CA2276624A1 - On-line control of a chemical process plant - Google Patents
On-line control of a chemical process plant Download PDFInfo
- Publication number
- CA2276624A1 CA2276624A1 CA002276624A CA2276624A CA2276624A1 CA 2276624 A1 CA2276624 A1 CA 2276624A1 CA 002276624 A CA002276624 A CA 002276624A CA 2276624 A CA2276624 A CA 2276624A CA 2276624 A1 CA2276624 A1 CA 2276624A1
- Authority
- CA
- Canada
- Prior art keywords
- control
- product
- polymer
- chemical process
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000001311 chemical methods and process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 abstract 5
- 229920000642 polymer Polymers 0.000 abstract 2
- 238000004458 analytical method Methods 0.000 abstract 1
- 238000009529 body temperature measurement Methods 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 229920005555 halobutyl Polymers 0.000 abstract 1
- 125000004968 halobutyl group Chemical group 0.000 abstract 1
- 238000012625 in-situ measurement Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000005259 measurement Methods 0.000 abstract 1
- 238000012544 monitoring process Methods 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
- 238000004886 process control Methods 0.000 abstract 1
- 239000000523 sample Substances 0.000 abstract 1
- 230000003595 spectral effect Effects 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05D—SYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
- G05D21/00—Control of chemical or physico-chemical variables, e.g. pH value
- G05D21/02—Control of chemical or physico-chemical variables, e.g. pH value characterised by the use of electric means
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
- C08F210/10—Isobutene
- C08F210/12—Isobutene with conjugated diolefins, e.g. butyl rubber
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/28—Investigating the spectrum
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/28—Investigating the spectrum
- G01J3/45—Interferometric spectrometry
- G01J3/453—Interferometric spectrometry by correlation of the amplitudes
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/3563—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing solids; Preparation of samples therefor
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/359—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using near infrared light
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/84—Systems specially adapted for particular applications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2400/00—Characteristics for processes of polymerization
- C08F2400/02—Control or adjustment of polymerization parameters
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N2021/3595—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using FTIR
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/84—Systems specially adapted for particular applications
- G01N2021/8411—Application to online plant, process monitoring
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2201/00—Features of devices classified in G01N21/00
- G01N2201/12—Circuits of general importance; Signal processing
- G01N2201/129—Using chemometrical methods
Abstract
A process plant for the manufacture of halobutyl rubber is provided with online monitoring and control of the process parameters to control the properties of the product. It incorporates an in situ measurement system that does not require the removal of any sample material from the process. It uses a Fourier Transform Near Infrared (FTNIR) spectrometer, fiber-optic cables, a viscometer for measuring solution viscosity and a Resistance Temperature Device (RTD) for temperature measurement. An online real-time analyzer system using a Constrained Principal Spectral Analysis program predicts the property of the polymer product and provides the process control system with analysis of the data using derived relationships between the physical properties of the polymer and these spectral measurements and the measured values of fluid viscosity and temperature. Differences between the predicted and desired property of the product are used to control process parameters. The method can be used for a variety of chemical process plants.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3461496P | 1996-12-31 | 1996-12-31 | |
