CA2380987A1 - Stabilized medium and high voltage cable insulation composition - Google Patents

Stabilized medium and high voltage cable insulation composition Download PDF

Info

Publication number
CA2380987A1
CA2380987A1 CA002380987A CA2380987A CA2380987A1 CA 2380987 A1 CA2380987 A1 CA 2380987A1 CA 002380987 A CA002380987 A CA 002380987A CA 2380987 A CA2380987 A CA 2380987A CA 2380987 A1 CA2380987 A1 CA 2380987A1
Authority
CA
Canada
Prior art keywords
tert
20alkyl
phenyl
octyldiphenylamine
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002380987A
Other languages
French (fr)
Other versions
CA2380987C (en
Inventor
Wolfgang Voigt
John Kenny
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of CA2380987A1 publication Critical patent/CA2380987A1/en
Application granted granted Critical
Publication of CA2380987C publication Critical patent/CA2380987C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes

Abstract

The invention relates to a polyethylene composition for use as insulation for wire and cable that has improved scorch resistance comprising (a) a polyethylene (b) a scorch inhibitor having a melting point below 50 °C at atmospheric pressure, and (c) an organic peroxide.

Claims (10)

1. A composition comprising (a) a polyethylene (b) a scorch inhibitor having a melting point below 50 °C at atmospheric pressure, and (c) an organic peroxide.
2. A composition according to claim 1, wherein the scorch inhibitor is a compound of the formula I

wherein R1 is C1-20alkyl or C1-20alkyl which is substituted by phenyl, C2-20alkenyl, C3-20alkinyl, C5-9cycloalkyl, phenyl or tolyl;
R2 and R3 each independently of the other are:
C1-20alkyl or C1-20alkyl which is substituted by the following radicals:
phenyl, one or two hydroxyl, cyano, formyl, acetyl, -O-COR5; R5 is C1-20alkyl;
C2-20alkenyl;
C3-20alkinyl;
C5-7cycloalkyl or C5-7cycloalkyl which is substituted by hydroxyl;
phenyl, 4-chlorophenyl, 2-methoxycarbonylphenyl, p-tolyl, 1,3-benzthiazol-2-yl, or -(CHR6)n COOR7 or -(CHR6)n CONR8R9 with n is 1 or 2, R6 is hydrogen or C1-6alkyl, R7 is C1-20alkyl, C1-20alkyl which is interrupted by one to five O or S, C5-7cycloalkyl, phenyl, benzyl, tolyl, R8 and R9 are hydrogen or C1-6alkyl;
R4 is hydrogen or methyl.
3. A composition according to claim 2, wherein R1 is C1-20alkyl, and R2 and R3 are identical and are C1-20alkyl or C1-20alky substituted by one or two hydroxyl.
4. A composition according to claim 2 or 3, wherein the scorch inhibitor of formula I is 2,4-bis(n-octylthiomethyl)-6-methylphenol or 2,4-bis(n-dodecylthiomethyl)-6-methylphenol.
5. A composition according to claim 1, wherein the scorch inhibitor is a compound of the formula II or III or mixtures thereof wherein R1 is C1-20alkyl or C1-20alkyl which is substituted by phenyl, C2-20alkenyl, C3-20alkinyl, C5-9cycloalkyl, phenyl or tolyl;
R2 and R3 each independently of the other are:
C1-20alkyl or C1-20alkyl which is substituted by the following radicals:
phenyl, one or two hydroxyl, cyano, formyl, acetyl, -O-COR5; R5 is C1-20alkyl;
C2-20alkenyl;
C3-20alkinyl;
C5-7cycloalkyl or C5-7cycloalkyl which is substituted by hydroxyl;
phenyl, 4-chlorophenyl, 2-methoxycarbonylphenyl, p-tolyl, 1,3-benzthiazol-2-yl, or -(CHR6)n COOR7 or -(CHR6)n CONR8R9 with n is 1 or 2, R6 is hydrogen or C1-6alkyl, R7 is C1-20alkyl, C1-20alkyl which is interrupted by one to five O or S, C5-7cycloalkyl, phenyl, benzyl, tolyl, R8 and R9 are hydrogen or C1-6alkyl;
R4 is hydrogen or methyl; and Z is -S-, -CH2-, -CH(CH3)- or -C(CH3)2-.
6. A composition according to claim 1, wherein the scorch inhibitor is a mixture containing an amine selected from diphenylamine, 4-tert.-butyldiphenylamine, 4-tert.-octyldipenylamine, 4,4'-di-tert.-butyldiphenylamine, 2,4,4'-tris-tert.-butyldiphenylamine, 4-tert.-butyl-4'-tert.-octyl-diphenylamine, o,o'-, m,m'- or p,p'-di-tert.-octyldiphenylamine, 2,4-di-tert.-butyl-4'-tert.-octyl-diphenylamine, 4,4'-di-tert.-octyldiphenylamine, 2,4-di-tert.-octyl-4'-tert.-butyldiphenylamine, and in addition a phenol according to formula I, II, or III according to claims 2 and 5 or a phenol selected from the following phenols:

