CA2478516A1 - A process for the recovery of value metals from base metal sulfide ores - Google Patents
A process for the recovery of value metals from base metal sulfide ores Download PDFInfo
- Publication number
- CA2478516A1 CA2478516A1 CA002478516A CA2478516A CA2478516A1 CA 2478516 A1 CA2478516 A1 CA 2478516A1 CA 002478516 A CA002478516 A CA 002478516A CA 2478516 A CA2478516 A CA 2478516A CA 2478516 A1 CA2478516 A1 CA 2478516A1
- Authority
- CA
- Canada
- Prior art keywords
- value
- leaching
- metals
- base
- base metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
- C22B23/0461—Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0069—Leaching or slurrying with acids or salts thereof containing halogen
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0084—Treating solutions
- C22B15/0089—Treating solutions by chemical methods
- C22B15/0093—Treating solutions by chemical methods by gases, e.g. hydrogen or hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
- C22B23/0423—Halogenated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/10—Hydrochloric acid, other halogenated acids or salts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
A process for leaching a value metal from a base metal sulfide ore, comprising the step of leaching the ore with a lixiviant comprising a chloride, an oxidant and hydrochloric acid is disclosed. The leaching is controlled, by use of low concentrations of hydrochloric acid and a redox potential, to effect formation of hydrogen sulfide from the base metal sulfide ore. The hydrogen sulfide is stripped from the leach solution, thereby reducing the amount of sulfate generated in the leach to very low levels. The leaching may also be conducted to limit the co-dissolution of platinum group metals and gold with the base value metals. The leach forms a value metal-rich leachate and a solids residue. The solids residue may be subsequently leached to recover the platinum group metals and gold. The value metal-rich leachate can be oxidized and neutralized to recover the value base metals. In an embodiment, the chloride is magnesium chloride and lixiviant solution is regenerated.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US50677303P | 2003-09-30 | 2003-09-30 | |
US60/506,773 | 2003-09-30 | ||
US55857104P | 2004-04-02 | 2004-04-02 | |
US60/558,571 | 2004-04-02 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2478516A1 true CA2478516A1 (en) | 2005-02-09 |
CA2478516C CA2478516C (en) | 2007-12-11 |
Family
ID=34139076
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002478516A Active CA2478516C (en) | 2003-09-30 | 2004-09-27 | A process for the recovery of value metals from base metal sulfide ores |
Country Status (9)
Country | Link |
---|---|
US (2) | US7736606B2 (en) |
EP (1) | EP1678336B9 (en) |
AR (1) | AR046413A1 (en) |
AU (1) | AU2004276391B2 (en) |
BR (1) | BRPI0414905A (en) |
CA (1) | CA2478516C (en) |
EA (1) | EA010792B1 (en) |
PE (1) | PE20050849A1 (en) |
WO (1) | WO2005031012A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007071021A1 (en) * | 2005-12-23 | 2007-06-28 | Harris G Bryn | Process for recovering a base metal from a sulfide ore material |
WO2010135776A1 (en) | 2009-05-26 | 2010-12-02 | Metaleach Limited | Method of oxidative leaching of sulfide ores and/or concentrates |
CN113373311A (en) * | 2021-06-08 | 2021-09-10 | 金川镍钴研究设计院有限责任公司 | Method for fully soaking copper-nickel alloy powder in sulfuric acid at normal temperature and normal pressure |
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WO2007039665A1 (en) * | 2005-10-03 | 2007-04-12 | Outotec Oyj. | Method for processing nickel bearing raw material in chloride-based leaching |
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US7658895B2 (en) * | 2007-11-28 | 2010-02-09 | Chevron U.S.A. Inc | Process for recovering base metals from spent hydroprocessing catalyst |
