CA2319813A1 - Continuous electrolytically regenerated packed bed suppressor for ion chromatography - Google Patents
Continuous electrolytically regenerated packed bed suppressor for ion chromatography Download PDFInfo
- Publication number
- CA2319813A1 CA2319813A1 CA002319813A CA2319813A CA2319813A1 CA 2319813 A1 CA2319813 A1 CA 2319813A1 CA 002319813 A CA002319813 A CA 002319813A CA 2319813 A CA2319813 A CA 2319813A CA 2319813 A1 CA2319813 A1 CA 2319813A1
- Authority
- CA
- Canada
- Prior art keywords
- suppressor
- bed
- electrode
- chamber
- cathode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/96—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation using ion-exchange
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/96—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation using ion-exchange
- G01N2030/965—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation using ion-exchange suppressor columns
Abstract
An electrolytic suppressor (22) including (a) a suppressor bed (26) of ion exchange resin, (b) an electrode chamber (44) adjacent the suppressor, (c) a first electrode (42) in the electrode chamber, (d) a barrier (40) separating the suppressor bed from the first electrode chamber preventing significant liquid flow but permitting transport of ions only of the same charge as the suppressor bed resin, (e) a second electrode (36) in electrical communication with the resin bed, and (f) a recycle conduit (30, 32, 34, 38, 48) between the suppressor outlet port and said electrode chamber. The second electrode may be in contact with the ion exchange resin in the suppressor or located in second electrode chamber. For anion analysis, the method of using the apparatus includes: (a) flowing an aqueous liquid sample stream containing anions to be detected and cation hydroxide through the separator bed, (b) flowing the aqueous effluent from the separator bed through the flow-through suppressor, (c) flowing the effluent liquid from the suppressor past a detector, (d) recycling said liquid effluent from the detector through a cathode chamber proximate to the suppressor bed and separated by the first barrier, and (e) applying an electrical potential between the cathode and the anode. Water is electrolyzed at the anode to cause cations on the cation exchange resin to electromigrate toward the barrier and to be transported across the barrier toward the cathode while water in the cathode chamber is electrolyzed to generate hydroxide ions which combine with the transported cations to form cation hydroxide in the cathode chamber.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/031,221 | 1998-02-26 | ||
US09/031,221 US6325976B1 (en) | 1998-02-26 | 1998-02-26 | Continuous electrolytically regenerated packed bed suppressor for ion chromatography |
PCT/US1999/003427 WO1999044054A1 (en) | 1998-02-26 | 1999-02-17 | Continuous electrolytically regenerated packed bed suppressor for ion chromatography |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2319813A1 true CA2319813A1 (en) | 1999-09-02 |
CA2319813C CA2319813C (en) | 2005-05-03 |
Family
ID=21858253
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002319813A Expired - Lifetime CA2319813C (en) | 1998-02-26 | 1999-02-17 | Continuous electrolytically regenerated packed bed suppressor for ion chromatography |
Country Status (7)
Country | Link |
---|---|
US (3) | US6325976B1 (en) |
EP (1) | EP1057013A1 (en) |
JP (1) | JP3488202B2 (en) |
KR (1) | KR100423660B1 (en) |
AU (1) | AU754051B2 (en) |
CA (1) | CA2319813C (en) |
WO (1) | WO1999044054A1 (en) |
Families Citing this family (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE196949T1 (en) * | 1995-03-03 | 2000-10-15 | Alltech Associates Inc | METHOD AND DEVICE FOR THE ELECTROCHEMICAL MODIFICATION OF CHROMATOGRAPHY MATERIAL |
US6610546B1 (en) * | 1998-02-26 | 2003-08-26 | Dionex Corporation | Continuous electrolytically regenerated packed suppressor for ion chromatography |
US6325976B1 (en) * | 1998-02-26 | 2001-12-04 | Dionex Corporation | Continuous electrolytically regenerated packed bed suppressor for ion chromatography |
US6444475B1 (en) * | 1999-08-02 | 2002-09-03 | Alltech Associates, Inc. | Ion chromatography apparatus and method for removing gas prior to sample detection |
US6468804B1 (en) | 1999-08-02 | 2002-10-22 | Alltech Associates, Inc. | Suppressor for continuous electrochemically suppressed ion chromatography and method |
US6436719B1 (en) | 2000-03-08 | 2002-08-20 | Dionex Corporation | Displacement chemical regeneration method and apparatus |
