CA2315543C - Electrostatically fiber planted steel sheet and production process therefor - Google Patents
Electrostatically fiber planted steel sheet and production process therefor Download PDFInfo
- Publication number
- CA2315543C CA2315543C CA002315543A CA2315543A CA2315543C CA 2315543 C CA2315543 C CA 2315543C CA 002315543 A CA002315543 A CA 002315543A CA 2315543 A CA2315543 A CA 2315543A CA 2315543 C CA2315543 C CA 2315543C
- Authority
- CA
- Canada
- Prior art keywords
- steel sheet
- planting
- fiber
- fibers
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 176
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 99
- 239000010959 steel Substances 0.000 title claims abstract description 99
- 238000004519 manufacturing process Methods 0.000 title description 9
- 229920005989 resin Polymers 0.000 claims abstract description 46
- 239000011347 resin Substances 0.000 claims abstract description 46
- 239000000853 adhesive Substances 0.000 claims abstract description 43
- 230000001070 adhesive effect Effects 0.000 claims abstract description 43
- 239000000839 emulsion Substances 0.000 claims abstract description 43
- 239000000203 mixture Substances 0.000 claims abstract description 35
- 239000000049 pigment Substances 0.000 claims abstract description 18
- 239000013530 defoamer Substances 0.000 claims abstract description 13
- 230000009477 glass transition Effects 0.000 claims abstract description 13
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 13
- 239000011248 coating agent Substances 0.000 claims abstract description 12
- 238000000576 coating method Methods 0.000 claims abstract description 12
- 238000004040 coloring Methods 0.000 claims abstract description 9
- 239000006185 dispersion Substances 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 10
- 239000002562 thickening agent Substances 0.000 claims description 8
- 239000003431 cross linking reagent Substances 0.000 claims description 6
- 238000004804 winding Methods 0.000 claims 2
- 239000000758 substrate Substances 0.000 abstract description 19
- 229920000728 polyester Polymers 0.000 abstract description 8
- 229920003002 synthetic resin Polymers 0.000 abstract description 7
- 239000000057 synthetic resin Substances 0.000 abstract description 7
- 239000010410 layer Substances 0.000 description 40
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 229910001335 Galvanized steel Inorganic materials 0.000 description 6
- 239000005038 ethylene vinyl acetate Substances 0.000 description 6
- 239000008397 galvanized steel Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 6
- 229920005749 polyurethane resin Polymers 0.000 description 5
- 230000002265 prevention Effects 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 4
- 239000011247 coating layer Substances 0.000 description 4
- 239000002075 main ingredient Substances 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- 229920000180 alkyd Polymers 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- -1 carbodiimide compound Chemical class 0.000 description 3
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 2
- 239000004035 construction material Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 239000011115 styrene butadiene Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 239000005061 synthetic rubber Substances 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- JMADMUIDBVATJT-UHFFFAOYSA-N 2-methylprop-2-enamide;propan-2-one Chemical compound CC(C)=O.CC(C)=O.CC(=C)C(N)=O JMADMUIDBVATJT-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 1
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920008712 Copo Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910000151 chromium(III) phosphate Inorganic materials 0.000 description 1
- IKZBVTPSNGOVRJ-UHFFFAOYSA-K chromium(iii) phosphate Chemical compound [Cr+3].[O-]P([O-])([O-])=O IKZBVTPSNGOVRJ-UHFFFAOYSA-K 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007739 conversion coating Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- SHHGHQXPESZCQA-UHFFFAOYSA-N oxiran-2-ylmethylsilicon Chemical compound [Si]CC1CO1 SHHGHQXPESZCQA-UHFFFAOYSA-N 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/16—Layered products comprising a layer of metal next to a particulate layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
- B05D1/12—Applying particulate materials
- B05D1/14—Flocking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/18—Layered products comprising a layer of metal comprising iron or steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
- B05D1/04—Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
- B05D1/06—Applying particulate materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
Abstract
A fiber planted steel sheet obtained by forming only a fiber planting layer having excellent adhesion to a substrate made from a composition having special composition on the surface of a surface treated steel sheet as a substrate without forming a primer of a polyester synthetic resin containing an anticorrosive pigment and the like and electrostatically planting short fibers in the planting layer. Therefore, the electrostatically fiber planted steel sheet is produced by coating an aqueous adhesive composition for planting fibers comprising an emulsion resin having a glass transition temperature of -40 to 40 °C, aqueous coloring pigment dispersion, defoamer and pH modifier on the surface of the surface treated steel sheet to form a fiber planting layer having excellent adhesion to the steel sheet on the surface of the steel sheet and electrostatically planting short fibers while the surface of the planting layer retains adhesion.
Description
ELEC'I'ROSTATICALLY FIBER PLANTED STEEL SHEET
AND PRODUCTION PROCESS THEREFOR
BACKGROUND OF THE INVENTION
Field of the Invention The present invention relates to a fiber planted steel sheet comprising a surface treated steel sheet or the like as a substrate, a fiber planting layer which is directly formed on the substrate without: a primer made from a synthetic resin containing an anticorrosive pigment formed on the substrate and an electrostatically short fiber planted layer formed on the planting layer and to a production process therefor.
Description of the Prior Art As a prior art to the present invention, there is known a fiber planted steel sheet to be formed which is produced by degreasing the su:=face of a steel sheet, subjecting it to a chemical conversion treatment with chromic acid to improve adhesion between the steel sheet and a polyester synthetic resin, formirrg a polyester synthetic resin layer containing an anticorrosive pigment on this surface treated steel sheet, forming on part o.- al]. of the surface of the resin layer a reactive acrylic adhesive layer having flexibility which is not broken, cracked or separated at the time of drawing or bending and planting syrlthetic resin piles on this adhesive layer electrostat__call.y (for example, Japanese Patent Publication No. 27864j1987).
There are known a. f'iber planted steel material produced by subjecting the surface of an H type steel, steel tube, sheet pile or steel sheet useci as a construction steel material to a rust removal treatment with a shot blast, grinder, belt sander or the like, coatir..g it with an acrylic urethane-based adhesive and planting non-metal fibers while it is uncured and a production process therefor (for example, Japanese Patent Disclosure No. 138813/1993).
It is known that a chemical conversion coating film is formed by treating both sides of aluminum or an alloy thereof with chromic acid or chromium phosphate, the film is coated with an acryloniti-ile-butadiene copolymer rubber emulsion adhesive and fibers such as nylon pile are planted on this film (Japanese Patent I)iscl.osure No. 34778/1972).
As a prior art related to an electrostatic planting adhesive for a weather strip member used in lower and upper opening/closi.ng portions of car window glass, there is known an adhesive which compr:ises 100 parts by weight of an ethylene-vinyl acetate copolymer, 1 to 30 parts by weight of a non-yellowing urethane prepolymer (this polymer is a non-yellowing polyisocya.nate resin used as a curing agent for an ethylene-vinyl acetate copolymer) , 0. 1 to 5 parts by weight of a glycidyl silane coupling agent and 0. 01 to 5 parts by weight of a wetting agent. (Japanese Patent Disclosure No.
145635/1994).
The present applicant proposes an electrostatically fiber planted steel. sheet produced by forming a fiber planting layer of afiberbon3ing aqueouscoat.ingcompositioncomprising an aqueous epoxy modified polyurethane resin, aqueous acidic black dye, antifoaming agent and pH modifier formed on the surface of a surface treated steel sheet and an electrostatically fiber planted layer of organic short fibers on the planting layer (Japanese Patent Disclosure No.
258472/1998).
The above proposal of the present applicant has such an economical problem that an expensive polyurethane resin must be used though an extra step of forming a primer such as a polyester synthetic resin containing an anticorrosive pigment or the like can be eliminated. Since a disperse solvent other than water is separated aLt the time of drying the f iber bonding aqueous coating composit:ion when a polyurethane resin is used in the fiber bonding aqueous coating composition, means of collecting the disperse solvent is required, resulting in a bulky apparatus.