US60/034,614 | 1996-12-31 | ||
PCT/US1997/023734 WO1998029787A1 (en) | 1996-12-31 | 1997-12-31 | On-line control of a chemical process plant |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2276624A1 true CA2276624A1 (en) | 1998-07-09 |
CA2276624C CA2276624C (en) | 2001-07-24 |
Family
ID=21877515
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002276624A Expired - Lifetime CA2276624C (en) | 1996-12-31 | 1997-12-31 | On-line control of a chemical process plant |
Country Status (18)
Country | Link |
---|---|
US (1) | US6072576A (en) |
EP (1) | EP0948761B2 (en) |
JP (1) | JP4435307B2 (en) |
KR (1) | KR100500802B1 (en) |
CN (1) | CN1105956C (en) |
AU (1) | AU727750B2 (en) |
BR (1) | BR9714450A (en) |
CA (1) | CA2276624C (en) |
DE (1) | DE69705323T3 (en) |
ES (1) | ES2160983T5 (en) |
HK (1) | HK1026034A1 (en) |
IL (1) | IL130731A (en) |
MY (1) | MY117038A (en) |
NO (1) | NO316346B1 (en) |
PL (1) | PL334397A1 (en) |
RU (1) | RU99116247A (en) |
TW (2) | TW558557B (en) |
WO (1) | WO1998029787A1 (en) |
Families Citing this family (106)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19736310A1 (en) * | 1997-08-21 | 1999-02-25 | Bayer Ag | Process for the production of partially hydrogenated acrylonitrile butadiene rubbers (HNBR) using on-line Raman spectroscopy |
US6200134B1 (en) | 1998-01-20 | 2001-03-13 | Kerr Corporation | Apparatus and method for curing materials with radiation |
WO2000001521A1 (en) * | 1998-07-06 | 2000-01-13 | Exxon Chemical Patents Inc. | Apparatus and method for dewatering an elastomeric polymer |
US6635224B1 (en) * | 1998-10-30 | 2003-10-21 | General Electric Company | Online monitor for polymer processes |
FI991542A (en) * | 1999-07-06 | 2001-01-07 | Neste Chemicals Oy | Process for controlling the production process for polyhydric alcohols |
US6748334B1 (en) * | 1999-12-06 | 2004-06-08 | Jorge E. Perez | Specialty gas analysis system |
SK932010A3 (en) | 2000-04-27 | 2011-09-05 | Ineos Usa Llc | Method for regulating the chemical manufacturing process |
WO2002012969A1 (en) * | 2000-08-07 | 2002-02-14 | Mitsui Chemicals, Inc. | Production control method |
US6632680B1 (en) * | 2000-09-22 | 2003-10-14 | Deslauriers Paul J. | Measurement of short chain branching in olefin copolymers using chemometric analysis |
GB0026173D0 (en) * | 2000-10-26 | 2000-12-13 | Imerys Minerals Ltd | Processing of inorganic particulate materials |
US7194369B2 (en) * | 2001-07-23 | 2007-03-20 | Cognis Corporation | On-site analysis system with central processor and method of analyzing |
KR100749589B1 (en) * | 2001-10-25 | 2007-08-14 | 에스케이에너지 주식회사 | Method for applying near-infrared spectroscopic analysis to ethylene plant |
ATE389174T1 (en) | 2001-10-30 | 2008-03-15 | Lanxess Deutschland Gmbh | DETERMINATION OF REACTION PROGRESS OF GRAFT POLYMERIZATION REACTIONS |
CN100443868C (en) | 2001-11-09 | 2008-12-17 | 埃克森美孚化学专利公司 | On-line measurement and control of polymer properties by Raman spectroscopy |
WO2003056281A2 (en) * | 2002-01-01 | 2003-07-10 | Exxonmobil Chemical Patents Inc. | Method and apparatus for on-line measurement of polymer properties |
