CA2528655A1 - Heterogeneous reactive ink composition - Google Patents

Heterogeneous reactive ink composition Download PDF

Info

Publication number
CA2528655A1
CA2528655A1 CA002528655A CA2528655A CA2528655A1 CA 2528655 A1 CA2528655 A1 CA 2528655A1 CA 002528655 A CA002528655 A CA 002528655A CA 2528655 A CA2528655 A CA 2528655A CA 2528655 A1 CA2528655 A1 CA 2528655A1
Authority
CA
Canada
Prior art keywords
ink composition
meth
acrylate
temperature
latex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002528655A
Other languages
French (fr)
Other versions
CA2528655C (en
Inventor
Marcel P. Breton
Guerino G. Sacripante
Christine E. Bedford
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xerox Corp
Original Assignee
Xerox Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xerox Corp filed Critical Xerox Corp
Publication of CA2528655A1 publication Critical patent/CA2528655A1/en
Application granted granted Critical
Publication of CA2528655C publication Critical patent/CA2528655C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/068—Copolymers with monomers not covered by C09D133/06 containing glycidyl groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers

Abstract

An ink composition includes a colorant, a reactive polymer latex such as an epoxy copolymer latex, an optional dissipatable polymer, a dispersant such as a sulfonated polyester, and a liquid vehicle such as water. The ink composition is a stable liquid at ambient temperature, but becomes a gel upon heating or removal of part of the liquid vehicle.

Claims (28)

1. An ink composition, comprising:
a colorant;
a reactive polymer latex;
an optional dissipatable polymer;
a dispersant; and a liquid vehicle.
2. The ink composition of claim 1, wherein the colorant is selected from dyes, pigments, and mixtures of dyes and pigments.
3. The ink composition of claim 1, wherein the reactive polymer latex is a reactive copolymer latex.
4. The ink composition of claim 1, wherein the reactive copolymer latex comprises a random copolymer comprised of monomer units of the following formula:

wherein A and B represent the random units of the copolymer, each R, is independently a hydrogen or methyl group, R2 is an alkyl or aryl group of from about 2 to 12 carbon atoms, and m and n are independently from about 0.1 to about 99.9 mole percent, provided that the sum of n and m is 100 mole percent of the copolymer.
5. The ink composition of claim 4, wherein A and B are independently selected from the group consisting of (meth)acrylate, alkyl (meth)acrylate, an aryl (meth)acrylate, and an alkoxyl (meth)acrylate, wherein at least one of A and B
comprises one or more epoxy functionalities.
6. The ink composition of claim 4, wherein A and B are independently selected from the group consisting of (meth)acrylate, alkyl (meth)acrylate having a substitute or unsubstituted alkyl chain of from 1 to about 10 carbon atoms, an aryl (meth)acrylate where the aryl group is a substituted or unsubstituted phenyl group, and an alkoxyl (meth)acrylate where the alkoxyl group has one or more oxygen atoms, wherein at least one of A and B comprises one or more epoxy functionalities
7. The ink composition of claim 4, wherein m is from about 65 to about 95 mole percent and n is from about 5 to about 35 mole percent.
8. The ink composition of claim 4, wherein the copolymer displays a glass transition temperature of from about 10 to about 150°C, a number average molecular weight of from about 10,000 to about 200,000 grams per mole, a weight average molecular weight of from about 20,000 to about 750,000 grams per mole and a polydispersity of from about 1.5 to about 20, and a latex particle size of from about 20 to about 500 nm.
9. The ink composition of claim 4, wherein A is a methyl (meth)acrylate and B is a glycidyl (meth)acrylate.
10. The ink composition of claim 1, wherein the dissipatable polymer comprises a mixture of one or more of the following:

and any other mono-, di-, tri-, and tetravalent groups thereof, wherein a, b, c, d, e, f, and g are each integers representing the number of ethylene oxide repeat units.
11. The ink composition of claim 1, wherein the dispersant is a sulfonated polyester.
12. The ink composition of claim 1, wherein the dispersant is represented by the following formula:

