CA2266381C - Method of throttle-valving control for the co-extrusion of plastic materials as for molding and the like, and apparatus therefor - Google Patents
Method of throttle-valving control for the co-extrusion of plastic materials as for molding and the like, and apparatus therefor Download PDFInfo
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- CA2266381C CA2266381C CA002266381A CA2266381A CA2266381C CA 2266381 C CA2266381 C CA 2266381C CA 002266381 A CA002266381 A CA 002266381A CA 2266381 A CA2266381 A CA 2266381A CA 2266381 C CA2266381 C CA 2266381C
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/16—Making multilayered or multicoloured articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/16—Making multilayered or multicoloured articles
- B29C45/1603—Multi-way nozzles specially adapted therefor
- B29C45/1607—Multi-way nozzles specially adapted therefor having at least three different ways
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/16—Making multilayered or multicoloured articles
- B29C45/1642—Making multilayered or multicoloured articles having a "sandwich" structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/16—Making multilayered or multicoloured articles
- B29C45/1603—Multi-way nozzles specially adapted therefor
- B29C2045/1614—Multi-way nozzles specially adapted therefor side-by-side flow of materials in the same channel
Abstract
A novel multiple-plastic stream co-extruder and method, as for injection-molding cavities, in which the extruder is internally provided therewithin and therealong with a restrictor or throttle pin, rod or element that forces combined plastic material streams, formed with an interior core stream encased in outer and inner stream layers, into corresponding concentric annular flow stream layers that are ultimately split transversely in opposite directions into a cavity gated to the extruder, and with the core stream at a region of zero gradient in the transverse flow velocity profile within the extruder and cavity.
Description
WETHOD OF THROTTLE-VALVTNG CONTROL FOR THE
CO-EXTRUSION OF PLASTIC MATERIALS AS FOR MOLDING
AND THE L (KE, AND AP P ARATU S THE REFO R
Field of Invention The present invention relates to the co-extrusion of two or more streams of plastic materials and the like, as for introduction into molding apparatus or similar applications; being more particularly directed to the problems of providing better controlling of such co-extrusion and enabling more uniform molding of the extruded materials and with greater t3exibility of the use of a wide range of different-proposed materials, e:ctruding temperatures and other conditions.
With specific reference to injection systems for co-injecting at least two materials, the present invention relates to an improved technique and apparatus for combining the different tlow streams of materials, wherein a velocity profile of the combined stream is produced in the melt delivery system that is similar to the velocity profile of the combined stream in the injection moid cavity, for insuring uniformity in the resulting molded item.
Back;round of Invention A common problem in the field of co-injection molding resides in the need to keep the leading edge of the core (interior) layer as uniform with respect to thickness as trailing portions of the core (interior) layer entering the mold cavity.
CO-EXTRUSION OF PLASTIC MATERIALS AS FOR MOLDING
AND THE L (KE, AND AP P ARATU S THE REFO R
Field of Invention The present invention relates to the co-extrusion of two or more streams of plastic materials and the like, as for introduction into molding apparatus or similar applications; being more particularly directed to the problems of providing better controlling of such co-extrusion and enabling more uniform molding of the extruded materials and with greater t3exibility of the use of a wide range of different-proposed materials, e:ctruding temperatures and other conditions.
With specific reference to injection systems for co-injecting at least two materials, the present invention relates to an improved technique and apparatus for combining the different tlow streams of materials, wherein a velocity profile of the combined stream is produced in the melt delivery system that is similar to the velocity profile of the combined stream in the injection moid cavity, for insuring uniformity in the resulting molded item.
Back;round of Invention A common problem in the field of co-injection molding resides in the need to keep the leading edge of the core (interior) layer as uniform with respect to thickness as trailing portions of the core (interior) layer entering the mold cavity.
A tapered leading edge will produce a molded part that is not uniform in its properties near the position of farthest penetration of the interior layer.
Usually, the leading edge of the core (interior) layer becomes tapered as it flows through a cylindrical central channel of prior art co-injection nozzles disposed downstream of the combining area of the nozzle and as it flows through the cylindrical gate portion of the mold cavity. Typical of such nozzles are those described, for example, in U. S. Letters Patent Nos. 4,895,504 and 4,892,699.
The amount of taper depends on the velocity profile of the combined flow which causes a gradient of velocity between the radially innermost portion and the ~ radially outermost portion of the leading edge. The amount of taper also depends on the total axial distance of cylindrical flow between the area of combination and the cavity-end of the cylindrical gate.
To minimize the leading edge taper, such prior art nozzles have been constructed with a short axial flow distance between the area of combination and the cavity end of the cylindrical gate. Typically, this axial flow distance is between about Smm and 25mm, and the resulting leading edge taper length is greater than about 1.8mm for the shorter axial flow distance and 9mm for the longer axial flow distance. This short axial flow distance requires that the combining means be part of the nozzle.
Usually, the leading edge of the core (interior) layer becomes tapered as it flows through a cylindrical central channel of prior art co-injection nozzles disposed downstream of the combining area of the nozzle and as it flows through the cylindrical gate portion of the mold cavity. Typical of such nozzles are those described, for example, in U. S. Letters Patent Nos. 4,895,504 and 4,892,699.
The amount of taper depends on the velocity profile of the combined flow which causes a gradient of velocity between the radially innermost portion and the ~ radially outermost portion of the leading edge. The amount of taper also depends on the total axial distance of cylindrical flow between the area of combination and the cavity-end of the cylindrical gate.
To minimize the leading edge taper, such prior art nozzles have been constructed with a short axial flow distance between the area of combination and the cavity end of the cylindrical gate. Typically, this axial flow distance is between about Smm and 25mm, and the resulting leading edge taper length is greater than about 1.8mm for the shorter axial flow distance and 9mm for the longer axial flow distance. This short axial flow distance requires that the combining means be part of the nozzle.
Another problem with the current art is that the outermost diameter of the co-injection nozzle close to the gate is larger than nozzle diameters used in single-material injection molding. This larger size requires a large clearance bore in the mold which makes it difficult to provide adequate cooling of the mold cavity near the gate. Some designs of current art use a combining means that has a comically or frustoconically-shaped portion to minimize the outermost diameter near the Sate: even so, this diameter of the nozzle meat the gate may be twice the size of a sinele material nozzle.
Objects of Invention An object of the present invention is to provide a new and improved method of and apparatus for co-extrusion that shall not be subject to the above and other disadvantages of the prior art, but that, to the contrary, through a radically different conversion of the nozzle to a throttle-control extruder, provides for significantly improved, more uniform and more flexible operation.
Another object is to provide a novel extrusion apparatus in which a combined flow is produced having a velocity profile within and downstream of the area of combination of the extrusion materials which has a substantially zero gradient of velocity across the leading edge of the core (interior) layer, such velocity profile enabling the leading edge of the core (interior) layer to not become tapered, as in prior art nozzles, as it flows from the area of combination to the cavity end of the mold gate.
Still another object of the invention is to provide a novel apparatus in which the combining means is remote from the gate area of the nozzle so that mold design and mold cooling are not compromised.
A further object is the achievement of such novel results through radically converting prior art cylindrical nozzles designs into an extruder structure containing throttle or restrictor needles, rods or stems that force annular extrusion;
and, in the case of inner core molding, create concentric outer and inner annular extrusion streams, with the core-forming annular stream encased within annular co-extruded outer and inner stream layers.
A further object is to provide such a novel extruder in which a gate vestige is left on the molded part which is as small as that which can be obtained by single material molding systems.
An additional object of the invention is to provide a novel co-extrusion method and apparatus wherein the velocity profile of the combined stream of the plastic materials downstream of the combining area is made substantially the same as the velocity profile of the combined stream in the cavity, so that improved part properties and improved cycle times are possible.
Other and further objects will be explained hereinafter and are more particularly delineated in the appended claims.
Summary of The Invention In summary, however, from one of its broader aspects, the invention embraces a 5 method of co-extruding multiple plastic materials as for injecting through a gate region into a mold cavity to produce a molded product, that comprises: combining streams of such flowing plastic materials with at least one internal stream that is to serve as an interior core of a resulting molded plastic product within internal and outer streams of plastic material to serve as covering plastic material layers; restricting the combined streams to flow along concentric annular flow paths within and along a longitudinally extending tubular flow channel to the cavity gate region, with the annular core stream encased by inner and outer annular covering plastic material stream layers at the gate region; and splitting the concentric annular streams along opposite transverse directions to inject into corresponding opposite transverse sections of the cavity.
Preferred and best mode embodiments and apparatus designs for practising the novel method of the invention are hereinafter more fully described.
