CA2569438A1 - Applicator liquid for use in electronic fabrication processes - Google Patents

Applicator liquid for use in electronic fabrication processes Download PDF

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Publication number
CA2569438A1
CA2569438A1 CA002569438A CA2569438A CA2569438A1 CA 2569438 A1 CA2569438 A1 CA 2569438A1 CA 002569438 A CA002569438 A CA 002569438A CA 2569438 A CA2569438 A CA 2569438A CA 2569438 A1 CA2569438 A1 CA 2569438A1
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CA
Canada
Prior art keywords
applicator liquid
applicator
nanotubes
solvent
liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002569438A
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French (fr)
Other versions
CA2569438C (en
Inventor
Rahul Sen
Ramesh Sivarajan
Thomas Rueckes
Brent M. Segal
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Nantero Inc
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Individual
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Publication of CA2569438A1 publication Critical patent/CA2569438A1/en
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Anticipated expiration legal-status Critical

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01CRESISTORS
    • H01C17/00Apparatus or processes specially adapted for manufacturing resistors
    • H01C17/06Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base
    • H01C17/065Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base by thick film techniques, e.g. serigraphy
    • H01C17/06506Precursor compositions therefor, e.g. pastes, inks, glass frits
    • H01C17/06513Precursor compositions therefor, e.g. pastes, inks, glass frits characterised by the resistive component
    • H01C17/0652Precursor compositions therefor, e.g. pastes, inks, glass frits characterised by the resistive component containing carbon or carbides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y10/00Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/10Deposition of organic active material
    • H10K71/12Deposition of organic active material using liquid deposition, e.g. spin coating
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/311Purifying organic semiconductor materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/20Carbon compounds, e.g. carbon nanotubes or fullerenes
    • H10K85/221Carbon nanotubes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/70Nanostructure
    • Y10S977/734Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
    • Y10S977/742Carbon nanotubes, CNTs
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/70Nanostructure
    • Y10S977/734Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
    • Y10S977/742Carbon nanotubes, CNTs
    • Y10S977/743Carbon nanotubes, CNTs having specified tube end structure, e.g. close-ended shell or open-ended tube
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/70Nanostructure
    • Y10S977/734Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
    • Y10S977/753Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc. with polymeric or organic binder
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/30Self-sustaining carbon mass or layer with impregnant or other layer

Abstract

Certain spin-coatable liquids and application techniques are described, which can be used to form nanotube films or fabrics of controlled properties. A spin-coatable liquid containing nanotubes for use in an electronics fabrication process includes a solvent containing a plurality of nanotubes. The nanotubes are at a concentration of greater than 1 mg/L. The nanotubes are pretreated to reduce the level of metallic and particulate impurities to a preselected level, and the preselected metal and particulate impurities levels are selected to be compatible with an electronics manufacturing process. The solvent also is selected for compatibility with an electronics manufacturing process.

Claims (46)

