CA2449239A1 - Polyazole-based polymer films - Google Patents
Polyazole-based polymer films Download PDFInfo
- Publication number
- CA2449239A1 CA2449239A1 CA002449239A CA2449239A CA2449239A1 CA 2449239 A1 CA2449239 A1 CA 2449239A1 CA 002449239 A CA002449239 A CA 002449239A CA 2449239 A CA2449239 A CA 2449239A CA 2449239 A1 CA2449239 A1 CA 2449239A1
- Authority
- CA
- Canada
- Prior art keywords
- polymer
- polymer films
- membranes
- polyazole
- based polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
- C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
Abstract
The present invention relates to polymer films and a polymer membrane having an improved mechanical property profile produced therefrom, to a process for producing them and to their use.
The polymer films, polymer membranes and separation membranes of the invention are produced from selected polymer raw materials and have excellent chemical, thermal and mechanical properties as are required for use as polymer electrolyte membranes (PEMs) in PEM fuel cells or in apparatuses for the filtration and/or separation of gases and/or liquids or for reverse osmosis.
The polymer films, polymer membranes and separation membranes of the invention are produced from selected polymer raw materials and have excellent chemical, thermal and mechanical properties as are required for use as polymer electrolyte membranes (PEMs) in PEM fuel cells or in apparatuses for the filtration and/or separation of gases and/or liquids or for reverse osmosis.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10129458.1 | 2001-06-19 | ||
DE10129458A DE10129458A1 (en) | 2001-06-19 | 2001-06-19 | Improved polymer films based on polyazoles |
PCT/EP2002/006773 WO2002102881A1 (en) | 2001-06-19 | 2002-06-19 | Polyazole-based polymer films |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2449239A1 true CA2449239A1 (en) | 2002-12-27 |
CA2449239C CA2449239C (en) | 2008-08-26 |
Family
ID=7688642
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002449239A Expired - Fee Related CA2449239C (en) | 2001-06-19 | 2002-06-19 | Polyazole-based polymer films |
Country Status (10)
Country | Link |
---|---|
US (2) | US20040262227A1 (en) |
EP (1) | EP1404745B1 (en) |
JP (1) | JP4392553B2 (en) |
CN (1) | CN1239581C (en) |
AT (1) | ATE283888T1 (en) |
CA (1) | CA2449239C (en) |
DE (2) | DE10129458A1 (en) |
ES (1) | ES2233839T3 (en) |
MX (1) | MXPA03011703A (en) |
WO (1) | WO2002102881A1 (en) |
Families Citing this family (45)
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DE10109829A1 (en) * | 2001-03-01 | 2002-09-05 | Celanese Ventures Gmbh | Polymer membrane, process for its production and its use |
DE10117686A1 (en) * | 2001-04-09 | 2002-10-24 | Celanese Ventures Gmbh | Proton-conducting membrane for use e.g. in fuel cells, is made by coating a support with a solution of aromatic tetra-amine and aromatic polycarboxylic acid in polyphosphoric acid and then heating the coating |
DE10209419A1 (en) | 2002-03-05 | 2003-09-25 | Celanese Ventures Gmbh | Process for producing a polymer electrolyte membrane and its use in fuel cells |
US7846982B2 (en) | 2002-03-06 | 2010-12-07 | Pemeas Gmbh | Proton conducting electrolyte membrane having reduced methanol permeability and the use thereof in fuel cells |
DK1518282T3 (en) | 2002-04-25 | 2011-01-03 | Basf Fuel Cell Res Gmbh | Multilayer electrolyte membrane |
DE10230477A1 (en) | 2002-07-06 | 2004-01-15 | Celanese Ventures Gmbh | Functionalized polyazoles, processes for their preparation and their use |
DE10235358A1 (en) * | 2002-08-02 | 2004-02-12 | Celanese Ventures Gmbh | Proton conducting polymer membrane, useful for the production of fuel cells, is prepared by mixing an aromatic tetra-amino compound with an aromatic carboxylic acid in vinyl containing phosphoric acid |
