CA2641757A1 - Chemical reactor and method for catalytic gas phase reactions - Google Patents

Chemical reactor and method for catalytic gas phase reactions Download PDF

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Publication number
CA2641757A1
CA2641757A1 CA002641757A CA2641757A CA2641757A1 CA 2641757 A1 CA2641757 A1 CA 2641757A1 CA 002641757 A CA002641757 A CA 002641757A CA 2641757 A CA2641757 A CA 2641757A CA 2641757 A1 CA2641757 A1 CA 2641757A1
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compartment
reaction chamber
chamber
gaseous reactant
catalyst material
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French (fr)
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CA2641757C (en
Inventor
Anna Lee Y. Tonkovich
Yong Wang
Sean P. Fitzgerald
Jennifer L. Marco
Gary L. Roberts
David P. Vanderwiel
Robert S. Wegeng
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Battelle Memorial Institute Inc
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    • C—CHEMISTRY; METALLURGY
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    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
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Abstract

The present invention provides chemical reactors and reaction chambers and methods for conducting catalytic chemical reactions having gas phase reactants. In preferred embodiments, these reaction chambers and methods include at least one porous catalyst material that has pore sizes large enough to permit molecular diffusion within the porous catalyst material.

Claims (10)

1. A chemical reactor comprising:

at least one reaction chamber comprising catalyst rods, plates or baffles having a length to thickness ratio of at least 10, and wherein each of said at least one reaction chamber has an internal volume defined by reaction chamber walls;

wherein said internal volume has dimensions of chamber height, chamber width and chamber length;
wherein said at least one reaction chamber comprises a chamber height or chamber width that is about
2 mm or less; and wherein said catalyst rods, plates or baffles are disposed in said reaction chamber such that the pressure drop across the reaction chamber is less than 20% of the total system inlet pressure.

2. The reactor of claim 1 wherein said at least one reaction chamber comprises fibers or baffles and said fibers or baffles comprise said porous catalyst material.
3. A method of conducting a chemical reaction in a chemical reactor comprising:

passing a gaseous reactant into a first compartment of a reaction chamber;

wherein said reaction chamber comprises a porous catalyst material, a first compartment and a second compartment;

wherein said first compartment has an internal volume wherein said internal volume has dimensions of compartment height, compartment width and compartment length;

wherein said first compartment comprises a compartment height or chamber compartment that is about 2 mm or less;

wherein said porous catalyst material is disposed between said first compartment and said second compartment;
wherein said gaseous reactant reacts within said porous catalyst material to form at least one product; and wherein said first compartment and said second compartment comprise open spaces that permit bulk flow of a gas.
4. The method of claim 3 wherein said at least one product passes into the second compartment.
5. The method of claim 3 further comprising passing a second gaseous reactant into the second compartment, wherein the gaseous reactant from the second compartment travels into the porous catalyst material and reacts with the gaseous reactant from the first compartment.
6. A method of conducting a chemical reaction in a reaction chamber of a chemical reactor comprising:
passing a gaseous reactant into a first and/or second compartment;

wherein a partition is disposed between the first compartment and the second compartment;

wherein said partition comprises a fluid distribution layer or a separating agent;

wherein said first compartment has an internal volume wherein said internal volume has dimensions of compartment height, compartment width and compartment length;

wherein said first compartment comprises a compartment height or compartment width that is about 2 mm or less;

wherein said first compartment comprises a porous catalyst material;

wherein a gas travels through said partition; and wherein said first compartment comprises at least one open space that permits bulk flow of a gas;

wherein the reaction chamber exchanges heat with another channel; and wherein the reaction chamber and the other channel have a heat flux of at least 0.6 w per cubic centimeter.
7. The method of claim 6 wherein said second compartment comprises at least one open space that permits bulk flow of a gas, and said partition comprises a flow distribution layer;

wherein said gaseous reactant convectively travels through the flow distribution layer from the first to the second compartment;

wherein said gaseous reactant, after traveling through said flow distribution sheet, reacts in a porous catalyst material contained within the second compartment.
8. The method of claim 6 wherein said second compartment comprises at least one open space that permits bulk flow of a gas, and said partition comprises a separating agent selected from the group consisting of a membrane and a sorbent.
9. The method of claim 6 wherein said chemical reactor comprises multiple reaction chambers arranged in parallel or in series; and comprising passing a gaseous reactant into the first compartment of multiple reaction chambers.
10. The method of claim 8 wherein said separating agent comprises a palladium membrane, and wherein said method comprises continually removing hydrogen through the palladium membrane.
CA2641757A 1999-08-17 2000-08-17 Chemical reactor and method for catalytic gas phase reactions Expired - Fee Related CA2641757C (en)

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US09/375,614 US6488838B1 (en) 1999-08-17 1999-08-17 Chemical reactor and method for gas phase reactant catalytic reactions
US09/375,614 1999-08-17
US09/640,903 US6680044B1 (en) 1999-08-17 2000-08-16 Method for gas phase reactant catalytic reactions
US09/640,903 2000-08-16
CA002381154A CA2381154C (en) 1999-08-17 2000-08-17 Chemical reactor and method for catalytic gas phase reactions