The present invention provides an electrostatically fiber planted steel sheet produced by using a surface treated steel sheet such as a commercially available galvanized steel sheet (including products treated with a chromate or coated with an orgar.iic or inorganic composite film containing no chromium) as a sutstrate, directly forming a fiber planting layer of an aqueous adhesive composition for planting fibers which is essentially composed of a specific aqueous emulsion resin on the surface of the substrate such as a steel sheet without a pricner oi: a polyester synthetic resin containing an anticorrosive pigment in the prior art on the surface of the substrate, and electrostatically planting short fibers on this planting layer as well a.s a process for producing the same at a low cost.
AND PRODUCTION PROCESS THEREFOR
BACKGROUND OF THE INVENTION
Field of the Invention The present invention relates to a fiber planted steel sheet comprising a surface treated steel sheet or the like as a substrate, a fiber planting layer which is directly formed on the substrate without: a primer made from a synthetic resin containing an anticorrosive pigment formed on the substrate and an electrostatically short fiber planted layer formed on the planting layer and to a production process therefor.
Description of the Prior Art As a prior art to the present invention, there is known a fiber planted steel sheet to be formed which is produced by degreasing the su:=face of a steel sheet, subjecting it to a chemical conversion treatment with chromic acid to improve adhesion between the steel sheet and a polyester synthetic resin, formirrg a polyester synthetic resin layer containing an anticorrosive pigment on this surface treated steel sheet, forming on part o.- al]. of the surface of the resin layer a reactive acrylic adhesive layer having flexibility which is not broken, cracked or separated at the time of drawing or bending and planting syrlthetic resin piles on this adhesive layer electrostat__call.y (for example, Japanese Patent Publication No. 27864j1987).
There are known a. f'iber planted steel material produced by subjecting the surface of an H type steel, steel tube, sheet pile or steel sheet useci as a construction steel material to a rust removal treatment with a shot blast, grinder, belt sander or the like, coatir..g it with an acrylic urethane-based adhesive and planting non-metal fibers while it is uncured and a production process therefor (for example, Japanese Patent Disclosure No. 138813/1993).
It is known that a chemical conversion coating film is formed by treating both sides of aluminum or an alloy thereof with chromic acid or chromium phosphate, the film is coated with an acryloniti-ile-butadiene copolymer rubber emulsion adhesive and fibers such as nylon pile are planted on this film (Japanese Patent I)iscl.osure No. 34778/1972).
As a prior art related to an electrostatic planting adhesive for a weather strip member used in lower and upper opening/closi.ng portions of car window glass, there is known an adhesive which compr:ises 100 parts by weight of an ethylene-vinyl acetate copolymer, 1 to 30 parts by weight of a non-yellowing urethane prepolymer (this polymer is a non-yellowing polyisocya.nate resin used as a curing agent for an ethylene-vinyl acetate copolymer) , 0. 1 to 5 parts by weight of a glycidyl silane coupling agent and 0. 01 to 5 parts by weight of a wetting agent. (Japanese Patent Disclosure No.
145635/1994).
The present applicant proposes an electrostatically fiber planted steel. sheet produced by forming a fiber planting layer of afiberbon3ing aqueouscoat.ingcompositioncomprising an aqueous epoxy modified polyurethane resin, aqueous acidic black dye, antifoaming agent and pH modifier formed on the surface of a surface treated steel sheet and an electrostatically fiber planted layer of organic short fibers on the planting layer (Japanese Patent Disclosure No.
258472/1998).
The above proposal of the present applicant has such an economical problem that an expensive polyurethane resin must be used though an extra step of forming a primer such as a polyester synthetic resin containing an anticorrosive pigment or the like can be eliminated. Since a disperse solvent other than water is separated aLt the time of drying the f iber bonding aqueous coating composit:ion when a polyurethane resin is used in the fiber bonding aqueous coating composition, means of collecting the disperse solvent is required, resulting in a bulky apparatus.
The present invention provides an electrostatically fiber planted steel sheet produced by using a surface treated steel sheet such as a commercially available galvanized steel sheet (including products treated with a chromate or coated with an orgar.iic or inorganic composite film containing no chromium) as a sutstrate, directly forming a fiber planting layer of an aqueous adhesive composition for planting fibers which is essentially composed of a specific aqueous emulsion resin on the surface of the substrate such as a steel sheet without a pricner oi: a polyester synthetic resin containing an anticorrosive pigment in the prior art on the surface of the substrate, and electrostatically planting short fibers on this planting layer as well a.s a process for producing the same at a low cost.
SUMMAFtY OF THE INVENTION
The fiber planting layer of the present invention is improved to have exce:Llent adhesion strength to a substrate such as a surface treated steel sheet and high flexibility.
Therefore, when the fiber planted substrate is processed (for example, pressed or for.rned) , the planting layer is not broken, cracked or separated.
The electrostatically fiber planted steel sheet of the present inven.tion can be used as a raw material for construction material products such as ducts for the prevention of dripping of condensed dew and panels for the prevention of dripping of condensed dew, kitchen utensils, electric appliances, office equipment, car parts, toys, containers, casings and the like by using a surface treated steel sheet such as a commercially available galvanized steel sheet as a substrate and planting fibers in the stei=_l sheet electrostatically.
The present j_nvention also provides a fiber planted steel sheet by directly forming a fiber plating layer of an aqueous adhesive composition for planting fibers essentially composed of an aqueousemulsionresin having a specific glass transition temperature of -40 to 40 ~C on the substrate without using an aqueous polyurethane resin containing a polar solvent, for example, a disperse solvent other than water such as N
methylpyrrolidoneandelectrostatically planting short f ibers in this planting layer as well as a process for producing the same at a low cost.
The emulsior. resir.L which is the main ingredient of the aqueous adhesive composition for planting fibers forming the fiber planting layer of the present invention is mainly an acrylic emulsion or ethylene-vinyl acetate emulsion resin.
Other emulsion resins such as a synthetic rubber emulsion typified by styrene-butadiene, vinylchloride -basedemulsion, vinylidene chloride-based emulsion, alkyd resin-based emulsion, polyester-based emulsion, phenolic resin-based emulsion and copo:_ymer emulsions thereof may be used and the glass transition temperature of the main ingredient resin is limited to -40 to 40 C.
As for other cornponents of the aqueous adhesive composition for planting fibers, 0 to 20 parts by weight of an aqueous pigment dispersion, 0 to 3 parts by weight of a defoamer, 0 to 5 parts by weight of a pH modifier, 0 to 25 parts by weight of a crosslinking agent, 0 to 10 pats by weight of a thickener, 0 to 20 parts by weight of a water-soluble resin and an emulsion resin having a glass transition temperature outside the above range are suitably mixed together based on 100 parts by weight of the above emulsion resin as required.
The plantinq operation is carried out in such a manner that the fiber pla.nting voltage is controlled to 10 to 80 kV
or the viscosity of the aqueous adhesive composition for planting fibers is adjusted to 200 to 20,000 cps/25 - C at the time of planting fibers to ensure that the roots of the short fibers are situate!d at an intermediate position of the fiber planting layer and the short fibers do not contact the surface of the surface treated steel sheet through the fiber planting layer.
Since the fiber planting layer made from the aqueous adhesive composition for planting fibers used in the electrostatically fiber planted steel sheet of the present invention has exce.llent adhesion strength to a substrate such as a steel sheet and high flexibility, it is not broken, cracked or separated when the fiber planted substrate is processed (pressed or ~ormed) . I t also has excellent fiber adhesion that the planted short fibers do not fall off at the time of processing.
In the present invention, a fiber planting layer having high flexibility and excellent adhesion to a substrate can be formed on a su.bstrate such as a steel sheet by coating a special aqueous adhesive composition forplanting fibers on the surface of asurfacetreatedsteelsheet. Therefore, the coating layer is not brokeri, cracked or separated when the obtained fiber planted steel sheet product is processed such as drawn or bent and the planted short fibers do not fall off at the time of processing.
