CA2433664A1 - Heat-sealable laminate - Google Patents

Heat-sealable laminate Download PDF

Info

Publication number
CA2433664A1
CA2433664A1 CA002433664A CA2433664A CA2433664A1 CA 2433664 A1 CA2433664 A1 CA 2433664A1 CA 002433664 A CA002433664 A CA 002433664A CA 2433664 A CA2433664 A CA 2433664A CA 2433664 A1 CA2433664 A1 CA 2433664A1
Authority
CA
Canada
Prior art keywords
laminate
facestock
layer
adhesive layer
ink
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002433664A
Other languages
French (fr)
Other versions
CA2433664C (en
Inventor
Richard L. Sandt
Mark D. Kittel
Henry Lum Jr.
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CCL Label Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2433664A1 publication Critical patent/CA2433664A1/en
Application granted granted Critical
Publication of CA2433664C publication Critical patent/CA2433664C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/08—Fastening or securing by means not forming part of the material of the label itself
    • G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/14—Layer or component removable to expose adhesive
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/14—Layer or component removable to expose adhesive
    • Y10T428/1481—Dissimilar adhesives
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/14—Layer or component removable to expose adhesive
    • Y10T428/1486—Ornamental, decorative, pattern, or indicia
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y10T428/2486—Intermediate layer is discontinuous or differential with outer strippable or release layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24934—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including paper layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2813—Heat or solvent activated or sealable
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2813—Heat or solvent activated or sealable
    • Y10T428/2817—Heat sealable
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2839—Web or sheet containing structurally defined element or component and having an adhesive outermost layer with release or antistick coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2843—Web or sheet containing structurally defined element or component and having an adhesive outermost layer including a primer layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2848—Three or more layers

Abstract

This invention relates to a heat-sealable laminate (200), comprising: a facestock (210) having an upper surface (214) and a lower surface (216); a heat-activatable first adhesive layer (217) underlying the lower surface (21 6) of the facestock (210); and a second adhesive layer (230) overlaying the upp er surface (214) of the facestock (210), with the proviso that the laminate (20 0) is characterized by the absence of either an adhesion promoting layer or an abrasion-resistant transparent coating layer positioned between the upper surface (216) of the facestock (210) and the second adhesive layer (230). These heat-sealable laminates (200) may be used in providing pictorial and/or print designs or messages (e.g., labels decals, etc.) that can be adhered to substrates (e.g., metal, plastic, leather, paper or textile substrates) such as automotive interior surfaces, hard plastic component parts, consumer durable goods, and the like.

Claims (42)