US6425284B1 (en) | 2000-03-08 | 2002-07-30 | Dionex Corporation | Method and apparatus for gas-assisted suppressed chromatography |
US6562628B1 (en) | 2000-07-07 | 2003-05-13 | Dionex Corporation | Electrolytic suppressor and separate eluent generator combination |
US6752927B2 (en) | 2001-03-01 | 2004-06-22 | Dionex Corporation | Suppressed chromatography and salt conversion system |
US6902937B2 (en) * | 2001-07-13 | 2005-06-07 | Air Liquide America, L.P. | Method for the determination of low-concentration anions in the presence of an excess of another anion |
US7402283B2 (en) * | 2002-09-11 | 2008-07-22 | Dionex Corporation | Electrolytic eluent generator and method of use |
US7288176B2 (en) * | 2003-04-23 | 2007-10-30 | Dionex Corporation | Method and apparatus for generating high purity eluant |
US20030180186A1 (en) * | 2003-05-19 | 2003-09-25 | Carson William W. | Process and device for continuous tonic monitoring of aqueous solutions |
US20050100477A1 (en) * | 2003-11-06 | 2005-05-12 | Alltech Associates, Inc. | Apparatus and method for removing gas prior to sample detection and/or analysis |
US7306720B2 (en) * | 2004-08-23 | 2007-12-11 | Dionex Corporation | Membrane based volatile component-removal devices for liquid chromatography |
US8216515B2 (en) | 2004-09-16 | 2012-07-10 | Dionex Corporation | Capillary ion chromatography |
US7892848B2 (en) | 2005-04-14 | 2011-02-22 | Trovion Singapore Pte. Ltd., Co. | Method of ion chromatography wherein a specialized electrodeionization apparatus is used |
US7473354B2 (en) * | 2005-09-16 | 2009-01-06 | Dionex Corporation | Recycled suppressor regenerants |
US7618826B2 (en) * | 2006-09-19 | 2009-11-17 | Dionex Corporation | Membrane suppressor with an outlet substantially non-retentive for ionic species |
US7632404B2 (en) * | 2007-11-15 | 2009-12-15 | Dionex Corporation | Barrier with a seated ion exchange bead and method |
US8597571B2 (en) * | 2008-01-28 | 2013-12-03 | Dionex Corporation | Electrolytic eluent recycle device, apparatus and method of use |
US9188573B2 (en) * | 2010-01-20 | 2015-11-17 | Dionex Corporation | Multichannel ion chromatography system and method |
JP4968812B2 (en) * | 2010-04-21 | 2012-07-04 | 日理工業株式会社 | High purity electrolyte solution generator |
US8529758B2 (en) | 2011-03-22 | 2013-09-10 | Dionex Corporation | CO2-removal device and method |
US20160000974A1 (en) * | 2011-08-09 | 2016-01-07 | New Jersey Institute Of Technoloty | Composite Matrix for Bone Repair Applications |
US10048233B2 (en) | 2012-11-12 | 2018-08-14 | Dionex Corporation | Suppressor device |
US9914651B2 (en) | 2013-05-08 | 2018-03-13 | Dionex Corporation | Current efficient electrolytic device and method |
US9964510B2 (en) | 2013-09-16 | 2018-05-08 | Dionex Corporation | Electrolytic four-channel device and method |
US9400268B2 (en) | 2014-08-08 | 2016-07-26 | Dionex Corporation | Method for reducing suppressor noise |
US20160137530A1 (en) | 2014-11-13 | 2016-05-19 | Dionex Corporation | Ion exchange based volatile component removal device for ion chromatography |
US10175211B2 (en) | 2014-12-31 | 2019-01-08 | Dionex Corporation | Current-efficient suppressor and pretreatment device and method |
US11287403B2 (en) | 2016-01-07 | 2022-03-29 | Board Of Regents, The University Of Texas System | Ion chromatography system and methods utilizing a weak acid or weak base extraction device |
US10416137B2 (en) * | 2016-09-07 | 2019-09-17 | Board Of Regents, University Of Texas System | Electrodialytic capillary suppressor for suppressed conductometric ion chromatography |
US10150056B2 (en) | 2016-11-14 | 2018-12-11 | Lilac Solutions, Inc. | Lithium extraction with coated ion exchange particles |
US10948466B2 (en) * | 2017-03-03 | 2021-03-16 | Dionex Corporation | Flow control in an electrolytic reagent concentrator for ion chromatography |
CN107561127A (en) * | 2017-06-26 | 2018-01-09 | 海南核电有限公司 | It is a kind of integrated from regeneration hydrogen conductivity negative electricity conductance and the measurement apparatus of total conductivity |
AR112663A1 (en) | 2017-08-02 | 2019-11-27 | Lilac Solutions Inc | LITHIUM EXTRACTION WITH ION EXCHANGE POROUS PEARLS |
KR20200116526A (en) | 2018-02-28 | 2020-10-12 | 리락 솔루션즈, 인크. | Ion exchange reactor with particle trap for lithium extraction |
US11243194B2 (en) | 2019-01-25 | 2022-02-08 | Dionex Corporation | Suppressors with eluent screens for use in ion chromatography |
US20220107292A1 (en) * | 2020-10-06 | 2022-04-07 | Board Of Regents, The University Of Texas System | On-line suppressor |