US6847899B2 (en) | 2002-04-26 | 2005-01-25 | Dean Allgeyer, M.D., Inc. | Device and method for qualitative and quantitative determination of intravenous fluid components |
CA2501528A1 (en) * | 2002-10-15 | 2004-04-15 | Exxonmobil Chemical Patents Inc. | On-line measurement and control of polymer properties by raman spectroscopy |
US7319040B2 (en) * | 2002-10-28 | 2008-01-15 | Ineos Usa Llc | Process control using on-line instrumentation and process models |
WO2004040283A2 (en) * | 2002-10-28 | 2004-05-13 | Bp Corporation North America Inc. | Control of a polymerization process |
WO2004063234A1 (en) * | 2003-01-06 | 2004-07-29 | Exxonmobil Chemical Patents Inc. | On-line measurement and control of polymer product properties by raman spectroscopy |
DE10304615A1 (en) * | 2003-02-05 | 2004-08-19 | Bayer Ag | Process for monitoring and managing nitriding processes with the help of online spectrometers |
DE10322439A1 (en) * | 2003-05-19 | 2004-12-09 | Bayer Ag | Method and device for determining the isomer composition in isocyanate production processes |
US7173095B2 (en) * | 2003-06-20 | 2007-02-06 | Akzo Nobel N. V. | Polymerization process involving the dosing initiators |
US7402635B2 (en) * | 2003-07-22 | 2008-07-22 | Fina Technology, Inc. | Process for preparing polyethylene |
DE10336875A1 (en) * | 2003-08-11 | 2005-03-17 | Bayer Chemicals Ag | Spectroscopic concentration determination in a rectification column |
EP1713840B1 (en) * | 2004-01-14 | 2019-04-24 | Chevron Phillips Chemical Company Lp | Method and apparatus for monitoring polyolefin production |
US7400941B2 (en) * | 2004-01-14 | 2008-07-15 | Chrevron Phillips Chemical Company Lp | Method and apparatus for monitoring polyolefin production |
CA2470887C (en) * | 2004-06-14 | 2014-10-21 | Nova Chemicals Corporation | Detection of gels in a solution polymerization |
PL209549B1 (en) * | 2004-08-02 | 2011-09-30 | Dow Technology Investments Llc | Hydroformylation stabilization process |
US20060190137A1 (en) * | 2005-02-18 | 2006-08-24 | Steven W. Free | Chemometric modeling software |
ATE548645T1 (en) | 2005-03-31 | 2012-03-15 | Hitachi Chemical Co Ltd | METHOD FOR ESTIMATING THE DISSOLUTION RATE OF POLYIMIDE |
DE102005020352A1 (en) * | 2005-05-02 | 2007-08-16 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Chemical product`s production process controlling method for e.g. pipe system, involves providing variables by individual adjustment in production process and measuring variables in process, to generate horizon, with three scale arms |
US7483129B2 (en) * | 2005-07-22 | 2009-01-27 | Exxonmobil Chemical Patents Inc. | On-line properties analysis of a molten polymer by raman spectroscopy for control of a mixing device |
WO2007018773A1 (en) | 2005-07-22 | 2007-02-15 | Exxonmobil Chemical Patents Inc. | On-line analysis of polymer properties for control of a solution phase reaction system |
US7505127B2 (en) * | 2005-07-22 | 2009-03-17 | Exxonmobil Chemical Patents Inc. | On-line raman analysis and control of a high pressure reaction system |
WO2007016309A2 (en) * | 2005-07-29 | 2007-02-08 | Exxonmobil Research And Engineering Company | Method to determine predictive tests and device applying same to lubricant formulations |
DE102005036643A1 (en) * | 2005-08-04 | 2007-02-08 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Method and device for determining the maturity of thermoset compositions |
US20070059838A1 (en) * | 2005-09-13 | 2007-03-15 | Pavilion Technologies, Inc. | Dynamic constrained optimization of chemical manufacturing |
US7764379B1 (en) | 2005-12-20 | 2010-07-27 | Axsun Technologies, Inc. | Semiconductor laser natural gas analysis system and method |
US7803629B2 (en) * | 2006-06-27 | 2010-09-28 | Chevron Phillips Chemical Company, Lp | Method for employing SEC-FTIR data to predict mechanical properties of polyethylene |
