CA2497760A1 - A machinable austempered cast iron article having improved machinability, fatigue performance, and resistance to environmental cracking and a method of making the same - Google Patents

A machinable austempered cast iron article having improved machinability, fatigue performance, and resistance to environmental cracking and a method of making the same Download PDF

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Publication number
CA2497760A1
CA2497760A1 CA002497760A CA2497760A CA2497760A1 CA 2497760 A1 CA2497760 A1 CA 2497760A1 CA 002497760 A CA002497760 A CA 002497760A CA 2497760 A CA2497760 A CA 2497760A CA 2497760 A1 CA2497760 A1 CA 2497760A1
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Canada
Prior art keywords
microstructure
austempering
cast iron
plus austenitic
ferritic plus
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002497760A
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French (fr)
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CA2497760C (en
Inventor
Alan Peter Druschitz
David Carroll Fitzgerald
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Intermet Corp
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Individual
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Publication of CA2497760A1 publication Critical patent/CA2497760A1/en
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Publication of CA2497760C publication Critical patent/CA2497760C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/08Making cast-iron alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D5/00Heat treatments of cast-iron
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/10Cast-iron alloys containing aluminium or silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • C21D1/185Hardening; Quenching with or without subsequent tempering from an intercritical temperature
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • C21D1/19Hardening; Quenching with or without subsequent tempering by interrupted quenching
    • C21D1/20Isothermal quenching, e.g. bainitic hardening
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/56General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
    • C21D1/607Molten salts
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/30Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for crankshafts; for camshafts

Abstract

A machinable austempered cast iron article has improved strength, machinability, fatigue performance, and resistance to environmental cracking . A method of making the machinable austempered cast iron article includes austenitizing an iron composition having a substantially pearlitic microstructure in an intercritical temperature range of between 1380~F and 1500 ~F. This produces a ferritic plus austenitic microstructure. The ferrit ic plus austenitic microstructure is quenched into an austempering temperature range of between 575 ~F and 750 ~F within 3 minutes to prevent formation of pearlite. The ferritic plus austenitic microstructure is then austempered in the austempering temperature range of between 575 ~F and 750 ~F to produce a microstructure of a continuous matrix of equiaxed ferrite with islands of austenite. Finally, the microstructure of the continuous matrix of equiaxed ferrite with islands of austenite is cooled to ambient temperature to produc e the machinable austempered cast iron article.

Claims (36)