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Families Citing this family (166)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6440895B1 (en) 1998-07-27 2002-08-27 Battelle Memorial Institute Catalyst, method of making, and reactions using the catalyst
US6616909B1 (en) * 1998-07-27 2003-09-09 Battelle Memorial Institute Method and apparatus for obtaining enhanced production rate of thermal chemical reactions
US6946111B2 (en) * 1999-07-30 2005-09-20 Conocophilips Company Short contact time catalytic partial oxidation process for recovering sulfur from an H2S containing gas stream
US6800269B2 (en) * 1999-07-30 2004-10-05 Conocophillips Company Short contact time catalytic sulfur recovery system for removing H2S from a waste gas stream
US6403051B1 (en) * 1999-07-30 2002-06-11 Conoco Inc. Recovery of sulfur from H2S and concurrent production of H2 using short contact time CPOX
AU778040B2 (en) * 1999-08-17 2004-11-11 Battelle Memorial Institute Catalyst structure and method of fischer-tropsch synthesis
US6969506B2 (en) * 1999-08-17 2005-11-29 Battelle Memorial Institute Methods of conducting simultaneous exothermic and endothermic reactions
US6488838B1 (en) * 1999-08-17 2002-12-03 Battelle Memorial Institute Chemical reactor and method for gas phase reactant catalytic reactions
US6451864B1 (en) * 1999-08-17 2002-09-17 Battelle Memorial Institute Catalyst structure and method of Fischer-Tropsch synthesis
EP1206316B1 (en) * 1999-08-17 2005-06-29 Battelle Memorial Institute Chemical reactor and method for catalytic gas phase reactions
FR2807746B1 (en) * 2000-04-13 2002-12-13 Air Liquide METHOD FOR PRODUCING A MIXTURE COMPRISING HYDROGEN AND CO
US7125540B1 (en) * 2000-06-06 2006-10-24 Battelle Memorial Institute Microsystem process networks
US7122170B2 (en) * 2000-07-25 2006-10-17 Conocophillips Company Catalysts for SPOC™ enhanced synthesis gas production
WO2002103268A2 (en) * 2000-07-28 2002-12-27 Honda Giken Kogyo Kabushiki Kaisha Multi-purpose microchannel micro-component
US7326397B2 (en) * 2000-12-18 2008-02-05 Conocophillips Company Catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream
US7357908B2 (en) * 2000-12-18 2008-04-15 Conocophillips Company Apparatus and catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream
US7118917B2 (en) * 2001-03-07 2006-10-10 Symyx Technologies, Inc. Parallel flow reactor having improved thermal control
US6630012B2 (en) * 2001-04-30 2003-10-07 Battelle Memorial Institute Method for thermal swing adsorption and thermally-enhanced pressure swing adsorption
US6503298B1 (en) * 2001-04-30 2003-01-07 Battelle Memorial Institute Apparatus and methods for hydrogen separation/purification utilizing rapidly cycled thermal swing sorption
US6746515B2 (en) 2001-04-30 2004-06-08 Battelle Memorial Institute Method and apparatus for thermal swing adsorption and thermally-enhanced pressure swing adsorption
US6863867B2 (en) * 2001-05-07 2005-03-08 Uop Llc Apparatus for mixing and reacting at least two fluids
FR2826293B1 (en) * 2001-06-21 2004-01-30 Elf Antar France PROCESS FOR OBTAINING SYNTHESIS GAS BY PARTIAL CATALYTIC OXIDATION
GB0116894D0 (en) * 2001-07-11 2001-09-05 Accentus Plc Catalytic reactor
US7326669B2 (en) * 2001-09-20 2008-02-05 Honda Motor Co., Ltd. Substrate having catalyst compositions on surfaces of opposite sides
BR0213170B1 (en) * 2001-10-12 2012-08-07 catalytic reactor and method for steam reforming a hydrocarbon.
GB0124999D0 (en) * 2001-10-18 2001-12-05 Accentus Plc Catalytic reactor
GB0125035D0 (en) * 2001-10-18 2001-12-12 Accentus Plc Catalytic reactor
GB0129054D0 (en) * 2001-12-05 2002-01-23 Accentus Plc Catalytic reactor and process
US20050171217A1 (en) * 2001-12-05 2005-08-04 Bowe Michael J. Process and apparatus for steam-methane reforming
CA2478333C (en) 2002-03-11 2013-10-15 Battelle Memorial Institute Microchannel reactors with temperature control
US6746657B2 (en) * 2002-03-12 2004-06-08 Precision Combustion, Inc. Method for reduced methanation
US8206666B2 (en) * 2002-05-21 2012-06-26 Battelle Memorial Institute Reactors having varying cross-section, methods of making same, and methods of conducting reactions with varying local contact time
US7402719B2 (en) * 2002-06-13 2008-07-22 Velocys Catalytic oxidative dehydrogenation, and microchannel reactors for catalytic oxidative dehydrogenation
US9192929B2 (en) 2002-08-15 2015-11-24 Velocys, Inc. Integrated combustion reactor and methods of conducting simultaneous endothermic and exothermic reactions
US6969505B2 (en) * 2002-08-15 2005-11-29 Velocys, Inc. Process for conducting an equilibrium limited chemical reaction in a single stage process channel
AU2003256422A1 (en) * 2002-08-15 2004-03-03 Velocys, Inc. Tethered catalyst processes in microchannel reactors and systems containing a tethered catalyst or tethered chiral auxiliary
US7250151B2 (en) * 2002-08-15 2007-07-31 Velocys Methods of conducting simultaneous endothermic and exothermic reactions
US6622519B1 (en) * 2002-08-15 2003-09-23 Velocys, Inc. Process for cooling a product in a heat exchanger employing microchannels for the flow of refrigerant and product
