CA2513508C

CA2513508C - Facing material with controlled porosity for construction boards

Info

Publication number: CA2513508C
Application number: CA 2513508
Authority: CA
Inventors: John F. Porter
Original assignee: Saint Gobain Technical Fabrics Canada Ltd; Saint Gobain Technical Fabrics America Inc
Current assignee: Saint Gobain Adfors America Inc; Saint Gobain Adfors Canada Ltd
Priority date: 2003-01-21
Filing date: 2004-01-20
Publication date: 2009-04-21
Anticipated expiration: 2024-01-20
Also published as: DE602004028343D1; CA2513508A1; EP1595012B1; AU2004207774B2; AU2004207774A1; CN1754015B; EP1595012A4; US20060105653A1; US7049251B2; MX366513B; WO2004067271A3; JP5019486B2; JP5019482B2; JP5019481B2; JP2009174310A; US20040142618A1; US7300515B2; CN1754015A; US7300892B2; MXPA05007692A

Abstract

A cementitious board (100) and a method for manufacturing the cementitious board (100) has a facing layer (105) having an areal weight of about 300 grams/M2, and an air permeability rating of no greater than about 300 CFM/ft2 (FG 436-910 test method). The facing layer (105) reduces the penetration of a slurry (28) of cementitious material during the manufacture of the board (100), and passes water vapor from the slurry (28) while the slurry (28) cures. Binders, coatings or saturants (107) decrease pore size, increase or decrease the contact angle of liquids, promote adhesion to cementitious cores (101), promote adhesion to the facing layer (105) and promote adhesion or affinity to adhesive compositions used to join cementitious boards to exterior insulation systems and exterior finishing systems (EIS and EIFS).

Description

FACING MATERIAL WITH CONTROLLED POROSITY

FOR CONSTRUCTION BOARDS
Field of the Invention [0001] This invention relates to improvements to cementitious boards useful in building construction, such as cement and gypsum sheathing for exterior insulation finishing systems EIFS, shaft walls, tile backers and fire walls.
Background of the Invention [0002] Cementitious boards useful in the construction industry are known to contain inorganic, hydraulically setting material, such as Portland ceinent or gypsum. Hydraulic gypsum and cement, once set, have very little tensile strength and are usually reinforced with facing materials which improve the resistance to tensile and torsional loads. This has been the basis for using paper facing on conventional-gypsum wall board and-glass fiber scrim in cement boards.

[0003] Recently, gypsum sheathing has been used outdoors in exterior insulation or finishing systems, with or without insulation layers, (sometimes referred to as "EIF systems"). These systems are designed to accept polystyrene insulation adhered to a glass-faced gypsum board, followed by brick, stone, a thin application of stucco, or siding, for example. Because of the exposure to the eleinents, these boards are often treated or impregnated with hydrophobic additives. Simply adding hydrophobic agents, such as asphalt, waxes, or siloxane to the core or paper facing, however, does not prevent delainination at the interface between the core and paper facing, nor does it prevent the paper from losing most of its strength due to water absorption over time. Cementitious boards used in exterior sheathing applications should also be fire resistant, which limits the use of flammable facing materials. It has become essential, therefore, that the core, the interface, and the facing material, on the exposed side of these boards, retain their strength after exposure to wind, rain, snow, fire and ultraviolet light.

[0004] To the extent that cementitious boards are used in the interior of buildings, for tile backing, shaft wall, and fire wall applications, moisture and fire resistance requirements also limit the use of paper facing. While paper can be treated with moisture vapor retarders and non-permeable barrier films, these layers impede water vapor from cementitious slurries from evaporating through the facing. This makes continuous board manufacturing with vapor impermeable fihns difficult, since the slurry must be allowed to evaporate the excess "water of convenience", which represents additional water used to facilitate a slurry, which is not used in hydration.

[0005] Accordingly, artisans over the last thirty years have developed facing materials made from glass fibers which are known to overcome many of the weaknesses of paper facing materials. For example, in Canadian Patent No.
993,779, gypsum boards are disclosed which are prepared by depositing a plaster slurry on a sheet of inorganic fibers on a moving conveyor belt. A second sheet of similar fibers is pressed on top of the slurry, followed by guiding the sandwiched plaster slurry between rollers to cause a slurry to penetrate into the fibrous sheets at the surfaces of the slurry mass. It has been found that such a process gives only partial and irregular penetration of the slurry into the inorganic, fibrous sheet, leaving the resulting board with a rough surface in which both fibers and gypsum are apparent. Due to the penetration of slurry, cantamination of the rollers by set gypsum is an unfortunate consequence. Such contamination can leave imperfections in the surface of subsequently produced boards on the same line if not remedied. Unfortunately, remediating contaminated rollers requires shutting down the entire continuous wallboard manufacturing line for a period of hours or days, whicli leads to significant losses in production and downtime costs.

[0006] Others have addressed this problem of gypsum slurry penetration during continuous board production. In U.S. Patent Nos. 3,993,822 and 4,504,533 a composite glass mat layer containing a fiberglass cloth joined with a fiberglass fleece, pasteboard, foil, felt or paper is used to make boards. In each method, the fleece, felt or alternative sheet is resistant to the penetration of gypsum and the structure is formed by simple successive application of the different sheets and compositions to a forming table or conveyor. The resulting product has a surface texture determined by the nature of the outer sheet used. However, due to the lack of any integral fastening measure between the glass fiber cloth and the outer sheet, the outer sheets selected can be insufficiently bonded to the set gypsum core. This can lead to unintended delaminations during adhesive bonding in the assembly of E1F systems.
Polymeric webs combined with glass scrim reinforcement has also been suggested for facing sheets of cementitious boards. See U.S. Pat. No. 6,054,205.

[0007] More recently, attempts have been made to employ the use of random oriented, chopped glass fibrous mats bonded by a resinous adhesive. See U.S. Patent Nos. 4,647,496, 4,810,569 and 5,220,762. The described production ..methods of these patents_pxefer to employ viscosity-control agents, such as paper fiber, cellulosic thickeners, bentonite clays, and starches for penmitting the top glass fiber mat to be substantially free of set gypsum, while not preventing penetration through the lower mat. Since only one surface of the gypsum board needs to be free of set gypsum, for adhesive attachment of polystyrene insulation layers, and such, designing a slurry to penetrate the lower glass mat, while only partially penetrating the upper glass mat, produces a commercially acceptable product. However, the fouling of shaping and feeder rolls used to press and shape glass mat faced gypsum wallboard is not entirely solved by such a solution, since gypsum sluny penetration through the lower mat is not prevented.

[0008] While efforts have been made to reduce moisture penetration in glass mat faced gypsum boards by applying latex coatings to the set board (see U.S. Pat. No. 5,552,187) artisans have been reluctant to reduce the porosity of the glass mat prior to contacting the gypsum slurry. Two reasons for this could be the fear of insufficient penetration by the slurry into the pores of the mat, which would result in poor adhesion, or the concern that a less porous mat would prohibit or reduce water vapor from successfully escaping the core during setting.

[0009] Accordingly, there remains a need in the industry for manufacturing cementitious boards to create a high strength, fire-resistant facing material which does not delaminate in wet environments, yet is not substantially permeable to slurries of cementitious material which have been known to contaminate rolls used in the continuous processing of such boards.
Summary of the Invention [0010] In accordance with an einbodiment of the present invention, a facing material is provided for use in the manufacture of cementitious boards for building construction. The facing material includes a porous facing layer containing glass fibers, said facing layer substantially preventing a slurry of said cementitious material disposed on top of said facing layer from_substantially penetrating through its full thickness during the manufacture of said cementitious board. The porous spacing layer also permits the passage of water vapor from said slurry to pass therethrough.

[0011] The facing materials of this invention provide cementitious boards, such as those made from Portland cement and gypsum, to achieve high strength and greater fire resistance than paper-faced boards. The most preferred facing materials are not substantially permeable to cementitious slurries, which have been lcnown to contaminate rolls, and are preferably joined to the board's core in such a way so as to substa.ntially eliminate delamination between the facing and the core, or between the layers of the facing material, if more than one layer is applied. VJhile substantially reducing the penetration of a cementitious slurry, the facing materials of this invention still permit the passage of water vapor from the slurry to pass througll, before and during the setting of the cementitious material.
The facing materials, and boards manufactured using them, are suitable for exterior grade sheathing containing a modified gypsum or cement core. They can contain exposed glass fibers on one or both sides for helping to join to adhesives, such as mortar, acrylic or silicone based adhesives, and glue, in exterior insulation finishing systems ("EIF") or tile=backing applications, for example. The cementitious boards produced by this invention can contain a porous facing layer containing glass fibers on one or both faces, and can contain water- and fire-resistant additives in the facings, core, or both.

