CA2423851A1 - Aluminum-zirconium antiperspirant salts with high peak 5 a1 content - Google Patents
Aluminum-zirconium antiperspirant salts with high peak 5 a1 content Download PDFInfo
- Publication number
- CA2423851A1 CA2423851A1 CA002423851A CA2423851A CA2423851A1 CA 2423851 A1 CA2423851 A1 CA 2423851A1 CA 002423851 A CA002423851 A CA 002423851A CA 2423851 A CA2423851 A CA 2423851A CA 2423851 A1 CA2423851 A1 CA 2423851A1
- Authority
- CA
- Canada
- Prior art keywords
- aluminum
- content
- antiperspirant salt
- salt compositions
- zirconium antiperspirant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/28—Zirconium; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/006—Compounds containing, besides zirconium, two or more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/87—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by chromatography data, e.g. HPLC, gas chromatography
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S424/00—Drug, bio-affecting and body treating compositions
- Y10S424/05—Stick
Abstract
Disclosed are enhanced efficacy aluminum-zirconium antiperspirant salt compositions which exhibit an HPLC peak 5 area content of about 33 % or more, preferably at least 45 %, more preferably at least 50 %, most preferably at least 55 %.
Especially preferred are aluminum-zirconium antiperspirant salt compositions which, in addition to the aforementioned high peak 5 content, also exhibit an HPLC peak 4 to peak 3 area ratio of at least 0.4, preferably at least 0.7. The aforementioned salt compositions will preferably have a metal (Al + Zr) to chloride (or anion) ratio of about 0.90 to about 1.00. Also disclosed are methods of making such antiperspirant salt compositions and aqueous solutions of such antiperspirant salt compositions. Further disclosed are topical compositions comprising a dermatologically acceptable carrier vehicle and a perspiration reducing effective amount of an aluminum-zirconium antiperspirant salt composition as described above.
Especially preferred are aluminum-zirconium antiperspirant salt compositions which, in addition to the aforementioned high peak 5 content, also exhibit an HPLC peak 4 to peak 3 area ratio of at least 0.4, preferably at least 0.7. The aforementioned salt compositions will preferably have a metal (Al + Zr) to chloride (or anion) ratio of about 0.90 to about 1.00. Also disclosed are methods of making such antiperspirant salt compositions and aqueous solutions of such antiperspirant salt compositions. Further disclosed are topical compositions comprising a dermatologically acceptable carrier vehicle and a perspiration reducing effective amount of an aluminum-zirconium antiperspirant salt composition as described above.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/696,271 | 2000-10-25 | ||
US09/696,271 US6436381B1 (en) | 2000-10-25 | 2000-10-25 | Aluminum-zirconium antiperspirant salts with high peak 5 al content |
PCT/US2001/046112 WO2002034223A2 (en) | 2000-10-25 | 2001-10-24 | Aluminum-zirconium antiperspirant salts |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2423851A1 true CA2423851A1 (en) | 2002-05-02 |
CA2423851C CA2423851C (en) | 2009-06-23 |