US7014835B2 (en) * 2002-08-15 2006-03-21 Velocys, Inc. Multi-stream microchannel device
US7118920B2 (en) * 2002-10-22 2006-10-10 Battelle Memorial Institute Multiphasic microchannel reactions
US7404936B2 (en) * 2002-10-22 2008-07-29 Velocys Catalysts, in microchannel apparatus, and reactions using same
US20040112571A1 (en) * 2002-11-01 2004-06-17 Cooligy, Inc. Method and apparatus for efficient vertical fluid delivery for cooling a heat producing device
US8464781B2 (en) * 2002-11-01 2013-06-18 Cooligy Inc. Cooling systems incorporating heat exchangers and thermoelectric layers
US20050211418A1 (en) * 2002-11-01 2005-09-29 Cooligy, Inc. Method and apparatus for efficient vertical fluid delivery for cooling a heat producing device
GB0314790D0 (en) * 2003-06-25 2003-07-30 Accentus Plc Catalytic reactor and process
US7326394B2 (en) * 2003-03-07 2008-02-05 Velocys Catalysts, methods of making catalysts, and methods of combustion
US20040182551A1 (en) * 2003-03-17 2004-09-23 Cooligy, Inc. Boiling temperature design in pumped microchannel cooling loops
US7405338B2 (en) * 2003-04-07 2008-07-29 Velocys Dehydrogenation reactions in narrow reaction chambers and integrated reactors
US7294734B2 (en) 2003-05-02 2007-11-13 Velocys, Inc. Process for converting a hydrocarbon to an oxygenate or a nitrile
US7220390B2 (en) * 2003-05-16 2007-05-22 Velocys, Inc. Microchannel with internal fin support for catalyst or sorption medium
CA2526965C (en) * 2003-05-16 2011-10-11 Velocys Inc. Process for forming an emulsion using microchannel process technology
WO2004104140A1 (en) * 2003-05-16 2004-12-02 Battelle Memorial Institute Rapid start fuel reforming systems and techniques
US8580211B2 (en) * 2003-05-16 2013-11-12 Velocys, Inc. Microchannel with internal fin support for catalyst or sorption medium
US7485671B2 (en) * 2003-05-16 2009-02-03 Velocys, Inc. Process for forming an emulsion using microchannel process technology
US20050203195A1 (en) * 2003-08-05 2005-09-15 Yong Wang Tailored Fischer-Tropsch synthesis product distribution
JP4578867B2 (en) * 2003-09-30 2010-11-10 株式会社日立製作所 Hydrogen storage / supply device and system thereof, distributed power source using the same, and automobile
US8066955B2 (en) * 2003-10-17 2011-11-29 James M. Pinchot Processing apparatus fabrication
US7470408B2 (en) * 2003-12-18 2008-12-30 Velocys In situ mixing in microchannels
US7029647B2 (en) * 2004-01-27 2006-04-18 Velocys, Inc. Process for producing hydrogen peroxide using microchannel technology
US7084180B2 (en) * 2004-01-28 2006-08-01 Velocys, Inc. Fischer-tropsch synthesis using microchannel technology and novel catalyst and microchannel reactor
US9023900B2 (en) 2004-01-28 2015-05-05 Velocys, Inc. Fischer-Tropsch synthesis using microchannel technology and novel catalyst and microchannel reactor
US20050175519A1 (en) 2004-02-06 2005-08-11 Rogers William A.Jr. Microchannel compression reactor
US8747805B2 (en) * 2004-02-11 2014-06-10 Velocys, Inc. Process for conducting an equilibrium limited chemical reaction using microchannel technology
US7520917B2 (en) * 2004-02-18 2009-04-21 Battelle Memorial Institute Devices with extended area structures for mass transfer processing of fluids
JP4580664B2 (en) * 2004-03-01 2010-11-17 大日本印刷株式会社 Microreactor and manufacturing method thereof
KR100828489B1 (en) * 2004-03-01 2008-05-13 다이니폰 인사츠 가부시키가이샤 Micro?reactor and method of manufacturing the same
US8378163B2 (en) 2004-03-23 2013-02-19 Velocys Corp. Catalysts having catalytic material applied directly to thermally-grown alumina and catalytic methods using same, improved methods of oxidative dehydrogenation
JP4590202B2 (en) * 2004-04-02 2010-12-01 日産自動車株式会社 Fuel reforming reactor
US7572432B2 (en) * 2004-04-13 2009-08-11 General Electric Company Method and article for producing hydrogen gas
US7304198B2 (en) * 2004-05-14 2007-12-04 Battelle Memorial Institute Staged alkylation in microchannels
US7305850B2 (en) * 2004-07-23 2007-12-11 Velocys, Inc. Distillation process using microchannel technology
JP5627837B2 (en) 2004-07-23 2014-11-19 ヴェロシス，インク． Distillation process using microchannel technology
CA2575165C (en) 2004-08-12 2014-03-18 Velocys Inc. Process for converting ethylene to ethylene oxide using microchannel process technology
US8517717B2 (en) * 2004-08-13 2013-08-27 Velocys, Inc. Detonation safety in microchannels
WO2006039568A1 (en) 2004-10-01 2006-04-13 Velocys Inc. Multiphase mixing process using microchannel process technology
DE102004050506A1 (en) * 2004-10-15 2006-04-20 Degussa Ag Process for the preparation of olefin oxides and peroxides, reactor and its use
US7468455B2 (en) * 2004-11-03 2008-12-23 Velocys, Inc. Process and apparatus for improved methods for making vinyl acetate monomer (VAM)
CA2586971C (en) 2004-11-12 2013-07-23 Velocys Inc. Process using microchannel technology for conducting alkylation or acylation reaction
WO2006055609A1 (en) 2004-11-16 2006-05-26 Velocys Inc. Multiphase reaction process using microchannel technology
US20060120213A1 (en) * 2004-11-17 2006-06-08 Tonkovich Anna L Emulsion process using microchannel process technology
