CA2541891A1 - Zeolite-containing cement composition - Google Patents
Zeolite-containing cement composition Download PDFInfo
- Publication number
- CA2541891A1 CA2541891A1 CA 2541891 CA2541891A CA2541891A1 CA 2541891 A1 CA2541891 A1 CA 2541891A1 CA 2541891 CA2541891 CA 2541891 CA 2541891 A CA2541891 A CA 2541891A CA 2541891 A1 CA2541891 A1 CA 2541891A1
- Authority
- CA
- Canada
- Prior art keywords
- zeolite
- cement
- base blend
- mixing
- cement mix
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/42—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
- C09K8/46—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement
- C09K8/467—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement containing additives for specific purposes
- C09K8/487—Fluid loss control additives; Additives for reducing or preventing circulation loss
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/047—Zeolites
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/42—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
- C09K8/46—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/42—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
- C09K8/46—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement
- C09K8/467—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement containing additives for specific purposes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/42—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
- C09K8/46—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement
- C09K8/467—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement containing additives for specific purposes
- C09K8/473—Density reducing additives, e.g. for obtaining foamed cement compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/46—Water-loss or fluid-loss reducers, hygroscopic or hydrophilic agents, water retention agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
Methods and cement compositions are provided for sealing a subterranean zone penetrated by a wellbore, wherein the cement composition comprises zeolite, cementitious material, and a mixing fluid.
Claims (220)
1. ~A method of sealing a subterranean zone penetrated by a wellbore comprising:
mixing a cement mix comprising a base blend comprising zeolite and at least one cementitious material with a mixing fluid to form a cement composition;
placing the cement composition into the subterranean zone; and allowing the cement composition to set therein.
mixing a cement mix comprising a base blend comprising zeolite and at least one cementitious material with a mixing fluid to form a cement composition;
placing the cement composition into the subterranean zone; and allowing the cement composition to set therein.
2. ~The method of claim 1 wherein the zeolite is represented by the formula:~
M a/n[(AlO2)a(SiO2)b] - xH2O
where M represents one or more cations selected from the group consisting of Na, K, Mg, Ca, Sr, Li, Ba, NH4, CH3NH3, (CH3)3NH, (CH3)4 N, Ga, Ge and P; n represents the cation valence; the ratio of b:a is in a range from greater than or equal to 1 and less than or equal to 5; and x represents the moles of water entrained into the zeolite framework.
M a/n[(AlO2)a(SiO2)b] - xH2O
where M represents one or more cations selected from the group consisting of Na, K, Mg, Ca, Sr, Li, Ba, NH4, CH3NH3, (CH3)3NH, (CH3)4 N, Ga, Ge and P; n represents the cation valence; the ratio of b:a is in a range from greater than or equal to 1 and less than or equal to 5; and x represents the moles of water entrained into the zeolite framework.
3. ~The method of claim 1, wherein the zeolite is selected from the group consisting of analcime, bikitaite, brewsterite, chabazite, clinoptilolite, faujasite, harmotome, heulandite, laumontite, mesolite, natrolite, paulingite, phillipsite, scolecite, stellerite, stilbite, and thomsonite.
4. ~The method of claim 1 wherein the base blend comprises from about 20 to about 50 weight percent zeolite.
5. ~The method of claim 1 wherein the base blend comprises from about 30 to about 90 weight percent zeolite.
6. ~The method of claim 1 wherein the base blend comprises from about 5 to about 75 weight percent zeolite.
7. ~The method of claim 1 wherein the base blend comprises from about 50 to about 75 weight percent zeolite.
8. ~The method of claim 1 wherein the base blend comprises from about 0.5 to about 35 weight percent zeolite.
9. ~The method of claim 1 wherein the cement mix comprises a base blend comprising at least one cementitious material selected from the group consisting of micronized cement, Portland cement, pozzolan cement, gypsum cement, aluminous cement, silica cement, and alkaline cement.
10. ~The method of claim 9 wherein the cement mix further comprises fly ash.
11. ~The method of claim 1 wherein the mixing fluid is present in a range of about 22% to about 200% by weight of the base blend.
12. ~The method of claim 1 wherein the mixing fluid is present in a range of about 40% to about 135% by weight of the base blend.
13. ~The method of claim 1 wherein the cement composition further comprises at least one accelerating additive.
14. ~The method of claim 13 wherein the at least one accelerating additive is selected from the group consisting of sodium sulfate, sodium carbonate, calcium sulfate, calcium carbonate, potassium sulfate, and potassium carbonate.
15. ~The method of claim 14 wherein the cement composition comprises at least two accelerating additives selected from the group consisting of sodium sulfate, sodium carbonate, calcium sulfate, calcium carbonate, potassium sulfate, and potassium carbonate.
16. ~The method of claim 15 wherein at least one accelerating additive is selected from the group consisting of sodium sulfate, calcium sulfate, and potassium sulfate;
and at least one accelerating additive is selected from the group consisting of sodium carbonate, calcium carbonate, and potassium carbonate.
and at least one accelerating additive is selected from the group consisting of sodium carbonate, calcium carbonate, and potassium carbonate.
17. ~The method of claim 1 wherein the cement mix comprises:
a base blend comprising zeolite and at least one cementitious material; and at least one accelerating additive in an amount of about 0.5% to about 10% by weight of the base blend.
a base blend comprising zeolite and at least one cementitious material; and at least one accelerating additive in an amount of about 0.5% to about 10% by weight of the base blend.
18. ~The method of claim 17 wherein the accelerating additive is present in the base blend in an amount of about 3% to about 7% by weight of the base blend.
19. ~The method of claim 1 wherein the cement composition further comprises a fluid loss control additive selected from the group consisting of anionic water based soluble polymers, hydrophobically modified anionic water based soluble polymers, non-ionic water based soluble polymers and hydrophobically modified non-ionic water based soluble polymers.
20. ~The method of claim 1 wherein the cement composition further comprises a fluid loss control additive selected from the group consisting of hydroxyethylcellulose, hydrophobically modified hydroxyethylcellulose, carboxymethylhydroxyethylcellulose, guar, modified guar, polyvinyl alcohol, montmorillonite clay, anhydrous sodium silicate, grafted polymers prepared by the polymerization of monomers or salts of monomers of N,N-dimethylacrylamide, 2-acrylamido-2-methylpropanesulfonic acid and acrylonitrile having a lignin or lignite or other backbone, and copolymers or salts of copolymers of N,N-dimethylacrylamide (NNDMA) and 2-acrylamido, 2-methyl propane sulfonic acid (AMPS).
21. ~The method of claim 1 wherein the cement mix further comprises:
a base blend comprising zeolite and at least one cementitous material; and at least one fluid loss control additive in an amount of about 0.5% to about 1.0% by weight of the base blend.
a base blend comprising zeolite and at least one cementitous material; and at least one fluid loss control additive in an amount of about 0.5% to about 1.0% by weight of the base blend.
22. ~The method of claim 1 wherein a flow enhancing agent is absorbed on the zeolite.
23. ~The method of claim 22 wherein the flow enhancing agent is present in an amount of from about 15% to about 25% by weight of the zeolite.
24. ~The method of claim 1 wherein the base blend comprises zeolite in an amount of from about 35% to about 50% of the weight of the base blend, and the cement composition formed has a density equal up to about 13.5 lb/gal.
25. ~The method of claim 1 wherein the zeolite has a mean particle size of about 100 microns or less.
26. ~The method of claim 1 wherein the zeolite has a mean particle size from about 3 microns to about 15 microns.
27. ~The method of claim 1 further comprising reducing an apparent viscosity of the cement composition wherein the reduction is caused by dispersant properties of the zeolite.
28. ~The method of claim 1 wherein the mixing fluid comprises water.
29. ~The method of claim 28 wherein the mixing fluid further comprises a defoaming agent.
30. ~The method of claim 28 wherein the mixing fluid further comprises bentonite.
31. ~The method of claim 1 further comprising preparing the base blend by mixing zeolite and at least one cementitious material.
32. ~The method of claim 31 wherein the preparing of the base blend comprises mixing zeolite in an amount from about 20 to about 50 weight percent with at least one cementitious material.
-73-~
-73-~
33. The method of claim 31 wherein the preparing of the base blend comprises mixing zeolite in an amount from about 30 to about 90 weight percent with at least one cementitious material.
34. The method of claim 31 wherein the preparing of the base blend comprises mixing zeolite in an amount from about 5 to about 75 weight percent with at least one cementitious material.
35. The method of claim 31 wherein the preparing of the base blend comprises mixing zeolite in an amount from about 50 to about 75 weight percent with at least one cementitious material.
36. The method of claim 31 wherein the preparing of the base blend comprises mixing zeolite in an amount from about 0.5 to about 35 weight percent with at least one cementitious material.
37. The method of claim 31 wherein the base blend comprises at least one cementitious material selected from the group consisting of micronized cement, Portland cement, pozzolan cement, gypsum cement, aluminous cement, silica cement, and alkaline cement.
38. The method of claim 37 wherein the cement mix further comprises fly ash.
39. The method of claim 31 wherein the preparing of the base blend comprises:
preparing a base blend comprising zeolite and at least one cementitious material; and adding at least one accelerating additive to the base blend in an amount of about 0.5% to about 10% by weight of the base blend.
preparing a base blend comprising zeolite and at least one cementitious material; and adding at least one accelerating additive to the base blend in an amount of about 0.5% to about 10% by weight of the base blend.
40. The method of claim 39 wherein the accelerating additive is added to the base blend in an amount of about 3% to about 7% by weight of the base blend.
41. ~The method of claim 31 wherein the preparing of the base blend further comprises adding at least one fluid loss control additive to the base blend in an amount of about 0.5% to about 1.0% by weight of the base blend.
42. ~The method of claim 31 further comprising absorbing a flow enhancing agent on the zeolite prior to the preparing of the base blend.
43. ~A method for preparing a cement mix comprising mixing zeolite and at least one cementitious material to form a base blend comprising the cement mix.
44. ~The method of claim 43 wherein the preparing of the cement mix comprises mixing zeolite in an amount from about 20 to about 50 weight percent with at least one cementitious material.
45. ~The method of claim 43 wherein the preparing of the cement mix comprises mixing zeolite in an amount from about 30 to about 90 weight percent with at least one cementitious material.
46. ~The method of claim 43 wherein the preparing of the cement mix comprises mixing zeolite in an amount from about 5 to about 75 weight percent with at least one cementitious material.
47. ~The method of claim 43 wherein the preparing of the cement mix comprises mixing zeolite in an amount from about 50 to about 75 weight percent with at least one cementitious material.
48. ~The method of claim 43 wherein the preparing of the cement mix comprises mixing zeolite in an amount from about 0.5 to about 35 weight percent with at least one cementitious material.
49. ~The method of claim 43 wherein the cement mix comprises a base blend comprising at least one cementitious material selected from the group consisting of micronized cement, Portland cement, pozzolan cement, gypsum cement, aluminous cement, silica cement, and alkaline cement.
50. ~The method of claim 49 wherein the cement mix further comprises fly ash.
51. ~The method of claim 43 wherein the preparing of the cement mix further comprises adding at least one accelerating additive to the base blend in an amount of from about 0.5% to about 10% by weight of the base blend.
52. ~The method of claim 51 wherein the accelerating additive is added to the base blend in an amount of from about 3% to about 7% by weight of the base blend.