Family
ID=24796386
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002423851A Expired - Lifetime CA2423851C (en) | 2000-10-25 | 2001-10-24 | Aluminum-zirconium antiperspirant salts with high peak 5 a1 content |
Country Status (10)
Country | Link |
---|---|
US (3) | US6436381B1 (en) |
EP (1) | EP1330232B1 (en) |
AT (1) | ATE336225T1 (en) |
AU (1) | AU2015902A (en) |
BR (1) | BR0114895A (en) |
CA (1) | CA2423851C (en) |
DE (1) | DE60122359T2 (en) |
ES (1) | ES2269496T3 (en) |
MX (1) | MXPA03003618A (en) |
WO (1) | WO2002034223A2 (en) |
Families Citing this family (86)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6436381B1 (en) | 2000-10-25 | 2002-08-20 | The Gillette Company | Aluminum-zirconium antiperspirant salts with high peak 5 al content |
US6726901B2 (en) | 2002-05-09 | 2004-04-27 | The Gillette Company | Stabilized antiperspirant compositions containing aluminum-zirconium salts with low M:Cl ratio |
US6663854B1 (en) | 2002-06-19 | 2003-12-16 | Yan-Fei Shen | Aluminum-zirconium antiperspirant salts made with zirconium salts having low Zr:Cl ratio |
US6960338B2 (en) | 2002-06-28 | 2005-11-01 | Reheis, Inc. | Amino acid free stable aluminum/zirconium antiperspirant solution |
US20040091436A1 (en) * | 2002-11-12 | 2004-05-13 | Zijun Li | Antiperspirant compositions of enhanced efficacy containing strontium |
US6936242B2 (en) | 2002-11-15 | 2005-08-30 | The Gillette Company | Multi-portion antiperspirant composition |
US20040109833A1 (en) | 2002-12-09 | 2004-06-10 | Xiaozhong Tang | High efficacy, low irritation aluminum salts and related products |
US6923952B2 (en) * | 2003-08-14 | 2005-08-02 | The Gillette Company | Enhanced efficacy antiperspirant compositions containing strontium or calcium |
US20050095210A1 (en) * | 2003-10-29 | 2005-05-05 | Jairajh Mattai | Underarm products with superabsorbent component |
US7060258B2 (en) * | 2004-02-17 | 2006-06-13 | Reheis, Inc. | Method of making aluminum-zirconium antiperspirant of enhanced efficacy |
US6902724B1 (en) | 2004-03-24 | 2005-06-07 | Reheis, Inc. | Enhanced efficacy basic aluminum halides, antiperspirant active compositions and methods for making |
US7014843B2 (en) * | 2004-03-24 | 2006-03-21 | Reheis, Inc. | Enhanced efficacy basic aluminum halides/metal cation salt, antiperspirants actives and compositions containing such materials and methods for making |
US7731943B2 (en) * | 2004-07-07 | 2010-06-08 | Summit Research Labs, Inc. | Stabilized aqueous aluminum zirconium solutions |
US7087220B2 (en) * | 2004-05-28 | 2006-08-08 | Reheis, Inc. | High pH antiperspirant compositions of enhanced efficacy |
US7153495B2 (en) * | 2004-06-10 | 2006-12-26 | Reheis, Inc. | Fragrance friendly and cost effective antiperspirant actives and method of making the same |
US7704531B2 (en) | 2005-02-18 | 2010-04-27 | Colgate-Palmolive Company | Enhanced efficacy aluminum or aluminum-zirconium antiperspirant salt compositions containing calcium salt(s) and betaine |
CL2006003116A1 (en) * | 2005-11-16 | 2008-02-29 | Colgate Palmolive Co | ANTI-TRANSPIRING COMPOSITION THAT INCLUDES AT LEAST ONE CHOSEN ALUMINUM SALT, ZIRCONY ALUMINUM, A COMPLEX ALUMINUM SALT OR A COMPLEX ALUMINUM-ZIRCONY SALT, A HYDROXIACIDE AND AN ACID COMPOUND OF QUATERNARY AMMONIUM; PROCESS TO PREPARE |