WO 98/13187 PCT/1896101369 _ Brief Description of The Drawings The invention will now be described in connection with the accompanying drawings, Fig. 1 of which shows a cross-section of a complete system including source of materials, material distribution and combination system and mold cavity;
Fig. 2 is a cross-section of flow from the material combination area to the mold cavity, showing that the core (interior) layer flows along the zero-gradient of the velocity profile in accordance with the technique and construction of the present invention;
Fig. 3 illustrates in cross-section the annular flow channel of this construction, also showing the core (interior) layer along the zero-gradient of the velocity profile;
Fig. 4 is a cross-sectional view of an annular flow channel as in Fig. 3, but with maldistributed outer and inner annular flow layers causing the core (interior) layer to be offset from the median of the annular diameters;
Fig. 5 presents a cross-section of prior art cylindrical flow showing the core (interior) layer in an area of high gradient of velocity, to contrast from the conditions of the invention as presented in Figs. 3 and 4;
Fig. 6 is similar to Fig. 5 but shows prior art cylindrical flow with maldistributed outer and inner layers;
WO 98/13187 PCT/IB96/01369 _ Fig. 7 is a cross-sectional view showing velocity profiles of core (interior) layer in annular flow nozzle area, annular flow gate area and cavity;
Fig. 8 is similar to Fig. 7, showing, however, the effect of maldistributed outer and inner layer flow on the relative position of leading edge of the core (interior) layer in the mold cavity;
Figs. 9 and 10 are views similar to respective Figs. 7 and 8, but showing prior art cylindrical flow in nozzle gate and cavity;
Fig. I 1 is a cross-sectional view of a molded part formed by the structure of the invention, showing the amount of leading edge taper caused by annular flow length in Fig. 8 of 75 mm from combination area to cavity side of gate, when the inner and outer maldistribution is 10%;
Fig. 12 is a view similar to Fig. 11 but of a molded part made by the prior art cylindrical nozzle structure, Fig. 10, showing the amount of leading edge taper caused by cylindrical flow inner and outer maldistribution of 10%;
Fig. 13 is a cross-section of a modified extruder constructed in accordance with the invention and in which the flow from the manifold is through a flat disc combining means with a fixed throttle valve means, through the annular flow nozzle and gate into the cavity;
WO 98/13187 PCT/1B96/01369 _ Fig. 14 is a cross-sectional view of a further modification in which an axial combining means is provided and with a fixed throttle valve means as part of the nozzle itself;
Fig. 15 is a more complete cross-section of the axial combining means with the fixed throttle valve means of Fig. 14, being a cross-sectional view of a combing means consisting of 3 concentric axial cylinders around a central fixed throttle valve means which extends through the combination area, through the separate nozzle and through the gate into the mold;
Fig. l6 is a view similar to Fig. 13, but showing a moveable throttle valve means;
Fig. 17 is an enlarged cross-section of the combining means and moveable throttle valve of Fig. 16;
Figs. 18 and 19 are annular to Fig. 17, showing the valve in a neutral position, with throttle positions for reduced and increased inner layer flow rates, respectively;
Fig. 20 illustrates, on an enlarged scale, the relative locations of the nozzle end and gate into the cavity wherein the throttle valve maintains the desired annular flow to the cavity;
WO 98/13187 PCT/1896/01369 _ Fig. 21 is similar to Fig. 20, but provides a conical valve corresponding to a conical gate to produce a reduced gate mark on the molded part;
Fig. 22 is again similar to Fig. 20, but the throttle valve is terminated prior to the gate to allow molding of plastics that require an open gate;
Fig. 23 is once more similar to Figs. 20 and 22 but the throttle valve is adjusted to act as a gate valve, shown in the open position; whereas in Fig.
24, it is shown in the closed position;
Fig. 25 is a cross-section of the nozzle end of the invention, the gate and a partially filled cavity, showing outer layers and core (interior) layer operated at the same temperature; whereas in Fig. 26, the outer layers are injected at a much higher temperature than the core (interior) layer;
Figs. 27 (a)-(d) show the fill sequence for a core (interior) layer that is uniformly distributed throughout the molded part;
Figs. 28 (a)-(d) are similar to Figs. 27(a)-(d) but show a fill sequence for a core (interior) layer wherein the maximum amount of core is injected into the molded part using a fixed throttle valve;
Figs. 29 (a)-(d) again are similar to Figs. 27 and 28, but show the fill sequence for a core (interior) layer wherein the maximum amount of core is injected into the molded part using a combining means designed to produce an WO 98/13187 PCT/>B96/01369 _ outer layer tlow at a greater rate relative to the inner annular layer to effect a thicker outer layer on the gate side of the molded part; while Fig. 30 shows the reverse;
Fig. 31 is a cross-section of the gate and cavity area, showing the fill sequence using a moveable throttle valve, increasing the inner annular layer flow relative to the outer annular layer during the flow shown in Fig. 3 I (b), thereby injecting more core (interior) layer material into the gate-side of the molded part;
Fig. 32 is a cross section of the gate and cavity area showing the fill sequence wherein the throttle valve moves to decrease the inner annular layer flow relative to the outer annular layer (l. e. the opposite relative flow to Fig.
31 ) during the flow shown in Fig. 32(B), thereby injecting more core (interior) layer material into the molded part side opposite the gate;
Fig. 33 is a graph plotting velocity/average velocity and flow fraction in the annular channel and cavity; and Fig. 34 is a graph plotting velocity/average velocity and flow fraction in a prior cylindrical channel for comparison with the results of Fig. 33.
Preferred Embodiment(sl of Invention Referring to Fig. I, and in the exemplary context of the invention as applied to plastic, (such as PET, EVOH, polycarbonates and the like) co-injection molding systems adapted to inject at least two materials into a cavity of a mold, the system comprises respective sources S1 and SZ for each material, a means, such as a manifold D, for delivering each material stream to a combining means C upstream of each gate of the mold, and a novel throttle valve controlling extruder nozzle means E for delivering the combined stream to the gate into the mold M. The sources S, and Sz for each material are shown as reciprocating screw injection units; the means for delivering the material streams is a manifold block D with respective separate flow channels Cl and CZ for each material arranged such that the flow is balanced and equal to each; the combining means C is disposed upstream of the throttle nozzle means E with its internal co-extensive throttle needle T which delivers the combined stream to each gate region G of the mold M. In the embodiments disclosed herein, Fig. 2, the streams forming each layer L of the molded product are combined in an annular channel A of the combining means C so that the leading edge of the core (interior) layer I is disposed in the zero velocity gradient portion of the combined flow stream, as later more fully explained. The longitudinally extending-extruder nozzle means E with its central longitudinal throttle needle or flow restrictor T downstream of the combining means C
provides an uninterrupted continuation of the annular flow developed in the combining means.
l2 In the three-layer combined flow stream embodiment of Fig. 2, two materials L and I are provided, each from its own source; the first material L, which forms the outer or covering layers OL, and IL, of the molded part, forms the inner and outer layers Ol and LL of the annular flow combined stream at A, formed by the presence of the central throttle T; the second material I, which forms the core (interior) layer I, of the molded part, forms the middle or inner or interior annular layer IA of the annular flow combined stream A. The first material L is delivered through its flow channel to the combining means C wherein it is divided from a single stream into two streams, one forming the aforesaid inner annular layer IL of the combined annular flow stream and the other forming the aforesaid outer annular layer OL. The second material I is delivered through its flow channel to the combining means C wherein it is disposed to form the middle or interior annular layer IA of the concentric annular flow combined streams, as also shown in the annular flow channel cross section of Fig. 3. Preferably, as shown, the throttle needle or central restrictor is of reduced diameter T' at the extruder opening distal end at the cavity gate injection end of the nozzle.
The nozzle means thus has an internal bore which surrounds the throttle valve pin to form an annular channel to deliver the combined flow stream to the gate while maintaining the aforesaid velocity profile. By disposing the core (interior) layer material to be in the zero gradient of the velocity profile VP,, the leading edge of the core (interior) layer does not become tapered regardless of the axial flow distance between the combining means and the gate into the cavity. The nozzle axial length, unlike in prior art nozzles, can accordin~~,.ly be made as long as required to provide for good mold cooling. The outermost diameter of the nozzle is typically no larger than that required for single-material molding, thereby not compromising mold design or mold cooling. This embodiment, moreover, also makes it easier to convert a mold designed for single-material molding to be used for co-injection. At the gate region G adjacent the proximal distal end of the restrictor or throttle needle, rod or element T', the annular flow streams are laterally split and flow is injected in opposite directions transversely into the corresponding opening sections of the mold cavity, as shown by the arrows in Fig.
2.
In this and later-described embodiments that dispose the material forming the core (interior) layer of the molded part to be the middle layer of the combined flow stream, a part can be readily molded with its core (interior) layer at a melt temperature that is lower than the outer layers of the molded part. In single layer molding, on the other hand, the temperature of the material as provided at its source must be high enough 1 ) to lower its viscosity for ease of flow between the t-t walls of the injection cavity and 2) to produce a good cosmetic appearance on the outer surfaces of the molded part. Because the material of a single layer molded part is provided by a single material source, the temperature of its interior layer will be the temperature needed for ease of cavity flow and surface appearance, and the cooling time needed to cool the interior of the molded part is dependent on the melt temperature provided by the source. Using the present invention, however, the core (interior) layer can be provided at a temperature much different than the temperature of the outer layer material, thereby producing several unexpected improvements compared to single layer molding. While some other prior art systems can also permit this effect, it is particularly simply and ei~tciently effected with the technique and construction of the invention.
Improvements that can be produced by providing the outer layers at normal or higher than normal temperature and the core (interior) layer at a correspondingly lower temperature include:
1 ) cavity fill pressure will be lower because the outer layer viscosity will be lower than normal;
Z) part surface appearance will be improved because of the hotter outer layer melt temperature;
3) cooling time, and thereby cycle time, will be reduced if the relative increase in outer layer melt temperature is less than the corresponding core (interior) layer melt temperature decrease, such that the total heat content of the combined melt is less than normal for a single-material molding;
5 4) an increased core (interior) layer melt viscosity will increase the core (interior) layer volume relative to a decreased outer layer volume if that is a desirable property of the molded part; and 5) a core (interior) layer material can be used that has a higher coefficient of thermal expansion than that of the outer layers without causing undue molded-in 1 0 stresses, etc.
Other improvements can be produced by providing differing relative melt temperatures of the core (interior) and outer layers materials. One such reason is to control relative shrinking between layers when the core (interior) layer has a different coefficient of thermal expansion than the outer layers material.
Another 15 reason is to produce parts that have lower molded-in stresses by using temperature differences to reduce relative shrinkage between the core (interior) and outer layers without affecting part surface cosmetic appearance.
Returning to the flow distribution illustrated in Figs. 2 and 3, the extruder structure of the present invention can accommodate for maldistributed or t6 unsymmet~cal outer and inner annular flow layers that, as shown in Fig. 4, may cause the core (interior) annular layer IA to be offset from the median of the annular diameters of the encasing inner and outer layers IL and OL. From the velocity profile VP,' of Fig. 4, it will be observed that the core, though offset, is none-the-less close to the zero gradient velocity profile, still enabling improved results. This is to be contrasted from the cylindrical flows in prior art nozzles E', shown in Figs. 5 and 6, for symmetrical and unsymmetrical conditions, and wherein the core layer is subjected to areas of high gradient of velocity in the profiles VP," and VP,"', with the attendant limitations and disadvantages 1 0 previously discussed.
In the throttled or centrally restricted co-extruder of Fig. 7, wherein the extruder E is shown connected to an annular flow gate G' and cavity, the velocity profiles of the annular core layer IA in the annular extruder area (VPz) and in the annular flow gate area (VP3) and in the cavity (VP3) are all presented, demonstrating the maintaining of zero gradient throughout the flow and cavity injection process of the invention. Substantially these benefits are also obtained in the event of misalignment or maldistribution of outer and inner layer flow, Fig. 8, with the erect illustrated of maldistributed outer and inner layer flow on the relative position D ~! of leading edge of the core (interior) layer in the mold cavity.