53. ~The method of claim 43 wherein the preparing of the cement mix further comprises adding at least one fluid loss control additive to the base blend in an amount of from about 0.5%
to about 1.0% by weight of the base blend.
to about 1.0% by weight of the base blend.
54. ~The method of claim 43 further comprising absorbing a flow enhancing agent on the zeolite prior to the preparing of the cement mix.
55. ~A method of sealing a subterranean zone penetrated by a wellbore comprising:
blending a cement mix comprising a base blend with an aqueous zeolite suspension to form a cement composition;
placing the cement composition into the subterranean zone; and allowing the cement composition to set therein.
blending a cement mix comprising a base blend with an aqueous zeolite suspension to form a cement composition;
placing the cement composition into the subterranean zone; and allowing the cement composition to set therein.
56. ~The method of claim 55 wherein the aqueous zeolite suspension comprises zeolite represented by the formula:
Ma/n[(AlO2)a(SiO2)b]- xH2O
where M represents one or more cations selected from the group consisting of Na, K, Mg, Ca, Sr, Li, Ba,NH4, CH3NH3, (CH3)3NH, (CH3)4N, Ga, Ge and P; n represents the cation valence;
the ratio of b:a is in a range from greater than or equal to 1 and less than or equal to 5; and x represents the moles of water entrained into the zeolite framework.
Ma/n[(AlO2)a(SiO2)b]- xH2O
where M represents one or more cations selected from the group consisting of Na, K, Mg, Ca, Sr, Li, Ba,NH4, CH3NH3, (CH3)3NH, (CH3)4N, Ga, Ge and P; n represents the cation valence;
the ratio of b:a is in a range from greater than or equal to 1 and less than or equal to 5; and x represents the moles of water entrained into the zeolite framework.
57. ~The method of claim 55, wherein the aqueous zeolite suspension comprises zeolite selected from the group consisting of analcime, bikitaite, brewsterite, chabazite, clinoptilolite, faujasite, harmotome, heulandite, laumontite, mesolite, natrolite, paulingite, phillipsite, scolecite, stellerite, stilbite, and thomsonite.
58. ~The method of claim 55 further comprising mixing zeolite with a mixing fluid to form the aqueous zeolite suspension.
59. ~The method of claim 58 wherein the aqueous zeolite suspension is formed by mixing zeolite in an amount from about 40 to about 50 weight percent with the mixing fluid.
60. ~The method of claim 58 wherein the mixing fluid comprises water.
61. ~The method of claim 58 wherein the aqueous zeolite suspension is stable for at least two weeks before the blending with the cement mix.
62. ~The method of claim 55 wherein the cement mix comprises a base blend comprising at least one cementitious material.
63. ~The method of claim 62 wherein the cement mix further comprises hydrated lime.
64. ~The method of claim 55 wherein the blending further comprises blending the aqueous zeolite suspension in an amount of about 1-150% by weight of the base blend with the cement mix.
65. The method of claim 55 further comprising mixing the aqueous zeolite suspension with a mixing fluid before the blending of the aqueous zeolite suspension with the cement mix.
66. The method of claim 65 wherein the mixing fluid comprises water.
67. The method of claim 65 further comprising mixing the cement mix with a mixing fluid before the blending of the cement mix with the aqueous zeolite suspension.
68. The method of claim 55 further comprising mixing the cement mix with a mixing fluid before the blending of the cement mix with the aqueous zeolite suspension.
69. The method of claim 55 further comprising adding lightweight materials to the aqueous zeolite suspension prior to the blending of the aqueous zeolite suspension with the cement mix.
70. The method of claim 69 further comprising adding the lightweight materials to the aqueous zeolite suspension in an amount of from about 1 % to about 70% by weight of the base blend comprising the cement mix.
71. The method of claim 70 further comprising mixing zeolite with a mixing fluid to form the aqueous zeolite suspension; and adding at least one lightweight material to the aqueous zeolite suspension.
72. The method of claim 71 further comprising mixing the cement mix with a mixing fluid prior to the blending of the aqueous zeolite suspension with the cement mix.
73. The method of claim 72 further comprising blending the aqueous zeolite suspension with the cement mix to form a cement composition having a density less than about 12 lb/gal.
74. A method of sealing a subterranean zone penetrated by a wellbore comprising:
mixing a cement mix comprising a base blend comprising zeolite and at least one cementitious material with a mixing fluid to form an unfoamed cement composition;
foaming the unfoamed cement composition to form a foamed cement composition;
placing the foamed cement composition into the subterranean zone; and allowing the foamed cement composition to set therein.
mixing a cement mix comprising a base blend comprising zeolite and at least one cementitious material with a mixing fluid to form an unfoamed cement composition;
foaming the unfoamed cement composition to form a foamed cement composition;
placing the foamed cement composition into the subterranean zone; and allowing the foamed cement composition to set therein.
75. The method of claim 74 wherein the cement mix further comprises bentonite.
76. The method of claim 74 wherein the foamed cement composition has a density of at least 8 lb/gal.
77. The method of claim 74 wherein the base blend from about 20 to about 40 weight percent zeolite.
78. The method of claim 74 further comprising blending the cement mix with an aqueous zeolite suspension prior to the foaming.
79. The method of claim 78 further comprising forming the aqueous zeolite suspension by mixing zeolite in an amount from about 40 to about 50 weight percent with a mixing fluid.
80. The method of claim 78 wherein the foamed cement composition is stabilized by the zeolite in the aqueous zeolite suspension.
81. The method of claim 74 wherein the foamed cement composition is stabilized caused by the zeolite in the base blend.
82. The method of claim 74 further comprising preparing the cement mix by mixing zeolite and at least one cementitious material to form the base blend.
83. The method of claim 82 further comprising mixing the zeolite and the at least one cementitious material with bentonite.
84. The method of claim 82 wherein the forming of the base blend comprises mixing the zeolite in an amount from about 20 to about 40 weight percent with the at least one cementitious material.
85. A method for making a cement composition comprising mixing a cement mix comprising a base blend comprising cementitious material and zeolite with a mixing fluid.
86. The method of claim 85 wherein the zeolite is represented by the formula:
M a/n[(AO2)a(SiO2)]-xH2O
where M represents one or more cations selected from the group consisting of Na, K, Mg, Ca, Sr, Li, Ba, NH4, CH3NH3, (CH3)3NH, (CH3)4N, Ga, Ge and P; n represents the canon valence; the ratio of b:a is in a range from greater than or equal to 1 and less than or equal to 5; and x represents the moles of water entrained into the zeolite framework.
M a/n[(AO2)a(SiO2)]-xH2O
where M represents one or more cations selected from the group consisting of Na, K, Mg, Ca, Sr, Li, Ba, NH4, CH3NH3, (CH3)3NH, (CH3)4N, Ga, Ge and P; n represents the canon valence; the ratio of b:a is in a range from greater than or equal to 1 and less than or equal to 5; and x represents the moles of water entrained into the zeolite framework.
87. The method of claim 85, wherein the zeolite is selected from the group consisting of analcime, bikitaite, brewsterite, chabazite, clinoptilolite, faujasite, harmotome; heulandite, laumontite, mesolite, natrolite, paulingite, phillipsite, scolecite, stellerite, stilbite, and thomsonite.
88. The method of claim 85 wherein the base blend comprises from about 20 to about 50 weight percent zeolite.
89. The method of claim 85 wherein the base blend comprises from about 30 to about 90 weight percent zeolite.
90. The method of claim 85 wherein the base blend comprises from about 5 to about 75 weight percent zeolite.
91. The method of claim 85 wherein the base blend comprises from about 50 to about 75 weight percent zeolite.
92. The method of claim 85 wherein the base blend comprises from about 0.5 to about 35 weight percent zeolite.
93. The method of claim 85 wherein the cement mix comprises at least one cementitious material selected from the group consisting of micronized cement, Portland cement, pozzolan cement, gypsum cement, aluminous cement, silica cement, and alkaline cement.
94. The method of claim 93 wherein the cement mix further comprises fly ash.
95. The method of claim 85 further comprising mixing the cement mix with mixing fluid that is present in a range of from about 22% to about 200% by weight of the base blend.
96. The method of claim 85 further comprising mixing the cement mix with mixing fluid that is present in a range of from about 40% to about 135% by weight of the base blend.
97. The method of claim 85 further comprising mixing the cement mix comprising the base blend with at least one accelerating additive.
98. The method of claim 9? wherein the at least one accelerating additive is selected from the group consisting of sodium sulfate, sodium carbonate, calcium sulfate, calcium carbonate, potassium sulfate, and potassium carbonate.
99. The method of claim 98 wherein at least two accelerating additives are selected from the group consisting of sodium sulfate, sodium carbonate, calcium sulfate, calcium carbonate, potassium sulfate, and potassium carbonate.
100. The method of claim 99 wherein at least one accelerating additive is selected from the group consisting of sodium sulfate, calcium sulfate, and potassium sulfate;
and at least one accelerating additive is selected from the group consisting of sodium carbonate, calcium carbonate, and potassium carbonate.
and at least one accelerating additive is selected from the group consisting of sodium carbonate, calcium carbonate, and potassium carbonate.
101. The method of claim 85 wherein the cement mix comprises:
a base blend comprising zeolite and at least one cementitious material; and at least one accelerating additive in an amount of from about 0.5% to about 10% by weight of the base blend.
a base blend comprising zeolite and at least one cementitious material; and at least one accelerating additive in an amount of from about 0.5% to about 10% by weight of the base blend.
102. The method of claim 101 wherein the accelerating additive is present in an amount of from about 3% to about 7% by weight of the base blend.
103. The method of claim 85 further comprising mixing the cement mix comprising the base blend with a fluid loss control additive selected from the group consisting of anionic water based soluble polymers, hydrophobically modified anionic water based soluble polymers, non-ionic water based soluble polymers and hydrophobically modified non-ionic water based soluble polymers.
104. The method of claim 85 further comprising mixing the cement mix comprising the base blend with a fluid loss control additive selected from the group consisting of hydroxyethylcellulose, hydrophobically modified hydroxyethylcellulose, carboxymethylhydroxyethylcellulose, guar, modified guar, polyvinyl alcohol, montmorillonite clay, anhydrous sodium silicate, grafted polymers prepared by the polymerization of monomers or salts of monomers of N,N-dimethylacrylamide, 2-acrylamido-2-methylpropanesulfonic acid and acrylonitrile having a lignin or lignite or other backbone, and copolymers or salts of copolymers of N,N-dimethylacrylamide (NNDMA) and 2-acrylamido, 2-methyl propane sulfonic acid (AMPS).
105. The method of claim 85 wherein the cement mix further comprises at least one fluid loss control additive in an amount of from about 0.5% to about 1.0% by weight of the base blend.
106. The method of claim 85 further comprising absorbing a flow enhancing agent on the zeolite.
107. The method of claim 106 wherein the flow enhancing agent is present in an amount of from about 15% to about 25% by weight of the zeolite.
108. The method of claim 85 wherein the base blend comprises from about 35 to about 50 weight percent zeolite, and the cement composition formed has a density up to about 13.5 lb/gal.
