CA2291214A1 - Coating compositions containing alkoxysilanes - Google Patents

Coating compositions containing alkoxysilanes Download PDF

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Publication number
CA2291214A1
CA2291214A1 CA002291214A CA2291214A CA2291214A1 CA 2291214 A1 CA2291214 A1 CA 2291214A1 CA 002291214 A CA002291214 A CA 002291214A CA 2291214 A CA2291214 A CA 2291214A CA 2291214 A1 CA2291214 A1 CA 2291214A1
Authority
CA
Canada
Prior art keywords
weight
coating compositions
compositions containing
polyisocyanate
ch2ch2ch2
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002291214A
Other languages
French (fr)
Other versions
CA2291214C (en
Inventor
Stefan Groth
Reinhard Halpaap
Markus Mechtel
Lutz Schmalstieg
Philip E. Yeske
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of CA2291214A1 publication Critical patent/CA2291214A1/en
Application granted granted Critical
Publication of CA2291214C publication Critical patent/CA2291214C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/79Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805Compounds having only one group containing active hydrogen
    • C08G18/2815Monohydroxy compounds
    • C08G18/282Alkanols, cycloalkanols or arylalkanols including terpenealcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805Compounds having only one group containing active hydrogen
    • C08G18/288Compounds containing at least one heteroatom other than oxygen or nitrogen
    • C08G18/289Compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/758Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31652Of asbestos
    • Y10T428/31663As siloxane, silicone or silane

Abstract

The present invention relates to coating compositions containing 40 to 100% by weight, based on resin solids, of an alkoxysilyl-functional polyisocyanate polyurea which is reaction product of A) a polyisocyanate component having an average functionality of 2.5 to 5.5, an NCO content of 11.0 to 20.0% by weight and a monomeric diisocyanate content of less than 10% by weight, and containing at least 50% by weight of a polyisocyanate prepared from 4,4'-diisocyanatodicyclohexyl-methane with B) at least 0.7 equivalents, based on the equivalents of isocyanate groups, of an aminosilane corresponding to formula (I) (RO) n Y(3-n)Si-CH2CH2CH2-NHZ ~(I), wherein R represents methyl or ethyl, Y represents methyl, Z represents H, a C1-C12alkyl or CH2CH2CH2-Si(OR) n Y3-n, and n is 1, 2 or 3, and C) optionally other isocyanate-reactive compounds. The present invention also relates the hydrolyzates/condensates that are prepared by adding water or an aqueous solution of a catalyst to the coating compositions according to the invention.
CA002291214A 1998-12-04 1999-11-29 Coating compositions containing alkoxysilanes Expired - Fee Related CA2291214C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19855999A DE19855999A1 (en) 1998-12-04 1998-12-04 Lacquer preparation containing alkoxysilane
DE19855999.2 1998-12-04

Publications (2)

Publication Number Publication Date
CA2291214A1 true CA2291214A1 (en) 2000-06-04
CA2291214C CA2291214C (en) 2007-10-23

Family

ID=7889983

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002291214A Expired - Fee Related CA2291214C (en) 1998-12-04 1999-11-29 Coating compositions containing alkoxysilanes

Country Status (7)