Since the electrostatically fiber planted steel sheet product planted with fi:bers using the aqueous adhesive composition for plantinq fibers of the present invention has excellent in not only processing but also the prevention of dripping of condensed dew, incombustibility and corrosion resistance, the fiber planted steel sheet product of the present invention can be used as a raw material for construction material products such as ducts for the prevention of dripping of condensed dew a::id panels for the prevention of dripping of condensed dew, kitchen utensils, electric appliances, office equipment, auto cars parts, toys, containers and casings.
Further, in the production of conventional electrostatically fiber planted steel sheets, a steel sheet is subjected to an electrostatic fiber planting treatment. In the production of the electrostatically fiber planted steel sheet of the present invention, a rolled surface treated steel sheet can be unrolled, straightened out, subjectect to an electrostatic fiber plariting treatment continuously and then wound up, it has an effect specific to the present invention that it can be slit into a thin belt and supplied as a raw material for rolled products such as a spiral tube.
Therefore, it is a first object of the present invention to make it possible to use a surface treated steel sheet such as a rolled galvanized steel sheet (including products treated with a chromate or coated with an organic or inorganic composite film containing no chromium) as a substrate for an electrostatically fiber planted steel sheet.
It is a second object of the present invention to provide an electrostatica=_ly fiber planted steel sheet produced by directly forming a fiber planting layer on a surface treated steel sheet as a:>ubst.rate without a primer of a polyester synthetic resin containing an anticorrosive pigment or the like and electrostatically planting short fibers in this planting layer as well as a process for producing the same at a low cost.
It is a third. object of the present invention to provide an electrosta.tica].ly fiber planted steel sheet produced by directly forming a fiber planting layer of an aqueous adhesive composition for plantirrg fibers which is essentially composed of a specified aqueous emulsion resin on a substrate such as a surface treated steel sheet and electrostatically planting short fibers in tr. is planting layer as well as a process for producing the same at a low cost.
The above ob lects and advantages of the present invention will become more apparent from the following description when taken in conjunction with the accompanying drawings.
BRIEF DESCRIPTION OF THE ATTACHED DRAWINGS
Fig. 1 is a side view of the cross section of an embodiment of a fiber planted steel sheet product obtained by the process of the preserit inventi.on; and Fig. 2 is a partially enlarged sectional view for explaining the fiber planted state of the fiber planted steel sheet product: shovin in Fig. 1.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The surface treated steel sheet used in the present invention is a hot-dipped galvanized steel sheet, alloy-based hot-dipped steel sheet, electrically galvanized steel sheet, alloy electroplated steel sheet, precoated steel sheet or the like. The galvanized steel sheet includes products treated with a chromate or coated with an organic or inorganic composite film containing no chromium. The short fibers to be electrostatically planted in the fiber planting layer are chemical fibers such as regenerated fibers, semi-synthetic fibers or synthetic fibers, or natural fibers suchasvegetable fibers, animal fibers, carbon fibers or glass fibers and may be either organic fiber.s or inorganic fibers.
An acrylic emulsion of the aqueous adhesive composition for plantingfibersusedintheelectrostaticallyfiberplanted steel sheet of the present invention is obtained by emulsion copolymerizing a monomer such as methyl methacrylate, ethyl methacrylate, isopropyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, n-hexyl methacrylate, 2-ethylhexyl methacrylate, lauryl methacrylate, methacrylic acid, hydroxypropyl methacrylate, glycidyl methacrylate, acrylic acid, methyl acrylate, ethyl acrylate, isopropyl acrylate, n-butyl acrylate, 2-eth.ylhexyl acrylate, hydroxypropyl acrylate, hydroxybutyl acrylate, acrylic amide, N-methylol acrylamide, diacetone acrylamide, diacetone methacrylamide, styrene, vinyl toluene, acrylonitrile, methacrylonitrile or vinyl acetate in accordarice with a conventionally known method.
The ethylene-vinyl acetate-based emulsion is obtained by conventiorially known emulsion copolymerization or melting an ethylene-vinyl acetate resin which is a thermoplastic resin by heating and emulsifyirig it in water by a known method. Other emulsions are obtained by the known method.
Besides these main ingredients, an aqueous coloring pigment dispersion [example of trade product: Aqua Fine Color of Dainichi ;3eika Kogyosha Co.], defoamer [Defoamer of Sun Nopco Co.], pH modifier such as a tertiary amine, aqueous crosslinking agent for the functional group of an emulsion resin [oxazoline pendant resin, ethylene imine compound, carbodiimide compound, :melamine resin, epoxy resin, amino resin, block isocyanate compound, metal salt compound, etc. ], thickener [example of ti-ade product: Primal of Rohm and Harse Co.], and water-soluble resin [alkyd resin-based, acrylic resin-based, styrene resin-based, epoxy resin-based, cellulose resin-based, etc.] are added as required.
Stated more specifically, as for the composition of the aqueous adhesive composition for planting fibers, 0 to 20 parts by weight of an aqueous coloring pigment dispersion, 0 to 3 parts by weiqht of' a defoamer, 0 to 5 parts by weight of a pH
modifier, 0 to 25 parts by weight of a crosslinking agent, 0 to 10 parts by weight of a thickener, 0 to 20 parts by weight of a water-soluble resin and an emulsion resin having a glass transition temperature outside the specified range are suitably mixed together based on 100 parts by weight of the emulsion resin having a specific transition temperature of -40 to 40 - C. To blend thern, they are stirred with a disperser for 5 to 10 minutes to adjust a pH value to 7.0 to 9.0 in the end.
Although bubbles are formed right after production, the aqueous adhesive composition is used 2 to 3 hours after production.
The emulsion resiri having a specific transition temperature of -40 to 40 - C is mainly an acrylic emulsion resin or ethylene-vinyl ace'tate-based emulsion resin. Other emulsion resin such as a styrene-butadiene synthetic rubber-based emulsion, viriyl chloride-based emulsion, vinylidene chloride-based emulsion, alkyd resin-based emulsion, polyester-based erlulsi.on, phenolic resin-based emulsion or copolymer emulsiorr thereof may be used.
In the present irivention, an aqueous resin which is an emulsion resin hav:-ng a specific transition temperature of -40 to 40 - C is used. This emulsion resin aqueous resin generally has an organic resin particle diameter of 0.114-yn or more, enables organic resin particles having a diameter of 0.01 to 0. 1/{!.m to suspend in water and can keep the particles suspending in water stably by ionizing the particles or adding an emulsifier. Since this emulsion resin aqueous resin is an anionic self-emulsified organic resin and has a hydrophilic group which :Ls an ionic functional group in the interior of its resin particle, the resin itself can suspend in water. As for the physical properties of the coating film, as resin particles emulsion suspending in water form a coating film through fusion polymerization, the coating film has excellent adhesion.
As for the characteristic properties of the aqueous adhesive composition for planting fibers used in the electrostatically fiber planted steel sheet of the present invention, since the composition is water-soluble, it has such an advantage that 3-t is not necessary to use an organic solvent having high contamination properties. A coating layer having flexibility c:an be formed by applying an aqueous solution of this adhesive composition to a substrate with a roll coater, spray or applicator and the thickness of the coating layer after drying is about 10 to 50.4ft. Examples are provided to further illustrate the present invention.
(Example 1) Fig. 1 is a sectional view showing the structure of an electrostatically fiber planted steel sheet obtained by the production process of the present invention. In Fig. 1, reference numeral 1 is a surface treated steel sheet as a substrate, 2 an electrostatically fiber planting layer formed on the surface of the surface treated steel sheet 1 and coated with an adhesive composition, and 3 short fibers planted in the electrostatically fiber planting layer 2 by electrostatic fiber planting operation. In this Example, organic short fibers are plante~d as the short fibers 3.
