CA2516066A1 - Oriented thermoplastic elastomer film and process for producing the same - Google Patents
Oriented thermoplastic elastomer film and process for producing the same Download PDFInfo
- Publication number
- CA2516066A1 CA2516066A1 CA 2516066 CA2516066A CA2516066A1 CA 2516066 A1 CA2516066 A1 CA 2516066A1 CA 2516066 CA2516066 CA 2516066 CA 2516066 A CA2516066 A CA 2516066A CA 2516066 A1 CA2516066 A1 CA 2516066A1
- Authority
- CA
- Canada
- Prior art keywords
- nylon
- film
- thermoplastic elastomer
- oriented thermoplastic
- blowing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C08L23/283—Halogenated homo- or copolymers of iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/254—Polymeric or resinous material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/268—Monolayer with structurally defined element
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/269—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension including synthetic resin or polymer layer or component
Abstract
An oriented thermoplastic elastomer film having reduced permeability and improved fatigue resistance comprising a dynamically vulcanized polymer blend of (A) a halogenated isobutylene elastomer and (B) polyamide, the film is produced by casting or blowing the above polymer blend under the condition such that a shear rate at a die lip for casting or blowing is regulated to control the molecular arrangement in the film, whereby the planar birefringemence (PBR) of the resultant film becomes greater or equal to 0.002 and a production process of the same.
Claims (4)
1. An oriented thermoplastic elastomer film having reduced permeability and improved fatigue resistance comprising a dynamically vulcanized polymer blend of (A) a halogenated isobutylene elastomer and (B) polyamide, the film is produced by casting or blowing the above polymer blend under the condition such that a shear rate at a die lip for casting or blowing is regulated to control the molecular arrangement in the film, whereby the planar birefringemence (PBR) of the resultant film becomes greater or equal to 0.002.
2. An oriented thermoplastic elastomer film as claimed in claim 1, wherein the amount of the halogenated isobutylene elastomer is 95 to 25 parts by weight and the amount of the polyamide is 5 to 75 parts by weight.
3. An oriented thermoplastic elastomer film as claimed in claim 1 wherein the halogenated isobutylene elastomer is brominated poly(isobutylene-co-p-methylstyrene.
4. An oriented thermoplastic elastomer film as claimed in claim 1, wherein the polyamide is at least one member selected from the group consisting of Nylon 6, Nylon 66 Nylon 11, Nylon 69, Nylon 12, Nylon 610, Nylon 612, Nylon 46, Nylon MXD6, Nylon 6/66 and the copolymers thereof, and the blends thereof.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2003/006560 WO2004081116A1 (en) | 2003-03-06 | 2003-03-06 | Oriented thermoplastic elastomer film and process for producing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2516066A1 true CA2516066A1 (en) | 2004-09-23 |
CA2516066C CA2516066C (en) | 2010-06-08 |
Family
ID=32986318
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2516066 Expired - Fee Related CA2516066C (en) | 2003-03-06 | 2003-03-06 | Oriented thermoplastic elastomer film and process for producing the same |
Country Status (7)
Country | Link |
---|---|
US (2) | US20060241244A1 (en) |
EP (1) | EP1599542B1 (en) |
JP (1) | JP2006514138A (en) |
CN (1) | CN100473692C (en) |
AU (1) | AU2003216509A1 (en) |
CA (1) | CA2516066C (en) |
WO (1) | WO2004081116A1 (en) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050113532A1 (en) * | 2003-11-26 | 2005-05-26 | Fish Robert B.Jr. | High flow, toughened, weatherable polyamide compositions containing a blend of stabilizers |
WO2006101718A1 (en) * | 2005-03-23 | 2006-09-28 | Wilk Patent, Llc | Device and instrument kit for use in trans-vascular surgical method |