109. The method of claim 85 wherein the zeolite has a mean particle size of about 100 microns or less.
110. The method of claim 85 wherein the zeolite has a mean particle size from about 3 microns to about 15 microns.
111. The method of claim 85 wherein the apparent viscosity of the cement composition is reduced by the zeolite.
112. The method of claim 85 wherein the mixing fluid comprises water.
113. The method of claim 112 wherein the mixing fluid further comprises a defoaming agent.
114. The method of claim 112 wherein the mixing fluid further comprises bentonite.
115. The method of claim 85 further comprising preparing the cement mix by preparing the base blend by mixing the cementitious material and the zeolite.
116. The method of claim 115 wherein the preparing of the base blend comprises mixing zeolite in an amount about 20 to about 50 weight percent with the cementitious material.
117. The method of claim 115 wherein the preparing of the base blend comprises mixing zeolite in an amount from about 30 to about 90 weight percent with the cementitious material.
118. The method of claim 115 wherein the preparing of the base blend comprises mixing zeolite in an amount from about 5 to about 75 weight percent with the cementitious material.
119. The method of claim 115 wherein the preparing of the base blend comprises mixing zeolite in an amount from about 50 to about 75 weight percent with the cementitious material.
120. The method of claim 115 wherein the preparing of the base blend comprises mixing zeolite in the amount from about 0.5 to about 35 weight percent with the cementitious material.
121. The method of claim 115 wherein the preparing of the cement mix further comprises adding at least one accelerating additive to the base blend in an amount of from about 0.5% to about 10% by weight of the base blend.
122. The method of claim 121 further comprising adding the accelerating additive to the base blend in an amount of from about 3% to about 7% by weight of the base blend.
123. The method of claim 115 wherein the preparing of the cement mix further comprises adding at least one fluid loss control additive to the base blend in an amount of about 0.5% to about 1.0% by weight of the base blend.
124. The method of claim 115 further comprising absorbing a flow enhancing agent on the zeolite prior to the preparing of the base blend.
125. A method for making a cement composition comprising blending a cement mix comprising a base blend with an aqueous zeolite suspension.
126. The method of claim 125 wherein the aqueous zeolite suspension comprises zeolite represented by the formula:
Ma/n[AlO2)a(SiO2)b].cndot.xH2O
where M represents one or more cations selected from the group consisting of Na, K, Mg, Ca, Sr, Li, Ba,NH4, CH3NH3, (CH3)3NH, (CH3)4N, Ga, Ge and P; n represents the cation valence;
the ratio of b:a is in a range from greater than or equal to 1 and less than or equal to 5; and x represents the moles of water entrained into the zeolite framework.
Ma/n[AlO2)a(SiO2)b].cndot.xH2O
where M represents one or more cations selected from the group consisting of Na, K, Mg, Ca, Sr, Li, Ba,NH4, CH3NH3, (CH3)3NH, (CH3)4N, Ga, Ge and P; n represents the cation valence;
the ratio of b:a is in a range from greater than or equal to 1 and less than or equal to 5; and x represents the moles of water entrained into the zeolite framework.
127. The method of claim 126, wherein the aqueous zeolite suspension comprises zeolite selected from the goup consisting of analcime, bikitaite, brewsterite, chabazite, clinoptilolite, faujasite, hanmotome, heulandite, laumontite, mesolite, natrolite, paulingite, phillipsite, scolecite, stellerite, stilbite, and thomsonite.
128. The method of claim 126 further comprising mixing zeolite with a mixing fluid to form the aqueous zeolite suspension.
129. The method of claim 128 wherein the aqueous zeolite suspension is formed by mixing zeoite in an amount of from about 40 to about 50 by weight percent with the mixing fluid.
130. The method of claim 128 wherein the mixing fluid comprises water.
131. The method of claim 128 wherein the aqueous zeolite suspension is stable for at least two weeks before the blending with the cement mix.
132. The method of claim 125 wherein the base blend comprises at least one cementitious material.
133. The method of claim 132 wherein the cement mix further comprises hydrated lime.
134. The method of claim 125 wherein the blending further comprises blending the aqueous zeolite suspension in an amount of from about 1% to about 150% by weight of the base blend with the cement mix.
135. The method of claim 125 further comprising mixing the aqueous zeolite suspension with a mixing fluid before the blending of the aqueous zeolite suspension with the cement mix.
136. The method of claim 135 wherein the mixing fluid comprises water.
137. The method of claim 135 further comprising mixing the cement mix with a mixing fluid before the blending of the cement mix with the aqueous zeolite suspension.
138. The method of claim 125 further comprising mixing the cement mix with a mixing fluid before the blending of the cement mix with the aqueous zeolite suspension.
139. The method of claim 125 further comprising adding lightweight materials to the aqueous zeolite suspension prior to the blending of the aqueous zeolite suspension with the cement mix.
140. The method of claim 139 further comprising adding the lightweight materials to the aqueous zeolite suspension in an amount of from about 1 % to about 70% by weight of the base blend comprising the cement mix.
141. The method of claim 139 further comprising mixing zeolite with a mixing fluid to form the aqueous zeolite suspension; and adding at least one lightweight material to the aqueous zeolite suspension.
142. The method of claim 141 further comprising mixing the cement mix with a mixing fluid prior to the blending of the aqueous zeolite suspension with the cement mix.
143. The method of claim 142 further comprising blending the aqueous zeolite suspension with the cement mix to form a cement composition having a density less than about 12 lb/gal.
144. A method for making a foamed cement composition comprising:
mixing a cement mix comprising a base blend comprising zeolite and at least one cementitious material with a mixing fluid to form an unfoamed cement composition; and foaming the unfoamed cement composition to form the foamed cement composition.
mixing a cement mix comprising a base blend comprising zeolite and at least one cementitious material with a mixing fluid to form an unfoamed cement composition; and foaming the unfoamed cement composition to form the foamed cement composition.
145. The method of claim 144 wherein the cement mix further comprises bentonite.
146. The method of claim 144 wherein the foamed cement composition has a density of at least 8 lb/gal.
147. The method of claim 144 wherein the base blend comprises from about 20 to about 40 weight percent zeolite.
148. The method of claim 144 further comprising blending the cement mix with an aqueous zeolite suspension prior to the foaming.
149. The method of claim 148 further comprising forming the aqueous zeolite suspension by mixing zeolite in an amount of from about 40 to about 50 weight percent with a mixing fluid.
150. The method of claim 148 wherein the foam cement composition is stabilized by the zeolite in the aqueous zeolite suspension.
151. The method of claim 144 wherein the foam cement composition is stabilized by the zeolite in the base blend.
152. The method of claim 144 further comprising preparing the base blend by mixing the zeolite and the at least one cementitious material.
153. The method of claim 152 further comprising mixing bentonite with the base blend.
154. The method of claim 152 further comprising mixing the zeolite in an amount from about 20 to about 40 weight percent with the at least one cementitious material.
155. A cement composition comprising:
zeolite, cementitious material, and a mixing fluid.
zeolite, cementitious material, and a mixing fluid.
156. The cement composition of claim 155 wherein the zeolite is represented by the formula:
Ma/n[(AlO2)a(SiO2)b].cndot.xH2O
where M represents one or more cations selected from the group consisting of Na, K, Mg, Ca, Sr, Li, Ba, NH4, CH3NH3, (CH3)3NH, (CH3)4N, Ga, Ge and P; n represents the canon valence; the ratio of b:a is in a range from greater than or equal to 1 and less than or equal to 5; and x represents the moles of water entrained into the zeolite framework.
Ma/n[(AlO2)a(SiO2)b].cndot.xH2O
where M represents one or more cations selected from the group consisting of Na, K, Mg, Ca, Sr, Li, Ba, NH4, CH3NH3, (CH3)3NH, (CH3)4N, Ga, Ge and P; n represents the canon valence; the ratio of b:a is in a range from greater than or equal to 1 and less than or equal to 5; and x represents the moles of water entrained into the zeolite framework.
157. The cement composition of claim 155, wherein the zeolite is selected from the group consisting of analcime, bikitaite, brewsterite, chabazite, clinoptilolite, faujasite, harmotome, heulandite, laumontite, mesolite, natrolite, paulingite, phillipsite, scolecite, stellerite, stilbite, and thomsonite.
158. The cement composition of claim 155 wherein the zeolite is present in the cement composition as an additive.
159. The cement composition of claim 158 further comprising a lightweight additive.
160. The cement composition of claim 158 further comprising a dispersant.
161. The cement composition of claim 155 wherein the at least one cementitious material is selected from the goup consisting of micronized cement, Portland cement, pozzolan cement, gypsum cement, aluminous cement, silica cement, and alkaline cement.
162. The cement composition of claim 161 further comprising fly ash.
163. The cement composition of claim 155 further comprising at least one accelerating additive.
164. The cement composition of claim 163 wherein the at least one accelerating additive is selected from the goup consisting of sodium sulfate, sodium carbonate, calcium sulfate, calcium carbonate, potassium sulfate, and potassium carbonate.
165. The cement composition of claim 164 wherein the cement composition comprises at least two accelerating additives selected from the goup consisting of sodium sulfate, sodium carbonate, calcium sulfate, calcium carbonate, potassium sulfate, and potassium carbonate.
166. The cement composition of claim 165 wherein at least one of the accelerating additives is selected from the goup consisting of sodium sulfate, calcium sulfate, and potassium sulfate; and at least one of the accelerating additives is selected from the goup consisting of sodium carbonate, calcium carbonate, and potassium carbonate.
167. The cement composition of claim 155 further comprising a fluid loss control additive selected from the goup consisting of anionic water based soluble polymers, hydrophobically modified anionic water based soluble polymers, non-ionic water based soluble polymers and hydrophobically modified non-ionic water based soluble polymers.
168. The cement composition of claim 155 further comprising a fluid loss control additive selected from the goup consisting of hydroxyethylcellulose, hydrophobically modified hydroxyethylcellulose, carboxymethylhydroxyethylcellulose, guar, modified guar, polyvinyl alcohol, montmorillonite clay, anhydrous sodium silicate, grafted polymers prepared by the polymerization of monomers or salts of monomers of N,N-dimethylacrylamide, 2-acrylamido-2-methylpropanesulfonic acid and acrylonitrile having a lignin or lignite or other backbone, and copolymers or salts of copolymers of N,N-dimethylacrylamide (NNDMA) and 2-acrylamido, 2-methyl propane sulfonic acid (AMPS).
169. The cement composition of claim 155 wherein a flow enhancing agent is absorbed on the zeolite.
170. The cement composition of claim 155 wherein the cement composition has a density up to about 13.5 lb/gal.
171. The cement composition of claim 155 wherein the zeolite has a mean particle size of about 100 microns or less.
172. The cement composition of claim 155 wherein the zeolite has a mean particle size of from about 3 microns to about 15 microns.
173. The cement composition of claim 155 wherein the mixing fluid comprises water.
174. The cement composition of claim 173 wherein the mixing fluid further comprises a defoaming agent.
175. The cement composition of claim 173 wherein the mixing fluid further comprises bentonite.
176. A cement mix comprising a base blend comprising zeolite and at least one cementitious material.
177. The cement mix of claim 176 wherein the zeolite is represented by the formula:
Ma/n[(AlO2)a(SiO2)].cndot.xH2O
where M represents one or more canons selected from the group consisting of Na, K, Mg, Ca, Sr, Li, Ba, NH4, CH3NH3, (CH3)3NH, (CH3)4N, Ga, Ge and P; n represents the canon valence; the ratio of b:a is in a range from greater than or equal to 1 and less than or equal to 5; and x represents the moles of water entrained into the zeolite framework.