To produce this electrostatically fiber planted steel sheet, an aqueous adhesive compositionfor planting fibers was first obtained by adding 1 part by weight of a defoamer, 0.5 part by weight of diethanolamine (pH modifier) and 5 parts by weight of an aqueous epoxy resin to 100 parts by weight of an acrylic emulsion (soli(i content of 55 %) having a glass transition temperature of -20 0 C obtained from methyl methacrylate and 2-ethy7Lhexyl acrylate as main ingredients and stirring them wit.h a d:isperser for 10 minutes.
This aqueous adhesive composition for planting fibers having a sol:id coritent: of 55 %, a viscosity of 2, 000 cps/25 - C
and a pH of 8.0 was coated on a surface treated steel sheet with a reverse ro:.l coater in a wet state to 50_4,11q and organic short fibers of nylon. 66 were planted immediately in the obtained coating laye:r using an electrostatic fiber planting apparatus (of Mesac C'.o.) at a voltage of 30 kV to form an electrostatically fibeir planted layer.
In the above fiber planting operation, the above electrostatically fiber planted layer is such as shown in the enlarged sectional view of Fig. 2 that the voltage of the electrostatic fiber planting apparatus had to be controlled or the viscosity of the adhesive conlposition had to be adjusted to ensure that the roots 3a of the organic short fibers 3 were situated at an intermediate portion of the electrostatically fiber planting la'Yer 2 and that the organic short fibers 3 did not contact the surface la of the surface treated steel sheet 1 as a substrate through the electrostatically fiber planting layer 2. This is because if the roots 3a of the planted organic short fibers 3 contacted the surface la of the surface treated steel sheet 1 through t:he electrostatically fiber planting layer 2, the electrostatically fiber planting layer 2 would be easily separated frorn the surface treated steel sheet 1 at the time of processing or use. After the organic short fibers 3 were planted as described above, the coating was forcedly dried in a di:rer at a temperature of 150 to 200 ~C for 3 minutes to obtain an electrostatically fiber planted steel sheet product. A r-oll coater or applicator may be used to coat the adhesive composit:ion on the surface treated steel sheet 1. The electrostatically fiber planted steel sheet shown in Fig. 1 is obtained by this operation.
(Example 2) As an alternative method different from that of Example 1, to produce an electrostatically fiber planted steel sheet, 15 parts by weight of an acrylic emtilsion resin (solid content of 50 %) having a glass transition temperature of 40 - C obtained by copolymerizing methyl methacrylate, n-butyl acrylate and hydroxypropyl acrylate, 0.5 part by weight of a defoamer, 1 part by weight of ammonia (pH modifier) and 3 parts by weight of aqueous block :Lsocyanate were added to 100 parts by weight of an ethylene-vinyl acetate emulsion resin (solid content of 55 %) having a glass transition temperature of -18 OC and stirred with a disperser for 10 minutes to obtain an aqueous adhesive composit:ion for planting fibers.
This aqueous adhesive composition for planting fibers havirig a solid corrtent: of 52 %, a viscosity of 5, 000 cps/25 0 C
and a pH of 3.5 were coated on a surface treated steel sheet with a reverse ro:Ll coater in a wet state to 60.411t and organic short fibers. of nylon 66 were planted immediately using an electrostatic fiber planting apparatus (of Mesac Co.) at a voltage of 40 kV to for=m an electrostatically fiber planted layer. Also in this Example 2, the same care as in Example 1 must be taken to plant fibers.
The results of a durability test made on the fiber planted steel sheet products obtained in the above Examples 1 and 2 in accordance with JIS-K-5400 (general coating test standard) and a scratch test not specified in JIS and conducted additionally on these products are shown in Table 1.
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flex resistance: test for the examination of separation of an adhesive fiber planting layer by pressing an electrostatically fiber planted steel sheet against an iron bar having a diameter of 2 mm to bend it.
adhesion/cross-cut test method: test for the examination of separation of the adhesive f iber planting layer of the electrostatically fiber pianted steel sheet by cross cutting the layer and affixing an adhesive tape to the layer.
impact resistance test/Dupont method: test for the examination of separation of the adhesive fiber planting layer by dropping a steel ball having a weight of 500 g and a radius of 1/2 inch from a height of 50 cm onto the electrostatically fiber planted steel sheet.
Erichsen value/breaking length method: test for the examination of separation of the adhesive f iber planting layer by pushing a steel ball. having a diameter of 20 0.005 mm from the back of the el.ectro.statically fiber planted steel sheet.
moisture resistance test/fixed method: test by leaving at a temperature of 40 ~C and a humidity of 95 % for 240 hours.
scratch test/coin. method: test for the examination of separation of the surface by scratching with a 10 yen coin under a load of 500 g.
In the above description, the aqueous adhesive composition for planting fibers used in the electrostatically fiber planted steel sheet of the present invention comprises an aqueous polyurethane resin, aqueous acrylic resin, aqueous coloring pig;:nent paste, thickener, defoamer and pH modifier.
A fiber planted steel sheet can be pi-oduced by forming a coating layer from an aqueous adhesive composition for planting fibers comprising various components and planting short fibers in the layer.
While the preferred embodiments of the present invention have been described, it will be obvious to those skilled in the art that various preferred changes and modifications may be made without departing from the spirit of the invention and should be covered as fall within the scope of the invention.
The fiber planting layer of the present invention is improved to have exce:Llent adhesion strength to a substrate such as a surface treated steel sheet and high flexibility.
Therefore, when the fiber planted substrate is processed (for example, pressed or for.rned) , the planting layer is not broken, cracked or separated.
The electrostatically fiber planted steel sheet of the present inven.tion can be used as a raw material for construction material products such as ducts for the prevention of dripping of condensed dew and panels for the prevention of dripping of condensed dew, kitchen utensils, electric appliances, office equipment, car parts, toys, containers, casings and the like by using a surface treated steel sheet such as a commercially available galvanized steel sheet as a substrate and planting fibers in the stei=_l sheet electrostatically.
The present j_nvention also provides a fiber planted steel sheet by directly forming a fiber plating layer of an aqueous adhesive composition for planting fibers essentially composed of an aqueousemulsionresin having a specific glass transition temperature of -40 to 40 ~C on the substrate without using an aqueous polyurethane resin containing a polar solvent, for example, a disperse solvent other than water such as N
methylpyrrolidoneandelectrostatically planting short f ibers in this planting layer as well as a process for producing the same at a low cost.
The emulsior. resir.L which is the main ingredient of the aqueous adhesive composition for planting fibers forming the fiber planting layer of the present invention is mainly an acrylic emulsion or ethylene-vinyl acetate emulsion resin.
Other emulsion resins such as a synthetic rubber emulsion typified by styrene-butadiene, vinylchloride -basedemulsion, vinylidene chloride-based emulsion, alkyd resin-based emulsion, polyester-based emulsion, phenolic resin-based emulsion and copo:_ymer emulsions thereof may be used and the glass transition temperature of the main ingredient resin is limited to -40 to 40 C.
As for other cornponents of the aqueous adhesive composition for planting fibers, 0 to 20 parts by weight of an aqueous pigment dispersion, 0 to 3 parts by weight of a defoamer, 0 to 5 parts by weight of a pH modifier, 0 to 25 parts by weight of a crosslinking agent, 0 to 10 pats by weight of a thickener, 0 to 20 parts by weight of a water-soluble resin and an emulsion resin having a glass transition temperature outside the above range are suitably mixed together based on 100 parts by weight of the above emulsion resin as required.
The plantinq operation is carried out in such a manner that the fiber pla.nting voltage is controlled to 10 to 80 kV
or the viscosity of the aqueous adhesive composition for planting fibers is adjusted to 200 to 20,000 cps/25 - C at the time of planting fibers to ensure that the roots of the short fibers are situate!d at an intermediate position of the fiber planting layer and the short fibers do not contact the surface of the surface treated steel sheet through the fiber planting layer.