DE102006052673A1 (en) * | 2006-11-07 | 2008-05-08 | Thomas Schneider | Method and device for recalibrating manufacturing processes |
WO2008060570A1 (en) * | 2006-11-14 | 2008-05-22 | Abb Inc. | System for storing and presenting sensor and spectral data for batch processes |
KR100913232B1 (en) * | 2007-05-31 | 2009-08-24 | 학교법인 서강대학교 | An online optimization system and optimization method for petrochemical process |
EP2014641A3 (en) * | 2007-06-06 | 2009-03-18 | Huntsman International Llc | Process for preparing mixtures of diphenylmethane diisocyanates and polyphenyl polymethylene polyisocyanates |
ATE490457T1 (en) * | 2007-06-15 | 2010-12-15 | Bp Chem Int Ltd | METHOD FOR ONLINE ANALYSIS OF A GAS PHASE PROCESS STREAM |
US20090060783A1 (en) * | 2007-09-04 | 2009-03-05 | Kenneth Charles Barrett | Polymer concentration monitoring system and use thereof |
US20090192340A1 (en) * | 2007-11-01 | 2009-07-30 | Robert Dielman Culp | Alkylaromatic dehydrogenation system and method for monitoring and controlling the system |
US9072572B2 (en) | 2009-04-02 | 2015-07-07 | Kerr Corporation | Dental light device |
US9066777B2 (en) | 2009-04-02 | 2015-06-30 | Kerr Corporation | Curing light device |
WO2010138271A2 (en) | 2009-05-29 | 2010-12-02 | Exxonmobil Chemical Patents Inc. | Feedback and feedforward closed loop purity and recovery control |
DK2460017T3 (en) * | 2009-07-30 | 2018-11-26 | Sgs North America Inc | PVT ANALYSIS OF COMPRESSED FLUIDS |
US9223301B2 (en) * | 2010-04-19 | 2015-12-29 | Honeywell International Inc. | Active cloud point controller for refining applications and related method |
US8645082B2 (en) * | 2010-09-13 | 2014-02-04 | Mks Instruments, Inc. | Monitoring, detecting and quantifying chemical compounds in a sample |
US20120085151A1 (en) * | 2010-10-07 | 2012-04-12 | Bayer Materialscience Ag | Method and apparatus for characterizing polymers |
KR101564817B1 (en) * | 2010-10-08 | 2015-10-30 | 란세스 도이치란트 게엠베하 | Activity monitoring and polymerization process control |
US8843324B2 (en) | 2011-02-03 | 2014-09-23 | Nova Chemicals (International) S.A. | Double derivative NIR process control |
US8618226B2 (en) | 2011-05-19 | 2013-12-31 | Bridgestone Corporation | Method for quantitative analysis of styrene microblock content |
JP5845001B2 (en) * | 2011-06-01 | 2016-01-20 | 出光興産株式会社 | Hydrogenated petroleum resin manufacturing method and hydrogenated petroleum resin pellet manufacturing plant |
AU2012330761B2 (en) | 2011-11-03 | 2016-01-21 | Verifood Ltd. | Low-cost spectrometry system for end-user food analysis |
US10082600B2 (en) * | 2011-12-16 | 2018-09-25 | Halliburton Energy Services, Inc. | Methods of calibration transfer for a testing instrument |
US9170155B2 (en) | 2012-05-08 | 2015-10-27 | Panaridus, Llc | System and apparatus for analysis of a guayule plant in situ |
WO2013169809A1 (en) * | 2012-05-08 | 2013-11-14 | Panaridus, Llc | System and apparatus for analysis of a guayule plant in situ |
CN104684875A (en) * | 2012-10-01 | 2015-06-03 | 巴斯夫欧洲公司 | Method for separating a mixture of hydrocarbons by extractive distillation |
EP3028020B1 (en) | 2013-08-02 | 2021-11-24 | Verifood Ltd. | Spectrometry system |
EP3090239A4 (en) | 2014-01-03 | 2018-01-10 | Verifood Ltd. | Spectrometry systems, methods, and applications |
CN104049624B (en) * | 2014-07-07 | 2017-07-11 | 蓝星(北京)技术中心有限公司 | Chemical products production model optimization method, device and continuous type chemical system |
EP3201598A4 (en) | 2014-10-01 | 2018-02-28 | Advanced Polymer Monitoring Technologies Inc. | Systems and methods for control of polymer reactions and processing using automatic continuous online monitoring |