[0012] An embodiment of a porous facing layer contains glass fibers having an average diaineter of about 16 microns or less, said facing layer having an areal weight of about 15-300 gram/m2, and an air permeability rating of no greater than about 300 CFIliI/ft2 according to (FG 436-910 test methods). An embodiment of a water- and fire-resistant facing material of this invention has an areal weight of at least about 15 grams/mz and desirably, has an areal weight of between about 30 and 150 grams/m2. This areal weight is high enough to provide the board with the required physical properties such as stiffness, flexural strength, nail or screw holding capability, and dimensional stability. It is light enough to be economically transported when applied to a board, and handled by EIF or shaft wall system installers, without premature fatigue.

[0013] The desirable properties of the facing layers and materials of this invention include being substantially impervious to the penetration of a slurry having a viscosity of about 300-10,000 cp at 70 F, having a screw holding value of at least about 20 lbs. when applied to a cementitious material, and an ASTM
D309 tensile strength of at least about 20 psi in the machine direction, and at least about 5 psi in the cross-machine direction.

[0014] In a further embodiment of this invention, a method of making a cementitious board for building construction, includes the steps of (a) forming a slurry of cementitious material and water in a quantity greater than that required to set said cementitious material; (b) disposing said slurry on top of a first facing layer; wherein said first facing layer comprises a porous material containing glass fibers substantially resisting penetration of said slurry, and having a permeability for passage of water vapor from said slurry;(c) disposing a second facing layer on top of said slurry; and (d) setting said slurry to a set core, while water vapor from said slurry passes through said first facing layer.

[0015] In still a fiuther embodiment of this invention, a water-resistant and first-resistant cementitious board useful in building construction is provided. This cementitious board embodiment includes a layer of said cementitious material sandwiched between a pair of facing layers, at least a first of said facing layers comprising glass fibers bonded together with a resinous binder composition having a hydrophilic or adhesive affinity toward said cementitious material when wet, said first facing layer having an air penneability rating of no greater than about 300 CFM/ft2 so as to substantially prevent penetration of a slurry precursor of said cementitious material having a viscosity of less than 5,000 sp at 70 F, but permit water vapor from said slurry to pass therethrough.

[0016] In still a further embodiment of this invention, a facing material for gypsum boards is provided which includes a first layer including an oriented fiber-containing layer which is porous to a gypsum slurry; and a second non-woven layer joined to said first layer, said second non-woven layer being less porous to said gypsum slurry than said first layer, and comprising randomly oriented fibers bonded with a resinous binder applied in excess of about 15% by weight of the fibers. This resinous binder does not inhibit adhesion of said facing material to said gypsum, and does not encourage "blocking" between adjacent pairs of said boards during storage.

A Brief Descrapta u of the I-rawflngo [0017] The present invention will be further described witll reference to the following drawings:

[0018] FIG. 1: is a front perspective view of a preferred facing material of this invention employing a plain weave;

[0019] FIG. 2: is an alternative facing material of this invention depicting a five-harness satin weave;

[0020] FIG. 3: is a further embodiment of the facing material of this invention depicting a uni-directional weave;

[0021] FIG. 4: is a further embodiment of the facing material of this invention depicting a full-width plain weave witll selvage;

[0022] FIG. 5: is a diagrainmatic, side elevational view of a proposed continuous manufacturing line for producing cementitious boards using the facing material of this invention;

[0023] FIG. 6: is a magnified view of a coated cementitious board of FIG.
5;

[0024] FIG. 7: is a loose full-width plain weave glass fabric prior to manipulation;

[0025] FIG. 8: is the full-width plain weave glass fabric of FIG. 7, after the glass fiber filaments have been electrostatically or mechanically manipulated;
and [0026] FIG. 9: is a front perspective, exploded view of a preferred composite facing material of this invention.

IDefined Terms [0027] Facing materials, cementitious boards and methods of manufacturing cementitious boards having the facing materials of this invention are provided. These facing materials have low areal weiglits, and substantially prevent the penetration of cementitious slurries, such as those containing Portland cement, mortar and gypsum, yet remain porous enough for water vapor to pass through easily.

[0028] In accordance with the present invention, the following definitions are used:

[0029] Areal weight. The weight of fiber per unit area (width x length) of tape or fabric.

[0030] Cementitious material. An inorganic hydraulically setting material, such as those containing one or more of: Portland cement, mortar, plaster, gypsum, and/or other ingredients, such as, foaming agents, aggregate, glass fibers, moisture repellants and moisture resistant additives and fire retardants.

[0031] Composite facing material. Two or more layers of the same or different materials including two or more layers of fabrics, cloth, knits, mats, wovens, non-wovens and/or scrims, for example.

[0032] Barrier coat. An exterior coating applied to a composite structure to provide protection.

[0033] Fabric. Woven or non-woven flexible materials, such as tissues, cloth, knits, weaves, carded tissue, spun-bonded and point-bonded non-wovens, needled or braided materials.

[0034] Fiber. A general terin used to refer to filamentary materials.
Often, fiber is used synonymously with fila.inent. It is generally accepted that a filament routinely has a finite length that is at least 100 times its diameter. In most cases, it is prepared by drawing from a molten bath, spinning, or by deposition on a substrate.

[0035] Filament. The smallest unit of a fibrous material. The basic units formed during drawing and spinning, which are gathered into strands of fiber for use in composites. Filaments usually are of extreme length and very small diameter. Some textile filaments can function as a yam when they are of sufficient strength and flexibility.

[0036] Glass. An inorganic product of fusion that has cooled to a rigid condition without crystallizing. Glass is typically hard and relatively brittle, and has a conchoidal fracture.

[0037] Glass cloth. An oriented fabric which can be woven, knit, needled, or braided glass fiber material, for example.

[0038] Glass fiber. A fiber spun from an inorganic product of fusion that has cooled to a rigid condition without crystallizing.

[0039] Glass Filament. A form of glass that has been drawn to a small diameter and long lengths.

[0040] Knitted fabrics. Fabrics produced by interlooping chains of filaments, roving or yarn.

[0041] Mat. A fibrous material consisting of randomly oriented chopped filainents, short fibers, or swirled filaments loosely held together with a binder.

[0042] Roving. A number of yarns, strands, tows, or ends collected into a parallel bundle with little or no twist.

[0043] Tensile strength. The maximum load or force per unit cross-sectional area, within the gage length, of the specimen. The pulling stress required to break a given specimen. (See ASTM D579 and D3039) [0044] Tez. Linear density (or gauge) of a fiber expressed in grams per 1000 meters.

[0045] Textile fibers. Fibers or filaments that can be processed into yarn or made into a fabric by interlacing in a variety of methods, including weaving, knitting and braiding.

[0046] Viscosity. The property of resistance to flow exhibited within the body of a material, expressed in terms of the relationship between applied shearing stress and resulting rate of strain in shear. Viscosity is usually taken to mean Newtonian viscosity, in which case the ratio of sheathing stress to the rate of shearing strain is constant. In non-Newtonian behavior, the ratio varies with the shearing stress. Such ratios are often called the apparent viscosities at the 5, corresponding shearing stresses. Viscosity is measured in terms of flow in Pa - s (P), with water as the base standard (value of 1.0). The higher the number, the less flow.

[0047] Warp. The yarn, fiber or roving running lengthwise in a woven fabric. A group of yarns, fibers or roving in long lengths and approximately parallel.

[0048] Weave. The particular manner in which a fabric is formed by interlacing yarns, fibers or roving. Usually assigned a style number.

[0049] Weft. The transverse threads or fibers in a woven fabric. Those fibers running perpendicular to the warp. Also called fill, filling, yarn or woof.

[0050] Woven fabric. A material (usually a planar structure) consti-ucted by interlacing yarns, fibers, roving or filaments, to form suchIabric patterns as plain, harness satin, or leno weaves.

[0051] Woven roving. A heavy glass fiber fabric made by weaving roving or yarn bundles.

[0052] 'Yarn. An assemblage of twisted filaments, fibers, or strands, either natural or manufactured, to form a continuous length that is suitable for use in weaving or interveaving into textile materials.