JP2006315339A (en) * | 2005-05-13 | 2006-11-24 | Yokohama Rubber Co Ltd:The | Thermoplastic elastomer film |
RU2379187C1 (en) | 2005-10-27 | 2010-01-20 | Эксонмобил Кемикал Пэйтентс, Инк. | Structure with joining layer |
WO2007050076A1 (en) | 2005-10-27 | 2007-05-03 | Exxonmobil Chemical Patents Inc. | Low permeability thermoplastic elastomer composition |
CA2627338C (en) | 2005-10-27 | 2011-08-02 | Exxonmobil Chemical Patents Inc. | Construction comprising tie layer |
EP2502742B1 (en) | 2005-10-27 | 2017-06-21 | ExxonMobil Chemical Patents Inc. | Construction comprising tie layer for pneumatic tire |
DE602006016867D1 (en) | 2006-01-10 | 2010-10-21 | Yokohama Rubber Co Ltd | LAMINATE OF THERMOPLASTIC POLYMER COMPOSITION WITH LOW AIR PURPOSES AND THESE AIR TIRES USING AS INTERIOR LAYER |
WO2007111584A1 (en) * | 2006-03-24 | 2007-10-04 | The Yokohama Rubber Co., Ltd. | Thermoplastic elastomer composition having excellent low temperature property |
CN101541530B (en) | 2006-10-26 | 2015-09-09 | 埃克森美孚化学专利公司 | Low moisture permeability laminate construction |
US8846792B2 (en) | 2006-10-26 | 2014-09-30 | The Yokohama Rubber Co., Ltd. | Construction comprising tie layer |
US9177323B2 (en) | 2007-08-28 | 2015-11-03 | Causam Energy, Inc. | Systems and methods for determining and utilizing customer energy profiles for load control for individual structures, devices, and aggregation of same |
US8805552B2 (en) | 2007-08-28 | 2014-08-12 | Causam Energy, Inc. | Method and apparatus for actively managing consumption of electric power over an electric power grid |
US8806239B2 (en) | 2007-08-28 | 2014-08-12 | Causam Energy, Inc. | System, method, and apparatus for actively managing consumption of electric power supplied by one or more electric power grid operators |
US8890505B2 (en) | 2007-08-28 | 2014-11-18 | Causam Energy, Inc. | System and method for estimating and providing dispatchable operating reserve energy capacity through use of active load management |
US9130402B2 (en) | 2007-08-28 | 2015-09-08 | Causam Energy, Inc. | System and method for generating and providing dispatchable operating reserve energy capacity through use of active load management |
JP4821868B2 (en) * | 2009-03-13 | 2011-11-24 | 横浜ゴム株式会社 | Thermoplastic elastomer composition |
US8809455B2 (en) * | 2009-08-27 | 2014-08-19 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions and their use in articles |
JP5736677B2 (en) | 2010-06-25 | 2015-06-17 | 横浜ゴム株式会社 | Thermoplastic elastomer composition and method for producing the same |
WO2013191685A1 (en) * | 2012-06-19 | 2013-12-27 | The Yokohama Rubber Co., Ltd. | Thermoplastic elastomer composition and process to produce same |
US10475138B2 (en) | 2015-09-23 | 2019-11-12 | Causam Energy, Inc. | Systems and methods for advanced energy network |
US8983669B2 (en) | 2012-07-31 | 2015-03-17 | Causam Energy, Inc. | System, method, and data packets for messaging for electric power grid elements over a secure internet protocol network |
US8849715B2 (en) | 2012-10-24 | 2014-09-30 | Causam Energy, Inc. | System, method, and apparatus for settlement for participation in an electric power grid |
US10861112B2 (en) | 2012-07-31 | 2020-12-08 | Causam Energy, Inc. | Systems and methods for advanced energy settlements, network-based messaging, and applications supporting the same on a blockchain platform |
US9513648B2 (en) | 2012-07-31 | 2016-12-06 | Causam Energy, Inc. | System, method, and apparatus for electric power grid and network management of grid elements |
EP2892722A1 (en) | 2012-09-06 | 2015-07-15 | ExxonMobil Chemical Patents Inc. | Construction comprising tie layer |
CN103072253B (en) * | 2012-12-26 | 2014-12-10 | 江阴升辉包装材料有限公司 | Forming process suitable for thermoplasticity elastic body extrusion blow molding |