DE50302082D1 (en) | 2002-08-02 | 2006-02-02 | Pemeas Gmbh | PROTON-CONDUCTIVE POLYMEMBRANE COMPRISING POLYMERS CONTAINING SULPHONIC ACID GROUPS AND THEIR APPLICATION IN FUEL CELLS |
DE10239701A1 (en) | 2002-08-29 | 2004-03-11 | Celanese Ventures Gmbh | Production of polymer membrane, used in membrane electrode unit for fuel cell, uses phosphorus and/or sulfur oxy-acid in liquid for hydrolyzing membrane made by heating mixture of polyphosphoric acid and polyazole or precursors |
DE10242708A1 (en) * | 2002-09-13 | 2004-05-19 | Celanese Ventures Gmbh | Proton-conducting membranes and their use |
DE10246461A1 (en) * | 2002-10-04 | 2004-04-15 | Celanese Ventures Gmbh | Polymer electrolyte membrane containing a polyazole blend for use, e.g. in fuel cells, obtained by processing a mixture of polyphosphoric acid, polyazole and non-polyazole polymer to form a self-supporting membrane |
DE10246372A1 (en) * | 2002-10-04 | 2004-04-15 | Celanese Ventures Gmbh | Catalyst-coated polymer electrolyte membrane for use, e.g. in fuel cells, obtained by processing a mixture of polyphosphoric acid and polyazole to form a self-supporting membrane which is then coated with catalyst |
DE10246373A1 (en) | 2002-10-04 | 2004-04-15 | Celanese Ventures Gmbh | Polymer electrolyte membrane for use, e.g. in fuel cells, manufactured by heating a mixture of sulfonated aromatic polyazole monomers in polyphosphoric acid and then processing to form a self-supporting membrane |
DE10246459A1 (en) | 2002-10-04 | 2004-04-15 | Celanese Ventures Gmbh | Polymer electrolyte membrane for use, e.g. in fuel cells, obtained by heating a mixture of phosphonated aromatic polyazole monomers in polyphosphoric acid and then processing to form a self-supporting membrane |
US7892993B2 (en) | 2003-06-19 | 2011-02-22 | Eastman Chemical Company | Water-dispersible and multicomponent fibers from sulfopolyesters |
US20040260034A1 (en) | 2003-06-19 | 2004-12-23 | Haile William Alston | Water-dispersible fibers and fibrous articles |
US8513147B2 (en) | 2003-06-19 | 2013-08-20 | Eastman Chemical Company | Nonwovens produced from multicomponent fibers |
US7820314B2 (en) | 2003-07-27 | 2010-10-26 | Basf Fuel Cell Research Gmbh | Proton-conducting membrane and use thereof |
DE102004008628A1 (en) | 2004-02-21 | 2005-09-08 | Celanese Ventures Gmbh | High performance membrane electrode assembly and its application in fuel cells |
CN1997690A (en) | 2004-05-14 | 2007-07-11 | 佩密斯股份有限公司 | Anisotropic shaped bodies, method for the production and utilization of anisotropic shaped bodies |
DE102004034139A1 (en) | 2004-07-15 | 2006-02-02 | Pemeas Gmbh | Process for the preparation of membrane-electrode assemblies |
WO2006028190A1 (en) * | 2004-09-09 | 2006-03-16 | Asahi Kasei Chemicals Corporation | Solid polymer electrolyte membrane and method for producing same |
ATE533200T1 (en) * | 2004-12-07 | 2011-11-15 | Toray Industries | COMPOSITE FILM ELECTRODE ELEMENT AND PROCESS FOR PRODUCTION THEREOF AND FUEL CELL |
DE102005020604A1 (en) * | 2005-05-03 | 2006-11-16 | Pemeas Gmbh | Fuel cells with lower weight and volume |
JP5220599B2 (en) * | 2005-07-01 | 2013-06-26 | ビーエーエスエフ、フューエル、セル、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | Gas diffusion electrode, membrane-electrode assembly and method of manufacturing the same |
US8945736B2 (en) | 2005-09-10 | 2015-02-03 | Basf Fuel Cell Gmbh | Method for conditioning membrane-electrode-units for fuel cells |
DE102005051887A1 (en) * | 2005-10-29 | 2007-05-03 | Pemeas Gmbh | Membrane for fuel cells containing polymers comprising phosphonic acid and / or sulfonic acid groups, membrane-electrode assembly and their application in fuel cells |
