CA2276160A1 - Products of and methods for improving adhesion between substrate and polymer layers - Google Patents

Products of and methods for improving adhesion between substrate and polymer layers Download PDF

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Publication number
CA2276160A1
CA2276160A1 CA002276160A CA2276160A CA2276160A1 CA 2276160 A1 CA2276160 A1 CA 2276160A1 CA 002276160 A CA002276160 A CA 002276160A CA 2276160 A CA2276160 A CA 2276160A CA 2276160 A1 CA2276160 A1 CA 2276160A1
Authority
CA
Canada
Prior art keywords
base substrate
substrate
uncured
composite
methods
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002276160A
Other languages
French (fr)
Other versions
CA2276160C (en
Inventor
Rodney Lane Patrick
Peter Uwe Mekailian
James Michael Caldwell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nextec Applications Inc
Original Assignee
Nextec Applications Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nextec Applications Inc filed Critical Nextec Applications Inc
Publication of CA2276160A1 publication Critical patent/CA2276160A1/en
Application granted granted Critical
Publication of CA2276160C publication Critical patent/CA2276160C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/08—Impregnating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
    • B29C37/0078—Measures or configurations for obtaining anchoring effects in the contact areas between layers
    • B29C37/0082—Mechanical anchoring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06—Fibrous reinforcements only
    • B29C70/08—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
    • B29C70/086—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers and with one or more layers of pure plastics material, e.g. foam layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/54—Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • B29C70/546—Measures for feeding or distributing the matrix material in the reinforcing structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/02—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving pretreatment of the surfaces to be joined
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2313/00—Use of textile products or fabrics as reinforcement
    • B29K2313/02—Use of textile products or fabrics as reinforcement coated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B2038/0052—Other operations not otherwise provided for
    • B32B2038/0076—Curing, vulcanising, cross-linking

Abstract

The present invention relates to a method for improving both adhesion between substrate and polymer layers and the durability of such composite structures; while maintaining the malleability and preferred characteristics of the original substrate. Quite unexpectedly, the application of a layer or film upon an uncured, encapsulated base substrate which has been encapsulated by the shear thinning methods of the present invention, results in superior adhesion of multiple layers when compared to conventional layering, coating or composite manufacturing methods. Moreover, the uncured or at most, semi-cured, polymer composition applied to the base substrate ensures that the substrate maintains maximum flexibility for subsequent shaping into composite articles prior to curing. The methods described herein produce multiple layer composite articles that are lighter, stronger, more flexible and utilize less material, than composite articles produced by conventional techniques.
The method comprises applying an uncured, substantially solvent free, polymer composition exhibiting thixotropic or pseudoplastic characteristics, onto a base substrate having structural elements and interstices therebetween; shear thinning the polymer composition to place it into the base substrate, thereby encapsulating most of the structural elements while leaving a plurality of interstitial spaces open; overlaying a layer or film of polymer or thermoplastic material to at least one surface of the uncured encapsulated base substrate; pressuring the layer or film into the interstices of the uncured encapsulated base substrate to form a chemical and mechanical interlocking bond between the polymer composition of the base substrate and the overlay material; optionally shaping the multi layer composite and curing the completed composite. This method produces multi layer composite articles and medical garments exhibiting increased adhesion and durability with excellent malleability and flexibility over conventional methods.
CA002276160A 1998-06-23 1999-06-22 Products of and methods for improving adhesion between substrate and polymer layers Expired - Lifetime CA2276160C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/103,235 1998-06-23
US09/103,235 US6416613B1 (en) 1998-06-23 1998-06-23 Products of and method for improving adhesion between substrate and polymer layers

Publications (2)

Publication Number Publication Date
CA2276160A1 true CA2276160A1 (en) 1999-12-23
CA2276160C CA2276160C (en) 2003-12-23

Family

ID=22294097

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002276160A Expired - Lifetime CA2276160C (en) 1998-06-23 1999-06-22 Products of and methods for improving adhesion between substrate and polymer layers

Country Status (4)