or random copolymers thereof wherein the n and p segments are separated, wherein R is an alkylene, R' is an arylene, X represents a counterion, and p and n represent mole percents of the respective randomly repeating segments.
13. The ink composition of claim 1, wherein the liquid vehicle is selected from the group consisting of water, diols, polyols, and mixtures thereof.
14. The ink composition of claim 1, wherein the liquid vehicle comprises water.
15. The ink composition of claim 1, wherein the ink composition has a solids content of greater than about 10% by weight.
16. The ink composition of claim 1, wherein the ink composition has a water content of less than about 80% by weight.
17. The ink composition of claim 1, wherein the ink composition exhibits a phase transition from a liquid state to a gel state at a temperature of not less than about 30°C.
18. The ink composition of claim 1, wherein the ink composition exhibits a phase transition from a liquid state to a gel state at a temperature of not less than about 40°C
19. The ink composition of claim 1, wherein the ink composition exhibits a phase transition from a liquid state to a gel state at a temperature of not less than about 50°C
20. The ink composition of claim 1, wherein the ink composition is a stable liquid state at room temperature, but transforms to a gel state upon at least one of heating or removal of a part of the liquid vehicle.
21. The ink composition of claim 1, wherein the reactive latex and at least one other component of the ink composition react at a temperature of at least 40°C.
22. The ink composition of claim 1, wherein the reactive latex and at least one other component of the ink composition react at a temperature of at least 60°C.
23. The ink composition of claim 1, wherein the reactive latex and at least one other component of the ink composition react at a temperature of at least 80°C.
24. The ink composition of claim 1, wherein the reactive latex and at least one other component of the ink composition react at a temperature of at least 100°C and not higher than 200°C.
25. A process for making the ink composition of claim 1, comprising:
mixing said colorant, said dissipatable polymer, said dispersant, and said liquid vehicle to form a mixture; and blending said reactive polymer latex into said mixture.
26. A process for forming an image, comprising:
jetting droplets of the ink composition of claim 1 to form an image on a substrate; and fixing said image to said substrate.
27. The process of claim 26, wherein said jetting comprises:
jetting said droplets of the ink composition onto a heated intermediate transfer member to form an image; and transferring said image from said heated intermediate transfer member to said substrate.
28. The process of claim 26, wherein said fixing comprises at least one of fusing under temperature, fusing under pressure, and fusing with a radiant fuser.
CA2528655A 2004-12-10 2005-12-02 Heterogeneous reactive ink composition Expired - Fee Related CA2528655C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/008,628 2004-12-10
US11/008,628 US7202883B2 (en) 2004-12-10 2004-12-10 Heterogeneous reactive ink composition

Publications (2)

Publication Number Publication Date
CA2528655A1 true CA2528655A1 (en) 2006-06-10
CA2528655C CA2528655C (en) 2010-04-27

Family

ID=35613876

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2528655A Expired - Fee Related CA2528655C (en) 2004-12-10 2005-12-02 Heterogeneous reactive ink composition

Country Status (5)