Since the fiber planting layer made from the aqueous adhesive composition for planting fibers used in the electrostatically fiber planted steel sheet of the present invention has exce.llent adhesion strength to a substrate such as a steel sheet and high flexibility, it is not broken, cracked or separated when the fiber planted substrate is processed (pressed or ~ormed) . I t also has excellent fiber adhesion that the planted short fibers do not fall off at the time of processing.
In the present invention, a fiber planting layer having high flexibility and excellent adhesion to a substrate can be formed on a su.bstrate such as a steel sheet by coating a special aqueous adhesive composition forplanting fibers on the surface of asurfacetreatedsteelsheet. Therefore, the coating layer is not brokeri, cracked or separated when the obtained fiber planted steel sheet product is processed such as drawn or bent and the planted short fibers do not fall off at the time of processing.
Since the electrostatically fiber planted steel sheet product planted with fi:bers using the aqueous adhesive composition for plantinq fibers of the present invention has excellent in not only processing but also the prevention of dripping of condensed dew, incombustibility and corrosion resistance, the fiber planted steel sheet product of the present invention can be used as a raw material for construction material products such as ducts for the prevention of dripping of condensed dew a::id panels for the prevention of dripping of condensed dew, kitchen utensils, electric appliances, office equipment, auto cars parts, toys, containers and casings.
Further, in the production of conventional electrostatically fiber planted steel sheets, a steel sheet is subjected to an electrostatic fiber planting treatment. In the production of the electrostatically fiber planted steel sheet of the present invention, a rolled surface treated steel sheet can be unrolled, straightened out, subjectect to an electrostatic fiber plariting treatment continuously and then wound up, it has an effect specific to the present invention that it can be slit into a thin belt and supplied as a raw material for rolled products such as a spiral tube.
Therefore, it is a first object of the present invention to make it possible to use a surface treated steel sheet such as a rolled galvanized steel sheet (including products treated with a chromate or coated with an organic or inorganic composite film containing no chromium) as a substrate for an electrostatically fiber planted steel sheet.
It is a second object of the present invention to provide an electrostatica=_ly fiber planted steel sheet produced by directly forming a fiber planting layer on a surface treated steel sheet as a:>ubst.rate without a primer of a polyester synthetic resin containing an anticorrosive pigment or the like and electrostatically planting short fibers in this planting layer as well as a process for producing the same at a low cost.
It is a third. object of the present invention to provide an electrosta.tica].ly fiber planted steel sheet produced by directly forming a fiber planting layer of an aqueous adhesive composition for plantirrg fibers which is essentially composed of a specified aqueous emulsion resin on a substrate such as a surface treated steel sheet and electrostatically planting short fibers in tr. is planting layer as well as a process for producing the same at a low cost.
The above ob lects and advantages of the present invention will become more apparent from the following description when taken in conjunction with the accompanying drawings.
BRIEF DESCRIPTION OF THE ATTACHED DRAWINGS
Fig. 1 is a side view of the cross section of an embodiment of a fiber planted steel sheet product obtained by the process of the preserit inventi.on; and Fig. 2 is a partially enlarged sectional view for explaining the fiber planted state of the fiber planted steel sheet product: shovin in Fig. 1.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The surface treated steel sheet used in the present invention is a hot-dipped galvanized steel sheet, alloy-based hot-dipped steel sheet, electrically galvanized steel sheet, alloy electroplated steel sheet, precoated steel sheet or the like. The galvanized steel sheet includes products treated with a chromate or coated with an organic or inorganic composite film containing no chromium. The short fibers to be electrostatically planted in the fiber planting layer are chemical fibers such as regenerated fibers, semi-synthetic fibers or synthetic fibers, or natural fibers suchasvegetable fibers, animal fibers, carbon fibers or glass fibers and may be either organic fiber.s or inorganic fibers.
An acrylic emulsion of the aqueous adhesive composition for plantingfibersusedintheelectrostaticallyfiberplanted steel sheet of the present invention is obtained by emulsion copolymerizing a monomer such as methyl methacrylate, ethyl methacrylate, isopropyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, n-hexyl methacrylate, 2-ethylhexyl methacrylate, lauryl methacrylate, methacrylic acid, hydroxypropyl methacrylate, glycidyl methacrylate, acrylic acid, methyl acrylate, ethyl acrylate, isopropyl acrylate, n-butyl acrylate, 2-eth.ylhexyl acrylate, hydroxypropyl acrylate, hydroxybutyl acrylate, acrylic amide, N-methylol acrylamide, diacetone acrylamide, diacetone methacrylamide, styrene, vinyl toluene, acrylonitrile, methacrylonitrile or vinyl acetate in accordarice with a conventionally known method.
The ethylene-vinyl acetate-based emulsion is obtained by conventiorially known emulsion copolymerization or melting an ethylene-vinyl acetate resin which is a thermoplastic resin by heating and emulsifyirig it in water by a known method. Other emulsions are obtained by the known method.
Besides these main ingredients, an aqueous coloring pigment dispersion [example of trade product: Aqua Fine Color of Dainichi ;3eika Kogyosha Co.], defoamer [Defoamer of Sun Nopco Co.], pH modifier such as a tertiary amine, aqueous crosslinking agent for the functional group of an emulsion resin [oxazoline pendant resin, ethylene imine compound, carbodiimide compound, :melamine resin, epoxy resin, amino resin, block isocyanate compound, metal salt compound, etc. ], thickener [example of ti-ade product: Primal of Rohm and Harse Co.], and water-soluble resin [alkyd resin-based, acrylic resin-based, styrene resin-based, epoxy resin-based, cellulose resin-based, etc.] are added as required.
Stated more specifically, as for the composition of the aqueous adhesive composition for planting fibers, 0 to 20 parts by weight of an aqueous coloring pigment dispersion, 0 to 3 parts by weiqht of' a defoamer, 0 to 5 parts by weight of a pH
modifier, 0 to 25 parts by weight of a crosslinking agent, 0 to 10 parts by weight of a thickener, 0 to 20 parts by weight of a water-soluble resin and an emulsion resin having a glass transition temperature outside the specified range are suitably mixed together based on 100 parts by weight of the emulsion resin having a specific transition temperature of -40 to 40 - C. To blend thern, they are stirred with a disperser for 5 to 10 minutes to adjust a pH value to 7.0 to 9.0 in the end.
Although bubbles are formed right after production, the aqueous adhesive composition is used 2 to 3 hours after production.
The emulsion resiri having a specific transition temperature of -40 to 40 - C is mainly an acrylic emulsion resin or ethylene-vinyl ace'tate-based emulsion resin. Other emulsion resin such as a styrene-butadiene synthetic rubber-based emulsion, viriyl chloride-based emulsion, vinylidene chloride-based emulsion, alkyd resin-based emulsion, polyester-based erlulsi.on, phenolic resin-based emulsion or copolymer emulsiorr thereof may be used.
In the present irivention, an aqueous resin which is an emulsion resin hav:-ng a specific transition temperature of -40 to 40 - C is used. This emulsion resin aqueous resin generally has an organic resin particle diameter of 0.114-yn or more, enables organic resin particles having a diameter of 0.01 to 0. 1/{!.m to suspend in water and can keep the particles suspending in water stably by ionizing the particles or adding an emulsifier. Since this emulsion resin aqueous resin is an anionic self-emulsified organic resin and has a hydrophilic group which :Ls an ionic functional group in the interior of its resin particle, the resin itself can suspend in water. As for the physical properties of the coating film, as resin particles emulsion suspending in water form a coating film through fusion polymerization, the coating film has excellent adhesion.
As for the characteristic properties of the aqueous adhesive composition for planting fibers used in the electrostatically fiber planted steel sheet of the present invention, since the composition is water-soluble, it has such an advantage that 3-t is not necessary to use an organic solvent having high contamination properties. A coating layer having flexibility c:an be formed by applying an aqueous solution of this adhesive composition to a substrate with a roll coater, spray or applicator and the thickness of the coating layer after drying is about 10 to 50.4ft. Examples are provided to further illustrate the present invention.