US7846318B2 (en) * | 2006-01-06 | 2010-12-07 | Nextchem, Llc | Polyaluminum chloride and aluminum chlorohydrate, processes and compositions: high-basicity and ultra high-basicity products |
US8801909B2 (en) * | 2006-01-06 | 2014-08-12 | Nextchem, Llc | Polymetal hydroxychloride processes and compositions: enhanced efficacy antiperspirant salt compositions |
DE102008028821A1 (en) | 2007-06-20 | 2009-01-29 | Henkel Ag & Co. Kgaa | Cosmetic stick based on a thickened oil-in-water dispersion / emulsion |
EP2167017A2 (en) | 2007-06-20 | 2010-03-31 | Henkel AG & Co. KGaA | Cosmetic stick based on a congealed oil-in-water dispersion/emulsion having a hydrogel former |
BRPI0814158A2 (en) | 2007-09-21 | 2015-01-06 | Colgate Palmolive Co | COMPOUND, PROCESS FOR PREPARING A COMPOUND, AND METHOD FOR MANUFACTING AN ACTIVE ZIRCON ALUMINUM AMINO ACID COMPOUND |
US8257689B2 (en) * | 2007-12-12 | 2012-09-04 | Colgate-Palmolive Company | Antiperspirant active compositions having SEC chromatogram exhibiting high SEC peak 4 intensity |
WO2009075678A1 (en) * | 2007-12-12 | 2009-06-18 | Colgate-Palmolive Company | Antiperspirant active compositions having sec chromatogram exhibiting high sec peak 4 intensity |
DE102007063352A1 (en) | 2007-12-28 | 2009-07-02 | Henkel Ag & Co. Kgaa | Anhydrous antiperspirant compositions with improved drug release |
US20090257970A1 (en) * | 2008-03-14 | 2009-10-15 | Ernest Bloom | Antiperspirant compositions containing a copper salt and a penetration enhancer and methods of using the same |
DE102008035013A1 (en) | 2008-07-25 | 2010-01-28 | Henkel Ag & Co. Kgaa | Anhydrous deodorant compositions with improved performance, which are administered as nonaerosol |
DE102008035014A1 (en) | 2008-07-25 | 2010-01-28 | Henkel Ag & Co. Kgaa | Anhydrous deodorant compositions with improved performance, which are applied as a spray |
DE102008064198A1 (en) | 2008-12-22 | 2010-07-01 | Henkel Ag & Co. Kgaa | Transparent antiperspirant gels |
DE102009027052A1 (en) | 2009-06-19 | 2010-12-23 | Henkel Ag & Co. Kgaa | Antiperspirant compositions with silver citrate |
DE102009027604A1 (en) | 2009-07-10 | 2011-01-20 | Henkel Ag & Co. Kgaa | Cosmetic compositions with suspensions of silver salts |
RU2495657C1 (en) * | 2009-08-06 | 2013-10-20 | Колгейт-Палмолив Компани | Method for preparing antiperspirant active compound having sec chromatogram showing high sec peak 4 intensity |
DE102009029423A1 (en) | 2009-09-14 | 2011-03-24 | Henkel Ag & Co. Kgaa | Antibacterial cosmetic or pharmaceutical body odor deodorant compositions against body odor |
US9494268B2 (en) * | 2009-10-21 | 2016-11-15 | Brasscraft Manufacturing Company | Supply stop with connection verification |
US9523454B2 (en) * | 2009-10-21 | 2016-12-20 | Brasscraft Manufacturing Company | Anti-rotation gripper ring |
DE102009055255A1 (en) | 2009-12-23 | 2011-06-30 | Henkel AG & Co. KGaA, 40589 | Anhydrous antiperspirant sprays with improved performance |
US9144695B2 (en) * | 2010-06-01 | 2015-09-29 | Coty Inc. | Antiperspirant compositions |
DE102010038358A1 (en) | 2010-07-23 | 2012-01-26 | Henkel Ag & Co. Kgaa | Double salt antiperspirant roll-ons |
