CA2468182A1 - Articles and methods for applying color on surfaces - Google Patents

Articles and methods for applying color on surfaces Download PDF

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Publication number
CA2468182A1
CA2468182A1 CA002468182A CA2468182A CA2468182A1 CA 2468182 A1 CA2468182 A1 CA 2468182A1 CA 002468182 A CA002468182 A CA 002468182A CA 2468182 A CA2468182 A CA 2468182A CA 2468182 A1 CA2468182 A1 CA 2468182A1
Authority
CA
Canada
Prior art keywords
sheet
adhesive
color component
dry color
optionally
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002468182A
Other languages
French (fr)
Other versions
CA2468182C (en
Inventor
Shawn Christopher Pallotta
Von Adoniram Kinsey
Michael John O'brien
Robert Lawrence Prosise
John William Toussant
Andrew Julian Wnuk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
The Procter & Gamble Company
Shawn Christopher Pallotta
Von Adoniram Kinsey
Michael John O'brien
Robert Lawrence Prosise
John William Toussant
Andrew Julian Wnuk
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company, Shawn Christopher Pallotta, Von Adoniram Kinsey, Michael John O'brien, Robert Lawrence Prosise, John William Toussant, Andrew Julian Wnuk filed Critical The Procter & Gamble Company
Publication of CA2468182A1 publication Critical patent/CA2468182A1/en
Application granted granted Critical
Publication of CA2468182C publication Critical patent/CA2468182C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17Dry transfer
    • B44C1/1733Decalcomanias applied under pressure only, e.g. provided with a pressure sensitive adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/06Interconnection of layers permitting easy separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/26Printing on other surfaces than ordinary paper
    • B41M1/30Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/10Applying flat materials, e.g. leaflets, pieces of fabrics
    • B44C1/105Applying flat materials, e.g. leaflets, pieces of fabrics comprising an adhesive layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17Dry transfer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17Dry transfer
    • B44C1/1712Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/914Transfer or decalcomania
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/1405Capsule or particulate matter containing [e.g., sphere, flake, microballoon, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/1438Metal containing
    • Y10T428/1448Coloring agent containing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/1476Release layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/1486Ornamental, decorative, pattern, or indicia
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/149Sectional layer removable
    • Y10T428/1495Adhesive is on removable layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
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    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851Intermediate layer is discontinuous or differential
    • Y10T428/2486Intermediate layer is discontinuous or differential with outer strippable or release layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/24868Translucent outer layer
    • Y10T428/24876Intermediate layer contains particulate material [e.g., pigment, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/24893Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
    • Y10T428/24901Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material including coloring matter
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/2813Heat or solvent activated or sealable
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    • Y10T428/2839Web or sheet containing structurally defined element or component and having an adhesive outermost layer with release or antistick coating
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    • Y10T428/2848Three or more layers

Abstract

Articles for applying color on a surface comprise a sheet of dry color component and an adhesive on one surface of the sheet of dry color component.
In one embodiment, the article is free of a releasable liner and a carrier sheet. In another embodiment, the sheet of dry color component and adhesive have a combined thickness of about 3 mils or less. Methods for providing a substantially permanent color effect on an architectural surface comprise applying dry color component to the architectural surface.

Claims (32)