US8221710B2 (en) * | 2007-11-28 | 2012-07-17 | Sherritt International Corporation | Recovering metals from complex metal sulfides |
US7846404B2 (en) * | 2007-11-28 | 2010-12-07 | Chevron U.S.A. Inc. | Process for separating and recovering base metals from used hydroprocessing catalyst |
US7837960B2 (en) * | 2007-11-28 | 2010-11-23 | Chevron U.S.A. Inc. | Process for separating and recovering base metals from used hydroprocessing catalyst |
WO2009086460A1 (en) | 2007-12-28 | 2009-07-09 | Calera Corporation | Methods of sequestering co2 |
US7754169B2 (en) * | 2007-12-28 | 2010-07-13 | Calera Corporation | Methods and systems for utilizing waste sources of metal oxides |
US20100239467A1 (en) | 2008-06-17 | 2010-09-23 | Brent Constantz | Methods and systems for utilizing waste sources of metal oxides |
US7749476B2 (en) * | 2007-12-28 | 2010-07-06 | Calera Corporation | Production of carbonate-containing compositions from material comprising metal silicates |
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US7815880B2 (en) | 2008-09-30 | 2010-10-19 | Calera Corporation | Reduced-carbon footprint concrete compositions |
US7939336B2 (en) | 2008-09-30 | 2011-05-10 | Calera Corporation | Compositions and methods using substances containing carbon |
US9133581B2 (en) | 2008-10-31 | 2015-09-15 | Calera Corporation | Non-cementitious compositions comprising vaterite and methods thereof |
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US20100224503A1 (en) * | 2009-03-05 | 2010-09-09 | Kirk Donald W | Low-energy electrochemical hydroxide system and method |
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WO2011140593A1 (en) * | 2010-05-10 | 2011-11-17 | Wintermute Metals Pty Ltd | Recovery of platinum group metals from platinum group metal-containing materials |
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-
2004
- 2004-09-27 CA CA002478516A patent/CA2478516C/en active Active
- 2004-09-28 BR BRPI0414905 patent/BRPI0414905A/en not_active IP Right Cessation
- 2004-09-28 EA EA200600691A patent/EA010792B1/en not_active IP Right Cessation
- 2004-09-28 AU AU2004276391A patent/AU2004276391B2/en not_active Ceased
- 2004-09-28 EP EP20040786671 patent/EP1678336B9/en not_active Not-in-force
- 2004-09-28 US US10/950,671 patent/US7736606B2/en not_active Expired - Fee Related
- 2004-09-28 WO PCT/CA2004/001753 patent/WO2005031012A1/en active Application Filing
- 2004-09-29 PE PE2004000949A patent/PE20050849A1/en not_active Application Discontinuation
- 2004-09-29 AR ARP040103527 patent/AR046413A1/en not_active Application Discontinuation
-
2008
- 2008-09-29 US US12/216,940 patent/US7968065B2/en not_active Expired - Fee Related
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007071021A1 (en) * | 2005-12-23 | 2007-06-28 | Harris G Bryn | Process for recovering a base metal from a sulfide ore material |
WO2010135776A1 (en) | 2009-05-26 | 2010-12-02 | Metaleach Limited | Method of oxidative leaching of sulfide ores and/or concentrates |
US9771631B2 (en) | 2009-05-26 | 2017-09-26 | Metaleach Limited | Method of oxidative leaching of sulfide ores and/or concentrates |
CN113373311A (en) * | 2021-06-08 | 2021-09-10 | 金川镍钴研究设计院有限责任公司 | Method for fully soaking copper-nickel alloy powder in sulfuric acid at normal temperature and normal pressure |
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EP1678336A1 (en) | 2006-07-12 |
EP1678336B9 (en) | 2015-04-29 |
PE20050849A1 (en) | 2005-12-03 |
WO2005031012A1 (en) | 2005-04-07 |
US20050118081A1 (en) | 2005-06-02 |
EP1678336A4 (en) | 2008-06-11 |
US20090013829A1 (en) | 2009-01-15 |
AU2004276391A1 (en) | 2005-04-07 |
BRPI0414905A (en) | 2006-11-07 |
AU2004276391B2 (en) | 2010-12-16 |
US7968065B2 (en) | 2011-06-28 |
AR046413A1 (en) | 2005-12-07 |
CA2478516C (en) | 2007-12-11 |
US7736606B2 (en) | 2010-06-15 |
EP1678336B1 (en) | 2014-11-12 |
EA200600691A1 (en) | 2006-08-25 |
EA010792B1 (en) | 2008-12-30 |
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