DE102010038357A1 (en) | 2010-07-23 | 2012-01-26 | Henkel Ag & Co. Kgaa | Double salt antiperspirant sticks |
DE102010038356A1 (en) | 2010-07-23 | 2012-01-26 | Henkel Ag & Co. Kgaa | Double salt alcoholic antiperspirants |
BR112013010694A2 (en) | 2010-11-02 | 2016-07-05 | Colgate Palmolive Co | active antiperspirant compositions and their production |
US9463985B2 (en) | 2010-11-02 | 2016-10-11 | Colgate-Palmolive Company | Aluminum salt containing high percentage of Al30 |
DE102010063250A1 (en) | 2010-12-16 | 2012-06-21 | Henkel Ag & Co. Kgaa | Hydrous antiperspirant compositions with improved residue masking |
DE102011002863A1 (en) | 2011-01-19 | 2012-07-19 | Henkel Ag & Co. Kgaa | Antiperspirant sticks with improved long-term stability |
EP2702007B1 (en) | 2011-04-26 | 2018-11-14 | Colgate-Palmolive Company | Antiperspirant active compositions and manufacture thereof |
WO2012148481A1 (en) | 2011-04-26 | 2012-11-01 | Colgate-Palmolive Company | Compositions containing polyhydroxyoxoaluminum cations and manufacture thereof |
DE102011083293A1 (en) | 2011-09-23 | 2013-03-28 | Henkel Ag & Co. Kgaa | Anhydrous formulations with cooling effect |
DE102011083872A1 (en) | 2011-09-30 | 2012-06-21 | Henkel Ag & Co. Kgaa | Sweat-absorbing complex, useful for reducing and/or regulating perspiration and/or body odor, comprises sheet silicate which is modified with quaternary ammonium compound, and oily extract of sprouts of Bambusa vulgaris and lignocellulose |
DE102011086923A1 (en) | 2011-11-23 | 2013-05-23 | Henkel Ag & Co. Kgaa | Deodorising compositions |
DE102011087980A1 (en) | 2011-12-08 | 2012-09-06 | Henkel Kgaa | Cosmetic and non-therapeutic use of platycodin e.g. for influencing natural pigmentation process of hair and its follicles in armpit region, for reducing shaving or epilation frequency, and as active substance in topically applied agents |
DE102011089012A1 (en) | 2011-12-19 | 2013-06-20 | Henkel Ag & Co. Kgaa | Textile-friendly antiperspirants |
DE102011088967A1 (en) | 2011-12-19 | 2013-06-20 | Henkel Ag & Co. Kgaa | Deodorants and antiperspirants with stabilized antioxidant |
DE102012205218A1 (en) | 2012-03-30 | 2013-10-02 | Henkel Ag & Co. Kgaa | Antiperspirant compositions with cycloaliphatic diols and zirconium salts |
DE102012209621A1 (en) | 2012-06-08 | 2013-12-24 | Henkel Ag & Co. Kgaa | Thickened antiperspirant rollons with improved residue behavior |
DE102012223197A1 (en) | 2012-12-14 | 2014-06-18 | Henkel Ag & Co. Kgaa | Anhydrous compositions against body odor |
DE102012224133A1 (en) | 2012-12-21 | 2014-06-26 | Henkel Ag & Co. Kgaa | Textile-friendly nonaerosol antiperspirants with methanesulfonic acid |
DE102012224156A1 (en) | 2012-12-21 | 2014-06-26 | Henkel Ag & Co. Kgaa | Textile-friendly nonaerosol antiperspirants with hydroxycarboxylic acids |
EP2964024B1 (en) * | 2013-03-08 | 2017-10-11 | RiboCor, Inc. | Methods for treating flowering plants with ribose |
DE102013211313A1 (en) | 2013-06-17 | 2014-12-18 | Henkel Ag & Co. Kgaa | Anhydrous compositions against body odor |
DE102013211312A1 (en) | 2013-06-17 | 2014-12-18 | Henkel Ag & Co. Kgaa | Anhydrous compositions |