[0053] Zero-twist-yarn. A lightweight roving, i.e., a strand of near zero twist with linear densities and filament diameters typical of fiberglass yam (but substantially without twist).

Detailed Description of the Invention [0054] With reference to the Figures, and particularly to FIGS. 1-4 thereof, there is depicted a series of fabrics useful as the facing layer of the preferred facing material of this invention. Needled, woven, knitted and composite materials are preferred because of their impressive strength-to-weight ratio and, in the case of wovens and knits, their ability to form weft and warp yarn patterns which substantially resist the penetration of cementitious slurries.
While the facing layers of this invention can contain fibers and filaments of organic and inorganic materials, the most preferred fibers contain glass, olefin (such as polyethylene, polystyrene and polypropylene), Kevlar , grapllite, rayon, polyester, carbon, ceramic fibers, or combinations thereof, such as glass-polyester blends or Twintex glass-olefin composite, available from St. Gobain Corporation, France. Of these types of fibers and filaments, glass compositions are the most desirable for their fire resistance, low cost and high mechanical strength properties.
Glass Composition [0055] Although a number of glass compositions have been developed, only a few are used commercially to create continuous glass fibers. The four main glasses used are high alkali (A-glass or AR-glass) useful in mortar or cement applications, such as in tile backing, electrical grade (E-glass), a modified E-glass that is chemically resistant (ECR-glass), and high strength (S-glass). The representative chemical compositions of these four glasses are given in Table 1.

[0056] Table 1: Glass composition Material, wt%
Calciu m Magnesi Boric Calcium Total Glass type Silica Alumina oxide a oxide Soda fluoride minor oxides E-glass 54 14 20.5 0.5 8 1 1 1 A-glass 72 1 8 4 - 14 - 1 ECR-glass 61 11 22 3 - 0.6 - 2.4 S-glass 64= 25 - 10 - 0.3 - 0.7 [0057] The inherent properties of the four glass fibers having these compositions are given in Table 2.

[0058] Table 2: Inherent properties of glass fibers Tensile Tensile Coefficient of strength modulus thermal - -- Liquidus temperature Specific MP GP expansion, Dielectric gravity a ksi a 106 psi 10-6 /K constant(a) C F
E-glass 345 72.
2.58 500 10.5 5.0 6.3 1065 1950 A-glass 304 69.
2.50 440 10.0 8.6 6.9 996 1825 ECR-glass 362 72.
2.62 525 10.5 5.0 6.5 1204 2200 S-glass 459 86.
2.48 665 12.5 5.6 5.1 1454 2650 (a) At 20 C(72 F) and 1 MHZ. Source: Ref 4 Gla.ss Melting and Forming [0059] The conversion of molten glass in the forehearth into continuous glass fibers is basically an attenuation process. The molten glass flows through a platinum-rhodium alloy bushing with a large number of holes or tips (400 to 8000, in typical production). The bushing is heated electrically, and the heat is controlled very precisely to maintain a constant glass viscosity. The fibers are drawn down and cooled rapidly as they exit the bushing. A sizing is then applied to the surface of the fibers by passing them over an applicator that continually rotates through the sizing bath to maintain a thin film through which the glass filaments pass. After the sizing is applied, the filaments are gathered into a strand before approaching the talce-up device. If smaller bundles of filaments (split strands) are required, multiple gathering devices (often called shoes) are used.

[0060] The attenuation rate, and therefore the final filament diameter, is controlled by the take-up device. Fiber diameter is also impacted by bushing temperature, glass viscosity, and the pressure head over the bushing. The most widely used take-up device is the forining winder, which employs a rotating collet and a traverse mechanism to distribute the strand in a random manner as the forming package grows in diameter. This facilitates strand removal from the package in subsequent processing steps, such as roving or chopping. The forming packages are dried and transferred to the specific. fabrication area for conversion into the finished fiberglass roving, mat, chopped strand, or other product. In recent years, processes have been developed to produce finished roving or chopped products directly during forming, thus leading to the term direct draw roving or direct chopped strand.

Fabrication Process [0061] Once the continuous glass fibers have been produced they must be converted into a suitable form for their intended application. The major finished forms are continuous roving, woven roving, fiberglass mat, chopped strand, and yams for textile applications.

[0062] Fiberglass roving is produced by collecting a bundle of strands into a single large strand, which is wound into a stable, cylindrical package. This is called a multi-end roving process. The process begins by placing a number of oven-dried forming packages into a creel. The ends are then gathered together under tension and collected on a precision roving winder that has constant traverse-to-winding ratio, called the waywind.

[0063] Roving are used in many applications of this invention. Woven roving is produced by weaving fiberglass roving into a fabric form. This yields a coarse product that is used in continuous board manufacturing. The course surface is ideal for stucco and adhesive applications, such as EIF systems, since these material can bind to the coarse fibers easily. Plain or twill weaves are less rough, thereby being easier to handle without protective gloves, but will absorb stucco and adhesive. They also provide strength in both directions, while a unidirectionally stitched or knitted fabric provides strength primarily in one dimension. Many novel fabrics are currently available, including biaxial, double bias, and triaxial weaves for special applications.

[0064] Combinations of fiberglass mat, scrim, chopped fibers and woven or knit filaments or roving can also be used for the facing layers of this invention.
The appropriate weights of fiberglass mat (usually chopped-strand mat) and woven roving filaments or loose chopped fibers are either bound together with a chemical binder or mechanically loiit, needled felted or stitched together.
One suitable combination would be a fiberglass and/or resin fiber mat or scrim layered with chopped glass or resin fibers and then rieedled, felted or stitched together to decrease porosity. These facing materials can have uniform porosity or non-uniform porosity in either the x, y, or z planar directions. For example, as in U.S.
Pat. Nos. 3,993,822 and 4,504,533, a porosity gradient can be made within a coinposite facing to allow partial penetration of the slurry. Alternatively, the coating or saturant, such as a latex resin or wetting or non-wetting agent, can be unevenly applied through the facing thickness to allow partial penetration of the slurry. One exainple could be to coat the slurry facing side with a low contact angle surface treatment and the outer-facing side with a resinous saturant or high contact angle treatment or hydrophobic agent, for example.

[0065] Fiberglass paper can also be used for the facing layers of this invention, so long as it is relatively impervious to slurry and pervious to water vapor. Chopped strands of 25 to 50 mm (1- to 2-in.) lengths are usually used in making fiberglass paper. In this process, chopped fibers are dispersed in a water to form a dilute solution. The fiberglass strands filamentize during the mixing and dispersion process. The solution is pumped onto a continuously moving chain or belt, where most of the water is removed by vacuum, leaving behind a uniformly distributed, thin fiberglass mat. A binding resin is added on-line, followed by drying and curing, to form the fiberglass paper. Although possessing a lower mechanical strength than woven glass fabric, glass paper is cheaper to make and is fire resistant.

[0066] The yams of the facing layers of this invention can be made by conventional means. Fine-fiber strands of yam from the forming operation can be air dried on forming tubes to provide sufficient integrity to undergo a twisting operation. Twist provides additional integrity to yam before it is subjected to the weaving process, a typical twist consisting of up to one tum per inch. In many instances heavier yams are needed for the weaving operation. This is normally accomplished by twisting together two or more single strands, followed by a plying operation. Plying essentially involves retwisting the twisted strands in the opposite direction from the original twist. The two types of twist normally used are known as S and Z, which indicate the direction in which the twisting is done.
Usually, two or more strands twisted together with an S twist are plied with a Z
twist in order to give a balanced yarn. Thus, the yam properties, such as strength, bundle diarneter, and yield, can be manipulated by the twisting and plying operations. Fiberglass yams are converted to fabric forln by conventional weaving operations. Looms of various kinds are used in the industry, but the air jet loom is the most popular.

[0067] Zero twist-yams may also be used. This input can offer the ease of spreading of (twistless) roving with the coverage of fine-filament yarns. The number of filaments per strand used directly affect the porosity and are related to yam weight as follows: n= (490 x Tex) / d2, where "d" is the individual filament diameter expressed in microns. Thus, if the roving with coarse filaments can be replaced with near zero twist yarn with filaments half the diameter, then the number of filaments increases by a factor of 4 at the same strand Tex.

[0068] The major characteristics of the woven facing embodiments of this invention include its style or weave pattern, fabric count, and the construction of warp yarn and fill yarn. Together, these characteristics determine fabric properties such as drapability and perfoimance in the final board. The fabric count identifies the number of warp and fill yarns per inch. Warp yarns run parallel to the machine direction, and fill yarns are perpendicular.