1. A method of making a machinable austempered cast iron article from an iron composition having a substantially pearlitic microstructure that includes carbon, silicon, nickel, copper, and molybdenum, said method comprising the steps of:
austenitizing the substantially pearlitic microstructure in an intercritical temperature range of from 1380°F to 1500°F for a period of at least 10 minutes to produce a ferritic plus austenitic microstructure;
quenching the ferritic plus austenitic microstructure at a rate sufficient to prevent formation of pearlite;
austempering the ferritic plus austenitic microstructure in an austempering temperature range of from 575°F to 750°F for a period of at least 8 minutes to produce a microstructure of a continuous matrix of equiaxed ferrite with islands of austenite; and cooling the microstructure of the continuous matrix of equiaxed ferrite with islands of austenite to ambient temperature to produce the machinable austempered cast iron article having improved strength, ductility, machinability, fatigue performance, and resistance to environmental cracking.
2. A method according to claim 1 further comprising the step of casting the iron composition to produce the substantially pearlitic microstructure having at least 80% pearlite prior to austenitizing.
3. A method according to claim 1 wherein the step of austenitizing the substantially pearlitic microstructure is further defined as austenitizing the substantially pearlitic microstructure in an intercritical temperature range of from 1380°F to 1472°F.
4. A method according to claim 1 wherein the step of austenitizing the substantially pearlitic microstructure is further defined as austenitizing the substantially pearlitic microstructure in an intercritical temperature range of from 1380°F to 1449°F.
5. A method according to claim 1 wherein the step of austenitizing the substantially pearlitic microstructure is further defined as austenitizing the substantially pearlitic microstructure for a period of from 10 to 360 minutes.
6. A method according to claim 1 wherein the step of austempering the ferritic plus austenitic microstructure is further defined as austempering the ferritic plus austenitic microstructure for a period of from 8 to 1440 minutes.
7. A method according to claim 6 wherein the step of austempering the ferritic plus austenitic microstructure is further defined as austempering the ferritic plus austenitic microstructure for a period of from 60 minutes to 180 minutes.
8. A method according to claim 1 wherein the step of quenching the ferritic plus austenitic microstructure is further defined as quenching the ferritic plus austenitic microstructure into the austempering temperature range of from 575°F to 750°F within a period of from 5 to 180 seconds to prevent the formation of pearlite.
9. A method according to claim 1 wherein the step of quenching the ferritic plus austenitic microstructure is further defined as quenching the ferritic plus austenitic microstructure into the austempering temperature range in a salt bath.
10. A method according to claim 9 wherein the salt bath comprises at least one of nitrate salts, nitrite salts, and combinations thereof.
11. A method according to claim 1 wherein the step of quenching the ferritic plus austenitic microstructure is further defined as quenching the ferritic plus austenitic microstructure into the austempering temperature range in a fluidized bed.
12. A method according to claim 1 wherein the step of cooling the microstructure of the continuous matrix of equiaxed ferrite with islands of austenite to ambient temperature is further defined as cooling the microstructure of the continuous matrix of equiaxed ferrite with islands of austenite to ambient temperature in at least one of air, oil, and water.
13. A method according to claim 1 wherein the machinable austempered cast iron article is a crankshaft component.
14. A method according to claim 1 wherein the machinable austempered cast iron article is a chassis component.
15. A method of making a machinable austempered cast iron article from an iron composition that includes carbon, silicon, nickel, copper, and molybdenum, said method comprising the steps of:
casting the iron composition at a temperature of greater than 2200°F;
cooling the iron composition to a temperature of from 1000°F to 1340°F;
holding the iron composition at the temperature of from 1000°F to 1340°F for at least 8 seconds to produce a substantially pearlitic microstructure;
cooling the iron composition to an ambient temperature;
austenitizing the substantially pearlitic microstructure in an intercritical temperature range of from 1380°F to 1500°F for a period of at least 10 minutes to produce a ferritic plus austenitic microstructure;
quenching the ferritic plus austenitic microstructure at a rate sufficient to prevent formation of pearlite;
austempering the ferritic plus austenitic microstructure in an austempering temperature range of from 575°F to 750°F for a period of at least 8 minutes to produce a microstructure of a continuous matrix of equiaxed ferrite with islands of austenite; and cooling the microstructure of the continuous matrix of equiaxed ferrite with islands of austenite to ambient temperature to produce the machinable austempered cast iron article having improved strength, machinability, fatigue performance, and resistance to environmental cracking.
16. A method according to claim 15 wherein the step of austenitizing the substantially pearlitic microstructure is further defined as austenitizing the substantially pearlitic microstructure having at least 80% pearlite in an intercritical temperature range of from 1380°F
to 1472°F.
17. A method according to claim 15 wherein the step of austenitizing the substantially pearlitic microstructure is further defined as austenitizing the substantially pearlitic microstructure having at least 80% pearlite in an intercritical temperature range of from 1380°F
to 1449°F.