1. An applicator liquid for use in an electronics manufacturing process, comprising:
an electronics-grade solvent and a plurality of nanotubes, wherein the nanotubes are at a concentration of greater than or equal to 10 mg/L, wherein the nanotubes are pretreated to reduce a level of metallic and particulate impurities to a preselected level, and wherein the preselected level is selected to satisfy a criteria of the electronics manufacturing process.
2. The applicator liquid of claim 1, wherein the solvent is selected for compatibility with the electronics manufacturing process.
3. The applicator liquid of claim 1, wherein the solvent is selected for compatibility with a semiconductor manufacturing process.
4. The applicator liquid of any one of claims 1 to 3, wherein the preselected level is selected to be compatible with a semiconducting manufacturing process.
5. The applicator liquid of any one of claims 1 to 4, wherein the nanotubes are substantially separated from one another and are distributed in the solvent without substantial precipitation or flocculation.
6. The applicator liquid of any one of claims 1 to 5, wherein the nanotubes are at a concentration of greater than 100 mg/L.
7. The applicator liquid of any one of claims 1 to 6, wherein the nanotubes are at a concentration of greater than 1000 mg/L.
8. The applicator liquid of any one of claims 1 to 7, wherein the solvent is a non-halogen solvent.
9. The applicator liquid of any one of claims 1 to 8, wherein the solvent is a non-aqueous solvent.
10. The applicator liquid of any one of claims 1 to 9, wherein the solvent comprises ethyl lactate.
11. The applicator liquid of any one of claims 1 to 10, wherein the applicator liquid is surfactant-free.
12. The applicator liquid of any one of claims 1 to 11, wherein the nanotubes are single-walled nanotubes.
13. The applicator liquid of any one of claims 1 to 12, wherein the applicator liquid is substantially free of particulate impurities having a diameter greater than about 500 nm.
14. The applicator liquid of any one of claims 1 to 12, wherein the applicator liquid is substantially free of particulate impurities having a diameter greater than about 200 nm.
15. The applicator liquid of any one of claims 1 to 12, wherein the applicator liquid is substantially free of particulate impurities having a diameter greater than about 100 nm.
16. The applicator liquid of any one of claims 1 to 12, wherein the applicator liquid is substantially free of particulate impurities having a diameter greater than about 45 nm.
17. The applicator liquid of any one of claims 1 to 16, wherein the applicator liquid comprises less than about 1 × 10 18 atoms/cm3 of metal impurities.
18. The applicator liquid of any one of claims 1 to 16, wherein the applicator liquid comprises less than about 1 × 10 18 atoms/cm3 of transition metal impurities.
19. The applicator liquid of any one of claims 1 to 16 and 18, wherein the applicator liquid comprises less than about 1 × 10 18 atoms/cm3 of heavy metal impurities.
20. The applicator liquid of any one of claims 1 to 16, 18 and 19, wherein the applicator liquid comprises less than about 1 × 10 18 atoms/cm3 of group I and group II
metal impurities.
21. The applicator liquid of any one of claims 1 to 16, wherein the applicator liquid comprises less than about 15 × 10 10 atoms/cm3 of metal impurities.
22. The applicator liquid of any one of claims 1 to 16, wherein the applicator liquid comprises less than about 15 × 10 10 atoms/cm3 of transition metal impurities.
23. The applicator liquid of any one of claims 1 to 16 and 22, wherein the applicator liquid comprises less than about 15 × 10 10 atoms/cm3 of heavy metal impurities.
24. The applicator liquid of any one of claims 1 to 16, 22 and 23, wherein the applicator liquid comprises less than about 15 × 10 10 atoms/cm3 of group I and group II
metal impurities.
25. An applicator liquid for use in an electronics manufacturing process, comprising:
an electronics-grade solvent and a plurality of nanotubes, wherein the nanotubes are at a concentration of greater than or equal to 10 mg/L, wherein the nanotubes are pretreated to reduce a level of metal and particulate impurities to a preselected level, wherein the nanotubes are substantially separated from one another and are distributed in the solvent without precipitation or flocculation, and wherein the solvent is selected for compatibility with the electronics manufacturing process.
26. The applicator liquid of claim 25, wherein the preselected level is selected to be compatible with the electronics manufacturing process.
27. The applicator liquid of claim 25 or 26, wherein the solvent is selected for compatibility with a semiconductor manufacturing process.
28. The applicator liquid of any one of claims 25 to 27, wherein the solvent is a non-halogen solvent.
29. The applicator liquid of any one of claims 25 to 28, wherein the solvent is a non-aqueous solvent.
30 30. ~The applicator liquid of any one of claims 25 to 29, wherein the solvent comprises ethyl lactate.
31. ~The applicator liquid of any one of claims 25 to 30, wherein the applicator liquid is surfactant-free.
32. ~The applicator liquid of any one of claims 25 to 31, wherein the nanotubes are at a concentration of greater than 100 mg/L.
33. ~The applicator liquid of any one of claims 25 to 32, wherein the nanotubes are at a concentration of greater than 1000 mg/L.
34. ~The applicator liquid of any one of claims 25 to 33, wherein the nanotubes are single-walled nanotubes.
35. The applicator liquid of any one of claims 25 to 34, wherein the applicator liquid is substantially free of particulate impurities having a diameter greater than about 500 nm.
36. ~The applicator liquid of any one of claims 25 to 34, wherein the applicator liquid is substantially free of particulate impurities having a diameter greater than about 300 nm.
37. ~The applicator liquid of any one of claims 25 to 34, wherein the applicator liquid is substantially free of particulate impurities having a diameter greater than about 100 nm.
38. ~The applicator liquid of any one of claims 25 to 34, wherein the applicator liquid is substantially free of particulate impurities having a diameter greater than about 45 nm.
39. ~The applicator liquid of any one of claims 25 to 38, wherein the applicator liquid comprises less than about 15x10 10 atoms/cm3 of metal impurities.
40. ~The applicator liquid of any one of claims 25 to 38, wherein the applicator liquid comprises less than about 15x10 10 atoms/cm3 of transition metal impurities.
41. ~The applicator liquid of any one of claims 25 to 38 and 40, wherein the applicator liquid comprises less than about 15x10 10 atoms/cm3 of heavy metal impurities.
42. ~The applicator liquid of any one of claims 25 to 38, 40 and 41, wherein the applicator liquid comprises less than about 15x10 10 atoms/cm3 of group I and group II
metal impurities.
43. ~The applicator liquid of any one of claims 25 to 38, wherein the applicator liquid comprises less than about 1x10 18 atoms/cm3 of metal impurities.
44. ~The applicator liquid of any one of claims 25 to 38, wherein the applicator liquid comprises less than about 1x10 18 atoms/cm3 of transition metal impurities.
45. ~The applicator liquid of any one of claims 25 to 38 and 44, wherein the applicator liquid comprises less than about 1x10 18 atoms/cm3 of heavy metal impurities.
46.~ The applicator liquid of any one of claims 25 to 38, 44 and 45, wherein the applicator liquid comprises less than about 1x10 18 atoms/cm3 of group I and group II
metal impurities.
CA2569438A 2004-06-03 2005-05-26 Applicator liquid for use in electronic fabrication processes Active CA2569438C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/860,432 2004-06-03
US10/860,432 US7504051B2 (en) 2003-09-08 2004-06-03 Applicator liquid for use in electronic manufacturing processes
PCT/US2005/018465 WO2006078297A2 (en) 2004-06-03 2005-05-26 Spin-coatable liquid for use in electronic fabrication processes

Publications (2)

Publication Number Publication Date
CA2569438A1 true CA2569438A1 (en) 2006-07-27
CA2569438C CA2569438C (en) 2012-02-21

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA2569438A Active CA2569438C (en) 2004-06-03 2005-05-26 Applicator liquid for use in electronic fabrication processes

Country Status (7)

Country Link
US (1) US7504051B2 (en)
EP (1) EP1751778B1 (en)
JP (1) JP5781718B2 (en)
CN (1) CN101015025B (en)
CA (1) CA2569438C (en)
TW (1) TWI317952B (en)
WO (1) WO2006078297A2 (en)

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