CA2278656A1 - Improved emulsion polymerization process utilizing ethylenically unsaturated amine salts of sulfonic, phosphoric and carboxylic acids - Google Patents

Improved emulsion polymerization process utilizing ethylenically unsaturated amine salts of sulfonic, phosphoric and carboxylic acids Download PDF

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Publication number
CA2278656A1
CA2278656A1 CA002278656A CA2278656A CA2278656A1 CA 2278656 A1 CA2278656 A1 CA 2278656A1 CA 002278656 A CA002278656 A CA 002278656A CA 2278656 A CA2278656 A CA 2278656A CA 2278656 A1 CA2278656 A1 CA 2278656A1
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CA
Canada
Prior art keywords
sulfonic
phosphoric
carboxylic acids
ethylenically unsaturated
emulsion polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002278656A
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French (fr)
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CA2278656C (en
Inventor
Alfred K. Schultz
Adnan Siddiqui
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stepan Co
Original Assignee
Stepan Company
Alfred K. Schultz
Adnan Siddiqui
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Filing date
Publication date
Application filed by Stepan Company, Alfred K. Schultz, Adnan Siddiqui filed Critical Stepan Company
Publication of CA2278656A1 publication Critical patent/CA2278656A1/en
Application granted granted Critical
Publication of CA2278656C publication Critical patent/CA2278656C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • C08F2/24Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/28Emulsion polymerisation with the aid of emulsifying agents cationic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen

Abstract

An improved method of making polymers is provided, wherein the method utilizes at least one ethylenically unsatured monomer and at least one polymerizable surface active agent. The polymerizable surface active agent is capable of co-polymerization with traditional monomers and is preferably substantially completely consumed during the course of the polymerization. Polymers produced by the method of the present invention are well suited for use in coatings, adhesives, sealants, elastomers.
CA002278656A 1997-01-28 1998-01-28 Improved emulsion polymerization process utilizing ethylenically unsaturated amine salts of sulfonic, phosphoric and carboxylic acids Expired - Fee Related CA2278656C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US3650597P 1997-01-28 1997-01-28
US60/036,505 1997-01-28
PCT/US1998/001492 WO1998032773A1 (en) 1997-01-28 1998-01-28 Improved emulsion polymerization process utilizing ethylenically unsaturated amine salts of sulfonic, phosphoric and carboxylic acids

Publications (2)

Publication Number Publication Date
CA2278656A1 true CA2278656A1 (en) 1998-07-30
CA2278656C CA2278656C (en) 2009-09-08

Family

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CA002278656A Expired - Fee Related CA2278656C (en) 1997-01-28 1998-01-28 Improved emulsion polymerization process utilizing ethylenically unsaturated amine salts of sulfonic, phosphoric and carboxylic acids

Country Status (10)