[0069] There are basically four weave patterns: plain, basket, twill, and satin. Plain weave is the simplest form, in which ne warp yarn interlaces over and under one fill yarn. Basket weave has two or more warp yarns interlacing over and under two or more fill yarns. Twill weave has one or more warp yarns over at least two fill yarns. Satin weave (crowfoot) consists of one warp yam interfacing over three and under one fill yarn, to give an irregular pattern in the fabric. The eigllt harness satin weave is a special case, in which one warp yarn interlaces over seven and under one fill yarn to give an irregular pattern. In fabricating a board, the satin weave gives the best conformity to complex contours, such as around corners, followed in descending order by twill, basket, and plain weaves.

[0070] Texturizing is a process in which the textile yarn is subjected to an air jet that impinges on its surface to make the yarn g`#luffy,'. The air jet causes the surface filaments to break at random, giving the yarn a bulkier appearance.
The extent to which this occurs can be controlled by the velocity of the air jet and the yarn feed rate. An equivalent effect can be produced by electrostatic or mechanical manipulation of the fibers, yarns or roving.

Fabric Design [0071] The fabric pattern, often called the construction, is an x, y coordinate system. The y-axis represents warp yams and is the long axis of the fabric roll (typically 30 to 150 m, or 100 to 500 ft.). The x-axis is the fill direction, that is, the roll width (typically 910 to 3050 mm, or 36 to 120 in.).
Basic fabrics are few in number, but combinations of different types and sizes of yarns witli different warp/fill counts allow for hundreds of variations.

[0072] Basic fabric structures include those made by woven, non-woven and knit processes. In this invention, one preferred design is a knit structure in which bot11 the x axis strands and the y axis strands are held together with a third strand or knitting yam. This type of knitting is weft-inserted-warp knitting.
I_f awn unshifted tricot stitch is used, the s and y axis strands are the least compressed and, therefore, give the best coverage at a given areal weight. This structure's coverage can be further increased, i.e., further reduction in porosity, by using near-zero-twist-yarn or roving which, naturally, spreads more than tightly twisted yam. This design can be further improved by assisting the spreading of filaments by mechanical (needling) means, or by higl7-speed air dispersion of the filaments before or after fabric formation.

[0073] The most common weave construction used for everything from cotton shirts to fiberglass stadium canopies is the plain weave (10), shown in FIG.
1. The essential construction requires only four weaving yarns: two warp and two fill. This basic unit is called the pattern repeat. Plain weave (10), which is the most highly interlaced, is therefore the tightest of the basic fabric designs and most resistant to in-plane shear movement. Basket weave, a variation of plain weave, has warp and fill yams that are paired: two up and two down. The satin weave (15) represent a fainily of constructions with a minimum of interlacing.
In these, the weft yams periodically skip, or float, over several warp yarns, as shown in Fig. 2. The satin weave (15) repeat is x yanls long and the float length is x-1 yarns; that is, there is only one interlacing point per pattern repeat per yam. The floating yams that are not being woven into the fabric create considerable loose-ness or suppleness. The satin weave (15) produces- a construction with low resistance to shear distortion and is thus easily molded (draped) over common compound curves. Satin weaves can be produced as standard four-, five-, or eight-harness forms. As the number of harnesses increases, so do the float lengths and the degree of looseness making the fabric more difficult to control during handling operations. Textile fabrics generally exhibit greater tensile strength in plain weaves, but greater tear strength in satin weaves. The ultimate mechanical properties are obtained from unidirectional-style fabric (14) (Fig.
3), where the carrier properties essentially vanish when attached to a set core (101).
The higher the yam interlacing (for a giveii-size yam), the fewer the number of yams that can be woven per unit length. The necessary separation between yams reduces the number that can be packed together. This is the reason for the higher yam count (yams/in.) that is possible in unidirectional material and its better physical properties.

[0074] A plain weave (16) having glass weft (11) and warp (12) yams or roving, in a weave construction is known as locking leno (Fig. 4), which is used only in special areas of the fabric, such as the selvage (13), and is woven on a shuttleless loom. The gripping action of the intertwining leno yarns anchors or locks the open selvage edges produced on rapier looms. The leno weave helps prevent selvage (13) unraveling during subsequent handling operations.
However, it has found applications where a very open (but stable) weave is desired.

[0075] The design of glass fabrics suitable for this invention begins with only a few fabric parameters: type of fiber, type of yearn, weave style, yam count, and areal weight.

[0076] Fiber finish is also important because it helps lubricate and protect the fiber as it is exposed to the sometimes harsh weaving operation. The quality of the woven fabric is often determined wholly by the type and quality of the fiber finish. The fmish of choice, however, is usually dictated by end-use and resin chemistry, and can consist of resinous materials, such as epoxy.

[0077] The following fabric styles and categories are useful in the practice of this invention:

Fabric Areal wt.
grams/m2 oz/yd2 Light weight 10-35 3-10 Intermediate weight 35-70 10-20 Heavy weight 59-300 15-90 Fabric Thickness m mil Light weight 25-125 1-5 Interinediate weight 125-250 5-10 Heavy weight 250-500 10-20 [0078] It has been determined that fabrics having an areal weight of about 15-300 grains/m2, preferably about 30-150 grams/m2, and thicknesses of about 1-22 mils are most preferred. Such fabric should have an air permeability rating of between 10 and 300 CFIVI/ft2 (FG436-910 test method) and preferably about 10-200 CFWft2, and/or can substantially reduce the penetration of slurries, having viscosities of about 300-10,000 CP at 70 F, preferably less than 5,000 CP, and most preferably about 1,000-4,000 CP. The preferred facing material should also possess an ASTIV! D309 tensile strength of at least about 20 psi in the machine direction and about 5 psi in the cross-machine direction.

[0079] Combining fibers with very different properties can provide a fabric with good longitudinal strength/stiffness values, as well as transverse (fill direction) toughness and impact resistance. The ability to hybridize the fabric allows the board designer the freedom to build cementitious boards with different and perhaps conflicting requirements without major compromises. It is also possible to "teach" the looms new tricks, particularly in three-directional weaving, but interesting modifications are even possible for two-directional fabric.
The loom has the capability of weaving an endless helix using different warp and fiber fill. Alternatively, a glass textile roving warp (17) and olefin weft (18), such as polyethylene or polystyrene fiber, can be used, as shown in FIG. 3.
Alterna.tively, blends such as Twintex glass-polyolefin blends produced by Saint-Gobain S.A., or individual multiple layers of polymers, elastomerics, rayon, polyester and glass filaments can be used as roving or yam for the facing material, or as additional bonded or sewn layers of woven, knitted felt or non-woven layers.

[0080] For example, a light weight thermoplastic, thermoset and/or glass Jiber layer (111), such as a woven fabric, knit fabric, non-woven tissue, paper, needled layer or mat, could be laminated, adhered, needled, sewn knitted, woven, melt bonded, or joined using a combination of these techniques, with a stronger, more porous layer, such as a polymeric or glass scrim (104), or loose knitted or woven substrate, as shown in FIG. 9, to provide both slurry penetration resistance and core reinforcement. (See Altenhofer et al., U.S. Pat. No. 4,504,533, or Knauf et al., U.S. Pat. No. 3,993,822.) The scrim (104) can be a woven open mesh, or non-woven generally transverse and longitudinal fibers joined at cross-over points with or without adhesive binder or sizing, and containing fibers, rovings or yard, for exaxnple. As such, the denser, light weight layer (111) provides oi-dy limited or negligible penetration of gypsum or cement slurry, while the scrim (104) can be embedded in the core (101)to provide good mechanical adherence to the core (101), and greater overall strength to the board (100). Additionally, since the scrim (104) can reinforce the light weight denser layer prior to adherence to the core (101), the light weight, denser layer (111) can be inexpensive and need not possess the tensile strength required to withstand the rigors of a continuous cementitious board manufacturing line by itself. As such, tlie scrim (104) acts to reinforce the light weight, denser layer (111) to resist distortion of said layer and, naturally, the overall facer layer itself, during continuous board manufacturing. Optionally, an additional light weight layer (117) can be applied to the set core facing side of the scrim (104).
Light weight layers (111) and (117) need not be the same density, nor contain the same fibrous material, and each may or may not be impregnated or coated.