CN107250739A (en) | 2014-10-23 | 2017-10-13 | 威利食品有限公司 | The annex of Handheld spectrometer |
EP3241017B1 (en) * | 2014-12-29 | 2021-12-01 | Bridgestone Corporation | Methods for quantifying rubber content in a plant with low-field nmr |
JP6663919B2 (en) * | 2015-01-22 | 2020-03-13 | アドヴァンスド ポリマー モニタリング テクノロジーズ インコーポレイテッド,ディービーエー/フルエンス アナリティクスAdvanced Polymer Monitoring Technologies,Inc.,Dba/Fluence Analytics | Systems and methods for predicting and controlling the properties of a species during a time-dependent process |
WO2016125164A2 (en) | 2015-02-05 | 2016-08-11 | Verifood, Ltd. | Spectrometry system applications |
WO2016125165A2 (en) | 2015-02-05 | 2016-08-11 | Verifood, Ltd. | Spectrometry system with visible aiming beam |
WO2016162865A1 (en) | 2015-04-07 | 2016-10-13 | Verifood, Ltd. | Detector for spectrometry system |
CN104792725B (en) * | 2015-04-30 | 2018-01-23 | 西安近代化学研究所 | Monoethanolamine dehydration prepares the rapid analysis method of aziridine product stream |
US10066990B2 (en) | 2015-07-09 | 2018-09-04 | Verifood, Ltd. | Spatially variable filter systems and methods |
US20170097330A1 (en) * | 2015-10-05 | 2017-04-06 | Honeywell International Inc. | Hybrid analyzer for fluid processing processes |
DE102015223789A1 (en) * | 2015-10-07 | 2017-04-13 | Sms Group Gmbh | Online analysis by means of near-infrared spectroscopy analysis NIR, in particular for the production of polyaluminum chloride hydroxide |
US10203246B2 (en) | 2015-11-20 | 2019-02-12 | Verifood, Ltd. | Systems and methods for calibration of a handheld spectrometer |
CN106892843A (en) * | 2015-12-17 | 2017-06-27 | 英尼奥斯欧洲股份公司 | Recovery tower is controlled |
JP2019507879A (en) * | 2016-03-07 | 2019-03-22 | アドヴァンスド ポリマー モニタリング テクノロジーズ インコーポレイテッドAdvanced Polymer Monitoring Technologies, Inc. | Device and method for simultaneously identifying intrinsic viscosity and non-newton behavior of polymers |
US10254215B2 (en) | 2016-04-07 | 2019-04-09 | Verifood, Ltd. | Spectrometry system applications |
EP3488204A4 (en) | 2016-07-20 | 2020-07-22 | Verifood Ltd. | Accessories for handheld spectrometer |
US10791933B2 (en) | 2016-07-27 | 2020-10-06 | Verifood, Ltd. | Spectrometry systems, methods, and applications |
IT201600081868A1 (en) * | 2016-08-03 | 2018-02-03 | Versalis Spa | METHOD AND SYSTEM FOR THE CONTROL OF A CONTINUOUS POLYMER PRODUCTION PLANT. |
CN106290068A (en) * | 2016-08-25 | 2017-01-04 | 青岛励赫化工科技有限公司 | A kind of sizing material half parts surface viscosity on-line measuring device and using method thereof |
GB201616787D0 (en) * | 2016-10-03 | 2016-11-16 | Renishaw Plc | Measurement apparatus and methods |
CN107957379B (en) * | 2016-10-18 | 2020-07-24 | 中国石油化工股份有限公司 | On-line continuous detection device and method and polymerization reaction system and method |
CN106526653B (en) * | 2016-12-19 | 2023-02-28 | 桂林百锐光电技术有限公司 | Scintillation detector |
KR102153474B1 (en) * | 2017-06-20 | 2020-09-08 | 주식회사 엘지화학 | Control system and method for ethylene vinyl acetate copolymerization process |
US10696906B2 (en) | 2017-09-29 | 2020-06-30 | Marathon Petroleum Company Lp | Tower bottoms coke catching device |
US11098139B2 (en) | 2018-02-28 | 2021-08-24 | Chevron Phillips Chemical Company Lp | Advanced quality control tools for manufacturing bimodal and multimodal polyethylene resins |
JP7087468B2 (en) * | 2018-03-08 | 2022-06-21 | 東ソー株式会社 | Aliphatic-Aromatic Petroleum Resin Manufacturing Method |
SG11202008576WA (en) | 2018-03-28 | 2020-10-29 | Dow Global Technologies Llc | Method to monitor and control the polymerization of a polymer |
CN110873699A (en) * | 2018-08-30 | 2020-03-10 | 广东生益科技股份有限公司 | Method, device and system for online quality control of bonding sheet and storage medium |
