CA2526313A1 - Method for uniform deposition of fabric care actives in a non-aqueous fabric treatment system - Google Patents
Method for uniform deposition of fabric care actives in a non-aqueous fabric treatment system Download PDFInfo
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- CA2526313A1 CA2526313A1 CA002526313A CA2526313A CA2526313A1 CA 2526313 A1 CA2526313 A1 CA 2526313A1 CA 002526313 A CA002526313 A CA 002526313A CA 2526313 A CA2526313 A CA 2526313A CA 2526313 A1 CA2526313 A1 CA 2526313A1
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- fabric
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- 238000000034 method Methods 0.000 title claims abstract 26
- 239000004744 fabric Substances 0.000 title claims abstract 23
- 230000008021 deposition Effects 0.000 title claims abstract 3
- 239000000203 mixture Substances 0.000 claims abstract 10
- 239000003795 chemical substances by application Substances 0.000 claims 9
- 239000012530 fluid Substances 0.000 claims 8
- 125000000217 alkyl group Chemical group 0.000 claims 6
- 125000003342 alkenyl group Chemical group 0.000 claims 5
- -1 glycol ethers Chemical class 0.000 claims 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 5
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 3
- 125000002015 acyclic group Chemical group 0.000 claims 3
- 125000003118 aryl group Chemical group 0.000 claims 3
- 125000004122 cyclic group Chemical group 0.000 claims 3
- 239000003995 emulsifying agent Substances 0.000 claims 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 3
- 229920006395 saturated elastomer Polymers 0.000 claims 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 2
- 229910019142 PO4 Inorganic materials 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 2
- 125000003368 amide group Chemical group 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 2
- 239000002421 finishing Substances 0.000 claims 2
- 125000000623 heterocyclic group Chemical group 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000002245 particle Substances 0.000 claims 2
- 239000002304 perfume Substances 0.000 claims 2
- 239000010452 phosphate Substances 0.000 claims 2
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 2
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims 2
- 239000002689 soil Substances 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- 125000006274 (C1-C3)alkoxy group Chemical group 0.000 claims 1
- 125000000923 (C1-C30) alkyl group Chemical group 0.000 claims 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims 1
- 102000004190 Enzymes Human genes 0.000 claims 1
- 108090000790 Enzymes Proteins 0.000 claims 1
- 229930194542 Keto Natural products 0.000 claims 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims 1
- 229910020388 SiO1/2 Inorganic materials 0.000 claims 1
- 239000004902 Softening Agent Substances 0.000 claims 1
- 230000006750 UV protection Effects 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 239000003242 anti bacterial agent Substances 0.000 claims 1
- 230000001680 brushing effect Effects 0.000 claims 1
- 150000001720 carbohydrates Chemical class 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 150000007942 carboxylates Chemical class 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 229940124447 delivery agent Drugs 0.000 claims 1
- 238000007598 dipping method Methods 0.000 claims 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical group [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims 1
- 238000005516 engineering process Methods 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 239000000834 fixative Substances 0.000 claims 1
- 239000003063 flame retardant Substances 0.000 claims 1
- 125000004991 fluoroalkenyl group Chemical group 0.000 claims 1
- 125000003709 fluoroalkyl group Chemical group 0.000 claims 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 claims 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims 1
- 150000002334 glycols Chemical class 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 125000005842 heteroatom Chemical group 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 230000002209 hydrophobic effect Effects 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 230000002401 inhibitory effect Effects 0.000 claims 1
- 125000000468 ketone group Chemical group 0.000 claims 1
- 125000005647 linker group Chemical group 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000006210 lotion Substances 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 claims 1
- 125000005245 nitryl group Chemical group [N+](=O)([O-])* 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 239000006187 pill Substances 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 230000002265 prevention Effects 0.000 claims 1
- 239000011814 protection agent Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000002195 soluble material Substances 0.000 claims 1
- 238000009987 spinning Methods 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 230000008685 targeting Effects 0.000 claims 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims 1
- 230000037303 wrinkles Effects 0.000 claims 1
- 238000000151 deposition Methods 0.000 abstract 2
- 239000003125 aqueous solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/82—Compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0004—Non aqueous liquid compositions comprising insoluble particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0017—Multi-phase liquid compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
- D06L1/04—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents combined with specific additives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
-
- C11D2111/12—
Abstract
A method for uniform deposition of fabric care actives to a fabric article in a non-aqueous solvent based fabric treatment process; and compositions capable of uniformly depositing the fabric care actives on the fabric article being treated to achieve maximum benefit.