WO 98/13187 PCTlIB96/01369 Figs. 9 and 10 show prior art cylindrical nozzles corresponding, respectively, to the extruder of the invention shown in Figs. 7 and 8, and illustrate the undesirable high gradients of velocity for the flow of the core (interior) layer in the nozzle E' (VPz') and at the gate (VP3'), with zero gradient of the velocity profile attained only in the cavity (VP,, ).
Fig. 10 shows the development of the core leading edge taper caused by the effect of the velocity difference across the maldistributed core leading edge as it flows through extruder E'. As leading edge streamline IA' 1 flows at a higher velocity than 1A'3, 0 Q taper results by time the core enters the cavity through gate G'. Even though the core layer I, remains offset from the cavity flow centerline, the velocity difference across the tapered leading edge in the cavity remain small, so that the increase in 0 Q within the cavity is small compared to the OQ developed in the prior art extruder E'.
Further to contrast the significantly improved molding results and tolerances attainable with the annular flow construction of the invention with the prior art cylindrical nozzles, Fig. 11 illustrates the minimal acceptable amount of leading edge taper carried in a molded part for a 10% inner and outer flow maldistribution with the annular flow of the structure of the invention (Fig.
8) for an annular flow length of 75mm from combination area C to the cavity-side of the WO 98/13187 PCT/IB96/01369 _ l8 gate G; whereas Fig. 12 shows the much greater leading edge taper in the molded part that the art has had to accept with prior cylindrical flow nozzles for the same l0% maidistribution with a cylindrical flow length of 75mm from combination area to cavity-side of the gate (Fig. 10).
To achieve a minimal acceptable amount (6 to 6mm) of leading edge taper as shown in Fig. 11 when using prior art, the length of combined flow in the central channel from the area of combination to the surface of the molded part should not exceed about 11 mm if the maldistribution of inner and outer flow is as shown in Fig. 6 and Fig. 34. To provide for a minimal amount of mold cooling near the gate, the short length of the prior art central channel requires that the shape of the combining means be conical or ftustoconical. Such shape still requires the distal end of the nozzle to be nearly twice the outside diameter of a single-material nozzle, thus causing part cooling near the gate to be compromised.
Fig. 13 illustrates another embodiment of the invention wherein the three layer combining means consists of four flat discs FD surrounding a central fixed throttle valve pin T-T' which forms the inner flow channel wall for the inner layer of the combined flow stream. Flow channels C,', C~', etc. are created between the three mating planar surfaces of the discs FD uniformly to dispose each flow layer to produce a uniform flow of the respective material flowing from each channel l9 into the area of combination C, so that each layer of the combined flow stream is uniformly annularly disposed as it flows from the combining means through the extruding restricted or throttled nozzle means E and gate G into the cavity.
The manifold combining means may, moreover, be incorporated as part of the extruder nozzle structure itself as shown, for example, in Fig. 14, wherein axial combining channels C,", C2", etc. are provided at the top of the extruder E
itself, with a fixed throttle valve T extending along and within the extrusion nozzle.
Another embodiment (shown in Fig. 15) uses three concentric shells S,', SZ' and S;' surrounding a central throttle pin T which forms the inner flow channel wall for the inner layer of the combined flow stream. The flow channels created between the shells and between the innermost shell and throttle valve pin are designed to produce a uniform flow of the respective material flowing from each channel into the area of combination so that each layer of the combined flow stream is uniformly annularly disposed as it flows from the combining means through the nozzle means into the cavity. In this embodiment, the combining means C is a separate assembly sandwiched between the delivery manifold D and the extruder nozzle E. This allows the extruder nozzle to be identical in design as those used in single material molding. The combining means is coaxial with WO 98113187 PCT/IB96101369 _ 2() respect to the extruder nozzle so that the throttle pin T and the cylindrical wall of the extruder nozzle form a uniform annular channel A.
While the centrally longitudinally extending restrictors or throttle pins heretofore described have been shown as fixed, as, for example, in the embodiment of Fig. 13, they may also be made movable, as by an adjusting rod R, Fig. 16, for various useful throttle valuing or adjusting purposes, providing further flexibility not present in prior art cylindrical nozzles.
The moveable throttle or restrictor valve pin T-T' can vary the percentage of the outer layers material in the inner annular flow layer vs. the outer annular flow layer of the combined flow stream downstream of the combining area.
Changing the relative volumes of the outer layers shifts the position of the core (interior) layer in the mold cavity to produce a part with controlled outer layer thickness on both surfaces of the molded part. If the outer layer flow is evenly distributed between the inner annular flow layer and outer annular flow layer, the outer layer thickness will be similar on both surfaces of the molded part. if the outer layer flow is biased toward either the inner of outer annular flow layers, the outer layer thickness in the molded part will be similarly biased on the corresponding surface molded from the biased annular layers. Material from the inner annular flow layer forms the outer layer of the part molded by the cavity wall WO 98/13187 PCT/1896/01369 _ opposite the gate into the cavity, and the material from the outer annular flow layer forms the outer layer of the part molded by the cavity wall adjacent to the gate.
The use of a moveable throttle valve pin is typically appropriate in cases where it is advantageous to vary, during each injection, the relative percentage of the outer layers material in the inner annular flow layer vs. the outer annular flow layer. The moveable throttle pin is not used to initiate nor to terminate the flow of any material for any layer. For cases where the relative thickness of the outer layer on both surfaces of the molded part can remain in fixed proportion to each other, the embodiment uses a non-moving throttle valve pin.
In the enlarged views of Figs. 17, 18 and 19, the throttle valve T is shown positioned by the rod R in a neutral position with disc channels C,' , CZ', etc. open to balance inner layer flow with respect to the outer layer flow; in a lower position to reduce the inner layer flow rate with respect to the outer layer flow rate (Fig.
18); and in an elevated position, Fig. 19, to increase the inner layer flow rate with respect to the outer layer flow rate.
Turning, now, to the distal or gate end of the extruder nozzle structures, having adjustability of the position of the throttle pin, the position shown in Fig. 20 enables the throttle valve pin to maintain annular flow to the cavity as before described. To produce a reduced gate vestige height, the distal end of the throttle valve pin T' is conically further tapered at T" as it approaches the cavity end of the gate G, as in Fig. 21. The shape of this distal end with respect to the gate length, taper and diameter is of the same nature as that used to produce a reduced gate vestige height on single material molded parts, because the material in the gate area at the initiation and termination of each cycle is only outer layer material.
Some molding materials, however, such as PET (Polyethylene Terephtholate), require that the gate flow be cylindrical rather than annular.
In the embodiment of Fig. 22, adjusted for such materials, the throttle valve pin terminates at the end of the nozzle means so that cylindrical flow occurs only through the gate G, thereby minimizing the possible detrimental effects on the core (interior) layer leading edge.
To produce a zero gate height vestige, the moveable throttle valve pin may have a distaff end shaped with respect to the gate length, taper and diameter similar to those used to produce a zero gate vestige height in single material molding.
The throttle valve may be adjusted, furthermore, to serve also as a gate valve at the gate into cavity region, if desired; shown in open position in Fig. 23, and in closed position in Fig. 24.
It has earlier been mentioned that the novel structures of the present invention lend themselves to great flexibility in the use at similar or different temperatures. In the extrusion into the cavity shown in Fig. 25, similar to that of before-discussed Fig. 2, the system is illustrated as operated with the horizontally Bowing annular outer layers OL and IL containing encased therewithin the annular core (interior) layer IA, at the same melt temperature of, for example, about 500°F, for ABS type plastics, during transversely splitting in opposite lateral directions into the cavity, producing the same-temperature filling of the cavity of the outer layers, O L, and IL,, covering or encasing the core material I'. In Fig. 26, on the other hand, the system readily enables a cooler core material I', say 400°F, as for the reasons before explained, extruded and molded with hotter outer layers O
L., and IL,, of, say 500°F; and so on, for any desired variations depending on the plastic material properties and the desired molded effects.
It is next in order to examine the annularly extruded material filling sequence within the mold cavity for an inner core layer I (EVOH, for example), as shown in successive Figs. 27(a), (b), (c), and (d), demonstrating the remarkably uniform distribution attainable with the structures of the invention as the concentric annular plastic streams split on opposite sides of the throttle or restrictor element T' and inject into opposite sides of the mold cavity, (the relatively thick outer layers being of, for example, PET). In Figs. 28 (a), (b), (c) an (d), the same fill sequence is shown for the injection of a maximum amount of WO 98/13187 PCT/)(896101369 2~
core material I' in the molded part (polycarbonate, for example), this being achieved with a fixed throttle valve pin T', as shown, producing outer layer flow (recycled polycarbonate plastic, for example), equally distributed between inner and outer annular layers IL and OL.
The flexibility of the adjustable throttle structure of the invention is fixrther illustrated in Figs. 29(a)-(d), showing the cavity filling sequence again for a maximum amount of inner core material in the molded part, but using a throttle valve adjustment that produced an outer layer flow OL at a greater rate relative to the inner annular layer IL to effect a thicker outer layer OL on the gate side of the molded part (Fig. 29(d)), than the inner layer IL,. The operation in Figs. 30 (a)-(d) produces the reverse, with the layer IL,, thicker than the gate side layer OL, of the molded part (Fig. 30 (d)). The position of the moveable throttle pin R
shown in Fig. 20 will produce the increased OL and OL, of Fig. 29. The position of moveable throttle pin shown in Fig. 19 will produce the increased IL and IL, of Fig. 3d. For embodiments using a fixed throttle pin, for example T of Fig. 15, the relative thickness difference of OL, and IL,, can be created by appropriate corresponding design of combining means channels C,' and C3' of Fig. 13 and C,"
of Figs. 14 and 15.
Figs. 31 (a)-(d) and 32 (a)-(d) are similar cross-sectional sketches of the cavity filling sequences using a moveable throttle valve element, respectively increasing the inner annular layer flow and the outer annular layer flow for injecting more core (interior) layer I' into the gate side and opposite the gate side, 5 respectively, of the molded part.