CA3216001A1 (en) * | 2021-04-23 | 2022-10-27 | David Henry SNYDACKER | Ion exchange devices for lithium extraction |
US20230184728A1 (en) * | 2021-12-09 | 2023-06-15 | Dionex Corporation | Suppressor |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3925019A (en) | 1973-08-06 | 1975-12-09 | Dow Chemical Co | Chromatographic analysis of ionic species |
US3926559A (en) | 1973-08-06 | 1975-12-16 | Dow Chemical Co | Method and apparatus for quantitative chromatographic analysis of cationic species |
US3920397A (en) | 1973-08-06 | 1975-11-18 | Dow Chemical Co | Apparatus and method for quantitative analysis of ionic species by liquid column chromatography |
US3897213A (en) | 1973-08-06 | 1975-07-29 | Dow Chemical Co | Automated quantitative analysis of ionic species |
US4314823A (en) | 1979-03-05 | 1982-02-09 | Dionex Corporation | Combination apparatus and method for chromatographic separation and quantitative analysis of multiple ionic species |
US4474664A (en) | 1980-01-16 | 1984-10-02 | The Dow Chemical Company | Ion analysis method and apparatus |
JPS56162050A (en) * | 1980-04-22 | 1981-12-12 | Dionex Corp | Liquid chromatography and method of using ion condensation |
DE3126860A1 (en) | 1981-07-08 | 1983-01-27 | BIOTRONIK Wissenschaftliche Geräte GmbH, 6000 Frankfurt | METHOD AND DEVICE FOR QUANTITATIVELY DETERMINING CATIONS OR ANIONS BY ION CHROMATOGRAPHY |
US4999098A (en) | 1984-10-04 | 1991-03-12 | Dionex Corporation | Modified membrane suppressor and method for use |
CA2087481C (en) | 1992-02-10 | 2001-09-04 | John R. Stillian | Ion chromatography system using electrochemical suppression and detector effluent recycle |
US5248426A (en) | 1992-02-10 | 1993-09-28 | Dionex Corporation | Ion chromatography system using electrochemical suppression and detector effluent recycle |
JP2750002B2 (en) | 1993-08-27 | 1998-05-13 | ダイオネックス コーポレイション | Ion chromatography using frequent regeneration of batch suppressors. |
US5425858A (en) | 1994-05-20 | 1995-06-20 | The Regents Of The University Of California | Method and apparatus for capacitive deionization, electrochemical purification, and regeneration of electrodes |
US5567307A (en) | 1994-09-30 | 1996-10-22 | Lachat Instruments | System and a method for using a small suppressor column in performing liquid chromatography |
ATE196949T1 (en) | 1995-03-03 | 2000-10-15 | Alltech Associates Inc | METHOD AND DEVICE FOR THE ELECTROCHEMICAL MODIFICATION OF CHROMATOGRAPHY MATERIAL |
US5569365A (en) * | 1995-03-03 | 1996-10-29 | Dionex Corporation | Intermittent electrolytic membrane suppressor regeneration for ion chromatography |
US5633171A (en) | 1995-03-03 | 1997-05-27 | Dionex Corporation | Intermittent electrolytic packed bed suppressor regeneration for ion chromatography |
US5914025A (en) | 1997-01-09 | 1999-06-22 | Dionex Corporation | Ion chromatographic method and apparatus using ion reflux |
US6027643A (en) | 1997-09-04 | 2000-02-22 | Dionex Corporation | Ion chromatographic method and apparatus using a combined suppressor and eluent generator |
US6325976B1 (en) | 1998-02-26 | 2001-12-04 | Dionex Corporation | Continuous electrolytically regenerated packed bed suppressor for ion chromatography |
-
1998
- 1998-02-26 US US09/031,221 patent/US6325976B1/en not_active Expired - Lifetime
-
1999
- 1999-02-17 WO PCT/US1999/003427 patent/WO1999044054A1/en active IP Right Grant
- 1999-02-17 KR KR10-2000-7009449A patent/KR100423660B1/en not_active IP Right Cessation
- 1999-02-17 CA CA002319813A patent/CA2319813C/en not_active Expired - Lifetime
- 1999-02-17 JP JP2000533752A patent/JP3488202B2/en not_active Expired - Lifetime
- 1999-02-17 EP EP99936120A patent/EP1057013A1/en not_active Ceased
- 1999-02-17 AU AU32988/99A patent/AU754051B2/en not_active Expired
-
2001
- 2001-06-08 US US09/877,667 patent/US6495371B2/en not_active Expired - Lifetime
- 2001-06-08 US US09/877,666 patent/US6508985B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
AU754051B2 (en) | 2002-10-31 |
CA2319813C (en) | 2005-05-03 |
EP1057013A1 (en) | 2000-12-06 |
KR100423660B1 (en) | 2004-03-18 |
US6495371B2 (en) | 2002-12-17 |
WO1999044054A1 (en) | 1999-09-02 |
US20010026773A1 (en) | 2001-10-04 |
US6508985B2 (en) | 2003-01-21 |
US6325976B1 (en) | 2001-12-04 |
KR20010041336A (en) | 2001-05-15 |
JP3488202B2 (en) | 2004-01-19 |
AU3298899A (en) | 1999-09-15 |
US20010026774A1 (en) | 2001-10-04 |
JP2002509238A (en) | 2002-03-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKEX | Expiry |
Effective date: 20190218 |