CA2372695A1 - Detergent composition and method for removing soil - Google Patents
Detergent composition and method for removing soil Download PDFInfo
- Publication number
- CA2372695A1 CA2372695A1 CA002372695A CA2372695A CA2372695A1 CA 2372695 A1 CA2372695 A1 CA 2372695A1 CA 002372695 A CA002372695 A CA 002372695A CA 2372695 A CA2372695 A CA 2372695A CA 2372695 A1 CA2372695 A1 CA 2372695A1
- Authority
- CA
- Canada
- Prior art keywords
- detergent composition
- surfactant
- composition according
- alkaline detergent
- article
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000000203 mixture Substances 0.000 title claims abstract 47
- 239000003599 detergent Substances 0.000 title claims abstract 41
- 239000002689 soil Substances 0.000 title claims abstract 22
- 238000000034 method Methods 0.000 title claims abstract 17
- 239000004094 surface-active agent Substances 0.000 claims abstract 23
- 239000002736 nonionic surfactant Substances 0.000 claims abstract 9
- 229920000642 polymer Polymers 0.000 claims abstract 7
- 239000000654 additive Substances 0.000 claims abstract 5
- 230000000996 additive effect Effects 0.000 claims abstract 5
- 125000000217 alkyl group Chemical group 0.000 claims abstract 5
- 230000002209 hydrophobic effect Effects 0.000 claims abstract 3
- 125000001165 hydrophobic group Chemical group 0.000 claims abstract 3
- 229920001296 polysiloxane Polymers 0.000 claims 11
- 239000003352 sequestering agent Substances 0.000 claims 5
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 4
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 239000001257 hydrogen Substances 0.000 claims 4
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims 3
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims 3
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 claims 3
- 229910052708 sodium Inorganic materials 0.000 claims 3
- 239000011734 sodium Substances 0.000 claims 3
- 235000019832 sodium triphosphate Nutrition 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims 2
- 125000005192 alkyl ethylene group Chemical group 0.000 claims 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims 2
- 229920005646 polycarboxylate Polymers 0.000 claims 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims 1
- 150000008041 alkali metal carbonates Chemical class 0.000 claims 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 239000008188 pellet Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 229910000029 sodium carbonate Inorganic materials 0.000 claims 1
- 235000017550 sodium carbonate Nutrition 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- CCUJQAYWGVMIMO-UHFFFAOYSA-K trisodium;3-carboxy-6-hydroxy-6-oxo-3-phosphonatohexanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(C([O-])=O)(P(O)(=O)O)CCC([O-])=O CCUJQAYWGVMIMO-UHFFFAOYSA-K 0.000 claims 1
- NCPXQVVMIXIKTN-UHFFFAOYSA-N trisodium;phosphite Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])[O-] NCPXQVVMIXIKTN-UHFFFAOYSA-N 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 2
- 238000004140 cleaning Methods 0.000 abstract 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/82—Compounds containing silicon
Abstract
The invention relates to a highly alkaline or mildly alkaline detergent composition having enhanced cleaning properties. The detergent combines a source of alkalinity and a blend of nonionic surfactants that enhances cleaning starchy soils. The blend of nonionic surfactants preferably includes an alkyl polyglycoside surfactant and a silicon surfactant having a hydrophobic silicon group and a pendant hydrophilic group. Preferably, the blend of nonionic surfactants includes a surfactant having a hydrophobic group and an ethylene oxide residue containing group and a polymer additive. A
method for removing soil from an article is provided.
method for removing soil from an article is provided.
Claims (38)
1. An alkaline detergent composition comprising:
(a) an effective soil removing amount of a source of alkalinity; and (b) an effective soil removing amount of a surfactant blend comprising:
(i) an alkyl polyglycoside surfactant; and (ii) a silicone surfactant comprising a hydrophobic silicone group and a pendant hydrophilic group;
wherein the detergent composition provides a use solution having a detergent concentration of between about 500 ppm and 2,000 ppm exhibiting a surface tension of less than about 35 dynes/cm.