(Example 1) Fig. 1 is a sectional view showing the structure of an electrostatically fiber planted steel sheet obtained by the production process of the present invention. In Fig. 1, reference numeral 1 is a surface treated steel sheet as a substrate, 2 an electrostatically fiber planting layer formed on the surface of the surface treated steel sheet 1 and coated with an adhesive composition, and 3 short fibers planted in the electrostatically fiber planting layer 2 by electrostatic fiber planting operation. In this Example, organic short fibers are plante~d as the short fibers 3.
To produce this electrostatically fiber planted steel sheet, an aqueous adhesive compositionfor planting fibers was first obtained by adding 1 part by weight of a defoamer, 0.5 part by weight of diethanolamine (pH modifier) and 5 parts by weight of an aqueous epoxy resin to 100 parts by weight of an acrylic emulsion (soli(i content of 55 %) having a glass transition temperature of -20 0 C obtained from methyl methacrylate and 2-ethy7Lhexyl acrylate as main ingredients and stirring them wit.h a d:isperser for 10 minutes.
This aqueous adhesive composition for planting fibers having a sol:id coritent: of 55 %, a viscosity of 2, 000 cps/25 - C
and a pH of 8.0 was coated on a surface treated steel sheet with a reverse ro:.l coater in a wet state to 50_4,11q and organic short fibers of nylon. 66 were planted immediately in the obtained coating laye:r using an electrostatic fiber planting apparatus (of Mesac C'.o.) at a voltage of 30 kV to form an electrostatically fibeir planted layer.
In the above fiber planting operation, the above electrostatically fiber planted layer is such as shown in the enlarged sectional view of Fig. 2 that the voltage of the electrostatic fiber planting apparatus had to be controlled or the viscosity of the adhesive conlposition had to be adjusted to ensure that the roots 3a of the organic short fibers 3 were situated at an intermediate portion of the electrostatically fiber planting la'Yer 2 and that the organic short fibers 3 did not contact the surface la of the surface treated steel sheet 1 as a substrate through the electrostatically fiber planting layer 2. This is because if the roots 3a of the planted organic short fibers 3 contacted the surface la of the surface treated steel sheet 1 through t:he electrostatically fiber planting layer 2, the electrostatically fiber planting layer 2 would be easily separated frorn the surface treated steel sheet 1 at the time of processing or use. After the organic short fibers 3 were planted as described above, the coating was forcedly dried in a di:rer at a temperature of 150 to 200 ~C for 3 minutes to obtain an electrostatically fiber planted steel sheet product. A r-oll coater or applicator may be used to coat the adhesive composit:ion on the surface treated steel sheet 1. The electrostatically fiber planted steel sheet shown in Fig. 1 is obtained by this operation.
(Example 2) As an alternative method different from that of Example 1, to produce an electrostatically fiber planted steel sheet, 15 parts by weight of an acrylic emtilsion resin (solid content of 50 %) having a glass transition temperature of 40 - C obtained by copolymerizing methyl methacrylate, n-butyl acrylate and hydroxypropyl acrylate, 0.5 part by weight of a defoamer, 1 part by weight of ammonia (pH modifier) and 3 parts by weight of aqueous block :Lsocyanate were added to 100 parts by weight of an ethylene-vinyl acetate emulsion resin (solid content of 55 %) having a glass transition temperature of -18 OC and stirred with a disperser for 10 minutes to obtain an aqueous adhesive composit:ion for planting fibers.
This aqueous adhesive composition for planting fibers havirig a solid corrtent: of 52 %, a viscosity of 5, 000 cps/25 0 C
and a pH of 3.5 were coated on a surface treated steel sheet with a reverse ro:Ll coater in a wet state to 60.411t and organic short fibers. of nylon 66 were planted immediately using an electrostatic fiber planting apparatus (of Mesac Co.) at a voltage of 40 kV to for=m an electrostatically fiber planted layer. Also in this Example 2, the same care as in Example 1 must be taken to plant fibers.
The results of a durability test made on the fiber planted steel sheet products obtained in the above Examples 1 and 2 in accordance with JIS-K-5400 (general coating test standard) and a scratch test not specified in JIS and conducted additionally on these products are shown in Table 1.
>1 >1 -0 ~
w " ~ =~
0 N O 1i -i ri Q) b o~ ~7 c ro ro ~n v a~ ~ -1 m r-i r-i m o: 4 ~ R' m O n M 0 0 E ro o O' i>y ~~ G ~
~ ~ o ID4 Ga >1 >1 w ~ =.1 --I
0 O 4 =--I ~
'C7 ~7 rC rd r[S
cn U 0 ~' I ~ '-i -1 ~ n u) s4 s~
I-Ac~ Ui o O 1n Ca 0 0 E rts a 173 U) rd a CD o ID4 IZ4 ro ro Ei ~ a ~ -w U
ol ~-1 = r-i O
O '1~.. O
~ Ln O U LC) t-1 4-1 ro w C) (d `4 0 O 0 -4 o~+ O
U (D U
H 11 3 N U) En Ln a) U) bi ~ Z7 " Q1 =ri 0 o s4 a) a) x a) s4 ul 'r. 41 ~ ~ a U Q) U =~ _ fd U) ~ RS
44 ~ O t~ fd Q O
yJ ~ U 'b ~=-~ 'L~ G". CV (l~ ri E
U) ~
U) Ul 4) ,~ 0) .
A S-I tn rd O rn c~ a) cN 4 y a O
O
~ 0 oo co O~ CO C) co a) ~ O
~ Ln U) dP
~ O o O CD O O O U
~ O CV O w-H O w o O Ln=rl O~ -:r 0 44 E: ~r O1 i~
04 U-) b in r0 Ln u- In rd (D
~ ~ 4-) C) X >
D4 b~ DC Q) r-q :,4 ~; (,a x S 4 A C!~ -~ U} ~ > c!n =~ U:I II uS U UUi 1~-I
.,-A H U ) H N F-i N H H OQ -~
w h ~'D 3 t) =O h ~ 0 4-I Ci O
N 41 ~
U ~v U
r. rl ~ >~
rt3 U ) (0 O
GJ -= 0 S=a U U:! ~ RJ QI
0 q U.'! ~ O ~} tn .~ N\
w 4) fIS C1 7l ,i,' ~I U) C- 4--7 3-i ~ 4-1 S- `d =-1 1-) rti 4) O U~
N rl U) U O 7] Q) ~= ~~ 34 'L3 U
CL =~+ ~. ~ ~) ~ tn; v ,-~
U) G~ ~ ~ ': G~ C: N X
r-1 N O (1) 1J ~S Q.) -i I~-i =1 .~
~{ =r-I F- UI -S. ::1 4-1 U 'L3 N UI J O (1y!~0 \41 O
a4--) b o41 U Cu cn 4'j N r~
A N t U) a, ~.~I Sa =ri m S-a 1J
rd ~ rCl QJ E4 C~ ~I Q O (1) U Q) E-1 w fci J.~ =rl \ Cil \:.; F- 11 U) E
flex resistance: test for the examination of separation of an adhesive fiber planting layer by pressing an electrostatically fiber planted steel sheet against an iron bar having a diameter of 2 mm to bend it.
adhesion/cross-cut test method: test for the examination of separation of the adhesive f iber planting layer of the electrostatically fiber pianted steel sheet by cross cutting the layer and affixing an adhesive tape to the layer.
impact resistance test/Dupont method: test for the examination of separation of the adhesive fiber planting layer by dropping a steel ball having a weight of 500 g and a radius of 1/2 inch from a height of 50 cm onto the electrostatically fiber planted steel sheet.