US7569085B2 (en) * 2004-12-27 2009-08-04 General Electric Company System and method for hydrogen production
US7485161B2 (en) * 2005-01-04 2009-02-03 Air Products And Chemicals, Inc. Dehydrogenation of liquid fuel in microchannel catalytic reactor
KR20060080385A (en) 2005-01-05 2006-07-10 삼성에스디아이 주식회사 Fuel cell system, reformer, reaction substrate and manufacturing method of the reaction substrate
DE102005004075B4 (en) * 2005-01-28 2008-04-03 Umicore Ag & Co. Kg Ceramic microreactor
GB0501731D0 (en) * 2005-01-31 2005-03-02 Accentus Plc Catalytic reactor
US7507274B2 (en) 2005-03-02 2009-03-24 Velocys, Inc. Separation process using microchannel technology
EP1861478B1 (en) * 2005-03-16 2012-02-22 Fuelcor LLC Systems and methods for production of synthetic hydrocarbon compounds
WO2006127889A2 (en) 2005-05-25 2006-11-30 Velocys Inc. Support for use in microchannel processing
US7862331B2 (en) * 2005-06-17 2011-01-04 University Of Delaware Catalytic microcombustors for compact power or heat generation
US8216323B2 (en) * 2005-06-30 2012-07-10 General Electric Company System and method for hydrogen production
US20070004810A1 (en) * 2005-06-30 2007-01-04 Yong Wang Novel catalyst and fischer-tropsch synthesis process using same
WO2007008495A2 (en) 2005-07-08 2007-01-18 Velocys Inc. Catalytic reaction process using microchannel technology
ES2380231T3 (en) * 2005-08-31 2012-05-09 Fmc Corporation Production by hydrogen peroxide autoxidation by oxidation of a microreactor
JP2009529479A (en) * 2005-08-31 2009-08-20 エフ エム シー コーポレーション Autooxidation of hydrogen peroxide by hydrogenation in a microreactor
US7943547B2 (en) * 2005-09-14 2011-05-17 Hamilton Sundstrand Space Systems International, Inc. Selective catalytic oxidation of ammonia to water and nitrogen
JP5081830B2 (en) * 2005-10-13 2012-11-28 ヴェロシス インコーポレイテッド Electroless plating in microchannels
US20070203352A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070197801A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process
FR2895405A1 (en) * 2005-12-22 2007-06-29 Shell Int Research PROCESS FOR THE PREPARATION OF AN OLEFIN OXIDE OR A CHEMICAL PRODUCING OLEFIN OXIDE
US20070151451A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the cooling, concentration or purification of ethylene oxide
US20070203350A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US7459589B2 (en) * 2005-12-22 2008-12-02 Shell Oil Company Process for the preparation of an alkylene glycol
US20070197808A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203349A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070213545A1 (en) * 2005-12-22 2007-09-13 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US7750170B2 (en) * 2005-12-22 2010-07-06 Shell Oil Company Process for mixing an oxidant having explosive potential with a hydrocarbon
US20070154377A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the removal of combustible volatile contaminant materials from a process stream
US7913719B2 (en) * 2006-01-30 2011-03-29 Cooligy Inc. Tape-wrapped multilayer tubing and methods for making the same
US7226572B1 (en) 2006-03-03 2007-06-05 Conocophillips Company Compact sulfur recovery plant and process
CN102836675B (en) * 2006-03-23 2016-06-15 万罗赛斯公司 A kind of device
EP2024078A2 (en) * 2006-04-20 2009-02-18 Velocys, Inc. Process for treating and/or forming a non-newtonian fluid using microchannel process technology
US7709541B2 (en) * 2006-07-14 2010-05-04 Headwaters Technology Innovation, Llc Fischer-Tropsch catalysts incorporating promoter for increasing yields of C5+ hydrocarbons and methods for making and using same
US20080041764A1 (en) * 2006-08-18 2008-02-21 Linde Aktiengesellschaft Method and apparatus for steam dealkylation in a plant for the catalytic splitting of hydrocarbons
US7501111B2 (en) 2006-08-25 2009-03-10 Conoco Phillips Company Increased capacity sulfur recovery plant and process for recovering elemental sulfur
US7999144B2 (en) 2006-09-01 2011-08-16 Velocys Microchannel apparatus and methods of conducting catalyzed oxidative dehydrogenation
US8497308B2 (en) 2006-09-05 2013-07-30 Velocys, Inc. Integrated microchannel synthesis and separation
US7820725B2 (en) 2006-09-05 2010-10-26 Velocys, Inc. Integrated microchannel synthesis and separation
US8592220B2 (en) * 2006-10-26 2013-11-26 Intermolecular, Inc. High pressure parallel fixed bed reactor and method
US20080154051A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
US20080154052A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
JP5222303B2 (en) * 2006-12-21 2013-06-26 セラマテック・インク Catalytic microchannel reformer
US7923592B2 (en) 2007-02-02 2011-04-12 Velocys, Inc. Process for making unsaturated hydrocarbons using microchannel process technology
JP5013514B2 (en) * 2007-02-09 2012-08-29 国立大学法人東京工業大学 Microreactor and catalytic reaction method
US8034985B2 (en) * 2007-02-15 2011-10-11 Honeywell International, Ltd. Catalyst for the synthesis of CF3CF2I
US8603407B2 (en) 2007-03-21 2013-12-10 Precision Combustion, Inc. Catalytic isobutane alkylation
GB0718398D0 (en) * 2007-09-21 2007-10-31 Robert Gordon The University Process for the production of alcohols