DE102013220779A1 (en) | 2013-10-15 | 2015-04-16 | Henkel Ag & Co. Kgaa | Antiperspirant cosmetic products containing lactates |
DE102013220782A1 (en) | 2013-10-15 | 2014-04-17 | Henkel Ag & Co. Kgaa | Antiperspirant cosmetic agent comprises cosmetic oils which are liquid at specific temperature and pressure, perfumes or waxes, antiperspirant aluminum salt, and substituted benzoate salt |
DE102013220789A1 (en) | 2013-10-15 | 2015-04-16 | Henkel Ag & Co. Kgaa | Antiperspirant cosmetic products containing aromatic sulfonic acids |
DE102013220786A1 (en) | 2013-10-15 | 2015-04-16 | Henkel Ag & Co. Kgaa | Antiperspirant cosmetic products containing amidosulfonic acids |
DE102013220783A1 (en) | 2013-10-15 | 2015-04-16 | Henkel Ag & Co. Kgaa | Antiperspirant cosmetic products containing alkyl sulfonic acids |
DE102013220770A1 (en) | 2013-10-15 | 2015-04-16 | Henkel Ag & Co. Kgaa | Antiperspirant cosmetic products containing polyphosphoric acids |
DE102013220767A1 (en) | 2013-10-15 | 2015-04-16 | Henkel Ag & Co. Kgaa | Use of polysaccharides in antiperspirant cosmetic agents for textile care |
DE102013220777A1 (en) | 2013-10-15 | 2015-04-16 | Henkel Ag & Co. Kgaa | Antiperspirant cosmetic products with alpha hydroxy acids |
DE102013220771A1 (en) | 2013-10-15 | 2015-04-16 | Henkel Ag & Co. Kgaa | Antiperspirant cosmetic products containing polycarboxylic acids |
DE102013225616A1 (en) | 2013-12-11 | 2015-06-11 | Henkel Ag & Co. Kgaa | Antiperspirant cosmetic products containing lysozyme and / or bovine serum albumin and / or yoghurt protein |
DE102013226812A1 (en) | 2013-12-20 | 2015-06-25 | Henkel Ag & Co. Kgaa | Antiperspirant emulsions with improved adsorption |
DE102014205199A1 (en) | 2014-03-20 | 2014-10-23 | Henkel Ag & Co. Kgaa | Antiperspirant cosmetic compositions containing water-soluble polysaccharides |
US9572758B2 (en) | 2015-06-30 | 2017-02-21 | Gulbrandsen Technologies, Inc. | Method of making high performance activated aluminum sesquichlorohydrate powders |
BR102016026099B1 (en) * | 2015-11-09 | 2021-09-28 | Gulbrandsen Technologies, Inc | ACTIVE ANTI-TRANSPIRING SOLUTION, TOPIC COMPOSITION, AND, METHOD TO REDUCE HUMAN SKIN TRANSPIRATION AND PROVIDE ANTI-BACTERIAL ACTIVITIES |
DE102015225693A1 (en) | 2015-12-17 | 2017-06-22 | Henkel Ag & Co. Kgaa | Propellant-free deodorant and / or antiperspirants with special preservative combinations |
DE102015225687A1 (en) | 2015-12-17 | 2017-06-22 | Henkel Ag & Co. Kgaa | Propellant-free deodorant and / or antiperspirants with at least two different preservatives |
DE102015225958A1 (en) | 2015-12-18 | 2017-06-22 | Henkel Ag & Co. Kgaa | Cosmetic compositions containing a combination of at least two different active ingredients |
DE102015225876A1 (en) | 2015-12-18 | 2017-06-22 | Henkel Ag & Co. Kgaa | "Deodorants containing specific cationic morpholino compounds in combination with certain active substances" |
DE102015225971A1 (en) | 2015-12-18 | 2017-06-22 | Henkel Ag & Co. Kgaa | A method for reducing perspiration-induced body odor using special protein hydrolysates |
DE102015225892A1 (en) | 2015-12-18 | 2016-10-27 | Henkel Ag & Co. Kgaa | Deodorants containing specific cyclic alcohols in combination with certain Deowirkstoffen |