7. A composition according to claim 6, wherein the amine is 4,4'-di-tert.-octyldiphenylamine or Amine (A) which is a mixture of: 3wt% diphenylamine, 14wt% 4-tert.-butyldiphenylamine, 30wt% (4-tert.-octyldiphenylamine 4,4'-di-tert.-butyldiphenylamine and 2,4,4'-tris-tert.-butyl-diphenylamine), 29wt% (4-tert.-butyl-4'-tert.-octyldiphenylamine, o,o', m,m' or p,p'-di-tert.-octyldiphenylamine and 2,4-di-tert.-butyl-4'-tert.-octyldiphenylamine), 18wt%
4,4'-di-tert.-octyldiphenylamine and 6wt% 2,4-di-tert.-octyl-4'-tert.-butyldiphenylamine.
8. A composition according to claim 6, wherein the scorch inhibitor is a mixture of 80wt%
4,4'-di-tert.-octyldiphenylamine and 20wt% of Phenol P.
9. A composition according to claim 1, wherein the amount of scorch inhibitor is in the range from 0.01 to 1wt% and the amount of the peroxide is in the range from 0.5 to 5 wt%.
10. A process for preparing a crosslinked polyethylene composition whereby the polyethylene or the polyethylene/peroxide blend is introduced into an extruder and the scorch inhibitor having a melting point below 50 °C or the scorch inhibitor and the peroxide is added to said extruder and whereby the extrudate is then crosslinked by exposing it to a temperature greater than the decomposition temperature of which the organic peroxide decomposes.
CA2380987A 2001-04-10 2002-04-09 Stabilized medium and high voltage cable insulation composition Expired - Lifetime CA2380987C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP01810356 2001-04-10
EP01810356.4 2001-04-10
EP01810511 2001-05-23
EP01810511.4 2001-05-23

Publications (2)

Publication Number Publication Date
CA2380987A1 true CA2380987A1 (en) 2002-10-10
CA2380987C CA2380987C (en) 2011-03-15

Family

ID=26077366

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2380987A Expired - Lifetime CA2380987C (en) 2001-04-10 2002-04-09 Stabilized medium and high voltage cable insulation composition

Country Status (15)