Ma/n[(AlO2)a(SiO2)].cndot.xH2O
where M represents one or more canons selected from the group consisting of Na, K, Mg, Ca, Sr, Li, Ba, NH4, CH3NH3, (CH3)3NH, (CH3)4N, Ga, Ge and P; n represents the canon valence; the ratio of b:a is in a range from greater than or equal to 1 and less than or equal to 5; and x represents the moles of water entrained into the zeolite framework.
178. The cement mix of claim 176, wherein the zeolite is selected from the group consisting of analcime, bikitaite, brewsterite, chabazite, clinoptilolite, faujasite, harmotome, heulandite, laumontite, mesolite, natrolite, paulingite, phillipsite, scolecite, stellerite, stilbite, and thomsonite.
179. The cement mix of claim 176 wherein the base blend comprises from about 20 to about 50 weight percent zeolite.
180. The cement mix of claim 176 wherein the base blend comprises from about 30 to about 90 weight percent zeolite.
181. The cement mix of claim 176 wherein the base blend comprises from about 5 to about 75 weight percent zeolite.
182. The cement mix of claim 176 wherein the base blend comprises from about 50 to about 75 weight percent zeolite.
183. The cement mix of claim 176 wherein the base blend comprises from about 0.5 to about 35 weight percent zeolite.
184. The cement mix of claim 176 wherein the base blend comprises at least one cementinous material selected from the group consisting of micronized cement, Portland cement, pozzolan cement, gypsum cement, aluminous cement, silica cement, and alkaline cement.
185. The cement mix of claim 184 wherein the cement mix further comprises fly ash.
186. The cement mix of claim 176 further comprising at least one accelerating additive.
187. The cement mix of claim 186 wherein the at least one accelerating additive is selected from the group consisting of sodium sulfate, sodium carbonate, calcium sulfate, calcium carbonate, potassium sulfate, and potassium carbonate.
188. The cement mix of claim 187 further comprising at least two accelerating additives selected from the group consisting of sodium sulfate, sodium carbonate, calcium sulfate, calcium carbonate, potassium sulfate, and potassium carbonate.
189. The cement mix of claim 188 wherein at least one of the accelerating additives is selected from the group consisting of sodium sulfate, calcium sulfate, and potassium sulfate; and at least one of the accelerating additives is selected from the group consisting of sodium carbonate, calcium carbonate, and potassium carbonate.
190. The cement mix of claim 176 further comprising at least one accelerating additive in an amount of from about 0.5% to about 10% by weight of the base blend.
191. The cement mix of claim 190 wherein the accelerating additive is present in an amount of from about 3% to about 7% by weight of the base blend.
192. The cement mix of claim 176 further comprising a fluid loss control additive selected from the group consisting of anionic water based soluble polymers, hydrophobically modified anionic water based soluble polymers, non-ionic water based soluble polymers and hydrophobically modified non-ionic water based soluble polymers.
193. The cement mix of claim 176 further comprising a fluid loss control additive selected from the group consisting of hydroxyethylcellulose, hydrophobically modified hydroxyethylcellulose, carboxymethylhydroxyethylcellulose, guar, modified guar, polyvinyl alcohol, montmorillonite clay, anhydrous sodium silicate, grafted polymers prepared by the polymerization of monomers or salts of monomers of N,N-dimethylacrylamide, 2-acrylamido-2-methylpropanesulfonic acid and acrylonitrile having a lignin or lignite or other backbone, and copolymers or salts of copolymers of N,N-dimethylacrylamide (NNDMA) and 2-acrylamido, 2-methyl propane sulfonic acid (AMPS).
194. The cement mix of claim 176 further comprising at least one fluid loss control additive in an amount of from about 0.5% to about 1.0% by weight of the base blend.
195. The cement mix of claim 176 wherein a flow enhancing agent is absorbed on the zeolite.
196. The cement mix of claim 195 wherein the flow enhancing agent is present in an amount of from about 15% to about 25% by weight of the zeolite.
197. The cement mix of claim 176 wherein the zeolite has a mean particle size of about 100 microns or less.
198. The cement mix of claim 176 wherein the zeolite has a mean particle size of from about 3 microns to about 15 microns.
199. A method of sealing a subterranean zone penetrated by a wellbore comprising:
mixing a base blend comprising at least one cementitious material with zeolite to form a cement mix;
mixing the cement mix with a mixing fluid to form a cement composition;
placing the cement composition into the subterranean zone; and allowing the cement composition to set therein.
mixing a base blend comprising at least one cementitious material with zeolite to form a cement mix;
mixing the cement mix with a mixing fluid to form a cement composition;
placing the cement composition into the subterranean zone; and allowing the cement composition to set therein.
200. The method of claim 199 wherein the cement mix comprises a base blend comprising 100 weight percent of the at least one cementitious material.
201. The method of claim 200 wherein the mixing of the base blend with zeolite further comprises mixing the base blend with zeolite in an amount of from about 5% to about 25% by weight of the base blend.
202. The method of claim 201 wherein the mixing of the base blend with zeolite further comprises mixing a lightweight additive with the base blend and the zeolite.
203. The method of claim 201 wherein the mixing of the base blend with zeolite further comprises mixing a dispersant with the base blend and the zeolite.
204. A method for making a cement composition comprising mixing a base blend comprising cementitious material with zeolite and a mixing fluid.
205. The method of claim 204 wherein the base blend comprises 100 weight percent of the at least one cementitious material.
206. The method of claim 205 wherein the mixing of the base blend with zeolite further comprises mixing the base blend with zeolite in an amount of from about 5% to about 25% by weight of the base blend.
207. The method of claim 206 wherein the mixing of the base blend with zeolite further comprises mixing a lightweight additive with the base blend and the zeolite.
208. The method of claim 206 wherein the mixing of the base blend with zeolite further comprises mixing a dispersant with the base blend and the zeolite.
209. A cement mix comprising:
a base blend comprising at least one cementitious material; and zeolite.
a base blend comprising at least one cementitious material; and zeolite.
210. The cement mix of claim 209 wherein the base blend comprises 100 weight percent of the least one cementitious material.
211. The cement mix of claim 210 wherein the zeolite is present in an amount from about 5%
to about 25% by weight of the base blend.
to about 25% by weight of the base blend.
212. The cement mix of claim 210 further comprising a lightweight additive.
213. The cement mix of claim 210 further comprising a dispersant.
214. A method of sealing a subterranean zone penetrated by a wellbore comprising:
mixing a cement mix comprising a base blend comprising at least one cementitious material with an aqueous zeolite suspension and a mixing fluid to form an unfoamed cement composition;
foaming the unfoamed cement composition to form a foamed cement composition;
placing the foamed cement composition into the subterranean zone; and allowing the foamed cement composition to set therein.
mixing a cement mix comprising a base blend comprising at least one cementitious material with an aqueous zeolite suspension and a mixing fluid to form an unfoamed cement composition;
foaming the unfoamed cement composition to form a foamed cement composition;
placing the foamed cement composition into the subterranean zone; and allowing the foamed cement composition to set therein.
215. The method of claim 214 wherein the cement mix comprises a base blend comprising 100 weight percent of the at least one cementitious material.
216. The method of claim 214 wherein the foamed cement composition is stabilized by the zeolite in the aqueous zeolite suspension.
217. A method for making a foamed cement composition comprising:
mixing a cement mix comprising a base blend comprising at least one cementitious material with an aqueous zeolite suspension and a mixing fluid to form an unfoamed cement composition; and foaming the unfoamed cement composition to form the foamed cement composition.
mixing a cement mix comprising a base blend comprising at least one cementitious material with an aqueous zeolite suspension and a mixing fluid to form an unfoamed cement composition; and foaming the unfoamed cement composition to form the foamed cement composition.
218. The method of claim 217 wherein the cement mix comprises a base blend comprising 100 weight percent of the at least one cementitious material.
219. The method of claim 217 further comprising forming the aqueous zeolite suspension by mixing zeolite in an amount of from about 40 to about 50 weight percent with a mixing fluid.