1. An article for applying color on a surface, characterized by a sheet of dry color component and an adhesive on one surface of the sheet of dry color component, wherein the article is free of a releasable liner and is free of a carrier sheet.
2. The article according to claim 1, wherein the sheet of dry color component is characterized by an opacifying layer; optionally wherein said opacifying layer comprises a film having a layer on at least one of its surfaces; optionally wherein said film is selected from polymeric films, metallic films, fibrous films and combinations thereof.
3. The article according to claim 1, further characterized by an opacifying agent; optionally wherein said opacifying agent is in the adhesive.
4. The article according to claim 1, wherein the adhesive is adapted to exhibit an initial tack in response to a first condition and a subsequent tack greater than the initial tack in response to a second condition.
5. The article according to claim 1, wherein the sheet of dry color component is characterized by a topcoat on a surface opposite the adhesive; optionally wherein said topcoat is characterized by a protective film layer.
6. An article for applying color on a surface, characterized by a sheet of dry color component and an adhesive on one surface of the sheet of dry color component, wherein the sheet and the adhesive have a combined thickness of 3.3 mils or less;
optionally wherein said sheet of dry color component is removable.
7. An article for applying color on a surface, characterized by a sheet of dry color component and an adhesive on one surface of the sheet of dry color component, wherein the sheet and the adhesive have a combined thickness of 3.3 mils or less;
optionally wherein said sheet of dry color component is removable.
8. The article according to claim 6, wherein the sheet of dry color component is characterized by an opacifying layer; optionally wherein said opacifying layer is characterized by a film having a layer on at least one of its surfaces;
preferably wherein said film is selected from polymeric films, metallic films, fibrous films and combinations thereof.
9. The article according to claim 6, further characterized by an opacifying agent; optionally wherein said opacifying agent is in the adhesive.
10. The article according to claim 6, wherein the adhesive is adapted to exhibit an initial tack in response to a first condition and a subsequent tack greater than the initial tack in response to a second condition.
11. The article according to claim 6, wherein the sheet of dry color component is characterized by a topcoat on a surface opposite the adhesive.
12. The article according to claim 6, further characterized by a releasable liner, wherein the sheet of dry color component is arranged between the releasable liner and the adhesive.
13. The article according to claim 12, wherein a release agent is provided between the releasable liner and the sheet of dry color component.
14. The article according to claim 12, wherein a surface of the releasable liner opposite the sheet of dry color component has a release agent thereon.
15. The article according to claim 12, wherein the releasable liner is formed of a polymer having release characteristics.
16. The article according to claim 12, wherein the adhesive is adapted to exhibit an initial tack in response to a first condition and a subsequent tack greater than the initial tack in response to a second condition; optionally wherein the adhesive is characterized by a pressure sensitive adhesive.
17. The article according to claim 16, wherein the adhesive is characterized by a blocking agent at a surface thereof; optionally wherein said blocking agent is selected from starch, talc, silicon dioxide, titanium dioxide, zeolite, polymers, glass, ceramic and mixtures thereof.
18. An article for applying color on a surface, characterized by (a) a sheet of dry color component including (i) a pigment, dye, or combination thereof in a polymeric binder, and (ii) a topcoat layer, (b) an adhesive on a surface of the sheet of dry colorant opposite the topcoat layer, and (c) a releasable liner, wherein the sheet of dry color component is arranged between the releasable liner and the adhesive, the releasable liner having a release agent on its surface adjacent the dry color component;
wherein the sheet of dry color component and the adhesive are characterized by a combined thickness of 3.3 mils or less preferably, wherein the adhesive is adapted to exhibit an initial tack in response to a first condition and a subsequent tack greater than the first tack in response to a second condition.
19. An article for applying color on a surface, characterized by (a) a sheet of dry color component including a backing layer at one surface, and (b) an adhesive on the surface of the sheet of dry color component including the backing layer, wherein the sheet and adhesive have a combined thickness of 3.3 mils or less;