Country Link
US (1) US7056967B2 (en)
JP (1) JP4051667B2 (en)
KR (1) KR100923284B1 (en)
CN (1) CN1250636C (en)
AR (1) AR033211A1 (en)
AU (1) AU784703B2 (en)
BR (1) BR0201173B1 (en)
CA (1) CA2380987C (en)
CZ (1) CZ305019B6 (en)
MX (1) MXPA02003611A (en)
MY (1) MY133253A (en)
NO (1) NO333375B1 (en)
SG (1) SG103854A1 (en)
SK (1) SK287686B6 (en)
TW (1) TWI239019B (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0508350D0 (en) * 2005-04-26 2005-06-01 Great Lakes Chemical Europ Stabilized crosslinked polyolefin compositions
EP1848768B1 (en) * 2006-02-24 2011-02-09 LG Chem, Ltd. Cross-linked polyethylene having excellent inhibition of sweat-out and insulation properties
KR100727207B1 (en) * 2006-02-24 2007-06-13 주식회사 엘지화학 Cross-linked polyethylene having excellent inhibition of sweat-out and insulation properties
CN101802079A (en) * 2007-07-13 2010-08-11 陶氏环球技术公司 The low dissipation loss power cable sheath that comprises the high pressure polyolefin that does not contain the silane functionality
KR101362560B1 (en) * 2011-08-08 2014-02-14 주식회사 엘지화학 Cross-linked polyethylene compositions
CN104334630B (en) 2012-06-04 2018-03-20 神华集团有限责任公司 The cross-linked polyethylene composition that a kind of processing characteristics improves
WO2013185302A1 (en) 2012-06-13 2013-12-19 北京低碳清洁能源研究所 Crosslinked polyethylene composition
BR112015015531B1 (en) * 2012-12-29 2021-05-18 Dow Global Technologies Llc process for preparing a crosslinkable polymer composition, process for treating at least a portion of a crosslinkable polymer composition, and process for producing a coated conductor
GB201320919D0 (en) 2013-11-27 2014-01-08 Addivant Switzerland Gmbh Composition
JP6421217B2 (en) * 2017-06-07 2018-11-07 ダウ グローバル テクノロジーズ エルエルシー Crosslinkable polymer composition, method of making the same, and article made therefrom
KR102061478B1 (en) 2018-04-26 2020-01-02 정대기 Polycrystalline silicon molded article and manufacturing method thereof
KR102060324B1 (en) 2018-04-26 2019-12-30 정대기 Polycrystalline silicon insulator, method of manufacturing the same, and insulator, power device, and bushing including the same
KR102055569B1 (en) 2018-04-26 2019-12-13 (주) 이우티이씨 Insulators and lightning arresters containing polycrystalline silicon insulators
KR101953630B1 (en) 2018-04-26 2019-03-04 정대기 Polycrystaline Silicone Composition
KR102133574B1 (en) 2018-05-29 2020-07-13 정대기 Cable cast fabric containing polycrystalline silicon insulators
CN115219634A (en) * 2022-08-26 2022-10-21 南方电网科学研究院有限责任公司 Evaluation method of scorch resistance of crosslinkable polyethylene insulating material for cable