(a) an effective soil removing amount of a source of alkalinity; and (b) an effective soil removing amount of a surfactant blend comprising:
(i) an alkyl polyglycoside surfactant; and (ii) a silicone surfactant comprising a hydrophobic silicone group and a pendant hydrophilic group;
wherein the detergent composition provides a use solution having a detergent concentration of between about 500 ppm and 2,000 ppm exhibiting a surface tension of less than about 35 dynes/cm.
2. An alkaline detergent composition according to claim 1, wherein the surfactant blend further comprises a nonionic surfactant comprising a hydrophobic group and an -(EO)x group, wherein x is a number of about 1 to about 100.
3. An alkaline detergent composition according to claim 2, wherein the nonionic surfactant comprises an alkyl-ethylene oxide-propylene oxide surfactant.
4. An alkaline detergent composition according to claim 2, wherein the nonionic silicone surfactant comprises a surfactant having the formula:
wherein PE represents -CH2-(CH2)p-O-(EO)m(PO)n-Z, x is a number that ranges from about 0 to about 100, y is a number that ranges from about 1 to 100, p is 0 to 6, m and n are numbers that range from about 0 to about 50, m+n>=1, and Z
represents hydrogen or R and each R independently represents a lower (C1-6) alkyl.
wherein PE represents -CH2-(CH2)p-O-(EO)m(PO)n-Z, x is a number that ranges from about 0 to about 100, y is a number that ranges from about 1 to 100, p is 0 to 6, m and n are numbers that range from about 0 to about 50, m+n>=1, and Z
represents hydrogen or R and each R independently represents a lower (C1-6) alkyl.
5. An alkaline detergent composition according to claim 2, wherein the silicone surfactant has the formula:
wherein x represent a number that ranges from about 0 to about 100, y represent a number that ranges from about 1 to about 100, a and b represent numbers that independently represent numbers that range from about 0 to about 60, a+b >= 1 and R
is hydrogen or a lower (C1-6) alkyl.
wherein x represent a number that ranges from about 0 to about 100, y represent a number that ranges from about 1 to about 100, a and b represent numbers that independently represent numbers that range from about 0 to about 60, a+b >= 1 and R
is hydrogen or a lower (C1-6) alkyl.
6. An alkaline detergent composition according to claim 1, wherein the silicone surfactant has the formula:
wherein PE represents -CH2-(CH2)p-O-(EO)m(PO)n-Z, x is a number that ranges from about 0 to about 100, p is 0 to 6, m and n are numbers that range from about 0 to about 50, m+n>=1.
wherein PE represents -CH2-(CH2)p-O-(EO)m(PO)n-Z, x is a number that ranges from about 0 to about 100, p is 0 to 6, m and n are numbers that range from about 0 to about 50, m+n>=1.
7. An alkaline detergent composition according to claim 1, wherein the composition comprises a polymer additive.
8. An alkaline detergent composition according to claim 7, wherein the polymer additive comprises a polycarboxylate polymer.
9. An alkaline detergent composition according to claim 1, wherein the alkyl polyglycoside surfactant has a degree of polymerization of between about 1 and about 4, and the alkyl group contains between about 12 and about 16 carbon atoms.
10. An alkaline detergent composition according to claim 1 wherein the source of alkalinity comprises an alkali metal hydroxide.
11. An alkaline detergent composition according to claim 1, wherein the source of alkalinity comprises an alkali metal carbonate.
12. An alkaline detergent composition according to claim 1, further comprising a hardness sequestering agent.
13. An alkaline detergent composition according to claim 12, wherein the hardness sequestering agent comprises an amino trialkylene phosphonic acid sodium salt.
14. An alkaline detergent composition according to claim 13, wherein the hardness sequestering agent additionally comprises a 2-phosphono-butane-1,2,4-tricarboxylic acid sodium salt, 1-hydroxyethylidene-1,1-diphosphonic acid, diethylenetriamine-penta(methylenephosphonic acid) or mixtures thereof.