An adjustment of the relative flow rate of OL, iA and IL occurs during each extrusion. The relative volumes and flow rates of core layer and covering layers is controlled by S, and Sz, while the relative flow rates between the covering layers is controlled by adjustment of moveable throttle R of Fig. 17, for example.
10 During each extrusion, S,, Sz and R are controlled to produce a core layer I' that has a leading edge LE, that is flowing along a streamline which has a V /V
that prevents LE, from breaking through the flow front FF of the covering layers.
After the FF has progressed further into the cavity away from the gate G, the rate of flow of core layer IA is increased relative to the flow of covering layers OL and 15 IL and the relative flow rates of OL and IL are adjusted closer to a neutral position of R such that a core leading edge LEz is created long the maximum velocity streamline of the cavity. LEz flowing at a higher velocity than LE, will penetrate shallower, the same or deeper into the cavity than LE, depending on the timing of the adjustment of Si, Sz and R during the extrusion. The moveable throttle pin allows the creation of LE, before creation of LEz, thus more core layer volume can be injected into a cavity than in prior art which can create only one core leading edge in each extrusion cycle.
A comparison of the flow fraction and velocity profile plots of Figs. 33 and 34, for the throttled annular channel flow of the invention and of the prior art cylindrical channel, respectively, graphically demonstrates the significantly improved characteristics attained by the invention Fig. 33 is the velocity profile Vp = V / V and volumetric fraction of the annular flow between the channel formed by the throttle valve pin and the cylindrical wall of the extruder body, represented by -50% and +50%, respectively, on the horizontal axis of the graph. The mean diameter of flow is represented as the ''0" on the horizontal axis. The velocity profile and flow fraction is based on the Power Lw model for non-Newtonian fluids (Ref. J. S. Brydson, low Proyerties of Polvme~r Melts, second edition, George Godwin Limited in association with the Plastics and Rubber Institute).
If the design and construction of the channels C,', Cz', etc., as shown in Fig. 13, etc., in the combining means produces perfectly annular flow of the inner and outer annular layers, the core leading edge streamline will be centered on the mean diameter of flow, and thus is has a velocity Vm equal to I .44 x the average velocity V of the combined annular flow.
In actual equipment constriction and operation, the annular distribution of the inner and outer annular layers is not perfect, and a l0% maldistribution is not unexpected within the normal tolerances of channel fabrication, processing temperature distribution and plastic melt property variations. The effect of such a maldistribution is shown in Fig. 4 where the core annular layer IA is biased away from the mean diameter of the annular channel. The three streamlines IAI, IA2, IA3, in Fig. 33 correspond to the three points of the core annular layers shown in Fig. =4 as IAI, (A2, IA3. The maximum velocity difference between points on the core leading edge is that between streamlines IAI and IA2. It can be shown that the leading edge tape is calculated by the following equation:
WO 98/13187 PCTIIB96/01369 _ c"~= aV X ~
where o,P = leading edge taper o V = difference in velocity / V
L = total length of combined flow For the aforementioned maldistribution, o V=V~ V~ = 1.44V-1.36V=0.08V
1 o L = 75mm for the example shown in Fg. 1 i therefore, ~ .~ = 6 mm ~ as shown in Fg. 11.
WO 98/13187 PCT/iB96/01369 _ Since perfect annular flow is not realistically possible as discussed, the effect of a 10°h maldistribution as shown in Fig. 6 where the core layer is biased away from the mean diameter of flow will result in the flow with a high and low velocity of the core leading edge corresponding to IA'1 and IA'3 of Fig. 6 and Fig. 34. Using the previous calculations, the difference of 0.53 V between the high and low velocities of the leading edge will produce a 39.8 mm taper in the cavity, as shown in Fig. 12, if the length of the cylindrical channel is 75 mm between the combination area and the cavity side of the gate. This magnitude is nearly a factor of 10 larger than the minimal acceptable taper in most applications.
Obviously, prior art required that the cooling of the mold cavity be compromised in order to shorten the length of the combined flow. To achieve the same taper of 6 mm as shown in Fig. 11, the prior art length of flow must be about 11 mm for the maldistribution of 10°h. This length is about what is used in existing molding systems.
WO 98!13187 PCTIIB96/01369 _ A leading edge taper of 6 mm is about the maximum acceptable taper for a core layer used as a gas barrier layer in PET container preforms. Thus, an annular combined flow downstream of the combining means allows up to 75 mm length between the area of combination and the gate into the cavity. This allows normal amount of mold cooling to be built around the gate area of the mold.
Fig. 34, is the velocity profile and volumetric fraction for circular flow channels that are used in prior art between the area of combination and the gate into the cavity. The wall of the flow channel is represented 10 by -100~/~ and +100~J~ on the horizontal axis. The mean diameter of flow, i. e. 50~l~ of flow volume flows within this diameter and 50~/~ flows between this diameter and the wall of the channel, is shown as IA' in Fig.
5 and Fig. 34. For flows, wherein the core layer IA' flows between and inner cylindrical layer IL' that has the same volumetric flow rate as the 15 outer annular layer OL' of Fig. 5, the leading edge of the core layer will flow along a streamline on the mean diameter of flow. If the flow created by the combining means is perfectly annular, there will be no taper of the core leading edge when the leading edge exits the gate into the cavity.
Objects of Invention An object of the present invention is to provide a new and improved method of and apparatus for co-extrusion that shall not be subject to the above and other disadvantages of the prior art, but that, to the contrary, through a radically different conversion of the nozzle to a throttle-control extruder, provides for significantly improved, more uniform and more flexible operation.
Another object is to provide a novel extrusion apparatus in which a combined flow is produced having a velocity profile within and downstream of the area of combination of the extrusion materials which has a substantially zero gradient of velocity across the leading edge of the core (interior) layer, such velocity profile enabling the leading edge of the core (interior) layer to not become tapered, as in prior art nozzles, as it flows from the area of combination to the cavity end of the mold gate.
Still another object of the invention is to provide a novel apparatus in which the combining means is remote from the gate area of the nozzle so that mold design and mold cooling are not compromised.
A further object is the achievement of such novel results through radically converting prior art cylindrical nozzles designs into an extruder structure containing throttle or restrictor needles, rods or stems that force annular extrusion;
and, in the case of inner core molding, create concentric outer and inner annular extrusion streams, with the core-forming annular stream encased within annular co-extruded outer and inner stream layers.
A further object is to provide such a novel extruder in which a gate vestige is left on the molded part which is as small as that which can be obtained by single material molding systems.
An additional object of the invention is to provide a novel co-extrusion method and apparatus wherein the velocity profile of the combined stream of the plastic materials downstream of the combining area is made substantially the same as the velocity profile of the combined stream in the cavity, so that improved part properties and improved cycle times are possible.
Other and further objects will be explained hereinafter and are more particularly delineated in the appended claims.
Summary of The Invention In summary, however, from one of its broader aspects, the invention embraces a 5 method of co-extruding multiple plastic materials as for injecting through a gate region into a mold cavity to produce a molded product, that comprises: combining streams of such flowing plastic materials with at least one internal stream that is to serve as an interior core of a resulting molded plastic product within internal and outer streams of plastic material to serve as covering plastic material layers; restricting the combined streams to flow along concentric annular flow paths within and along a longitudinally extending tubular flow channel to the cavity gate region, with the annular core stream encased by inner and outer annular covering plastic material stream layers at the gate region; and splitting the concentric annular streams along opposite transverse directions to inject into corresponding opposite transverse sections of the cavity.
Preferred and best mode embodiments and apparatus designs for practising the novel method of the invention are hereinafter more fully described.
WO 98/13187 PCT/1896101369 _ Brief Description of The Drawings The invention will now be described in connection with the accompanying drawings, Fig. 1 of which shows a cross-section of a complete system including source of materials, material distribution and combination system and mold cavity;
Fig. 2 is a cross-section of flow from the material combination area to the mold cavity, showing that the core (interior) layer flows along the zero-gradient of the velocity profile in accordance with the technique and construction of the present invention;
Fig. 3 illustrates in cross-section the annular flow channel of this construction, also showing the core (interior) layer along the zero-gradient of the velocity profile;
Fig. 4 is a cross-sectional view of an annular flow channel as in Fig. 3, but with maldistributed outer and inner annular flow layers causing the core (interior) layer to be offset from the median of the annular diameters;
Fig. 5 presents a cross-section of prior art cylindrical flow showing the core (interior) layer in an area of high gradient of velocity, to contrast from the conditions of the invention as presented in Figs. 3 and 4;
Fig. 6 is similar to Fig. 5 but shows prior art cylindrical flow with maldistributed outer and inner layers;
WO 98/13187 PCT/IB96/01369 _ Fig. 7 is a cross-sectional view showing velocity profiles of core (interior) layer in annular flow nozzle area, annular flow gate area and cavity;
Fig. 8 is similar to Fig. 7, showing, however, the effect of maldistributed outer and inner layer flow on the relative position of leading edge of the core (interior) layer in the mold cavity;
Figs. 9 and 10 are views similar to respective Figs. 7 and 8, but showing prior art cylindrical flow in nozzle gate and cavity;
Fig. I 1 is a cross-sectional view of a molded part formed by the structure of the invention, showing the amount of leading edge taper caused by annular flow length in Fig. 8 of 75 mm from combination area to cavity side of gate, when the inner and outer maldistribution is 10%;
Fig. 12 is a view similar to Fig. 11 but of a molded part made by the prior art cylindrical nozzle structure, Fig. 10, showing the amount of leading edge taper caused by cylindrical flow inner and outer maldistribution of 10%;
Fig. 13 is a cross-section of a modified extruder constructed in accordance with the invention and in which the flow from the manifold is through a flat disc combining means with a fixed throttle valve means, through the annular flow nozzle and gate into the cavity;
WO 98/13187 PCT/1B96/01369 _ Fig. 14 is a cross-sectional view of a further modification in which an axial combining means is provided and with a fixed throttle valve means as part of the nozzle itself;
Fig. 15 is a more complete cross-section of the axial combining means with the fixed throttle valve means of Fig. 14, being a cross-sectional view of a combing means consisting of 3 concentric axial cylinders around a central fixed throttle valve means which extends through the combination area, through the separate nozzle and through the gate into the mold;
Fig. l6 is a view similar to Fig. 13, but showing a moveable throttle valve means;
Fig. 17 is an enlarged cross-section of the combining means and moveable throttle valve of Fig. 16;
Figs. 18 and 19 are annular to Fig. 17, showing the valve in a neutral position, with throttle positions for reduced and increased inner layer flow rates, respectively;
Fig. 20 illustrates, on an enlarged scale, the relative locations of the nozzle end and gate into the cavity wherein the throttle valve maintains the desired annular flow to the cavity;
WO 98/13187 PCT/1896/01369 _ Fig. 21 is similar to Fig. 20, but provides a conical valve corresponding to a conical gate to produce a reduced gate mark on the molded part;
Fig. 22 is again similar to Fig. 20, but the throttle valve is terminated prior to the gate to allow molding of plastics that require an open gate;
Fig. 23 is once more similar to Figs. 20 and 22 but the throttle valve is adjusted to act as a gate valve, shown in the open position; whereas in Fig.