Family Cites Families (102)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR732895A (en) * 1932-10-18 1932-09-25 Consortium Elektrochem Ind Articles spun in polyvinyl alcohol
US4329383A (en) * 1979-07-24 1982-05-11 Nippon Zeon Co., Ltd. Non-thrombogenic material comprising substrate which has been reacted with heparin
EP0165209B1 (en) 1984-06-12 1989-07-19 Ciba-Geigy Ag O,p-bifunctionalised, o'-substituted phenols
US4656242A (en) * 1985-06-07 1987-04-07 Henkel Corporation Poly(ester-amide) compositions
US4733665C2 (en) * 1985-11-07 2002-01-29 Expandable Grafts Partnership Expandable intraluminal graft and method and apparatus for implanting an expandable intraluminal graft
EP0224442B1 (en) * 1985-11-13 1990-05-16 Ciba-Geigy Ag Use of substituted phenols as stabilizers
EP0273013B2 (en) * 1986-12-24 1996-07-24 Ciba-Geigy Ag Substituted phenols as stabilizers
US5721131A (en) * 1987-03-06 1998-02-24 United States Of America As Represented By The Secretary Of The Navy Surface modification of polymers with self-assembled monolayers that promote adhesion, outgrowth and differentiation of biological cells
US4800882A (en) * 1987-03-13 1989-01-31 Cook Incorporated Endovascular stent and delivery system
US5019096A (en) * 1988-02-11 1991-05-28 Trustees Of Columbia University In The City Of New York Infection-resistant compositions, medical devices and surfaces and methods for preparing and using same
US5091099A (en) * 1988-06-09 1992-02-25 Ciba-Geigy Corporation Lubricating oil composition
US4908404A (en) * 1988-08-22 1990-03-13 Biopolymers, Inc. Synthetic amino acid-and/or peptide-containing graft copolymers
IL90193A (en) * 1989-05-04 1993-02-21 Biomedical Polymers Int Polurethane-based polymeric materials and biomedical articles and pharmaceutical compositions utilizing the same
US5292516A (en) * 1990-05-01 1994-03-08 Mediventures, Inc. Body cavity drug delivery with thermoreversible gels containing polyoxyalkylene copolymers
US5300295A (en) * 1990-05-01 1994-04-05 Mediventures, Inc. Ophthalmic drug delivery with thermoreversible polyoxyalkylene gels adjustable for pH
US5298260A (en) * 1990-05-01 1994-03-29 Mediventures, Inc. Topical drug delivery with polyoxyalkylene polymer thermoreversible gels adjustable for pH and osmolality
US5306501A (en) * 1990-05-01 1994-04-26 Mediventures, Inc. Drug delivery by injection with thermoreversible gels containing polyoxyalkylene copolymers
US5258020A (en) * 1990-09-14 1993-11-02 Michael Froix Method of using expandable polymeric stent with memory
GB9027793D0 (en) * 1990-12-21 1991-02-13 Ucb Sa Polyester-amides containing terminal carboxyl groups
MX9702434A (en) * 1991-03-07 1998-05-31 Masimo Corp Signal processing apparatus.
DE69325845T2 (en) * 1992-04-28 2000-01-05 Terumo Corp Thermoplastic polymer composition and medical devices made therefrom
US5464650A (en) * 1993-04-26 1995-11-07 Medtronic, Inc. Intravascular stent and method
US5861168A (en) * 1993-06-11 1999-01-19 The Board Of Trustees Of The Leland Stanford Junior University Intramural delivery of nitric oxide enhancer for inhibiting lesion formation after vascular injury
US5380299A (en) * 1993-08-30 1995-01-10 Med Institute, Inc. Thrombolytic treated intravascular medical device
WO1995010989A1 (en) * 1993-10-19 1995-04-27 Scimed Life Systems, Inc. Intravascular stent pump
US6051576A (en) * 1994-01-28 2000-04-18 University Of Kentucky Research Foundation Means to achieve sustained release of synergistic drugs by conjugation
CA2182603A1 (en) 1994-03-22 1995-09-28 Kurt Hoffmann Process for the stabilization of hdpe
US5516881A (en) * 1994-08-10 1996-05-14 Cornell Research Foundation, Inc. Aminoxyl-containing radical spin labeling in polymers and copolymers
US5485496A (en) * 1994-09-22 1996-01-16 Cornell Research Foundation, Inc. Gamma irradiation sterilizing of biomaterial medical devices or products, with improved degradation and mechanical properties
US5482720A (en) * 1994-10-11 1996-01-09 Church & Dwight Co., Inc. Encapsulated co-micronized bicarbonate salt compositions
ES2155534T3 (en) * 1994-10-12 2001-05-16 Focal Inc ADMINISTRATION DIRECTED THROUGH BIODEGRADABLE POLYMERS.
US5869127A (en) * 1995-02-22 1999-02-09 Boston Scientific Corporation Method of providing a substrate with a bio-active/biocompatible coating
US5837313A (en) * 1995-04-19 1998-11-17 Schneider (Usa) Inc Drug release stent coating process
US5609629A (en) * 1995-06-07 1997-03-11 Med Institute, Inc. Coated implantable medical device