Claims (20)
1. A method for uniform and efficient deposition of fabric care active onto a fabric article in a non-aqueous fabric treatment process comprising the steps of:
(a) obtaining a delivery system comprising:
a first phase comprising a lipophilic fluid;
a second phase comprising a carrier and a fabric care active, the carrier being substantially insoluble in the lipophilic fluid; and an effective amount of an emulsifying agent sufficient to emulsify the composition such that the second phase forms discrete particles;
(b) contacting a fabric article with the delivery system; and (c) removing at least a portion of the lipophilic fluid.
(a) obtaining a delivery system comprising:
a first phase comprising a lipophilic fluid;
a second phase comprising a carrier and a fabric care active, the carrier being substantially insoluble in the lipophilic fluid; and an effective amount of an emulsifying agent sufficient to emulsify the composition such that the second phase forms discrete particles;
(b) contacting a fabric article with the delivery system; and (c) removing at least a portion of the lipophilic fluid.
2. The method according to Claim 1, wherein the second phase is in the form of droplets having a median particle diameter (.chi.50) of less than 1000 microns.
3. The method according to Claim1, wherein in a 1 mL sample of the delivery system, greater than 0.95 weight fraction of the second phase is in the form of droplets, each droplet having an individual weight of less than 1 wt%, of the total mass of the second phase in the 1 mL sample of the delivery system.
4. The method according to any one of the preceding claims, wherein the fabric care active has a logP value of less than 0.
5. The method according to any one of claims 1-3, wherein the fabric care active has a logP value of from 1 to -1.
6. The method according to any one of the preceding claims, wherein amount of fabric care active in the first phase versus the second phase ranges from 1:2 to 1:1000.
7. The method according to any one of the preceding claims, wherein a weight ratio of the carrier to the emulsifying agent ranges from 10000:1 to 1:1.
8. The method according to any one of the preceding claims, wherein a weight ratio of the fabric care active to the carrier ranges 1:1000 to 3:1.
9. The method according to any one of the preceding claims, wherein the lipophilic fluid is selected from the group consisting of silicones, glycol ethers, glycerol ethers, fluorocarbons, hydrocarbons, and mixtures thereof.
10. The method according to any one of the preceding claims, wherein the lipophilic fluid is a cyclic siloxane solvent.
11. The method according to any one of the preceding claims, wherein the lipophilic fluid is decamethylcyclopentasiloxane.
12. The method according to any one of the preceding claims, wherein the delivery system comprises at least 50% by weight of the delivery system of the lipophilic fluid.
13. The method according to any one of the preceding claims, wherein the carrier comprises water, and optionally, linear or branched C1-C6 alcohols, C1-C4 glycols, or mixtures thereof.
14. The method according to any one of the preceding claims, wherein the carrier comprises from 0.01% to 5% by weight of the composition.
15. The method according to any one of the preceding claims, wherein the fabric care active is a water soluble or partially water soluble material, a water insoluble liquid, or a water insoluble solid.
16. The method according to any one of the preceding claims, wherein greater than 70wt% of the fabric care actives is deposited onto the fabric article.
17. The method according to any one of the preceding claims, wherein the fabric care active is selected from the group consisting of soil release polymers, bleaches, enzymes, perfumes, softening agents, finishing polymers, dye transfer inhibiting agents, dye fixatives, UV protection agents, wrinkle reducing/removing agents, fabric rebuild agents, fiber repair agents, perfume release and/or delivery agents, shape retention agents, fabric and/or soil targeting agents, antibacterial agents, anti-discoloring agents, hydrophobic finishing agents UV
blockers, brighteners, pigments, pill prevention agents, temperature control technology, skin care lotions, fire retardants, and mixtures thereof.
blockers, brighteners, pigments, pill prevention agents, temperature control technology, skin care lotions, fire retardants, and mixtures thereof.