220. The method of claim 217 wherein the foamed cement composition is stabilized by the zeolite in the aqueous zeolite suspension.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/686,098 | 2003-10-15 | ||
US10/686,098 US6964302B2 (en) | 2002-12-10 | 2003-10-15 | Zeolite-containing cement composition |
PCT/GB2004/004284 WO2005040550A1 (en) | 2003-10-15 | 2004-10-11 | Zeolite-containing cement composition |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2541891A1 true CA2541891A1 (en) | 2005-05-06 |
CA2541891C CA2541891C (en) | 2012-06-05 |
Family
ID=34520712
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2541891 Active CA2541891C (en) | 2003-10-15 | 2004-10-11 | Zeolite-containing cement composition |
Country Status (3)
Country | Link |
---|---|
US (2) | US6964302B2 (en) |
CA (1) | CA2541891C (en) |
WO (1) | WO2005040550A1 (en) |
Families Citing this family (148)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6617175B1 (en) * | 2002-05-08 | 2003-09-09 | Advanced Technology Materials, Inc. | Infrared thermopile detector system for semiconductor process monitoring and control |
US6964302B2 (en) * | 2002-12-10 | 2005-11-15 | Halliburton Energy Services, Inc. | Zeolite-containing cement composition |
US7140440B2 (en) * | 2002-12-10 | 2006-11-28 | Halliburton Energy Services, Inc. | Fluid loss additives for cement slurries |
US6989057B2 (en) * | 2002-12-10 | 2006-01-24 | Halliburton Energy Services, Inc. | Zeolite-containing cement composition |
US7147067B2 (en) * | 2002-12-10 | 2006-12-12 | Halliburton Energy Services, Inc. | Zeolite-containing drilling fluids |
US7150321B2 (en) * | 2002-12-10 | 2006-12-19 | Halliburton Energy Services, Inc. | Zeolite-containing settable spotting fluids |
US7544640B2 (en) * | 2002-12-10 | 2009-06-09 | Halliburton Energy Services, Inc. | Zeolite-containing treating fluid |
US7048053B2 (en) * | 2002-12-10 | 2006-05-23 | Halliburton Energy Services, Inc. | Zeolite compositions having enhanced compressive strength |
US7140439B2 (en) * | 2002-12-10 | 2006-11-28 | Halliburton Energy Services, Inc. | Zeolite-containing remedial compositions |
US7021380B2 (en) | 2003-06-27 | 2006-04-04 | Halliburton Energy Services, Inc. | Compositions comprising set retarder compositions and associated methods |
US7073585B2 (en) * | 2003-06-27 | 2006-07-11 | Halliburton Energy Services, Inc. | Cement compositions with improved fluid loss characteristics and methods of cementing in surface and subterranean applications |
US7413014B2 (en) * | 2003-12-19 | 2008-08-19 | Halliburton Energy Services, Inc. | Foamed fly ash cement compositions and methods of cementing |
US7137448B2 (en) * | 2003-12-22 | 2006-11-21 | Bj Services Company | Method of cementing a well using composition containing zeolite |
EP1547985A1 (en) * | 2003-12-23 | 2005-06-29 | Sika Technology AG | Dry admixture for hydraulic binders |
US7607482B2 (en) | 2005-09-09 | 2009-10-27 | Halliburton Energy Services, Inc. | Settable compositions comprising cement kiln dust and swellable particles |
US9512346B2 (en) | 2004-02-10 | 2016-12-06 | Halliburton Energy Services, Inc. | Cement compositions and methods utilizing nano-hydraulic cement |
US7770455B2 (en) * | 2004-03-16 | 2010-08-10 | Tribo Flow Separations, Llc | Instruments, related systems, and methods for monitoring or controlling foaming |
US20050241538A1 (en) * | 2004-04-28 | 2005-11-03 | Vargo Richard F Jr | Methods of making cement compositions using liquid additives containing lightweight beads |
US20050241545A1 (en) * | 2004-04-28 | 2005-11-03 | Vargo Richard F Jr | Methods of extending the shelf life of and revitalizing lightweight beads for use in cement compositions |
US7297664B2 (en) * | 2004-07-28 | 2007-11-20 | Halliburton Energy Services, Inc. | Cement-free zeolite and fly ash settable fluids and methods therefor |
US7182137B2 (en) * | 2004-09-13 | 2007-02-27 | Halliburton Energy Services, Inc. | Cementitious compositions containing interground cement clinker and zeolite |
US7219733B2 (en) * | 2004-09-29 | 2007-05-22 | Halliburton Energy Services, Inc. | Zeolite compositions for lowering maximum cementing temperature |
US20100044057A1 (en) * | 2004-10-20 | 2010-02-25 | Dealy Sears T | Treatment Fluids Comprising Pumicite and Methods of Using Such Fluids in Subterranean Formations |
US7293609B2 (en) * | 2004-10-20 | 2007-11-13 | Halliburton Energy Services, Inc. | Treatment fluids comprising vitrified shale and methods of using such fluids in subterranean formations |
US9512345B2 (en) | 2004-10-20 | 2016-12-06 | Halliburton Energy Services, Inc. | Settable spacer fluids comprising pumicite and methods of using such fluids in subterranean formations |
US7219732B2 (en) * | 2004-12-02 | 2007-05-22 | Halliburton Energy Services, Inc. | Methods of sequentially injecting different sealant compositions into a wellbore to improve zonal isolation |
US7350573B2 (en) * | 2005-02-09 | 2008-04-01 | Halliburton Energy Services, Inc. | Servicing a wellbore with wellbore fluids comprising perlite |
US7373981B2 (en) * | 2005-02-14 | 2008-05-20 | Halliburton Energy Services, Inc. | Methods of cementing with lightweight cement compositions |
US7390356B2 (en) * | 2005-03-11 | 2008-06-24 | Halliburton Energy Services, Inc. | Compositions for high temperature lightweight cementing |
US7398827B2 (en) * | 2005-03-11 | 2008-07-15 | Halliburton Energy Services, Inc. | Methods for high temperature lightweight cementing |
JP2007018198A (en) * | 2005-07-06 | 2007-01-25 | Sony Corp | Device for generating index information with link information, device for generating image data with tag information, method for generating index information with link information, method for generating image data with tag information, and program |
US7789150B2 (en) | 2005-09-09 | 2010-09-07 | Halliburton Energy Services Inc. | Latex compositions comprising pozzolan and/or cement kiln dust and methods of use |
US7213646B2 (en) * | 2005-09-09 | 2007-05-08 | Halliburton Energy Services, Inc. | Cementing compositions comprising cement kiln dust, vitrified shale, zeolite, and/or amorphous silica utilizing a packing volume fraction, and associated methods |
US8281859B2 (en) | 2005-09-09 | 2012-10-09 | Halliburton Energy Services Inc. | Methods and compositions comprising cement kiln dust having an altered particle size |
US8403045B2 (en) | 2005-09-09 | 2013-03-26 | Halliburton Energy Services, Inc. | Settable compositions comprising unexpanded perlite and methods of cementing in subterranean formations |
US9006155B2 (en) | 2005-09-09 | 2015-04-14 | Halliburton Energy Services, Inc. | Placing a fluid comprising kiln dust in a wellbore through a bottom hole assembly |
US7478675B2 (en) | 2005-09-09 | 2009-01-20 | Halliburton Energy Services, Inc. | Extended settable compositions comprising cement kiln dust and associated methods |
US8333240B2 (en) | 2005-09-09 | 2012-12-18 | Halliburton Energy Services, Inc. | Reduced carbon footprint settable compositions for use in subterranean formations |
US9676989B2 (en) | 2005-09-09 | 2017-06-13 | Halliburton Energy Services, Inc. | Sealant compositions comprising cement kiln dust and tire-rubber particles and method of use |
US9023150B2 (en) | 2005-09-09 | 2015-05-05 | Halliburton Energy Services, Inc. | Acid-soluble cement compositions comprising cement kiln dust and/or a natural pozzolan and methods of use |
US8950486B2 (en) | 2005-09-09 | 2015-02-10 | Halliburton Energy Services, Inc. | Acid-soluble cement compositions comprising cement kiln dust and methods of use |
US7077203B1 (en) * | 2005-09-09 | 2006-07-18 | Halliburton Energy Services, Inc. | Methods of using settable compositions comprising cement kiln dust |
US8505629B2 (en) | 2005-09-09 | 2013-08-13 | Halliburton Energy Services, Inc. | Foamed spacer fluids containing cement kiln dust and methods of use |
US8609595B2 (en) | 2005-09-09 | 2013-12-17 | Halliburton Energy Services, Inc. | Methods for determining reactive index for cement kiln dust, associated compositions, and methods of use |
US8505630B2 (en) | 2005-09-09 | 2013-08-13 | Halliburton Energy Services, Inc. | Consolidating spacer fluids and methods of use |
US9150773B2 (en) | 2005-09-09 | 2015-10-06 | Halliburton Energy Services, Inc. | Compositions comprising kiln dust and wollastonite and methods of use in subterranean formations |
US8522873B2 (en) | 2005-09-09 | 2013-09-03 | Halliburton Energy Services, Inc. | Spacer fluids containing cement kiln dust and methods of use |
US8327939B2 (en) | 2005-09-09 | 2012-12-11 | Halliburton Energy Services, Inc. | Settable compositions comprising cement kiln dust and rice husk ash and methods of use |
US7743828B2 (en) | 2005-09-09 | 2010-06-29 | Halliburton Energy Services, Inc. | Methods of cementing in subterranean formations using cement kiln cement kiln dust in compositions having reduced Portland cement content |
US8672028B2 (en) | 2010-12-21 | 2014-03-18 | Halliburton Energy Services, Inc. | Settable compositions comprising interground perlite and hydraulic cement |
US9051505B2 (en) | 2005-09-09 | 2015-06-09 | Halliburton Energy Services, Inc. | Placing a fluid comprising kiln dust in a wellbore through a bottom hole assembly |
US8297357B2 (en) | 2005-09-09 | 2012-10-30 | Halliburton Energy Services Inc. | Acid-soluble cement compositions comprising cement kiln dust and/or a natural pozzolan and methods of use |
US8555967B2 (en) | 2005-09-09 | 2013-10-15 | Halliburton Energy Services, Inc. | Methods and systems for evaluating a boundary between a consolidating spacer fluid and a cement composition |
US7607484B2 (en) | 2005-09-09 | 2009-10-27 | Halliburton Energy Services, Inc. | Foamed cement compositions comprising oil-swellable particles and methods of use |
US9809737B2 (en) | 2005-09-09 | 2017-11-07 | Halliburton Energy Services, Inc. | Compositions containing kiln dust and/or biowaste ash and methods of use |
US8307899B2 (en) | 2005-09-09 | 2012-11-13 | Halliburton Energy Services, Inc. | Methods of plugging and abandoning a well using compositions comprising cement kiln dust and pumicite |
US7296626B2 (en) * | 2005-11-08 | 2007-11-20 | Halliburton Energy Services, Inc. | Liquid additive for reducing water-soluble chromate |
CN100343358C (en) * | 2005-12-02 | 2007-10-17 | 大庆石油管理局 | Deep well low-density cement slurry |
US20070130608A1 (en) * | 2005-12-05 | 2007-06-07 | Samsung Electronics Co., Ltd. | Method and apparatus for overlaying broadcast video with application graphic in DTV |
US7338923B2 (en) * | 2006-04-11 | 2008-03-04 | Halliburton Energy Services, Inc. | Settable drilling fluids comprising cement kiln dust |
CA2545810C (en) * | 2006-05-04 | 2011-07-12 | The Mosaic Company | Cementitious composition for use in elevated to fully saturated salt environments |