DE102005052378A1 (en) * | 2005-10-31 | 2007-05-03 | Pemeas Gmbh | Production of high-mol. wt. polymer with phosphonic acid groups for use in membrane-electrolyte units for fuel cells, involves radical polymerisation of unsaturated monomers with phosphonic acid groups |
DE102005058578A1 (en) | 2005-12-08 | 2007-06-28 | Sartorius Ag | Membranes of polyazoles, processes for their preparation and fuel cells using such membranes |
US20080317946A1 (en) * | 2007-06-21 | 2008-12-25 | Clearedge Power, Inc. | Fuel cell membranes, gels, and methods of fabrication |
US20110114160A1 (en) * | 2008-04-24 | 2011-05-19 | Nitto Denko Corporation | Transparent substrate |
US8512519B2 (en) | 2009-04-24 | 2013-08-20 | Eastman Chemical Company | Sulfopolyesters for paper strength and process |
JP5416546B2 (en) * | 2009-10-23 | 2014-02-12 | 日東電工株式会社 | Transparent substrate |
US20110189484A1 (en) | 2010-02-04 | 2011-08-04 | Hopkins Jr John B | Porous polybenzimidazole resin and method of making same |
US8460591B2 (en) * | 2010-03-23 | 2013-06-11 | GM Global Technology Operations LLC | Porous membranes and methods of making the same |
WO2011132152A1 (en) * | 2010-04-22 | 2011-10-27 | Basf Se | Improved polymer electrolyte membrane based on polyazole |
DE102010039900A1 (en) * | 2010-08-27 | 2012-03-01 | Wacker Chemie Ag | Porous polymer films based on nitrogen-containing aromatic polymers |
US20120183861A1 (en) | 2010-10-21 | 2012-07-19 | Eastman Chemical Company | Sulfopolyester binders |
US8541517B2 (en) | 2011-03-10 | 2013-09-24 | Battelle Energy Alliance, Llc | Polymer compositions, polymer films and methods and precursors for forming same |
US8840758B2 (en) | 2012-01-31 | 2014-09-23 | Eastman Chemical Company | Processes to produce short cut microfibers |
US9283523B2 (en) * | 2012-05-25 | 2016-03-15 | Pbi Performance Products, Inc. | Acid resistant PBI membrane for pervaporation dehydration of acidic solvents |
US9617685B2 (en) | 2013-04-19 | 2017-04-11 | Eastman Chemical Company | Process for making paper and nonwoven articles comprising synthetic microfiber binders |
US9309205B2 (en) * | 2013-10-28 | 2016-04-12 | Wincom, Inc. | Filtration process for purifying liquid azole heteroaromatic compound-containing mixtures |
US9605126B2 (en) | 2013-12-17 | 2017-03-28 | Eastman Chemical Company | Ultrafiltration process for the recovery of concentrated sulfopolyester dispersion |
US9598802B2 (en) | 2013-12-17 | 2017-03-21 | Eastman Chemical Company | Ultrafiltration process for producing a sulfopolyester concentrate |
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US3313783A (en) * | 1962-07-20 | 1967-04-11 | Teijin Ltd | Process for preparation of polybenzimidazoles |
BE788751A (en) * | 1971-09-13 | 1973-01-02 | Teijin Ltd | PERMSELECTIVE POLYMERIC MEMBRANES |
US4120098A (en) * | 1976-06-22 | 1978-10-17 | E. I. Du Pont De Nemours And Company | Solvent exchange drying of membranes for gas separation |
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US4259183A (en) * | 1978-11-07 | 1981-03-31 | Midwest Research Institute | Reverse osmosis membrane |
IL64967A0 (en) * | 1981-03-17 | 1982-04-30 | Aligena Ag | Semipermeable membranes containing modified polysulfones,their manufacture and their use |
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US4814399A (en) * | 1987-07-24 | 1989-03-21 | Hoechst Celanese Corporation | Sulfoalkylation of polybenzimidazole |
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JP3607004B2 (en) * | 1996-07-05 | 2005-01-05 | クラリアント インターナショナル リミテッド | Solution of polybenzimidazole compound and process for producing the same |
JP2000281819A (en) * | 1999-01-27 | 2000-10-10 | Aventis Res & Technol Gmbh & Co Kg | Production of cross-linked polymer membrane and fuel cell |