18. The method according to any one of the preceding claims, wherein the emulsifying agent is a siloxane-based surfactant invention having the general formula:
(I) Y u -(L t - X v)x - Y'w (II) L y -(X v - Y u)x - L'z and mixtures thereof;
wherein L and L' are solvent compatibilizing (or lipophilic) moieties, which are independently selected from:
(a) C1-C22 alkyl or C4-C12 alkoxy, linear or branched, cyclic or acyclic, saturated or unsaturated, substituted or unsubstituted;
(b) siloxanes having the formula:
M a D b D'c D"d (III) wherein a is 0-2; b is 0-1000; c is 0-50; d is 0-50, provided that a+c+d is at least 1;
M of formula (III) is R1 3-e X e SiO1/2 wherein R1 of formula (III) is independently H, or an alkyl group, X of formula (III) is hydroxyl group, and e is 0 or 1;
D of formula (III) isR4 2SiO2/2 wherein R4 of formula (III) is independently H
or an alkyl group;
D' of formula (III) is R5 2SiO2/2 wherein R5 of formula (III) is independently H, an alkyl group, or (CH2)f(C6Q4)g O-(C2H4O)h-(C3H6O)i(C k H2k)j-R3, provided that at least one R5 of formula (III) is (CH2)f(C6Q4)g O-(C2H4O)h-(C3H6O)i(C k H2k)j-R3 (referred to as formula IIIb), wherein R3 of formula (IIIb) is independently H, an alkyl group or an alkoxy group, f of formula (IIIb) is 1-10, g of formula (IIIb) is 0 or 1, h of formula (IIIb) is 1-50, i of formula (IIIb) is 0-50, j of formula (IIIb) is 0-50, k of formula (IIIb) is 4-8; C6Q4 of formula (IIIb) is unsubstituted or substituted with Q of formula (IIIb) is independently H, C1-10 alkyl, C1-10 alkenyl, and mixtures thereof.
D" of formula (III) is R6 2SiO2/2 wherein R6 of formula (III) is independently H, an alkyl group or (CH2)l(C6Q4)m(A)n-[(T)o-(A')p-]q-(T')r Z(G)s (referred to as formula IIIc), wherein 1 of formula (IIIc) is 1-10; m of formula (IIIc) is 0 or 1; n of formula (IIIc) is 0-5; o of formula (IIIc) is 0-3; p of formula (IIIc) is 0 or 1; q of formula (IIIc) is 0-10; r of formula (IIIc) is 0-3; s of formula (IIIc) is 0-3; C6Q4 of formula (IIIc) is unsubstituted or substituted with Q
of formula (IIIc) is independently H, C1-10 alkyl, C1-10 alkenyl, and mixtures thereof; A and A' of formula (IIIc) are each independently a linking moiety representing an ester, a keto, an ether, a thio, an amido, an amino, a C1-4 fluoroalkyl, a C1-4 fluoroalkenyl, a branched or straight chained polyalkylene oxide, a phosphate, a sulfonyl, a sulfate, an ammonium, and mixtures thereof; T and T' of formula (IIIc) are each independently a C1-30 straight chained or branched alkyl or alkenyl or an aryl which is unsubstituted or substituted; Z of formula (IIIc) is a hydrogen, carboxylic acid, a hydroxy, a phosphato, a phosphate ester, a sulfonyl, a sulfonate, a sulfate, a branched or straight-chained polyalkylene oxide, a nitryl, a glyceryl, an aryl unsubstituted or substituted with a C1-30 alkyl or alkenyl, a carbohydrate unsubstituted or substituted with a C1-10 alkyl or alkenyl or an ammonium;
G of formula (IIIc) is an anion or cation such as H+, Na+, Li+, K+, NH4+, Ca+2, Mg+2, Cl-, Br-, I-, mesylate or tosylate;
Y and Y' are hydrophilic moieties, which are independently selected from hydroxy;
polyhydroxy; C1-C3 alkoxy; mono- or di- alkanolamine; C1-C4 alkyl substituted alkanolamine;
substituted heterocyclic containing O, S, N; sulfates; carboxylate; carbonate;
and when Y and/or Y' is ethoxy (EO) or propoxy (PO), it must be capped with R, which is selected from the group consisting of:
(i) a 4 to 8 membered, substituted or unsubstituted, heterocyclic ring containing from 1 to 3 hetero atoms; and (ii) linear or branched, saturated or unsaturated, substituted or unsubstituted, cyclic or acyclic, aliphatic or aromatic hydrocarbon radicals having from 1 to 30 carbon atoms;
X is a bridging linkage selected from O; S; N; P; C1 to C22 alkyl, linear or branched, saturated or unsaturated, substituted or unsubstituted, cyclic or acyclic, aliphatic or aromatic, interrupted by O, S, N, P; glycidyl, ester, amido, amino, PO42-, HPO4-, PO3 2-, HPO3-, which are protonated or unprotonated;
u and w are integers independently selected from 0 to 20, provided that u+w >1;
t is an integer from 1 to 10;
v is an integer from 0 to 10;
x is an integer from 1 to 20; and y and z are integers independently selected from 1 to 10.