15. An alkaline detergent composition according to claim 1, further comprising a sequestering agent comprising at least one of sodium tripolyphosphate and amino trimethylene phosphonic acid sodium salt, 2-phosphono-butane-1,2,4-tricarboxylic acid, 1-hydroxyethylidene-1,1-diphosphonic acid, diethylenetriamine-penta(methylenephosphonic acid) or mixtures thereof.
16. An alkaline detergent composition according to claim 2, wherein the nonionic surfactant comprises a capped linear alcohol ethoxylate.
17. An alkaline detergent composition according to claim 16, wherein the nonionic surfactant comprises a benzyl capped C8-12 linear alcohol 6 to 16 mole ethoxylate.
18. An alkaline detergent composition according to claim 1, wherein the detergent comprises a solid block having a mass of at least 100 grams.
19. An alkaline detergent according to claim 18, wherein the detergent is packaged within a flexible wrapping.
20. An alkaline detergent composition according to claim 1, wherein the detergent is in the form of a powder.
21. An alkaline detergent composition according to claim 1, wherein the composition is in the form of a pellet.
22. An alkaline detergent composition according to claim 1, wherein the alkaline detergent composition comprises:
(a) about 5 to 65 wt% of Na2CO3; and (b) about 1 to 25 wt% of a hardness sequestering agent selected from the group consisting of sodium tripolyphosphate, and organic phosphonate sequesterant, and mixtures thereof.
(a) about 5 to 65 wt% of Na2CO3; and (b) about 1 to 25 wt% of a hardness sequestering agent selected from the group consisting of sodium tripolyphosphate, and organic phosphonate sequesterant, and mixtures thereof.
23. An alkaline detergent composition according to claim 22, wherein the phosphonate sequesterant comprises an amino trimethylene phosphonic acid sodium salt.
24. An alkaline detergent composition according to claim 23, wherein the sequesterant additionally comprises a sodium tripolyphosphate and amino trimethylene phosphonic acid sodium salt, 2-phosphono-butane-1,2,4-tricarboxylic acid, 1-hydroxyethylidene-1,1-diphosphonic acid, diethylenetriamine-penta(methylenephosphonic acid) or mixtures thereof.
25. A method for removing soil from an article, the method comprising:
(a) contacting an article surface containing a starchy soil with an aqueous detergent composition comprising:
(i) an effective soil removing amount of a source of alkalinity;
and (ii) an effective soil removing amount of a surfactant blend comprising an alkyl polyglycoside surfactant and a silicone surfactant, wherein the silicone surfactant includes a hydrophobic silicone group and a pendant hydrophilic group.
(a) contacting an article surface containing a starchy soil with an aqueous detergent composition comprising:
(i) an effective soil removing amount of a source of alkalinity;
and (ii) an effective soil removing amount of a surfactant blend comprising an alkyl polyglycoside surfactant and a silicone surfactant, wherein the silicone surfactant includes a hydrophobic silicone group and a pendant hydrophilic group.
26. A method for removing soil from an article according to claim 25, wherein said step of contacting comprises contacting the article with an aqueous detergent composition provided at a temperature of between about 120° F and about 170° F.
27. A method for removing soil from an article according to claim 25, wherein the aqueous detergent composition comprises a nonionic surfactant comprising a hydrophobic group and an -(EO)x group, wherein x is a number of about 1 to about 100.
28. A method for removing soil from an article according to claim 25, wherein the aqueous detergent composition comprises a polymer additive.
29. A method for removing soil from an article according to claim 25, wherein the polymer additive comprises a polycarboxylate polymer.
30. A method for removing soil from an article according to claim 25, wherein the detergent composition is provided at a concentration of between about 500 ppm and about 2,000 ppm.
31. A method for removing soil from an article according to claim 25, wherein the detergent composition is provided at a concentration of about 500 ppm and about 5,000 ppm.
32. A method for removing soil from an article according to claim 25, wherein said article comprises dishware.
33. A method for removing soil from an article according to claim 25, wherein said article comprises laundry.
34. A method for removing soil from an article according to claim 25, wherein the aqueous detergent composition comprises a nonionic surfactant comprising alkyl-ethylene oxide-propylene oxide surfactant.
