-23.
However, it is noted that the elongation values for both the known and partially oriented yam (POY) scrim and 3M oriented propylene (O-PP) (samples 22 and 30) were almost equivalent.
Samples shown in Table 4 were prepared by hot melt coating a 100% solid natural rubber base adhesive formulated with a tackifier and plasticizer to yield adhesion and shear properties typical for commercially available duct tapes, at a coating weight of 35 grains per 24 square inches (164 gram per square meter), to form a pressure sensitive tape.
Sample 32 was made with a 3.2 mil (0.008 cm) thick low density polyethylene film from Pliant Corporation (called P1) having a tensile of 9.2 lbs/inch (16.1 N/cm), elongation of 494%, and modulus of 31,000 psi (214 MPa) and with an elongated partial oriented polyester scrim (POY) AF&F 25X7 threads per inch (96/150 Denier), 60% drawn elongation (POY-60%). Sample 33 was made with a film sample and with a known polyester scrim AF&F 25X7 (70/150 Denier) having less than about 30% drawn down elongation commercially available from American Fabric and Finishing, Inc.
Sample 34 was made with a 2.5 mil (0.006 cm) thick low density polyethylene, linear low density polyethylene blend film from Pliant Corporation (called P2) having an elongation tensile of 13.7 lbs/inch (23.8 N/cm), elongation of 754%, and modulus of 10,000 psi (69 MPa) and with a partial oriented polyester yam (POY) scrim AF&F 25X7 threads per inch (96/150 Denier), warp drawn 60% elongation.
Tensile, elongation and modulus test results for the example duct tapes are shown in Table 4. This testing demonstrated that no significant differences were observed in tensile, elongation, or modulus measurements between sample 32 and sample 34.
However, compared to sample 33 having scrim described in U.S. Patent No.
7,056,844, the samples 32 and 34 with a POY-60% scrim, exhibit approximately two (2) times higher elongation (stretch) as demonstrated by their corresponding elongation at break values.
Also, sample 33 exhibited about 50% less elongation than the samples 32 and 34, as determined by the values in the elongation at break column. The modulus measurements of Table 4 show no significant differences between the various film and scrim combinations of duct tape constructions.

Table 4 Duct Tape Physical Properties: Tensile, Elongation & Young's Modulus . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . .
Sample Film + Scrim Caliper Tensile at Elon- Young's Total Break gation Modulus mils lb/in at lb/in2 (cm) (N/cm) Break (MPa) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . .
32 P2 + POY Scrim 6.0 23.7 58% 56,000 (0.015) (41.5) (386) 33 P2 + Std Scrim 6.0 37.3 22% 60,000 (0.015) (65.3) (414) 34 P1 + POY Scrim 5.0 20.4 54% 62,000 (0.013) (35.7) (427) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . .
Note: Tensile and Elongation test at 2 inch (5.1 cm)gauge length and 20 inch/min (50.8 cm/min)separation rate.

Elastic recovery properties, which measures cinchability of the duct tapes (samples 32 thru 34), were measured according to test method ASTM D5459-95. The elastic properties of the above constructions were determined by subjecting the samples to specified extensions and measuring the quantity of recovery and permanent change with respect to the original samples dimensions. For this testing, elastic recovery measurements were made up to extension at break for each of the specimens.
The results of this testing are shown in Chart 1. The tape sample with known scrim, sample 33, broke at 22% elongation. Duct tape samples with the polyester POY-60% elongated scrim, that is samples 32 and 34, demonstrated elongation up to 58% to 54%; respectively before breaking, which confirms test results previously discussed.
Because of the enhanced elastic recovery provided thereby, these samples were highly conformable and cinchable, especially when compared to known duct tape constructions.
However, the one significant difference of this test method compared to elongation or modulus testing is that it demonstrated the effect or influence of film backing properties with respect to overall duct tape physical properties containing scrim. Sample 34 with the higher elongation film backing exhibited significantly higher elastic recovery compared to sample 32 with the known LDPE film backing. The elastic recovery test results indicate that sample 34, with higher recovery values, will have better "cinching" or "snugness"
properties as related to tape applications, such as hoses, tubing and packaging boxes. The data illustrate an elastic recovery from about 80 to 90% with an elongation extension to break from about 20% to 60%.