Country Link
US (1) US7202883B2 (en)
EP (1) EP1669422B1 (en)
JP (1) JP2006169525A (en)
CA (1) CA2528655C (en)
DE (1) DE602005004870T2 (en)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7767011B2 (en) 2005-05-31 2010-08-03 Xerox Corporation Aqueous gel ink compositions and method of printing same
US7759432B2 (en) * 2005-10-13 2010-07-20 Xerox Corporation Emulsion containing epoxy resin
US8236761B2 (en) * 2006-07-07 2012-08-07 Washington State University Research Foundation C-Met receptor regulation by angiotensin IV (AT4) receptor ligands
GB0625530D0 (en) * 2006-12-21 2007-01-31 Eastman Kodak Co Aqueous inkjet fluid
US7954430B2 (en) 2007-11-28 2011-06-07 Xerox Corporation Underside curing of radiation curable inks
US8029861B2 (en) * 2008-09-23 2011-10-04 Xerox Corporation Ink carriers containing low viscosity functionalized waxes, phase change inks including same, and methods for making same
JP2012143942A (en) * 2011-01-11 2012-08-02 Ricoh Co Ltd Ink-jet image forming apparatus
JP5861222B2 (en) * 2011-09-29 2016-02-16 株式会社ミマキエンジニアリング Printing method and inkjet discharge apparatus
JP6244907B2 (en) * 2013-01-15 2017-12-13 株式会社リコー Water-based ink, ink cartridge
US9022546B1 (en) 2013-11-25 2015-05-05 Xerox Corporation Method of jetting ink
US9644105B2 (en) 2013-12-23 2017-05-09 Xerox Corporation Aqueous dispersible polymer inks
US9724909B2 (en) * 2013-12-23 2017-08-08 Xerox Corporation Methods for ink-based digital printing with high ink transfer efficiency
US9683130B2 (en) 2014-03-19 2017-06-20 Xerox Corporation Polydiphenylsiloxane coating formulation and method for forming a coating
US9494884B2 (en) 2014-03-28 2016-11-15 Xerox Corporation Imaging plate coating composite composed of fluoroelastomer and aminosilane crosslinkers
JP6260780B2 (en) * 2014-03-31 2018-01-17 ブラザー工業株式会社 Water-based ink for ink-jet recording and ink cartridge
US9428663B2 (en) 2014-05-28 2016-08-30 Xerox Corporation Indirect printing apparatus employing sacrificial coating on intermediate transfer member
US9611404B2 (en) 2014-09-23 2017-04-04 Xerox Corporation Method of making sacrificial coating for an intermediate transfer member of indirect printing apparatus
US9593255B2 (en) 2014-09-23 2017-03-14 Xerox Corporation Sacrificial coating for intermediate transfer member of an indirect printing apparatus
US9550908B2 (en) 2014-09-23 2017-01-24 Xerox Corporation Sacrificial coating for intermediate transfer member of an indirect printing apparatus
US9421758B2 (en) 2014-09-30 2016-08-23 Xerox Corporation Compositions and use of compositions in printing processes
US9956760B2 (en) 2014-12-19 2018-05-01 Xerox Corporation Multilayer imaging blanket coating
US9458341B2 (en) 2015-02-12 2016-10-04 Xerox Corporation Sacrificial coating compositions comprising polyvinyl alcohol and waxy starch
US9816000B2 (en) 2015-03-23 2017-11-14 Xerox Corporation Sacrificial coating and indirect printing apparatus employing sacrificial coating on intermediate transfer member
US9718964B2 (en) 2015-08-19 2017-08-01 Xerox Corporation Sacrificial coating and indirect printing apparatus employing sacrificial coating on intermediate transfer member
US11478991B2 (en) 2020-06-17 2022-10-25 Xerox Corporation System and method for determining a temperature of an object
US11499873B2 (en) 2020-06-17 2022-11-15 Xerox Corporation System and method for determining a temperature differential between portions of an object printed by a 3D printer
US11498354B2 (en) 2020-08-26 2022-11-15 Xerox Corporation Multi-layer imaging blanket
US11767447B2 (en) 2021-01-19 2023-09-26 Xerox Corporation Topcoat composition of imaging blanket with improved properties