US6623639B2 (en) * | 1999-03-19 | 2003-09-23 | Bend Research, Inc. | Solvent-resistant microporous polybenzimidazole membranes |
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US6623634B1 (en) * | 2000-10-11 | 2003-09-23 | Paul L. Whitehurst | Tissue float water bath liner and filter |
DE10052242A1 (en) * | 2000-10-21 | 2002-05-02 | Celanese Ventures Gmbh | Acid-doped, single- or multi-layer plastic membrane with layers comprising polymer blends comprising polymers with repeating azole units, processes for producing such plastic membranes and their use |
JP3924675B2 (en) * | 2001-01-09 | 2007-06-06 | 独立行政法人産業技術総合研究所 | PROTON CONDUCTIVE MEMBRANE, MANUFACTURING METHOD THEREOF, AND FUEL CELL USING THE SAME |
DE10110752A1 (en) * | 2001-03-07 | 2002-09-19 | Celanese Ventures Gmbh | Process for the production of a membrane from bridged polymer and fuel cell |
JP3698067B2 (en) * | 2001-03-30 | 2005-09-21 | Jsr株式会社 | Monomer having electron-withdrawing group and electron-donating group, copolymer using the same, and proton conducting membrane |
DE10117687A1 (en) * | 2001-04-09 | 2002-10-17 | Celanese Ventures Gmbh | Proton-conducting membrane and its use |
DE10117686A1 (en) * | 2001-04-09 | 2002-10-24 | Celanese Ventures Gmbh | Proton-conducting membrane for use e.g. in fuel cells, is made by coating a support with a solution of aromatic tetra-amine and aromatic polycarboxylic acid in polyphosphoric acid and then heating the coating |
DE50302082D1 (en) * | 2002-08-02 | 2006-02-02 | Pemeas Gmbh | PROTON-CONDUCTIVE POLYMEMBRANE COMPRISING POLYMERS CONTAINING SULPHONIC ACID GROUPS AND THEIR APPLICATION IN FUEL CELLS |
US6878475B2 (en) * | 2002-11-22 | 2005-04-12 | T/J Technologies, Inc. | Membrane for fuel cell, and fuel cell incorporating that membrane |
US6946015B2 (en) * | 2003-06-26 | 2005-09-20 | The Regents Of The University Of California | Cross-linked polybenzimidazole membrane for gas separation |
US6997971B1 (en) * | 2004-07-28 | 2006-02-14 | The Regents Of The University Of California | Cross-linked polybenzimidazole membrane for gas separation |
-
2001
- 2001-06-19 DE DE10129458A patent/DE10129458A1/en not_active Withdrawn
-
2002
- 2002-06-19 MX MXPA03011703A patent/MXPA03011703A/en not_active Application Discontinuation
- 2002-06-19 JP JP2003506350A patent/JP4392553B2/en not_active Expired - Fee Related
- 2002-06-19 AT AT02748797T patent/ATE283888T1/en not_active IP Right Cessation
- 2002-06-19 DE DE50201690T patent/DE50201690D1/en not_active Expired - Lifetime
- 2002-06-19 EP EP02748797A patent/EP1404745B1/en not_active Expired - Lifetime
- 2002-06-19 CN CNB028120930A patent/CN1239581C/en not_active Expired - Fee Related
- 2002-06-19 US US10/481,170 patent/US20040262227A1/en not_active Abandoned
- 2002-06-19 ES ES02748797T patent/ES2233839T3/en not_active Expired - Lifetime
- 2002-06-19 WO PCT/EP2002/006773 patent/WO2002102881A1/en active IP Right Grant
- 2002-06-19 CA CA002449239A patent/CA2449239C/en not_active Expired - Fee Related
-
2006
- 2006-08-30 US US11/512,803 patent/US7485227B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP1404745B1 (en) | 2004-12-01 |
DE50201690D1 (en) | 2005-01-05 |
ES2233839T3 (en) | 2005-06-16 |
EP1404745A1 (en) | 2004-04-07 |
CN1516717A (en) | 2004-07-28 |
WO2002102881A1 (en) | 2002-12-27 |
US20070102361A1 (en) | 2007-05-10 |
ATE283888T1 (en) | 2004-12-15 |
JP4392553B2 (en) | 2010-01-06 |
US20040262227A1 (en) | 2004-12-30 |
US7485227B2 (en) | 2009-02-03 |
MXPA03011703A (en) | 2004-03-19 |
CA2449239C (en) | 2008-08-26 |
CN1239581C (en) | 2006-02-01 |
JP2004534882A (en) | 2004-11-18 |
DE10129458A1 (en) | 2003-01-02 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |