CA2401562A1 - Ion exchange membrane fuel cell - Google Patents

Ion exchange membrane fuel cell Download PDF

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Publication number
CA2401562A1
CA2401562A1 CA002401562A CA2401562A CA2401562A1 CA 2401562 A1 CA2401562 A1 CA 2401562A1 CA 002401562 A CA002401562 A CA 002401562A CA 2401562 A CA2401562 A CA 2401562A CA 2401562 A1 CA2401562 A1 CA 2401562A1
Authority
CA
Canada
Prior art keywords
fuel cell
ion exchange
anode
cathode
electrode diffusion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002401562A
Other languages
French (fr)
Inventor
William A. Fuglevand
Peter D. Devries
Greg A. Lloyd
David R. Lott
John P. Scartozzi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Relion Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2401562A1 publication Critical patent/CA2401562A1/en
Abandoned legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0258Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0247Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1004Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/247Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S429/00Chemistry: electrical current producing apparatus, product, and process
    • Y10S429/90Fuel cell including means for power conditioning, e.g. Conversion to ac

Abstract

An ion exchange membrane fuel cell (10) is described and which includes a module (11) enclosing a membrane diffusion electrode assembly (100), which h as an active area defined by a surface area, and which produces an average current density of at least about 350 mA per square centimeter of surface ar ea when supplied with a dilute fuel at a nominal voltage of about 0.5 volts.</S DOAB>

Description

DESCRIPTION
ION EXCHANGE MEMBRANE FUEL CELL
Technical Field s The present invention relates to an ion exchange membrane fuel cell, and more specifically, to an ion exchange membrane fuel cell module which is incorporated into a fuel cell power system.
Background Art to The operation of fuel cells are well known. A fuel cell generates electricity from a fuel source, such as hydrogen gas, and an oxidant such as oxygen or air. The chemical reaction does not result in a burning of the fuel to produce heat energy, therefore, the thermodynamic limits on the efficiency of such a reaction are much greater than conventional power generation Is processes. In a proton exchange membrane fuel cell, the fuel gas (hydrogen) is ionized on one electrode and the hydrogen ions diffuse across the membrane to recombine with oxygen ions on the cathode. The byproduct of the reaction is water and the production of an electrical current.
In our application Serial No. 08/979,853, now U.S. Patent No.
20 6,030,718, the inventors disclosed a new and novel proton exchange membrane fuel cell power system which includes a plurality of discrete fuel cell modules which are self-humidifying and which offer a degree of reliability, ease of maintenance and other advantages not known heretofore with respect to fuel cell designs which have been primarily directed to stack-type arrangements.
2s The teachings of this earlier patent are incorporated by reference herein.
While the modular fuel cell disclosed in the earlier patent referenced above operates with a great deal of success, the inventors have endeavored to improve upon this inventive concept by focusing further investigation on increasing the performance, versatility, and the range of the operational 3o parameters of fuel cells of this general design.
Accordingly, an ion exchange membrane fuel cell which achieves the benefits to be derived from the aforementioned technology, but which avoids ..
the detriments individually associated with stack type fuel cell designs is the subject matter of the present invention.
Summary of the Invention s One aspect of the present invention is to provide an ion exchange membrane fuel cell having multiple modules each enclosing ~ a membrane electrode diffusion assembly, and wherein at least one of the modules can be easily removed from the ion exchange membrane fuel cell, by hand, while the remaining modules continue to operate.
to Another aspect of the present invention is to provide an ion exchange membrane fuel cell having a module enclosing a membrane electrode diffusion assembly which has an active area defined by a surface area, and which produces an average current density of at least about 350 mA per square centimeter of surface area when supplied with a dilute fuel at a Is nominal voltage of about 0.5 volts.
Another aspect of the present invention is to provide an ion exchange membrane fuel cell power system having a plurality of discrete ion exchange membrane fuel cell modules which can be manipulated by hand, and which further produce a given amount of heat energy, and wherein each of the ao discrete ion exchange membrane fuel cell modules have an anode heat sink which removes a preponderance of the heat energy generated by the respective ion exchange membrane fuel cell modules.
Yet further, another aspect of the present invention is to provide an ion exchange membrane fuel cell power system which has an ion exchange as membrane fuel cell module which produces heat energy and which has a bifurcated air flow which regulates the operational temperature of the ion exchange membrane fuel cell module by removing the heat energy therefrom.
Yet another aspect of the present invention relates to an ion exchange membrane fuel cell module having a pair of membrane electrode diffusion 3o assemblies disposed in spaced relation, one to the other, and wherein each membrane electrode diffusion assembly has an anode ide, and an opposite cathode side, and wherein the cathode side of each of the membrane electrode diffusion assemblies are proximally related, and the anode sides are distally related, and wherein each cathode side defines, in part, a bifurcated cathode air passageway.
Another aspect of the present invention relates to an ion exchange s membrane fuel cell module having a pair of membrane electrode diffusion assemblies each having opposite anode and cathode sides, and wherein anode and cathode current collectors are electrically coupled with the opposite anode and cathode sides; a support member disposed between the pair of membrane electrode diffusion assemblies, and wherein the cathode side of to each membrane electrode diffusion assembly faces in the direction of the support member; a cathode air passageway defined between the support member and the cathode side of each of the membrane electrode diffusion assemblies; a fuel distribution assembly coupled in fluid flowing relation relative to the anode side of each membrane diffusion assembly; and an Is anode heat sink oriented in heat receiving relation relative to the anode side of each membrane electrode diffusion assembly to facilitate the removal of a preponderance of the heat energy generated by each membrane electrode diffusion assembly.
These and other aspects of the present invention will be discussed in ~o further detail hereinafter.
Brief Description of the Drawings Preferred embodiments of the invention are described below with reference to the following accompanying drawings.
2s Fig. 1 is a perspective, side elevation view of an ion exchange membrane fuel cell module of the present invention.
Fig. 2 is a perspective, exploded, side elevation view of an ion exchange membrane fuel cell module of the present invention.
Fig. 3 is a perspective, partial, exploded, side elevation view of an ion 3o exchange membrane fuel cell module of the present invention.
Fig. 4 is a partial, transverse, vertical sectional view of a cathode current collector, and which is taken from a position along line 4-4 of Fig.
3.
Fig. 5 is a fragmentary, side elevation view of a current conductor s assembly employed with the ion exchange membrane fuel cell module of the present invention.
Fig. 6 is a fragmentary, perspective, greatly enlarged, exploded view of a membrane electrode diffusion assembly employed with the ion exchange membrane fuel cell module of the present invention.
to Fig. 7 is a fragmentary, side elevational view of a fuel distribution assembly utilized with the ion exchange membrane fuel cell module of the present invention.
Fig. 8 is a second, fragmentary, side elevational view of the fuel distribution assembly taken from a position opposite to that seen in Fig 7.
Is Fig. 9 is a second, perspective, partial, exploded view of a portion of the ion exchange membrane fuel cell module of the present invention.
Fig. 10 is a transverse vertical sectional view taken from a position along line 10-10 of Fig. 1.
Fig. 11 is a perspective view of an ion exchange membrane fuel cell ao power system of the present invention.
Fig. 12 is a fragmentary, transverse, vertical sectional view taken from a position along line 12-12 of Fig. 11.
Fig. 13 is a fragmentary, schematic representation of an ion exchange membrane fuel cell module, and associated power systems of the present as invention.
Best Modes for Carryin~ Out the Invention and Disclosure of Invention This disclosure of the invention is submitted in furtherance of the constitutional purposes of the U.S. Patent Laws "to promote the progress of 3o science and useful arts" (Article 1, Section 8).
The ion exchange membrane fuel cell of the present invention is generally indicated by the numeral 10 in Fig. 1. As shown therein, the ion exchange membrane fuel cell comprises a hand manipulatable module 11 which has a forward edge 12, an opposite, rearward edge 13, top and bottom surfaces or edges 14 and 15, and opposite sidewalls generally indicated by the numeral 16. Each facet of the module 11 will be discussed in greater detail s hereinafter.
As best seen in Figs. 2 and 3, the module 11 includes a nonconductive, dielectric support member generally indicated by the numeral 20. The support member can be fashioned out of various synthetic polymeric substrates. The support member has a main body 21, which is defined by a to forward peripheral edge 22; a rearward peripheral edge 23; a top peripheral edge 24; an opposite, bottom peripheral edge 25; and opposite sidewalls generally indicated by the numeral 26. As best seen in Fig. 2, a pair of recessed channels 30 are formed in the forward peripheral edge 22. Further, a plurality of fastener receiving passageways 31 are also formed in the Is forward peripheral edge. Yet further, and as seen in Fig. 3, a plurality of spaced ribs 32 are borne by, or made integral with the respective sidewalls 26 and are disposed in spaced relation, one to the other. Fastener passageways or apertures 33 are formed through each of the ribs. Further, cavities 34 are defined between the respective ribs 32 on each sidewall. The 2o cavities 34 formed on each of the sidewalls are disposed in substantially opposed relation one to the other. This is seen in Fig. 3. Further, as best seen in Fig. 3, a pair of orientation members 35 are disposed between each of the ribs 32 and define a space therebetween. A pair of mounting tabs 36 are mounted in spaced relationship, one to the other, on the rearward 2s peripheral edge 23 of the main body 21. A pair of substantially coaxially aligned apertures 37 are individually formed in each of the mounting tabs 36 and are operable to receive a fastener therethrough. This aspect of the invention will be discussed in further detail hereinafter.
A fuel coupling 40 is made integral with or forms a portion of the 3o rearward peripheral edge 23 of the support member 20. The fuel coupling 40 includes a fuel delivery passageway 41 which is substantially T shaped and which is defined by an intake end 42 and a pair of exhaust ends labeled 43.

Additionally, the fuel coupling also includes an exhaust passageway 44 which is also substantially T shaped and which is defined by a pair of intake ends 45, and an exhaust end 46. The operation of the fuel coupling 40 will be discussed in greater detail hereinafter.
s As best seen in Figs. 2 and 3, individual conductor plates generally designated by the numeral 50 are matingly received within the individual cavities 34 which are defined by the support member 20. The conductor plates which are fabricated from an electrically conductive substrate, have a substantially planar main body 51, which has a first end 52, and an opposite, to second end 53. The main body 51 further has a conductive tab 54 which extends outwardly relative to the first end 52, and which is oriented between the individual orientation members 35. The conductive tab extends substantially normally outwardly relative to the top peripheral edge 24 of the support member 20. As will be recognized, the main body 51 matingly rests is between the individual ribs 32 which define, in part, the respective cavities 34.
As best seen in the exploded view of Fig. 3, a cathode current collector is generally designated by the numeral 60, and rests in ohmic electrical contact with the main body 51 of the individual conductor plates 20 50. The cathode current collector, which is fabricated from an electrically conductive substrate, has a main body 61 which has opposite first and second ends 62 and 63, respectively. The cathode current collector simultaneously performs the functions of current collection, force application and heat dissipation. These functional aspects of the current collector will be discussed 2s in greater detail hereinafter. Still further, the main body 61 of the current collector 60 is defined by a peripheral edge 64. As seen in the cross sectional view of Fig. 4, the main body 61 of the cathode current collector 60 defines a channel shaped member. The main body also has a first surface 65 which rests in ohmic electrical contact against the main body 51 of the 3o underlying conductor plate 50, and an opposite second surface 66. Still further, a plurality of elastically deformable electrically conductive members 70 are formed in the main body 61 and extend downwardly from the second surface. It should be understood that each of the deformable electrically conductive members 70 have a cathode engagement surface 71, which rests in ohmic electrical contact against an adjacent cathode which will be discussed in greater detail hereinafter. However, it will be appreciated from s this discussion that the conductive members 70 and the cathode engagement surfaces 71 operate to provide both current collection and a force application element. Still further, the fabrication of the deformable members 70 defines individual apertures 72 in the main body 61. Yet further, a space 73 is defined between the elastically deformable electrically conductive members 70, to and the second surface 66, of the main body 61. This physical arrangement of the cathode current collector 60 will be discussed in greater detail hereinafter.
As best seen by reference to Fig. 4, which shows a greatly exaggerated view of one of the deformable electrically conductive members 70, it will be is seen that the cathode current collector 60 comprises an electrically and thermally conductive metallic composite substrate having a plurality of layers.
In this regard, the cathode current collector has a first layer fabricated from a suitable electrically conductive substrate such as stainless steel 74. This layer 74 has a thickness dimension of about 20/1000 to about 40/1000 inches.
2o Yet further, and resting on the exposed surface of the stainless steel layer 74, are individual first and second layers of nickel 76A and 76B respectively.
The respective layers of nickel have an average thickness of about 0.1/1000 to about 1.0/1000 inches.
As should be understood, while a conductor plate 50 and cathode as current collector 60 are shown in combination, it is possible to fabricate a cathode current collector 60 having a conductive tab similar to the conductive tab 54 which is made integral with the conductor plate 50. This would eliminate the necessity for the individual conductor plates 50.
As best seen in Figs. 3 and 5, a current conductor assembly or circuit 3o board is generally designated by the numeral 80. This current conductor assembly, in operation, rests on, and is releasably secured to, the top peripheral edge 24 of the support member 20, and further matingly fits g between the mounting tabs 36 which are mounted on the rearward peripheral edge 23 of the support member 20 (Fig. 1). The current conductor assembly or circuit board 80 has a main body 81 which is fabricated from a substrate upon which it is possible to conduct soldering operations. Formed on the s main body 81 are a number of conductive tracings (not shown) which are thereafter covered by a dielectric substance. The main body 81 also has a first end 82, and an opposite second end 83. Further, an engagement member 84 is mounted on the first end 82 and is operable to matingly couple with the handle assembly which will be discussed in greater detail hereinafter.
to Yet further, a plurality of electrical contacts 85 are mounted on, or made integral with the second end 83, and are electrically coupled with the numerous electrical tracings (not shown) which are laid out along the main body 81 of the current conductor assembly 80. As seen in Fig. 5, an aperture 90 is formed in the main body 81, and is operable to be coaxially Is aligned with the apertures 37, which are individually formed in the pair of mounting tabs 36. When coaxially aligned, the respective apertures receive a fastener which releasably secures the current conductor assembly on the top peripheral edge 24 of the support member 20. An alignment or engagement member 91 is fastened or borne on the second end 82, and is operable to ao releasably engage a subrack which will be discussed, below. Further, a plurality of conductive areas 92 and 93 are formed along the main body.
The conductive areas 92 are disposed in ohmic electrical contact with the conductor plates 50 when the ion exchange membrane fuel cell module is assembled. Further, anode current collectors are disposed in ohmic electrical 2s contact with the conductive areas 93. The anode current collectors will also be discussed in greater detail hereinafter. It should be understood that the current conductor assembly 80 couples each of the individual cavities 34 in serial electrical contact one with the other.
As best seen in the exploded view of Figs. 6 and 9, the ion exchange 3o membrane fuel cell module 11 includes a plurality of membrane electrode diffusion assemblies generally indicated by the numeral 100. Each of the membrane electrode diffusion assemblies have an anode side 101, and an opposite cathode side 102. Still further, each of the membrane electrode diffusion assemblies is defined by a peripheral edge 103, and further has formed in its anode side, a plurality of interlinking channels 104. The membrane electrode diffusion assembly 100, as noted above, is formed of a s solid ion conducting membrane 105 which is sealably mounted or received in each of the respective cavities 34. In this arrangement, the cathode side 102 of each membrane electrode diffusion assembly is held in spaced relation relative to the support member 20 by means of the deformable electrically conductive members 70 of the cathode current collector 60. This spacial to arrangement, which is provided by the cathode current collector, facilitates, in part heat dissipation from the module 11. This will be discussed in greater detail below. As described, above, the membrane electrode diffusion assembly 100; associated cathode current collector 60; and support member 20 in combination, define a cathode air passageway 106 therebetween (Figs.
Is 10 and 13). The construction of a suitable membrane electrode diffusion assembly was described in our U.S. Patent Application Serial No. 08/979,853, which was filed on 11/20/97, and which is now U.S. Patent No. 6,030,718.
This earlier patent is incorporated by reference herein, and further discussion regarding the construction of the membrane electrode diffusion assembly is ao not undertaken herein.
As will be appreciated, from a study of Fig. 13, the cathode air passageway 106 is defined or otherwise oriented on each side 26 of the support member 20. Therefore, the module 11 has a bifurcated cathode air flow. This will also be discussed in greater detail hereinafter. As will be 2s appreciated, while the earlier described membrane electrode diffusion assembly was directed to a proton exchange membrane, this invention is not limited solely to proton exchange membranes, but also may utilize anion exchange membranes.
As best seen by reference to Figs. 7 and 9, a fuel distribution 3o assembly, generally indicated by the numeral 110, is coupled in fluid flowing relation relative to the anode side 101 of each of the membrane electrode diffusion assemblies 100. Each fuel distribution assembly 110 is coupled with a source of a fuel 340 which may be substantially pure, or which is diluted to various degrees. If fabricated in the nature of a proton exchange membrane fuel cell, the dilute fuel supply would include hydrogen. The concentration of the hydrogen in the dilute fuel would be in a range of about s 30% to about 80% by volume. When supplied with this dilute fuel mixture (regardless of the type), the ion exchange membrane fuel cell 10 produces an average current density of at least about 350 mA per square centimeter of surface area of the anode side 101 at a nominal voltage of 0.5 volts.
Further, the interlinking channels 104 formed in the surface of the anode to side 101 facilitate the distribution of the dilute fuel substantially about the entire surface area of the anode side 101. In this arrangement, if contaminants are introduced by way of the dilute fuel mixture or other blockage occurs, the interlinking channels 104 provide a convenient means by which the fuel may reach substantially the entire surface area of the anode Is side 101, even though some portions of the interlinking channels 104 may be blocked or otherwise substantially occluded. The dilute fuel 340 may be supplied by means of a reactor 342 which receives a hydrocarbon based fuel, and then through a chemical reaction fractionates the hydrocarbon source to liberate a dilute stream of hydrogen which is mixed with other substances.
2o In the alternative, the fuel may be supplied by a pressurized container 341.
These alternative arrangements are shown in Fig. 11 and will be discussed in greater detail hereinafter.
As best seen by reference to the exploded view as shown in Fig. 9 and Fig. 1, the ion exchange membrane fuel cell 10 of the present invention 2s includes a pair of fuel distribution assemblies 110 which are individually mounted in fluid flowing relation relative to the anode side 101 of the respective membrane electrode diffusion assemblies 100. As best seen in Figs. 7 and 8, each of the fuel distribution assemblies 110 include a main body 111 which has an inside facing surface 112, (Fig. 8) and an outside 3o facing surface 113 (Fig. 7). The main body 111 further defines an intake plenum 114, and an exhaust plenum 115. Further, a fluid coupling 116 (Fig.
1) is mounted in fluid flowing relation relative to the individual intake and exhaust plenums 114 and 115 respectively. A reduced dimension orifice 114A
is formed in the main body and communicates with the intake plenum. This reduced diameter orifice operates to create a pressure differential in the respective apertures or cavities 120 during certain operational conditions to s facilitate the clearance of contaminants or other obstructions which may be blocking any of the channels 104 which are formed in the membrane electrode diffusion assembly 100. A plurality of cavities or apertures 120 are formed in the main body 111, and extend between the inside and outside facing surfaces 112 and 113 respectively. The cavities or apertures 120 are to disposed in spaced relation, one to the other, and when assembled, the cavities 120 receive the individual membrane electrode diffusion assemblies 100. As best seen in Fig. 7, a plurality of channels or passageways 121 are formed in the main body 111, and couple the individual cavities 120 in fluid flowing relation with the respective intake and exhaust plenums 114 and 115.
Is Additionally, a plurality of fastener apertures 109 are formed in the main body. As further seen in Fig. 9, a sealing member 122 lies in covering relation relative to the individual channels 121.
As best seen in Fig. 1, a plurality of conduits 150 couple in fluid flowing relation the fuel coupling 40 with the fuel distribution assembly 110.
ao Two of the conduits designated as 151 allow a dilute fuel mixture to be delivered by way of the intake plenum 114 to the individual membrane electrode diffusion assemblies 100. Thereafter, any remaining fuel, and associated by-products of the chemical reaction are received back into the exhaust plenum 115 and then flow by way of conduits 152 to the fuel ~s coupling 40 and then to the exhaust passageway 44.
First and second pressure sensitive adhesive seals 123 and 124, respectively are provided, and are disposed in juxtaposed relation relative to the opposite inside and outside facing surfaces 112 and 113 respectively.
Each of the seals 123 and 124 have apertures 125 formed therein which are 3o substantially coaxially oriented relative to the respective cavities 120.
As will be recognized, the cavities 120 which are formed in the main body 111 of the fuel distribution assembly 110, matingly cooperate and are substantially coaxially aligned with the individual cavities 34 which are formed in the nonconductive support plate 20. As will be recognized and following the assembly of same, the respective membrane electrode diffusion assemblies 100 are individually received in mating relation in each of the cavities 120 and s 34 which are defined by both the fuel distribution assembly 110, and the support member 20. Further, a plurality of fastener apertures 126 are formed in the individual seals 123, and 124, and are operable to receive fasteners which will be discussed in greater detail hereinafter.
Lying in immediate juxtaposed relation relative to the second pressure to sensitive adhesive seal 124 is an anode current collector which is generally designated by the numeral 140. Additionally, and as seen in Fig. 9, a substantially rigid sealing plate 130 is provided and which is juxtaposed relative to the cathode side 102 of the membrane diffusion assembly 100.
The sealing plate 130 has a main body 131 which defines a plurality of Is apertures 132 which matingly receive, in part, the respective membrane electrode diffusion assemblies 100. Still further, the main body has a plurality of fastener apertures 133 formed therein and which when assembled, are substantially coaxially aligned with the aforementioned fastener apertures formed in the earlier described portions of the fuel cell module 11. Each ao anode current collector lies in ohmic electrical contact thereagainst the anode side 101 of each of the membrane electrode diffusion assemblies 100 and further is oriented in heat receiving relation relative thereto. The anode current collector 140 has an electrically conductive main body 141 (which may be fabricated from nickel, or a nickel coated copper) and which has an inside 2s facing surface 142 which lies against the anode side 101 of the membrane electrode diffusion assembly 100, and an opposite outside facing surface 143.
Still further, a plurality of fastener apertures 144 are formed in the main body and are operable to be substantially coaxially aligned relative to the other fastener apertures 126 formed in the various seals 123, 124, and in the 3o fuel distribution assembly 110. Further, the main body 141 has a plurality of electrical contact members 145 which are operable, when assembled, to make ohmic electrical contact with the conductive areas 93 which are formed along the main body 81 of the current conductor assembly 80. This is best seen in Fig. 10.
As seen in Fig. 9, an electrically insulative member or gasket 160 is mounted or oriented in juxtaposed relation relative to the outside facing s surface 143, of the anode current collector 140. This insulative member has a main body 161 which has an inside facing surface 162 which rests in contact with the outside facing surface 143 of the anode current collector, and further has an outside facing surface 163. Further, a plurality of fastener apertures 164 are operable to be coaxially aligned with the previously to described fastener apertures formed in the remaining parts of the ion exchange membrane fuel cell 10.
As best seen in Figs. 9 and 10, an anode heat sink 170 is oriented in juxtaposed relation relative to the insulative member 160, and further, is mounted in heat receiving relation relative to the anode sides 101 of each of Is the membrane electrode diffusion assemblies 100 to conduct heat energy generated by the ion exchange membrane module 11 away from the membrane electrode diffusion assembly 100. In this arrangement, the fuel distribution assembly 110 is located substantially between the anode side 101 of the membrane electrode diffusion assembly 100, and the anode current ao collector 140. The anode heat sink 170 has a main body 171 which has an inside facing surface 172, which lies in juxtaposed relation relative to the insulative member 160, and an opposite outside facing surface 173. Similarly, and as discussed above, numerous fastener apertures 174 are formed therein, and which are substantially coaxially aligned with the remaining fastener as apertures which are formed in the earlier disclosed portions of the ion exchange membrane fuel cell module 11. Fasteners 175 are provided and are received in these coaxially aligned fastener apertures such that the module is held firmly together. These fasteners 175 along with the respective current collectors 60 create pressure sufficient to allow the individual current 3o collectors 60 and 140 to make effective ohmic electrical contact with the anode and cathode sides 101 and 102 respectively of the membrane electrode diffusion assembly 100. As will be recognized from the discussion above, the anode current collector 140 is substantially electrically isolated from the anode heat sink 170. Additionally, the anode heat sink has sufficient thermal conductivity such that it substantially inhibits the formation of a temperature gradient across the membrane electrode diffusion assembly 100 during s operation of the ion exchange membrane fuel cell 10.
A handle assembly is generally indicated by the numeral 190 and is best seen in Fig. 2. As shown therein, the handle assembly 190 has a back plate generally indicated by the numeral 191, and which is defined by a front surface 192, and an opposite rear surface 193. Formed through the front and to rear surfaces is an aperture 194 which matingly receives the member 84 which is mounted on the main body 81 of the current conductor assembly 80. Still further, a pair of handles 195 are fastened on the front surface 192, and additionally, a plurality of fastening apertures 196 are formed through the front and rear surfaces 192 and 193 and are operable to receive fasteners 197 Is which threadably engage the fastener apertures 31, which are formed in the forward edge 23 of the support member 20. The handles permit the module 11 to be easily manipulated by hand, and removed without the use of any tools, when utilized with a subrack which will be discussed in greater detail hereinafter.
2o Referring more specifically now to Figs. 11 and 12, an ion exchange membrane fuel cell power system is shown and which includes a subrack generally indicated by the numeral 210. This subrack releasably supports a plurality of ion exchange membrane fuel cell modules 11 in an operable arrangement. The subrack 210 includes a principal enclosure 211. The .
as principal enclosure is defined by a top surface 212; bottom surface 213;
front sidewall 214; rear sidewall 215; left sidewall 216, and right sidewall 217.
The respective sidewalk 212 through 217 define an internal cavity 220. In this arrangement, the principal enclosure will receive multiple modules 11, each enclosing a membrane electrode diffusion assembly 100. As seen in Fig 11, 3o the ion exchange membrane fuel cell power system is configured in a manner where at least one of the modules 11 can be easily removed from the ion exchange membrane fuel cell power system by hand, while the remaining modules continue to operate. As noted above this removal is normally accomplished without the use of any tools, however it may be neccessary in some commercial or industrial applications where vibration, and other outside physical forces may be imparted to the system, to use threaded fasteners and s the like to releasably secure the individual modules to the subrack to prevent the unintentional displacement or dislocation of the respective modules from the subrack.- If utilzed, the hand tools which will be employed will be simple hand tools, and the removal will be accomplished in minutes, as opposed the prior .art stack arrangements where replacement of a damaged membrane to electrode assembly (MEA) may take hours to accomplish.
As best seen by reference to Fig. 12, an aperture 230 is formed in the top surface 12 of the subrack 210, and further, the cavity 220 is comprised of a first or fuel cell module cavity 231, and a second cavity or electrical control bay 232. As best seen by reference to Fig. 11, a plurality of Is individual module apertures 233 are formed in the front surface 214 of the principal housing 211, and are operable to individually receive the respective fuel cell modules 11, and position them in predetermined spaced relation, one to the other. The fuel cell module cavity 231 is further defined by a supporting member or shelf 234 which orients the individual fuel cell modules zo 11 in a predetermined substantially upright orientation within the cavity 231.
Additionally, the fuel cell module cavity 231 is defined by a rear wall 235 which supports a DC bus 236 in an orientation which will allow it to releasably, matingly, electrically couple with the current conductor assembly 80 which is borne by the fuel cell module 11. Yet further, and as seen in 2s the cross sectional view of Fig. 12, the rear wall 234 further supports a fuel supply line 237 and a byproduct removal line 238. These are operable to be releasably coupled in fluid flowing relation with respect to the fuel delivery passageway 41 and the exhaust passageway 44 of the fuel coupling 40. As best seen in Fig. 12, the second cavity or electrical control bay '232 encloses 3o a digital or analog controller 250 which is electrically coupled with the respective ion exchange membrane fuel cell modules 11, and a power conditioning assembly 260 which is electrically coupled with the DC bus 236, and the controller 250, and which is operable to receive the electrical power produced by the ion exchange membrane fuel cell modules 11. The operation of the controller and power conditioning assembly and related control circuitry is discussed in our prior U.S. Application Serial Nos.
s' 09/108,667 and 09/322,666, which are incorporated by reference herein, and are not discussed in further detail in this application. As further seen in Fig.
12, an aperture 270 is formed in the rear wall 215 of the principal enclosure 211, and is operable to receive an air filter 271 which is operable to remove particulate matter from an outside ambient air stream passing therethrough to and into the principal enclosure 211.
As best seen by the cross sectional view in Fig. 12, the subrack 210 includes an air distribution plenum which is coupled in fluid flowing relation relative to each of the ion exchange membrane fuel cell modules 11. The air distribution plenum 290 has a first or intake end 291 which receives both Is air which has previously come into contact with each of the ion exchange fuel cell modules 11, and air which comes from outside of the respective ion exchange membrane fuel cell modules. Further, the air distribution plenum has a second or exhaust end 292 which delivers an air stream to each of the ion exchange fuel cell modules 11. Disposed intermediate the first or intake 2o end 291, and the second or exhaust end 292 is an air mixing valve 293 which is coupled to the air distribution plenum 290, and which meters the amount of air which is passed through the respective ion exchange membrane fuel cell modules 11 and is recirculated back to the ion exchange fuel cell membrane modules and by way of the air filter 271. As illustrated the as mixing valve 293 selectively occludes an aperture 294 which is formed in the rear wall 215 of the subrack 210. An air movement assembly such as a fan 295 is provided and is mounted along the air distribution plenum 290. As shown in Fig. 12, the air movement assembly is positioned near the intake end 291, and is substantially coaxially aligned with the aperture 230 which is 3o formed in the top surface 212 of the subrack 210. The air mixing valve and the fan assembly 293 and 295 respectively are electrically coupled with the controller 250 and are controlled thereby. The air mixing valve 293 comprises a pivotally movable valve member 296 which can be moved from a first occluding position 297 relative to the aperture 294, and a second, substantially non-occluding position 298 as shown in phantom lines. As will be recognized when the valve member 296 is in the second non-occluding s position, air received in the intake end 291 and which has previously passed through the individual fuel cell modules will pass out of the principal enclosure 211 and then be exhausted to the ambient environment. On the other hand, when the valve member 296 is in the occluding position 297 air from the intake end 291 which has passed through the fuel cell module 11 to will return to the exhaust end and then pass through the modules 11 and return again to the intake end. As will be recognized by controlling the relative position of the valve member 296, temperature as well as relative humidity of the air stream 299 can be easily controlled. Still further, in the occluding position 297, air from the ambient will continue to enter the air Is distribution plenum by means of the air filter 270.
More specifically, the air stream 299 which is supplied to the fuel cell modules is provided in an amount of at least about 5 to about 1000 times the volume required to support a fuel cell chemical relation which produces water vapor as a byproduct. The present air plenum arrangement provides zo a convenient means by which the air stream delivered to the cathode side can be humidified by the water vapor generated as a byproduct of the chemical reaction taking place on the cathode. Additionally, during cold operating conditions, this same air, which has now been heated by each of the fuel cell modules 11, will contribute to bringing the entire fuel cell up as to normal operating temperatures. Further, the air mixing valve 293 limits the amount of air which has previously passed through the modules 11 and which is added to the air distribution plenum 290. This resulting recirculated air stream and fresh ambient air forms an air stream having substantially optimal operating characteristics which maximizes the current densities and 30 outputs of the respective membrane electrode diffusion assemblies enclosed within each of the modules 11.

Referring now to Fig. 13, what is shown is a greatly simplified, exaggerated, partial, and cross-sectional view of an ion exchange membrane fuel cell module 11 positioned in an operational relationship relative to the air distribution plenum 290. This particular sectional view, which does not s include many of the subassemblies previously discussed, is provided to illustrate the principals that will be set forth below. As seen in Figs. 12 and 13, and as discussed above, the subrack 210 includes an air distribution plenum 290 which provides a stream of air 299 to each of the ion exchange fuel cell modules 11 which are received in an operational position on the to shelf or supporting member 234. The air stream 299 exists from the exhaust end 292 and then becomes a bifurcated air flow which is generally indicated by the numeral 320. The bifurcated air flow 322 comprises a first cathode air stream 321, which is received in the respective ion exchange membrane fuel cell modules 11; and a second anode heat sink air stream which is Is generally indicated by the numeral 322. As will be recognized by a study of Fig. 13, the first cathode air stream 321 enters the ion exchange membrane fuel cell module 11, and is further bifurcated into a first component 323 which moves along one of the cathode air passageways 106 which is defined on one side of the support member 20. Further, the first cathode air stream 20 321 has a second component 324 which passes along the cathode air passageway 106 on the opposite side of the support member 20. As will be appreciated, the bifurcated cathode air stream 321 provides the necessary oxidant (oxygen in the ambient air stream) to the cathode side 102 of the membrane electrode diffusion assembly 100. Yet further, the cathode air flow 2s operates to remove less than a preponderance of the heat energy generated by the membrane electrode diffusion assembly 100 while it is in operation.
As will be recognized the cathode air flow is facilitated by the respective cathode current collectors 60 which create in part, the cathode air passageway 106. The anode heat sink air stream 322 is further bifurcated into a first 3o component 325 and a second component 326, both of which individually move along the opposite sides 16 of the ion exchange membrane fuel cell module 11, and over each of the anode heat sinks 170. As the anode heat sink air stream components 325 and 326 move over the opposite anode heat sinks 170, the anode heat sink air stream operates to remove a preponderance of the heat energy generated by the ion exchange membrane fuel cell module 11 during operation. Therefore, it will be recognized that the present s invention provides an ion exchange fuel cell module 11 which has a bifurcated air flow 320 which regulates the operational temperature of the ion exchange membrane fuel cell module by removing the heat energy generated therefrom.
Referring now to Fig. 11, and as earlier discussed, the individual ion to exchange membrane fuel cell modules 11 and the subrack 210 comprise in combination a fuel cell power system which is coupled in fluid flowing relation relative to a source of a substantially pure or dilute fuel generally indicated by the numeral 340. The fuel gas supply may comprise a source of bottled and compressed fuel gas generally indicated by the numeral 341, Is or a fuel stream which is provided by a chemical reactor, or reformer 342 which produces the fuel stream for use by the individual ion exchange fuel cell modules 11. A conduit 343 would couple either fuel gas supply 340 with the respective ion exchange fuel cell modules 11 and the associated subrack 210. When a chemical reformer 342 is provided, the reformer would receive 2o a suitable hydrocarbon stream such as natural gas, propane, butane, and other fuel gases and would thereafter, through a chemical reaction release a fuel stream which would then be delivered by way of the conduits 343. The present apparatus 10 may also include a fuel gas recovery and recycling system (not shown) which would recover or recapture unreacted fuel gas 2s which has previously passed through the individual ion exchange fuel cell modules 11. This system, in summary, would separate the unreacted fuel gas and would return the unreacted fuel gas back to the individual ion exchange fuel cell modules for further use. This recovery system would be coupled with the byproduct removal line 238. The operation of the described 3o embodiment of the present invention is believed to be readily apparent and is briefly summarized at this point.

In its broadest aspect, the present invention comprises an ion exchange membrane fuel cell which includes multiple modules 11 each enclosing a membrane electrode diffusion assembly 100, and wherein at least one of the modules 11 can be easily removed from the ion exchange membrane fuel cell, s by hand, while the remaining modules continue to operate.
Another broad aspect of the present invention relates to an ion exchange membrane fuel cell which includes a module 11 enclosing a membrane electrode diffusion assembly 100 which has an active area 107 defined by a surface area, and which produces an average current density of to at least about 350 mA per square centimeter of surface area when supplied with a dilute fuel 340 at a nominal voltage of 0.5 volts.
Another broad aspect of the present invention relates to an ion exchange membrane fuel cell power system which includes a plurality of discrete ion exchange membrane fuel cell modules 11 and which produce a Is given amount of heat energy, and wherein each of the discrete ion exchange membrane fuel cell modules have an anode heat sink 170 which removes a preponderance of the heat energy generated by the respective ion exchange membrane fuel cell modules. This is best appreciated by a study of Fig. 13.
Another broad aspect of the present invention is to provide an ion 2o exchange fuel cell 10 having an ion exchange membrane 100 have opposite sides and wherein an anode 101 and cathode 102 are individually positioned on the opposite sides of the ion exchange membrane.
A fuel supply 340 is provided to the anode, and an oxidant supply 321 comprising ambient air is supplied in a cathode air stream 323 and 324 which zs has a volume of at least about 5 to about 1000 times the volume required to support a fuel cell chemical reaction which provides water vapor as a byproduct.
Another broad aspect of the present invention is to provide an ion exchange membrane fuel cell 10 having a module 11 which encloses a 3o membrane electrode diffusion assembly 100 having opposite anode 101 and cathode 102 sides, and which, during operation, generates electricity and produces heat energy as a byproduct. The ion exchange membrane fuel cell ~1 100 further has a cathode current collector 60 which rests in ohmic electrical contact with the cathode side of the membrane electrode diffusion assembly, and which exerts force on the membrane electrode diffusion assembly, and conducts, in part, the heat energy generated by the membrane electrode s diffusion assembly away from the membrane electrode assembly.
Yet still another broad aspect of the present invention relates to an ion exchange fuel cell module 11 which has a bifurcated air flow 320 which regulates the operational temperature of the ion exchange membrane fuel cell module by removing the heat energy generated therefrom.
to Yet still further, another broad aspect of the present invention relates to an ion exchange fuel cell module 11 ~ which has a pair of membrane electrode diffusion assemblies 100 which are disposed in spaced relation, one to the other, and wherein each membrane electrode diffusion assembly 100 has an anode and an opposite cathode side 101 and 102 respectively. In this Is arrangement, the cathode side 101 of each of the membrane electrode diffusion assemblies are proximally related, and the anode sides 101 are distally related, and wherein each cathode side defines in part a bifurcated cathode air passageway 106.
Referring to Figs. 3 and 9, an ion exchange membrane fuel cell module ao 11 of the present invention is shown and which includes a pair of membrane electrode diffusion assemblies 100 each having opposite anode and cathode sides 101 and 102, and wherein anode and cathode current collectors 140 and 160 respectively, are electrically coupled with the opposite anode and cathode sides. The ion exchange membrane fuel cell module 100 further has a 2s support member 20 disposed between the pair of membrane electrode diffusion assemblies 100, and wherein the cathode side 102 of each of the membrane electrode diffusion assemblies faces the support member. The ion exchange membrane fuel cell module defines a cathode air passageway 106 ' which is located between the support member 20 and the cathode side 102 30 of each of the membrane electrode diffusion assemblies. A fuel distribution assembly 110 is provided, and is coupled in fluid flowing relation relative to the anode side 101 of each membrane electrode diffusion assembly 100.

Finally, an anode heat sink 170 is provided and oriented in heat receiving relation relative to the anode side 101 to facilitate the removal of a preponderance of the heat energy generated by each membrane electrode diffusion . assembly.
s As presently conceived, the ion exchange membrane fuel cell module 11 of the present invention includes a support member 20 having opposite sides 26 and which defines opposing cavities 34. A cathode current collector 60 is received in each of the cavities 34 which is defined by the support member 20. A membrane electrode diffusion assembly 100 is matingly to received in each of the cavities 34, and has opposite anode and cathode sides 101 and 102 respectively. The cathode side 102 of the individual membrane electrode diffusion assemblies 100 cooperates with .each cavity 34. Further, the cathode current collector 60 lies in ohmic electrical contact with the cathode side 102 of the membrane electrode diffusion assembly 100. A fuel Is distribution assembly 110 cooperates with the support member 20 and is disposed in fluid flowing relation relative to the. anode side 101 of each of the membrane electrode diffusion assemblies 100. An anode current collector 140 is provided and disposed in ohmic electrical contact with the anode side 101 of each of the membrane electrode diffusion assemblies. In this ao arrangement, the fuel distribution assembly 110 is oriented between the membrane electrode diffusion assemblies and the adjacent anode current collector 140. An anode heat sink 170 is disposed in heat removing relation relative to the membrane electrode diffusion assembly 100. As seen in Fig.
13, the ion exchange membrane fuel cell module has a bifurcated air flow 320 2s comprising a cathode air stream 321 which passes into contact with the cathode side 102 of each of the membrane electrode diffusion assemblies.
bet further, the bifurcated air flow includes an anode airstream 322 which passes into heat receiving relation relative to the anode heat sink 170. The heat energy generated by the membrane electrode diffusion assembly is 3o dissipated from the anode heat sink to the anode air stream.
Therefore, it will be seen that the present fuel cell module 11 and associated power system has numerous advantages over the prior art techniques and teachings including the elimination of many of the balance of plant subassemblies typically utilized with stack-like fuel cell devices. Moreover, in view of the highly efficient manner in which heat is dissipated from the fuel cell modules, enhanced current densities are achieved and further, the fuel s cell module of the present invention is enabled, through the present design, to accept and effectively utilize a dilute fuel mixture, yet simultaneously deliver current densities equal to or greater than that described in eaxlier patents, and patent applications which are incorporated by reference herein.
Finally, the present invention provides many advantages over the prior art to fuel cells which employ stack-like arrangements by reducing or eliminating the control measures which have been provided for use with same. The elimination of these several control measures increases the performance capabilities of the present design while simultaneously reducing the capital costs to generate a given amount of electrical power.
is In compliance with the statute, the invention has been described in language more or less specific as to structural and methodical features. It is to be understood, however, that the invention is not limited to the specific features shown and described, since the means herein disclosed comprise preferred forms of putting the invention into effect. The invention is, 2o therefore, claimed in any of its forms or modifications within the proper scope of the appended claims appropriately interpreted in accordance with the doctrine of equivalents.

Claims (108)

1. An ion exchange membrane fuel cell, comprising:
multiple modules each enclosing a membrane electrode diffusion assembly, and wherein at least one of the modules can be easily removed from the ion exchange membrane fuel cell, by hand, while the remaining modules continue to operate.
2. An ion exchange membrane fuel cell as claimed in claim 1, wherein the membrane electrode diffusion assembly has an active area defined by a surface area, and which produces an average current density of at least about 350 mA per square centimeter of surface area when supplied with a dilute fuel at a nominal voltage of at least about 0.5 volts.
3. An ion exchange membrane fuel cell as claimed in claim 2, wherein the dilute fuel includes hydrogen, and wherein the concentration of hydrogen in the dilute fuel is about 30% to about 80%.
4. An ion exchange membrane fuel cell as claimed in claim 1, wherein each of the modules produce a given amount of heat energy during operation, and wherein each of the modules have an anode heat sink which removes a prepoderance of the heat energy generated by the respective modules.
5. An ion exchange membrane fuel cell as claimed in claim 1, wherein each of the modules produce a given amount of heat energy during operation, and wherein each module has a bifurcated air flow which regulates the operational temperature of each module by removing the heat energy therefrom.
6. An ion exchange membrane fuel cell as claimed in claim 1, wherein each module has a pair of membrane electrode diffusion assemblies disposed in spaced relation, one to the other, and wherein each membrane electrode diffusion assembly has an anode side, and an opposite cathode side, and wherein the cathode side of each membrane electrode diffusion assembly is proximally related, and the respective anode sides are distally related, and wherein each cathode side defines, in part, a cathode air passageway.
7. An ion exchange membrane fuel cell as claimed in claim 1, wherein the membrane electrode diffusion assembly has opposite anode and cathode sides and which, during operation, generates electricity and produces heat energy as a byproduct; and a cathode current collector rests in ohmic electrical contact with the cathode side of the membrane electrode diffusion assembly and exerts force on the membrane electrode diffusion assembly, and conducts, in part, the heat energy generated by the membrane electrode diffusion assembly away from the membrane electrode diffusion assembly.
8. An ion exchange membrane fuel cell as claimed in claim 1, wherein the membrane electrode diffusion assembly has opposite anode an cathode sides, and each module further has an anode heat sink disposed in heat removing relation relative to the anode side of the membrane electrode diffusion assembly, and wherein each module further has a bifurcated air flow comprising a cathode air stream and an anode heat sink air stream, and wherein each module produces heat energy during operation, and wherein less than a preponderance of the heat energy is removed by the cathode air stream.
9. An ion exchange membrane fuel cell as claimed in claim 8, wherein a preponderance of the heat energy is removed by the anode heat sink.
10. An ion exchange fuel cell as claimed in claim 1, wherein each module has an anode and cathode current collector, and wherein the ion exchange membrane fuel cell further comprises:

a subrack which supports the individual modules in an operable orientation; and a DC bus mounted adjacent to the subrack, and which electrically couples with the anode and cathode current collectors of each module, and wherein each module can be removed from the subrack without the use of any tools.
11. An ion exchange membrane fuel cell, comprising:
a module enclosing a membrane electrode diffusion assembly which has an active area defined by a surface area, and which produces an average current density of at least about 350 mA per square centimeter of surface area when supplied with a dilute fuel at a nominal voltage of at least about 0.5 volts.
12. An ion exchange membrane fuel cell as claimed in claim 11, wherein, the module can be manipulated by hand.
13. An ion exchange membrane fuel cell as claimed in claim 11, wherein the dilute fuel includes hydrogen, and wherein the concentration of hydrogen in the dilute fuel is about 30% to about 80%.
14. An ion exchange membrane fuel cell as claimed in claim 11, wherein the membrane electrode diffusion assembly has opposite anode and cathode sides, and wherein during operation, the ion exchange membrane fuel cell produces heat energy, and wherein the ion exchange membrane fuel cell has an anode heat sink disposed in heat removing relation relative to the anode side of the membrane electrode diffusion assembly to remove a preponderance of the heat energy generated by the membrane electrode diffusion assembly.
15. An ion exchange membrane fuel cell as claimed in claim 11, wherein the membrane electrode diffusion assembly has opposite anode and cathode sides and produces heat energy during operation, and wherein the anode has a plurality of channels formed therein, and wherein the module has a cathode air flow which removes less than a preponderance of the heat energy generated by the membrane electrode diffusion assembly.
16. An ion exchange membrane fuel cell as claimed in claim 11, wherein the membrane electrode diffusion assembly has opposite anode and cathode sides and produces heat energy during operation; and wherein the module further comprises an anode heat sink disposed in heat removing relation relative to the anode side of the membrane electrode diffusion assembly, and a cathode air flow, and wherein the anode heat sink and the cathode air flow remove the heat energy generated by the membrane electrode diffusion assembly during operation.
17. An ion exchange membrane fuel cell as claimed in claim 11, wherein the membrane electrode diffusion assembly has opposite anode and cathode sides and produces heat energy during operation, and wherein the module further has a bifurcated air flow for removing the heat energy generated by the membrane electrode diffusion assembly.
18. An ion exchange membrane fuel cell as claimed in claim 11, wherein the module can be manipulated by hand, and further comprises:
an electrically nonconductive support member having opposite sides and defining a pair of substantially opposed cavities, and wherein a pair of membrane electrode diffusion assemblies each having opposite anode and cathode sides are individually sealably received in the respective cavities, and wherein each cathode side is oriented in spaced relation relative to the nonconductive support member and defines a cathode air passageway therebetween; and a pair of fuel distribution assemblies individually mounted in fluid flowing relation relative to the anode side of each of the membrane electrode diffusion assemblies to deliver the fuel to same.
19. An ion exchange membrane fuel cell as claimed in claim 11, wherein the module can be manipulated by hand, and further comprises:
an electrically nonconductive support member having opposite sides and defining a pair of substantially opposed cavities, and wherein a pair of membrane electrode diffusion assemblies each having opposite anode and cathode sides are individually sealably received in the respective cavities, and wherein each cathode side is oriented in spaced relation relative to the nonconductive support member and defines a cathode air passageway therebetween;
an anode heat sink disposed in heat removing relation relative to the anode side of each membrane electrode diffusion assembly; and a bifurcated air flow delivered to the module and which comprises a cathode stream which is delivered to the cathode air passageway, and an anode heat sink stream which passes over the anode heat sink, and wherein the bifurcated air flow regulates the operational temperature of the ion exchange membrane fuel cell by the removal of heat energy generated during operation.
20. An ion exchange membrane fuel cell as claimed in claim 11, wherein the module can be manipulated by hand, and further comprises:
an electrically nonconductive support member having opposite sides and defining a pair of substantially opposed cavities, and wherein a pair of membrane electrode diffusion assemblies each having opposite anode and cathode sides are individually sealably fitted in the respective cavities, and wherein each cathode side is oriented in spaced relation relative to the nonconductive support member and defines a cathode air passageway therebetween;
an anode heat sink disposed in heat removing relation relative to the anode side of each membrane electrode diffusion assembly; and a bifurcated air flow delivered to the module and which comprises a cathode stream which is delivered to the cathode air passageway, and an anode heat sink stream which passes over the anode heat sink, and wherein the cathode air stream is further bifurcated and delivered to each cathode air passageway, and wherein the bifurcated air flow comprising the cathode stream and the anode heat sink stream regulates the operational temperature of the ion exchange membrane fuel cell by the removal of heat energy generated during operation.
21. An ion exchange membrane fuel cell as claimed in claim 11, wherein a pair of membrane electrode diffusion assemblies are disposed in spaced relation one to the other, and wherein each membrane electrode diffusion assembly has opposite anode and cathode sides, and wherein the cathode sides of each membrane electrode diffusion assembly are proximally related, and wherein the anode sides of each membrane electrode diffusion assembly are distally related, and wherein each cathode side defines in part a bifurcated cathode air passageway.
22. An ion exchange membrane fuel cell as claimed in claim 11, and further comprising a current collector which is positioned in ohmic electrical contact with the membrane electrode diffusion assembly and which simultaneously exerts force on the membrane electrode diffusion assembly, conducts heat energy away from the membrane electrode diffusion assembly, and collects current generated by the membrane electrode diffusion assembly.
23. An ion exchange membrane fuel cell as claimed in claim 11, and wherein the membrane electrode diffusion assembly has opposite anode and cathode sides, and produces heat energy during operation, and wherein the module further comprises a cathode current collector which rests in ohmic electrical contact with the cathode side and collects electrical current while simultaneously applying force to the membrane electrode diffusion assembly, and conducting heat energy away from membrane electrode diffusion assembly, and wherein the cathode current collector defines, in part, a cathode air passageway.
24. An ion exchange membrane fuel cell as claimed in claim 11, wherein the membrane electrode diffusion assembly has opposite anode and cathode sides and produces heat energy during operation, and wherein the module further comprises a cathode current collector which is juxtaposed relative to the cathode side of the membrane electrode diffusion assembly and which defines, in part, a cathode air passageway, and wherein the fuel cell module further has a bifurcated air flow, a portion of which is delivered to the cathode air passageway, and wherein the bifurcated air flow regulates the operational temperature of the membrane electrode diffusion assembly.
25. An ion exchange membrane fuel cell power system, comprising:
a plurality of discrete ion exchange membrane fuel cell modules which produce a given amount of heat energy, and wherein each of the discrete ion exchange membrane fuel cell modules have an anode heat sink which removes a preponderance of the heat energy generated by the ion exchange membrane fuel cell modules.
26. A power system as claimed in claim 25, wherein each discrete ion exchange membrane fuel cell module has at least two membrane electrode diffusion assemblies which have opposite anode and cathode sides, and wherein each ion exchange membrane fuel cell module can be manipulated by hand.
27. A power system as claimed in claim 26, wherein each discrete ion exchange membrane fuel cell module has a pair of current collectors which are individually disposed in electrical contact with the opposite anode and cathode sides of each of the membrane electrode diffusion assemblies.
28. A power system as claimed in claim 27, wherein each anode heat sink is disposed in heat receiving relation relative to the anode side of each membrane electrode diffusion assembly and further applies force to each pair of current collectors and the individual membrane electrode diffusion assemblies.
29. A power system as claimed in claim 28, wherein each membrane electrode diffusion assembly has an active area having a surface area, and wherein each ion exchange membrane fuel cell module produces a current density of at least about 350 mA per square centimeter of active area at a nominal voltage of at least about 0.5 volts when supplied with a dilute fuel.
30. A power system as claimed in claim 29, wherein the discrete ion exchange membrane fuel cell modules have a cathode air flow, and wherein less than a preponderance of the heat energy produced by the discrete ion exchange membrane fuel cell modules is removed by the cathode air flow, and wherein the dilute fuel is a dilute mixture of hydrogen.
31. A power system as claimed in claim 30, wherein each of the ion exchange membrane fuel cell modules comprise:
an electrically nonconductive support member having opposite sides and defining individual cavities, and wherein the respective membrane electrode diffusion assemblies are individually sealably mounted in the respective cavities, and disposed in spaced relation relative to the nonconductive support member, and wherein the nonconductive support member is oriented between the respective membrane electrode diffusion assemblies; and wherein the cathode current collector is disposed in ohmic electrical contact with the cathode side of each of the membrane electrode diffusion assemblies, and are individually received in each of the cavities defined by the nonconductive support member and disposed between the respective membrane electrode diffusion assemblies and the nonconductive support member; and a pair of fuel distribution assemblies individually mounted in fluid flowing relation relative to the anode side of each of the membrane electrode diffusion assemblies, and wherein the anode current collector is disposed in ohmic electrical contact with each of the anode sides; and wherein the anode heat sink is mounted in heat receiving relation relative to each of the anode sides to conduct heat energy generated by the ion exchange membrane module away from the membrane electrode diffusion assembly, and wherein the fuel distribution assembly is oriented substantially between the anode side and the anode current collector.
32. A power system as claimed in claim 31, wherein the cathode current collector comprises a deformable member which orients the membrane electrode diffusion assembly in spaced relation relative to the underlying nonconductive support member and exerts a force on same, and wherein a cathode air passageway is defined between the cathode current collector, membrane electrode diffusion assembly and the underlying nonconductive support member to facilitate the movement of air along the cathode side of the membrane electrode diffusion assembly, and wherein the cathode current collector further conducts heat energy away from membrane electrode diffusion assembly.
33. A power system as claimed in claim 32, wherein the fuel distribution assemblies are each coupled in fluid flowing relation with the dilute fuel and are operable to supply the dilute fuel to the anode side of each of the membrane electrode diffusion assemblies, and wherein each of the fuel distribution assemblies has a main body which defines an intake plenum, an exhaust plenum, and a cavity which is disposed intermediate the intake and exhaust plenums and which is coupled in fluid flowing relation thereto, and wherein the cavity formed in the respective fuel distribution assemblies matingly cooperates with the individual cavities defined by the nonconductive support plate.
34. A power system as claimed in claim 33, wherein the fuel distribution assembly has inside and outside facing surfaces, and wherein the cavity extends through the main body and between the inside and outside facing surfaces, and the anode current collector lies in ohmic electrical contact over a preponderance of the surface area of the anode side of the membrane electrode diffusion assembly and is further juxtaposed relative to the outside surface of the fuel distribution assembly.
35. A power system as claimed in claim 34, wherein the anode current collector is substantially electrically isolated from the anode heat sink, and wherein the anode heat sink substantially inhibits the formation of a temperature gradient across the membrane electrode diffusion assembly during operation of the ion exchange membrane fuel cell, and further conducts heat energy away from the membrane electrode diffusion assembly.
36. A power system as claimed in claim 35, wherein the individual ion exchange membrane fuel cell modules are releasably mounted on a subrack, and wherein the power system further comprises:
an air distribution plenum coupled in fluid flowing relation relative to each of the ion exchange membrane fuel cell modules, the air distribution plenum having an exhaust end which delivers an air stream to each of the ion exchange membrane fuel cell modules, and an opposite intake end which receives both air which has previously come into contact with each of the ion exchange membrane fuel cell modules, and air which comes from outside the respective ion exchange membrane fuel cell modules; and an air mixing valve coupled to the air distribution plenum and which controls the amount of air which has passed through the respective ion exchange membrane fuel cell modules and is recirculated back to same in the air stream.
37. A power system as claimed in claim 36, wherein the air stream delivered by the air distribution plenum is bifurcated into an anode heat sink stream, and a cathode stream, and wherein the cathode stream is supplied to the cathode air passageway, and wherein the anode heat sink stream passes over the anode heat sink and is operable to remove the preponderance of the heat energy generated by the ion exchange membrane fuel cell membrane, and wherein the air mixing valve is intermediate the intake end and exhaust end of the air distribution plenum.
38. A power system as claimed in claim 37, and which further comprises a DC bus, and wherein the anode and cathode current collectors are releasably electrically coupled with the DC bus when the ion exchange membrane fuel cell modules are oriented on the subrack.
39. A power system as claimed in claim 38, and further comprising:
a controller electrically coupled with each of the ion exchange membrane fuel cell modules.
40. A power system as claimed in claim 38, and further comprising:
a power conditioning assembly for receiving the electrical power produced by each of the discrete ion exchange membrane fuel cell modules.
41. An ion exchange membrane fuel cell power system comprising:
an ion exchange membrane fuel cell module which produces heat energy, and which has a bifurcated air flow which regulates the operational temperature of the ion exchange membrane fuel cell module by removing the heat energy therefrom.
42. A power system as claimed in claim 41, wherein the ion exchange membrane fuel cell module has a membrane electrode diffusion assembly with opposite anode and cathode sides, and a pair of current collectors are individually disposed in ohmic electrical contact with the respective anode and cathode sides, and wherein the membrane electrode diffusion assembly has an active area having a surface area, and wherein the ion exchange membrane fuel cell module produces a current density of at least about 350 mA per square centimeter of active area at a nominal voltage of at least about 0.5 volts when provided with a source of a dilute fuel.
43. A power system as claimed in claim 42, and further comprising:
a housing defining a cavity;
a subrack mounted in the cavity and which is defined by the housing, and wherein the ion exchange membrane fuel cell module is releasably supported on the subrack;
a DC bus mounted in the housing and adjacent the subrack and which is electrically coupled with each of the current collectors when the ion exchange membrane fuel cell module is received on the subrack; and an air distribution plenum borne by the housing and coupled in fluid flowing relation relative to the ion exchange membrane fuel cell module.
44. A power system as claimed in claim 43, wherein the ion exchange membrane fuel cell module further comprises an anode heat sink, and wherein the air distribution plenum has an intake end and an opposite, exhaust end which provides the bifurcated air flow, which comprises an anode heat sink stream, and a cathode steam, and wherein the cathode stream is supplied to the cathode side of the membrane electrode diffusion assembly, and the anode heat sink stream passes over the anode heat sink and is operable to remove the preponderance of the heat energy generated by the ion exchange membrane fuel cell membrane.
45. A power system as claimed in claim 44, wherein an air mixing valve is operably coupled to the air distribution plenum and is mounted downstream of the ion exchange membrane fuel cell module, and wherein the intake end of the air distribution plenum receives a first air source which has previously come into contact with the ion exchange membrane fuel cell module, and a second air source which comes from outside the ion exchange membrane fuel cell module, and wherein the air mixing valve controls the relative amount of each of the respective air sources delivered to the ion exchange membrane fuel cell module.
46. A power system as claimed in claim 45, and further comprising:

a controller electrically coupled with the ion exchange membrane fuel cell module, and the air mixing valve.
47. A power system as claimed in claim 41, wherein the ion exchange membrane fuel cell module has at least two membrane electrode diffusion assemblies which have opposite anode and cathode sides, and wherein the ion exchange membrane fuel cell module can be manipulated by hand, and wherein anode sides each have channels formed therein.
48. A power system as claimed in claim 47, wherein the ion exchange membrane fuel cell module has an anode and cathode current collector which are individually disposed in electrical contact with the opposite anode and cathode sides of each of the membrane electrode diffusion assemblies.
49. A power system as claimed in claim 48, wherein the ion exchange membrane fuel cell module further comprises:
an anode heat sink disposed in heat receiving relation relative to the anode side of each membrane electrode diffusion assembly and which applies a force to each pair of current collectors and the membrane electrode diffusion assemblies disposed therebetween.
50. A power system as claimed in claim 49, wherein the ion exchange membrane fuel cell module further comprises:
a bifurcated air flow comprising a cathode air stream and an anode heat sink air stream, and wherein less than a preponderance of the heat energy produced by the ion exchange membrane fuel cell module is removed by the cathode air stream.
51. A power system as claimed in claim 50, wherein the ion exchange membrane fuel cell module further comprises:

an electrically nonconductive support member having opposite sides and defining individual cavities, and wherein the respective membrane electrode diffusion assemblies are individually sealably mounted in the respective cavities, and disposed in spaced relation relative to the nonconductive support member, and wherein the nonconductive support member is oriented between the respective membrane electrode diffusion assemblies, and wherein the cathode current collector is disposed in ohmic electrical contact with the cathode side of each of the membrane electrode diffusion assemblies, and wherein each of the cathode current collectors are individually associated with each of the cavities defined by the nonconductive support member and disposed substantially between the respective membrane electrode diffusion assemblies and the nonconductive support member;
a pair of fuel distribution assemblies individually mounted in fluid flowing relation relative to the anode side of each of the membrane electrode diffusion assemblies, and wherein the anode current collector is disposed in ohmic electrical contact with the anode side of each membrane electrode diffusion assembly, and is juxtaposed relative to each of the fuel distribution assemblies; and the anode heat sink is mounted in heat receiving relation relative to each of the anodes to conduct heat energy generated by the ion exchange membrane fuel cell module away from the membrane electrode diffusion assembly.
52. A power system as claimed in claim 51, wherein the cathode current collector comprises a deformable member which orients the membrane electrode diffusion assembly in spaced relation relative to the underlying nonconductive support member and exerts a force on same, and wherein a cathode air passageway is created between the deformable member of the cathode current collector, membrane electrode diffusion assembly and the underlying nonconductive support member to facilitate the movement of air along the cathode side of the membrane electrode diffusion assembly, and wherein the cathode current collector, and the movement of air along the cathode side of the membrane electrode diffusion assembly dissipates heat energy generated by the membrane electrode diffusion assembly.
53. A power system as claimed in claim 52, wherein the fuel distribution assemblies are each coupled in fluid flowing relation with a dilute source of fuel and are operable to supply the dilute source of fuel to the anode side of each of the membrane electrode diffusion assemblies, and wherein each of the fuel distribution assemblies has a main body which defines an intake plenum, an exhaust plenum, and a cavity which is disposed intermediate the intake and exhaust plenums and which is coupled in fluid flowing relation relative thereto, and wherein the cavity formed in the respective fuel distribution assemblies substantially matingly cooperates with the individual cavities defined by the nonconductive support plate and operably receives the individual membrane electrode diffusion assemblies.
54. A power system as claimed in claim 53, wherein the fuel distribution assembly has inside and outside facing surfaces, and wherein the cavity extends through the main body and between the inside and outside facing surfaces, and wherein the outside facing surface of the fuel distribution assembly has a surface area, and the anode current collector lies in juxtaposed substantially covering relation over a preponderance of the surface area of the outside facing surface of the fuel distribution assembly and is disposed in ohmic electrical contact with the anode of the membrane electrode diffusion assembly that is received in the cavity defined by the fuel distribution assembly.
55. A power system as claimed in claim 54, wherein the anode current collector is substantially electrically isolated from the anode heat sink, and wherein the anode heat sink inhibits the formation of a temperature gradient across the active area of the membrane electrode diffusion assembly during operation of the ion exchange membrane fuel cell.
56. A power system as claimed in claim 55, wherein the individual ion exchange membrane fuel cell modules are releasably mounted on a subrack, and wherein the power system further comprises:
an air distribution plenum coupled in fluid flowing relation relative to each of the ion exchange membrane fuel cell modules, the air distribution plenum having an exhaust end which delivers an air stream to each of the ion exchange membrane fuel cell modules, and an opposite intake end which receives both air which has previously come into contact with each of the ion exchange membrane fuel cell modules, and air which comes from outside of the respective ion exchange membrane fuel cell modules; and an air mixing valve coupled to the air distribution plenum and which meters the amount of air which has passed through the respective ion exchange membrane fuel cell modules and is recirculated back to ion exchange membrane fuel cell module.
57. A power system as claimed in claim 56, and wherein the cathode air stream is supplied to the cathode air passageway, and wherein the anode heat sink stream passes over the anode heat sink and removes a preponderance of the heat energy generated by the ion exchange membrane fuel cell membrane, and wherein the air mixing valve is located downstream of the ion exchange membrane fuel module.
58. A power system as claimed in claim 57, and which further comprises a DC bus, and wherein the anode and cathode current collectors are electrically coupled with the DC bus when the ion exchange membrane fuel cell modules are mounted on the subrack.
59. A power system as claimed in claim 58, wherein the power system further comprises:
a controller electrically coupled with each of the ion exchange membrane fuel cell modules.
60. A power system as claimed in claim 59, wherein the power system further comprises:
a power conditioning assembly for receiving the electrical power produced by each of the discrete ion exchange membrane fuel cell modules.
61. An ion exchange membrane fuel cell module, comprising:
a pair of membrane electrode diffusion assemblies disposed in spaced relation, one to the other, and wherein each membrane electrode diffusion assembly has an anode side, and an opposite cathode side, and wherein the cathode side of each membrane electrode diffusion assembly is proximally related, and the anode sides are distally related, and wherein each cathode side defines, in part, a bifurcated cathode air passageway.
62. An ion exchange membrane fuel cell module as claimed in claim 61, and further comprising:
a nonconductive support member disposed intermediate the pair of membrane electrode diffusion assemblies, and wherein the nonconductive support member has opposite sides which define discreet cavities, and wherein the opposite sides of the support member define, in part, the bifurcated cathode air passageway, and wherein the cathode side of each membrane electrode diffusion assembly faces one of the cavities defined by the nonconductive support member.
63. An ion exchange membrane fuel cell module as claimed in claim 62, and further comprising:
a cathode current collector received in each cavity defined by the nonconductive support member and disposed in ohmic electrical contact with the cathode side of the membrane electrode diffusion assembly, the cathode current collector having a plurality of resilient electrically conductive members which engage the cathode side of the membrane electrode diffusion assembly and orient it in spaced relation relative to the support member, the cathode current collector defining, in part, the bifurcated cathode air passageway and further conducting heat energy generated by the membrane electrode diffusion away from the membrane electrode diffusion assembly.
64. An ion exchange membrane fuel cell module as claimed in claim 63, and further comprising:
a fuel distribution assembly disposed in fluid flowing relation relative to the anode side of each membrane electrode diffusion assembly, and cooperating with the support member, and wherein the fuel distribution assembly is disposed in juxtaposed relation relative to the anode side of each membrane electrode diffusion assembly.
65. An ion exchange membrane fuel cell module as claimed in claim 64, and further comprising:
an anode current collector disposed in ohmic electrical contact with the anode side of each membrane electrode diffusion assembly, and which conducts away heat energy generated by the membrane electrode diffusion assembly, and wherein the fuel distribution assembly is disposed intermediate the anode side of each membrane electrode diffusion assembly and the anode current collector.
66. An ion exchange membrane fuel cell module, as claimed in claim 65, and further comprising:
an anode heat sink disposed in heat removing relation relative to the membrane electrode diffusion assembly and which is substantially electrically isolated from the anode current collector, and oriented in heat receiving relation relative thereto, and wherein the membrane electrode diffusion assembly generates heat energy and the anode heat sink removes a preponderance of the heat energy generated by the membrane electrode diffusion assembly.
67. An ion exchange membrane fuel cell module, as claimed in claim 66, wherein the bifurcated cathode air passageway receives a cathode air stream, and wherein less than a preponderance of the heat energy produced by the ion exchange membrane fuel cell module is removed by way of the cathode air stream.
68. An ion exchange membrane fuel cell module, as claimed in claim 67, and further comprising:
an air distribution plenum coupled in fluid flowing relation relative to the ion exchange membrane fuel cell module, the air distribution plenum having an intake end and an opposite exhaust end, and wherein the air distribution plenum delivers a bifurcated air stream which comprises the cathode air stream, and an anode heat sink stream, and wherein the intake end receives the cathode air stream which has passed through the bifurcated cathode air passageway, and air which comes from outside the ion exchange membrane fuel cell module; and an air mixing valve coupled in fluid metering relation to the air distribution plenum to control the amount of outside air and the previous cathode air stream delivered to the ion exchange membrane fuel cell module.
69. An ion exchange membrane fuel cell module as claimed in claim 68, and further comprising:
a subrack for releasably supporting the ion exchange membrane fuel cell module in an operable orientation;
a DC bus mounted operatively adjacent the subrack, and wherein the DC bus is electrically coupled with the anode and cathode current collectors when the ion exchange membrane fuel cell module is operatively oriented on the subrack; and wherein the intake end of the air distribution plenum is disposed in fluid flowing relation relative to the ion exchange membrane fuel cell module when it is operatively oriented on the subrack.
70. An ion exchange membrane fuel cell module as claimed in claim 69, and further comprising:

a controller electrically coupled with the ion exchange membrane fuel cell module; and a power conditioning assembly electrically coupled with the DC bus and the controller and which is operable to receive the electrical power produced by the ion exchange membrane fuel cell module.
71. An ion exchange membrane fuel cell module, comprising:
a pair of membrane electrode diffusion assemblies each having opposite anode and cathode sides;
anode and cathode current collectors electrically coupled with the opposite anode and cathode sides of the membrane electrode diffusion assembly;
a support member disposed between the pair of membrane electrode diffusion assemblies, and wherein the cathode side of each membrane electrode diffusion assembly faces the support member;
a cathode air passageway defined between the support member and the cathode side of each of the membrane electrode diffusion assemblies;
a fuel distribution assembly coupled in fluid flowing relation relative to the anode side of each membrane electrode diffusion assembly; and an anode heat sink oriented in heat receiving relation relative to each anode.
72. An ion exchange membrane fuel cell module as claimed in claim 71, wherein the support member has a main body with opposite first and second ends, and opposite sides which define individual cavities, and wherein the cathode side of each membrane electrode diffusion assembly is mounted in the cavity and oriented in spaced relation relative to the support member, and wherein the cathode current collector is received in each cavity and disposed between the support member and the cathode side of each membrane electrode diffusion assembly, and wherein the cathode current collector positions the cathode side of the membrane electrode diffusion assembly in spaced relation relative to the support member, and wherein the cathode side of each membrane electrode diffusion assembly, the cathode current collector, and the support member define the cathode air passageway which extends between the first and second end of the support member.
73. An ion exchange membrane fuel cell module as claimed in claim 72, wherein the fuel distribution assembly is oriented between the membrane electrode diffusion assembly and the anode current collector, and wherein the anode current collector is disposed in ohmic electrical contact with the anode of the membrane electrode diffusion assembly, and wherein the anode current collector is substantially electrically isolated from the anode heat sink, and wherein the anode side has a plurality of interconnecting channels which are formed therein.
74. An ion exchange membrane fuel cell module, as claimed in claim 73, and further comprising:
an air distribution plenum coupled in fluid flowing relation relative to the ion exchange membrane fuel cell module, the air distribution plenum having an intake end and an opposite exhaust end, and wherein the air distribution plenum delivers an air stream which is bifurcated the fuel cell module, and wherein the bifurcated air stream comprises a cathode air stream which is delivered to the cathode air passageway, and an anode heat sink air stream which passes over the anode heat sink to conduct heat away from the anode heat sink, and wherein the intake end receives the cathode air stream which has passed through the cathode air passageway, and the air which comes from outside the ion exchange membrane fuel cell module; and an air mixing valve coupled in fluid metering relation relative to the air distribution plenum to control the percentage of outside air and the previous cathode air stream delivered to the ion exchange membrane fuel cell module.
75. An ion exchange membrane fuel cell module as claimed in claim 74, and further comprising:

a subrack for releasably supporting the ion exchange membrane fuel cell module in an operable orientation;
a DC bus mounted operatively adjacent the subrack, and which is electrically coupled with the anode and cathode current collectors when the ion exchange membrane fuel cell module is operatively oriented on the subrack; and wherein the intake end of the air distribution plenum is disposed in fluid flowing relation relative to the ion exchange membrane fuel cell module when it is operatively oriented on the subrack.
76. An ion exchange membrane fuel cell module as claimed in claim 75, and further comprising:~
a controller electrically coupled with the ion exchange membrane fuel cell module; and a power conditioning assembly electrically coupled with the DC bus and the controller and which is operable to receive the electrical power produced by the ion exchange membrane fuel cell module.
77. An ion exchange membrane fuel cell module, comprising:
a support member having opposite sides and which defines opposing cavities;
a cathode current collector received in each of the cavities defined by the support member;
a membrane electrode diffusion assembly matingly received in each of the cavities, and having opposite anode and cathode sides, and wherein the cathode side of the individual membrane electrode diffusion assembly cooperates with each cavity, and the cathode current collector lies in ohmic electrical contact with the cathode side of the membrane electrode diffusion assembly;
a fuel distribution assembly cooperating with the support member and disposed in fluid flowing relation relative to the anode side of each of the membrane electrode diffusion assemblies;

an anode current collector disposed in ohmic electrical contact with the anode side of each of the membrane electrode diffusion assemblies, and wherein the fuel distribution assembly is disposed between the membrane electrode diffusion assembly and the anode current collector; and an anode heat sink disposed in heat removing relation relative to the membrane electrode diffusion assembly, and wherein the ion exchange membrane fuel cell module has a bifurcated air flow comprising a cathode air stream which passes into contact with the cathode side of the membrane electrode diffusion assembly, and an anode air stream which passes into heat receiving relation relative to the anode heat sink, and wherein heat energy generated by the membrane electrode diffusion assembly is dissipated from the anode heat sink to the anode air stream.
78. An ion exchange membrane fuel cell module as claimed in claim 77, wherein the support member is fabricated from a dielectric material, and wherein the individual cavities are formed in the opposite sides of the support member, and wherein the cathode current collector, the cathode side of the membrane electrode diffusion assembly and the nonconductive support member define a cathode air passageway which facilitates the delivery of the cathode air stream to the cathode side of the membrane electrode diffusion assembly.
79. An ion exchange membrane fuel cell module as claimed in claim 78, wherein the cathode current collector has a plurality of resilient electrically conductive members which orient the cathode side of the membrane electrode diffusion assembly in spaced relation relative to the underlying support member, and further conducts away heat which is generated by the membrane electrode diffusion assembly, and wherein the membrane electrode diffusion assembly is substantially sealably mounted in the cavity.
80. An ion exchange membrane fuel cell module as claimed in claim 79, wherein the fuel distribution assembly is substantially electrically isolated from the anode heat sink.
81. An ion exchange membrane fuel cell module, comprising:
a dielectric support member defining opposed cavities;
a cathode current collector received in each cavity;
a membrane electrode diffusion assembly having opposite anode and cathode sides and which is received in each cavity, and wherein the cathode side is positioned in spaced relation relative to the support member by the cathode current collector to define a cathode air passageway therebetween;
a fuel distribution assembly disposed in fuel dispensing relation relative to the anode side of the membrane electrode diffusion assembly;
an anode current collector electrically coupled with the anode side of the membrane electrode diffusion assembly; and an anode heat sink disposed in heat removing relation relative to the membrane electrode diffusion assembly and electrically isolated from the anode current collector.
82. An ion exchange membrane fuel cell module, as claimed in claim 81, wherein the support member has a main body having opposite first and second ends, and wherein the cathode air passageway defined in each cavity extends between the opposite ends, and wherein the respective cathode air passageways are substantially parallel one to the other.
83. An ion exchange membrane fuel cell module, as claimed in claim 82, wherein each current collector has a plurality of resilient electrically conductive members which orient the membrane electrode diffusion assembly in spaced relation to the support member, and wherein the cathode current collector further includes a conductive contact member which extends outwardly from the cavity at the first end of support member.
84. An ion exchange membrane fuel cell module, as claimed in claim 83, wherein the fuel distribution assembly is disposed in juxtaposed relation relative to the anode side of the membrane electrode diffusion assembly, and wherein the anode side has formed therein a plurality of interlocking channel which receive the fuel delivered by the fuel distribution assembly.
85. A proton exchange membrane fuel cell module, as claimed in claim 83, wherein the anode current collector is disposed in ohmic electrical contact with anode side of the membrane electrode diffusion assembly, and wherein anode current collector further has a contact member which extends outwardly relative to the first end of the support member and is further disposed in substantially spaced parallel relation relative to the contact member of the cathode current collector.
86. An ion exchange membrane fuel cell comprising:
an ion exchange fuel cell membrane having opposite sides;
an anode and cathode individually positioned on the opposite sides of the ion exchange membrane;
a fuel supply provided to the anode;
an oxidant supply comprising ambient air provided to the cathode, and wherein the air is supplied in a cathode air stream which has a volume of at least about 5 to about 1000 times the volume required to support a fuel cell chemical reaction which produces water vapor as a byproduct.
87. An ion exchange fuel cell as claimed in claim 86, and wherein the fuel cell chemical reaction produces heat as a byproduct and wherein the cathode air stream removes less than a preponderance of the heat produced by the fuel cell chemical reaction.
88. An ion exchange fuel cell as claimed in claim 87, and wherein the ion exchange membrane, anode and cathode are made integral with a fuel cell module, and wherein the fuel cell module further comprises an anode heat sink disposed in heat removing relation relative to the anode, and wherein the anode heat sink removes a preponderance of the heat produced by the fuel cell chemical reaction.
89. An ion exchange fuel cell as claimed in claim 88, wherein the ion exchange membrane fuel cell module is coupled with a subrack, and wherein the subrack further has an air distribution plenum coupled in fluid flowing relation with the ion exchange fuel cell module, and wherein the cathode air stream delivered to the ion exchange fuel cell module by the air distribution plenum is humidified in part, by the water vapor generated by the chemical reaction on the cathode.
90. An ion exchange fuel cell as claimed in claim 89, wherein the cathode air stream delivered to the ion exchange fuel cell module is recirculated back to the ion exchange fuel cell module, and wherein the air distribution plenum further comprises an air mixing valve which facilitates the addition of fresh ambient air to the recirculated cathode air stream, the selective combination of the recirculated cathode air stream and the fresh ambient air forming a cathode air stream having a substantially stable operating temperature.
91. An ion exchange membrane fuel cell comprising:
a module enclosing a membrane electrode diffusion assembly having opposite anode and cathode sides and which, during operation, generates electricity and produces heat energy as a byproduct; and a cathode current collector which rests in ohmic electrical contact with the cathode side of the membrane electrode diffusion assembly and which exerts force on the membrane electrode diffusion assembly, and conducts, in part, the heat energy generated by the membrane electrode diffusion assembly away from the membrane electrode diffusion assembly.
92, An ion exchange membrane fuel cell as claimed in claim 91, wherein the cathode current collector defines, in part, a cathode air passageway, and wherein the ion exchange membrane further comprises a bifurcated air flow, and wherein a first portion of the bifurcated air flow is provided to the cathode air passageway and facilitates the removal of less than a preponderance of the heat generated by the membrane electrode diffusion assembly.
93. An ion exchange membrane fuel cell as claimed in claim 92, and further comprising an anode heat sink which is disposed in heat receiving relation relative to the anode side of membrane electrode diffusion assembly, and wherein a second portion of the bifurcated air flow is provided to the anode heat sink and which facilitates the removal of a preponderance of the heat generated by the membrane electrode diffusion assembly.
94. An ion exchange membrane fuel cell as claimed in claim 93, and further comprising:
an anode current collector resting in ohmic electrical contact with the anode side of the membrane electrode diffusion assembly; and a fuel distribution assembly disposed in fuel dispensing relation relative to the anode side of membrane electrode diffusion assembly, and which is disposed therebetween the anode current collector and the anode heat sink.
95. An ion exchange membrane fuel cell as claimed in claim 94, wherein the membrane electrode diffusion assembly has an active area defined by a surface area, and which produces an average current density of at least about 350 mA per square centimeter of surface area when supplied with a dilute fuel by the fuel distribution assembly at a nominal voltage of at least about 0.5 volts.
96. An ion exchange membrane fuel cell as claimed in claim 95, wherein the module can be manipulated by hand, and wherein the dilute fuel includes hydrogen, and wherein the concentration of the hydrogen in the dilute fuel is about 30% to about 80%.
97. An ion exchange fuel cell comprising:
an ion exchange membrane having opposite sides;
an anode electrode mounted on one side of the ion exchange membrane, and a cathode electrode mounted on the opposite side thereof;
and wherein a plurality of anode and cathode current collectors are provided, the plurality of anode and cathode current collectors being oriented along substantially common planes; and a conductive member electrically coupling the respective anode and cathode current collectors, the conductive member oriented in spaced relation relative to the ion exchange membrane.
98. An ion exchange fuel cell as claimed in claim 97 and further comprising:
a second ion exchange membrane having opposite sides;
a second anode electrode mounted on one side of the second membrane and a second cathode electrode mounted on the opposite side thereof, and wherein a second plurality of anode and cathode current collectors are provided, the second plurality of anode and cathode current collectors being oriented along substantially common planes; and wherein the conductive member electrically couples the respective second anode current collectors and second cathode current collectors, the conductive member oriented in spaced relation relative to the second ion exchange membrane.
99. An ion exchange fuel cell as claimed in claim 98, wherein the first and second ion exchange membranes are disposed in substantially parallel spaced relation, such that the respective cathode sides of each of the ion exchange membranes are positioned proximally and the anode sides of the respective ion exchange membranes are positioned distally relative to each other.
100. An ion exchange fuel cell as claimed in claim 99, and further comprising:
an air passage located substantially between the proximally spaced cathode electrodes.
101. An ion exchange fuel cell as claimed in claim 100, wherein a source of fuel is supplied to the distally positioned anode electrodes.
102. An ion exchange fuel cell as claimed in claim 101, wherein the source of fuel comprises hydrogen.
103. An ion exchange fuel cell as claimed in claim 102, and further comprising:
at least two anode heat sinks which are individually oriented in heat receiving relation relative to each of the distally positioned anode electrodes.
104. An ion exchange fuel cell as claimed in claim 103, and further comprising:
a bifurcated air supply which is delivered to the air passage located substantially between the proximally spaced cathode electrodes and to each of the anode heat sinks.
105. An ion exchange fuel cell as claimed in claim 104, wherein the fuel cell is enclosed within a fuel cell module.
106. An ion exchange fuel cell as claimed in claim 105, wherein the fuel cell module comprises:
a pair of substantially opposed cavities, and wherein each cavity contains one of the two ion exchange membranes and the electrodes and current collectors associated therewith.
107. An ion exchange fuel cell as claimed in claim 106, wherein the fuel cell module further comprises:

a support member disposed substantially between the pair of opposed cavities and substantially between the first plurality of cathode current collectors and second plurality of cathode current collectors.
108. An ion exchange fuel cell as claimed in claim 107, wherein the fuel cell module further comprises:

a fuel distribution assembly disposed substantially between each anode heat sink and the corresponding anode current collector associated therewith.
CA002401562A 2000-05-17 2001-05-08 Ion exchange membrane fuel cell Abandoned CA2401562A1 (en)

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US09/577,407 US6468682B1 (en) 2000-05-17 2000-05-17 Ion exchange membrane fuel cell
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Families Citing this family (110)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6468682B1 (en) 2000-05-17 2002-10-22 Avista Laboratories, Inc. Ion exchange membrane fuel cell
US20020022382A1 (en) * 2000-08-18 2002-02-21 Franklin Jerrold E. Compliant electrical contacts for fuel cell use
US20020022170A1 (en) * 2000-08-18 2002-02-21 Franklin Jerrold E. Integrated and modular BSP/MEA/manifold plates for fuel cells
EP1326298A4 (en) * 2000-09-18 2006-07-19 Mitsubishi Heavy Ind Ltd Solid polymer type fuel battery
DE10050467A1 (en) * 2000-10-12 2002-05-16 Omg Ag & Co Kg Method for producing a membrane electrode assembly for fuel cells
JP2002164056A (en) * 2000-11-22 2002-06-07 Aisin Seiki Co Ltd Solid high molecular electrolyte-type fuel cell and electrode and method of manufacturing electrode
US6532792B2 (en) 2001-07-26 2003-03-18 Avista Laboratories, Inc. Method of compensating a MOS gas sensor, method of manufacturing a MOS gas sensor, MOS gas sensor, and fuel cell system
US20080068801A1 (en) * 2001-10-04 2008-03-20 Ise Corporation High-Power Ultracapacitor Energy Storage Cell Pack and Coupling Method
US7085112B2 (en) * 2001-10-04 2006-08-01 Ise Corporation High-power ultracapacitor energy storage pack and method of use
US20090021871A1 (en) * 2001-10-04 2009-01-22 Ise Corporation Energy Storage Pack Having Overvoltage Protection and Method of Protection
US20090190273A1 (en) * 2001-10-04 2009-07-30 Ise Corporation Ultracapacitor Overvoltage Protection Circuit With Self Verification
US20070002518A1 (en) * 2001-10-04 2007-01-04 Ise Corporation High-Power Ultracapacitor Energy Storage Pack and Method of Use
US20070020513A1 (en) * 2001-10-04 2007-01-25 Ise Corporation Energy Storage Cell Support Separator and Cooling System for a Multiple Cell Module
US7144646B2 (en) 2001-12-14 2006-12-05 Ballard Power Systems Inc. Method and apparatus for multiple mode control of voltage from a fuel cell system
US6716549B2 (en) * 2001-12-27 2004-04-06 Avista Laboratories, Inc. Fuel cell having metalized gas diffusion layer
WO2003057529A2 (en) * 2002-01-08 2003-07-17 Hypercar, Inc. Advanced composite hybrid-electric vehicle
US6620538B2 (en) * 2002-01-23 2003-09-16 Avista Laboratories, Inc. Method and apparatus for monitoring equivalent series resistance and for shunting a fuel cell
FR2837024B1 (en) * 2002-03-06 2007-04-27 Air Liquide FUEL CELL, CELL OR GROUP OF CELLS BELONGING TO SUCH BATTERY, REPLACEMENT KIT FOR THIS CELL AND ITS MANUFACTURING PROCESS
WO2003090334A2 (en) * 2002-04-22 2003-10-30 Proton Energy Systems, Inc. Method and apparatus for providing modular power
US7820949B2 (en) * 2002-05-14 2010-10-26 Honda Motor Co., Ltd. Method of starting, stopping and operating gas sensor with built-in heater
US20040009380A1 (en) * 2002-05-16 2004-01-15 Ballard Power Systems Inc. Adjustable array of fuel cell systems
US8188718B2 (en) * 2002-05-28 2012-05-29 Advanced Battery Management, Llc Method and apparatus for a remote battery charger with a self contained power source
JP4121315B2 (en) * 2002-06-11 2008-07-23 本田技研工業株式会社 Fuel cell
US7393369B2 (en) 2002-06-11 2008-07-01 Trulite, Inc. Apparatus, system, and method for generating hydrogen
US6974646B2 (en) * 2002-06-24 2005-12-13 Delphi Technologies, Inc. Solid-oxide fuel cell assembly having an electronic control unit within a structural enclosure
AU2002364240A1 (en) * 2002-06-28 2004-01-19 Foamex L.P. Gas diffusion layer for fuel cells
FI118553B (en) * 2002-06-28 2007-12-14 Enfucell Oy Apparatus and method for producing electric power and power source
US6960402B2 (en) * 2002-06-28 2005-11-01 Advanced Energy Technology Inc. Perforated cylindrical fuel cells
US6884745B2 (en) 2002-06-28 2005-04-26 Advanced Energy Technology Inc. Perforated cylindrical fuel cells
US20040001991A1 (en) * 2002-07-01 2004-01-01 Kinkelaar Mark R. Capillarity structures for water and/or fuel management in fuel cells
JP3951841B2 (en) * 2002-07-19 2007-08-01 トヨタ自動車株式会社 Fuel cell seal structure and manufacturing method thereof
DE10235431A1 (en) * 2002-08-02 2004-02-12 Proton Motor Fuel Cell Gmbh Electrical drive source for motor drive does not have direct voltage converter, but has controllable pre-chargeable circuit for pre-charging ultra-capacitor unit for temporary storage
US7045234B2 (en) * 2002-08-14 2006-05-16 Hewlett-Packard Development Company, L.P. Fuel-cell integral multifunction heater and methods
DK1396896T3 (en) * 2002-09-04 2017-07-31 Hexis Ag Room heating system with fuel cells and connection to a public electric grid
US20040062977A1 (en) * 2002-10-01 2004-04-01 Graftech, Inc. Fuel cell power packs and methods of making such packs
US7063912B2 (en) * 2002-11-01 2006-06-20 Deere & Company Fuel cell assembly system
US20040086775A1 (en) * 2002-11-06 2004-05-06 Lloyd Greg A. Fuel cell having a variable gas diffusion layer
US7329471B2 (en) * 2002-12-10 2008-02-12 General Electric Company Methods and apparatus for assembling solid oxide fuel cells
US20040126641A1 (en) * 2002-12-27 2004-07-01 Pearson Martin T. Regenerative fuel cell electric power plant and operating method
US20040191605A1 (en) * 2002-12-27 2004-09-30 Foamex L.P. Gas diffusion layer containing inherently conductive polymer for fuel cells
US7056608B2 (en) 2003-02-14 2006-06-06 Relion, Inc. Current collector for use in a fuel cell
US6806678B2 (en) 2003-02-20 2004-10-19 Relion, Inc. Battery charger
US20040180253A1 (en) * 2003-03-12 2004-09-16 Fisher John M. Fuel cell power system
US6939636B2 (en) * 2003-04-28 2005-09-06 Relion, Inc. Air cooled fuel cell module
US7799474B2 (en) * 2003-04-29 2010-09-21 Hewlett-Packard Development Company, L.P. System and method for managing electrically isolated fuel cell powered devices within an equipment rack
US20040219397A1 (en) * 2003-04-29 2004-11-04 Lyon Geoff M. Electrically isolated fuel cell powered server
US7378165B2 (en) * 2003-04-29 2008-05-27 Hewlett-Packard Development Company, L.P. System and method for providing electrical power to an equipment rack using a fuel cell
US7632583B2 (en) * 2003-05-06 2009-12-15 Ballard Power Systems Inc. Apparatus for improving the performance of a fuel cell electric power system
US7308510B2 (en) * 2003-05-07 2007-12-11 Intel Corporation Method and apparatus for avoiding live-lock in a multinode system
JP2006529054A (en) * 2003-05-09 2006-12-28 フォーメックス エル ピー Gas diffusion layer with carbon particle mixture
US7419734B2 (en) * 2003-05-16 2008-09-02 Ballard Power Systems, Inc. Method and apparatus for fuel cell systems
US6838923B2 (en) * 2003-05-16 2005-01-04 Ballard Power Systems Inc. Power supply and ultracapacitor based battery simulator
US20050004716A1 (en) * 2003-05-22 2005-01-06 Mark Lillis Method and apparatus for providing modular communications in a modular power system
DE10323883A1 (en) * 2003-05-26 2004-12-30 Siemens Ag Electrochemical battery
US7556660B2 (en) 2003-06-11 2009-07-07 James Kevin Shurtleff Apparatus and system for promoting a substantially complete reaction of an anhydrous hydride reactant
US20040265662A1 (en) * 2003-06-30 2004-12-30 Cyril Brignone System and method for heat exchange using fuel cell fluids
US7670707B2 (en) * 2003-07-30 2010-03-02 Altergy Systems, Inc. Electrical contacts for fuel cells
US7358005B2 (en) 2003-09-18 2008-04-15 General Electric Company Methods and apparatus for isolating solid oxide fuel cells
DE10356012A1 (en) * 2003-11-27 2005-06-30 Airbus Deutschland Gmbh Arrangement and method for producing water on board an aircraft
US7521138B2 (en) * 2004-05-07 2009-04-21 Ballard Power Systems Inc. Apparatus and method for hybrid power module systems
EP1624512A2 (en) 2004-08-05 2006-02-08 Pemeas GmbH Long-life membrane electrode assemblies
FR2875340B1 (en) * 2004-09-14 2006-11-17 Renault Sas DEVICE AND METHOD FOR MANAGING POWER SUPPLIES OF A FUEL CELL
WO2006053236A1 (en) 2004-11-12 2006-05-18 Trulite, Inc. Hydrogen generator cartridge
TWI237920B (en) * 2004-12-08 2005-08-11 Delta Electronics Inc Stacked fuel cell assembly
US7691502B2 (en) * 2005-03-15 2010-04-06 Jadoo Power Systems, Inc. Modular fuel cell power system, and technique for controlling and/or operating same
US20060228610A1 (en) * 2005-04-11 2006-10-12 Hsi-Ming Shu Card-insertion type of fuel cell apparatus
US20060228614A1 (en) * 2005-04-11 2006-10-12 Hsi-Ming Shu Assembly structure of clustering fuel cell
WO2006113985A1 (en) * 2005-04-27 2006-11-02 Hydrogenics Corporation Systems and methods for adaptive energy management in a fuel cell system
US7565535B2 (en) * 2005-05-06 2009-07-21 Microsoft Corporation Systems and methods for demonstrating authenticity of a virtual machine using a security image
US8046655B2 (en) * 2005-05-18 2011-10-25 Stmicroelectronics Pvt. Ltd. Area efficient memory architecture with decoder self test and debug capability
US7445647B1 (en) 2005-08-03 2008-11-04 Hydra Fuel Cell Corporation Method for making a single unit fuel cell
US7722972B2 (en) * 2005-08-17 2010-05-25 Relion, Inc. Apparatus and method for controlling a fuel cell using the rate of voltage recovery
US7798892B2 (en) * 2005-08-31 2010-09-21 Siemens Industry, Inc. Packaging method for modular power cells
US20070114850A1 (en) * 2005-11-18 2007-05-24 Relion, Inc. Power system and method for supplying electrical power to a load
US7833645B2 (en) 2005-11-21 2010-11-16 Relion, Inc. Proton exchange membrane fuel cell and method of forming a fuel cell
US20080032174A1 (en) * 2005-11-21 2008-02-07 Relion, Inc. Proton exchange membrane fuel cells and electrodes
CN100472872C (en) * 2006-02-01 2009-03-25 松下电器产业株式会社 Direct oxidation fuel cell and method for operating direct oxidation fuel cell system
US8962200B2 (en) * 2006-02-15 2015-02-24 Ford Motor Company Humidity measuring device and method
WO2007127195A2 (en) * 2006-04-24 2007-11-08 Jadoo Power Systems, Inc. Fuel cell power system having dock-type device, and technique for controlling and/or operating same
US7648786B2 (en) 2006-07-27 2010-01-19 Trulite, Inc System for generating electricity from a chemical hydride
US7651542B2 (en) 2006-07-27 2010-01-26 Thulite, Inc System for generating hydrogen from a chemical hydride
US7726177B2 (en) * 2007-03-06 2010-06-01 Detector Electronics Corporation Environmental hazard sensor
US20100035111A1 (en) * 2007-03-27 2010-02-11 Daihatsu Motor Co., Ltd. Fuel cell
US7764186B2 (en) * 2007-04-23 2010-07-27 J And N Enterprises Inc. Gas sensing method and instrument therefor
US8357214B2 (en) 2007-04-26 2013-01-22 Trulite, Inc. Apparatus, system, and method for generating a gas from solid reactant pouches
US8026020B2 (en) 2007-05-08 2011-09-27 Relion, Inc. Proton exchange membrane fuel cell stack and fuel cell stack module
US9293778B2 (en) 2007-06-11 2016-03-22 Emergent Power Inc. Proton exchange membrane fuel cell
TWI344716B (en) * 2007-06-22 2011-07-01 Young Green Energy Co Fuel cell module
WO2009015331A1 (en) 2007-07-25 2009-01-29 Trulite, Inc. Apparatus, system, and method to manage the generation and use of hybrid electric power
US20090080126A1 (en) * 2007-09-25 2009-03-26 Ise Corporation Energy Storage Device Coupler and Method
US8003274B2 (en) 2007-10-25 2011-08-23 Relion, Inc. Direct liquid fuel cell
DE102008019979B3 (en) 2008-04-21 2009-10-01 Futuree Fuel Cell Solutions Gmbh Power supply module and power cabinet
DE102008047399A1 (en) * 2008-09-16 2010-04-15 MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. Electrode device, generator device and method for generating electricity by membrane potential dissipation
US8409760B2 (en) * 2009-01-20 2013-04-02 Adaptive Materials, Inc. Method for controlling a water based fuel reformer
US8177884B2 (en) 2009-05-20 2012-05-15 United Technologies Corporation Fuel deoxygenator with porous support plate
GB0913836D0 (en) * 2009-08-07 2009-09-16 Afc Energy Plc Fuel cell
US20110215752A1 (en) * 2009-09-11 2011-09-08 Adaptive Materials, Inc. Fuel Cell Battery Charger
DE102009057494A1 (en) * 2009-12-10 2011-06-16 Fachhochschule Gelsenkirchen Device for energy conversion, in particular fuel cell stack or Elektrolyseurstack
US20110189578A1 (en) * 2010-02-01 2011-08-04 Adaptive Materials, Inc. Fuel cell system including a resilient manifold interconnecting member
EP2544283B1 (en) * 2010-03-02 2015-02-25 Toyota Jidosha Kabushiki Kaisha Fuel cell
US8796888B2 (en) 2010-07-07 2014-08-05 Adaptive Materials, Inc. Wearable power management system
JP5666396B2 (en) * 2011-07-14 2015-02-12 本田技研工業株式会社 Manufacturing method of metal separator for fuel cell
US8999599B2 (en) * 2011-07-19 2015-04-07 Panasonic Intellectual Property Management Co., Ltd. Method of fabricating membrane electrode assembly and gas diffusion layer
GB2499417A (en) 2012-02-15 2013-08-21 Intelligent Energy Ltd A fuel cell assembly
WO2014126595A1 (en) 2013-02-18 2014-08-21 Parker-Hannifin Corporation Modular fuel cell system
WO2018067506A1 (en) 2016-10-06 2018-04-12 Black & Decker Inc. Battery and motor system for replacing internal combustion engine
JP6804941B2 (en) * 2016-11-09 2020-12-23 日本碍子株式会社 Method of suppressing output deterioration of hybrid potential type gas sensor
KR20180055294A (en) 2016-11-16 2018-05-25 삼성전자주식회사 FBAR Oscillator and Gas Sensing System using the FBAR Oscillator
US11355807B2 (en) * 2020-01-17 2022-06-07 Bloom Energy Corporation Shippable battery module and method
CN111769312B (en) * 2020-07-20 2022-04-12 吉林大学 Fuel cell supply path decoupling control method based on pressure compensation

Family Cites Families (262)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2852554A (en) 1956-07-12 1958-09-16 Du Pont Alpha-sulfopolyfluoromonocarboxylic acids and derivatives hydrolyzable thereto
US3507702A (en) 1967-02-15 1970-04-21 United Aircraft Corp Fuel cell system including cooling and humidifying means
US3498844A (en) 1967-08-21 1970-03-03 United Aircraft Corp Fuel cell waste heat and water removal system
US3554803A (en) 1967-08-24 1971-01-12 Studebaker Corp Fuel cell designed for efficient stacking
US3528858A (en) 1968-12-04 1970-09-15 Gen Electric Sulfonated aryl-substituted polyphenylene ether ion exchange membranes
US3623913A (en) 1969-09-18 1971-11-30 Engelhard Min & Chem Fuel cell system
US3808534A (en) 1972-11-15 1974-04-30 United Aircraft Corp Intrinsically powered electronic monitor for fuel cells
US3823358A (en) 1973-06-18 1974-07-09 United Aircraft Corp Battery peaking unit for fuel cell power plants
US3975913A (en) 1973-12-20 1976-08-24 Erickson Donald C Gas generator and enhanced energy conversion systems
CH594292A5 (en) 1974-11-19 1978-01-13 Raffinage Cie Francaise
US4024036A (en) 1975-02-03 1977-05-17 Agency Of Industrial Science & Technology Proton permselective solid-state member and apparatus utilizing said permselective member
US3969145A (en) 1975-07-21 1976-07-13 United Technologies Corporation Fuel cell cooling system using a non-dielectric coolant
US3964930A (en) 1975-07-21 1976-06-22 United Technologies Corporation Fuel cell cooling system
US4000003A (en) * 1976-01-02 1976-12-28 The United States Of America As Represented By The Secretary Of The Army Fuel cell-secondary cell combination
CH608309A5 (en) 1976-05-28 1978-12-29 Raffinage Cie Francaise
CH608310A5 (en) 1976-05-28 1978-12-29 Raffinage Cie Francaise
US4035551A (en) 1976-09-01 1977-07-12 United Technologies Corporation Electrolyte reservoir for a fuel cell
FR2390021B1 (en) 1977-05-04 1980-11-28 Thomson Csf
US4185131A (en) 1978-06-28 1980-01-22 United Technologies Corporation Screen printing method for making an electrochemical cell electrode
US4287232A (en) 1978-06-28 1981-09-01 United Technologies Corporation Dry floc method for making an electrochemical cell electrode
US4192906A (en) 1978-07-10 1980-03-11 Energy Research Corporation Electrochemical cell operation and system
US4313338A (en) 1978-08-18 1982-02-02 Matsushita Electric Industrial Co., Ltd. Gas sensing device
US4219443A (en) 1978-12-20 1980-08-26 Gte Laboratories Incorporated Method of preparing a cathode current collector for use in an electrochemical cell
US4435252A (en) 1980-04-25 1984-03-06 Olin Corporation Method for producing a reticulate electrode for electrolytic cells
US4276355A (en) 1980-04-28 1981-06-30 Westinghouse Electric Corp. Fuel cell system configurations
US4469579A (en) 1981-06-26 1984-09-04 Diamond Shamrock Corporation Solid polymer electrolytes and electrode bonded with hydrophylic fluorocopolymers
US4624137A (en) 1981-10-09 1986-11-25 Honeywell Inc. Semiconductor device
US4463065A (en) 1982-02-02 1984-07-31 W. R. Grace & Co. Fuel cell and method for conducting gas-phase oxidation
JPS58165266A (en) 1982-03-26 1983-09-30 Hitachi Ltd Fuel cell
JPS58180936A (en) 1982-04-17 1983-10-22 Fuigaro Giken Kk Element for detecting combustion state and preparation thereof
US4500612A (en) 1982-04-21 1985-02-19 Mitsubishi Denki Kabushiki Kaisha Temperature control device for a fuel cell
GB2129237B (en) 1982-10-21 1986-06-25 Westinghouse Electric Corp Fuel cell protection circuits
US4510211A (en) 1983-06-17 1985-04-09 Struthers Ralph C Fuel cell electrolyte supply system and apparatus
US4476198A (en) 1983-10-12 1984-10-09 The United States Of America As Represented By The United States Department Of Energy Solid oxide fuel cell having monolithic core
US4598028A (en) 1985-02-13 1986-07-01 Westinghouse Electric Corp. High strength porous support tubes for high temperature solid electrolyte electrochemical cells
US4701739A (en) 1984-03-30 1987-10-20 Figaro Engineering Inc. Exhaust gas sensor and process for producing same
KR930000425B1 (en) 1984-10-17 1993-01-21 가부시기가이샤 히다찌세이사꾸쇼 Flexible fuel cell electrode plate
EP0275356B1 (en) 1984-10-23 1991-06-05 Mitsubishi Jukogyo Kabushiki Kaisha Solid electrolyte fuel cell and method for preparing it
JPS61147146A (en) 1984-12-20 1986-07-04 Fuigaro Giken Kk Lambda sensor
US4562124A (en) 1985-01-22 1985-12-31 Westinghouse Electric Corp. Air electrode material for high temperature electrochemical cells
US4648955A (en) 1985-04-19 1987-03-10 Ivac Corporation Planar multi-junction electrochemical cell
US4629537A (en) 1985-05-17 1986-12-16 Hsu Michael S Compact, light-weight, solid-oxide electrochemical converter
JPH0650293B2 (en) 1985-06-24 1994-06-29 フイガロ技研株式会社 Gas sensor
CA1262041A (en) 1985-06-28 1989-10-03 Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Natural Resources Canada Bonded hydrogen conducting solid electrolytes
US4795536A (en) 1985-07-10 1989-01-03 Allied-Signal Inc. Hydrogen separation and electricity generation using novel three-component membrane
US4816800A (en) 1985-07-11 1989-03-28 Figaro Engineering Inc. Exhaust gas sensor
JPS6217958A (en) 1985-07-16 1987-01-26 Sanyo Electric Co Ltd Control device for fuel cell power generation system
US4797185A (en) 1985-07-19 1989-01-10 Allied-Signal Inc. Hydrogen separation and electricity generation using novel electrolyte membrane
US4801211A (en) 1985-10-12 1989-01-31 Ngk Spark Plug Co., Ltd. Humidity and dew point detector
US4647359A (en) 1985-10-16 1987-03-03 Prototech Company Electrocatalytic gas diffusion electrode employing thin carbon cloth layer
US5037525A (en) 1985-10-29 1991-08-06 Commonwealth Scientific And Industrial Research Organisation Composite electrodes for use in solid electrolyte devices
JPS62172257A (en) 1986-01-27 1987-07-29 Figaro Eng Inc Proton conductor gas sensor
US4818735A (en) 1986-02-14 1989-04-04 National Institute For Research In Inorganic Materials Tetragonal system tunnel-structured compound AX(GA8MYGA(8+X)-YTI16-X0 56), and cation conductor and heat insulating material composed thereof
US4661411A (en) 1986-02-25 1987-04-28 The Dow Chemical Company Method for depositing a fluorocarbonsulfonic acid polymer on a support from a solution
US4702971A (en) 1986-05-28 1987-10-27 Westinghouse Electric Corp. Sulfur tolerant composite cermet electrodes for solid oxide electrochemical cells
US4767518A (en) 1986-06-11 1988-08-30 Westinghouse Electric Corp. Cermet electrode
US4755376A (en) 1986-08-25 1988-07-05 Institute Of Gas Technology Process for operating a dual compartment anode structure
US4797190A (en) 1986-10-06 1989-01-10 T And G. Corporation Ionic semiconductor materials and applications thereof
JPH067897B2 (en) 1986-10-20 1994-02-02 三洋電機株式会社 Air purifier controller
US4728584A (en) 1986-10-21 1988-03-01 Westinghouse Electric Corp. Fuel cell generator containing self-supporting high gas flow solid oxide electrolyte fuel cells
US4749632A (en) 1986-10-23 1988-06-07 The United States Of America As Represented By The United States Department Of Energy Sintering aid for lanthanum chromite refractories
DE3780560T2 (en) 1986-10-28 1992-12-10 Figaro Eng PROBE AND METHOD FOR THE PRODUCTION THEREOF.
DE3640206A1 (en) 1986-11-25 1988-06-01 Basf Ag METHANOL / AIR FUEL CELL BATTERIES WITH HIGH ENERGY AND PERFORMANCE DENSITY
US4851303A (en) 1986-11-26 1989-07-25 Sri-International Solid compositions for fuel cells, sensors and catalysts
US4816036A (en) 1986-12-15 1989-03-28 Allied-Signal Inc. Fabrication of ceramic trilayers for a monolithic solid oxide fuel cell
US4876115A (en) 1987-01-30 1989-10-24 United States Department Of Energy Electrode assembly for use in a solid polymer electrolyte fuel cell
US4770955A (en) 1987-04-28 1988-09-13 The Standard Oil Company Solid electrolyte fuel cell and assembly
US4849253A (en) 1987-05-29 1989-07-18 International Fuel Cell Corporation Method of making an electrochemical cell electrode
US4826741A (en) 1987-06-02 1989-05-02 Ergenics Power Systems, Inc. Ion exchange fuel cell assembly with improved water and thermal management
US4795683A (en) 1987-07-23 1989-01-03 United Technologies Corporation High power density evaporatively cooled ion exchange membrane fuel cell
JPS6451331A (en) 1987-08-20 1989-02-27 Kureha Chemical Ind Co Ltd Proton-conductive substance and its production
US4804592A (en) 1987-10-16 1989-02-14 The United States Of America As Represented By The United States Department Of Energy Composite electrode for use in electrochemical cells
US4769297A (en) 1987-11-16 1988-09-06 International Fuel Cells Corporation Solid polymer electrolyte fuel cell stack water management system
US4826742A (en) 1988-01-21 1989-05-02 International Fuel Cells Corporation Water and heat management in solid polymer fuel cell stack
JP2741381B2 (en) 1988-02-04 1998-04-15 フィガロ技研株式会社 Gas detector
US4824741A (en) 1988-02-12 1989-04-25 International Fuel Cells Corporation Solid polymer electrolyte fuel cell system with porous plate evaporative cooling
US4973531A (en) 1988-02-19 1990-11-27 Ishikawajima-Harima Heavy Industries Co., Ltd. Arrangement for tightening stack of fuel cell elements
US4847172A (en) 1988-02-22 1989-07-11 Westinghouse Electric Corp. Low resistance fuel electrodes
US4883497A (en) 1988-03-28 1989-11-28 Arch Development Corporation Formation of thin walled ceramic solid oxide fuel cells
US4943494A (en) 1988-04-22 1990-07-24 The United States Of America As Represented By The United States Department Of Energy Solid oxide fuel cell matrix and modules
US4818637A (en) 1988-05-20 1989-04-04 United Technologies Corporation Hydrogen/halogen fuel cell with improved water management system
JPH02193053A (en) 1988-07-14 1990-07-30 Figaro Eng Inc Exhaust gas sensor and manufacture thereof
US4863813A (en) 1988-09-15 1989-09-05 Bell Communications Research, Inc. Primary source of electrical energy using a mixture of fuel and oxidizer
DE3837814C1 (en) 1988-11-08 1989-11-23 Mtu Friedrichshafen Gmbh
US5035961A (en) 1989-07-05 1991-07-30 Combustion Engineering, Inc. Internal cross-anchoring and reinforcing of multi-layer conductive oxides
EP0406523A1 (en) 1989-07-07 1991-01-09 Osaka Gas Co., Ltd. Fuel cell
US5130210A (en) 1989-08-25 1992-07-14 Tonen Corporation Stabilized zirconia solid electrolyte and process for preparation thereof
US4994331A (en) 1989-08-28 1991-02-19 International Fuel Cells Corporation Fuel cell evaporative cooling using fuel as a carrier gas
US4973530A (en) 1989-12-21 1990-11-27 The United States Of America As Represented By The United States Department Of Energy Fuel cell water transport
US5045414A (en) 1989-12-29 1991-09-03 International Fuel Cells Corporation Reactant gas composition for fuel cell potential control
JP2528988B2 (en) 1990-02-15 1996-08-28 日本碍子株式会社 Solid oxide fuel cell
US5069985A (en) 1990-02-15 1991-12-03 International Fuel Cells Corporation Plaque fuel cell stack
US5223353A (en) 1990-03-16 1993-06-29 Ricoh Company, Ltd. Solid electrolyte, electrochemical device including the same and method of fabricating the solid electrolyte
US5035962A (en) 1990-03-21 1991-07-30 Westinghouse Electric Corp. Layered method of electrode for solid oxide electrochemical cells
JPH03274672A (en) 1990-03-26 1991-12-05 Ngk Insulators Ltd Solid electrolyte type fuel cell
US5059497A (en) 1990-04-20 1991-10-22 Hughes Aircraft Company Composite ion-conductive electrolyte member
US5169731A (en) 1990-04-24 1992-12-08 Yoshida Kogyo K.K. Solid oxide fuel cell and method for manufacturing the same
US4988582A (en) 1990-05-04 1991-01-29 Bell Communications Research, Inc. Compact fuel cell and continuous process for making the cell
US5244753A (en) 1990-05-29 1993-09-14 Matsushita Electric Industrial Co., Ltd. Solid electrolyte fuel cell and method for manufacture of same
JPH0443566A (en) 1990-06-06 1992-02-13 Murata Mfg Co Ltd Solid electrolyte type fuel cell
US5164060A (en) 1990-06-11 1992-11-17 The Dow Chemical Company Ion exchange membrane having increased efficiency in proton exchange processes
US5302269A (en) 1990-06-11 1994-04-12 The Dow Chemical Company Ion exchange membrane/electrode assembly having increased efficiency in proton exchange processes
US5069987A (en) 1990-07-06 1991-12-03 Igr Enterprises, Inc. Solid oxide fuel cell assembly
JPH07118327B2 (en) 1990-07-07 1995-12-18 日本碍子株式会社 Solid oxide fuel cell and porous electrode body used therefor
JPH0697613B2 (en) 1990-07-12 1994-11-30 日本碍子株式会社 Method for producing air electrode material for solid oxide fuel cell
US5154987A (en) 1990-07-17 1992-10-13 The United States Of America As Represented By The United States Department Of Energy Highly conductive electrolyte composites containing glass and ceramic, and method of manufacture
US5084144A (en) 1990-07-31 1992-01-28 Physical Sciences Inc. High utilization supported catalytic metal-containing gas-diffusion electrode, process for making it, and cells utilizing it
US5132193A (en) 1990-08-08 1992-07-21 Physical Sciences, Inc. Generation of electricity with fuel cell using alcohol fuel
US5395705A (en) 1990-08-31 1995-03-07 The Dow Chemical Company Electrochemical cell having an electrode containing a carbon fiber paper coated with catalytic metal particles
JP2572883B2 (en) 1990-09-04 1997-01-16 日本碍子株式会社 Solid electrolyte membrane, solid electrolyte fuel cell having the same, and methods of manufacturing these
JPH04118861A (en) 1990-09-10 1992-04-20 Fuji Electric Co Ltd Solid electrolyte type fuel cell and its manufacture
US5290642A (en) 1990-09-11 1994-03-01 Alliedsignal Aerospace Method of fabricating a monolithic solid oxide fuel cell
US5162167A (en) 1990-09-11 1992-11-10 Allied-Signal Inc. Apparatus and method of fabricating a monolithic solid oxide fuel cell
JPH053037A (en) 1990-10-03 1993-01-08 Fuji Electric Co Ltd Solid electrolyte type fuel cell
US5106706A (en) 1990-10-18 1992-04-21 Westinghouse Electric Corp. Oxide modified air electrode surface for high temperature electrochemical cells
US5143801A (en) 1990-10-22 1992-09-01 Battelle Memorial Institute Solid oxide fuel cells, and air electrode and electrical interconnection materials therefor
GB9023091D0 (en) 1990-10-24 1990-12-05 Ici Plc Composite membranes and electrochemical cells containing them
US5047298A (en) 1990-11-13 1991-09-10 Perry Oceanographics, Inc. Closed loop reactant/product management system for electrochemical galvanic energy devices
US5256499A (en) 1990-11-13 1993-10-26 Allied Signal Aerospace Monolithic solid oxide fuel cells with integral manifolds
US5192627A (en) 1990-11-13 1993-03-09 Energy Partners, Inc. Closed loop reactant/product management system for electrochemical galvanic energy device
DE4193026T1 (en) 1990-11-23 1993-10-07 Vickers Shipbuilding & Eng Use of fuel cells in energy generation systems
WO1992010862A1 (en) 1990-12-10 1992-06-25 Yuasa Battery Co., Ltd. Method for manufacturing solid-state electrolytic fuel cell
CH679620A5 (en) 1990-12-11 1992-03-13 Sulzer Ag
US5186806A (en) 1990-12-31 1993-02-16 California Institute Of Technology Ceramic distribution members for solid state electrolyte cells and method of producing
US5366818A (en) 1991-01-15 1994-11-22 Ballard Power Systems Inc. Solid polymer fuel cell systems incorporating water removal at the anode
DK167163B1 (en) 1991-02-13 1993-09-06 Risoe Forskningscenter FAST OXIDE FUEL CELLS FOR OXIDATION OF CH4
US5234777A (en) 1991-02-19 1993-08-10 The Regents Of The University Of California Membrane catalyst layer for fuel cells
JP3295945B2 (en) 1991-02-22 2002-06-24 株式会社村田製作所 Distributor of solid oxide fuel cell and method of manufacturing the same
US5200278A (en) 1991-03-15 1993-04-06 Ballard Power Systems, Inc. Integrated fuel cell power generation system
US5154986A (en) 1991-03-22 1992-10-13 Yamaha Hatsudoki Kabushiki Kaisha Shut-off device for fuel cell system