DE102016205332A1 (en) | 2016-03-31 | 2017-10-05 | Henkel Ag & Co. Kgaa | Antiperspirant and / or deodorant cosmetic products with low emulsifier content |
DE102016210037A1 (en) | 2016-06-07 | 2017-12-07 | Henkel Ag & Co. Kgaa | "Highly effective antiperspirants with improved skin tolerance" |
DE102017214799A1 (en) | 2017-08-24 | 2019-02-28 | Henkel Ag & Co. Kgaa | Oil mixture for microemulsions |
DE102017214798A1 (en) | 2017-08-24 | 2019-02-28 | Henkel Ag & Co. Kgaa | Emulsifier system for microemulsions |
DE102017214797A1 (en) | 2017-08-24 | 2019-02-28 | Henkel Ag & Co. Kgaa | Emulsifier system for microemulsions with high skin tolerance |
IT201900004805A1 (en) | 2019-03-29 | 2020-09-29 | Kalichem Srl | ANTIPPIRANT AND DEODORANT COMPOSITIONS |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2814585A (en) | 1954-04-30 | 1957-11-26 | Procter & Gamble | Buffered antiperspirant compositions |
US2854382A (en) | 1957-06-25 | 1958-09-30 | Procter & Gamble | Zirconyl hydroxy chloride antiperspirant compositions |
CA972922A (en) | 1970-07-30 | 1975-08-19 | Raymond E. Bolich (Jr.) | Aluminum-zirconium aerosol antiperspirant composition and process |
US4435382A (en) * | 1980-07-14 | 1984-03-06 | Bristol-Myers Company | Anhydrous alcoholic antiperspirant suspension composition containing certain aluminum or aluminum/zirconium salt glycine complexes |
US4331609A (en) | 1980-09-08 | 1982-05-25 | The Procter & Gamble Company | Antiperspirant composition |
CA1153313A (en) | 1980-12-15 | 1983-09-06 | Chung T. Shin | Antiperspirant composition containing aluminum chlorohydrate, aluminum chloride and an aluminum zirconium polychlorohydrate complex and method of use |
US4774079A (en) * | 1980-12-15 | 1988-09-27 | Bristol-Myers Company | Antiperspirant composition containing aluminum chlorohydrate, aluminum chloride and an aluminum zirconium polychlorohydrate complex and method of use |
US4775528A (en) | 1983-08-16 | 1988-10-04 | The Gillette Company | Antiperspirant composition |
US4871525A (en) | 1986-10-24 | 1989-10-03 | Westwood Chemical Corporation | Antiperspirant composition and method of preparation |
GB8619553D0 (en) | 1986-08-11 | 1986-09-24 | Unilever Plc | Antiperspirants |
US5330751A (en) | 1988-04-14 | 1994-07-19 | The Gilette Company | Antiperspirant and method of making same |
US5348720A (en) * | 1988-08-17 | 1994-09-20 | The Mennen Company | Basic aluminum antiperspirant active material having enhanced activity, antiperspirant active composition containing such material, and methods for preparation of such material and composition |
EP0444564B1 (en) | 1990-02-26 | 1996-01-24 | Somerville Technology Group, Inc. | Direct process for the preparation of activated antiperspirant salts |
JP3439474B2 (en) | 1990-09-07 | 2003-08-25 | リハイス・インコーポレイテッド | Basic aluminum and aluminum / zirconium antiperspirant and process for producing the same |
US5225187A (en) | 1991-02-15 | 1993-07-06 | Somerville Technology Group, Inc. | Process for preparing concentrated aluminum-zirconium solutions |
US5320770A (en) * | 1992-04-27 | 1994-06-14 | Dow Corning Corporation | Electrorheological (ER) fluid based on amino acid containing metal polyoxo-salts |
