CA2405736A1 - Ion-sensitive, water-dispersible polymers, a method of making same and items using same - Google Patents
Ion-sensitive, water-dispersible polymers, a method of making same and items using same Download PDFInfo
- Publication number
- CA2405736A1 CA2405736A1 CA002405736A CA2405736A CA2405736A1 CA 2405736 A1 CA2405736 A1 CA 2405736A1 CA 002405736 A CA002405736 A CA 002405736A CA 2405736 A CA2405736 A CA 2405736A CA 2405736 A1 CA2405736 A1 CA 2405736A1
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- mol
- polymer
- ion
- sensitive polymer
- combination
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/22—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
- A61L15/24—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/62—Compostable, hydrosoluble or hydrodegradable materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
Abstract
The present invention is directed to ion-sensitive, water-dispersible polymers. The present invention is also directed to a method of making ion- sensitive, water-dispersible polymers and their applicability as binder compositions. The present invention is further directed to fiber-containing fabrics and webs comprising ion-sensitive, water-dispersible binder compositions and their applicability in water-dispersible personal care products.
Claims (30)
1. An ion-sensitive polymer, wherein the polymer is insoluble in a neutral salt solution containing at least about 0.3 weight percent salt, said salt comprising one or more monovalent or multivalent ions; and wherein the polymer is soluble in tap water containing up to about 500 ppm of one or more multivalent ions.
2. The ion-sensitive polymer of Claim 1, wherein the polymer is insoluble in a neutral salt solution containing at least about 0.3 weight percent salt, said salt comprising one or more monovalent or multivalent ions; and wherein the polymer is soluble in tap water containing from about 15 ppm to about 200 ppm of one or more multivalent ions.
3. The ion-sensitive polymer of Claim 2, wherein the polymer is insoluble in a neutral salt solution containing at least about 0.3 weight percent salt, said salt comprising one or more monovalent or multivalent ions; and wherein the polymer is soluble in tap water containing from about 15 ppm to about 150 ppm of one or more multivalent ions.
4. The ion-sensitive polymer of Claim 3, wherein the polymer is insoluble in a neutral salt solution containing at least about 0.3 weight percent salt, said salt comprising one or more monovalent or multivalent ions; and wherein the polymer is soluble in tap water containing from about 15 ppm to about 100 ppm of one or more multivalent ions.
5. The ion-sensitive polymer of Claim 4, wherein the polymer is insoluble in a neutral salt solution containing at least about 0.3 weight percent salt, said salt comprising one or more monovalent or multivalent ions; and wherein the polymer is soluble in tap water containing from about 15 ppm to about 50 ppm of one or more multivalent ions.
6. The ion-sensitive polymer of Claim 1, wherein the polymer is insoluble in a neutral salt solution containing from about 0.5 weight percent to about 5.0 weight percent of the salt.
7. The ion-sensitive polymer of Claim 1, wherein the polymer is insoluble in a neutral salt solution containing from about 0.5 weight percent to about 3.0 weight percent of the salt.
8. The ion-sensitive polymer of Claim 1, wherein the multivalent ions comprise Ca2+ ions, Mg2+ ions, Zn2+ ions, or a combination thereof.
9. The ion-sensitive polymer of Claim 1, wherein the monovalent ions comprise Na+ ions, Li+ ions, K+ ions, NH4+ ions, or a combination thereof.
10. The ion-sensitive polymer of Claim 1, wherein the polymer is formed from (a) acrylic acid, methacrylic acid, or a combination thereof; (b) 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS), sodium salt of 2-acrylamido-2-methyl-1-propanesulfonic acid (NaAMPS), or a combination thereof; and (c) one or more alkyl acrylates.
11. The ion-sensitive polymer of Claim 10, wherein the polymer is formed from monomers: acrylic acid; AMPS, NaAMPS, or a combination thereof; butyl acrylate; and 2-ethylhexyl acrylate.
12. The ion-sensitive polymer of Claim 11, wherein the polymer is formed from about 35 to about 80 mol% acrylic acid; from greater than 0 to about 20 mol% AMPS, NaAMPS, or a combination thereof; from greater than 0 to about 65 mol% butyl acrylate; and from greater than 0 to about 45 mol%
2-ethylhexyl acrylate.