US20090225514A1 (en) * 2008-03-10 2009-09-10 Adrian Correa Device and methodology for the removal of heat from an equipment rack by means of heat exchangers mounted to a door
US8071836B2 (en) * 2008-03-13 2011-12-06 Fina Technology, Inc. Process for toluene and methane coupling in a microreactor
US7745667B2 (en) * 2008-04-07 2010-06-29 Velocys Microchannel apparatus comprising structured walls, chemical processes, methods of making formaldehyde
US8100996B2 (en) * 2008-04-09 2012-01-24 Velocys, Inc. Process for upgrading a carbonaceous material using microchannel process technology
AU2009233786B2 (en) * 2008-04-09 2014-04-24 Velocys Inc. Process for converting a carbonaceous material to methane, methanol and/or dimethyl ether using microchannel process technology
US7935259B2 (en) * 2008-07-03 2011-05-03 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Filtering apparatus and method of use
US8343403B2 (en) * 2008-07-16 2013-01-01 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Method for making a microporous membrane
US8254422B2 (en) * 2008-08-05 2012-08-28 Cooligy Inc. Microheat exchanger for laser diode cooling
US20100081577A1 (en) * 2008-09-30 2010-04-01 Symyx Technologies, Inc. Reactor systems and methods
CA2739325C (en) 2008-10-10 2018-11-27 Velocys Inc. Process and apparatus employing microchannel process technology
JP2010210118A (en) * 2009-03-09 2010-09-24 Jamco Corp Passenger plane mounted steam oven including safety valve for water leakage prevention purposes
US20110083997A1 (en) * 2009-10-09 2011-04-14 Silva Laura J Process for treating heavy oil
GB201000156D0 (en) * 2010-01-07 2010-02-24 Gas2 Ltd Isothermal reactor for partial oxidisation of methane
US9950305B2 (en) 2011-07-26 2018-04-24 Battelle Memorial Institute Solar thermochemical processing system and method
GB201214122D0 (en) 2012-08-07 2012-09-19 Oxford Catalysts Ltd Treating of catalyst support
DE102012016561B4 (en) 2012-08-22 2019-05-16 Airbus Defence and Space GmbH Aircraft fuel cell system and use thereof
US9394170B2 (en) * 2013-03-12 2016-07-19 Battelle Memorial Institute Reactor incorporating a heat exchanger
US9676623B2 (en) 2013-03-14 2017-06-13 Velocys, Inc. Process and apparatus for conducting simultaneous endothermic and exothermic reactions
JP2016522809A (en) * 2013-04-18 2016-08-04 ハネウェル・インターナショナル・インコーポレーテッド Reaction system and method for producing fluorinated organic compounds
WO2015069749A2 (en) 2013-11-06 2015-05-14 Watt Fuel Cell Corp. Liquid fuel cpox reformers and methods of cpox reforming
US10676354B2 (en) 2013-11-06 2020-06-09 Watt Fuel Cell Corp. Reformer with perovskite as structural component thereof
US9627701B2 (en) 2013-11-06 2017-04-18 Watt Fuel Cell Corp. Integrated gaseous fuel CPOX reformer and fuel cell systems, and methods of producing electricity
JP6549600B2 (en) 2013-11-06 2019-07-24 ワット・フューエル・セル・コーポレイションＷａｔｔ Ｆｕｅｌ Ｃｅｌｌ Ｃｏｒｐ． Liquid fuel CPOX reformer and fuel cell integrated system and method of generating electricity
AU2014346741B2 (en) 2013-11-06 2017-01-19 Watt Fuel Cell Corp. Gaseous fuel CPOX reformers and methods of CPOX reforming
AU2014346844B2 (en) 2013-11-06 2017-06-15 Watt Fuel Cell Corp. Chemical reactor with manifold for management of a flow of gaseous reaction medium thereto
US9943819B2 (en) 2014-11-03 2018-04-17 Singh Instrument LLC Small-scale reactor having improved mixing
US10458716B2 (en) 2014-11-04 2019-10-29 Roccor, Llc Conformal thermal ground planes
US9937484B2 (en) 2015-01-30 2018-04-10 Battelle Memorial Institute Reactor, CO2 sorbent system, and process of making H2 with simultaneous CO2 sorption
WO2016201218A2 (en) 2015-06-12 2016-12-15 Velocys, Inc. Synthesis gas conversion process
WO2017138028A1 (en) * 2016-02-08 2017-08-17 Kt Kinetics Technology Spa Enhanced efficiency endothermic reactor for syngas production with flexible heat recovery to meet low export steam generation.
US10054140B2 (en) 2016-02-12 2018-08-21 Crystaphase Products, Inc. Use of treating elements to facilitate flow in vessels
US11059278B2 (en) * 2016-02-28 2021-07-13 Roccor, Llc Two-phase thermal management devices, methods, and systems
US10207241B2 (en) 2016-11-29 2019-02-19 Kontak LLC Inductively heated microchannel reactor
JP6663074B2 (en) * 2017-02-22 2020-03-11 アルプスアルパイン株式会社 Flow path chip and method for manufacturing flow path chip
CN108067172A (en) * 2018-01-17 2018-05-25 北京国能中林科技开发有限公司 The micro passage reaction and method of dehydrogenating of a kind of dehydrogenation reaction suitable for liquid hydrogen source material
US11555473B2 (en) 2018-05-29 2023-01-17 Kontak LLC Dual bladder fuel tank
US11638331B2 (en) 2018-05-29 2023-04-25 Kontak LLC Multi-frequency controllers for inductive heating and associated systems and methods
US11358111B2 (en) 2019-03-20 2022-06-14 Battelle Memorial Institute, Pacific Northwest National Laboratories Reactor assemblies and methods of performing reactions
JP7085431B2 (en) * 2018-07-13 2022-06-16 三菱重工エンジニアリング株式会社 Catalytic reactor
WO2022056154A1 (en) 2020-09-09 2022-03-17 Crystaphase Products, Inc. Process vessel entry zones