US7575055B2 (en) * | 2006-07-05 | 2009-08-18 | Halliburton Energy Services, Inc. | Storable nonaqueous cement slurries and methods of using same |
US7789149B2 (en) * | 2006-11-03 | 2010-09-07 | Halliburton Energy Services, Inc. | Methods of servicing wellbore with composition comprising ultra low density thermatek® slurries |
GB0623232D0 (en) * | 2006-11-22 | 2007-01-03 | Dow Corning | Cementitious materials |
US7523784B2 (en) | 2007-01-11 | 2009-04-28 | Halliburton Energy Services, Inc. | Method of using humic acid grafted fluid loss control additives in cementing operations |
US7549320B2 (en) * | 2007-01-11 | 2009-06-23 | Halliburton Energy Services, Inc. | Measuring cement properties |
US7576040B2 (en) * | 2007-01-11 | 2009-08-18 | Halliburton Energy Services, Inc. | Cement compositions comprising humic acid grafted fluid loss control additives |
US7360598B1 (en) | 2007-02-05 | 2008-04-22 | Halliburton Energy Services, Inc, | Method of using lignite grafted fluid loss control additives in cementing operations |
US7388045B1 (en) | 2007-02-05 | 2008-06-17 | Halliburton Energy Services, Inc. | Cement compositions comprising lignite grafted fluid loss control additives |
US7967909B2 (en) * | 2007-02-26 | 2011-06-28 | Baker Hughes Incorporated | Method of cementing within a gas or oil well |
KR100760039B1 (en) * | 2007-04-20 | 2007-09-18 | 박민화 | Manufacture method of quick setting light weight bubble cement which superior to insulating effect |
US20080280786A1 (en) * | 2007-05-07 | 2008-11-13 | Halliburton Energy Services, Inc. | Defoamer/antifoamer compositions and methods of using same |
US8685903B2 (en) | 2007-05-10 | 2014-04-01 | Halliburton Energy Services, Inc. | Lost circulation compositions and associated methods |
US9512351B2 (en) | 2007-05-10 | 2016-12-06 | Halliburton Energy Services, Inc. | Well treatment fluids and methods utilizing nano-particles |
US8476203B2 (en) | 2007-05-10 | 2013-07-02 | Halliburton Energy Services, Inc. | Cement compositions comprising sub-micron alumina and associated methods |
US8586512B2 (en) | 2007-05-10 | 2013-11-19 | Halliburton Energy Services, Inc. | Cement compositions and methods utilizing nano-clay |
US9199879B2 (en) | 2007-05-10 | 2015-12-01 | Halliburton Energy Serives, Inc. | Well treatment compositions and methods utilizing nano-particles |
US9206344B2 (en) | 2007-05-10 | 2015-12-08 | Halliburton Energy Services, Inc. | Sealant compositions and methods utilizing nano-particles |
US7753618B2 (en) | 2007-06-28 | 2010-07-13 | Calera Corporation | Rocks and aggregate, and methods of making and using the same |
BRPI0812797A2 (en) | 2007-06-28 | 2014-12-02 | Calera Corp | DESALINIZATION SYSTEMS AND METHODS INCLUDING CARBONATE COMPOSITE PRECIPITATION |
CA2641472C (en) * | 2007-10-22 | 2014-11-25 | Sanjel Limited Partnership | Pumice containing compositions for cementing a well |
US7749476B2 (en) | 2007-12-28 | 2010-07-06 | Calera Corporation | Production of carbonate-containing compositions from material comprising metal silicates |
JP2012513944A (en) | 2007-12-28 | 2012-06-21 | カレラ コーポレイション | How to capture CO2 |
US20100239467A1 (en) | 2008-06-17 | 2010-09-23 | Brent Constantz | Methods and systems for utilizing waste sources of metal oxides |
US7754169B2 (en) | 2007-12-28 | 2010-07-13 | Calera Corporation | Methods and systems for utilizing waste sources of metal oxides |
KR20110033822A (en) * | 2008-05-29 | 2011-03-31 | 칼레라 코포레이션 | Rocks and aggregate, and methods of making and using the same |
US7740070B2 (en) * | 2008-06-16 | 2010-06-22 | Halliburton Energy Services, Inc. | Wellbore servicing compositions comprising a density segregation inhibiting composite and methods of making and using same |
EP2212033A4 (en) | 2008-07-16 | 2013-04-24 | Calera Corp | Low-energy 4-cell electrochemical system with carbon dioxide gas |
US7993500B2 (en) | 2008-07-16 | 2011-08-09 | Calera Corporation | Gas diffusion anode and CO2 cathode electrolyte system |
KR20110038691A (en) | 2008-07-16 | 2011-04-14 | 칼레라 코포레이션 | Co2 utilization in electrochemical systems |
CA2700644A1 (en) | 2008-09-11 | 2010-03-18 | Calera Corporation | Co2 commodity trading system and method |
US7939336B2 (en) | 2008-09-30 | 2011-05-10 | Calera Corporation | Compositions and methods using substances containing carbon |
US8869477B2 (en) | 2008-09-30 | 2014-10-28 | Calera Corporation | Formed building materials |
WO2010039903A1 (en) | 2008-09-30 | 2010-04-08 | Calera Corporation | Co2-sequestering formed building materials |
US7815880B2 (en) | 2008-09-30 | 2010-10-19 | Calera Corporation | Reduced-carbon footprint concrete compositions |
US7799128B2 (en) * | 2008-10-10 | 2010-09-21 | Roman Cement, Llc | High early strength pozzolan cement blends |
CN101724386B (en) * | 2008-10-22 | 2013-02-27 | 中国石油化工股份有限公司河南油田分公司第二采油厂 | Low-temperature filling sand control agent |
US9133581B2 (en) | 2008-10-31 | 2015-09-15 | Calera Corporation | Non-cementitious compositions comprising vaterite and methods thereof |
EP2620207A3 (en) | 2008-10-31 | 2013-09-18 | Calera Corporation | Non-cementitious compositions comprising CO2 sequestering additives |
EP2291550A4 (en) | 2008-12-23 | 2011-03-09 | Calera Corp | Low-energy electrochemical hydroxide system and method |
WO2010093716A1 (en) | 2009-02-10 | 2010-08-19 | Calera Corporation | Low-voltage alkaline production using hydrogen and electrocatlytic electrodes |
US8601882B2 (en) | 2009-02-20 | 2013-12-10 | Halliburton Energy Sevices, Inc. | In situ testing of mechanical properties of cementitious materials |
CA2694959A1 (en) | 2009-03-02 | 2010-09-02 | Calera Corporation | Gas stream multi-pollutants control systems and methods |
WO2010104989A1 (en) | 2009-03-10 | 2010-09-16 | Calera Corporation | Systems and methods for processing co2 |
US8936081B2 (en) | 2009-04-09 | 2015-01-20 | Schlumberger Technology Corporation | Compositions and methods for servicing subterranean wells |
US20100270016A1 (en) * | 2009-04-27 | 2010-10-28 | Clara Carelli | Compositions and Methods for Servicing Subterranean Wells |
US7993511B2 (en) | 2009-07-15 | 2011-08-09 | Calera Corporation | Electrochemical production of an alkaline solution using CO2 |
GB0914307D0 (en) * | 2009-08-15 | 2009-09-30 | Dow Corning | Antimicrobial quarternary ammonium silane compositions |
US8783091B2 (en) | 2009-10-28 | 2014-07-22 | Halliburton Energy Services, Inc. | Cement testing |
US8414700B2 (en) | 2010-07-16 | 2013-04-09 | Roman Cement, Llc | Narrow PSD hydraulic cement, cement-SCM blends, and methods for making same |
US9272953B2 (en) | 2010-11-30 | 2016-03-01 | Roman Cement, Llc | High early strength cement-SCM blends |
USRE49415E1 (en) | 2011-10-20 | 2023-02-14 | Roman Cement, Llc | Particle packed cement-SCM blends |
US8960013B2 (en) | 2012-03-01 | 2015-02-24 | Halliburton Energy Services, Inc. | Cement testing |
US9790132B2 (en) | 2012-03-09 | 2017-10-17 | Halliburton Energy Services, Inc. | Set-delayed cement compositions comprising pumice and associated methods |
US10082001B2 (en) | 2012-03-09 | 2018-09-25 | Halliburton Energy Services, Inc. | Cement set activators for cement compositions and associated methods |
US9227872B2 (en) | 2012-03-09 | 2016-01-05 | Halliburton Energy Services, Inc. | Cement set activators for set-delayed cement compositions and associated methods |
US9505972B2 (en) | 2012-03-09 | 2016-11-29 | Halliburton Energy Services, Inc. | Lost circulation treatment fluids comprising pumice and associated methods |
US9328583B2 (en) | 2012-03-09 | 2016-05-03 | Halliburton Energy Services, Inc. | Set-delayed cement compositions comprising pumice and associated methods |
US9212534B2 (en) | 2012-03-09 | 2015-12-15 | Halliburton Energy Services, Inc. | Plugging and abandoning a well using a set-delayed cement composition comprising pumice |
US9371712B2 (en) | 2012-03-09 | 2016-06-21 | Halliburton Energy Services, Inc. | Cement set activators for set-delayed cement compositions and associated methods |
US9580638B2 (en) | 2012-03-09 | 2017-02-28 | Halliburton Energy Services, Inc. | Use of synthetic smectite in set-delayed cement compositions |
US9328281B2 (en) | 2012-03-09 | 2016-05-03 | Halliburton Energy Services, Inc. | Foaming of set-delayed cement compositions comprising pumice and hydrated lime |
US9255031B2 (en) | 2012-03-09 | 2016-02-09 | Halliburton Energy Services, Inc. | Two-part set-delayed cement compositions |
US9255454B2 (en) | 2012-03-09 | 2016-02-09 | Halliburton Energy Services, Inc. | Set-delayed cement compositions comprising pumice and associated methods |
US9534165B2 (en) | 2012-03-09 | 2017-01-03 | Halliburton Energy Services, Inc. | Settable compositions and methods of use |
US10195764B2 (en) | 2012-03-09 | 2019-02-05 | Halliburton Energy Services, Inc. | Set-delayed cement compositions comprising pumice and associated methods |
US9856167B2 (en) | 2012-03-09 | 2018-01-02 | Halliburton Energy Services, Inc. | Mitigation of contamination effects in set-delayed cement compositions comprising pumice and hydrated lime |
US8851173B2 (en) | 2012-03-09 | 2014-10-07 | Halliburton Energy Services, Inc. | Set-delayed cement compositions comprising pumice and associated methods |
US10202751B2 (en) | 2012-03-09 | 2019-02-12 | Halliburton Energy Services, Inc. | Set-delayed cement compositions comprising pumice and associated methods |
US8978761B2 (en) | 2012-03-27 | 2015-03-17 | Halliburton Energy Services, Inc. | Hydrated sheet silicate minerals for reducing permeability in a well |
TW201400023A (en) * | 2012-06-20 | 2014-01-01 | Agrofresh Inc | Particle size reduction |
US8794078B2 (en) | 2012-07-05 | 2014-08-05 | Halliburton Energy Services, Inc. | Cement testing |
CN104099071A (en) * | 2013-04-03 | 2014-10-15 | 中国石油天然气股份有限公司 | Horizontal well-cementation expandable cement mortar and preparation method thereof |
MX2016002546A (en) * | 2013-09-09 | 2016-10-13 | Halliburton Energy Services Inc | Cement set activators for cement compositions and associated methods. |
GB2534042B (en) * | 2013-09-20 | 2021-04-21 | Halliburton Energy Services Inc | Cement blends including inert microparticles |
WO2018017700A1 (en) | 2016-07-20 | 2018-01-25 | Hexion Inc. | Materials and methods of use as additives for oilwell cementing |
US10131575B2 (en) | 2017-01-10 | 2018-11-20 | Roman Cement, Llc | Use of quarry fines and/or limestone powder to reduce clinker content of cementitious compositions |
US11168029B2 (en) | 2017-01-10 | 2021-11-09 | Roman Cement, Llc | Use of mineral fines to reduce clinker content of cementitious compositions |
US10730805B2 (en) | 2017-01-10 | 2020-08-04 | Roman Cement, Llc | Use of quarry fines and/or limestone powder to reduce clinker content of cementitious compositions |