Chart 1 Elastic Recovery for Standard versus Conformable Duct Tape Constructions of the Present description.

ASTM D5459 Elastic Recovery Comparison #32 #33 100% 98%
...............................................................................
..................... sa% 0434 sa%

96%9 95% 94% 94% 94%

90% -- ----- ----- ------ --- 88% -- ------- -------X

U
85%
85% t 83%
MI MIN
80 /o XIk IN IN
\X m X\ 011 75% ry Y a 10% 15% 20% 25% 35% 50% 55%
Elongation Extension to Break From the foregoing chart, it can be determined that the samples of the present disclosure Sample 32 (POY-60%) scrim and backing film sample P1) as well as sample 34 (POY-60%) scrim and higher elongation backing film Sample P2) outperform the duct tape construction Sample 33. Samples 32 and 34 provide for enhanced elongation to break beyond the control samples as well as exhibit significantly enhanced elastic recovery, thereby providing for enhanced cinchability.
The above experimental data illustrated in the above Tables and chart demonstrate the materials used and the dramatic effect brought about by the improved reinforced article 10 on the ability of the reinforced adhesive tape article 12 to provide improved stretchable, hand-tearable, conformable, and cinchable properties for reinforced adhesive tape articles relative to known reinforced adhesive tape articles.
The present disclosure may take on various modifications and alterations without departing from the spirit and scope. Accordingly, this disclosure is not limited to the above-described embodiments, but is to be controlled by limitations set forth in the following claims and any equivalents thereof.

The present disclosure may also be suitably practiced in the absence of any element not specifically disclosed herein. All patents and publications noted above, including any in the Background section are incorporated by reference into this document in total.

Claims

1. A conformable reinforced article adapted to be used in combination in a reinforced tape, the reinforced article comprising: an elastomeric polymeric backing layer having opposing first and second major surfaces; and, an elastomeric polymeric reinforcing material layer carried along at least one of the first and second major surfaces, wherein the backing layer and the reinforcing material layer of the reinforced article exhibit an elongation extension at break of about at least about 25 to 60%, and tensile strength greater than about 10 lb/in (17 N/cm) at break.

2. The reinforced article of claim 1, further comprising an adhesive layer disposed in generally covering relationship to the reinforcing material layer for forming a reinforced tape.

3. The reinforced article of claim 1, wherein the tensile strength of the reinforced article is between about 20 to 40 lb/in (35 to 70 N/cm) for hand-tearability.

4. The reinforced article of claim 3, wherein the reinforced article exhibits an elastic recovery from about 80 to 90% with an elongation extension to break from about 20% to 60%.

5. The reinforced article of claim 1, further wherein the backing layer exhibits an elongation extension at break of at least greater than 50%.

6. The reinforced article of claim 1, further wherein the backing layer exhibits an elongation extension at break of about 300 to 500%.

7. The reinforced article of claim 1, wherein the reinforcing material layer is made of a reinforcing scrim material that is highly extensible.

8. The reinforced article of claim 7, wherein the reinforcing scrim material is from a group of materials that consists of fiberglass, acetate, acrylic, modacrylics, rayon, nylon, polyester, cotton, polyethylene, polypropylene, polyamine, Kevlar, and any combination thereof.

9. The reinforced article of claim 8, wherein the reinforcing scrim material is made of partially oriented yam having a drawn down elongation value in a range of from about greater than 30% to about 60%.

10. The reinforced article of claim 9, wherein the partially oriented yam reinforcing scrim has a drawn down elongation value in a range of from about 40% to about 55%.

11. The reinforced article of claim 1, wherein the polymeric material for the backing layer is from a group consisting of polyolefin elastomers, polypropylene elastomers, polyvinyl elastomers, polyurethane elastomers, and any combination thereof.

12. The reinforced article of claim 11, wherein the backing layer has a thickness of about 1.0 mil to about 7.0 mils (0.002 cm to about 0.018 cm).

13. The reinforced article of claim 2, wherein the adhesive layer includes a pressure-sensitive material.

14. The reinforced article of claim 13, wherein the pressure sensitive material is from a group consisting of. natural rubber, synthetic rubber, synthetic elastomers, acrylates, and blends thereof.