Country Link
US (1) US6281322B1 (en)
EP (1) EP1006132B1 (en)
JP (1) JP4602499B2 (en)
AT (1) ATE283876T1 (en)
CA (1) CA2291214C (en)
DE (2) DE19855999A1 (en)
ES (1) ES2234200T3 (en)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6541088B1 (en) * 2000-03-03 2003-04-01 Eg Technology Partners, L.P. Alkylenimine/organic barrier coatings having bis-silane additives
US6498210B1 (en) * 2000-07-13 2002-12-24 Adco Products, Inc. Silylated polyurethanes for adhesives and sealants with improved mechanical properties
DE10048615A1 (en) * 2000-09-30 2002-04-11 Degussa Non-aqueous heat-hardening two-component coatings with a good environmental resistance/mechanical properties balance have polyisocyanate crosslinkers reacted with N-alkyl- or N-aryl-3-aminopropyltrialkoxysilanes
DE10053545A1 (en) * 2000-10-27 2002-05-08 Henkel Kgaa Polymers with urea groups and silyl groups, their production and use
DE10060327A1 (en) * 2000-12-04 2002-06-06 Degussa Crosslinker and thermosetting lacquers
DE10162642A1 (en) * 2001-12-20 2003-07-10 Henkel Kgaa Adhesion promoter for reactive polyurethanes
US6896963B2 (en) * 2001-12-21 2005-05-24 Owens Corning Composites Sprl System for preparing glass fiber pellets having low discoloration
JP3838953B2 (en) * 2002-08-26 2006-10-25 横浜ゴム株式会社 Primer composition
EP1502927A1 (en) * 2003-07-31 2005-02-02 Sika Technology AG Isocyanate free primer composition for glass and glass-ceramics
US7482420B2 (en) 2004-03-24 2009-01-27 Construction Research & Technology Gmbh Silane-terminated polyurethanes with high strength and high elongation
US20060210807A1 (en) * 2005-03-11 2006-09-21 Microphase Coatings, Inc. Antifouling coating composition
US7674864B2 (en) * 2005-12-23 2010-03-09 Boston Scientific Scimed, Inc. Polymeric hybrid precursors, polymeric hybrid precursor composite matrices, medical devices, and methods
US7470466B2 (en) * 2005-12-23 2008-12-30 Boston Scientific Scimed, Inc. Nanoparticle structures and composite materials comprising a silicon-containing compound having a chemical linker that forms a non-covalent bond with a polymer
US8455088B2 (en) 2005-12-23 2013-06-04 Boston Scientific Scimed, Inc. Spun nanofiber, medical devices, and methods
US8378037B2 (en) * 2007-12-26 2013-02-19 Momentive Performance Materials Inc. Moisture-curable silylated polyurea and adhesive, sealant and coating compositions containing same
CN102105552A (en) * 2008-07-28 2011-06-22 旭硝子株式会社 Adhesive material, pressure-sensitive adhesive sheet, and use thereof
ES2340756B1 (en) * 2010-01-18 2011-07-21 Antonio Oliva Gurgui COMPOSITE FOR THE MANUFACTURE OF A WATER-BASED BRAND IN A TEXTILE LAMINAR MATERIAL AND CORRESPONDING COMPOSITION, MATERIAL, PROCEDURE AND USE.
US8133964B2 (en) * 2010-06-29 2012-03-13 Science Applications International Corporation Single-component coating having alkoxysilane-terminated N-substituted urea resins
WO2012168079A1 (en) * 2011-06-09 2012-12-13 Basf Coatings Gmbh Coating agent compositions, coatings made therefrom and exhibiting high scratch resistance and good polishability, and use thereof
US9371469B2 (en) * 2011-06-09 2016-06-21 Basf Coatings Gmbh Coating agent compositions, coatings made therefrom and exhibiting high scratch resistance and good polishability, and use thereof
AU2014242111B2 (en) * 2013-03-14 2017-03-23 The Government Of The United States Of America, As Represented By The Secretary Of The Navy Single-component moisture-curable coatings based on N-substituted urea polymers with extended chains and terminal alkoxysilanes
JP6418086B2 (en) * 2015-07-06 2018-11-07 信越化学工業株式会社 Powder coating composition and coated product thereof
KR20180036827A (en) * 2016-09-30 2018-04-10 석승국 Method of coating a surface of a building interior or exterior using a coating composition containing non-yellowing polyaspartic urea
EP3589695A4 (en) 2017-03-03 2021-01-20 The Government of the United States of America, as represented by the Secretary of the Navy Moisture-curable omniphobic coatings
CN113354024A (en) * 2021-06-08 2021-09-07 江西省核工业地质局机械研究所 Method for preparing nickel nitrate by using electroplating wastewater