Family Cites Families (101)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4006102A (en) 1975-08-25 1977-02-01 Ford Motor Company Stabilized rhenium catalyst
JPS551816A (en) 1978-06-15 1980-01-09 Mitsubishi Rayon Co Ltd Vapor-liquid contactor
EP0025308B1 (en) 1979-09-06 1984-07-11 Imperial Chemical Industries Plc A process and apparatus for catalytically reacting steam with a hydrocarbon in endothermic conditions
CA1137962A (en) * 1980-05-20 1982-12-21 Martin Moskovits Heterogeneous catalyst and process for its manufacture
NL8200544A (en) 1982-02-12 1983-09-01 Veg Gasinstituut Nv METHOD FOR PREPARING METHANE FROM CARBON MONOXIDE-CONTAINING GAS MIXTURES USING CATALYSTS USING NICKEL
US4597947A (en) * 1983-06-30 1986-07-01 The United States Of America As Represented By The Secretary Of The Army Mass transfer and material separation microchannel plate apparatus
DE3435319A1 (en) 1984-09-26 1986-04-03 Michael 4150 Krefeld Laumen CATALYTIC STEAM GENERATOR
JPS61111140A (en) * 1984-11-06 1986-05-29 Toyota Central Res & Dev Lab Inc Catalyst for synthesizing hydrocarbon
DK156701C (en) * 1987-08-27 1990-01-29 Haldor Topsoe As PROCEDURE FOR IMPLEMENTING Heterogeneous CATALYTIC CHEMICAL REACTIONS
JPH0422827Y2 (en) 1987-09-25 1992-05-26
SE462143C (en) 1988-03-07 1996-01-18 Heraeus Gmbh W C Catalytic converter for car exhaust cleaning, process for its preparation and use thereof
DE3813946A1 (en) 1988-04-26 1989-11-09 Asea Brown Boveri METHOD FOR APPLYING A CATALYST LAYER COMPOSED OF PRECIOUS METALS AND / OR PRECAST METAL COMPOUNDS TO A CARRIER OF CERAMIC MATERIAL
EP0396650B2 (en) 1988-09-02 1995-04-12 GebràœDer Sulzer Aktiengesellschaft Device for carrying out catalytic reactions
US5440872A (en) 1988-11-18 1995-08-15 Pfefferle; William C. Catalytic method
US5051241A (en) 1988-11-18 1991-09-24 Pfefferle William C Microlith catalytic reaction system
US5047381A (en) 1988-11-21 1991-09-10 General Electric Company Laminated substrate for catalytic combustor reactor bed
JPH0380937A (en) * 1989-08-25 1991-04-05 Tonen Corp Steam reforming catalyst of hydrocarbon and preparation thereof
NL8902250A (en) * 1989-09-08 1991-04-02 Veg Gasinstituut Nv METHOD FOR PERFORMING A CHEMICAL REACTION AND REACTOR TO BE USED THERE
DZ1444A1 (en) * 1989-09-12 2004-09-13 Inst Francais Du Petrole Differential pressure drop oxidation process and reactor and its use.
AU661877B2 (en) 1990-04-03 1995-08-10 Standard Oil Company, The Endothermic reaction apparatus
RU2093261C1 (en) 1991-05-12 1997-10-20 Татьяна Николаевна Довбышева Method of preparing solid block catalyst for afterburning of hydrogen in presence of water vapor
JP2564739Y2 (en) * 1991-06-21 1998-03-09 石川島播磨重工業株式会社 Steam reformer
US5270127A (en) 1991-08-09 1993-12-14 Ishikawajima-Harima Heavy Industries Co., Ltd. Plate shift converter
JPH05105405A (en) 1991-10-21 1993-04-27 Ishikawajima Harima Heavy Ind Co Ltd Plate type reformer
IT1253064B (en) 1991-12-13 1995-07-10 Unicoat Srl COMPOSITE INSERT FOR CUTTING TOOLS
US5364711A (en) * 1992-04-01 1994-11-15 Kabushiki Kaisha Toshiba Fuel cell
US5846494A (en) * 1992-04-30 1998-12-08 Gaiser; Gerd Reactor for catalytically processing gaseous fluids
EP0574012B1 (en) 1992-06-10 1998-12-30 Shimadzu Corporation Exhaust gas catalytic purifier construction
TW216453B (en) * 1992-07-08 1993-11-21 Air Prod & Chem Integrated plate-fin heat exchange reformation
JPH06111838A (en) 1992-09-30 1994-04-22 Toshiba Corp Reformer, reforming system, and fuel cell system
AU5741594A (en) 1992-12-17 1994-07-04 Thermatrix Inc. Method and apparatus for control of fugitive voc emissions
US5426442A (en) 1993-03-01 1995-06-20 Aerojet-General Corporation Corrugated feed horn array structure
US5534328A (en) 1993-12-02 1996-07-09 E. I. Du Pont De Nemours And Company Integrated chemical processing apparatus and processes for the preparation thereof
JPH06287003A (en) * 1993-03-31 1994-10-11 Chubu Electric Power Co Inc Device for reforming fuel
JPH0729589A (en) 1993-07-09 1995-01-31 Ishikawajima Harima Heavy Ind Co Ltd Differential pressure control method of plate type reformer in fuel cell power generating system