Country Link
US (1) US6416613B1 (en)
EP (1) EP0967060A3 (en)
JP (1) JP3204953B2 (en)
CA (1) CA2276160C (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004502884A (en) * 2000-07-07 2004-01-29 ミリケン・アンド・カンパニー Woven substrate with improved sustained water repellency and soil release and method of making same
US20050226993A1 (en) * 2000-10-03 2005-10-13 Nawrocki Jesse G Medical devices having durable and lubricious polymeric coating
DE10105234A1 (en) * 2001-02-02 2002-08-29 Schoeller Textil Ag Sevelen Textile surface
FR2843119B1 (en) * 2002-07-30 2006-10-06 Rhodia Chimie Sa COMPOSITION OF ELASTOMERICALLY ELASTOMERIC SILICONE OILS FOR THE TREATMENT BY IMPREGNATION OF FIBROUS MATERIALS
US7041088B2 (en) * 2002-10-11 2006-05-09 Ethicon, Inc. Medical devices having durable and lubricious polymeric coating
CA2552054A1 (en) * 2003-12-31 2005-07-21 Akro-Fireguard, Products, Inc. Dimensionally stable fabric
US7157140B1 (en) * 2004-03-03 2007-01-02 Rtp Company Malleable composites and methods of making and using the same
US7611998B2 (en) * 2004-06-16 2009-11-03 Bluestar Silicones France Sas Enhanced elastomer coated, protective barrier fabric and process for producing same
US20060065428A1 (en) * 2004-07-13 2006-03-30 Kummer Randy D Electrical cable having a surface with reduced coefficient of friction
US9630031B2 (en) 2006-03-29 2017-04-25 Chapman Thermal Products, Inc. Lightweight protective fabrics and clothing for protection against hot or corrosive materials
US20110145984A1 (en) * 2009-11-30 2011-06-23 Chapman Thermal Products, Inc. Methods of protecting a person from hot high heat capacity materials and hot corrosive material
US20070231573A1 (en) * 2006-03-29 2007-10-04 Chapman Thermal Products, Inc. Fire retardant and heat resistant yarns and fabrics treated for increased strength and liquid shedding
US20100071119A1 (en) * 2006-03-29 2010-03-25 Chapman Therman Products, Inc. Yarns and fabrics that shed liquids, gels, sparks and molten metals and methods of manufacture and use
US8782812B2 (en) * 2006-05-23 2014-07-22 Bha Altair, Llc Waterproof breathable garment with tape-free seams
US7980283B2 (en) * 2008-01-16 2011-07-19 Nextec Applications, Inc. System and method for using a force model to control process configurations for the encapsulation of a web
US8430511B2 (en) 2010-10-07 2013-04-30 Vicoh, Llc Kit of higher order aberration contact lenses and methods of use
CN103189563B (en) * 2010-10-26 2015-04-01 东洋纺株式会社 Coated base fabric for air bags
CN104139531A (en) * 2014-06-27 2014-11-12 中航飞机股份有限公司西安飞机分公司 Method for improving adhesion property of prepreg and fixture when composite material is automatically belt-laid
MX2019014946A (en) 2017-06-16 2020-08-06 Nitto Denko Corp Multilayer film, laminate, air bag, and method for producing laminate.
MX2019014948A (en) 2017-06-16 2020-08-06 Nitto Denko Corp Laminate and air bag.
MX2019014947A (en) * 2017-06-16 2020-08-06 Nitto Denko Corp Multilayer film, laminate, airbag, and method of manufacturing laminate.
MX2019014945A (en) 2017-06-16 2020-08-06 Nitto Denko Corp Method for producing laminate, laminate, and air bag.
CN109068523B (en) * 2018-07-03 2024-03-08 深圳市德汇云服科技有限公司 Blade type computer network server
US20220264961A1 (en) * 2019-06-28 2022-08-25 Eastman Chemical Company Molded articles made with cellulose ester fibers