US6010530A (en) * 1995-06-07 2000-01-04 Boston Scientific Technology, Inc. Self-expanding endoluminal prosthesis
US7550005B2 (en) * 1995-06-07 2009-06-23 Cook Incorporated Coated implantable medical device
US7611533B2 (en) * 1995-06-07 2009-11-03 Cook Incorporated Coated implantable medical device
US6774278B1 (en) * 1995-06-07 2004-08-10 Cook Incorporated Coated implantable medical device
US5877224A (en) * 1995-07-28 1999-03-02 Rutgers, The State University Of New Jersey Polymeric drug formulations
US5723219A (en) * 1995-12-19 1998-03-03 Talison Research Plasma deposited film networks
US6033582A (en) * 1996-01-22 2000-03-07 Etex Corporation Surface modification of medical implants
US6054553A (en) * 1996-01-29 2000-04-25 Bayer Ag Process for the preparation of polymers having recurring agents
US5610241A (en) * 1996-05-07 1997-03-11 Cornell Research Foundation, Inc. Reactive graft polymer with biodegradable polymer backbone and method for preparing reactive biodegradable polymers
US5876433A (en) * 1996-05-29 1999-03-02 Ethicon, Inc. Stent and method of varying amounts of heparin coated thereon to control treatment
US5874165A (en) * 1996-06-03 1999-02-23 Gore Enterprise Holdings, Inc. Materials and method for the immobilization of bioactive species onto polymeric subtrates
NL1003459C2 (en) * 1996-06-28 1998-01-07 Univ Twente Copoly (ester amides) and copoly (ester urethanes).
US5711958A (en) * 1996-07-11 1998-01-27 Life Medical Sciences, Inc. Methods for reducing or eliminating post-surgical adhesion formation
US6530951B1 (en) * 1996-10-24 2003-03-11 Cook Incorporated Silver implantable medical device
US6240616B1 (en) * 1997-04-15 2001-06-05 Advanced Cardiovascular Systems, Inc. Method of manufacturing a medicated porous metal prosthesis
US6159978A (en) * 1997-05-28 2000-12-12 Aventis Pharmaceuticals Product, Inc. Quinoline and quinoxaline compounds which inhibit platelet-derived growth factor and/or p56lck tyrosine kinases
US6180632B1 (en) * 1997-05-28 2001-01-30 Aventis Pharmaceuticals Products Inc. Quinoline and quinoxaline compounds which inhibit platelet-derived growth factor and/or p56lck tyrosine kinases
US6211249B1 (en) * 1997-07-11 2001-04-03 Life Medical Sciences, Inc. Polyester polyether block copolymers
CA2298580A1 (en) * 1997-08-08 1999-02-18 The Procter & Gamble Company Laundry detergent compositions with amino acid based polymers to provide appearance and integrity benefits to fabrics laundered therewith
US20030040790A1 (en) * 1998-04-15 2003-02-27 Furst Joseph G. Stent coating
CA2320259C (en) * 1998-04-27 2006-01-24 Surmodics, Inc. Bioactive agent release coating
US6228917B1 (en) * 1998-06-16 2001-05-08 Union Carbide Chemicals & Plastics Technology Corporation Polyethylene crosslinkable composition
CA2340652C (en) * 1998-08-20 2013-09-24 Cook Incorporated Coated implantable medical device comprising paclitaxel
US6335029B1 (en) * 1998-08-28 2002-01-01 Scimed Life Systems, Inc. Polymeric coatings for controlled delivery of active agents
US6011125A (en) * 1998-09-25 2000-01-04 General Electric Company Amide modified polyesters
US6530950B1 (en) * 1999-01-12 2003-03-11 Quanam Medical Corporation Intraluminal stent having coaxial polymer member
US6143822A (en) 1999-03-18 2000-11-07 Union Carbide Chemicals & Plastics Technology Corporation Polyethylene crosslinkable composition
EP1036805B1 (en) 1999-03-18 2013-01-09 Union Carbide Chemicals & Plastics Technology LLC A polyethylene crosslinkable composition
US6231978B1 (en) 1999-03-31 2001-05-15 Union Carbide Chemicals & Plastics Technology Corporation Crosslinkable polyethylene composition
JP2000306433A (en) * 1999-04-23 2000-11-02 Sumitomo Electric Ind Ltd Insulating resin composition and electric wire and cable using it, and power cable connecting part
US6494862B1 (en) * 1999-07-13 2002-12-17 Advanced Cardiovascular Systems, Inc. Substance delivery apparatus and a method of delivering a therapeutic substance to an anatomical passageway
US6283947B1 (en) * 1999-07-13 2001-09-04 Advanced Cardiovascular Systems, Inc. Local drug delivery injection catheter
US6177523B1 (en) * 1999-07-14 2001-01-23 Cardiotech International, Inc. Functionalized polyurethanes
US6191230B1 (en) 1999-07-22 2001-02-20 Union Carbide Chemicals & Plastics Technology Corporation Polyethylene crosslinkable composition
US6503556B2 (en) * 2000-12-28 2003-01-07 Advanced Cardiovascular Systems, Inc. Methods of forming a coating for a prosthesis