24, it is shown in the closed position;
Fig. 25 is a cross-section of the nozzle end of the invention, the gate and a partially filled cavity, showing outer layers and core (interior) layer operated at the same temperature; whereas in Fig. 26, the outer layers are injected at a much higher temperature than the core (interior) layer;
Figs. 27 (a)-(d) show the fill sequence for a core (interior) layer that is uniformly distributed throughout the molded part;
Figs. 28 (a)-(d) are similar to Figs. 27(a)-(d) but show a fill sequence for a core (interior) layer wherein the maximum amount of core is injected into the molded part using a fixed throttle valve;
Figs. 29 (a)-(d) again are similar to Figs. 27 and 28, but show the fill sequence for a core (interior) layer wherein the maximum amount of core is injected into the molded part using a combining means designed to produce an WO 98/13187 PCT/>B96/01369 _ outer layer tlow at a greater rate relative to the inner annular layer to effect a thicker outer layer on the gate side of the molded part; while Fig. 30 shows the reverse;
Fig. 31 is a cross-section of the gate and cavity area, showing the fill sequence using a moveable throttle valve, increasing the inner annular layer flow relative to the outer annular layer during the flow shown in Fig. 3 I (b), thereby injecting more core (interior) layer material into the gate-side of the molded part;
Fig. 32 is a cross section of the gate and cavity area showing the fill sequence wherein the throttle valve moves to decrease the inner annular layer flow relative to the outer annular layer (l. e. the opposite relative flow to Fig.
31 ) during the flow shown in Fig. 32(B), thereby injecting more core (interior) layer material into the molded part side opposite the gate;
Fig. 33 is a graph plotting velocity/average velocity and flow fraction in the annular channel and cavity; and Fig. 34 is a graph plotting velocity/average velocity and flow fraction in a prior cylindrical channel for comparison with the results of Fig. 33.
Preferred Embodiment(sl of Invention Referring to Fig. I, and in the exemplary context of the invention as applied to plastic, (such as PET, EVOH, polycarbonates and the like) co-injection molding systems adapted to inject at least two materials into a cavity of a mold, the system comprises respective sources S1 and SZ for each material, a means, such as a manifold D, for delivering each material stream to a combining means C upstream of each gate of the mold, and a novel throttle valve controlling extruder nozzle means E for delivering the combined stream to the gate into the mold M. The sources S, and Sz for each material are shown as reciprocating screw injection units; the means for delivering the material streams is a manifold block D with respective separate flow channels Cl and CZ for each material arranged such that the flow is balanced and equal to each; the combining means C is disposed upstream of the throttle nozzle means E with its internal co-extensive throttle needle T which delivers the combined stream to each gate region G of the mold M. In the embodiments disclosed herein, Fig. 2, the streams forming each layer L of the molded product are combined in an annular channel A of the combining means C so that the leading edge of the core (interior) layer I is disposed in the zero velocity gradient portion of the combined flow stream, as later more fully explained. The longitudinally extending-extruder nozzle means E with its central longitudinal throttle needle or flow restrictor T downstream of the combining means C
provides an uninterrupted continuation of the annular flow developed in the combining means.
l2 In the three-layer combined flow stream embodiment of Fig. 2, two materials L and I are provided, each from its own source; the first material L, which forms the outer or covering layers OL, and IL, of the molded part, forms the inner and outer layers Ol and LL of the annular flow combined stream at A, formed by the presence of the central throttle T; the second material I, which forms the core (interior) layer I, of the molded part, forms the middle or inner or interior annular layer IA of the annular flow combined stream A. The first material L is delivered through its flow channel to the combining means C wherein it is divided from a single stream into two streams, one forming the aforesaid inner annular layer IL of the combined annular flow stream and the other forming the aforesaid outer annular layer OL. The second material I is delivered through its flow channel to the combining means C wherein it is disposed to form the middle or interior annular layer IA of the concentric annular flow combined streams, as also shown in the annular flow channel cross section of Fig. 3. Preferably, as shown, the throttle needle or central restrictor is of reduced diameter T' at the extruder opening distal end at the cavity gate injection end of the nozzle.
The nozzle means thus has an internal bore which surrounds the throttle valve pin to form an annular channel to deliver the combined flow stream to the gate while maintaining the aforesaid velocity profile. By disposing the core (interior) layer material to be in the zero gradient of the velocity profile VP,, the leading edge of the core (interior) layer does not become tapered regardless of the axial flow distance between the combining means and the gate into the cavity. The nozzle axial length, unlike in prior art nozzles, can accordin~~,.ly be made as long as required to provide for good mold cooling. The outermost diameter of the nozzle is typically no larger than that required for single-material molding, thereby not compromising mold design or mold cooling. This embodiment, moreover, also makes it easier to convert a mold designed for single-material molding to be used for co-injection. At the gate region G adjacent the proximal distal end of the restrictor or throttle needle, rod or element T', the annular flow streams are laterally split and flow is injected in opposite directions transversely into the corresponding opening sections of the mold cavity, as shown by the arrows in Fig.
2.
In this and later-described embodiments that dispose the material forming the core (interior) layer of the molded part to be the middle layer of the combined flow stream, a part can be readily molded with its core (interior) layer at a melt temperature that is lower than the outer layers of the molded part. In single layer molding, on the other hand, the temperature of the material as provided at its source must be high enough 1 ) to lower its viscosity for ease of flow between the t-t walls of the injection cavity and 2) to produce a good cosmetic appearance on the outer surfaces of the molded part. Because the material of a single layer molded part is provided by a single material source, the temperature of its interior layer will be the temperature needed for ease of cavity flow and surface appearance, and the cooling time needed to cool the interior of the molded part is dependent on the melt temperature provided by the source. Using the present invention, however, the core (interior) layer can be provided at a temperature much different than the temperature of the outer layer material, thereby producing several unexpected improvements compared to single layer molding. While some other prior art systems can also permit this effect, it is particularly simply and ei~tciently effected with the technique and construction of the invention.
Improvements that can be produced by providing the outer layers at normal or higher than normal temperature and the core (interior) layer at a correspondingly lower temperature include:
1 ) cavity fill pressure will be lower because the outer layer viscosity will be lower than normal;
Z) part surface appearance will be improved because of the hotter outer layer melt temperature;
3) cooling time, and thereby cycle time, will be reduced if the relative increase in outer layer melt temperature is less than the corresponding core (interior) layer melt temperature decrease, such that the total heat content of the combined melt is less than normal for a single-material molding;
5 4) an increased core (interior) layer melt viscosity will increase the core (interior) layer volume relative to a decreased outer layer volume if that is a desirable property of the molded part; and 5) a core (interior) layer material can be used that has a higher coefficient of thermal expansion than that of the outer layers without causing undue molded-in 1 0 stresses, etc.
Other improvements can be produced by providing differing relative melt temperatures of the core (interior) and outer layers materials. One such reason is to control relative shrinking between layers when the core (interior) layer has a different coefficient of thermal expansion than the outer layers material.
Another 15 reason is to produce parts that have lower molded-in stresses by using temperature differences to reduce relative shrinkage between the core (interior) and outer layers without affecting part surface cosmetic appearance.
Returning to the flow distribution illustrated in Figs. 2 and 3, the extruder structure of the present invention can accommodate for maldistributed or t6 unsymmet~cal outer and inner annular flow layers that, as shown in Fig. 4, may cause the core (interior) annular layer IA to be offset from the median of the annular diameters of the encasing inner and outer layers IL and OL. From the velocity profile VP,' of Fig. 4, it will be observed that the core, though offset, is none-the-less close to the zero gradient velocity profile, still enabling improved results. This is to be contrasted from the cylindrical flows in prior art nozzles E', shown in Figs. 5 and 6, for symmetrical and unsymmetrical conditions, and wherein the core layer is subjected to areas of high gradient of velocity in the profiles VP," and VP,"', with the attendant limitations and disadvantages 1 0 previously discussed.
In the throttled or centrally restricted co-extruder of Fig. 7, wherein the extruder E is shown connected to an annular flow gate G' and cavity, the velocity profiles of the annular core layer IA in the annular extruder area (VPz) and in the annular flow gate area (VP3) and in the cavity (VP3) are all presented, demonstrating the maintaining of zero gradient throughout the flow and cavity injection process of the invention. Substantially these benefits are also obtained in the event of misalignment or maldistribution of outer and inner layer flow, Fig. 8, with the erect illustrated of maldistributed outer and inner layer flow on the relative position D ~! of leading edge of the core (interior) layer in the mold cavity.
WO 98/13187 PCTlIB96/01369 Figs. 9 and 10 show prior art cylindrical nozzles corresponding, respectively, to the extruder of the invention shown in Figs. 7 and 8, and illustrate the undesirable high gradients of velocity for the flow of the core (interior) layer in the nozzle E' (VPz') and at the gate (VP3'), with zero gradient of the velocity profile attained only in the cavity (VP,, ).
Fig. 10 shows the development of the core leading edge taper caused by the effect of the velocity difference across the maldistributed core leading edge as it flows through extruder E'. As leading edge streamline IA' 1 flows at a higher velocity than 1A'3, 0 Q taper results by time the core enters the cavity through gate G'. Even though the core layer I, remains offset from the cavity flow centerline, the velocity difference across the tapered leading edge in the cavity remain small, so that the increase in 0 Q within the cavity is small compared to the OQ developed in the prior art extruder E'.