Country Link
US (1) US6900265B2 (en)
EP (1) EP0960134B1 (en)
JP (1) JP2001509195A (en)
AT (1) ATE258561T1 (en)
AU (1) AU748620B2 (en)
BR (1) BR9807294A (en)
CA (1) CA2278656C (en)
DE (1) DE69821337T2 (en)
IL (1) IL131106A0 (en)
WO (1) WO1998032773A1 (en)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7423167B2 (en) * 1997-01-28 2008-09-09 Stepan Company Ethylenically unsaturated amine salts of sulfonic, phosphoric and carboxylic acids
US5969032A (en) * 1998-03-09 1999-10-19 National Starch And Chemical Investment Holding Corporation Latex binders for coatings incorporating a polymerizable surfactant having a terminal allyl amine moiety
US5928783A (en) * 1998-03-09 1999-07-27 National Starch And Chemical Investment Holding Corporation Pressure sensitive adhesive compositions
EP1100325A1 (en) * 1998-07-28 2001-05-23 Stepan Company Polymer latexes prepared from ethylenically unsaturated amine salts
AU756846B2 (en) * 1998-12-11 2003-01-23 Biocompatibles Uk Limited Crosslinked polymers and refractive devices formed therefrom
US6956082B1 (en) 1999-12-14 2005-10-18 Rohm And Haas Company Inkjet ink composition
US6541590B1 (en) * 1999-12-14 2003-04-01 Rohm And Haas Company Polymeric binders from copolymers of unsaturated carboxylic acids and surfactant monomers
GB2376020B (en) * 2000-04-01 2004-09-29 Qinetiq Ltd Polymers
US20020134012A1 (en) 2001-03-21 2002-09-26 Monsanto Technology, L.L.C. Method of controlling the release of agricultural active ingredients from treated plant seeds
DE10133545A1 (en) * 2001-07-11 2003-02-06 Ge Bayer Silicones Gmbh & Co Mold-resistant sealant formulations containing benzothiophene-2-cyclohexylcarboxamide-S, S-dioxide
US20040142084A1 (en) * 2003-01-21 2004-07-22 Knueven Carl J. Alkali metal bisulfates to mask aftertaste of artificial sweeteners
WO2006092736A2 (en) * 2005-03-02 2006-09-08 Mondi Packaging South Africa (Proprietary) Limited Preparation of polymer latexes
US8372912B2 (en) * 2005-08-12 2013-02-12 Eastman Chemical Company Polyvinyl chloride compositions
US8067402B2 (en) * 2005-12-12 2011-11-29 Allaccem, Inc. Methods and systems for coating an oral surface
JPWO2007145242A1 (en) * 2006-06-13 2009-11-05 国立大学法人 熊本大学 Method for producing particle aggregate
US7988806B2 (en) * 2006-07-26 2011-08-02 Hung-Chih Wu Method for manufacturing a rubber magnet with a colored facial gum material layer and a rubber magnet thereof
ES2391866T3 (en) * 2006-08-30 2012-11-30 Eastman Chemical Company Terephthalates as plasticizers in polymeric vinyl acetate compositions
EP2057243B1 (en) 2006-08-30 2013-01-23 Eastman Chemical Company Sealant compositions having a novel plasticizer
US20080166384A1 (en) * 2007-01-05 2008-07-10 Darren Jones Stethoscope head cover and associated method
DK2125026T3 (en) 2007-02-21 2014-12-08 Allaccem Inc FORMATIONS BASED ON bridged POLYCYCLIC COMPOUNDS FOR INHIBITION AND RELIEF OF DISEASES
US8153618B2 (en) * 2007-08-10 2012-04-10 Allaccem, Inc. Bridged polycyclic compound based compositions for topical applications for pets
US8188068B2 (en) * 2007-08-10 2012-05-29 Allaccem, Inc. Bridged polycyclic compound based compositions for coating oral surfaces in pets
US8153617B2 (en) * 2007-08-10 2012-04-10 Allaccem, Inc. Bridged polycyclic compound based compositions for coating oral surfaces in humans
US20090047514A1 (en) * 2007-08-15 2009-02-19 Allen David P Thermal Activated Pressure Sensitive Adhesive and Method for Producing the Same and Product therewith
US20090074833A1 (en) * 2007-08-17 2009-03-19 Whiteford Jeffery A Bridged polycyclic compound based compositions for controlling bone resorption
ITMI20080162A1 (en) * 2008-02-04 2009-08-05 Mugue S A S Di Villanova Maria ADHESIVE COMPOSITIONS ABLE TO COMPLETELY REMOVE ACARES, BACTERIA, TARMAS, TICKS, FLEASES, FABRICS, AND ANIMAL HAIR
JP2009269960A (en) * 2008-05-01 2009-11-19 Tokyo Institute Of Technology Polymer having salt structure and method for producing the same
US20100004218A1 (en) * 2008-06-20 2010-01-07 Whiteford Jeffery A Bridged polycyclic compound based compositions for renal therapy
US20100016270A1 (en) * 2008-06-20 2010-01-21 Whiteford Jeffery A Bridged polycyclic compound based compositions for controlling cholesterol levels
US9653006B2 (en) 2008-09-17 2017-05-16 Avery Dennison Corporation Activatable adhesive, labels, and related methods
EP2393897B8 (en) 2009-09-17 2018-09-19 Avery Dennison Corporation Activatable adhesive, labels, and related methods
EP2514771A4 (en) * 2009-12-16 2014-01-22 Kao Corp Resin modifier
JP5479235B2 (en) * 2010-06-11 2014-04-23 国立大学法人豊橋技術科学大学 POLYALLYLAMINE POLYMER, POLYMER PARTICLE, AND METHOD FOR PRODUCING POLYMER PARTICLE
EP2457972A1 (en) * 2010-11-30 2012-05-30 Van Loon Chemical Innovations B.V. New sealant composition
CN106459299B (en) 2014-04-17 2018-11-30 陶氏环球技术有限责任公司 Aqueous liquid dispersion and coating composition comprising it
CN111163938B (en) 2017-10-12 2022-09-09 艾利丹尼森公司 Low-outgassing cleaning adhesive
CN112424295B (en) 2018-06-27 2024-01-26 陶氏环球技术有限责任公司 Phosphate surfactant composition
WO2021093941A1 (en) * 2019-11-12 2021-05-20 Archroma Ip Gmbh Wood coating formulation
US11512818B2 (en) 2020-07-10 2022-11-29 Junming Ding Multi-mode portable lighting device with novel battery charging unit