(I) Y u -(L t - X v)x - Y'w (II) L y -(X v - Y u)x - L'z and mixtures thereof;
wherein L and L' are solvent compatibilizing (or lipophilic) moieties, which are independently selected from:
(a) C1-C22 alkyl or C4-C12 alkoxy, linear or branched, cyclic or acyclic, saturated or unsaturated, substituted or unsubstituted;
(b) siloxanes having the formula:
M a D b D'c D"d (III) wherein a is 0-2; b is 0-1000; c is 0-50; d is 0-50, provided that a+c+d is at least 1;
M of formula (III) is R1 3-e X e SiO1/2 wherein R1 of formula (III) is independently H, or an alkyl group, X of formula (III) is hydroxyl group, and e is 0 or 1;
D of formula (III) isR4 2SiO2/2 wherein R4 of formula (III) is independently H
or an alkyl group;
D' of formula (III) is R5 2SiO2/2 wherein R5 of formula (III) is independently H, an alkyl group, or (CH2)f(C6Q4)g O-(C2H4O)h-(C3H6O)i(C k H2k)j-R3, provided that at least one R5 of formula (III) is (CH2)f(C6Q4)g O-(C2H4O)h-(C3H6O)i(C k H2k)j-R3 (referred to as formula IIIb), wherein R3 of formula (IIIb) is independently H, an alkyl group or an alkoxy group, f of formula (IIIb) is 1-10, g of formula (IIIb) is 0 or 1, h of formula (IIIb) is 1-50, i of formula (IIIb) is 0-50, j of formula (IIIb) is 0-50, k of formula (IIIb) is 4-8; C6Q4 of formula (IIIb) is unsubstituted or substituted with Q of formula (IIIb) is independently H, C1-10 alkyl, C1-10 alkenyl, and mixtures thereof.
D" of formula (III) is R6 2SiO2/2 wherein R6 of formula (III) is independently H, an alkyl group or (CH2)l(C6Q4)m(A)n-[(T)o-(A')p-]q-(T')r Z(G)s (referred to as formula IIIc), wherein 1 of formula (IIIc) is 1-10; m of formula (IIIc) is 0 or 1; n of formula (IIIc) is 0-5; o of formula (IIIc) is 0-3; p of formula (IIIc) is 0 or 1; q of formula (IIIc) is 0-10; r of formula (IIIc) is 0-3; s of formula (IIIc) is 0-3; C6Q4 of formula (IIIc) is unsubstituted or substituted with Q
of formula (IIIc) is independently H, C1-10 alkyl, C1-10 alkenyl, and mixtures thereof; A and A' of formula (IIIc) are each independently a linking moiety representing an ester, a keto, an ether, a thio, an amido, an amino, a C1-4 fluoroalkyl, a C1-4 fluoroalkenyl, a branched or straight chained polyalkylene oxide, a phosphate, a sulfonyl, a sulfate, an ammonium, and mixtures thereof; T and T' of formula (IIIc) are each independently a C1-30 straight chained or branched alkyl or alkenyl or an aryl which is unsubstituted or substituted; Z of formula (IIIc) is a hydrogen, carboxylic acid, a hydroxy, a phosphato, a phosphate ester, a sulfonyl, a sulfonate, a sulfate, a branched or straight-chained polyalkylene oxide, a nitryl, a glyceryl, an aryl unsubstituted or substituted with a C1-30 alkyl or alkenyl, a carbohydrate unsubstituted or substituted with a C1-10 alkyl or alkenyl or an ammonium;
G of formula (IIIc) is an anion or cation such as H+, Na+, Li+, K+, NH4+, Ca+2, Mg+2, Cl-, Br-, I-, mesylate or tosylate;
Y and Y' are hydrophilic moieties, which are independently selected from hydroxy;
polyhydroxy; C1-C3 alkoxy; mono- or di- alkanolamine; C1-C4 alkyl substituted alkanolamine;
substituted heterocyclic containing O, S, N; sulfates; carboxylate; carbonate;