US5387398A (en) 1993-12-03 1995-02-07 Aerojet General Corporation Supercritical water oxidation reactor with wall conduits for boundary flow control
US6040266A (en) 1994-02-22 2000-03-21 Ultramet Foam catalyst support for exhaust purification
US5422331A (en) 1994-02-25 1995-06-06 Engelhard Corporation Layered catalyst composition
US5512250A (en) 1994-03-02 1996-04-30 Catalytica, Inc. Catalyst structure employing integral heat exchange
JP3599370B2 (en) * 1994-05-23 2004-12-08 日本碍子株式会社 Hydrogen production equipment
US5560912A (en) 1994-06-27 1996-10-01 Technion Research & Development Foundation Ltd. Method for inhibiting growth of helicobacter pylori
JPH0812303A (en) 1994-07-05 1996-01-16 Ishikawajima Harima Heavy Ind Co Ltd Plate reformer
US5811062A (en) 1994-07-29 1998-09-22 Battelle Memorial Institute Microcomponent chemical process sheet architecture
US5611214A (en) * 1994-07-29 1997-03-18 Battelle Memorial Institute Microcomponent sheet architecture
US6129973A (en) 1994-07-29 2000-10-10 Battelle Memorial Institute Microchannel laminated mass exchanger and method of making
US6126723A (en) * 1994-07-29 2000-10-03 Battelle Memorial Institute Microcomponent assembly for efficient contacting of fluid
NL1000146C2 (en) 1995-04-13 1996-10-15 Gastec Nv Method for performing a chemical reaction.
US5733347A (en) 1995-12-27 1998-03-31 International Fuel Cells Corp. Compact fuel gas reformer assemblage
JPH09315801A (en) 1996-03-26 1997-12-09 Toyota Motor Corp Fuel reforming method, fuel reformer and fuel-cell system provided with the reformer
US5858314A (en) 1996-04-12 1999-01-12 Ztek Corporation Thermally enhanced compact reformer
DE19636064A1 (en) 1996-09-05 1998-03-12 Basf Ag Hydrogenation process
US5997594A (en) * 1996-10-30 1999-12-07 Northwest Power Systems, Llc Steam reformer with internal hydrogen purification
US5861137A (en) * 1996-10-30 1999-01-19 Edlund; David J. Steam reformer with internal hydrogen purification
DE19653991A1 (en) * 1996-12-21 1998-06-25 Degussa Reactor for carrying out endothermic catalytic reactions
DE19654361A1 (en) * 1996-12-24 1998-06-25 Behr Gmbh & Co Reactor stack with two dedicated areas
JP3129670B2 (en) * 1997-02-28 2001-01-31 三菱電機株式会社 Fuel reformer
GB2322633A (en) * 1997-02-28 1998-09-02 Norske Stats Oljeselskap Fischer-Tropsch reactor
US6200536B1 (en) * 1997-06-26 2001-03-13 Battelle Memorial Institute Active microchannel heat exchanger
US6036927A (en) * 1997-07-22 2000-03-14 Eastman Kodak Company Micro-ceramic chemical plant having catalytic reaction chamber
DE19739181A1 (en) * 1997-09-08 1999-03-11 Abb Research Ltd Discharge reactor and use of the same
US5976472A (en) * 1997-10-15 1999-11-02 Eastman Kodak Company Integrated micro-ceramic chemical plant with insertable catalytic reaction chambers
US6127571A (en) * 1997-11-11 2000-10-03 Uop Llc Controlled reactant injection with permeable plates
US6117578A (en) * 1998-04-16 2000-09-12 International Fuel Cells, Llc Catalyzed wall fuel gas reformer
US6048194A (en) 1998-06-12 2000-04-11 Precision Combustion, Inc. Dry, low nox catalytic pilot
JP2000007301A (en) * 1998-06-29 2000-01-11 Ngk Insulators Ltd Reforming reactor
US6616909B1 (en) * 1998-07-27 2003-09-09 Battelle Memorial Institute Method and apparatus for obtaining enhanced production rate of thermal chemical reactions
US6540975B2 (en) * 1998-07-27 2003-04-01 Battelle Memorial Institute Method and apparatus for obtaining enhanced production rate of thermal chemical reactions
US6440895B1 (en) * 1998-07-27 2002-08-27 Battelle Memorial Institute Catalyst, method of making, and reactions using the catalyst
US6190624B1 (en) 1998-09-08 2001-02-20 Uop Llc Simplified plate channel reactor arrangement
US6143943A (en) * 1998-09-08 2000-11-07 Uop Llc Process using plate exchanger with high thermal density heat transfer fluid and simultaneous reaction
US6274101B1 (en) 1998-09-08 2001-08-14 Uop Llc Apparatus for in-situ reaction heating
US6228341B1 (en) 1998-09-08 2001-05-08 Uop Llc Process using plate arrangement for exothermic reactions
US6159358A (en) 1998-09-08 2000-12-12 Uop Llc Process and apparatus using plate arrangement for reactant heating and preheating
US6180846B1 (en) * 1998-09-08 2001-01-30 Uop Llc Process and apparatus using plate arrangement for combustive reactant heating