KR102479346B1 (en) | 2018-11-12 | 2022-12-19 | 주식회사 엘지화학 | Method for predicting fouling in proccess of preparing polyolefin |
EP3711852A1 (en) | 2019-03-21 | 2020-09-23 | Covestro Deutschland AG | Method and apparatus for quantitative monitoring of the composition of a oligomer/monomer mixture |
US11384174B2 (en) | 2019-05-15 | 2022-07-12 | Exxonmobil Chemical Patents Inc. | Detection of polymer concentration in polymerization process using refractive index measurement |
CN112676193B (en) * | 2019-10-18 | 2022-08-09 | 李和伟 | Application of spectrum detection in detecting quality of modified membrane cloth, detection method and detection equipment |
CA3109675A1 (en) | 2020-02-19 | 2021-08-19 | Marathon Petroleum Company Lp | Low sulfur fuel oil blends for stability enhancement and associated methods |
US11905468B2 (en) | 2021-02-25 | 2024-02-20 | Marathon Petroleum Company Lp | Assemblies and methods for enhancing control of fluid catalytic cracking (FCC) processes using spectroscopic analyzers |
US11898109B2 (en) | 2021-02-25 | 2024-02-13 | Marathon Petroleum Company Lp | Assemblies and methods for enhancing control of hydrotreating and fluid catalytic cracking (FCC) processes using spectroscopic analyzers |
US11702600B2 (en) | 2021-02-25 | 2023-07-18 | Marathon Petroleum Company Lp | Assemblies and methods for enhancing fluid catalytic cracking (FCC) processes during the FCC process using spectroscopic analyzers |
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KR20220147932A (en) * | 2021-04-28 | 2022-11-04 | 에스케이가스 주식회사 | System and method for process core factor screening in commercial chemical processes |
CA3188122A1 (en) | 2022-01-31 | 2023-07-31 | Marathon Petroleum Company Lp | Systems and methods for reducing rendered fats pour point |
CN114752056B (en) * | 2022-03-02 | 2024-01-26 | 双驱智能科技(宁波)有限公司 | Device and method for repeatedly and stably producing polyaryletherketone with narrow molecular weight distribution |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3553295A (en) * | 1968-04-25 | 1971-01-05 | Shell Oil Co | Polymerization monitor |
WO1984001430A1 (en) * | 1982-09-30 | 1984-04-12 | Accuray Corp | Methods and apparatus for measuring and controlling curing of polymeric materials |
GB2152713B (en) * | 1983-05-12 | 1987-07-15 | Broken Hill Pty Co Ltd | Characterizing and handling multi-component substances |
US4830757A (en) * | 1985-08-06 | 1989-05-16 | The Mogul Corporation | Telemetry system for water and energy monitoring |
ATE146880T1 (en) † | 1987-08-18 | 1997-01-15 | Bp Oil Int | METHOD FOR DIRECT DETERMINATION OF THE PHYSICAL PROPERTIES OF HYDROCARBON PRODUCTS |
EP0305090B1 (en) † | 1987-08-18 | 1993-08-04 | Bp Oil International Limited | Method for the direct determination of physical properties of hydrocarbon products |
US5116915A (en) * | 1987-12-28 | 1992-05-26 | Giprokautchuk | Method of controlling polymerization process of olefinic hydrocarbons |
FR2625506B1 (en) * | 1987-12-31 | 1992-02-21 | Bp Chimie Sa | METHOD AND APPARATUS FOR THE MANUFACTURE OF CONTROLLED POLYMERS USING A REGULATION SYSTEM INCLUDING AN INFRARED SPECTROPHOTOMETER |
FR2626579B1 (en) † | 1988-02-01 | 1990-06-15 | Bp Chimie Sa | METHOD AND APPARATUS FOR MANUFACTURING CONTROLLED POLYOXYALCOYLENE USING A REGULATION SYSTEM INCLUDING AN INFRARED SPECTROPHOTOMETER |
FR2631957B1 (en) † | 1988-05-30 | 1990-08-31 | Bp Chimie Sa | PROCESS AND APPARATUS FOR MANUFACTURING OLEFINS AND DIOLEFINS BY CONTROLLED HYDROCARBON SPRAYING REACTION USING A SYSTEM COMPRISING AN INFRARED SPECTROPHOTOMETER |
US5132916A (en) * | 1990-05-21 | 1992-07-21 | Elsag International B.V. | Methodology for ph titration curve estimation for adaptive control |
MY107650A (en) * | 1990-10-12 | 1996-05-30 | Exxon Res & Engineering Company | Method of estimating property and / or composition data of a test sample |
