CA2285964A1 - Living olefin polymerization processes - Google Patents
Living olefin polymerization processes Download PDFInfo
- Publication number
- CA2285964A1 CA2285964A1 CA002285964A CA2285964A CA2285964A1 CA 2285964 A1 CA2285964 A1 CA 2285964A1 CA 002285964 A CA002285964 A CA 002285964A CA 2285964 A CA2285964 A CA 2285964A CA 2285964 A1 CA2285964 A1 CA 2285964A1
- Authority
- CA
- Canada
- Prior art keywords
- processes
- group
- ligand
- atoms
- initiators
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 abstract 4
- 229920001400 block copolymer Polymers 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 238000010550 living polymerization reaction Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/28—Titanium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
- C07C217/02—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C217/04—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
- C07C217/06—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted
- C07C217/08—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted the oxygen atom of the etherified hydroxy group being further bound to an acyclic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
- C07C217/78—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
- C07C217/80—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings
- C07C217/82—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring
- C07C217/90—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring the oxygen atom of at least one of the etherified hydroxy groups being further bound to a carbon atom of a six-membered aromatic ring, e.g. amino-diphenylethers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity
Abstract
Processes for the living polymerization of olefin monomers with terminal carbon-carbon double bonds are disclosed. The processes employ initiators that include a metal atom and a ligand having two group 15 atoms and a group 16 atom or three group 15 atoms.
The ligand is bonded to the metal atom through two anionic or covalent bonds and a dative bond. The initiators are particularly stable under reaction conditions in the absence of olefin monomer. The processes provide polymers having low polydispersities, especially block copolymers having low polydispersities. It is an additional advantage of these processes that, during block copolymer synthesis, a relatively small amount of homopolymer is formed.
The ligand is bonded to the metal atom through two anionic or covalent bonds and a dative bond. The initiators are particularly stable under reaction conditions in the absence of olefin monomer. The processes provide polymers having low polydispersities, especially block copolymers having low polydispersities. It is an additional advantage of these processes that, during block copolymer synthesis, a relatively small amount of homopolymer is formed.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2610433A CA2610433C (en) | 1997-04-11 | 1998-04-09 | Living olefin polymerization processes |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/843,161 | 1997-04-11 | ||
US08/843,161 US5889128A (en) | 1997-04-11 | 1997-04-11 | Living olefin polymerization processes |
PCT/US1998/007466 WO1998046651A2 (en) | 1997-04-11 | 1998-04-09 | Living olefin polymerization processes |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2610433A Division CA2610433C (en) | 1997-04-11 | 1998-04-09 | Living olefin polymerization processes |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2285964A1 true CA2285964A1 (en) | 1998-10-22 |
CA2285964C CA2285964C (en) | 2008-02-12 |
Family
ID=25289222
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002285964A Expired - Lifetime CA2285964C (en) | 1997-04-11 | 1998-04-09 | Living olefin polymerization processes |
Country Status (7)
Country | Link |
---|---|
US (5) | US5889128A (en) |
EP (1) | EP0975579B1 (en) |
JP (1) | JP2001520696A (en) |
AU (1) | AU6970998A (en) |
CA (1) | CA2285964C (en) |
DE (1) | DE69810605T2 (en) |
WO (1) | WO1998046651A2 (en) |
Families Citing this family (116)
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US6271315B1 (en) | 1999-06-17 | 2001-08-07 | Wisconsin Alumni Research Foundation | Methods for making multivalent arrays |
US6333423B1 (en) * | 1999-09-10 | 2001-12-25 | Ramot University Authority For Applied Research And Industrial Development Ltd. | Ultra-high activity non-metallocene pre-catalyst and method for catalytic polymerization of alpha-olefin monomers |
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US6265505B1 (en) * | 1999-11-18 | 2001-07-24 | Univation Technologies, Llc | Catalyst system and its use in a polymerization process |
US6300439B1 (en) * | 1999-11-08 | 2001-10-09 | Univation Technologies, Llc | Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process |
US6417304B1 (en) | 1999-11-18 | 2002-07-09 | Univation Technologies, Llc | Method of polymerization and polymer produced therefrom |
US6274684B1 (en) * | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
US6624107B2 (en) | 1999-10-22 | 2003-09-23 | Univation Technologies, Llc | Transition metal catalyst compounds having deuterium substituted ligand and catalyst systems thereof |
US6271323B1 (en) * | 1999-10-28 | 2001-08-07 | Univation Technologies, Llc | Mixed catalyst compounds, catalyst systems and their use in a polymerization process |
US6281306B1 (en) | 1999-12-16 | 2001-08-28 | Univation Technologies, Llc | Method of polymerization |
CA2403669A1 (en) * | 2000-03-21 | 2001-09-27 | Wisconsin Alumni Research Foundation | Methods and reagents for regulation of cellular responses in biological systems |
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US6686490B1 (en) * | 2000-11-06 | 2004-02-03 | Ramot University Authority For Applied Research & Industrial Development Ltd. | Active non-metallocene pre-catalyst and method for tactic catalytic polymerization of alpha-olefin monomers |
JP2002206007A (en) * | 2000-11-08 | 2002-07-26 | National Institute Of Advanced Industrial & Technology | Method for manufacturing olefinic block copolymer |
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1997
- 1997-04-11 US US08/843,161 patent/US5889128A/en not_active Expired - Lifetime
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1998
- 1998-04-09 WO PCT/US1998/007466 patent/WO1998046651A2/en active IP Right Grant
- 1998-04-09 CA CA002285964A patent/CA2285964C/en not_active Expired - Lifetime
- 1998-04-09 AU AU69709/98A patent/AU6970998A/en not_active Abandoned
- 1998-04-09 JP JP54419898A patent/JP2001520696A/en not_active Ceased
- 1998-04-09 DE DE69810605T patent/DE69810605T2/en not_active Expired - Lifetime
- 1998-04-09 EP EP98915559A patent/EP0975579B1/en not_active Expired - Lifetime
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1999
- 1999-03-04 US US09/307,241 patent/US6316555B1/en not_active Expired - Lifetime
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2001
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2003
- 2003-08-22 US US10/646,355 patent/US20040138324A1/en not_active Abandoned
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2004
- 2004-12-03 US US11/004,038 patent/US7135544B2/en not_active Expired - Fee Related
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EP0975579B1 (en) | 2003-01-08 |
US7135544B2 (en) | 2006-11-14 |
CA2285964C (en) | 2008-02-12 |
WO1998046651A3 (en) | 1999-03-25 |
WO1998046651A2 (en) | 1998-10-22 |
US20050187345A1 (en) | 2005-08-25 |
DE69810605T2 (en) | 2003-05-08 |
US20040138324A1 (en) | 2004-07-15 |
DE69810605D1 (en) | 2003-02-13 |
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