2-ethylhexyl acrylate.
13. The ion-sensitive polymer of Claim 12, wherein the polymer is formed from about 50 to about 67 mol% acrylic acid; from greater than 0 to about 10 mol% AMPS, NaAMPS, or a combination thereof; from about 15 to about 28 mol% butyl acrylate; and from about 7 to about 15 mol% 2-ethylhexyl acrylate.
14. The ion-sensitive polymer of Claim 13, wherein the polymer is formed from about 57 to less than 66 mol% acrylic acid; from about 1 to about 6 mol% AMPS, NaAMPS, or a combination thereof; from about 15 to about 28 mol% butyl acrylate; and from about 7 to about 13 mol% 2-ethylhexyl acrylate.
15. The ion-sensitive polymer of Claim 14, wherein the polymer is formed from about 60 mol% acrylic acid; about 5 mol% AMPS, NaAMPS, or a combination thereof; about 24.5 mol% butyl acrylate; and about 10.5 mol%
2-ethylhexyl acrylate.
2-ethylhexyl acrylate.
16. A binder composition for binding fibrous material into an integral web, said binder composition comprising the ion-sensitive polymer of Claim 1.
17. A nonwoven fabric comprising fibrous material and a binder material, wherein the binder material comprising the binder composition of Claim 16.
18. An ion-sensitive polymer formed from acrylic acid; AMPS, NaAMPS, or a combination thereof; butyl acrylate; and 2-ethylhexyl acrylate;
wherein the polymer is insoluble in a neutral salt solution containing at least about 0.3 weight percent salt, said salt comprising one or more monovalent or multivalent ions; and wherein the polymer is soluble in tap water containing up to about 500 ppm of one or more multivalent ions.
wherein the polymer is insoluble in a neutral salt solution containing at least about 0.3 weight percent salt, said salt comprising one or more monovalent or multivalent ions; and wherein the polymer is soluble in tap water containing up to about 500 ppm of one or more multivalent ions.
19. The ion-sensitive polymer of Claim 18, wherein the polymer is formed from about 35 to about 80 mol% acrylic acid; from greater than 0 to about 20 mol% AMPS, NaAMPS, or a combination thereof; from greater than 0 to about 65 mol% butyl acrylate; and from greater than 0 to about 45 mol%
2-ethylhexyl acrylate.
2-ethylhexyl acrylate.
20. The ion-sensitive polymer of Claim 19, wherein the polymer is formed from about 50 to about 67 mol% acrylic acid; from greater than 0 to about 10 mol% AMPS, NaAMPS, or a combination thereof; from about 15 to about 28 mol% butyl acrylate; and from about 7 to about 15 mol% 2-ethylhexyl acrylate.
21. The ion-sensitive polymer of Claim 20, wherein the polymer is formed from about 57 to less than 66 mol% acrylic acid; from about 1 to about 6 mol% AMPS, NaAMPS, or a combination thereof; from about 15 to about 28 mol% butyl acrylate; and from about 7 to about 13 mol% 2-ethylhexyl acrylate.
22. The ion-sensitive polymer of Claim 21, wherein the polymer is formed from about 60 mol% acrylic acid; about 5 mol% AMPS, NaAMPS, or a combination thereof; about 24.5 mol% butyl acrylate; and about 10.5 mol%
2-ethylhexyl acrylate.
2-ethylhexyl acrylate.
23. A binder composition for binding fibrous material into an integral web, said binder composition comprising the ion-sensitive polymer of Claim 18.
24. A nonwoven fabric comprising fibrous material and a binder material, wherein the binder material comprising the binder composition of Claim 23.
25. A method of making the ion-sensitive polymer of Claim 1, wherein the method comprises:
forming a hydrophilically/hydrophobically balanced mixture of two or more monomers, wherein at least one monomer contains one or more hydrophilic moieties, and at least one monomer contains one or more hydrophobic moieties; and polymerizing the mixture.
forming a hydrophilically/hydrophobically balanced mixture of two or more monomers, wherein at least one monomer contains one or more hydrophilic moieties, and at least one monomer contains one or more hydrophobic moieties; and polymerizing the mixture.