ZA945542B (en) | 1993-08-10 | 1995-05-26 | Bristol Myers Squibb Co | Novel zirconium salts and their synthesis |
US5534246A (en) * | 1994-08-29 | 1996-07-09 | Helene Curtis, Inc. | Topically-effective compositions |
US5955064A (en) | 1997-10-21 | 1999-09-21 | Westwood Chemical Corporation | Enhanced efficacy stable antiperspirant active solution and method of making same |
US5997850C1 (en) | 1997-10-29 | 2001-11-27 | Colgate Palmolive Co | Antiperspirant actives and formulations made therefrom |
US6042816A (en) * | 1998-08-19 | 2000-03-28 | The Gillette Company | Enhanced antiperspirant salts stabilized with calcium and concentrated aqueous solutions of such salts |
US6126928A (en) | 1999-08-24 | 2000-10-03 | The Procter & Gamble Company | Compositions containing solubilized, acid-enhanced antiperspirant active |
US6451296B1 (en) | 2000-02-01 | 2002-09-17 | Zijun Li | Enhanced efficacy aluminum-zirconium antiperspirants and methods for making |
AR031108A1 (en) * | 2000-06-19 | 2003-09-10 | Colgate Palmolive Co | A METHOD FOR IMPROVING THE ACTIVITY OF AN ALUMINUM OR ALUMINUM / CIRCONIUM SALT CONTAINING SMALL AND LARGE ALUMINUM SPECIES, SALES SO OBTAINED AND ANTI-TRANSPIRING AND / OR DEODORANT PRODUCTS PREPARED WITH SUCH IMPROVED SALTS |
US6375937B1 (en) | 2000-10-20 | 2002-04-23 | Colgate-Palmolive Company | Antiperspirant salts for enhanced cosmetic products |
US6436381B1 (en) | 2000-10-25 | 2002-08-20 | The Gillette Company | Aluminum-zirconium antiperspirant salts with high peak 5 al content |
-
2000
- 2000-10-25 US US09/696,271 patent/US6436381B1/en not_active Expired - Lifetime
-
2001
- 2001-10-24 DE DE60122359T patent/DE60122359T2/en not_active Expired - Lifetime
- 2001-10-24 ES ES01988579T patent/ES2269496T3/en not_active Expired - Lifetime
- 2001-10-24 AU AU2015902A patent/AU2015902A/en not_active Withdrawn
- 2001-10-24 BR BR0114895-8A patent/BR0114895A/en not_active IP Right Cessation
- 2001-10-24 AT AT01988579T patent/ATE336225T1/en not_active IP Right Cessation
- 2001-10-24 MX MXPA03003618A patent/MXPA03003618A/en active IP Right Grant
- 2001-10-24 CA CA002423851A patent/CA2423851C/en not_active Expired - Lifetime
- 2001-10-24 EP EP01988579A patent/EP1330232B1/en not_active Expired - Lifetime
- 2001-10-24 WO PCT/US2001/046112 patent/WO2002034223A2/en active IP Right Grant
-
2002
- 2002-05-03 US US10/138,476 patent/US6649152B2/en not_active Expired - Lifetime
-
2003
- 2003-11-03 US US10/700,026 patent/US6991780B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US6991780B2 (en) | 2006-01-31 |
US20030021757A1 (en) | 2003-01-30 |
WO2002034223A2 (en) | 2002-05-02 |
US6649152B2 (en) | 2003-11-18 |
EP1330232A2 (en) | 2003-07-30 |
ES2269496T3 (en) | 2007-04-01 |
DE60122359D1 (en) | 2006-09-28 |
EP1330232B1 (en) | 2006-08-16 |
US20040136934A1 (en) | 2004-07-15 |
DE60122359T2 (en) | 2007-08-30 |
CA2423851C (en) | 2009-06-23 |
US6436381B1 (en) | 2002-08-20 |
AU2015902A (en) | 2002-05-06 |
MXPA03003618A (en) | 2003-06-19 |
ATE336225T1 (en) | 2006-09-15 |
BR0114895A (en) | 2003-08-12 |
WO2002034223A3 (en) | 2003-04-03 |
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