US6168765B1 (en) 1998-09-08 2001-01-02 Uop Llc Process and apparatus for interbed injection in plate reactor arrangement
US6265451B1 (en) * 1999-09-21 2001-07-24 Hydrocarbon Technologies, Inc. Skeletal iron catalyst and its preparation for Fischer-Tropsch synthesis processes
EP1135328A1 (en) 1998-12-02 2001-09-26 Massachusetts Institute Of Technology Integrated palladium-based micromembranes for hydrogen separation and hydrogenation/dehydrogenation reactions
AU2043400A (en) * 1998-12-07 2000-06-26 Syntroleum Corporation Structured fischer-tropsch catalyst system and method for its application
US6203587B1 (en) * 1999-01-19 2001-03-20 International Fuel Cells Llc Compact fuel gas reformer assemblage
DE60031245D1 (en) 1999-02-02 2006-11-23 Virginia Tech Intell Prop SILICON-BASED DIAPHRAGNETICALLY SELECTED AGAINST HYDROGEN
US6140266A (en) * 1999-02-18 2000-10-31 International Fuel Cells, Co., Llc Compact and light weight catalyst bed for use in a fuel cell power plant and method for forming the same
DE29903296U1 (en) 1999-02-24 2000-08-03 Cpc Cellular Process Chemistry Microreactor
US6192596B1 (en) 1999-03-08 2001-02-27 Battelle Memorial Institute Active microchannel fluid processing unit and method of making
EP1063011B1 (en) * 1999-05-22 2001-12-12 OMG AG & Co. KG Use of a catalyst for the steam reforming of methanol
US6193501B1 (en) * 1999-07-06 2001-02-27 The Board Of Trustees Of The University Of Illinois Microcombustor having submillimeter critical dimensions
AU778040B2 (en) * 1999-08-17 2004-11-11 Battelle Memorial Institute Catalyst structure and method of fischer-tropsch synthesis
US6451864B1 (en) * 1999-08-17 2002-09-17 Battelle Memorial Institute Catalyst structure and method of Fischer-Tropsch synthesis
EP1206316B1 (en) * 1999-08-17 2005-06-29 Battelle Memorial Institute Chemical reactor and method for catalytic gas phase reactions
EP1206509B1 (en) * 1999-08-17 2004-10-06 Battelle Memorial Institute Catalyst structure and method of fischer-tropsch synthesis
US6488838B1 (en) 1999-08-17 2002-12-03 Battelle Memorial Institute Chemical reactor and method for gas phase reactant catalytic reactions
JP3759406B2 (en) * 1999-12-15 2006-03-22 日産自動車株式会社 Methanol reforming catalyst, methanol reforming apparatus and methanol reforming method
JP3743995B2 (en) * 1999-12-15 2006-02-08 日産自動車株式会社 Methanol reforming catalyst
US6537506B1 (en) * 2000-02-03 2003-03-25 Cellular Process Chemistry, Inc. Miniaturized reaction apparatus
US7125540B1 (en) * 2000-06-06 2006-10-24 Battelle Memorial Institute Microsystem process networks
US6652830B2 (en) * 2001-02-16 2003-11-25 Battelle Memorial Institute Catalysts reactors and methods of producing hydrogen via the water-gas shift reaction
US6960235B2 (en) * 2001-12-05 2005-11-01 The Regents Of The University Of California Chemical microreactor and method thereof
US7402719B2 (en) * 2002-06-13 2008-07-22 Velocys Catalytic oxidative dehydrogenation, and microchannel reactors for catalytic oxidative dehydrogenation
US7404936B2 (en) * 2002-10-22 2008-07-29 Velocys Catalysts, in microchannel apparatus, and reactions using same
US7405338B2 (en) * 2003-04-07 2008-07-29 Velocys Dehydrogenation reactions in narrow reaction chambers and integrated reactors
US7220390B2 (en) * 2003-05-16 2007-05-22 Velocys, Inc. Microchannel with internal fin support for catalyst or sorption medium
US7084180B2 (en) * 2004-01-28 2006-08-01 Velocys, Inc. Fischer-tropsch synthesis using microchannel technology and novel catalyst and microchannel reactor

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JP2003507288A (en) 2003-02-25
US20030031613A1 (en) 2003-02-13
US6680044B1 (en) 2004-01-20
US6984363B2 (en) 2006-01-10
CA2641757C (en) 2012-03-20
US7632320B2 (en) 2009-12-15
NO330178B1 (en) 2011-02-28
NO20084211L (en) 2002-04-10
EP1568412A1 (en) 2005-08-31
EP1568412B1 (en) 2012-05-09
DK1568412T3 (en) 2012-07-09
JP4904480B2 (en) 2012-03-28
US6488838B1 (en) 2002-12-03
US20060067861A1 (en) 2006-03-30
JP5474863B2 (en) 2014-04-16
ZA200200864B (en) 2003-04-30
JP2011173120A (en) 2011-09-08
ATE556769T1 (en) 2012-05-15

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