US6379381B1 (en) * 1999-09-03 2002-04-30 Advanced Cardiovascular Systems, Inc. Porous prosthesis and a method of depositing substances into the pores
US6713119B2 (en) * 1999-09-03 2004-03-30 Advanced Cardiovascular Systems, Inc. Biocompatible coating for a prosthesis and a method of forming the same
US6503954B1 (en) * 2000-03-31 2003-01-07 Advanced Cardiovascular Systems, Inc. Biocompatible carrier containing actinomycin D and a method of forming the same
US6262157B1 (en) 1999-09-29 2001-07-17 Union Carbide Chemicals & Plastics Technology Corporation Polyethylene crosslinkable composition
US6203551B1 (en) * 1999-10-04 2001-03-20 Advanced Cardiovascular Systems, Inc. Chamber for applying therapeutic substances to an implant device
US6613432B2 (en) * 1999-12-22 2003-09-02 Biosurface Engineering Technologies, Inc. Plasma-deposited coatings, devices and methods
US6527801B1 (en) * 2000-04-13 2003-03-04 Advanced Cardiovascular Systems, Inc. Biodegradable drug delivery material for stent
US20020005206A1 (en) * 2000-05-19 2002-01-17 Robert Falotico Antiproliferative drug and delivery device
US20020007213A1 (en) * 2000-05-19 2002-01-17 Robert Falotico Drug/drug delivery systems for the prevention and treatment of vascular disease
US20020007214A1 (en) * 2000-05-19 2002-01-17 Robert Falotico Drug/drug delivery systems for the prevention and treatment of vascular disease
US6776796B2 (en) * 2000-05-12 2004-08-17 Cordis Corportation Antiinflammatory drug and delivery device
US20020007215A1 (en) * 2000-05-19 2002-01-17 Robert Falotico Drug/drug delivery systems for the prevention and treatment of vascular disease
US6673385B1 (en) * 2000-05-31 2004-01-06 Advanced Cardiovascular Systems, Inc. Methods for polymeric coatings stents
US6555157B1 (en) * 2000-07-25 2003-04-29 Advanced Cardiovascular Systems, Inc. Method for coating an implantable device and system for performing the method
US6503538B1 (en) * 2000-08-30 2003-01-07 Cornell Research Foundation, Inc. Elastomeric functional biodegradable copolyester amides and copolyester urethanes
US6716444B1 (en) * 2000-09-28 2004-04-06 Advanced Cardiovascular Systems, Inc. Barriers for polymer-coated implantable medical devices and methods for making the same
US6506437B1 (en) * 2000-10-17 2003-01-14 Advanced Cardiovascular Systems, Inc. Methods of coating an implantable device having depots formed in a surface thereof
US6544543B1 (en) * 2000-12-27 2003-04-08 Advanced Cardiovascular Systems, Inc. Periodic constriction of vessels to treat ischemic tissue
US6540776B2 (en) * 2000-12-28 2003-04-01 Advanced Cardiovascular Systems, Inc. Sheath for a prosthesis and methods of forming the same
US6544582B1 (en) * 2001-01-05 2003-04-08 Advanced Cardiovascular Systems, Inc. Method and apparatus for coating an implantable device
US6544223B1 (en) * 2001-01-05 2003-04-08 Advanced Cardiovascular Systems, Inc. Balloon catheter for delivering therapeutic agents
US20030032767A1 (en) * 2001-02-05 2003-02-13 Yasuhiro Tada High-strength polyester-amide fiber and process for producing the same
US20030004141A1 (en) * 2001-03-08 2003-01-02 Brown David L. Medical devices, compositions and methods for treating vulnerable plaque
US6712845B2 (en) * 2001-04-24 2004-03-30 Advanced Cardiovascular Systems, Inc. Coating for a stent and a method of forming the same
US6695920B1 (en) * 2001-06-27 2004-02-24 Advanced Cardiovascular Systems, Inc. Mandrel for supporting a stent and a method of using the mandrel to coat a stent
US6673154B1 (en) * 2001-06-28 2004-01-06 Advanced Cardiovascular Systems, Inc. Stent mounting device to coat a stent
US6706013B1 (en) * 2001-06-29 2004-03-16 Advanced Cardiovascular Systems, Inc. Variable length drug delivery catheter
US6527863B1 (en) * 2001-06-29 2003-03-04 Advanced Cardiovascular Systems, Inc. Support device for a stent and a method of using the same to coat a stent
US7195640B2 (en) * 2001-09-25 2007-03-27 Cordis Corporation Coated medical devices for the treatment of vulnerable plaque
US20030059520A1 (en) * 2001-09-27 2003-03-27 Yung-Ming Chen Apparatus for regulating temperature of a composition and a method of coating implantable devices
US20030073961A1 (en) * 2001-09-28 2003-04-17 Happ Dorrie M. Medical device containing light-protected therapeutic agent and a method for fabricating thereof
US20030065377A1 (en) * 2001-09-28 2003-04-03 Davila Luis A. Coated medical devices
US6709514B1 (en) * 2001-12-28 2004-03-23 Advanced Cardiovascular Systems, Inc. Rotary coating apparatus for coating implantable medical devices