Further to contrast the significantly improved molding results and tolerances attainable with the annular flow construction of the invention with the prior art cylindrical nozzles, Fig. 11 illustrates the minimal acceptable amount of leading edge taper carried in a molded part for a 10% inner and outer flow maldistribution with the annular flow of the structure of the invention (Fig.
8) for an annular flow length of 75mm from combination area C to the cavity-side of the WO 98/13187 PCT/IB96/01369 _ l8 gate G; whereas Fig. 12 shows the much greater leading edge taper in the molded part that the art has had to accept with prior cylindrical flow nozzles for the same l0% maidistribution with a cylindrical flow length of 75mm from combination area to cavity-side of the gate (Fig. 10).
To achieve a minimal acceptable amount (6 to 6mm) of leading edge taper as shown in Fig. 11 when using prior art, the length of combined flow in the central channel from the area of combination to the surface of the molded part should not exceed about 11 mm if the maldistribution of inner and outer flow is as shown in Fig. 6 and Fig. 34. To provide for a minimal amount of mold cooling near the gate, the short length of the prior art central channel requires that the shape of the combining means be conical or ftustoconical. Such shape still requires the distal end of the nozzle to be nearly twice the outside diameter of a single-material nozzle, thus causing part cooling near the gate to be compromised.
Fig. 13 illustrates another embodiment of the invention wherein the three layer combining means consists of four flat discs FD surrounding a central fixed throttle valve pin T-T' which forms the inner flow channel wall for the inner layer of the combined flow stream. Flow channels C,', C~', etc. are created between the three mating planar surfaces of the discs FD uniformly to dispose each flow layer to produce a uniform flow of the respective material flowing from each channel l9 into the area of combination C, so that each layer of the combined flow stream is uniformly annularly disposed as it flows from the combining means through the extruding restricted or throttled nozzle means E and gate G into the cavity.
The manifold combining means may, moreover, be incorporated as part of the extruder nozzle structure itself as shown, for example, in Fig. 14, wherein axial combining channels C,", C2", etc. are provided at the top of the extruder E
itself, with a fixed throttle valve T extending along and within the extrusion nozzle.
Another embodiment (shown in Fig. 15) uses three concentric shells S,', SZ' and S;' surrounding a central throttle pin T which forms the inner flow channel wall for the inner layer of the combined flow stream. The flow channels created between the shells and between the innermost shell and throttle valve pin are designed to produce a uniform flow of the respective material flowing from each channel into the area of combination so that each layer of the combined flow stream is uniformly annularly disposed as it flows from the combining means through the nozzle means into the cavity. In this embodiment, the combining means C is a separate assembly sandwiched between the delivery manifold D and the extruder nozzle E. This allows the extruder nozzle to be identical in design as those used in single material molding. The combining means is coaxial with WO 98113187 PCT/IB96101369 _ 2() respect to the extruder nozzle so that the throttle pin T and the cylindrical wall of the extruder nozzle form a uniform annular channel A.
While the centrally longitudinally extending restrictors or throttle pins heretofore described have been shown as fixed, as, for example, in the embodiment of Fig. 13, they may also be made movable, as by an adjusting rod R, Fig. 16, for various useful throttle valuing or adjusting purposes, providing further flexibility not present in prior art cylindrical nozzles.
The moveable throttle or restrictor valve pin T-T' can vary the percentage of the outer layers material in the inner annular flow layer vs. the outer annular flow layer of the combined flow stream downstream of the combining area.
Changing the relative volumes of the outer layers shifts the position of the core (interior) layer in the mold cavity to produce a part with controlled outer layer thickness on both surfaces of the molded part. If the outer layer flow is evenly distributed between the inner annular flow layer and outer annular flow layer, the outer layer thickness will be similar on both surfaces of the molded part. if the outer layer flow is biased toward either the inner of outer annular flow layers, the outer layer thickness in the molded part will be similarly biased on the corresponding surface molded from the biased annular layers. Material from the inner annular flow layer forms the outer layer of the part molded by the cavity wall WO 98/13187 PCT/1896/01369 _ opposite the gate into the cavity, and the material from the outer annular flow layer forms the outer layer of the part molded by the cavity wall adjacent to the gate.
The use of a moveable throttle valve pin is typically appropriate in cases where it is advantageous to vary, during each injection, the relative percentage of the outer layers material in the inner annular flow layer vs. the outer annular flow layer. The moveable throttle pin is not used to initiate nor to terminate the flow of any material for any layer. For cases where the relative thickness of the outer layer on both surfaces of the molded part can remain in fixed proportion to each other, the embodiment uses a non-moving throttle valve pin.
In the enlarged views of Figs. 17, 18 and 19, the throttle valve T is shown positioned by the rod R in a neutral position with disc channels C,' , CZ', etc. open to balance inner layer flow with respect to the outer layer flow; in a lower position to reduce the inner layer flow rate with respect to the outer layer flow rate (Fig.
18); and in an elevated position, Fig. 19, to increase the inner layer flow rate with respect to the outer layer flow rate.
Turning, now, to the distal or gate end of the extruder nozzle structures, having adjustability of the position of the throttle pin, the position shown in Fig. 20 enables the throttle valve pin to maintain annular flow to the cavity as before described. To produce a reduced gate vestige height, the distal end of the throttle valve pin T' is conically further tapered at T" as it approaches the cavity end of the gate G, as in Fig. 21. The shape of this distal end with respect to the gate length, taper and diameter is of the same nature as that used to produce a reduced gate vestige height on single material molded parts, because the material in the gate area at the initiation and termination of each cycle is only outer layer material.
Some molding materials, however, such as PET (Polyethylene Terephtholate), require that the gate flow be cylindrical rather than annular.
In the embodiment of Fig. 22, adjusted for such materials, the throttle valve pin terminates at the end of the nozzle means so that cylindrical flow occurs only through the gate G, thereby minimizing the possible detrimental effects on the core (interior) layer leading edge.
To produce a zero gate height vestige, the moveable throttle valve pin may have a distaff end shaped with respect to the gate length, taper and diameter similar to those used to produce a zero gate vestige height in single material molding.
The throttle valve may be adjusted, furthermore, to serve also as a gate valve at the gate into cavity region, if desired; shown in open position in Fig. 23, and in closed position in Fig. 24.
It has earlier been mentioned that the novel structures of the present invention lend themselves to great flexibility in the use at similar or different temperatures. In the extrusion into the cavity shown in Fig. 25, similar to that of before-discussed Fig. 2, the system is illustrated as operated with the horizontally Bowing annular outer layers OL and IL containing encased therewithin the annular core (interior) layer IA, at the same melt temperature of, for example, about 500°F, for ABS type plastics, during transversely splitting in opposite lateral directions into the cavity, producing the same-temperature filling of the cavity of the outer layers, O L, and IL,, covering or encasing the core material I'. In Fig. 26, on the other hand, the system readily enables a cooler core material I', say 400°F, as for the reasons before explained, extruded and molded with hotter outer layers O
L., and IL,, of, say 500°F; and so on, for any desired variations depending on the plastic material properties and the desired molded effects.
It is next in order to examine the annularly extruded material filling sequence within the mold cavity for an inner core layer I (EVOH, for example), as shown in successive Figs. 27(a), (b), (c), and (d), demonstrating the remarkably uniform distribution attainable with the structures of the invention as the concentric annular plastic streams split on opposite sides of the throttle or restrictor element T' and inject into opposite sides of the mold cavity, (the relatively thick outer layers being of, for example, PET). In Figs. 28 (a), (b), (c) an (d), the same fill sequence is shown for the injection of a maximum amount of WO 98/13187 PCT/)(896101369 2~
core material I' in the molded part (polycarbonate, for example), this being achieved with a fixed throttle valve pin T', as shown, producing outer layer flow (recycled polycarbonate plastic, for example), equally distributed between inner and outer annular layers IL and OL.
The flexibility of the adjustable throttle structure of the invention is fixrther illustrated in Figs. 29(a)-(d), showing the cavity filling sequence again for a maximum amount of inner core material in the molded part, but using a throttle valve adjustment that produced an outer layer flow OL at a greater rate relative to the inner annular layer IL to effect a thicker outer layer OL on the gate side of the molded part (Fig. 29(d)), than the inner layer IL,. The operation in Figs. 30 (a)-(d) produces the reverse, with the layer IL,, thicker than the gate side layer OL, of the molded part (Fig. 30 (d)). The position of the moveable throttle pin R
shown in Fig. 20 will produce the increased OL and OL, of Fig. 29. The position of moveable throttle pin shown in Fig. 19 will produce the increased IL and IL, of Fig. 3d. For embodiments using a fixed throttle pin, for example T of Fig. 15, the relative thickness difference of OL, and IL,, can be created by appropriate corresponding design of combining means channels C,' and C3' of Fig. 13 and C,"
of Figs. 14 and 15.
Figs. 31 (a)-(d) and 32 (a)-(d) are similar cross-sectional sketches of the cavity filling sequences using a moveable throttle valve element, respectively increasing the inner annular layer flow and the outer annular layer flow for injecting more core (interior) layer I' into the gate side and opposite the gate side, 5 respectively, of the molded part.
An adjustment of the relative flow rate of OL, iA and IL occurs during each extrusion. The relative volumes and flow rates of core layer and covering layers is controlled by S, and Sz, while the relative flow rates between the covering layers is controlled by adjustment of moveable throttle R of Fig. 17, for example.
10 During each extrusion, S,, Sz and R are controlled to produce a core layer I' that has a leading edge LE, that is flowing along a streamline which has a V /V
that prevents LE, from breaking through the flow front FF of the covering layers.
After the FF has progressed further into the cavity away from the gate G, the rate of flow of core layer IA is increased relative to the flow of covering layers OL and 15 IL and the relative flow rates of OL and IL are adjusted closer to a neutral position of R such that a core leading edge LEz is created long the maximum velocity streamline of the cavity. LEz flowing at a higher velocity than LE, will penetrate shallower, the same or deeper into the cavity than LE, depending on the timing of the adjustment of Si, Sz and R during the extrusion. The moveable throttle pin allows the creation of LE, before creation of LEz, thus more core layer volume can be injected into a cavity than in prior art which can create only one core leading edge in each extrusion cycle.