Family Cites Families (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE755392A (en) * 1969-08-28 1971-02-01 Teletype Corp INK AND ELECTROSTATIC PRINTING APPARATUS
JPS5850271B2 (en) * 1975-08-05 1983-11-09 日石三菱株式会社 Hifuku Keiseihou
US4094685A (en) * 1976-07-23 1978-06-13 Polymerics, Inc. Expandable polymeric coating compositions
US4390369A (en) * 1981-12-17 1983-06-28 Exxon Research And Engineering Co. Natural wax-containing ink jet inks
US4484948A (en) * 1981-12-17 1984-11-27 Exxon Research And Engineering Co. Natural wax-containing ink jet inks
US4538156A (en) * 1983-05-23 1985-08-27 At&T Teletype Corporation Ink jet printer
JPH07115470B2 (en) * 1984-05-10 1995-12-13 ウイレツト インターナシヨナル リミテツド Molten thermoplastic composition and method of applying the composition to a substrate
EP0187352B1 (en) 1984-12-31 1991-06-05 Howtek, Inc. A method of ink jet colour printing
US4745420A (en) * 1986-07-21 1988-05-17 Dataproducts Corporation Method and apparatus for controlling the size of dots produced by jetting phase change ink
JPS6354476A (en) * 1986-08-25 1988-03-08 Seiko Epson Corp Hot-melting ink
US4788123A (en) * 1987-06-08 1988-11-29 Xerox Corporation Process for minimizing image de-enhancement in flash fusing systems
US4889560A (en) * 1988-08-03 1989-12-26 Tektronix, Inc. Phase change ink composition and phase change ink produced therefrom
US5378574A (en) * 1988-08-17 1995-01-03 Xerox Corporation Inks and liquid developers containing colored silica particles
US4889761A (en) * 1988-08-25 1989-12-26 Tektronix, Inc. Substrates having a light-transmissive phase change ink printed thereon and methods for producing same
US5151120A (en) * 1989-03-31 1992-09-29 Hewlett-Packard Company Solid ink compositions for thermal ink-jet printing having improved printing characteristics
US5195430A (en) * 1989-05-24 1993-03-23 Tektronix, Inc. Dual roller apparatus for pressure fixing sheet material
US5006170A (en) * 1989-06-22 1991-04-09 Xerox Corporation Hot melt ink compositions
US5231135A (en) * 1989-09-05 1993-07-27 Milliken Research Corporation Lightfast colored polymeric coatings and process for making same
US5221335A (en) * 1990-05-23 1993-06-22 Coates Electrographics Limited Stabilized pigmented hot melt ink containing nitrogen-modified acrylate polymer as dispersion-stabilizer agent
US5145518A (en) * 1990-06-27 1992-09-08 Xerox Corporation Inks containing block copolymer micelles
US5099256A (en) * 1990-11-23 1992-03-24 Xerox Corporation Ink jet printer with intermediate drum
JP2895246B2 (en) 1990-12-26 1999-05-24 株式会社リコー Emulsion ink for stencil printing
US5225900A (en) * 1990-12-31 1993-07-06 Xerox Corporation Method of storing information within a reproduction system
US5286286A (en) * 1991-05-16 1994-02-15 Xerox Corporation Colorless fast-drying ink compositions for printing concealed images detectable by fluorescence
US5271764A (en) * 1992-02-12 1993-12-21 Xerox Corporation Ink compositions
US5146087A (en) * 1991-07-23 1992-09-08 Xerox Corporation Imaging process with infrared sensitive transparent receiver sheets
US5202265A (en) * 1991-10-24 1993-04-13 Xerox Corporation Toner taggant processes
US5208630A (en) * 1991-11-04 1993-05-04 Xerox Corporation Process for the authentication of documents utilizing encapsulated toners
US5275647A (en) * 1991-11-25 1994-01-04 Xerox Corporation Ink compositions
DE4205636C2 (en) 1992-02-25 1994-12-22 Siegwerk Druckfarben Gmbh & Co Gravure and planographic printing processes and printing machines for carrying out the processes
DE4205713C2 (en) 1992-02-25 1994-08-04 Siegwerk Druckfarben Gmbh & Co Printing ink, process for its production and its use
US5256193A (en) * 1992-06-25 1993-10-26 Xerox Corporation Porphyrin chromophore and dendrimer ink composition
US5385957A (en) * 1992-08-24 1995-01-31 Videojet Systems International, Inc. Hotmelt ink jet comprising ionomers having melting points from about 50° C. to about 130° or a softening point below about 80° C., and an image-forming agent
US5543177A (en) * 1992-11-05 1996-08-06 Xerox Corporation Marking materials containing retroreflecting fillers
US5372852A (en) * 1992-11-25 1994-12-13 Tektronix, Inc. Indirect printing process for applying selective phase change ink compositions to substrates
US5621022A (en) * 1992-11-25 1997-04-15 Tektronix, Inc. Use of polymeric dyes in hot melt ink jet inks
US5389958A (en) * 1992-11-25 1995-02-14 Tektronix, Inc. Imaging process
US5385803A (en) * 1993-01-04 1995-01-31 Xerox Corporation Authentication process
US5554212A (en) * 1994-05-06 1996-09-10 Tektronix, Inc. Waterfast high gloss hyperthermogelling aqueous phase change ink and method for use
US5554480A (en) * 1994-09-01 1996-09-10 Xerox Corporation Fluorescent toner processes
JP3396585B2 (en) 1995-12-25 2003-04-14 サカタインクス株式会社 Pigment dispersion and ink composition for offset printing using the same
JPH09272826A (en) * 1996-04-05 1997-10-21 Seiko Epson Corp Ink composition for ink jet recording and recording method
US5593807A (en) * 1996-05-10 1997-01-14 Xerox Corporation Toner processes using sodium sulfonated polyester resins
US5761597A (en) * 1996-09-12 1998-06-02 Tektronix, Inc. Fusing apparatus for a printer
JP4406472B2 (en) * 1997-03-28 2010-01-27 セイコーエプソン株式会社 Ink composition for inkjet recording
US5945245A (en) * 1998-01-13 1999-08-31 Xerox Corporation Toner processes
JPH11236523A (en) * 1998-02-20 1999-08-31 Dainippon Printing Co Ltd Ink for image formation and image formation method using sane
US6689837B1 (en) * 1998-06-17 2004-02-10 Meadwestvaco Corporation Hybrid polymers for phase change ink jet inks
US6046253A (en) * 1998-09-10 2000-04-04 Eastman Kodak Company Dispersant for ink jet ink
US6221137B1 (en) * 1999-06-18 2001-04-24 Xerox Corporation Metal phthalocyanine colorants for phase change inks
US6180691B1 (en) * 1999-08-02 2001-01-30 Xerox Corporation Processes for preparing ink jet inks
US6646024B2 (en) * 1999-12-14 2003-11-11 Lexmark International, Inc. Ink compositions
JP2002326444A (en) * 2001-05-02 2002-11-12 Seiko Epson Corp Ink jet recording method and ink jet recording device
JP4202680B2 (en) 2001-06-15 2008-12-24 日油株式会社 Ink-jet ink composition for color filter, method for producing ink composition, and method for producing color filter
US6872243B2 (en) * 2002-09-04 2005-03-29 Xerox Corporation Phase change inks containing gelator additives
US6811596B1 (en) * 2003-05-12 2004-11-02 Xerox Corporation Phase change inks with improved image permanence