US10737980B2 (en) | 2017-01-10 | 2020-08-11 | Roman Cement, Llc | Use of mineral fines to reduce clinker content of cementitious compositions |
CN107502324B (en) * | 2017-08-22 | 2020-09-22 | 中国海洋石油集团有限公司 | Multi-effect additive for well cementation low-density cement slurry and preparation method thereof |
US11643588B2 (en) | 2017-12-04 | 2023-05-09 | Hexion Inc. | Multiple functional wellbore fluid additive |
US10150904B1 (en) * | 2018-03-30 | 2018-12-11 | King Fahd University Of Petroleum And Minerals | Nano zeolite cement additive and methods of use |
WO2020214164A1 (en) | 2019-04-17 | 2020-10-22 | Halliburton Energy Services, Inc. | Agglomerated zeolite catalyst for cement slurry yield enhancement |
CN110255992A (en) * | 2019-06-28 | 2019-09-20 | 介休鑫峪沟集团企业管理有限公司 | A kind of method that common yellow clay produces clay cement refining |
AU2022305107A1 (en) * | 2021-06-30 | 2023-12-07 | Sika Technology Ag | Cement slurry composition |
WO2023225394A1 (en) * | 2022-05-20 | 2023-11-23 | Schlumberger Technology Corporation | Lightweight composite cement compositions and methods of cementing wells with said compositions |
CN116553871B (en) * | 2023-05-11 | 2023-11-10 | 苏州太湖中法环境技术有限公司 | Nano silicon dioxide modified sludge peat cement material, preparation method and application |
Family Cites Families (136)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1943584A (en) * | 1929-03-28 | 1934-01-16 | Silica Products Co | Inorganic gel composition |
FR763998A (en) | 1932-11-17 | 1934-05-12 | Hydraulic binder for mortar or concrete | |
US2131338A (en) | 1935-12-23 | 1938-09-27 | Philadelphia Quartz Co | Consolidation of porous materials |
US2094316A (en) | 1936-03-06 | 1937-09-28 | Kansas City Testing Lab | Method of improving oil well drilling muds |
US2349049A (en) * | 1940-08-03 | 1944-05-16 | Lubri Gel Products Company | Salt water drilling mud |
US2662827A (en) * | 1946-03-12 | 1953-12-15 | Stanolind Oil & Gas Co | Well cementing |
US2727001A (en) | 1952-12-24 | 1955-12-13 | Sun Oil Co | Drilling fluid |
US2848084A (en) | 1956-04-23 | 1958-08-19 | Thew Shovel Co | Transversely engaged clutch with compensating means |
US3047493A (en) | 1958-05-26 | 1962-07-31 | Gulf Research Development Co | Drilling process and water base drilling muds |
US3065170A (en) | 1959-07-02 | 1962-11-20 | Jersey Prod Res Co | Drilling fluids for use in wells |
US3179528A (en) | 1962-11-26 | 1965-04-20 | Pan American Petroleum Corp | Low temperature cementing composition |
US3359225A (en) | 1963-08-26 | 1967-12-19 | Charles F Weisend | Cement additives containing polyvinylpyrrolidone and a condensate of sodium naphthalene sulfonate with formaldehyde |
US3293040A (en) | 1964-05-25 | 1966-12-20 | American Tansul Company | Method for chill-proofing beer with water soluble alkyl cellulose ethers |
US3694152A (en) | 1968-10-18 | 1972-09-26 | Snam Progetti | Process for producing synthetic zeolite |
US3888998A (en) | 1971-11-22 | 1975-06-10 | Procter & Gamble | Beverage carbonation |
US3781225A (en) | 1972-04-17 | 1973-12-25 | Mobil Oil Corp | Treatment of colloidal zeolites |
NL7306868A (en) * | 1973-05-17 | 1974-11-19 | ||
US3884302A (en) | 1974-05-29 | 1975-05-20 | Mobil Oil Corp | Well cementing process |
US3963508A (en) | 1974-11-18 | 1976-06-15 | Kaiser Aluminum & Chemical Corporation | Calcium aluminate cement |
US4054462A (en) | 1976-03-01 | 1977-10-18 | The Dow Chemical Company | Method of cementing |
JPS52117316A (en) | 1976-03-29 | 1977-10-01 | Matsushita Electric Works Ltd | Method of manufacturing hardened cement products |
US4217229A (en) | 1976-09-20 | 1980-08-12 | Halliburton Company | Oil well spacer fluids |
US4141843A (en) | 1976-09-20 | 1979-02-27 | Halliburton Company | Oil well spacer fluids |
US4650593A (en) | 1977-09-19 | 1987-03-17 | Nl Industries, Inc. | Water-based drilling fluids having enhanced fluid loss control |
CA1167403A (en) | 1979-07-10 | 1984-05-15 | Unilever Limited | Microbial heteropolysaccharide |
US4368134A (en) | 1980-03-10 | 1983-01-11 | Colgate Palmolive Company | Method for retarding gelation of bicarbonate-carbonate-zeolite-silicate crutcher slurries |
US4311607A (en) | 1980-03-10 | 1982-01-19 | Colgate Palmolive Company | Method for manufacture of non-gelling, stable zeolite - inorganic salt crutcher slurries |
US4372876A (en) | 1980-05-02 | 1983-02-08 | Uop Inc. | Zeolite molecular sieve adsorbent for an aqueous system |
US4363736A (en) | 1980-06-13 | 1982-12-14 | W. R. Grace & Co. | Fluid loss control system |
US4474667A (en) | 1981-02-27 | 1984-10-02 | W. R. Grace & Co. | Fluid loss control system |
DE3132928C1 (en) * | 1981-08-20 | 1983-01-13 | Degussa Ag, 6000 Frankfurt | Process for accelerating the setting of hydraulic cement mixtures |
FR2516526B1 (en) | 1981-11-16 | 1987-05-22 | Rhone Poulenc Spec Chim | WATER-SOLUBLE GUM COMPOSITIONS, THEIR PREPARATION AND THEIR USE |
US4444668A (en) | 1981-12-31 | 1984-04-24 | Halliburton Company | Well completion fluid compositions |
US4536297A (en) | 1982-01-28 | 1985-08-20 | Halliburton Company | Well drilling and completion fluid composition |
US4530402A (en) | 1983-08-30 | 1985-07-23 | Standard Oil Company | Low density spacer fluid |
US4482379A (en) | 1983-10-03 | 1984-11-13 | Hughes Tool Company | Cold set cement composition and method |
DE3344291A1 (en) | 1983-12-07 | 1985-06-13 | Skw Trostberg Ag, 8223 Trostberg | DISPERSING AGENT FOR SALTY SYSTEMS |
US4515635A (en) | 1984-03-23 | 1985-05-07 | Halliburton Company | Hydrolytically stable polymers for use in oil field cementing methods and compositions |
US4555269A (en) | 1984-03-23 | 1985-11-26 | Halliburton Company | Hydrolytically stable polymers for use in oil field cementing methods and compositions |
HU195457B (en) | 1984-04-02 | 1988-05-30 | Vizepitoeipari Troeszt | Process for removing suspended materials, biogene nutrients and soluted metal-compounds from waters containing organic and inorganic impurities |
US4552591A (en) | 1984-05-15 | 1985-11-12 | Petrolite Corporation | Oil field biocide composition |
US4557763A (en) | 1984-05-30 | 1985-12-10 | Halliburton Company | Dispersant and fluid loss additives for oil field cements |
US4632186A (en) | 1985-12-27 | 1986-12-30 | Hughes Tool Company | Well cementing method using an AM/AMPS fluid loss additive blend |
US4717488A (en) | 1986-04-23 | 1988-01-05 | Merck Co., Inc. | Spacer fluid |
US4703801A (en) | 1986-05-13 | 1987-11-03 | Halliburton Company | Method of reducing fluid loss in cement compositions which may contain substantial salt concentrations |
US4676317A (en) | 1986-05-13 | 1987-06-30 | Halliburton Company | Method of reducing fluid loss in cement compositions which may contain substantial salt concentrations |
SU1373781A1 (en) | 1986-05-15 | 1988-02-15 | Брянский технологический институт | Method of producing prestrained ferroconcrete articles |
DE3631764A1 (en) | 1986-09-18 | 1988-03-24 | Henkel Kgaa | USE OF SWELLABLE, SYNTHETIC LAYERED SILICATES IN AQUEOUS DRILL RING AND HOLE TREATMENT AGENTS |
AU608038B2 (en) | 1987-09-04 | 1991-03-21 | Sumitomo Chemical Company, Limited | A copper zeolite fungicide composition |
US4784693A (en) | 1987-10-30 | 1988-11-15 | Aqualon Company | Cementing composition and aqueous hydraulic cementing solution comprising water-soluble, nonionic hydrophobically modified hydroxyethyl cellulose |
US5807810A (en) | 1989-08-24 | 1998-09-15 | Albright & Wilson Limited | Functional fluids and liquid cleaning compositions and suspending media |
US4943544A (en) * | 1989-10-10 | 1990-07-24 | Corhart Refractories Corporation | High strength, abrasion resistant refractory castable |
US5238064A (en) | 1991-01-08 | 1993-08-24 | Halliburton Company | Squeeze cementing |
US5121795A (en) | 1991-01-08 | 1992-06-16 | Halliburton Company | Squeeze cementing |
US5123487A (en) | 1991-01-08 | 1992-06-23 | Halliburton Services | Repairing leaks in casings |
US5127473A (en) | 1991-01-08 | 1992-07-07 | Halliburton Services | Repair of microannuli and cement sheath |
US5125455A (en) | 1991-01-08 | 1992-06-30 | Halliburton Services | Primary cementing |
JP2957293B2 (en) | 1991-01-28 | 1999-10-04 | 株式会社テルナイト | Composition for drilling fluid |
AU1762692A (en) * | 1991-03-29 | 1992-11-02 | Raymond S. Chase | Silica-containing cement and concrete composition |
US5565647A (en) * | 1991-05-24 | 1996-10-15 | Giat Industries | Warhead with sequential shape charges |
JPH07115897B2 (en) * | 1991-08-05 | 1995-12-13 | 財団法人鉄道総合技術研究所 | Cement admixture for suppressing deterioration of concrete |
US5151131A (en) | 1991-08-26 | 1992-09-29 | Halliburton Company | Cement fluid loss control additives and methods |
US5527387A (en) * | 1992-08-11 | 1996-06-18 | E. Khashoggi Industries | Computer implemented processes for microstructurally engineering cementious mixtures |
US5549859A (en) * | 1992-08-11 | 1996-08-27 | E. Khashoggi Industries | Methods for the extrusion of novel, highly plastic and moldable hydraulically settable compositions |
US5340860A (en) | 1992-10-30 | 1994-08-23 | Halliburton Company | Low fluid loss cement compositions, fluid loss reducing additives and methods |
US5346012A (en) | 1993-02-01 | 1994-09-13 | Halliburton Company | Fine particle size cement compositions and methods |
US5529624A (en) | 1994-04-12 | 1996-06-25 | Riegler; Norbert | Insulation material |
CA2153372A1 (en) | 1994-07-08 | 1996-01-09 | Patrick Brown | Zeolite-hydraulic cement containment medium |
US5566760A (en) | 1994-09-02 | 1996-10-22 | Halliburton Company | Method of using a foamed fracturing fluid |
US5759964A (en) | 1994-09-28 | 1998-06-02 | Halliburton Energy Services, Inc. | High viscosity well treating fluids, additives and methods |
US5626665A (en) * | 1994-11-04 | 1997-05-06 | Ash Grove Cement Company | Cementitious systems and novel methods of making the same |
US5494513A (en) | 1995-07-07 | 1996-02-27 | National Research Council Of Canada | Zeolite-based lightweight concrete products |
US5716910A (en) | 1995-09-08 | 1998-02-10 | Halliburton Company | Foamable drilling fluid and methods of use in well drilling operations |
US5588489A (en) | 1995-10-31 | 1996-12-31 | Halliburton Company | Lightweight well cement compositions and methods |
US5711383A (en) * | 1996-04-19 | 1998-01-27 | Halliburton Company | Cementitious well drilling fluids and methods |
MX9602271A (en) | 1996-06-10 | 1998-04-30 | Cemex S A De C V | High resistance hydraulic cement with accelerated development. |
US5866517A (en) | 1996-06-19 | 1999-02-02 | Atlantic Richfield Company | Method and spacer fluid composition for displacing drilling fluid from a wellbore |
US5789352A (en) | 1996-06-19 | 1998-08-04 | Halliburton Company | Well completion spacer fluids and methods |
JPH1011487A (en) | 1996-06-25 | 1998-01-16 | Sekisui Chem Co Ltd | Design system for single component constituting assembly component |