[0081] With further reference to a preferred construction employing a light weight layer (117) and woven layer or scrim (104) as the face or faces of a cementitious board (100) of this invention, preferred designs employ a light weight layer (117) employing a random oriented glass mat bound together with a resinous binder, such as glass fibers in sizes: K-fiber (13 microns); H-fiber (10 microns); or M-fiber (16 inicrons), or less. It is known, generally, that random oriented mats manufactured with H-fibers are nearly twice as dense as random oriented mats manufactured with M-fibers at the same areal weight, preferably about 1-3 lbs/per 100 ft 2, more preferable about 1.8 lbs/100 ft2. The scrim (104) can be lighter or heavier in weight than the light weight layer (117), and is preferably joined to the light weight layer (117) by adhesive, such as by the core or a resin binder, or mechanically joined, such as by sewing, needling, etc.

[0082] Random oriented glass mats are generally made by a wet process in which iuidividual or continuous fibers are disposed in a slurry and collected on a screen or porous belt for de-watering. The de-watered fibers are then subjected to a cascade waterfall of binder (also called a "sizing"), which is applied to the fibers and suctioned through it. Alternatively, the glass fibers can be wet processed or fitrther supplemented with tllerrnoplastic fibers which can be melted into the random oriented glass fibers to provide a resin binder.

[0083] A typical binder/glass wool loading is about 3-15 wt%, but this invention anticipates using in excess of 15 wt.% binder, and preferably greater than 20 wt.%, and most preferably about 25-30 wt% binder in the facing layer or layers, such as the above-described random oriented glass mat, for providing desirable properties, such as slurry penetration resistance, adherence to the core (101) or other layers or materials, hydrophobic or hydrophilic properties, or a combination of these properties. Such binders are not a barrier coating and will enable water vapor to pass through the facing during board manufacturing.
These binders also preferably do not completely coat the exterior facing fibers, so as to enable attachment to factory or field applied coatings or adhesives such as Portland cement based mortar, acrylic adhesive, silicon adhesive and glue on the outer surface of the cementitious board. The selected binders should also minimize "blocking" (adhesive bonding between adjacent boards during storage).
Various binders are appropriate for this purpose, such as, for example, phenolic binders, ureaformaldehyde resin, or ureaformaldehyde resin modified with acrylic, styrene acrylic, with or without carboxylated polymers as part of the molecule, or as a separate additive. Additionally, these binders can be provided with additives, such as UV and mold inhibitors, fire retardants, etc. Carboxylated polymer additions to the binder resin can promote greater affinity to set gypsum, o"r to Portland cement-based mortars, for example, but are less subjected to blocking than resins without such additions. One particularly desirable binder resin composition is a 70 wt% ureaformaldellyde resin-30 wt% styrene acrylic latex or an acrylic latex mixture, wit11 a carboxylated polymer addition.

[0084] The preferred composite facing should also include a scrim (104) or a woven or knit structure that is porous to gypsum or cement slurries.
Ideally, the scrim (104) contains a 6x6 ends/inch simple weave or bonded lattice structure, althougll sizes from about 4x4 through about l xl ends/inch will be acceptable.
The preferred fiber size for the scrim (104) is about 68 tex (G75; EC968)which is both economical and broadly available. The scrim (104, or equivalent layer, can also contain a sizing, which is chemically the same or different fiom those described above. It is understood that the sizings applied to light weight layer (117) and scrim (104) could be custom designed for end use applications. For example, the scrim (104) could be treated with a carboxylated styrene acrylic or acrylic blend having greater affinity to a gypsum core, while the binder resin of the light weight layer (117) might be treated with a hydrophobic additive, to resist slurry penetration. Other additives and resin compositions suggested herein as being useful in the cementitious core (101) and coating or saturant (107), could also be employed iii the binder.

[0085] The substrates or layers of this invention useful in construction of the porous facing layers can be further treated or saturated prior to adhering these layers to a core material in order to further reduce porosity, to resist slurry penetration, and to reduce the "fuzziness" of the surface, which can lead to some itching during repeated handling. Resinous coatings and saturants (107) are distinguished from the sizing or binder used to bond the fibers together to form the individual layers, as described above. Coatings and saturants (107) can include those described in U.S. Pat. 4,640,864, and are preferably water-resistant and/or fire-retardant in nature. They can be applied during the manufacture of the porous facing layers of this invention, or by the board manufacturer prior to use in malang boards. This is distinguished from coatings applied to the facings of finished boards following the setting of the gypsum core for imparting water resistance to the finished board.
See U.S. Pat. No. 5,552,187, for example.

[0086] The saturant or coating (107) applied to the porous facing layers, as shown in FIG. 6, of this invention preferably coats a portion of the fibers and reduces the porosity of the facing layer. Alternatively, the saturant or coating (107) can increase or decrease the wetting angle of the gypsum slurry to reduce penetration or increase adhesion. The saturant or coating (107) can further contain a UV stabilizer, mold retardant, water repellant, a flame retardant and/or other optional ingredients, such as dispersants, catalysts, fillers and the like.
Preferably, the saturant or coating (107) is in liquid form and the facing material is led through the liquid, or the liquid is sprayed (with or without a water spray precursor) on one or both sides of the facing material. For example, a resin which is adherent to gypsum can be applied to only the core facing side of light weight layer (117) and entirely around the scrim (104) to promote adhesion to the core (101). Thereafter, the facing material inay be squeezed and dried.

[0087] Various methods of applying the liquid may be used, including dip-coaters, doctor blade devices, roll coaters and the like. One preferred method of treating the facing material with the resinous coatings or saturants (107) of this invention is to have a lower portion of one roll partially submerged in a trough of the liquid resinous composition and the facer material pressed against the upper portion of the same roller so that an amount of the resinous composition is transferred to the facer material. The second roller above the first roller controls the movement of the facer material and the uniformity of the amount of resinous coating or saturant (107) disposed thereon. Thereafter, the coated facer material is led in a preferred method to steam cans to expedite drying. It is preferred to pass the coated facer material over steam cans at about 250-450 F (100-200 C) which drives_the water off, if a latex is used, and additionally may cause some flow of the liquid resinous material to further fill intersticies and reduce porosity in the facer material, as well as coat further and more uniformly fibers within the facer material. The coating preferably covers about 50-80% of the surface area targeted, more preferably about 80-95% of said area; 100% coverage is less desirable due to blow offs and blistering due to steam generated during the setting of gypsum products. Desirably, the saturated facing can be somewhat impermeable to liquid water, but is porous to water vapor, whether wet or dry, and is not considered a water vapor retarder or barrier.

[0088] The preferred saturant or coatings (107) of this invention can contain a resinous mixture containing one or more resins. The resin can contain solid particles or fibers which coalesce or melt to form a continuous or semi-continuous coating which substantially prevents the penetration of liquid moisture, but permits water vapor to pass through the cross section of the facing layer.
The coating can be applied in various thicknesses, such as for example, to sufficiently cover the fibrous constituents of the facing layer so that no fibers protrude from the coating or saturant, or to such a degree that the fibers protrude fiom the coating or saturant so that they can be used to join to additional layers in a EIF
system or to tile, for example. The resinous coating or saturant forms a liquid water barrier which protects the rolls and other equipment during the manufacture of a cementitious board, and which can later, optionally, protect the underlying set gypsum from moisture during storage or use.

[0089] The resinous coating or saturant (107) can comprise a thermoplastic or a thermoset resin. Numerous commercially available resins which are effective in forming water- or weather-resistant coatings are available.
The preferred coating or saturant (107) of this invention is optionally capable of forming a coating having a surface water absorption value of no greater than about 0.05 grams, as measured by a "Modified Cobb Test", in which a 5 inch 2 coated sample is contacted with a 4.5 inch diameter x 1 inch high Cobb ring filled with water for 2 hours. In this embodiment, boards should also absorb less than 10 wt.%, preferably less than 5 wt.%water when tested in accordance with the iminersion test of ASTM method C-473, when a water resistant core formulation is used.