1. A heat-sealable laminate, comprising:
a facestock having an upper surface and a lower surface;
a heat-activatable first adhesive layer underlying the lower surface of the facestock; and a second adhesive layer overlying the upper surface of the facestock;
with the proviso that the laminate is characterized by the absence of either an adhesion promoting layer or an abrasion-resistant transparent coating layer positioned between the upper surface of the facestock and the second adhesive layer.
2. The laminate of claim 1 wherein the laminate further comprises an adhesion promoting layer positioned between the upper surface of the facestock and the second adhesive layer.
3. The laminate of claim 1 wherein the laminate further comprises an abrasion-resistant transparent coating layer positioned between the upper surface of the facestock and the second adhesive layer.
4. The laminate of claim 1 wherein the laminate further comprises an ink or graphics layer positioned between the upper surface of the facestock and the second adhesive layer.
5. The laminate of claim 1 wherein the heat-activatable first adhesive layer is adhered to the lower surface of the facestock and the laminate further comprises an ink or graphics layer adhered to the heat-activatable first adhesive layer on the side of the heat-activatable first adhesive layer that is opposite the side of the heat-activatable first adhesive layer that is in contact with the facestock.
6. The laminate of claim 1 wherein the laminate further comprises an ink or graphics layer positioned between the lower surface of the facestock and the heat-activatable first adhesive layer.
7. The laminate of claim 1 wherein the heat-activatable first adhesive layer is adhered to the lower surface of the facestock and the laminate further comprises an ink or graphics layer positioned between the upper surface of the facestock and the second adhesive layer, and another ink or graphics layer adhered to the heat-activatable first adhesive layer on the side of the heat-activatable first adhesive layer that is opposite the side of the heat-activatable first adhesive layer that is in contact with the facestock.
8. The laminate of claim 1 wherein a carrier sheet overlies the second adhesive layer.
9. The laminate of claim 1 wherein the laminate further comprises an ink or graphics layer overlying the upper surface of the facestock and an adhesion promoting layer positioned between the ink or graphics layer and the upper surface of the facestock.
10. The laminate of claim 1 wherein the laminate further comprises an ink or graphics layer overlying the upper surface of the facestock and an abrasion-resistant transparent coating layer positioned between the ink or graphics layer and the second adhesive layer.
11. The laminate of claim 1 wherein the laminate further comprises a transparent film layer having an upper surface and a lower surface, and another adhesive layer adhered to the lower surface of the transparent film layer, the another adhesive layer being positioned between the transparent film layer and the upper surface of the facestock.
12. The laminate of claim 1 wherein the laminate is adhered to a substrate.
13. The laminate of claim 1 wherein the upper surface of the facestock is corona treated.
14. The laminate of claim 1 wherein the facestock comprises a single-layered construction.
15. The laminate of claim 1 wherein the facestock comprises a multi-layered construction.
16. The laminate of claim 1 wherein the facestock comprises foil, paper, polymer film, textile, or a combination thereof.
17. The laminate of claim 1 wherein the facestock is comprised of a polymeric film.
18. The laminate of claim 1 wherein the facestock is comprised of a multi-layered polymeric film.
19. The laminate of claim 1 wherein the facestock is comprised of a coextrudate.
20. The laminate of claim 1 wherein the facestock comprises a core layer having an upper surface and a lower surface, and the heat-activatable first adhesive layer is a thermoplastic film layer underlying the lower surface of the core layer, the facestock further comprising an upper thermoplastic film layer overlying the upper surface of the core layer.
21. The laminate of claim 20 wherein the upper thermoplastic film layer is comprised of a thermoplastic polymeric material selected from the group consisting of polyolefins, polyesters, polyamides, acrylic polymers, polystyrenes, polyurethanes, polycarbonates, polyacrylonitriles, ethylene-propylene copolymers, and mixtures of two or more thereof.
22. The laminate of claim 1 wherein the heat-activatable first adhesive layer is comprised of a heat-activatable adhesive or thermoplastic film material selected from the group consisting of polyolefins, polyamides, polyester copolymers, ionomers based on sodium or zinc salts of ethylene methacrylic acid, polyacrylonitriles, ethylene-vinyl acetate copolymers, ethylene methacrylic acid, ethylene methyl acrylate, ethylene acrylic acid, ethylene ethyl acrylate, and mixtures of two or more thereof.
23. The laminate of claim 1 wherein the facestock is comprised of a thermoplastic polymeric material selected from the group consisting of polyolefins, polyamides, polyesters, polyester copolymers, polyurethanes, polysulfones, styrene-malefic anhydride copolymers, styrene-acrylonitrile copolymers, ionomers based on sodium or zinc salts of ethylene methacrylic acid, polymethyl methacrylates, cellulosics, acrylic polymers and copolymers, polycarbonates, polyacryfonitriles, ethylene-vinyl acetate copolymers, and mixtures of two or more thereof.
24. The laminate of claim 1 wherein the second adhesive layer is comprised of a radiation-cured adhesive material or a removable pressure-sensitive adhesive material.
25. The laminate of claim 2 wherein the adhesion promoting layer is comprised of a material selected from the group consisting of polyolefins, polyamides, polyesters, polyester copolymers, polyurethanes, polysulfones, polyvinylidine chloride, styrene-malefic anhydride copolymers, styrene-acrylonitrile copolymers, ionomers based on sodium or zinc salts of ethylene methacrylic acid, polymethyl methacrylates, acrylic polymers and copolymers, polycarbonates, polyacrylonitriles, ethylene-vinyl acetate copolymers, and mixtures of two or more thereof.
26. The laminate of claim 3 wherein the abrasion-resistant transparent coating layer is made from UV curable oligomers selected from the group consisting of epoxies, urethanes, polyesters and acrylics.
27. The laminate of claim 4 wherein the ink or graphics layer is derived from a water-based ink, a solvent-based ink or a radiation curable ink.
28. The laminate of claim 4 wherein the ink or graphics layer is a mono-colored or multi-colored ink layer.
29. The laminate of claim 4 wherein the ink or graphics layer is comprised of variable imprinted data.
30. The laminate of claim 5 wherein the ink or graphics layer is derived from a water-based ink, a solvent-based ink or a radiation curable ink.
31. The laminate of claim 5 wherein the ink or graphics layer is a mono-colored or multi-colored ink layer.
32. The laminate of claim 5 wherein the ink or graphics layer is comprised of variable imprinted data.
33. The laminate of claim 8 wherein the carrier sheet is comprised ofpaper, polymer film, or a combination thereof.
34. The laminate of claim 8 wherein the carrier sheet is comprised of a transparent thermoplastic film.
35. The laminate of claim 12 wherein the substrate is comprised of a metal, plastic, leather, paper or textile material, or combination of two or more thereof.
36. The laminate of claim 12 wherein the substrate is an automotive interior surface, hard plastic component part or consumer durable good.
37. The laminate of claim 12 wherein the substrate is a seat belt, visor, dashboard, headrest, seat back, door panel, head liner, carpet, flooring, seat cover, appliance part, motor fluid cap, engine housing, helmet, vacuum cleaner, sports equipment, livestock tag, or a lock box tag.
38. A heat-sealable laminate, comprising:
a facestock having an upper surface and a lower surface;
a heat-activatable first adhesive layer underlying the lower surface of the facestock;
a second adhesive layer overlying the upper surface of the facestock; and an adhesion promoting layer positioned between the upper surface of the facestock and the second adhesive layer.
with the proviso that the laminate is characterized by the absence of an abrasion-resistant transparent coating layer positioned between the upper surface of the facestock and the second adhesive layer.
39. A heat-sealable laminate, comprising:
a facestock having an upper surface and a lower surface;
a heat-activatable first adhesive layer underlying the lower surface of the facestock;
a second adhesive layer overlying the upper surface of the facestock; and an abrasion-resistant transparent coating layer positioned between the upper surface of the facestock and the second adhesive layer;