A comparison of the flow fraction and velocity profile plots of Figs. 33 and 34, for the throttled annular channel flow of the invention and of the prior art cylindrical channel, respectively, graphically demonstrates the significantly improved characteristics attained by the invention Fig. 33 is the velocity profile Vp = V / V and volumetric fraction of the annular flow between the channel formed by the throttle valve pin and the cylindrical wall of the extruder body, represented by -50% and +50%, respectively, on the horizontal axis of the graph. The mean diameter of flow is represented as the ''0" on the horizontal axis. The velocity profile and flow fraction is based on the Power Lw model for non-Newtonian fluids (Ref. J. S. Brydson, low Proyerties of Polvme~r Melts, second edition, George Godwin Limited in association with the Plastics and Rubber Institute).
If the design and construction of the channels C,', Cz', etc., as shown in Fig. 13, etc., in the combining means produces perfectly annular flow of the inner and outer annular layers, the core leading edge streamline will be centered on the mean diameter of flow, and thus is has a velocity Vm equal to I .44 x the average velocity V of the combined annular flow.
In actual equipment constriction and operation, the annular distribution of the inner and outer annular layers is not perfect, and a l0% maldistribution is not unexpected within the normal tolerances of channel fabrication, processing temperature distribution and plastic melt property variations. The effect of such a maldistribution is shown in Fig. 4 where the core annular layer IA is biased away from the mean diameter of the annular channel. The three streamlines IAI, IA2, IA3, in Fig. 33 correspond to the three points of the core annular layers shown in Fig. =4 as IAI, (A2, IA3. The maximum velocity difference between points on the core leading edge is that between streamlines IAI and IA2. It can be shown that the leading edge tape is calculated by the following equation:
WO 98/13187 PCTIIB96/01369 _ c"~= aV X ~
where o,P = leading edge taper o V = difference in velocity / V
L = total length of combined flow For the aforementioned maldistribution, o V=V~ V~ = 1.44V-1.36V=0.08V
1 o L = 75mm for the example shown in Fg. 1 i therefore, ~ .~ = 6 mm ~ as shown in Fg. 11.
WO 98/13187 PCT/iB96/01369 _ Since perfect annular flow is not realistically possible as discussed, the effect of a 10°h maldistribution as shown in Fig. 6 where the core layer is biased away from the mean diameter of flow will result in the flow with a high and low velocity of the core leading edge corresponding to IA'1 and IA'3 of Fig. 6 and Fig. 34. Using the previous calculations, the difference of 0.53 V between the high and low velocities of the leading edge will produce a 39.8 mm taper in the cavity, as shown in Fig. 12, if the length of the cylindrical channel is 75 mm between the combination area and the cavity side of the gate. This magnitude is nearly a factor of 10 larger than the minimal acceptable taper in most applications.
Obviously, prior art required that the cooling of the mold cavity be compromised in order to shorten the length of the combined flow. To achieve the same taper of 6 mm as shown in Fig. 11, the prior art length of flow must be about 11 mm for the maldistribution of 10°h. This length is about what is used in existing molding systems.
WO 98!13187 PCTIIB96/01369 _ A leading edge taper of 6 mm is about the maximum acceptable taper for a core layer used as a gas barrier layer in PET container preforms. Thus, an annular combined flow downstream of the combining means allows up to 75 mm length between the area of combination and the gate into the cavity. This allows normal amount of mold cooling to be built around the gate area of the mold.
Fig. 34, is the velocity profile and volumetric fraction for circular flow channels that are used in prior art between the area of combination and the gate into the cavity. The wall of the flow channel is represented 10 by -100~/~ and +100~J~ on the horizontal axis. The mean diameter of flow, i. e. 50~l~ of flow volume flows within this diameter and 50~/~ flows between this diameter and the wall of the channel, is shown as IA' in Fig.
5 and Fig. 34. For flows, wherein the core layer IA' flows between and inner cylindrical layer IL' that has the same volumetric flow rate as the 15 outer annular layer OL' of Fig. 5, the leading edge of the core layer will flow along a streamline on the mean diameter of flow. If the flow created by the combining means is perfectly annular, there will be no taper of the core leading edge when the leading edge exits the gate into the cavity.
Claims (29)
1. A method of co-extruding multiple plastic materials as for injecting through a gate region into a mold cavity to produce a molded product, that comprises:
combining streams of such flowing plastic materials with at least one inner stream that is to serve as an interior core of a resulting molded plastic product within inner and outer streams of plastic material to serve as covering plastic material layers; restricting the combined streams to flow along concentric annular flow paths within and along a longitudinally extending tubular flow channel to the cavity gate region, with the annular core stream encased by inner and outer annular covering plastic material stream layers at the gate region; and splitting the concentric annular streams along opposite transverse directions to inject into corresponding opposite transverse sections of the cavity.
combining streams of such flowing plastic materials with at least one inner stream that is to serve as an interior core of a resulting molded plastic product within inner and outer streams of plastic material to serve as covering plastic material layers; restricting the combined streams to flow along concentric annular flow paths within and along a longitudinally extending tubular flow channel to the cavity gate region, with the annular core stream encased by inner and outer annular covering plastic material stream layers at the gate region; and splitting the concentric annular streams along opposite transverse directions to inject into corresponding opposite transverse sections of the cavity.
2. A method as claimed in Claim 1 and in which the restricting is effected by inserting a throttle pin longitudinally extending centrally within and along the flow channel toward a distal end opening at the gate region.
3. A method as claimed in Claim 2 and in which the throttle pin is fixed in position.
4. A method as claimed in Claim 2 and in which the throttle pin is longitudinally movably adjustable to vary the positions of the distal end of the pin and the gate region opening.
5. A method as claimed in Claim 2 and in which the flow is adjusted so that the annular interior core layer flows along a path of substantially zero gradient of the flow velocity profile transversely of the flow channel.
6. A method as claimed in Claim 5 and in which the flow through the gate region and within the cavity is adjusted to maintain the path of the interior core layer at substantially zero gradient of the transverse flow velocity profile therein.
7. A method as claimed in Claim 1 and in which the temperatures of the flowing core and outer and inner plastic streams are adjusted to substantially the same value within the cavity.
8. A method as claimed in Claim 1 and in which the temperatures of the flowing core and outer and inner plastic steams are adjusted to different values within the cavity.
9. A method as claimed in Claim 8 and in which the core plastic stream temperature is adjusted to a value lower than the outer and inner plastic stream temperatures.
10. A method as claimed in Claim 2 and in which the combining of the streams is effected by flowing along successive passage between parallel planes.
11. A method as claimed in Claim 4 and in which the throttle pin is tapered at its distal end.
12. A method as claimed in Claim 1 and in which the flow is adjusted to provide more or less flow for the inner stream relative to the outer stream.
13. A method as claimed in Claim 2 and in which the annular flows are confined along the flow channel between concentric cylindrical shells.
14. Apparatus for co-extruding multiple plastic materials as for injecting through a gate region into a mold cavity to produce a molded product, having, in combination:
plastic material flowing stream sources; means for combining streams of such flowing plastic materials with at least one inner stream that is to serve as an interior core of a resulting molded plastic product within inner and outer streams of plastic material to serve as covering plastic material layers; a longitudinally extending flow channel connected to the combining means to receive the outer and inner streams; flow restrictor means disposed within and along the flow channel to force the combined streams to flow along concentric annular flow paths within and along a longitudinally extending tubular extruder flow channel to the cavity gate region, with the annular core stream encased by the inner and outer annular covering plastic material stream layers; and means disposed at the gate region for splitting the concentric annular streams along opposite transverse directions to inject into corresponding opposite transverse sections of the cavity.
plastic material flowing stream sources; means for combining streams of such flowing plastic materials with at least one inner stream that is to serve as an interior core of a resulting molded plastic product within inner and outer streams of plastic material to serve as covering plastic material layers; a longitudinally extending flow channel connected to the combining means to receive the outer and inner streams; flow restrictor means disposed within and along the flow channel to force the combined streams to flow along concentric annular flow paths within and along a longitudinally extending tubular extruder flow channel to the cavity gate region, with the annular core stream encased by the inner and outer annular covering plastic material stream layers; and means disposed at the gate region for splitting the concentric annular streams along opposite transverse directions to inject into corresponding opposite transverse sections of the cavity.
15. Apparatus as claimed in Claim 14 and in which the flow restrictor means comprises a throttle pin longitudinally extending centrally within and along the flow channel toward a distal end opening at the gate region.
16. Apparatus as claimed in Claim 15 and in which the throttle pin is fixed in position.
17. Apparatus as claimed in Claim 15 and in which the throttle pin is longitudinally movably adjustable to vary the positions of the distal end of the pin and the extruder gate region opening.
18. Apparatus as claimed in Claim 15 and in which means is provided for adjusting the flow so that the annular interior core layer flows along a path of substantially zero gradient of the flow velocity profile transversely of the flow channel.
19. Apparatus as claimed in Claim 18 and in which the flow through the gate region and within the cavity is adjusted to maintain the path of the interior core layer at substantially zero gradient of the transverse flow velocity profile therein.
20. Apparatus as claimed in Claim 14 and in which means is provided for adjusting the temperatures of the flowing core and the outer and inner plastic streams are adjusted to substantially the same value within the cavity.
21. Apparatus as claimed in Claim 14 and in which the temperatures of the flowing core and outer and inner plastic streams are adjusted to different values within the cavity.
22. Apparatus as claimed in Claim 21 and in which the core plastic stream temperature is adjusted to a value lower than the outer and inner plastic stream temperatures.
23. Apparatus as claimed in Claim 17 and in which the combining of the streams is effected by flowing along successive passage between parallel planes.
24. Apparatus as claimed in Claim 15 and in which the throttle pin is tapered at its distal end.
25. Apparatus as claimed in Claim 14 and in which the flow is adjusted to provide more or less flow for the inner stream relative to the outer stream.
26. Apparatus as claimed in Claim 15 and in which the annular flows are confined along the flow channel between concentric cylindrical shells therein.
27. Apparatus as claimed in Claim 18 and in which the core layer does not flow in the zero gradient path just upstream and through the gate region.