Also Published As

Publication number Publication date
EP1669422B1 (en) 2008-02-20
EP1669422A1 (en) 2006-06-14
DE602005004870T2 (en) 2009-02-19
DE602005004870D1 (en) 2008-04-03
US7202883B2 (en) 2007-04-10
JP2006169525A (en) 2006-06-29
US20060128830A1 (en) 2006-06-15
CA2528655C (en) 2010-04-27

Similar Documents

Publication Publication Date Title
CA2528655A1 (en) Heterogeneous reactive ink composition
CA2528673A1 (en) Heterogeneous low energy gel ink composition
CN102977253B (en) Silicone modified acrylate hybrid emulsion and preparation method and application thereof
CN104231514B (en) Neutral layer polymers, methods of manufacture thereof and articles comprising the same
CN103214895B (en) Organosilicon coating levelling agent and preparation method thereof
EP2280047B1 (en) Releasing agent composition and releasing material
JP5968530B2 (en) Comb copolymer having ionic bonding groups
ES2340174T3 (en) PROCESS FOR THE CONTINUOUS PRODUCTION OF POLYMERS OF EPOXY- (MET) ACRYLIC STYRENE AND ITS USE IN COATINGS.
CN107108899B (en) Free radical polymerizable siloxanes and siloxane polymers
CA2479845A1 (en) Cationic, amino-functional, adhesion-promoting polymer for curable inks and other plastic film coatings, and plastic film comprising such polymer
CA2548019A1 (en) Polymeric dispersant
AU741255B2 (en) Polymeric compositions, and the preparation and use thereof
AU2293299A (en) Solvent based compositions containing a substantially non-gelled polymeric composition
US20060084736A1 (en) Thermosetting one-solution type composition for protective film of color filter and color filter using the same
CN102268138B (en) Aqueous organosilicon grafted (methyl) acrylic polymer and preparation method of emulsion thereof
CN104125992A (en) Room temperature-curable coating composition
CN101104660B (en) One solution-type thermosetting compositions for color filter protective films and color filters using the same
KR102528182B1 (en) UV-curable silicone adhesive composition and silicone adhesive film
US11414525B2 (en) Hyperbranched polydiorganosiloxane polyoxamide polymers
KR930703380A (en) Process for preparing blends of polyester and acrylic polymers
CN100575415C (en) Poly carbonate resin composition with good fatigue resistance
JP3769824B2 (en) Coating composition
KR101039374B1 (en) Heat resistanst coatings and manufacturing method of it
KR101418268B1 (en) Slip- and leveling agent
CN111808473B (en) Modified styrene-acrylate resin for prolonging uncapping time of thermal foaming ink

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20191202