35. A method for removing soil from an article according to claim 25, wherein said silicone surfactant comprises a surfactant having the formula:
wherein PE represents -CH2-(CH2)p-O-(EO)m(PO)n-Z, x is a number that ranges from about 0 to about 100, y is a number that ranges from about 1 to 100, p is 0 to 6, m and n are numbers that range from about 0 to about 50, m+n>=1, and Z
represents hydrogen or R and each R independently represents a lower (C1-6) alkyl.
wherein PE represents -CH2-(CH2)p-O-(EO)m(PO)n-Z, x is a number that ranges from about 0 to about 100, y is a number that ranges from about 1 to 100, p is 0 to 6, m and n are numbers that range from about 0 to about 50, m+n>=1, and Z
represents hydrogen or R and each R independently represents a lower (C1-6) alkyl.
36. A method for removing soil from an article according to claim 25, wherein the silicone surfactant has the formula:
wherein x represent a number that ranges from about 0 to about 100, y represent a number that ranges from about 1 to about 100, a and b represent numbers that independently represent numbers that range from about 0 to about 60, a+b >= 1 and R
is hydrogen or a lower (C1-6) alkyl.
wherein x represent a number that ranges from about 0 to about 100, y represent a number that ranges from about 1 to about 100, a and b represent numbers that independently represent numbers that range from about 0 to about 60, a+b >= 1 and R
is hydrogen or a lower (C1-6) alkyl.
37. A method for removing soil from an article according to claim 25, wherein the silicone surfactant comprises a surfactant having the formula:
wherein PE represents -CH2-(CH2)p-O-(EO)m(PO)n-Z, x is a number that ranges from about 0 to about 100, p is 0 to 6, m and n are numbers that range from about 0 to about 50, m+n>=1.
wherein PE represents -CH2-(CH2)p-O-(EO)m(PO)n-Z, x is a number that ranges from about 0 to about 100, p is 0 to 6, m and n are numbers that range from about 0 to about 50, m+n>=1.
38. A method for removing soil from an article according to claim 25, wherein said step of contacting comprises introducing the aqueous detergent composition into a machine warewashing apparatus.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/307,393 US6369021B1 (en) | 1999-05-07 | 1999-05-07 | Detergent composition and method for removing soil |
| US09/307,393 | 1999-05-07 | ||
| PCT/US2000/012387 WO2000068348A1 (en) | 1999-05-07 | 2000-05-05 | Detergent composition and method for removing soil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2372695A1 true CA2372695A1 (en) | 2000-11-16 |
| CA2372695C CA2372695C (en) | 2010-06-08 |
Family
ID=23189562
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2372695A Expired - Lifetime CA2372695C (en) | 1999-05-07 | 2000-05-05 | Detergent composition and method for removing soil |
Country Status (12)
| Country | Link |
|---|---|
| US (4) | US6369021B1 (en) |
| EP (1) | EP1177272B1 (en) |
| JP (2) | JP5270055B2 (en) |
| AR (1) | AR019509A1 (en) |
| AT (1) | ATE259874T1 (en) |
| AU (1) | AU769775B2 (en) |
| BR (1) | BR0010350B1 (en) |
| CA (1) | CA2372695C (en) |
| DE (1) | DE60008366T2 (en) |
| MX (1) | MXPA01011334A (en) |
| TW (1) | TW552303B (en) |
| WO (1) | WO2000068348A1 (en) |
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| US6649586B2 (en) | 2003-11-18 |
| US6812202B2 (en) | 2004-11-02 |
| JP2002544324A (en) | 2002-12-24 |
| ATE259874T1 (en) | 2004-03-15 |
| US20030166494A1 (en) | 2003-09-04 |
| DE60008366T2 (en) | 2004-12-23 |
| AR019509A1 (en) | 2002-02-20 |
| JP2011038113A (en) | 2011-02-24 |
| MXPA01011334A (en) | 2003-08-01 |
| JP5519468B2 (en) | 2014-06-11 |
| BR0010350A (en) | 2002-01-08 |
| EP1177272B1 (en) | 2004-02-18 |
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