US5680900A (en) | 1996-07-23 | 1997-10-28 | Halliburton Energy Services Inc. | Method for enhancing fluid loss control in subterranean formation |
GB9708831D0 (en) | 1997-04-30 | 1997-06-25 | Unilever Plc | Suspensions with high storage stability, comprising an aqueous silicate solution and filler material |
TR199902849T2 (en) * | 1997-05-26 | 2000-06-21 | Sobolev Konstantin | Production of complex additives and cement-based materials. |
US6070664A (en) | 1998-02-12 | 2000-06-06 | Halliburton Energy Services | Well treating fluids and methods |
US5980446A (en) * | 1997-08-12 | 1999-11-09 | Lockheed Martin Idaho Technologies Company | Methods and system for subsurface stabilization using jet grouting |
US6235809B1 (en) * | 1997-09-30 | 2001-05-22 | Bj Services Company | Multi-functional additive for use in well cementing |
FR2771444B1 (en) | 1997-11-26 | 2000-04-14 | Schlumberger Cie Dowell | IMPROVEMENT OF THE PLACEMENT OF CEMENT GROUT IN WELLS IN THE PRESENCE OF GEOLOGICAL ZONES CONTAINING SWELLING CLAYS OR SLUDGE CONTAINING CLAYS |
US6145591A (en) * | 1997-12-12 | 2000-11-14 | Bj Services Company | Method and compositions for use in cementing |
US6230804B1 (en) * | 1997-12-19 | 2001-05-15 | Bj Services Company | Stress resistant cement compositions and methods for using same |
US6171386B1 (en) | 1998-01-22 | 2001-01-09 | Benchmark Research& Technology Inc. | Cementing compositions, a method of making therefor, and a method for cementing wells |
US6409819B1 (en) * | 1998-06-30 | 2002-06-25 | International Mineral Technology Ag | Alkali activated supersulphated binder |
US6379456B1 (en) | 1999-01-12 | 2002-04-30 | Halliburton Energy Services, Inc. | Flow properties of dry cementitious and non-cementitious materials |
US6660080B2 (en) * | 1999-01-12 | 2003-12-09 | Halliburton Energy Services, Inc. | Particulate flow enhancing additives |
US6170575B1 (en) | 1999-01-12 | 2001-01-09 | Halliburton Energy Services, Inc. | Cementing methods using dry cementitious materials having improved flow properties |
US6245142B1 (en) * | 1999-01-12 | 2001-06-12 | Halliburton Energy Services, Inc. | Flow properties of dry cementitious materials |
US6063738A (en) | 1999-04-19 | 2000-05-16 | Halliburton Energy Services, Inc. | Foamed well cement slurries, additives and methods |
US6209646B1 (en) | 1999-04-21 | 2001-04-03 | Halliburton Energy Services, Inc. | Controlling the release of chemical additives in well treating fluids |
US6283213B1 (en) | 1999-08-12 | 2001-09-04 | Atlantic Richfield Company | Tandem spacer fluid system and method for positioning a cement slurry in a wellbore annulus |
CA2316059A1 (en) * | 1999-08-24 | 2001-02-24 | Virgilio C. Go Boncan | Methods and compositions for use in cementing in cold environments |
US6182758B1 (en) | 1999-08-30 | 2001-02-06 | Halliburton Energy Services, Inc. | Dispersant and fluid loss control additives for well cements, well cement compositions and methods |
CA2318703A1 (en) * | 1999-09-16 | 2001-03-16 | Bj Services Company | Compositions and methods for cementing using elastic particles |
US6213213B1 (en) | 1999-10-08 | 2001-04-10 | Halliburton Energy Services, Inc. | Methods and viscosified compositions for treating wells |
US6475275B1 (en) * | 1999-10-21 | 2002-11-05 | Isolatek International | Cement composition |
US6161753A (en) * | 1999-11-01 | 2000-12-19 | Advanced Semiconductor Engineering, Inc. | Method of making a low-profile wire connection for stacked dies |
US6138759A (en) | 1999-12-16 | 2000-10-31 | Halliburton Energy Services, Inc. | Settable spotting fluid compositions and methods |
FR2806717B1 (en) | 2000-03-23 | 2002-05-24 | Dowell Schlumberger Services | CEMENTING COMPOSITIONS AND APPLICATION THEREOF FOR CEMENTING OIL WELLS OR THE LIKE |
EP1260491A1 (en) | 2001-05-04 | 2002-11-27 | Services Petroliers Schlumberger | Permeable cements |
AU2001286233A1 (en) * | 2000-09-13 | 2002-03-26 | Denki Kagaku Kogyo Kabushiki Kaisha | Cement composition |
US6457524B1 (en) * | 2000-09-15 | 2002-10-01 | Halliburton Energy Services, Inc. | Well cementing compositions and methods |
FR2815629B1 (en) * | 2000-10-25 | 2003-09-05 | Coatex Sas | PROCESS FOR IMPROVING MECHANICAL RESISTANCE IN PARTICULAR "TO THE YOUNG AGES" OF CEMENT MATRICES, CEMENT MATRICES OBTAINED AND THEIR USES |
FR2815627B1 (en) * | 2000-10-25 | 2003-09-05 | Coatex Sas | PROCESS FOR IMPROVING MECHANICAL RESISTANCE IN PARTICULAR "TO THE YOUNG AGES" OF CEMENT MATRICES, CEMENT MATRICES THUS OBTAINED AND THEIR USES |
US6405801B1 (en) | 2000-12-08 | 2002-06-18 | Halliburton Energy Services, Inc. | Environmentally acceptable well cement fluid loss control additives, compositions and methods |
NL1016892C2 (en) * | 2000-12-15 | 2002-06-19 | Mega Tech Holding Bv | Composition intended as an additive for cement. |
US6729405B2 (en) * | 2001-02-15 | 2004-05-04 | Bj Services Company | High temperature flexible cementing compositions and methods for using same |
US20020117090A1 (en) * | 2001-02-20 | 2002-08-29 | Richard Ku | Super high strength concrete |
US6767868B2 (en) * | 2001-02-22 | 2004-07-27 | Bj Services Company | Breaker system for fracturing fluids used in fracturing oil bearing formations |
US6488091B1 (en) | 2001-06-11 | 2002-12-03 | Halliburton Energy Services, Inc. | Subterranean formation treating fluid concentrates, treating fluids and methods |
US6616753B2 (en) * | 2001-12-11 | 2003-09-09 | Halliburton Energy Services, Inc. | Methods and compositions for sealing subterranean zones |
US6887828B2 (en) * | 2001-12-21 | 2005-05-03 | A. John Allen | Phillipsitic zeolite soil amendments |
US6555505B1 (en) | 2002-03-08 | 2003-04-29 | Halliburton Energy Services, Inc. | Foamed acidizing fluids, additives and methods of acidizing subterranean zones |
US6722434B2 (en) * | 2002-05-31 | 2004-04-20 | Halliburton Energy Services, Inc. | Methods of generating gas in well treating fluids |
US6702044B2 (en) * | 2002-06-13 | 2004-03-09 | Halliburton Energy Services, Inc. | Methods of consolidating formations or forming chemical casing or both while drilling |
US6565647B1 (en) | 2002-06-13 | 2003-05-20 | Shieldcrete Ltd. | Cementitious shotcrete composition |
US7147067B2 (en) * | 2002-12-10 | 2006-12-12 | Halliburton Energy Services, Inc. | Zeolite-containing drilling fluids |
US6964302B2 (en) | 2002-12-10 | 2005-11-15 | Halliburton Energy Services, Inc. | Zeolite-containing cement composition |
US7150321B2 (en) * | 2002-12-10 | 2006-12-19 | Halliburton Energy Services, Inc. | Zeolite-containing settable spotting fluids |
US7140440B2 (en) * | 2002-12-10 | 2006-11-28 | Halliburton Energy Services, Inc. | Fluid loss additives for cement slurries |
US7048053B2 (en) * | 2002-12-10 | 2006-05-23 | Halliburton Energy Services, Inc. | Zeolite compositions having enhanced compressive strength |
US6989057B2 (en) * | 2002-12-10 | 2006-01-24 | Halliburton Energy Services, Inc. | Zeolite-containing cement composition |
US7544640B2 (en) * | 2002-12-10 | 2009-06-09 | Halliburton Energy Services, Inc. | Zeolite-containing treating fluid |
US6889767B2 (en) * | 2003-02-28 | 2005-05-10 | Halliburton E{umlaut over (n)}ergy Services, Inc. | Cementing compositions and methods of cementing in a subterranean formation using an additive for preventing the segregation of lightweight beads. |
US20040187740A1 (en) * | 2003-03-27 | 2004-09-30 | Research Incubator, Ltd. | Cementitious composition |
US20050034864A1 (en) * | 2003-06-27 | 2005-02-17 | Caveny William J. | Cement compositions with improved fluid loss characteristics and methods of cementing in surface and subterranean applications |
US7137448B2 (en) * | 2003-12-22 | 2006-11-21 | Bj Services Company | Method of cementing a well using composition containing zeolite |
US6840319B1 (en) * | 2004-01-21 | 2005-01-11 | Halliburton Energy Services, Inc. | Methods, compositions and biodegradable fluid loss control additives for cementing subterranean zones |
US7297664B2 (en) * | 2004-07-28 | 2007-11-20 | Halliburton Energy Services, Inc. | Cement-free zeolite and fly ash settable fluids and methods therefor |
US7182137B2 (en) * | 2004-09-13 | 2007-02-27 | Halliburton Energy Services, Inc. | Cementitious compositions containing interground cement clinker and zeolite |
-
2003
- 2003-10-15 US US10/686,098 patent/US6964302B2/en not_active Expired - Lifetime
-
2004
- 2004-10-11 WO PCT/GB2004/004284 patent/WO2005040550A1/en active Application Filing
- 2004-10-11 CA CA 2541891 patent/CA2541891C/en active Active
-
2005
- 2005-05-11 US US11/126,626 patent/US7285166B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CA2541891C (en) | 2012-06-05 |
US7285166B2 (en) | 2007-10-23 |
WO2005040550A1 (en) | 2005-05-06 |
US20050204962A1 (en) | 2005-09-22 |
US6964302B2 (en) | 2005-11-15 |
US20040112600A1 (en) | 2004-06-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2541891A1 (en) | Zeolite-containing cement composition | |
CA2561346A1 (en) | Fluid loss additives for cement slurries | |
EP1957602B1 (en) | Drilling and cementing with fluids containing zeolite | |
AU2011352794B2 (en) | Lightweight foamed fly ash based binders and method | |
US8747548B2 (en) | Lactate activated cement and activator compositions | |
US20040187740A1 (en) | Cementitious composition | |
US20050252420A1 (en) | Cementitious composition | |
CA2580527A1 (en) | Zeolite compositions for lowering maximum cementing temperature | |
AU2011352794A1 (en) | Lightweight foamed fly ash based binders and method | |
US20140033954A1 (en) | Activator composition for latent hydraulic and/or pozzolanic binder materials | |
JP2023529058A (en) | Method for accelerating and fluidizing wet concrete or mortar compositions containing activators, water-reducing polymers comprising the use of performance additives containing chaotropic ions, and their use in low carbon alternative binder compositions | |
US9394200B2 (en) | Highly workable, high strength cement compositions | |
KR101584324B1 (en) | Concrete composition for carbon dioxide reduction, high fludity and high durability | |
JP2002226245A (en) | Concrete mixing material and concrete composition | |
CN113003962A (en) | Cementing material of cement slurry and preparation method thereof | |
WO2023212335A1 (en) | Cement free activated binder for construction applications | |
JP2022027407A (en) | Bleeding inhibitor | |
CN104860563A (en) | Lactate activated cement and activator compositions | |
JPH013043A (en) | Hydrofluoric anhydride composition | |
CZ23048U1 (en) | Lightweight building material based on lime hydrate and gypsum | |
CZ126095A3 (en) | Process for producing environment-friendly agent for acceleration hardening of cement concretes |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request |