[0090] The coating or saturant (107) of this invention can be formed substantially by the water-resistant resin, but good results can also be achieved by forming the coating or saturant from a inixture of resin and fillers, such as silicates, silica, gypsum, titanium dioxide and calcium carbonate. The saturant or coating (107) can be applied in latex or curable thermosetting form.
Acceptable resins include styrene-acrylic copolymer, acrylics, flame retardant acrylics or brominated monomer additions to acrylic, such as Pyropoly AC2001, poly(vinyl acetates), poly(vinyl alcohols), vinylidene chloride, siloxane, and polyvinylchloride such as Vycar 578. In addition, fire retardants, such as bromated phosphorous complex, halogenated paraffin, colloidal antimony pentoxide, borax, unexpanded vermiculite, clay, colloidal silica and colloidal aluminum can be added to the resinous coating or saturant. Furthermore, water resistant additives can be added, such as paraffin, and combinations of paraffin and ammonium salt, fluorochemicals designed to impart alcohol and water repellency, such as FC-824 from 3M Co., organohydrogenpolysiloxanes, silicone oil, wax-asphalt emulsions and poly(vinyl alcohol) with or without a minor amount a minor amount of poly(vinyl acetate). Finally, the saturant and coatings can include pigment, such as kaolin clay, or lamp black thickeners such as modified bentonite clay, defoamers, such as fatty acid/polyglycol mixtures , UV
resistance additives, setting accelerators, such as clay compounds, polyacrylamide, potassium salts, or combinations thereof, and dispersants such as sodium polyacrylate. Known preservatives and, of course, water can be added in latex compositions, and solvents in thermosetting compositions. (See, for example, U.S. 4,640,864, which includes insulation boards including polyvinylchloride based coatings including fire- and water-repellants.) Other additives, suggested herein as being useful in the binder or cementitious core 101, could also be employed in the coating or saturant (107).

[0091] In this context, some preferred laminate constructions, such as those disclosed earlier in connection with the discussion of FIG. 9, can include coatings or saturants which assist in either joining the laminate to the set core (101), or assist it to reduce porosity to resist slurry penetration, and/or helping it to reduce irritation to workers. One laminate that evidences promise includes a laminate made from a polyvinyl alcohol coated fiberglass scrim (104), which is laminated using a polyvinyl alcohol binder to a fiberglass mat or tissue (111). The mat or tissue layer may or may not be saturated with the polyvinyl alcohol resin.
In a second practical example of this invention, a laminate is fabricated from a polyvinyl alcohol coated fiberglass scrim (104), which is laminated using a fire resistant and ultraviolet resistant acrylic binder to a fiberglass mat or tissue. The mat or tissue may or may not be saturated with an acrylic binder.

Board Manufacturing [0092] With reference to FIG. 5, a preferred method of continuously manufacturing cementitious boards (100) is described.

[0093] While it is preferred that slightly-modified, conventional wallboard manufacturing equipment be employed for producing the cementitious boards (100) of this invention, cementitious boards (100) can be manufactured in any number of ways, including molding, extrusion, and semi-continuous processes employing rollers and seginents of the glass fabrics of this invention.

[0094] With reference to FIG. 6, which is a blown up segment of the coated board shown in FIG. 5, the detail of a preferred a cementitious board (100) is provided. The cementitious board (100) includes a set core (101), made of set gypsum or Portland cement, for example. The set core (101) can also optimally contain fillers, reinforcing fiber (102) and performance additives (103).
Reinforcing fibers (102) desirably include chopped fibers of no greater than about two inches in length used to reinforce the set core (101). Such fibers (102) can include, for example, Kevlar , glass, polyolefin, and cellulosic fibers, such as straw or paper fiber. Performance additives (103) can include water resistant additives such as silicone, and fire resistant additives such as borax, as well as the other water-and fire-resistant additives discussed above in connection with the resinous saturant or coating of the facing layer. The composition from which the set core (101) is made can further include optional constituents, including, for example, those included in gypsuin and cement exterior sheathing. Examples of such constituents include set accelerators, foaming agents, and dispersing agents.

[0095] Examples of materials which have been reported as being effective for improving the water-resistant properties of cementitious products either as a coating (107) or performance additive (103) are the following: poly(vinyl alcohol), with or without a minor amount of poly(vinyl acetate); metallic resinates; wax or asphalt or mixtures thereof; a mixture of wax and/or asphalt and also corn-flower and potassium permanganate; water insoluble thermoplastic organic materials such as petroleum and natural asphalt, coal tar, and thermoplastic synthetic resins such as poly(vinyl acetate), polyvinylchloride and a copolymer of vinyl acetate and vinyl chloride and acrylic resins; a mixture of metal rosin soap, a water soluble alkaline earth metal salt, and residual fuel oil; a mixture of petroleum wax in the form of an emulsion and either residual fuel oil, pine tar or coal tar; a mixture comprising residual fuel oil and rosin, aromatic isocyanates and disocyanates; organohydrogenpolysiloxanes and other silicones, acrylics, and a wax-asphalt emulsion with or without such materials as potassium sulfate, alkali and alkaline earth eliminates. Performance additives (103) can be introduced directly into the cementitious slurry (28). The moisture retarding coatings (107) can be applied to the facing material before or after joining to the set core (101).

[0096] If gypsum is employed, the core (101) may be formed by mixing water with powdered anhydrous calcium sulfate or calcium sulfate hemidrate (Ca-SO412H20), also known as calcined gypsum, and thereafter allowing the mixture to hydrate or set into calcium sulfate dihydrate (CaS04 2H20), a relatively hard material. The set core (101) of the support member will in general coinprise at least about 85 wt. % set gypsum or cement.

[0097] The surface of the set core (101) is faced with one or more layers of the facing material. The facing material should be sufficiently porous to permit water in the aqueous slurry from which the core (101) is made to evaporate therethrough. As described in the detail below, the cementitious board (100) in the present invention can be made efficiently by forming an aqueous slurry which contains excess water and placing thereon the facing material. Aided by heating, excess water evaporates through the preferred upper and lower glass fabric facings (105) and (106) as the cementitious slurry (28) sets.

C ntinu tao Manufaeturarag IyII etla d [0098] An attractive feature of the present invention is that the cementitious board (100) can be made utilizing existing wallboard manufacturing lines, for example, as shown somewhat diagrammatically in FIG. 5. In conventional fashion, dry ingredients (not shown) from which the set core (101) is fonned are pre-mixed and then fed to a mixer of the type commonly referred to as a pin mixer (30). Water and other liquid constituents (not shown) used in making the core (101) are metered into the pin mixer (30) where they are combined with the dry ingredients to form an aqueous cementitious slurry (28). Foam is generally added to the slurry in the pin mixer (30) to control the density of the resulting set core (101).

[0099] In general, the facing material of this invention permits the use of lower viscosity slurries to be employed than would be expected when making gypsum or cement products with glass mats. Typically, as stated in U.S. Pat.
No.
5,319,900 at col. 12, line 45 - col. 13, line 2, viscosity control agents, such as cellulosic thickeners, bentonite clays, starches and gypsum whisker fibers, are employed to provide a gypsum slurry of about 5,000 - 7,000 (Brookfield test at 70 F at 10 rpm using a No. 3 paddle). The present invention, due to the slurry penetration resistance of the preferred facing material, can employ slurry viscosities of substantially less than 5000 cp, and preferably about 1,000-4,000 at 70 F, depending upon the product selected and whether the top or the bottom or both facing material is selected to be gypsum or cement free, and/or resistant to slurry and liquid water penetration. The cementitious slurry (28) thus formed, is dispersed through one or more outlets at the bottom of the pin mixer (30) onto a moving bottom glass fabric (22) which optionally may contain one or more layers of the facing material of this invention.
The bottom glass fabric (22), which may also contain, and preferably contains, one or more layers of the inventive facing material, is indefinite in length and is fed from the bottom glass fabric roll (20).

[00100] As is common practice in the manufacture of conventional paper-faced gypsum board, the two opposite edge portions of the bottom glass fabric (22) are progressively flexed upwardly from the mean plane of the fabric (22) and then turned inwardly at the margins so as to provide coverings for the edges of the resulting board (100).

[00101] A sheet of top glass fabric (32) is fed from the top glass fabric roll (29) onto the top of the cementitious slurry (28), thereby sandwiching the slurry between the two moving fibrous mats which form the facings of the set core (101) which is formed from the cementitious slurry (28). The bottom and top glass fabrics (22) and (32), with the cementitious slurry (28) sandwiched therebetween enter the nip between the upper and lower forming or shaping rolls (34) and (36) and are thereafter received on a conveyer belt (38). Conventional wallboard edge guiding devices (40) shape and maintain the edges of the composite until the slurry has set sufficiently to retain its shape. Water of convenience, or excess water, can be drained witll the assistance of vacuum boxes (42) disposed below the conveyor belt (38). In due course, sequential lengths of the board are cut by a water knife (44). The cementitious board (100) is next moved along feeder rolls (46) to peimit it to set. It is further processed by exposure to heat in a drying oven (48) which accelerates the drying of the board by increasing the rate of evaporation of excess water. An additional sprayer (49) cah be provided to add further treatments, such as silicone oil or fire retardants, to the board's exterior.
[0100] The facing materials and cementitious boards (100) of this invention are useful in all sorts of building construction applications. They are strong, having a screw strength of at least about 20 lbs., for gypsum cores of conventional densities and compositions. Some examples include shaft wall assemblies for elevators and stairways, fire doors and fire walls, roofing and siding substrates, with or without insulation, and tile backer boards. One of the most desirable and useful applications for this invention are in EIF systems (also called EIF systems for Exterior Insulation Finishing Systems).