US5121337A (en) * | 1990-10-15 | 1992-06-09 | Exxon Research And Engineering Company | Method for correcting spectral data for data due to the spectral measurement process itself and estimating unknown property and/or composition data of a sample using such method |
US5243546A (en) * | 1991-01-10 | 1993-09-07 | Ashland Oil, Inc. | Spectroscopic instrument calibration |
DE4118232A1 (en) † | 1991-06-04 | 1992-12-10 | Bayer Ag | CONTINUOUS PREPARATION OF POLYCARBONATES |
DE4127512C2 (en) † | 1991-08-20 | 1995-02-23 | Bayer Ag | Process for the production of polycarbonate with constant viscosity |
CH685003A5 (en) † | 1992-08-11 | 1995-02-28 | Buehler Ag | A method of continuously crystallizing and polymerizing plastic material, and apparatus therefor. |
EP0706049A1 (en) * | 1994-10-07 | 1996-04-10 | Bp Chemicals S.N.C. | Cracking property determination |
US5532487A (en) * | 1994-11-23 | 1996-07-02 | E. I. Du Pont De Nemours And Company | Near-infrared measurement and control of polyamide processes |
-
1997
- 1997-12-08 US US08/986,971 patent/US6072576A/en not_active Expired - Lifetime
- 1997-12-29 MY MYPI97006383A patent/MY117038A/en unknown
- 1997-12-31 EP EP97953394A patent/EP0948761B2/en not_active Expired - Lifetime
- 1997-12-31 WO PCT/US1997/023734 patent/WO1998029787A1/en active IP Right Grant
- 1997-12-31 KR KR10-1999-7006010A patent/KR100500802B1/en not_active IP Right Cessation
- 1997-12-31 IL IL13073197A patent/IL130731A/en not_active IP Right Cessation
- 1997-12-31 DE DE69705323T patent/DE69705323T3/en not_active Expired - Lifetime
- 1997-12-31 CA CA002276624A patent/CA2276624C/en not_active Expired - Lifetime
- 1997-12-31 AU AU57149/98A patent/AU727750B2/en not_active Expired
- 1997-12-31 ES ES97953394T patent/ES2160983T5/en not_active Expired - Lifetime
- 1997-12-31 PL PL97334397A patent/PL334397A1/en unknown
- 1997-12-31 RU RU99116247/09A patent/RU99116247A/en not_active Application Discontinuation
- 1997-12-31 CN CN97181653A patent/CN1105956C/en not_active Expired - Lifetime
- 1997-12-31 JP JP53015698A patent/JP4435307B2/en not_active Expired - Lifetime
- 1997-12-31 BR BR9714450-9A patent/BR9714450A/en not_active Application Discontinuation
-
1998
- 1998-01-26 TW TW086120089A patent/TW558557B/en not_active IP Right Cessation
- 1998-01-26 TW TW091124215A patent/TWI266769B/en not_active IP Right Cessation
-
1999
- 1999-06-30 NO NO19993261A patent/NO316346B1/en not_active IP Right Cessation
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2000
- 2000-08-22 HK HK00105264A patent/HK1026034A1/en not_active IP Right Cessation
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AU5714998A (en) | 1998-07-31 |
DE69705323T3 (en) | 2012-02-09 |
CN1245570A (en) | 2000-02-23 |
JP2001508354A (en) | 2001-06-26 |
NO316346B1 (en) | 2004-01-12 |
CN1105956C (en) | 2003-04-16 |
WO1998029787A1 (en) | 1998-07-09 |
RU99116247A (en) | 2001-08-20 |
EP0948761A1 (en) | 1999-10-13 |
ES2160983T5 (en) | 2012-02-15 |
JP4435307B2 (en) | 2010-03-17 |
EP0948761B1 (en) | 2001-06-20 |
IL130731A0 (en) | 2000-06-01 |
AU727750B2 (en) | 2000-12-21 |
DE69705323T2 (en) | 2002-04-25 |
TW558557B (en) | 2003-10-21 |
IL130731A (en) | 2004-07-25 |
KR100500802B1 (en) | 2005-07-12 |
CA2276624C (en) | 2001-07-24 |
BR9714450A (en) | 2000-12-05 |
NO993261L (en) | 1999-08-26 |
TWI266769B (en) | 2006-11-21 |
US6072576A (en) | 2000-06-06 |
HK1026034A1 (en) | 2000-12-01 |
PL334397A1 (en) | 2000-02-28 |
ES2160983T3 (en) | 2001-11-16 |
MY117038A (en) | 2004-04-30 |
DE69705323D1 (en) | 2001-07-26 |
EP0948761B2 (en) | 2011-09-07 |
KR20000062408A (en) | 2000-10-25 |
NO993261D0 (en) | 1999-06-30 |
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