optionally wherein said backing layer is characterized by a polymer film having a metallized layer; and optionally wherein said backing layer is free of cellulose.
20. The article according to claim 19, wherein the adhesive is adapted to exhibit an initial tack upon application of a first pressure and a subsequent tack greater than the initial tack upon application of a second pressure; wherein said second pressure is greater than said first pressure; and optionally wherein the adhesive is characterized by a pressure sensitive adhesive; preferably wherein the adhesive is characterized by a blocking agent at a surface thereof.
21. The article according to claim 1, claim 6, claim 18 or claim 19, wherein the adhesive is adapted to adhere the article to a surface at room temperature and upon application of a pressure of less than 50 lb/in2.
22. The article according to claim 1, claim 6, claim 18 or claim 19, wherein the article is characterized by an elongation of less than 50%.
23. An article for applying color on a surface, characterized by a sheet of dry color component and an adhesive on one surface of the sheet of dry color component, wherein the sheet and adhesive are adapted to provide a surface covering having a water vapor transmission rate of greater than 1 g-p,m/cm2/24 hrs.
24. A method for providing a substantially permanent color effect on a surface, characterized by the step of applying an article comprising a sheet of dry color to the surface; wherein, upon removal of a releasable liner, the applied article has a thickness of 3.3 mils or less.
25. The method according to claim 24, wherein the sheet of dry color is applied to an architectural surface; optionally wherein said sheet of dry color is in the form of a sheet of dry color component adjacent a releasable liner.
26. The method according to claim 24, wherein the dry color component is applied without the use of wet tools for applying the article to the surface, mess protection, or color component cleaning materials, optionally wherein the dry color component is substantially free of volatile organic components; optionally wherein said wet tools are selected from wet brushes, wet sprayers, wet rollers and combinations thereof.
27. The method according to claim 26, further characterized by the step of adhering the applied dry color component to the architectural surface.
28. The method according to claim 25, wherein the sheet of dry color component is adhered to the architectural surface by application of pressure to a surface of the releasable liner opposite the sheet of dry color component.
29. The method according to claim 26, wherein the sheet of dry color component is characterized by a dry color component layer comprising: (i) pigment, dye or a combination thereof, and (ii) a binder; optionally wherein the binder comprises a polymeric binder.
30. A method for providing a substantially permanent color effect on an architectural surface, characterized by the step of delivering to said surface an article according to claim 1, claim 6, claim 18, claim 19 or claim 23.
31. A process of making an article for applying color onto a surface, said process characterized by the steps of:
(a) providing a releasable liner in roll form;
(b) unrolling said releasable liner such that said releasable liner may travel though an assembly via rollers;
(c) pulling said releasable liner as a web through said assembly via a combination of rollers and a conveyer;

(d) applying a color component to the web of the releasable liner using an applicator;
(e) passing the web between said roller and said applicator using a rod that is held against the roller such that the web passes between the roller and the applicator;
(f) feeding a manifold by tubing from a pump that draws paint from a reservoir;
(g) forming a sheet of dry color component by drying paint on said web;
(h) applying an adhesive to a surface of the sheet of dry color component using an applicator;
(i) passing the web between said roller and applicator using a rod that is held against the roller such that the web passes between the roller and the applicator;
(j) feeding a manifold by tubing from a pump that draws adhesive from a reservoir;
(k) sending an adhesive-comprising web through a roller that traverses back and forth in said apparatus to impart a texture to the liquid adhesive;
(l) optionally, drying said adhesive by passing the web under a heater;
(m) optionally, cutting the web via one or more knives arranged on one or more edges of the web to provide a final article with homogenous edges;
(n) optionally, winding the resulting article on a roll;
(o) optionally, providing release agents in a form of coatings or layers during said process;
(p) optionally, providing a sheet of dry color component in a final article without a release liner; and (q) optionally, employing two releasable liner webs in said process.
32. A method of removing a dry color from an architectural surface, said method characterized by the steps of:
(a) identifying a sheet of dry color for which removal is sought;
(b) increasing or reducing the temperature of an exposed surface of said dry color such that adherence of said dry color is reduced;

(c) optionally, removing said dry color upon a reduction of adherence thereof.
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US60/380,225 2002-05-13
US60/380,205 2002-05-13
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EP1456041A2 (en) 2004-09-15
CA2468185C (en) 2010-06-15
US7897227B2 (en) 2011-03-01
JP2005515293A (en) 2005-05-26
WO2003062341A3 (en) 2003-11-13
CN100488788C (en) 2009-05-20
CN1635957A (en) 2005-07-06
KR100648021B1 (en) 2006-11-23
US7709070B2 (en) 2010-05-04
KR100648019B1 (en) 2006-11-23
WO2003053719A3 (en) 2003-11-13
JP2009107343A (en) 2009-05-21
CA2468182C (en) 2010-09-28
CA2468185A1 (en) 2003-07-03
DE60235194D1 (en) 2010-03-11
US7622175B2 (en) 2009-11-24

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