[0101] The essential components of an EIF system include some form of insulating material which is sandwiched between an underlying support surface and an exterior finishing material which can be an integral part of the insulating material, but is usually applied to the insulating material at the site of installation.
Cementitious boards including the facing material of this invention are particularly useful for the support surface. From one EIF system to the next, there exists various structural details and components. For example, although the exterior finishing material may be affixed directly to the insulating material, various systems include a reinforcing component sandwiched between the exterior finishing material and the insulating material. The reinforcing component comprises generally one or more plies of fiberglass reinforcing fabric or mesh which is adhered by suitable mastic to the surface of the insulating material.
In some systems, the support surface is affixed to a wooden frame attached to the exterior surface of the outside wall of a building, whereas in other systems a metal frame is used. In certain applications, the support surface may be affixed directly to the exterior surface of an outside wall, for example, one comprising cinder blocks or concrete blocks. In new construction, the support surface is typically affixed directly to the fraine of the building. The adhesive or mastic for adhering together components of the system tends to vary from one system to the next, and typically comprises specially formulated proprietary compositions.

[0102] Presently, the most popularly used insulating material in EIF
systems is expanded or foamed polystyrene, a material which has good moisture resistant properties. Although is has desirably low water vapor transmission, it is not a vapor barrier, but instead is capable of breathing. Rigid panels of expanded polystyrene are used most widely in EIF systems. Such panels have satisfactory compressive strength and resilience and are presently available in thicknesses ranging from %2 to 6 inches, widths from 6 to 48 inches and lengths ranging from 4 feet to 16 feet. One commercially available system utilizes rigid, expanded polystyrene pa.nels which are 2' x 4' x 1"

[0103] Other thermal insulating materials can be used in EIF systerns also.
Examples of such materials include extruded polystyrene, polyurethane, isocyanurate, cement-based insulating plasters, and phenolic foam. Insulating materials generally have low thermal conducting and low density.

[0104] As mentioned above, various EIF systems include a reinforcing component, for example, in cloth form, sandwiched between the insulating material and the exterior finishing material. Glass cloth is most widely used at the present time to reinforce the system, that is, to improve the impact strength of the system. The particular type or types of glass cloth used and the number of plies thereof which are used depend on the impact resistance which is desired.
Exainples of reinforcing cloth or fabric which can be used in the system are woven glass, glass fiber scrim and glass fiber mesh. Installation of the reinforcing fabric generally involves applying a suitable adhesive to the surface of the insulating material a.nd then applying the fabric thereto. Additional plies of fabric can be applied if desirable. A cement/acrylic resin is an example of an adhesive that can be used.

[0105] The exterior finishing material can be affixed directly to the insulating material or to an intermediate surface such as, for example, the surface of a reinforcing member as described above. The exterior finishing material should have weathering characteristics and is.preferably appealing in appearance.
Presently, the most widely used exterior finish is an acrylic resin-based composition which is available in a paste-type form which is spread or troweled on the underlying substrate. One type of such composition can be described as a ready-mixed synthetic resin plaster. After application, the resin sets to form a tough, weather-resistant solid material which adheres tightly to the underlying substrate. Such resin compositions are available commercially in a variety of colors. They include optional aggregate which can vary in size. This allows the applicator to choose a particular composition which permits him to apply a finish that can vary in texture from fine to coarse. Finishes which have a stucco-like appearance are popular. Small stones of various colors can be embedded in the composition for decorative purposes. Exarnples of other materials that can be used as an exterior finish are Portland cement stucco including, for example, sand and larger aggregate. The exterior finish can vary in thickness over a wide range, with a tliickness of about 1/16" to about 1/4" being exemplary.

[0106] From the foregoing, it can be realized that this invention provides facing materials for cementitious boards which are lightweight, exhibit high strength in combination with set cementitious core materials, and which remain porous to water vapor. The preferred glass fabric facings of this invention bond to set gypsum and Portland cement to form a strong integral structure, yet can present a textured surface for joining to other layers of EIF systems, such as, for example, adhesive bonding to polystyrene insulation. The woven, knitted or needled exterior surface of the preferred textile fiber fabrics is also easier to handle by construction workers, and will not lead to as much injury or in-itation as chopped fiber glass mats having exposed sharp individual fibers. The choice of needling, weaving and knitting operations of this invention lend themselves to numerous engineering and design choices which can combine wefts and warps of different filament orientation and filament composition, for creating unique facing properties. One of the desirable properties of the current invention is its ability to resist the penetration of cementitious slurries, thus avoiding roll contamination in continuous wall board making macllinery. Although various embodiments have been illustrated, this is for the purpose of describing, but not limiting, the invention. Various modifications, which will become apparent to one skilled in the art, are within the scope of this invention described in the attached claims.

Claims

1. A facing material for use with an aqueous slurry of cementitious material, comprising: a porous facing layer at an exterior side of the facing material; the porous facing layer having pores impermeable to liquid water and permeable to water vapor evaporated from said slurry; the porous facing layer having a first coating or saturant, which reduces porosity of an exterior side of the porous facing layer to resist slurry penetration; a slurry facing side of the porous facing layer having a second coating or saturant comprising a slurry wetting agent; a water repellant material on at least an exterior side of the porous facing layer providing the exterior side of the facing material with water repellency to repel rain and water from the facing material, said water repellant material repelling said slurry from penetration through the exterior side of the facing material to prevent slurry contamination on the exterior side of the facing material; and an inner layer having reinforcing fibers at an interior side of the facing material, the inner layer being substantially porous to said slurry for penetration of said slurry through the inner layer.

2. A facing material for use with an aqueous slurry of cementitious material, comprising: a porous facing layer at an exterior side of the facing material; the porous facing layer having pores impermeable to liquid water and permeable to water vapor evaporated from said slurry; a slurry wetting agent on a slurry facing side of the porous facing layer; and a hydrophobic agent on the exterior side of the porous facing layer; said hydrophobic agent comprising, a water repellant material on at least an exterior side of the porous facing layer providing the exterior side of the facing material with water repellency to repel rain and water from the facing material, said water repellant material repelling said slurry from penetration through the exterior side of the facing material to prevent slurry contamination on the exterior side of the facing material; and an inner layer having reinforcing fibers at an interior side of the facing material, the inner layer being substantially porous to said slurry for penetration of said slurry through the inner layer.

3. The facing material of claim 2, wherein the porous facing layer comprises a mat having fibers, strands, rovings or filaments, or a combination thereof, which are woven, knit, needled, felted or stitched together to decrease porosity of the mat.

4. The facing material of claim 2, further comprising: the first coating or saturant containing said water repellant material, and further containing, a UV stabilizer, a mold retardant, or a flame retardant, or a combination thereof.

5. The facing material of claim 2, further comprising: the porous facing layer comprising, fibers bonded by a resinous binder.

6. The facing material of claim 5, wherein the binder further comprises, a UV
stabilizer, a mold inhibitor, or a fire retardant, or a combination thereof.

7. The facing material of claim 5, wherein the binder further comprises, a hydrophobic additive to resist slurry penetration.

8. The facing material of claim 2, further comprising: the inner layer having a material with an affinity for forming an adhesive bond with said slurry.

9. The facing material of claim 2, further comprising: the porous facing layer comprising, fibers bonded by a resinous binder, wherein the resinous binder further comprises, a carboxylated polymer.

10. The facing material of claim 2, further comprising: a resin on the inner layer and on a slurry facing side of the porous facing layer, wherein the resin further comprises, a carboxylated polymer.

