CA2352391A1 - Composite electrodes for solid state electrochemical devices - Google Patents

Composite electrodes for solid state electrochemical devices Download PDF

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Publication number
CA2352391A1
CA2352391A1 CA002352391A CA2352391A CA2352391A1 CA 2352391 A1 CA2352391 A1 CA 2352391A1 CA 002352391 A CA002352391 A CA 002352391A CA 2352391 A CA2352391 A CA 2352391A CA 2352391 A1 CA2352391 A1 CA 2352391A1
Authority
CA
Canada
Prior art keywords
particles
ionic
solid state
electrocatalytic
electrochemical devices
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002352391A
Other languages
French (fr)
Other versions
CA2352391C (en
Inventor
Debabrata Ghosh
Frank Martell
Zheng Tang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Versa Power Systems Ltd
Original Assignee
Global Thermoelectric Inc.
Debabrata Ghosh
Frank Martell
Zheng Tang
Fuelcell Energy, Ltd.
Versa Power Systems, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Global Thermoelectric Inc., Debabrata Ghosh, Frank Martell, Zheng Tang, Fuelcell Energy, Ltd., Versa Power Systems, Ltd. filed Critical Global Thermoelectric Inc.
Publication of CA2352391A1 publication Critical patent/CA2352391A1/en
Application granted granted Critical
Publication of CA2352391C publication Critical patent/CA2352391C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9041—Metals or alloys
    • H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
    • H01M4/9066—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of metal-ceramic composites or mixtures, e.g. cermets
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403—Cells and electrode assemblies
    • G01N27/406—Cells and probes with solid electrolytes
    • G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
    • G01N27/4075—Composition or fabrication of the electrodes and coatings thereon, e.g. catalysts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
    • H01M2004/8689—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9041—Metals or alloys
    • H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49002—Electrical device making
    • Y10T29/49108—Electric battery cell making
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49002—Electrical device making
    • Y10T29/49108—Electric battery cell making
    • Y10T29/49115—Electric battery cell making including coating or impregnating

Abstract

A solid state ionic device includes a dense electrolyte sandwiched between two porous electrodes. In one em-bodiment, the device is anode supported and the cathode is formed of a porous three-dimensional solid phase structure having an electrocatalytic phase of a plurality of electrocatalytic particles (14) and an ionic conducting phase of a plurality of ionic conductor particles (16). The mean or median size of the electrocatalytic particles is larger than the mean or median size of the ionic conduc-tor particles. The device may further include a long range electronic conducting layer of lantham cobaltate or other electronically conducting material.
CA002352391A 1999-10-08 2000-10-06 Composite electrodes for solid state electrochemical devices Expired - Lifetime CA2352391C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US15812499P 1999-10-08 1999-10-08
US60/158,124 1999-10-08
US23154200P 2000-09-11 2000-09-11
US60/231,542 2000-09-11
PCT/CA2000/001166 WO2001028024A1 (en) 1999-10-08 2000-10-06 Composite electrodes for solid state electrochemical devices

Publications (2)

Publication Number Publication Date
CA2352391A1 true CA2352391A1 (en) 2001-04-19
CA2352391C CA2352391C (en) 2009-08-25

Family

ID=26854760

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002352391A Expired - Lifetime CA2352391C (en) 1999-10-08 2000-10-06 Composite electrodes for solid state electrochemical devices

Country Status (20)

Country Link
US (2) US6420064B1 (en)
EP (1) EP1135824B8 (en)
JP (1) JP5336685B2 (en)
KR (1) KR20010104686A (en)
CN (1) CN1336016A (en)
AT (1) ATE349777T1 (en)
AU (1) AU769575B2 (en)
BR (1) BR0007698A (en)
CA (1) CA2352391C (en)
CZ (1) CZ301735B6 (en)
DE (1) DE60032577T2 (en)
DK (1) DK1135824T3 (en)
EA (1) EA004168B1 (en)
HK (1) HK1044412A1 (en)
HU (1) HUP0104523A3 (en)
MX (1) MXPA01005771A (en)
NO (1) NO20012859L (en)
NZ (1) NZ512568A (en)
PL (1) PL348192A1 (en)
WO (1) WO2001028024A1 (en)

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NO20012859D0 (en) 2001-06-08
WO2001028024A1 (en) 2001-04-19
EA200100627A1 (en) 2001-10-22
AU7765700A (en) 2001-04-23
US6750169B2 (en) 2004-06-15
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US6420064B1 (en) 2002-07-16
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EP1135824B8 (en) 2007-04-25
HUP0104523A3 (en) 2003-07-28
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JP5336685B2 (en) 2013-11-06
DK1135824T3 (en) 2007-04-16

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