JP2018523729A (en) * | 2015-07-28 | 2018-08-23 | エクソンモービル ケミカル パテンツ インコーポレイテッド | Elastomer compositions and their use in articles |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100275391B1 (en) | 1993-04-05 | 2000-12-15 | 엑손 케미칼 패턴츠 인코포레이티드 | Composite tire inner-liners and inner tubes |
US5576372A (en) * | 1993-04-05 | 1996-11-19 | Exxon Chemical Patents Inc. | Composite tire innerliners and inner tubes |
US5576373A (en) * | 1993-04-05 | 1996-11-19 | Exxon Chemical Patents Inc. | Composite tire innerliners and inner tubes |
JP3153093B2 (en) | 1995-02-16 | 2001-04-03 | 横浜ゴム株式会社 | Pneumatic tire |
JP3217239B2 (en) | 1995-01-23 | 2001-10-09 | 横浜ゴム株式会社 | Polymer composition for tire and pneumatic tire using the same |
JPH08217922A (en) | 1995-02-16 | 1996-08-27 | Yokohama Rubber Co Ltd:The | Pneumatic tire |
JP3212470B2 (en) | 1995-02-16 | 2001-09-25 | 横浜ゴム株式会社 | Polymer composition for tires |
US6079465A (en) | 1995-01-23 | 2000-06-27 | The Yokohama Rubber Co., Ltd. | Polymer composition for tire and pneumatic tire using same |
JPH09124848A (en) | 1995-11-02 | 1997-05-13 | Yokohama Rubber Co Ltd:The | Thermoplastic elastomer composition for low permeability hose and low permeability hose using the same |
JPH09143366A (en) | 1995-11-21 | 1997-06-03 | Yokohama Rubber Co Ltd:The | Thermoplastic elastomer composition, its production and low-permeability hose |
JPH1036571A (en) | 1996-07-23 | 1998-02-10 | Yokohama Rubber Co Ltd:The | Functional thermoplastic elastomer composition and its production |
JPH1025375A (en) * | 1996-07-12 | 1998-01-27 | Yokohama Rubber Co Ltd:The | Thermoplastic elastomer composition and pneumatic tire and hose using the same |
JP3640467B2 (en) | 1996-05-29 | 2005-04-20 | 横浜ゴム株式会社 | Thermoplastic elastomer composition and pneumatic tire using the same |
JP3098191B2 (en) | 1996-06-27 | 2000-10-16 | 横浜ゴム株式会社 | Rubber / thermoplastic elastomer laminate |
US6062283A (en) | 1996-05-29 | 2000-05-16 | The Yokohama Rubber Co., Ltd. | Pneumatic tire made by using lowly permeable thermoplastic elastomer composition in gas-barrier layer and thermoplastic elastomer composition for use therein |
JPH09314752A (en) | 1996-05-29 | 1997-12-09 | Yokohama Rubber Co Ltd:The | Rubber-thermoplastic elastomer laminate |
JP3138861B2 (en) | 1996-07-22 | 2001-02-26 | 横浜ゴム株式会社 | Pneumatic tire |
JP3159941B2 (en) | 1996-07-23 | 2001-04-23 | 横浜ゴム株式会社 | Low gas permeable thermoplastic elastomer composition and method for producing the same |
EP0969039B1 (en) | 1998-01-13 | 2013-07-31 | The Yokohama Rubber Co., Ltd. | Thermoplastic elastomer composition, process for producing the same, and pneumatic tire and hose made with the same |
US6376598B1 (en) * | 2000-06-15 | 2002-04-23 | Exxon Mobil Chemical Patents Inc. | Thermoplastic blend |
HUP0301623A2 (en) * | 2000-08-15 | 2003-08-28 | Exxonmobil Chem Patents Inc | Oriented thermoplastic vulcanizate |
-
2003
- 2003-03-06 CA CA 2516066 patent/CA2516066C/en not_active Expired - Fee Related
- 2003-03-06 EP EP20030816271 patent/EP1599542B1/en not_active Expired - Lifetime
- 2003-03-06 JP JP2004569394A patent/JP2006514138A/en not_active Withdrawn
- 2003-03-06 CN CNB038261022A patent/CN100473692C/en not_active Expired - Lifetime
- 2003-03-06 US US10/548,064 patent/US20060241244A1/en not_active Abandoned
- 2003-03-06 WO PCT/US2003/006560 patent/WO2004081116A1/en active Application Filing
- 2003-03-06 AU AU2003216509A patent/AU2003216509A1/en not_active Abandoned
-
2009
- 2009-12-28 US US12/648,057 patent/US7879272B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN1751098A (en) | 2006-03-22 |
WO2004081116A1 (en) | 2004-09-23 |
AU2003216509A1 (en) | 2004-09-30 |
JP2006514138A (en) | 2006-04-27 |
AU2003216509A8 (en) | 2004-09-30 |
CN100473692C (en) | 2009-04-01 |
EP1599542B1 (en) | 2014-06-25 |
EP1599542A1 (en) | 2005-11-30 |
US20060241244A1 (en) | 2006-10-26 |
US7879272B2 (en) | 2011-02-01 |
US20100113701A1 (en) | 2010-05-06 |
CA2516066C (en) | 2010-06-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20220908 |
|
MKLA | Lapsed |
Effective date: 20210308 |