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1015488A (en) * 1972-02-17 1977-08-09 Seiji Nagahisa Polyurethane composition
DE2243628A1 (en) * 1972-09-06 1974-03-14 Bayer Ag POLYMERS WITH ALCOXYSILYL-SUBSTITUTED BIURET GROUPS AND PROCESS FOR THEIR PRODUCTION
US3856156A (en) 1973-08-06 1974-12-24 Midland Ross Corp Railway car coupler
US4031120A (en) * 1974-09-17 1977-06-21 Lord Corporation Isocyanatosilane adducts
US3979344A (en) 1974-11-19 1976-09-07 Inmont Corporation Vulcanizable silicon terminated polyurethane polymer composition having improved cure speed
JPS5540722A (en) * 1978-09-19 1980-03-22 Nippon Polyurethan Kogyo Kk Primer composition
DE3220866A1 (en) 1982-06-03 1983-12-08 Dynamit Nobel Ag, 5210 Troisdorf CROSSLINKABLE RESIN MIXTURES
US4628076A (en) * 1984-12-17 1986-12-09 Ppg Industries, Inc. Curable coating vehicle based upon aminoalkyloxy silanes and organic isocyanates
US4625012A (en) * 1985-08-26 1986-11-25 Essex Specialty Products, Inc. Moisture curable polyurethane polymers
US4640868A (en) * 1986-02-10 1987-02-03 Morton Thiokol Inc. Clear, weather resistant adherent coating
JP2772002B2 (en) * 1988-11-28 1998-07-02 サンスター技研株式会社 Primer composition
FI920502A (en) * 1991-02-08 1992-08-09 Sherwin Williams Co FOERTJOCKNINGSMEDEL FOER BELAEGGNINGAR.
FR2681072B1 (en) 1991-09-10 1994-02-11 Claude Meynier PROTECTIVE VARNISH WITH EXTERNAL NON-STICK SURFACE.
EP0576166A2 (en) 1992-06-08 1993-12-29 General Electric Company Heat curable silicone hardcoat compositions
DE4234325A1 (en) 1992-10-12 1994-04-14 Basf Magnetics Gmbh Magnetic recording media
US5423735A (en) * 1993-04-16 1995-06-13 Minnesota Mining And Manufacturing Company Orthopedic cast composed of an alkoxysilane terminated resin
DE4413562A1 (en) * 1994-04-19 1995-10-26 Herberts Gmbh Aqueous dispersion of polyurethanes containing siloxane bridges, their production and use in coating compositions
IT1273685B (en) 1994-07-26 1997-07-09 Ausimont Spa PROCEDURE FOR THE PROTECTION OF STONE OR COATING SURFACES
US5700868A (en) 1995-07-25 1997-12-23 Dainichiseika Color & Chemicals Mfg. Co., Ltd. Back-side coating formulations for heat-sensitive recording materials and heat-sensitive recording materials having a back layer coated therewith
US5750269A (en) 1995-12-28 1998-05-12 Eastman Chemical Company Removable coating composition and process for protecting surfaces
FR2747325A1 (en) 1996-04-15 1997-10-17 Bigotte Claude Treatment of exposed rigid surfaces to prevent graffiti
DE19619538A1 (en) * 1996-05-15 1997-11-20 Bayer Ag Polyurethane prepolymers containing alkoxysilane and hydantoin groups, a process for their preparation and their use for the production of sealants
US5852137A (en) * 1997-01-29 1998-12-22 Essex Specialty Products Polyurethane sealant compositions
DE19715427A1 (en) * 1997-04-14 1998-10-15 Bayer Ag Aqueous 2-component binders and their use
JPH10114813A (en) * 1997-09-01 1998-05-06 Mitsui Chem Inc One-pack type urethane resin composition
US5919860A (en) * 1997-12-17 1999-07-06 Bayer Corporation Aqueous polyurethane/urea dispersions containing alkoxysilane groups
US5952445A (en) * 1998-04-09 1999-09-14 Bayer Corporation Water dispersible compounds containing alkoxysilane groups
US5945476A (en) * 1998-04-09 1999-08-31 Bayer Corporation Aqueous two-component coating composition
US6057415A (en) * 1998-04-09 2000-05-02 Bayer Corporation Water dispersible polyisocyanates containing alkoxysilane groups
DE19846099C2 (en) * 1998-10-07 2000-08-24 Bayer Ag Amine functional urea alkoxy silanes, a process for their preparation and their use
US6096823A (en) * 1998-10-14 2000-08-01 Bayer Corporation Moisture-curable compounds containing isocyanate and alkoxysilane groups

Also Published As

Publication number Publication date
EP1006132A1 (en) 2000-06-07
US6281322B1 (en) 2001-08-28
DE19855999A1 (en) 2000-06-15
ES2234200T3 (en) 2005-06-16
JP2000169790A (en) 2000-06-20
JP4602499B2 (en) 2010-12-22
CA2291214C (en) 2007-10-23
EP1006132B1 (en) 2004-12-01
ATE283876T1 (en) 2004-12-15
DE59911188D1 (en) 2005-01-05

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Effective date: 20121129