with the proviso that the laminate is characterized by the absence of an adhesion promoting layer positioned between the upper surface of the facestock and the second adhesive layer.
40. A heat-sealable laminate, comprising:
a facestock having an upper surface and a lower surface;
a heat-activatable first adhesive layer underlying the lower surface of the facestock;
a second adhesive layer overlying the upper surface of the facestock;
an adhesion promoting layer positioned between the upper surface of the facestock and the second adhesive layer; and an ink or graphics layer positioned between the adhesion promoting layer and the second adhesive layer;
with the proviso that the laminate is characterized by the absence of an abrasion-resistant transparent coating layer positioned between the ink or graphics layer and the second adhesive layer.
41. A heat-sealable laminate, comprising:
a facestock having an upper surface and a lower surface;
a heat-activatable first adhesive layer underlying the lower surface of the facestock;
a second adhesive layer overlying the upper surface of the facestock;
an ink or graphics layer positioned between the upper surface of the facestock and the second adhesive layer; and an abrasion-resistant transparent coating layer positioned between the ink or graphics layer and the second adhesive layer;
with the proviso that the laminate is characterized by the absence of an adhesion promoting layer positioned between the upper surface of the facestock and the second adhesive layer.
42. The laminate of claim 1 wherein the second adhesive layer is a radiation-cured adhesive layer which remains adhered to the layer underlying it and functions as an additional protective layer.
CA2433664A 2001-01-10 2001-12-18 Heat-sealable laminate Expired - Lifetime CA2433664C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/758,092 2001-01-10
US09/758,092 US6756095B2 (en) 2001-01-10 2001-01-10 Heat-sealable laminate
PCT/US2001/049084 WO2002055295A1 (en) 2001-01-10 2001-12-18 Heat-sealable laminate

Publications (2)

Publication Number Publication Date
CA2433664A1 true CA2433664A1 (en) 2002-07-18
CA2433664C CA2433664C (en) 2011-08-16

Family

ID=25050454

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2433664A Expired - Lifetime CA2433664C (en) 2001-01-10 2001-12-18 Heat-sealable laminate

Country Status (8)

Country Link
US (1) US6756095B2 (en)
EP (1) EP1358066B1 (en)
JP (1) JP2004524993A (en)
AT (1) ATE462562T1 (en)
CA (1) CA2433664C (en)
DE (1) DE60141712D1 (en)
MX (1) MXPA03006203A (en)
WO (1) WO2002055295A1 (en)

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US6756095B2 (en) 2004-06-29
JP2004524993A (en) 2004-08-19

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