and when Y and/or Y' is ethoxy (EO) or propoxy (PO), it must be capped with R, which is selected from the group consisting of:
(i) a 4 to 8 membered, substituted or unsubstituted, heterocyclic ring containing from 1 to 3 hetero atoms; and (ii) linear or branched, saturated or unsaturated, substituted or unsubstituted, cyclic or acyclic, aliphatic or aromatic hydrocarbon radicals having from 1 to 30 carbon atoms;
X is a bridging linkage selected from O; S; N; P; C1 to C22 alkyl, linear or branched, saturated or unsaturated, substituted or unsubstituted, cyclic or acyclic, aliphatic or aromatic, interrupted by O, S, N, P; glycidyl, ester, amido, amino, PO42-, HPO4-, PO3 2-, HPO3-, which are protonated or unprotonated;
u and w are integers independently selected from 0 to 20, provided that u+w >1;
t is an integer from 1 to 10;
v is an integer from 0 to 10;
x is an integer from 1 to 20; and y and z are integers independently selected from 1 to 10.
19. The method according to any one of the preceding claims, wherein the delivery system is applied to the fabric article by a process selected from the group consisting of immersing, dipping, spraying, brushing on, rubbing on and combinations thereof.
20. The method according to any one of the preceding claims, wherein the lipophilic fluid is removed by a process selected form heating, spinning, squeezing, wringing, and combinations thereof.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US48339203P | 2003-06-27 | 2003-06-27 | |
| US60/483,392 | 2003-06-27 | ||
| US54736904P | 2004-02-24 | 2004-02-24 | |
| US60/547,369 | 2004-02-24 | ||
| PCT/US2004/020616 WO2005003282A1 (en) | 2003-06-27 | 2004-06-28 | Method for uniform deposition of fabric care actives in a non-aqueous fabric treatment system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2526313A1 true CA2526313A1 (en) | 2005-01-13 |
| CA2526313C CA2526313C (en) | 2010-10-26 |
Family
ID=33567690
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
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| CA2526313C (en) | 2010-10-26 |
| AU2004253930B2 (en) | 2008-04-03 |
| CA2526277C (en) | 2010-10-05 |
| AU2004253933B2 (en) | 2008-04-03 |
| MXPA05013676A (en) | 2006-02-24 |
| ES2382188T3 (en) | 2012-06-06 |
| AU2004253933A1 (en) | 2005-01-13 |
| ATE539142T1 (en) | 2012-01-15 |
| CA2526277A1 (en) | 2005-01-13 |
| BRPI0411898A (en) | 2006-08-29 |
| JP2006527313A (en) | 2006-11-30 |
| US8148315B2 (en) | 2012-04-03 |
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| AU2004253930A1 (en) | 2005-01-13 |
| ATE544842T1 (en) | 2012-02-15 |
| EP1639076B1 (en) | 2011-12-28 |
| JP4335255B2 (en) | 2009-09-30 |
| EP1639075A1 (en) | 2006-03-29 |
| WO2005003282A1 (en) | 2005-01-13 |
| US20050000028A1 (en) | 2005-01-06 |
| US7462589B2 (en) | 2008-12-09 |
| JP2006527787A (en) | 2006-12-07 |
| ES2380019T3 (en) | 2012-05-07 |
| MXPA05013675A (en) | 2006-02-24 |
| WO2005003281A1 (en) | 2005-01-13 |
| EP1639075B1 (en) | 2012-02-08 |
| US20050000027A1 (en) | 2005-01-06 |
| BRPI0411853A (en) | 2006-08-29 |
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