11. A cementitious board for building construction, comprising: a cementitious material layer between two facing layers; the cementitious material layer being formed by solidification of a slurry comprising, cementitious material and water; at least one of the two facing layers comprising, an inner layer having reinforcing fibers, and a porous facing layer having a slurry facing side and an exterior side; a water repellant material on at least the exterior side of the porous facing layer providing the exterior side with water repellency to repel rain and water from the cementitious board, said water repellant material repelling said slurry from penetration through the exterior side of the facing material to prevent slurry contamination on the exterior side of the facing material; the cementitious material layer penetrating the inner layer and the reinforcing fibers; the cementitious material layer being in contact with the slurry facing side of the porous facing layer; a slurry wetting agent on the slurry facing side of the porous facing layer for wetting by the slurry; and pores of the porous facing layer being permeable to evaporated water from the slurry.

12. The cementitious board as in claim 11, further comprising: a porosity reducing coating or saturant on the exterior side of the porous facing layer, which reduces porosity of the exterior side to resist slurry penetration, while the pores of the porous facing layer are permeable to the evaporated water from the slurry.

13. The cementitious board as in claims 11 and 12, further comprising: said water repellant material comprising hydrophobic material over at least the exterior side of the porous facing layer.

14. The cementitious board as in claim 13, further comprising: a porosity reducing coating or saturant on the exterior side of the porous facing layer, which reduces porosity of the exterior side to resist slurry penetration while the pores of the porous facing layer are permeable to the evaporated water from the slurry.

15. The cementitious board of any one of claims 11 to 14, wherein said one of the two facing layers comprises a scrim, knit, needled or woven fabric or cloth, a random oriented, non-woven mat, or combination thereof.

16. The cementitious board of any one of claims 11 to 15 wherein said slurry wetting agent comprises a resinous saturant or coating for wetting by the slurry to fill voids in the porous facing layer, to increase adherence to the cementitious material, alters to alter the wetting angle of the slurry, or a combination thereof.

17. The cementitious board of any one of claims 11 to 16, wherein said one of the two facing layers comprises, a dense, light weight non-woven or needled layer having glass fibers, the glass fibers having an average diameter of less than 16 microns, bonded to a glass scrim.

18. The cementitious board of any one of claims 11 to 17, wherein said one of the two facing layers comprises, glass fibers bonded together with a resinous binder composition having a hydrophilic affinity or adhesive affinity for said cementitious material when wetted by said slurry.

19. The cementitious board of any one of claims 11 to 18, wherein said one of the two facing layers comprises, a permeability having an air permeability rating of no greater than about 300 CFM/ft², substantially preventing penetration of said slurry having a viscosity of less than 5,000 cp at 70° F., and permitting passage therethrough of water vapor emitted from said slurry.

20. The cementitious board of any one of claims 11 to 19, wherein the porous facing layer further comprises; glass fibers having an average diameter of less than about 16 microns, and having an air permeability rating of less than about 300 CFM/ft2 (FG436-910 test method) to substantially prevent penetration of said slurry, and permit passage therethrough of water vapor emitted from said slurry.

21. The cementitious board of any one of claims 11 to 20, wherein the porous facing layer further comprises; a random oriented glass fiber-containing mat having an areal weight of about 30-150 grams/m2.

22. The cementitious board of any one of claims 11 to 21, wherein the porous facing layer resists penetration of said slurry without a substantial viscosity control additive in said slurry.

23. The cementitious board of any one of claims 11 to 22, wherein the porous facing layer further comprises; a scrim and a non-woven mat.

24. The cementitious board of claim 23, wherein said scrim and said non-woven mat are hydrophilic, and are bound by a non-hydrophobic resinous binder.

25. The cementitious board of claim 23, wherein, either said non-woven mat, or said scrim, or both, further comprise; a fire retardant, a water repellant, or both, in the form of a resinous saturant or coating.

26. The cementitious board of any one of claims 11 to 25, wherein said non-woven mat further comprises; a fire retardant, a water repellent, or both, in the form of a resinous saturant or coating.

27. The cementitious board of any one of claims 11 to 26, wherein the porous facing layer comprises, filaments located in both a machine and cross-machine direction.

28. The cementitious board of any one of claims 11 to 27, wherein said cementitious material comprises gypsum for a gypsum wall board.

29. A method of making a cementitious board useful in building construction, comprising: (a) layering an aqueous slurry between two layers of facing material, the slurry comprising, cementitious material and water, the facing material of at least one of the two layers comprising, an inner layer reinforced by reinforcing fibers, and a porous facing layer having a slurry facing side and an exterior side; (b) penetrating the slurry through both the inner layer and the reinforcing fibers, and contacting the slurry facing side of the porous facing layer with the slurry; (c) repelling said slurry by a hydrophobic material over at least the exterior side of the porous facing layer to resist slurry contamination of the exterior side, and to repel rain or water;
(d) evaporating water from the slurry through pores of the porous facing layer, the pores being permeable to water vapor;
and (e) solidifying the slurry to form a solidified cementitious material layer between the two layers of facing material.

30. The method of claim 29, further comprising: providing the slurry facing side of the porous layer with a slurry wetting agent comprising, a coating or a saturant for wetting the slurry facing side by said slurry when said slurry is between the two layers of facing material; and wetting the slurry facing side by said slurry.

31. The method of claims 29 or 30, further comprising: resisting slurry penetration through the exterior side of the porous facing layer by a porosity reducing coating or saturant on the exterior side, which reduces porosity of the exterior side to resist said slurry penetration.

32. The method of claims 29, 30 or 31, wherein the porous facing layer further comprises;
glass fibers having an average diameter of less than about 16 microns, and having an air permeability rating of less than about 300 CFM/ft2 (FG436-910 test method) to substantially prevent penetration of said slurry, and permit passage therethrough of water vapor emitted from said slurry.

33. The method of any one of claims 29 to 32 wherein the porous facing layer further comprises; a random oriented glass fiber-containing mat having an areal weight of about 30-150 grams/m2.

34. The method of any one of claims 29 to 33, further comprising: applying to the porous facing layer, a binder, a resinous saturant or a coating, which assists in, filling voids, increasing adherence to the cementitious material, increasing or decreasing the wetting angle of said slurry, or a combination thereof.

35. The method of any one of claims 29 to 34, wherein the porous facing layer further comprises; open voids which are small enough to resist penetration of said slurry, when said slurry does not contain a significant amount of a viscosity control additive.

36. The method of any one of claims 29 to 35, wherein the porous facing layer further comprises; pores of respective sizes resisting penetration of said slurry when said slurry has a viscosity of about 1,000-4,000 cp at 70° F.

37. The method of any one of claims 29 to 36, wherein the porous facing layer further comprises; a scrim and a non-woven mat.

38. The method of claim 37, wherein said scrim and said non-woven mat are hydrophilic, and are bound by a non-hydrophobic resinous binder.

39. The method of claim 37, further comprising: a fire retardant, a water repellant, or both, in the form of a resinous saturant or coating on, either said non-woven mat, or said scrim, or both.

40. The method of claim 37, further comprising: a fire retardant, a water repellant, or both, in the form of a resinous saturant or coating on said non-woven mat.

41. The method of any one of claims 29 to 40, wherein the porous facing layer comprises, filaments located in both a machine and cross-machine direction.

42. The method of any one of claims 29 to 41, wherein said slurry comprises gypsum cementitious material for a gypsum wall board.

43. A method of making a cementitious board useful in building construction, comprising: (a) layering an aqueous slurry between two layers of facing material, the slurry comprising, cementitious material and water, the facing material of at least one of the two layers comprising, an inner layer having reinforcing fibers, and a porous facing layer having a slurry facing side and an exterior side; (b) providing the slurry facing side of the porous layer with a slurry wetting agent comprising, a coating or a saturant for wetting the slurry facing side by said slurry, when said slurry is between the two layers of facing material; (c) penetrating the slurry through both the inner layer and the reinforcing fibers, and wetting the slurry facing side of the porous layer with the slurry; (d) evaporating water from the slurry through pores of the porous facing layer, the pores being permeable to water vapor; and (e) solidifying the slurry to form a solidified cementitious material layer between the two layers of facing material.

44. The method of claim 29, further comprising: resisting slurry penetration through the exterior side by a porosity reducing coating or saturant on the exterior side, which reduces porosity of the exterior side to resist said slurry penetration.

45. The method of claim 29, further comprising: repelling said slurry by a hydrophobic material on at least the exterior side of the porous facing layer to resist slurry contamination of the exterior side, and to repel rain or water.

46. The method of claim 35, further comprising: resisting slurry penetration through the exterior side by a porosity reducing coating or saturant on the exterior side, which reduces porosity of the exterior side to resist said slurry penetration.