Family Cites Families (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2673823A (en) 1949-08-26 1954-03-30 Owens Corning Fiberglass Corp Method of producing vapor permeable fluid impermeable fabric and product
US2893962A (en) 1951-11-10 1959-07-07 Floyd E Bartell Water-impermeable, gas-permeable coating compositions, method of preparation and articles coated therewith
DE1248006B (en) * 1963-08-16 1967-08-24 Riegel Textile Corp Process for the production of laminates
US3360394A (en) 1964-01-24 1967-12-26 Burlington Industries Inc Process for forming breathable polyurethane coating on a textile fabric and the resulting product
US3436366A (en) 1965-12-17 1969-04-01 Gen Electric Silicone potting compositions comprising mixtures of organopolysiloxanes containing vinyl groups
DE1289300B (en) * 1967-02-23 1969-02-13 Rost & Co H Fabric insert for a conveyor belt or drive belt
US3594213A (en) 1967-10-27 1971-07-20 Joseph T Rudman Process for controlling porosity in fibrous webs
BE759624A (en) 1969-12-01 1971-06-01 Dow Corning SILICONE RUBBER RESISTANT TO SOIL AND MANUFACTURING
US3762978A (en) 1971-07-15 1973-10-02 Dow Corning Method for improving the adhesion between silicone elastomers
US3969177A (en) 1974-06-24 1976-07-13 International Business Machines Corporation Laminating method
US3972757A (en) 1974-09-16 1976-08-03 Uniroyal Inc. Manufacture of vulcanized elastomeric hose
US4052521A (en) * 1974-09-19 1977-10-04 Serge Ferrari Coating and calendaring of 2-dimensionally tensioned fabric
US3962511A (en) 1974-11-21 1976-06-08 The Goodyear Tire & Rubber Company Textile composite structure and method of preparation
DD140123B1 (en) * 1975-10-30 1981-05-13 METHOD FOR PRODUCING OBJECTS OF FIBER-REINFORCED MATERIALS
US4112179A (en) 1975-12-10 1978-09-05 Maccalous Joseph W Method of coating with ablative heat shield materials
US4109543A (en) 1976-05-10 1978-08-29 The Goodyear Tire & Rubber Company Flexible composite laminate of woven fabric and thermoplastic material and method of making said laminate
US4181157A (en) 1978-01-03 1980-01-01 Flexfab, Inc. Fire sleeving
US4205559A (en) 1979-06-20 1980-06-03 M. Lowenstein Corporation Neoprene coating composition for reinforcement fabrics for rubber products, process, and products produced thereby
US4293611A (en) 1979-10-22 1981-10-06 Sws Silicones Corporation Silicone polyether copolymers
US4297265A (en) 1979-11-23 1981-10-27 Otto Fabric, Inc. Silicone rubber coating material having reduced surface tension
EP0079143A3 (en) 1981-10-20 1984-11-21 Adnovum Ag Pseudoplastic gel transfer
JPS58136878A (en) 1982-02-03 1983-08-15 日本バイリーン株式会社 Production of adhesive core fabric
US4483973A (en) 1982-02-17 1984-11-20 General Electric Company Adhesion promoters for one-component RTV silicone compositions
JPS5929157A (en) 1982-08-11 1984-02-16 東レ・ダウコーニング・シリコーン株式会社 Silicone elastomer coated cloth and its manufacture
US4525400A (en) 1982-09-27 1985-06-25 General Electric Company Composition for promoting adhesion of curable silicones to substrates
US4504549A (en) 1983-05-20 1985-03-12 Union Carbide Corporation Elastomeric silicone finishes applied to substrates and method of preparing same
US4472470A (en) 1983-07-07 1984-09-18 General Electric Silicones Transparent membrane structures
US4500584A (en) 1983-07-07 1985-02-19 General Electric Company Transparent membrane structures
US4666765A (en) * 1985-10-02 1987-05-19 Caldwell James M Silicone coated fabric
US5024594A (en) 1986-07-23 1991-06-18 Membrane Technology & Research, Inc. Protective clothing material
IL79955A0 (en) 1986-09-05 1986-12-31 Israel Atomic Energy Comm Protective composite materials,their production and articles of protective clothing made therefrom
US4681808A (en) 1986-10-02 1987-07-21 Dow Corning Corporation Adhesion of silicone elastomer to polyurethane
US5128198A (en) 1986-11-07 1992-07-07 Basf Aktiengesellschaft Production of improved preimpregnated material comprising a particulate thermoplastic polymer suitable for use in the formation of a substantially void-free fiber-reinforced composite article
US5128394A (en) 1987-05-06 1992-07-07 General Electric Company Silicone adhesive and organic adhesive composites
US4794192A (en) 1987-07-06 1988-12-27 General Electric Company Cyclic aminoalkylsilanes and their use as adhesion promoters in room temperature vulcanizable polydiorganosiloxane compositions