Erichsen value/breaking length method: test for the examination of separation of the adhesive f iber planting layer by pushing a steel ball. having a diameter of 20 0.005 mm from the back of the el.ectro.statically fiber planted steel sheet.
moisture resistance test/fixed method: test by leaving at a temperature of 40 ~C and a humidity of 95 % for 240 hours.
scratch test/coin. method: test for the examination of separation of the surface by scratching with a 10 yen coin under a load of 500 g.
In the above description, the aqueous adhesive composition for planting fibers used in the electrostatically fiber planted steel sheet of the present invention comprises an aqueous polyurethane resin, aqueous acrylic resin, aqueous coloring pig;:nent paste, thickener, defoamer and pH modifier.
A fiber planted steel sheet can be pi-oduced by forming a coating layer from an aqueous adhesive composition for planting fibers comprising various components and planting short fibers in the layer.
While the preferred embodiments of the present invention have been described, it will be obvious to those skilled in the art that various preferred changes and modifications may be made without departing from the spirit of the invention and should be covered as fall within the scope of the invention.
Claims (5)
1. A process for producing an electrostatically fiber planted steel sheet by a fiber planting operation, comprising:
providing a surface treated steel sheet having a surface to be coated;
directly coating the treated surface of said surface treated steel sheet with an aqueous adhesive composition for planting fibers using a roll coater, a sprayer or applicator, wherein the aqueous adhesive composition for planting fibers comprises an emulsion resin having a glass transition temperature of -40 to 40 °C, 0 to 20 parts by weight of an aqueous coloring pigment dispersion, 0 to 3 parts by weight of a defoamer, 0 to 5 parts by weight of a pH modifier, 0 to 25 parts by weight of a crosslinking agent, 0 to 10 parts by weight of a thickener and 0 to 20 parts by weight of a water-soluble resin, totaling 100 parts by weight, to form a fiber planting layer tightly adhered to the steel sheet on the surface of the steel sheet without a primer containing an anticorrosive pigment; and electrostatically planting fibers into the fiber planting layer while the surface of the fiber planting layer retains adhesion;
wherein, the fiber planting operation is carried out such that the fibers are planted so that roots of said fibers are situated at an intermediate depth position of the fiber planting layer thickness; and a fiber planting voltage is controlled to 10 to 80 kV, and the viscosity of the adhesive composition for planting fibers is adjusted to 200 to 20,000 cps/25 °C
to ensure that the fibers do not extend through the fiber planting layer and do not contact the surface of the surface treated steel sheet.
providing a surface treated steel sheet having a surface to be coated;
directly coating the treated surface of said surface treated steel sheet with an aqueous adhesive composition for planting fibers using a roll coater, a sprayer or applicator, wherein the aqueous adhesive composition for planting fibers comprises an emulsion resin having a glass transition temperature of -40 to 40 °C, 0 to 20 parts by weight of an aqueous coloring pigment dispersion, 0 to 3 parts by weight of a defoamer, 0 to 5 parts by weight of a pH modifier, 0 to 25 parts by weight of a crosslinking agent, 0 to 10 parts by weight of a thickener and 0 to 20 parts by weight of a water-soluble resin, totaling 100 parts by weight, to form a fiber planting layer tightly adhered to the steel sheet on the surface of the steel sheet without a primer containing an anticorrosive pigment; and electrostatically planting fibers into the fiber planting layer while the surface of the fiber planting layer retains adhesion;
wherein, the fiber planting operation is carried out such that the fibers are planted so that roots of said fibers are situated at an intermediate depth position of the fiber planting layer thickness; and a fiber planting voltage is controlled to 10 to 80 kV, and the viscosity of the adhesive composition for planting fibers is adjusted to 200 to 20,000 cps/25 °C
to ensure that the fibers do not extend through the fiber planting layer and do not contact the surface of the surface treated steel sheet.
2. A process for producing an electrostatically fiber planted continuous steel sheet comprising:
unrolling a rolled surface treated steel sheet having a surface to be coated, and straightening out the steel sheet;
directly coating the treated surface of said surface treated steel sheet with an aqueous adhesive composition for planting fibers using a roll coater, a sprayer or applicator, wherein the aqueous adhesive composition for planting fibers comprises an emulsion resin having a glass transition temperature of -40 to 40 °C, 0 to 20 parts by weight of an aqueous coloring pigment dispersion, 0 to 3 parts by weight of a defoamer, 0 to 5 parts by weight of a pH modifier, 0 to 25 parts by weight of a crosslinking agent, 0 to 10 parts by weight of a thickener and 0 to 20 parts by weight of a water-soluble resin, totaling 100 parts by weight, to form a fiber planting layer tightly adhered to the steel sheet on the surface of the steel sheet without a primer containing an anticorrosive pigment; and electrostatically planting fibers into the fiber planting layer while the surface of the fiber planting layer retains adhesion;
winding up the extending steel sheet after the fibers have been electrostatically planted continuously on the surface of the steel sheet;
wherein the fiber planting operation is carried out such that the fibers are planted so that roots of said fibers are situated at an intermediate depth position of the fiber planting layer thickness; and a fiber planting voltage is controlled to 10 to 80 kV, and the viscosity of the adhesive composition for planting fibers is adjusted to 200 to 20,000 cps/25 °C
to ensure that the fibers do not extend through the fiber planting layer and do not contact the surface of the surface treated steel sheet.
unrolling a rolled surface treated steel sheet having a surface to be coated, and straightening out the steel sheet;
directly coating the treated surface of said surface treated steel sheet with an aqueous adhesive composition for planting fibers using a roll coater, a sprayer or applicator, wherein the aqueous adhesive composition for planting fibers comprises an emulsion resin having a glass transition temperature of -40 to 40 °C, 0 to 20 parts by weight of an aqueous coloring pigment dispersion, 0 to 3 parts by weight of a defoamer, 0 to 5 parts by weight of a pH modifier, 0 to 25 parts by weight of a crosslinking agent, 0 to 10 parts by weight of a thickener and 0 to 20 parts by weight of a water-soluble resin, totaling 100 parts by weight, to form a fiber planting layer tightly adhered to the steel sheet on the surface of the steel sheet without a primer containing an anticorrosive pigment; and electrostatically planting fibers into the fiber planting layer while the surface of the fiber planting layer retains adhesion;
winding up the extending steel sheet after the fibers have been electrostatically planted continuously on the surface of the steel sheet;
wherein the fiber planting operation is carried out such that the fibers are planted so that roots of said fibers are situated at an intermediate depth position of the fiber planting layer thickness; and a fiber planting voltage is controlled to 10 to 80 kV, and the viscosity of the adhesive composition for planting fibers is adjusted to 200 to 20,000 cps/25 °C
to ensure that the fibers do not extend through the fiber planting layer and do not contact the surface of the surface treated steel sheet.
3. A process for producing an electrostatically fiber planted continuous steel sheet comprising:
(a) unrolling a rolled surface treated steel sheet having a surface to be coated, and straightening it out;
(b) directly coating the treated surface of said steel sheet with an aqueous adhesive composition for planting fibers using a roll coater, sprayer or applicator, wherein the aqueous adhesive composition for planting fibers includes an emulsion resin having a glass transition temperature of -40 to 40 °C, an aqueous coloring pigment dispersion, and optionally, each of a defoamer, a pH modifier, and a crosslinking agent, to form a fiber planting layer tightly adhered to the steel sheet on the surface of the steel sheet without a primer or anticorrosive pigment;
(c) electrostatically planting fibers into the fiber planting layer while the surface of the fiber planting layer retains adhesion;
(d) winding up the extending steel sheet after the fibers have been electrostatically planted continuously on the surface of the steel sheet;
(e) wherein the fiber planting operation is carried out such that the fibers are planted so that the roots of the said fibers are situated at an intermediate depth position of the fiber planting layer thickness; and (f) a fiber planting voltage is controlled to 10 to 80 kV, and the viscosity of the adhesive composition for planting fibers is adjusted to 200 to 20,000 cps/°C to ensure that the fibers do not extend through the fiber planting layer and do not contact the surface of the surface treated steel sheet.