Also Published As

Publication number Publication date
BR0201173A (en) 2003-06-10
KR20020079525A (en) 2002-10-19
JP4051667B2 (en) 2008-02-27
SG103854A1 (en) 2004-05-26
US20020198344A1 (en) 2002-12-26
JP2002363351A (en) 2002-12-18
SK287686B6 (en) 2011-06-06
TWI239019B (en) 2005-09-01
NO333375B1 (en) 2013-05-13
CN1381522A (en) 2002-11-27
KR100923284B1 (en) 2009-10-23
SK4702002A3 (en) 2002-11-06
AU784703B2 (en) 2006-06-01
MY133253A (en) 2007-10-31
US7056967B2 (en) 2006-06-06
AR033211A1 (en) 2003-12-10
MXPA02003611A (en) 2002-11-07
CZ305019B6 (en) 2015-04-01
NO20021657L (en) 2002-10-11
AU3299802A (en) 2002-10-17
CN1250636C (en) 2006-04-12
CA2380987C (en) 2011-03-15
BR0201173B1 (en) 2012-01-10
CZ20021236A3 (en) 2002-11-13
NO20021657D0 (en) 2002-04-08

Similar Documents

Publication Publication Date Title
CA2380987A1 (en) Stabilized medium and high voltage cable insulation composition
DE60315132D1 (en) THERMOPLASTIC COMPOSITION, POLYCARBONATE RESIN COMPOSITION AND FORM BODY THEREOF
EP1832617A3 (en) Polyfunctional phenylene ether oligomer, derivative thereof, resin composition containing the same, and use thereof
KR0122076B1 (en) Polyethylene stabilized by mixture of hindered phenol and aminie antioxidants
JP2002363351A5 (en)
EP0574651B1 (en) Liquid stabilizer compositions for polyols and polyurethane foam
TW200738777A (en) Cyclic olefin based resin composition, method of manufacturing resin molded product comprising the resin composition, and film comprising the resin composition
CA2653367A1 (en) A silicon containing compound as drying agent for polyolefin compositions
KR900007785A (en) Bromo-nitro compounds having antimicrobial properties, preparation methods thereof, and compositions containing such compounds
EP0101175B1 (en) Blends of organic peroxides
Yachigo et al. Studies on polymer stabilizers: Part V—Influences of structural factors on oxidative discoloration and thermal stability of polymers
US5238606A (en) Stabilization of polypols with liquid antiscorch composition
AR007419A1 (en) A FUNGICIDE COMPOSITION OF N-ACETONYLBENZAMIDE, A PROCESS FOR ITS PREPARATION, A METHOD FOR CONTROLLING PHYTOPATHOLOGICAL FUNGI AND A PROCESS FOR PREPARING A RACEMIC MIXTURE OF THE (R) AND (S) ENANTIOMERS OF SUCH COMPOSITION
ATE244738T1 (en) STABILIZER COMPOSITION FOR ORGANIC POLYMER MATERIALS CONTAINING 6-HYDROXICHROMANE COMPOUNDS AND ORGANIC POLYMER MATERIAL COMPOSITIONS
DK1601718T3 (en) Extrudable PVC Compositions
EP0427103A1 (en) Organic sulfide stabilized polymeric engineering resins
US4520146A (en) Chemical compounds and use
US4101507A (en) Stabilization of polyphosphazenes
US4082725A (en) Flame retardant plastic compositions
KR102445796B1 (en) Anti-scorch/hardening aid blend
EP1249845A2 (en) Stabilized medium and high voltage cable insulation composition
US4687797A (en) Halo phthalimides of phenolic-substituted hydrazides
CA1046688A (en) Stabilized polymeric composition and product using same
CN112358721B (en) Biaxially oriented nylon material and preparation method thereof
RU2002108887A (en) Stabilized material and compositions for high voltage cable insulation

Legal Events

Date Code Title Description
EEER Examination request
MKEX Expiry

Effective date: 20220411