26. The method of Claim 25, wherein the polymer is formed from about 35 to about 80 mol% acrylic acid; from greater than 0 to about 20 mol%
AMPS, NaAMPS, or a combination thereof; from greater than 0 to about 65 mol% butyl acrylate; and from greater than 0 to about 45 mol% 2-ethylhexyl acrylate.
AMPS, NaAMPS, or a combination thereof; from greater than 0 to about 65 mol% butyl acrylate; and from greater than 0 to about 45 mol% 2-ethylhexyl acrylate.
27. A fibrous substrate comprising:
fibrous material; and a binder composition comprising the ion-sensitive polymer of Claim 12.
fibrous material; and a binder composition comprising the ion-sensitive polymer of Claim 12.
28. A water-dispersible article comprising the fibrous substrate of Claim 27.
29. The water-dispersible article of Claim 28, wherein the water-dispersible article comprises a body-side liner, fluid distribution material, fluid in-take material, absorbent wrap sheet, cover stock, or wet wipe.
30. A wet wipe comprising the fibrous substrate of Claim 27.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/564,449 US6683143B1 (en) | 2000-05-04 | 2000-05-04 | Ion-sensitive, water-dispersible polymers, a method of making same and items using same |
US09/564,449 | 2000-05-04 | ||
PCT/US2001/014331 WO2001083572A1 (en) | 2000-05-04 | 2001-05-03 | Ion-sensitive, water-dispersible polymers, a method of making same and items using same |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2405736A1 true CA2405736A1 (en) | 2001-11-08 |
CA2405736C CA2405736C (en) | 2010-07-20 |
Family
ID=24254520
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2405736A Expired - Fee Related CA2405736C (en) | 2000-05-04 | 2001-05-03 | Ion-sensitive, water-dispersible polymers, a method of making same and items using same |
Country Status (12)
Country | Link |
---|---|
US (1) | US6683143B1 (en) |
EP (1) | EP1280835A1 (en) |
JP (1) | JP5062935B2 (en) |
KR (1) | KR100807892B1 (en) |
CN (1) | CN1187378C (en) |
AR (1) | AR028413A1 (en) |
AU (1) | AU2001259437A1 (en) |
BR (1) | BR0110588A (en) |
CA (1) | CA2405736C (en) |
MX (1) | MXPA02010712A (en) |
TW (1) | TWI233441B (en) |
WO (1) | WO2001083572A1 (en) |
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US10047329B2 (en) | 2013-09-27 | 2018-08-14 | Rohm And Haas Chemicals Llc | Water dispersible films for packaging high water containing formulations |
US10400114B2 (en) | 2013-09-27 | 2019-09-03 | Rohm And Haas Company | Ionic strength triggered disintegration of films and particulates |
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- 2001-05-03 JP JP2001580197A patent/JP5062935B2/en not_active Expired - Fee Related
- 2001-05-03 CN CNB018089755A patent/CN1187378C/en not_active Expired - Fee Related
- 2001-05-03 MX MXPA02010712A patent/MXPA02010712A/en active IP Right Grant
- 2001-05-03 TW TW090110569A patent/TWI233441B/en not_active IP Right Cessation
- 2001-05-04 AR ARP010102131A patent/AR028413A1/en unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10047329B2 (en) | 2013-09-27 | 2018-08-14 | Rohm And Haas Chemicals Llc | Water dispersible films for packaging high water containing formulations |
US10400114B2 (en) | 2013-09-27 | 2019-09-03 | Rohm And Haas Company | Ionic strength triggered disintegration of films and particulates |
Also Published As
Publication number | Publication date |
---|---|
JP5062935B2 (en) | 2012-10-31 |
EP1280835A1 (en) | 2003-02-05 |
CN1444607A (en) | 2003-09-24 |
WO2001083572A1 (en) | 2001-11-08 |
MXPA02010712A (en) | 2003-03-10 |
CN1187378C (en) | 2005-02-02 |
TWI233441B (en) | 2005-06-01 |
CA2405736C (en) | 2010-07-20 |
AU2001259437A1 (en) | 2001-11-12 |
US6683143B1 (en) | 2004-01-27 |
KR20020091268A (en) | 2002-12-05 |
BR0110588A (en) | 2004-02-17 |
AR028413A1 (en) | 2003-05-07 |
JP2003532754A (en) | 2003-11-05 |
KR100807892B1 (en) | 2008-02-27 |
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