(a) unrolling a rolled surface treated steel sheet having a surface to be coated, and straightening it out;
(b) directly coating the treated surface of said steel sheet with an aqueous adhesive composition for planting fibers using a roll coater, sprayer or applicator, wherein the aqueous adhesive composition for planting fibers includes an emulsion resin having a glass transition temperature of -40 to 40 °C, an aqueous coloring pigment dispersion, and optionally, each of a defoamer, a pH modifier, and a crosslinking agent, to form a fiber planting layer tightly adhered to the steel sheet on the surface of the steel sheet without a primer or anticorrosive pigment;
(c) electrostatically planting fibers into the fiber planting layer while the surface of the fiber planting layer retains adhesion;
(d) winding up the extending steel sheet after the fibers have been electrostatically planted continuously on the surface of the steel sheet;
(e) wherein the fiber planting operation is carried out such that the fibers are planted so that the roots of the said fibers are situated at an intermediate depth position of the fiber planting layer thickness; and (f) a fiber planting voltage is controlled to 10 to 80 kV, and the viscosity of the adhesive composition for planting fibers is adjusted to 200 to 20,000 cps/°C to ensure that the fibers do not extend through the fiber planting layer and do not contact the surface of the surface treated steel sheet.
4. The process for producing an electrostatically fiber planted continuous steel sheet of claim 3, wherein the aqueous adhesive composition for planting fibers comprises the emulsion resin having a glass transition temperature of -40 to 40 °C, 0 to 20 parts by weight of an aqueous coloring pigment dispersion, 0 to 3 parts by weight of a defoamer, 0 to 5 parts by weight of a pH
modifier, 0 to 10 parts by weight of a thickener, and 0 to 20 parts by weight of a water-soluble resin, totaling 100 parts by weight.
modifier, 0 to 10 parts by weight of a thickener, and 0 to 20 parts by weight of a water-soluble resin, totaling 100 parts by weight.
5. The process for producing an electrostatically fiber planted continuous steel sheet of claim 3, wherein the aqueous adhesive composition for planting fibers comprises the emulsion resin having a glass transition temperature of -40 to 40 °C, up to 20 parts by weight of an aqueous coloring pigment dispersion, up to 3 parts by weight of a defoamer, up to 5 parts by weight of a pH modifier, up to 25 parts by weight of a thickener, and up to 20 parts by weight of a water-soluble resin, totaling 100 parts by weight.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11-226889 | 1999-08-10 | ||
| JP22688999A JP3377765B2 (en) | 1999-08-10 | 1999-08-10 | Electrostatic flocking steel plate and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2315543A1 CA2315543A1 (en) | 2001-02-10 |
| CA2315543C true CA2315543C (en) | 2009-10-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002315543A Expired - Fee Related CA2315543C (en) | 1999-08-10 | 2000-08-08 | Electrostatically fiber planted steel sheet and production process therefor |
Country Status (10)
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|---|---|
| US (1) | US7211298B2 (en) |
| JP (1) | JP3377765B2 (en) |
| KR (1) | KR100671938B1 (en) |
| CA (1) | CA2315543C (en) |
| DE (1) | DE10038677A1 (en) |
| FR (1) | FR2797414B1 (en) |
| GB (1) | GB2354190B (en) |
| IT (1) | IT1318740B1 (en) |
| SG (1) | SG91881A1 (en) |
| TW (1) | TWI263594B (en) |
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| JP4819722B2 (en) * | 2006-05-30 | 2011-11-24 | 東洋鋼鈑株式会社 | Flocked metal plate, method for manufacturing flocked metal plate, roofing material and duct for air conditioning equipment |
| CN101378899B (en) * | 2006-05-30 | 2012-07-04 | 东洋钢钣株式会社 | Flocked metal plate, method of producing flocked metal plate and roofing material and duct for air-conditioning system |
| CN100388985C (en) * | 2006-06-09 | 2008-05-21 | 东莞贰发毛绒有限公司 | Process for preparing flocking face fabric |
| CN100388984C (en) * | 2006-06-09 | 2008-05-21 | 东莞贰发毛绒有限公司 | Method for preparing flocking face fabric |
| TR200606867A2 (en) * | 2006-12-04 | 2007-04-24 | Ateş Diş Ti̇caret Ve Sanayi̇ Li̇mi̇ted Şi̇rketi̇ | Door flock printing / coating method and the resulting flocked door sill and casing. |
| KR100829003B1 (en) | 2007-10-02 | 2008-05-14 | 황영미 | Flocking method of fiber about glass's surface or ceramic's surface |
| JP2009236293A (en) * | 2008-03-28 | 2009-10-15 | Akebono Brake Ind Co Ltd | Frictional material and electromagnetic clutch |
| JP2011255669A (en) * | 2010-05-10 | 2011-12-22 | Jfe Galvanizing & Coating Co Ltd | Fiber coat steel sheet |
| CN105546004A (en) * | 2016-01-14 | 2016-05-04 | 广州奥图弹簧有限公司 | Flocking spring manufacturing method |
| CN108402529B (en) * | 2018-01-15 | 2020-05-12 | 宏杰内衣股份有限公司 | Short fiber flocking pants |
| CN114857197A (en) * | 2022-04-15 | 2022-08-05 | 扬州市宝海机械有限公司 | Automobile front suspension assembly with spring rust-proof structure |
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| US3529986A (en) * | 1966-04-18 | 1970-09-22 | Nat Distillers Chem Corp | Method for applying flock to a resin coated substrate |
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| US3591403A (en) * | 1968-12-05 | 1971-07-06 | Bigelow Sanford Inc | Electrostatic flocking |
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| US4218501A (en) * | 1979-02-14 | 1980-08-19 | Taiyo Steel Co., Ltd. | Electrostatic flock-coated metal sheet with excellent corrosion resistance and fabricability |
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| US4734307A (en) * | 1984-12-14 | 1988-03-29 | Phillips Petroleum Company | Compositions with adhesion promotor and method for production of flocked articles |
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-
1999
- 1999-08-10 JP JP22688999A patent/JP3377765B2/en not_active Expired - Lifetime
-
2000
- 2000-08-08 IT IT2000MI001850A patent/IT1318740B1/en active
- 2000-08-08 DE DE10038677A patent/DE10038677A1/en not_active Ceased
- 2000-08-08 CA CA002315543A patent/CA2315543C/en not_active Expired - Fee Related
- 2000-08-08 SG SG200004423A patent/SG91881A1/en unknown
- 2000-08-09 KR KR1020000046185A patent/KR100671938B1/en not_active IP Right Cessation
- 2000-08-10 GB GB0019723A patent/GB2354190B/en not_active Expired - Fee Related
- 2000-08-10 FR FR0010533A patent/FR2797414B1/en not_active Expired - Fee Related
- 2000-08-10 TW TW089116089A patent/TWI263594B/en active
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2003
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| US7211298B2 (en) | 2007-05-01 |
| SG91881A1 (en) | 2002-10-15 |
| GB2354190B (en) | 2004-02-18 |
| ITMI20001850A1 (en) | 2002-02-08 |
| US20030205073A1 (en) | 2003-11-06 |
| GB0019723D0 (en) | 2000-09-27 |
| KR20010021254A (en) | 2001-03-15 |
| JP2001047558A (en) | 2001-02-20 |
| FR2797414A1 (en) | 2001-02-16 |
| TWI263594B (en) | 2006-10-11 |
| JP3377765B2 (en) | 2003-02-17 |
| FR2797414B1 (en) | 2005-01-14 |
| KR100671938B1 (en) | 2007-01-19 |
| DE10038677A1 (en) | 2001-04-05 |
| GB2354190A (en) | 2001-03-21 |
| ITMI20001850A0 (en) | 2000-08-08 |
| CA2315543A1 (en) | 2001-02-10 |
| IT1318740B1 (en) | 2003-09-10 |
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