Family Cites Families (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1282258A (en) * 1961-01-09 1962-01-19 Basf Ag Salts of vinylsulfonic acid and nitrogenous organic bases
US3780092A (en) * 1969-10-20 1973-12-18 Kendall & Co Monomeric emulsion stabilizers
US4011259A (en) * 1969-10-20 1977-03-08 The Kendall Company Monomeric emulsion stabilizers
GB1298099A (en) 1969-10-20 1972-11-29 Kendall & Co Unsaturated quaternary ammonium compounds and copolymers containing them
US3936492A (en) * 1969-10-20 1976-02-03 The Kendall Company Monomeric emulsion stabilizers
US3673142A (en) * 1970-02-16 1972-06-27 Dow Chemical Co Preparation of stable latexes from ethylenically unsaturated polymerizable surfactant and solution of preformed water insoluble polymer of an ethylenically unsaturated compound
US3759982A (en) * 1970-05-26 1973-09-18 Kendall & Co Anionic complexes of monomeric emulsion stabilizers
US3925442A (en) * 1971-01-28 1975-12-09 Kendall & Co Monomeric emulsion stabilizers
US3941857A (en) * 1973-03-15 1976-03-02 E. I. Du Pont De Nemours And Company Polyvinylchloride/olefin copolymers stabilized with epoxy resin
US3983166A (en) * 1974-03-18 1976-09-28 The Kendall Company Monomeric emulsion stabilizers
US4049608A (en) * 1974-08-16 1977-09-20 Alcolac Inc. Functional monomers and copolymers thereof
DE2519581C2 (en) * 1975-05-02 1983-09-29 Basf Ag, 6700 Ludwigshafen Paper sizing agents
US4075411A (en) * 1975-05-23 1978-02-21 Haven Industries, Inc. Vinyl-polymerizable surfactive monomers
US4188293A (en) * 1976-11-24 1980-02-12 Kewanee Industries, Inc. Method of effecting flocculation
US4176028A (en) * 1977-03-22 1979-11-27 E. I. Du Pont De Nemours And Company Plastisols made with polyelectrolyte binders
US4224455A (en) * 1978-11-13 1980-09-23 Stepan Chemical Company Sulfonated alkoxylated alkyl arylol maleate reactive surfactants
CA1141090A (en) * 1979-04-23 1983-02-08 Teiji Tsuruta Linear polydivinylbenzene and derivative thereof
DE2946550A1 (en) * 1979-11-17 1981-05-27 Agfa-Gevaert Ag, 5090 Leverkusen POLYMERS AND METHOD FOR THEIR PRODUCTION
US4337185A (en) * 1980-06-23 1982-06-29 The Dow Chemical Company Process for making cationic structured particle latexes using reactive polymeric surfactants
US4377185A (en) 1980-12-18 1983-03-22 Tubeco, Inc. Hydrotest apparatus
US4380601A (en) * 1981-09-25 1983-04-19 Ppg Industries, Inc. Thermosetting catonic acrylic latices and their use in coating compositions
US4552939A (en) * 1983-12-19 1985-11-12 Exxon Research And Engineering Co. Preparation of sulfonated copolymers by suspension copolymerization
US4657948A (en) * 1985-05-09 1987-04-14 Ethyl Corporation Fluid loss control in well cement slurries
CA1268294A (en) 1985-10-31 1990-04-24 Johnson (S. C.) & Son, Inc. Anticorrosive copolymer emulsions and methods of using and preparing them
DE3711680A1 (en) * 1987-04-07 1988-10-27 Hoechst Ag AQUEOUS BIOCIDES CATIONIC PLASTIC DISPERSIONS AND THE USE THEREOF AS FUNGICIDES, BACTERICIDES AND ALGICIDES EQUIPMENT
US4912157A (en) * 1987-05-18 1990-03-27 Eastman Kodak Company Ink compositions and preparation
GB8813966D0 (en) * 1988-06-13 1988-07-20 Nat Starch Chem Corp Process for manufacture of polymers
AU621916B2 (en) 1988-06-20 1992-03-26 Ppg Industries, Inc. Polymerizable surfactant
US5162475A (en) * 1988-06-20 1992-11-10 Ppg Industries, Inc. Polymerizable surfactant
US5296627A (en) * 1988-06-20 1994-03-22 Ppg Industries, Inc. Ethylenically unsaturated poly(alkyleneoxy) surfactants