JP2945157B2 (en) 1991-03-27 1999-09-06 日本碍子株式会社 Solid oxide fuel cell and method of manufacturing the same
JPH0748378B2 (en) 1991-03-28 1995-05-24 日本碍子株式会社 Air electrode for solid electrolyte fuel cell and solid electrolyte fuel cell having the same
JPH05135787A (en) 1991-03-28 1993-06-01 Ngk Insulators Ltd Manufacture of solid electrolyte film and manufacture of solid electrolyte fuel cell
EP0524326B1 (en) 1991-07-20 1995-03-15 Osaka Gas Co., Ltd. Fuel cell
US5219673A (en) 1991-08-23 1993-06-15 Kaun Thomas D Cell structure for electrochemical devices and method of making same
JPH06176771A (en) 1991-09-13 1994-06-24 Tanaka Kikinzoku Kogyo Kk Structure of ion-exchange membrane for fuel cell
US5252410A (en) 1991-09-13 1993-10-12 Ballard Power Systems Inc. Lightweight fuel cell membrane electrode assembly with integral reactant flow passages
US5292599A (en) 1991-09-27 1994-03-08 Ngk Insulators, Ltd. Cell units for solid oxide fuel cells and power generators using such cell units
US5200279A (en) 1991-10-11 1993-04-06 Westinghouse Electric Corp. Solid oxide fuel cell generator
US5232794A (en) 1991-10-17 1993-08-03 The United States Of America As Represented By The United States Department Of Energy Ionic conductors for solid oxide fuel cells
US5213911A (en) 1991-10-17 1993-05-25 The United States Of America As Represented By The United States Department Of Energy Solid-oxide fuel cell electrolyte
JPH05144444A (en) 1991-11-25 1993-06-11 Toshiba Corp Fuel cell and electrode manufacturing method
US5248566A (en) 1991-11-25 1993-09-28 The United States Of America As Represented By The United States Department Of Energy Fuel cell system for transportation applications
JP2989353B2 (en) * 1991-11-29 1999-12-13 三洋電機株式会社 Hybrid fuel cell system
US5372895A (en) 1991-12-12 1994-12-13 Yoshida Kogyo K.K. Solid oxide fuel cell and method for manufacturing the same
US5298235A (en) 1991-12-16 1994-03-29 The Trustees Of The University Of Pennsylvania Electrochemical devices based on single-component solid oxide bodies
US5318863A (en) 1991-12-17 1994-06-07 Bcs Technology, Inc. Near ambient, unhumidified solid polymer fuel cell
US5242764A (en) 1991-12-17 1993-09-07 Bcs Technology, Inc. Near ambient, unhumidified solid polymer fuel cell
JPH05174852A (en) 1991-12-17 1993-07-13 Yoshida Kogyo Kk <Ykk> Conductive connecting material for solid electrolyte fuel cell
WO1993013566A1 (en) 1991-12-26 1993-07-08 International Fuel Cells, Inc. Plate-shaped fuel cell component and a method of making the same
US5262249A (en) 1991-12-26 1993-11-16 International Fuel Cells Corporation Internally cooled proton exchange membrane fuel cell device
US5264299A (en) 1991-12-26 1993-11-23 International Fuel Cells Corporation Proton exchange membrane fuel cell support plate and an assembly including the same
JP2527876B2 (en) 1992-01-17 1996-08-28 日本碍子株式会社 Method for manufacturing solid oxide fuel cell
US5187025A (en) 1992-02-03 1993-02-16 Analytic Power Corp. Unitized fuel cell structure
JP3245929B2 (en) 1992-03-09 2002-01-15 株式会社日立製作所 Fuel cell and its application device
JP3352716B2 (en) 1992-03-31 2002-12-03 株式会社東芝 Solid polymer electrolyte fuel cell device
US5364711A (en) 1992-04-01 1994-11-15 Kabushiki Kaisha Toshiba Fuel cell
US5272017A (en) 1992-04-03 1993-12-21 General Motors Corporation Membrane-electrode assemblies for electrochemical cells
TW269058B (en) 1992-04-29 1996-01-21 Westinghouse Electric Corp
US5399184A (en) * 1992-05-01 1995-03-21 Chlorine Engineers Corp., Ltd. Method for fabricating gas diffusion electrode assembly for fuel cells
US5266421A (en) 1992-05-12 1993-11-30 Hughes Aircraft Company Enhanced membrane-electrode interface
JP3151933B2 (en) 1992-05-28 2001-04-03 株式会社村田製作所 Solid oxide fuel cell
JP3448876B2 (en) 1992-05-28 2003-09-22 株式会社村田製作所 Solid oxide fuel cell
US5350643A (en) 1992-06-02 1994-09-27 Hitachi, Ltd. Solid polymer electrolyte type fuel cell
SG73410A1 (en) 1992-06-13 2000-06-20 Hoechst Ag Polymer electrolyte membrane and process for the production thereof
JP3135991B2 (en) * 1992-06-18 2001-02-19 本田技研工業株式会社 Fuel cell and fuel cell stack tightening method
GB2268619B (en) 1992-07-01 1995-06-28 Rolls Royce & Ass A fuel cell
ATE137361T1 (en) 1992-07-16 1996-05-15 Siemens Ag MATERIAL FOR THE METALLIC COMPONENTS OF HIGH TEMPERATURE FUEL CELL SYSTEMS
US5292600A (en) 1992-08-13 1994-03-08 H-Power Corp. Hydrogen power cell
US5336570A (en) 1992-08-21 1994-08-09 Dodge Jr Cleveland E Hydrogen powered electricity generating planar member
US5330859A (en) 1992-08-24 1994-07-19 University Of Chicago Solid oxide fuel cell with single material for electrodes and interconnect
US5306574A (en) 1992-10-07 1994-04-26 Westinghouse Electric Corp. Method of low temperature operation of an electrochemical cell array
US5273838A (en) 1992-10-07 1993-12-28 Westinghouse Electric Corp. Double interconnection fuel cell array
US5382478A (en) 1992-11-03 1995-01-17 Ballard Power Systems Inc. Electrochemical fuel cell stack with humidification section located upstream from the electrochemically active section
US5395704A (en) 1992-11-19 1995-03-07 North Western Univ. Technology Transfer Prog. Solid-oxide fuel cells
US5304430A (en) 1993-02-22 1994-04-19 Hughes Aircraft Company Acid-base concentration cell for electric power generation
CA2124839C (en) 1993-02-26 1997-10-07 Yasuhide Noaki An ion exchange membrane used for a fuel cell
US5403461A (en) 1993-03-10 1995-04-04 Massachusetts Institute Of Technology Solid electrolyte-electrode system for an electrochemical cell
US5356730A (en) 1993-03-26 1994-10-18 Alliedsignal Inc. Monolithic fuel cell having improved interconnect layer
US5403675A (en) 1993-04-09 1995-04-04 Maxdem, Incorporated Sulfonated polymers for solid polymer electrolytes
US5338622A (en) 1993-04-12 1994-08-16 Ztek Corporation Thermal control apparatus
US5356728A (en) 1993-04-16 1994-10-18 Amoco Corporation Cross-flow electrochemical reactor cells, cross-flow reactors, and use of cross-flow reactors for oxidation reactions
US5330860A (en) 1993-04-26 1994-07-19 E. I. Du Pont De Nemours And Company Membrane and electrode structure
US5342705A (en) 1993-06-04 1994-08-30 Allied-Signal, Inc. Monolithic fuel cell having a multilayer interconnect
DE4324907A1 (en) 1993-07-24 1995-01-26 Dornier Gmbh Interconnection of fuel cells
US5372896A (en) 1993-09-20 1994-12-13 The United States Of America As Represented By The Secretary Of The Army Treated solid polymer electrolyte membrane for use in a fuel cell and fuel cell including the treated solid polymer electrolyte membrane
US5599638A (en) 1993-10-12 1997-02-04 California Institute Of Technology Aqueous liquid feed organic fuel cell using solid polymer electrolyte membrane
US5358620A (en) 1993-10-13 1994-10-25 Valence Technology, Inc. Allyl polyelectrolytes
US5470671A (en) 1993-12-22 1995-11-28 Ballard Power Systems Inc. Electrochemical fuel cell employing ambient air as the oxidant and coolant
GB9402887D0 (en) 1994-02-15 1994-04-06 Univ Napier Modular fuel cell stack design with particular reference to planar solid oxide fuel cell technology
US5547777A (en) 1994-02-23 1996-08-20 Richards Engineering Fuel cell having uniform compressive stress distribution over active area
BE1008456A3 (en) 1994-06-07 1996-05-07 Vito METHOD FOR MANUFACTURING AN ELECTRODE GAS DIFFUSION.
US5773160A (en) 1994-06-24 1998-06-30 Ballard Power Systems Inc. Electrochemical fuel cell stack with concurrent flow of coolant and oxidant streams and countercurrent flow of fuel and oxidant streams
JPH0817451A (en) 1994-06-29 1996-01-19 Aisin Seiki Co Ltd Fuel cell
DE4422409C2 (en) 1994-06-29 1996-07-11 Fraunhofer Ges Forschung Device for the exchange of charges between a plurality of energy stores or converters connected in series
DE4427077C1 (en) 1994-07-30 1996-03-21 Fraunhofer Ges Forschung Device for the exchange of charges between a plurality of energy stores or converters connected in pure
JP3487009B2 (en) * 1994-08-05 2004-01-13 株式会社デンソー Oxygen sensor heater control device
DE4433102A1 (en) 1994-09-16 1996-03-21 Fraunhofer Ges Forschung Electrode arrangement for signal detection of gas sensitive layers
US5783324A (en) 1994-10-06 1998-07-21 The United States Of America As Represented By The Secretary Of The Army Fuel cell including a single sheet of a polymer electrolyte membrane (PEM), the PEM being divided into regions of varying electrical and ionic conductivity
US5863671A (en) 1994-10-12 1999-01-26 H Power Corporation Plastic platelet fuel cells employing integrated fluid management
US5523177A (en) 1994-10-12 1996-06-04 Giner, Inc. Membrane-electrode assembly for a direct methanol fuel cell
RU2174728C2 (en) 1994-10-12 2001-10-10 Х Пауэр Корпорейшн Fuel cell using integrated plate technology for liquid-distribution
US5521020A (en) 1994-10-14 1996-05-28 Bcs Technology, Inc. Method for catalyzing a gas diffusion electrode
US5507175A (en) 1994-10-21 1996-04-16 Protimeter, Inc. Cycling chilled mirror dewpoint hygrometer including a sapphire optical mirror
US5525436A (en) 1994-11-01 1996-06-11 Case Western Reserve University Proton conducting polymers used as membranes
DE4443945C1 (en) 1994-12-09 1996-05-23 Fraunhofer Ges Forschung PEM fuel cell
US5514487A (en) 1994-12-27 1996-05-07 Ballard Power Systems Inc. Edge manifold assembly for an electrochemical fuel cell stack
DE19513292C1 (en) 1995-04-07 1996-08-22 Siemens Ag Polymer electrolyte membrane fuel cell
DE69614632T2 (en) 1995-04-12 2002-02-07 Int Fuel Cells Corp FUEL PROCESS APPARATUS WITH OVEN FOR FUEL CELL POWER PLANT
US5726105A (en) 1995-04-20 1998-03-10 International Fuel Cells Composite article
US5654109A (en) 1995-06-30 1997-08-05 The Dow Chemical Company Composite fuel cell membranes
US5599639A (en) 1995-08-31 1997-02-04 Hoechst Celanese Corporation Acid-modified polybenzimidazole fuel cell elements
US5716506A (en) 1995-10-06 1998-02-10 Board Of Trustees Of The University Of Illinois Electrochemical sensors for gas detection
US5607785A (en) 1995-10-11 1997-03-04 Tanaka Kikinzoku Kogyo K.K. Polymer electrolyte electrochemical cell and process of preparing same
US5925322A (en) 1995-10-26 1999-07-20 H Power Corporation Fuel cell or a partial oxidation reactor or a heat engine and an oxygen-enriching device and method therefor
JP3570644B2 (en) 1995-11-14 2004-09-29 フィガロ技研株式会社 Gas sensor
US5672439A (en) 1995-12-18 1997-09-30 Ballard Power Systems, Inc. Method and apparatus for reducing reactant crossover in an electrochemical fuel cell
US5863673A (en) 1995-12-18 1999-01-26 Ballard Power Systems Inc. Porous electrode substrate for an electrochemical fuel cell
US5624769A (en) 1995-12-22 1997-04-29 General Motors Corporation Corrosion resistant PEM fuel cell
GB9526393D0 (en) 1995-12-22 1996-02-21 Capteur Sensors & Analysers Gas sensing
US5716664A (en) 1995-12-22 1998-02-10 Marchetti; George A. Method of making a hydrophilic, graphite electrode membrane assembly
US6106965A (en) * 1996-03-29 2000-08-22 Mazda Motor Corporation Polymer electrolyte fuel cell
JP3215650B2 (en) 1996-05-23 2001-10-09 日本碍子株式会社 Electrochemical cell, method for producing the same, and electrochemical device
US5798186A (en) 1996-06-07 1998-08-25 Ballard Power Systems Inc. Method and apparatus for commencing operation of a fuel cell electric power generation system below the freezing temperature of water
US5677074A (en) 1996-06-25 1997-10-14 The Dais Corporation Gas diffusion electrode
US5763113A (en) 1996-08-26 1998-06-09 General Motors Corporation PEM fuel cell monitoring system
US5783325A (en) 1996-08-27 1998-07-21 The Research Foundation Of State Of New York Gas diffusion electrodes based on poly(vinylidene fluoride) carbon blends
US5739416A (en) 1996-09-18 1998-04-14 California Instiute Of Technology Fast, high sensitivity dewpoint hygrometer
US6007932A (en) 1996-10-16 1999-12-28 Gore Enterprise Holdings, Inc. Tubular fuel cell assembly and method of manufacture
US5789091C1 (en) 1996-11-19 2001-02-27 Ballard Power Systems Electrochemical fuel cell stack with compression bands
US5707755A (en) 1996-12-09 1998-01-13 General Motors Corporation PEM/SPE fuel cell
US5804326A (en) 1996-12-20 1998-09-08 Ballard Power Systems Inc. Integrated reactant and coolant fluid flow field layer for an electrochemical fuel cell
US5759712A (en) 1997-01-06 1998-06-02 Hockaday; Robert G. Surface replica fuel cell for micro fuel cell electrical power pack
US6028414A (en) 1997-01-29 2000-02-22 H Power Enterprises Of Canada Inc. Fuel cell stand-by energy supply system
JP3077618B2 (en) 1997-03-05 2000-08-14 富士電機株式会社 Solid polymer electrolyte fuel cell
US6051192A (en) 1997-04-15 2000-04-18 International Fuel Cells Corporation Control system and method for controlling a gas generating system
US5916699A (en) 1997-05-13 1999-06-29 Motorola, Inc. Hybrid energy storage system
WO1998056058A1 (en) * 1997-06-06 1998-12-10 Volkswagen Aktiengesellschaft Fuel cell methanol reformer with an energy storage unit and method for controlling the energy flow of the system
US5989741A (en) 1997-06-10 1999-11-23 E.I. Du Pont De Nemours And Company Electrochemical cell system with side-by-side arrangement of cells
US5776625A (en) 1997-06-18 1998-07-07 H Power Corporation Hydrogen-air fuel cell
US6001499A (en) 1997-10-24 1999-12-14 General Motors Corporation Fuel cell CO sensor
US6030718A (en) 1997-11-20 2000-02-29 Avista Corporation Proton exchange membrane fuel cell power system
US6096449A (en) 1997-11-20 2000-08-01 Avista Labs Fuel cell and method for controlling same
US5935726A (en) 1997-12-01 1999-08-10 Ballard Power Systems Inc. Method and apparatus for distributing water to an ion-exchange membrane in a fuel cell
US6051329A (en) 1998-01-15 2000-04-18 International Business Machines Corporation Solid oxide fuel cell having a catalytic anode
US6051330A (en) 1998-01-15 2000-04-18 International Business Machines Corporation Solid oxide fuel cell having vias and a composite interconnect
JPH11224679A (en) * 1998-02-06 1999-08-17 Matsushita Electric Ind Co Ltd Solid high polymer fuel cell and its manufacture
US5945232A (en) * 1998-04-03 1999-08-31 Plug Power, L.L.C. PEM-type fuel cell assembly having multiple parallel fuel cell sub-stacks employing shared fluid plate assemblies and shared membrane electrode assemblies
US6024848A (en) 1998-04-15 2000-02-15 International Fuel Cells, Corporation Electrochemical cell with a porous support plate
US6007933A (en) 1998-04-27 1999-12-28 Plug Power, L.L.C. Fuel cell assembly unit for promoting fluid service and electrical conductivity
DE69930347T2 (en) * 1998-05-04 2006-11-30 Samsung SDI Co., Ltd., Suwon A process for producing a suspension for forming a catalyst layer for a proton exchange membrane fuel cell
US6015634A (en) 1998-05-19 2000-01-18 International Fuel Cells System and method of water management in the operation of a fuel cell
US6007931A (en) 1998-06-24 1999-12-28 International Fuel Cells Corporation Mass and heat recovery system for a fuel cell power plant
US6080501A (en) 1998-06-29 2000-06-27 Motorola, Inc. Fuel cell with integral fuel storage
JP2000036308A (en) * 1998-07-16 2000-02-02 Toyota Motor Corp Fuel cell system
US6210823B1 (en) 1998-08-19 2001-04-03 Matsushita Electric Industrial Co. Ltd. Polymer electrolyte fuel cell
US6127058A (en) * 1998-10-30 2000-10-03 Motorola, Inc. Planar fuel cell
US6126311A (en) 1998-11-02 2000-10-03 Claud S. Gordon Company Dew point sensor using mems
US6073479A (en) 1998-11-13 2000-06-13 General Electric Company Dewpoint sensor
US6326763B1 (en) * 1999-12-20 2001-12-04 General Electric Company System for controlling power flow in a power bus generally powered from reformer-based fuel cells
US6852434B2 (en) 1999-12-23 2005-02-08 Ballard Power Systems Inc. Fuel cell assembly with an improved gas sensor
US6468682B1 (en) 2000-05-17 2002-10-22 Avista Laboratories, Inc. Ion exchange membrane fuel cell

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