NL8702275A (en) 1987-09-24 1989-04-17 Avery International Corp PRESSURE SENSITIVE ADHESIVE.
JP2614478B2 (en) 1988-02-01 1997-05-28 東レ・ダウコーニング・シリコーン株式会社 Film-shaped silicone rubber adhesive
US5869172A (en) 1988-03-14 1999-02-09 Nextec Applications, Inc. Internally-coated porous webs with controlled positioning of modifiers therein
US5004643A (en) 1988-03-14 1991-04-02 Sili-Tex, Inc. Silicone polymer-internally coated webs
US5846604A (en) 1988-03-14 1998-12-08 Nextec Applications, Inc. Controlling the porosity and permeation of a web
US5209965A (en) 1988-03-14 1993-05-11 Sili-Tex, Inc. Internally coated webs
US5698303A (en) 1988-03-14 1997-12-16 Nextec Applications, Inc. Controlling the porosity and permeation of a web
AU3440689A (en) 1988-03-14 1989-10-05 Sili-Tex, Inc. Silicone polymer-internally coated webs
US5876792A (en) * 1988-03-14 1999-03-02 Nextec Applications, Inc. Methods and apparatus for controlled placement of a polymer composition into a web
JP2651840B2 (en) 1988-07-15 1997-09-10 東レ・ダウコーニング・シリコーン株式会社 Silicone rubber adhesive
US4942093A (en) 1988-09-09 1990-07-17 Bridgestone/Firestone, Inc. Adhesive system for bonding uncured rubber to cured polyurethane
US4988779A (en) 1989-04-17 1991-01-29 General Electric Company Addition cured silicone pressure sensitive adhesive
US4991232A (en) 1989-06-27 1991-02-12 Standard Textile Company, Inc. Surgical gown and method of making same
US5573813A (en) * 1990-03-02 1996-11-12 Hexcel Corporation Method and apparatus for impregnating fibers with highly viscous materials and article made therewith
US5175058A (en) 1990-05-29 1992-12-29 General Electric Company Pressure sensitive adhesives
US5096981A (en) 1990-05-29 1992-03-17 General Electric Company Pressure sensitive adhesives
JP3080979B2 (en) 1990-10-04 2000-08-28 ポリプラスチックス株式会社 Adhesive products made of polyacetal resin
CA2055958A1 (en) 1990-12-17 1992-06-18 Gary M. Lucas Adhesion promoter system for one-component rtv silicone compositions
US5190827A (en) 1991-03-26 1993-03-02 General Electric Company Silicone pressure sensitive adhesive compositions having high solids content
US5292586A (en) * 1991-03-26 1994-03-08 General Electric Company Solventless or high solids-containing silicone pressure sensitive adhesive compositions
US5308887A (en) 1991-05-23 1994-05-03 Minnesota Mining & Manufacturing Company Pressure-sensitive adhesives
US5175057A (en) 1991-06-25 1992-12-29 General Electric Company Adhesion promoters for room temperature vulcanizable silicone compositions
US5180585A (en) 1991-08-09 1993-01-19 E. I. Du Pont De Nemours And Company Antimicrobial compositions, process for preparing the same and use
TW203094B (en) 1992-01-21 1993-04-01 Gen Electric
US5335372A (en) 1992-03-12 1994-08-09 Rotecno Ag Article of clothing, in particular for the medical or chemical field
AU681589B2 (en) 1992-06-26 1997-09-04 Procter & Gamble Company, The Biodegradable, liquid impervious multilayer film compositions
US5371136A (en) 1992-08-12 1994-12-06 Wacker Silicones Corporation High adhesion coating for rubber articles
US5398729A (en) 1992-08-25 1995-03-21 Cooper Tire & Rubber Company Low permeation fuel hose
AU5090293A (en) 1992-09-09 1994-03-29 Clock Spring Company L.P. High tensile strength composite reinforcing bands and methods for making same
CA2088814A1 (en) 1992-10-05 1994-04-06 Dane Kenton Parker Process for improving the interfacial bonding between fibers and rubber
US5342870A (en) 1993-12-15 1994-08-30 General Electric Company Addition-curable silicone adhesive compositions, and bis(trialkoxysilylalkyleneoxy-carbonylalkylene) amine adhesion promoters
US5416144A (en) 1993-12-20 1995-05-16 General Electric Company Addition-curable silicone adhesive compositions and bis (trialkoxysilyalkylene) urea adhesion promoters
US5503940A (en) 1994-10-24 1996-04-02 The Goodyear Tire & Rubber Company Elastomeric laminates containing a solventless elastomeric adhesive composition
TW296400B (en) 1994-11-17 1997-01-21 Shinetsu Chem Ind Co
US5700532A (en) 1995-11-17 1997-12-23 Highland Industries, Inc. Stable silicone coated fabric without adhesion promoter

Also Published As

Publication number Publication date
JP3204953B2 (en) 2001-09-04
CA2276160C (en) 2003-12-23
JP2000096456A (en) 2000-04-04
US6416613B1 (en) 2002-07-09
EP0967060A3 (en) 2003-06-04
EP0967060A2 (en) 1999-12-29

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