CA2569198A1 - Methods for producing polymers with control over composition distribution - Google Patents

Methods for producing polymers with control over composition distribution Download PDF

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Publication number
CA2569198A1
CA2569198A1 CA002569198A CA2569198A CA2569198A1 CA 2569198 A1 CA2569198 A1 CA 2569198A1 CA 002569198 A CA002569198 A CA 002569198A CA 2569198 A CA2569198 A CA 2569198A CA 2569198 A1 CA2569198 A1 CA 2569198A1
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CA
Canada
Prior art keywords
methods
control over
composition distribution
polyolefin
producing polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002569198A
Other languages
French (fr)
Other versions
CA2569198C (en
Inventor
John F. Szul
James M. Farley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Univation Technologies LLC
Original Assignee
John F. Szul
James M. Farley
Univation Technologies, Llc
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Application filed by John F. Szul, James M. Farley, Univation Technologies, Llc filed Critical John F. Szul
Publication of CA2569198A1 publication Critical patent/CA2569198A1/en
Application granted granted Critical
Publication of CA2569198C publication Critical patent/CA2569198C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905Polymerization in presence of transition metal containing catalyst in presence of hydrogen

Abstract

Methods for controlling a melt viscosity of a polyolefin, controlling comonomer distribution of a polyolefin, achieving a targeted melt viscosity of a polyolefin, and films made from such polyolefins are provided. The methods include contacting an olefin monomer and at least one comonomer with a catalyst system in the presence of a condensable fluid comprising a saturated hydrocarbon having from 2 to 8 carbon atoms. The catalyst system in one embodiment includes a hafnium metallocene catalyst component.
CA002569198A 2004-06-21 2005-05-04 Methods for producing polymers with control over composition distribution Expired - Fee Related CA2569198C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/872,847 US7157531B2 (en) 2004-06-21 2004-06-21 Methods for producing polymers with control over composition distribution
US10/872,847 2004-06-21
PCT/US2005/015568 WO2006007046A2 (en) 2004-06-21 2005-05-04 Methods for producing polymers with control over composition distribution

Publications (2)

Publication Number Publication Date
CA2569198A1 true CA2569198A1 (en) 2006-01-19
CA2569198C CA2569198C (en) 2009-10-20

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA002569198A Expired - Fee Related CA2569198C (en) 2004-06-21 2005-05-04 Methods for producing polymers with control over composition distribution

Country Status (13)

Country Link
US (1) US7157531B2 (en)
EP (1) EP1758944A4 (en)
JP (1) JP4531812B2 (en)
KR (1) KR100879196B1 (en)
CN (1) CN100547005C (en)
BR (1) BRPI0512329A (en)
CA (1) CA2569198C (en)
MX (1) MXPA06015163A (en)
MY (1) MY134760A (en)
RU (1) RU2356912C2 (en)
TW (1) TW200609246A (en)
WO (1) WO2006007046A2 (en)
ZA (1) ZA200610059B (en)

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Also Published As

Publication number Publication date
ZA200610059B (en) 2008-02-27
KR20070028436A (en) 2007-03-12
WO2006007046A2 (en) 2006-01-19
MXPA06015163A (en) 2007-03-27
TW200609246A (en) 2006-03-16
US20050282980A1 (en) 2005-12-22
JP2008503641A (en) 2008-02-07
EP1758944A2 (en) 2007-03-07
BRPI0512329A (en) 2008-02-26
EP1758944A4 (en) 2011-08-03
RU2006144361A (en) 2008-07-27
WO2006007046A3 (en) 2006-07-06
MY134760A (en) 2007-12-31
CN1968980A (en) 2007-05-23
RU2356912C2 (en) 2009-05-27
US7157531B2 (en) 2007-01-02
KR100879196B1 (en) 2009-01-16
CA2569198C (en) 2009-10-20
CN100547005C (en) 2009-10-07
JP4531812B2 (en) 2010-08-25

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