18. A method according to claim 15 wherein the step of austenitizing the substantially pearlitic microstructure is further defined as austenitizing the substantially pearlitic microstructure for a period of from 10 to 360 minutes.
19. A method according to claim 15 wherein the step of austempering the ferritic plus austenitic microstructure is further defined as austempering the ferritic plus austenitic microstructure for a period of from 8 to 1440 minutes.
20. A method according to claim 19 wherein the step of austempering the ferritic plus austenitic microstructure is further defined as austempering the ferritic plus austenitic microstructure for a period of from 60 minutes to 180 minutes.
21. A method according to claim 15 wherein the step of quenching the ferritic plus austenitic microstructure is further defined as quenching the ferritic plus austenitic microstructure into the austempering temperature range of from 575°F to 750°F within a period of from 5 to 180 seconds to prevent the formation of pearlite.
22. A method according to claim 15 wherein the step of quenching the ferritic plus austenitic microstructure is further defined as quenching the ferritic plus austenitic microstructure into the austempering temperature range in a salt bath.
23. A method according to claim 22 wherein the salt bath comprises at least one of nitrate salts, nitrite salts, and combinations thereof.
24. A method according to claim 15 wherein the step of quenching the ferritic plus austenitic microstructure is further defined as quenching the ferritic plus austenitic microstructure into the austempering temperature range in a fluidized bed.
25. A method according to claim 15 wherein the step of cooling the microstructure of the continuous matrix of equiaxed ferrite with islands of austenite to ambient temperature is further defined as cooling the microstructure of the continuous matrix of equiaxed ferrite with islands of austenite to ambient temperature in at least one of air, oil, and water.
26. A method according to claim 15 wherein the machinable austempered cast iron article is a crankshaft component.
27. A method according to claim 15 wherein the machinable austempered cast iron article is a chassis component.
28. A machinable austempered cast iron article, said article made by the steps of:
austenitizing an iron composition having a substantially pearlitic microstructure in an intercritical temperature range of from 1380°F to 1500°F for a period of at least 10 minutes to produce a ferritic plus austenitic microstructure;
quenching the ferritic plus austenitic microstructure at a rate sufficient to prevent the formation of pearlite;
austempering said ferritic plus austenitic microstructure in an austempering temperature range of from 575°F to 750°F for a period of at least 8 minutes to produce a microstructure of a continuous matrix of equiaxed ferrite with islands of austenite; and cooling said microstructure of said continuous matrix of equiaxed ferrite with islands of austenite to ambient temperature to produce said machinable austempered cast iron article having improved strength, machinability, ductility, fatigue performance, and resistance to environmental cracking.
29. A machinable austempered cast iron article as set forth in claim 28 wherein said substantially pearlitic microstructure includes at least 80% pearlite.
30. A machinable austempered cast iron article as set forth in claim 28 comprising, by weight, 3.3-3.9% carbon, 1.90-2.70% silicon, 0.45-2.05% nickel, 0.55-1.05%
copper, 0-0.20%
molybdenum, and a remainder of iron.
31. A machinable austempered cast iron article as set forth in claim 30 wherein said article has a Brinell hardness of between 180 and 340 BHN.
32. A machinable austempered cast iron article as set forth in claim 31 wherein said article has a yield strength of between 50,000 and 125,000 psi.
33. A machinable austempered cast iron article as set forth in claim 32 wherein said article has an ultimate tensile strength of between 70,000 and 170,000 psi.
34. A machinable austempered cast iron article as set forth in claim 33 wherein said article has an elongation of between 14% and 22%.
35. A machinable austempered cast iron composition, said composition comprising, by weight, 3.3-3.9% carbon, 1.90-2.70% silicon, 0.45-2.05% nickel, 0.55-1.05%
copper, 0-0.20% molybdenum, and a remainder of iron, said composition characterized by a microstructure of a continuous matrix of equiaxed ferrite with islands of austenite to provide said composition with improved strength, machinability, ductility, fatigue performance, and resistance to environmental cracking.
36. A machinable austempered cast iron composition as set forth in claim 35 comprising, by weight, 3.7% carbon, 2.5% silicon, 1.85% nickel, 0.85% copper, 0.05%
molybdenum, and a remainder of iron.
CA002497760A 2002-09-04 2003-08-29 A machinable austempered cast iron article having improved machinability, fatigue performance, and resistance to environmental cracking and a method of making the same Expired - Fee Related CA2497760C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US40817402P 2002-09-04 2002-09-04
US60/408,174 2002-09-04
PCT/US2003/027198 WO2004022792A2 (en) 2002-09-04 2003-08-29 Austempered cast iron article and a method of making the same

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CA2497760A1 true CA2497760A1 (en) 2004-03-18
CA2497760C CA2497760C (en) 2009-12-22

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US (2) US7070666B2 (en)
EP (1) EP1534867A2 (en)
CN (1) CN100398672C (en)
CA (1) CA2497760C (en)
MX (1) MXPA05002433A (en)
WO (1) WO2004022792A2 (en)

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WO2004022792A3 (en) 2004-06-17
US7497915B2 (en) 2009-03-03
US20060157160A1 (en) 2006-07-20
CA2497760C (en) 2009-12-22
CN100398672C (en) 2008-07-02
WO2004022792A2 (en) 2004-03-18
CN1688723A (en) 2005-10-26
US7070666B2 (en) 2006-07-04
EP1534867A2 (en) 2005-06-01
MXPA05002433A (en) 2005-05-27
US20040112479A1 (en) 2004-06-17

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