US5039339A (en) * 1988-07-28 1991-08-13 Eastman Kodak Company Ink composition containing a blend of a polyester and an acrylic polymer
DE69028116T2 (en) * 1989-12-22 1997-02-13 Courtaulds Coatings Holdings POLLUTION PREVENTING COATINGS
US5399617A (en) * 1990-06-13 1995-03-21 National Starch And Chemical Investment Holding Corporation Thermoplastic, aqueous latex paints having improved wet adhesion and freeze-thaw stability
US5250642A (en) * 1992-05-20 1993-10-05 Phillips Petroleum Company Copolymers of ampholytic ion pairs containing vinylic tertiary amine and olefinic comonomers
US5286843A (en) * 1992-05-22 1994-02-15 Rohm And Haas Company Process for improving water-whitening resistance of pressure sensitive adhesives
US5736247A (en) * 1992-10-30 1998-04-07 Toyoda Gosei Co., Ltd. Coated molded articles of olefin resin
US5344867A (en) * 1993-06-14 1994-09-06 The Bfgoodrich Company Vinylidene chloride emulsion interpolymer composition
IL113583A (en) * 1994-05-26 1999-12-22 Rohm & Haas Acrylic pressure sensitive adhesive
US5478883A (en) * 1995-04-11 1995-12-26 Basf Corporation Emulsion polymerization process utilizing a specifically defined ethylenically unsaturated polymerizable water-soluble nonionic surfactant formed by the reaction of a diallylamine, ethylene oxide and propylene oxide and/or butylene oxide
EP0745655A3 (en) * 1995-06-02 1998-04-29 National Starch and Chemical Investment Holding Corporation Dissipative laminating adhesive
US5962580A (en) 1995-06-07 1999-10-05 Rohm And Haas Company Method for providing a waterborne coating composition with improved color acceptance
US6248438B1 (en) 1995-10-25 2001-06-19 Rohm And Haas Company Method for preparing a paper label
US5891950A (en) 1996-05-28 1999-04-06 Eastman Chemical Company Use of stable amino-functional latexes in water-based inks
JP3989054B2 (en) * 1996-07-29 2007-10-10 株式会社メニコン Cleaning material for contact lenses
DE19646965C2 (en) 1996-11-14 1999-08-12 Roehm Gmbh Acrylate-based biophobic polymers, processes for their production and their use
DE19654897A1 (en) 1996-11-14 1998-06-04 Roehm Gmbh Monomers for polymers with antimicrobial properties
US6239240B1 (en) * 1997-01-28 2001-05-29 Stepan Company Emulsion polymerization process utilizing ethylenically unsaturated amine salts of sulfonic, phosphoric and carboxylic acids
US6017561A (en) * 1997-04-04 2000-01-25 The Clorox Company Antimicrobial cleaning composition
US5969032A (en) * 1998-03-09 1999-10-19 National Starch And Chemical Investment Holding Corporation Latex binders for coatings incorporating a polymerizable surfactant having a terminal allyl amine moiety
US5928783A (en) * 1998-03-09 1999-07-27 National Starch And Chemical Investment Holding Corporation Pressure sensitive adhesive compositions
JP4788852B2 (en) 2000-07-25 2011-10-05 住友金属鉱山株式会社 Transparent conductive substrate, manufacturing method thereof, transparent coating layer forming coating solution used in the manufacturing method, and display device to which transparent conductive substrate is applied

Also Published As

Publication number Publication date
AU748620B2 (en) 2002-06-06
CA2278656C (en) 2009-09-08
BR9807294A (en) 2000-10-31
ATE258561T1 (en) 2004-02-15
US20040092632A1 (en) 2004-05-13
US6900265B2 (en) 2005-05-31
JP2001509195A (en) 2001-07-10
DE69821337T2 (en) 2004-12-02
EP0960134A1 (en) 1999-12-01
EP0960134B1 (en) 2004-01-28
IL131106A0 (en) 2001-01-28
AU6042898A (en) 1998-08-18
DE69821337D1 (en) 2004-03-04
WO1998032773A1 (en) 1998-07-30

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