28. Apparatus as claimed in Claim 18 and in which the throttle pin terminates just upstream on the cavity side of the gate region.
29. Apparatus as claimed in Claim 18 and in which means is provided for adjusting the flow to provide a core layer leading edge flowing along the zero gradient before or after another layer leading edge flows offset from the zero gradient path.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/720,385 US5914138A (en) | 1996-09-27 | 1996-09-27 | Apparatus for throttle-valving control for the co-extrusion of plastic materials as interior core streams encased by outer and inner streams for molding and the like |
| US720,385 | 1996-09-27 | ||
| PCT/IB1996/001369 WO1998013187A1 (en) | 1996-09-27 | 1996-12-06 | Method of throttle-valving control for the co-extrusion of plastic materials as for molding and the like, and apparatus therefor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2266381A1 CA2266381A1 (en) | 1998-04-02 |
| CA2266381C true CA2266381C (en) | 2006-08-01 |
Family
ID=24893822
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002266381A Expired - Fee Related CA2266381C (en) | 1996-09-27 | 1996-12-06 | Method of throttle-valving control for the co-extrusion of plastic materials as for molding and the like, and apparatus therefor |
Country Status (20)
| Country | Link |
|---|---|
| US (2) | US5914138A (en) |
| EP (1) | EP0929390B1 (en) |
| JP (1) | JP3544992B2 (en) |
| KR (1) | KR100443136B1 (en) |
| CN (1) | CN1082875C (en) |
| AU (1) | AU719376B2 (en) |
| BR (1) | BR9612791A (en) |
| CA (1) | CA2266381C (en) |
| CZ (1) | CZ292815B6 (en) |
| DE (1) | DE69622763T2 (en) |
| DK (1) | DK0929390T3 (en) |
| ES (1) | ES2183015T3 (en) |
| HK (1) | HK1023308A1 (en) |
| HU (1) | HU222153B1 (en) |
| IL (1) | IL129069A (en) |
| PL (1) | PL182365B1 (en) |
| PT (1) | PT929390E (en) |
| RU (1) | RU2175288C2 (en) |
| SK (1) | SK40499A3 (en) |
| WO (1) | WO1998013187A1 (en) |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6062840A (en) | 1997-09-02 | 2000-05-16 | Dynisco Hotrunners, Inc. | Hot runner system for coinjection molding |
| US6352426B1 (en) | 1998-03-19 | 2002-03-05 | Advanced Plastics Technologies, Ltd. | Mold for injection molding multilayer preforms |
| TWI250934B (en) | 1997-10-17 | 2006-03-11 | Advancsd Plastics Technologies | Barrier-coated polyester articles and the fabrication method thereof |
| CA2219257C (en) * | 1997-10-23 | 2005-05-31 | Mold-Masters Limited | Sprue gated five layer injection molding apparatus |
| US6562276B1 (en) * | 1998-08-20 | 2003-05-13 | Eastman Chemical Company | Process for forming a multilayer, coinjected article |
| AU3184800A (en) * | 1999-03-18 | 2000-10-04 | Mold-Masters Limited | Apparatus and method for multi-layer injection molding |
| US6440350B1 (en) * | 1999-03-18 | 2002-08-27 | Mold-Masters Limited | Apparatus and method for multi-layer injection molding |
| US6655945B1 (en) | 1999-03-18 | 2003-12-02 | Mold Masters Limited | Apparatus and method for multi-layer injection molding |
| EP1315608A1 (en) | 2000-09-05 | 2003-06-04 | Advanced Plastics Technologies, Ltd | Multilayer containers and preforms having barrier properties utilizing recycled material |
| US6908581B2 (en) * | 2001-04-06 | 2005-06-21 | Kortec, Inc. | Optimized flow to prevent core layer breakthrough |
| US20030161977A1 (en) * | 2001-04-06 | 2003-08-28 | Douglas Sabin | Four layer nozzle for forming four layer articles |
| US6596213B2 (en) * | 2001-04-06 | 2003-07-22 | Kortec, Inc. | Method of molding multi-layer polymer plastic articles with control of relative shifting of the core layer |
| KR20040014560A (en) * | 2001-06-18 | 2004-02-14 | 벡톤 디킨슨 앤드 컴퍼니 | Multilayer containers and process for forming multilayer containers |
| US6649101B2 (en) * | 2001-07-31 | 2003-11-18 | Kortec, Inc. | Method for using a sprue to reduce the size of a core layer hole in an injection molding process by terminating an injection stream within the sprue |
| EP1478501A1 (en) * | 2002-01-31 | 2004-11-24 | Kortec, Inc. | Optimized flow to prevent core layer breakthrough |
| WO2003064134A1 (en) * | 2002-02-01 | 2003-08-07 | Kortec, Inc. | Four layer nozzle for forming four layer articles |
| WO2004043675A1 (en) * | 2002-11-08 | 2004-05-27 | Advanced Plastics Technologies Ltd | Injection mold having a wear resistant portion and a high heat transfer portion and a method for forming a preform |
| US7306446B2 (en) * | 2003-05-21 | 2007-12-11 | Kortec, Inc. | Co-injection nozzle with improved interior layer termination |
| US7517480B2 (en) * | 2003-08-18 | 2009-04-14 | Kortec, Inc. | Automatic process control for a multilayer injection molding apparatus |
| US20050136201A1 (en) * | 2003-12-22 | 2005-06-23 | Pepsico, Inc. | Method of improving the environmental stretch crack resistance of RPET without solid stating |
| US20050221036A1 (en) * | 2004-04-01 | 2005-10-06 | The Coca-Cola Company | Polyester composition with enhanced gas barrier, articles made therewith, and methods |
| ES2321421T3 (en) | 2004-04-16 | 2009-06-05 | Advanced Plastics Technologies Luxembourg S.A. | REFORM AND PROCEDURES FOR MANUFACTURING THE PREFORM AND A BOTTLE. |
| CA2573139C (en) * | 2004-07-07 | 2015-08-25 | Kortec, Inc. | Multilayer molding using temperature adjustment of flow rate in conjunction with shooting pot technology |
| US8545952B2 (en) * | 2005-06-07 | 2013-10-01 | The Coca-Cola Company | Polyester container with enhanced gas barrier and method |
| US20070020416A1 (en) * | 2005-07-22 | 2007-01-25 | Dean David M | Blow molded hollow articles and bottles made from trivalent cation neutralized ionomers |
| MX2008002479A (en) | 2005-08-30 | 2008-04-07 | Advanced Plastics Technologies | Methods and systems for controlling mold temperatures. |
| US7820258B2 (en) * | 2005-10-05 | 2010-10-26 | The Coca-Cola Company | Container and composition for enhanced gas barrier properties |
| US7765949B2 (en) * | 2005-11-17 | 2010-08-03 | Palo Alto Research Center Incorporated | Extrusion/dispensing systems and methods |
| US8124202B2 (en) * | 2006-09-15 | 2012-02-28 | The Coca-Cola Company | Multilayer container for enhanced gas barrier properties |
| US7790077B2 (en) * | 2006-09-15 | 2010-09-07 | The Coca-Cola Company | Pressurized tooling for injection molding and method of using |
| PL2014562T3 (en) * | 2007-07-12 | 2011-11-30 | Superfos As | Method of manufacturing a packaging article having IML barrier film in combination with an oxygen scavenger |
| FR2948056B1 (en) | 2009-07-16 | 2011-07-22 | Outinov | SYSTEM FOR INJECTING A MULTI-LAYER MOLDED ARTICLE |
| FI20096328A (en) * | 2009-12-15 | 2011-06-16 | Fiskars Brands Finland Oy Ab | Procedure for the manufacture of hand tool handles and hand tool handles |
| JP5906199B2 (en) * | 2010-03-08 | 2016-04-20 | コルテック，インコーポレーテッド | Molding method of multilayer polymer product for controlling breakthrough of core layer |
| GB2478732B (en) | 2010-03-15 | 2014-08-20 | Kraft Foods R & D Inc | Improvements in injection moulding |
| RU2570053C2 (en) | 2010-04-23 | 2015-12-10 | Мицубиси Гэс Кемикал Компани, Инк. | Multiply container, mould for said container and its production process |
| EP2593285B1 (en) * | 2010-07-16 | 2019-03-13 | Milacron LLC | Improved gas impermeability for injection molded containers |
| EP3453511B1 (en) | 2010-09-21 | 2020-09-16 | Mold-Masters (2007) Limited | Coinjection hot runner injection molding system |
| US9498911B2 (en) | 2010-09-21 | 2016-11-22 | Mold-Masters (2007) Limited | Coinjection hot runner injection molding system |
| PT2643136T (en) | 2010-11-24 | 2018-07-03 | Milacron Llc | Heat-seal failure prevention method |
| WO2013028933A1 (en) * | 2011-08-23 | 2013-02-28 | Kortec, Inc. | Methods and systems for the preparation of molded plastic articles having a structural barrier layer |
| WO2013040096A1 (en) | 2011-09-12 | 2013-03-21 | E. I. Du Pont De Nemours And Company | Low pearlescence compositions |
| US9073246B2 (en) | 2011-09-21 | 2015-07-07 | Mold-Masters (2007) Limited | Coinjection hot runner injection molding system |
| US8491290B2 (en) | 2011-10-21 | 2013-07-23 | Kortec, Inc. | Apparatus for producing non-symmetric multiple layer injection molded products |
| US9221204B2 (en) | 2013-03-14 | 2015-12-29 | Kortec, Inc. | Techniques to mold parts with injection-formed aperture in gate area |
| EP2969463B1 (en) | 2013-03-14 | 2020-10-21 | Milacron LLC | Individual cavity flow control method and system for co-injection molding |
| US9701047B2 (en) | 2013-03-15 | 2017-07-11 | Milacron Llc | Methods and systems for the preparation of molded plastic articles having a structural barrier layer |
| EP3019321A4 (en) * | 2013-07-12 | 2017-03-29 | Plastipak Packaging, Inc. | Co-injection method, preform, and container |
| CH710340A1 (en) | 2014-11-06 | 2016-05-13 | Fostag Formenbau Ag | Co-injection nozzle for an injection molding apparatus for manufacturing multi-layer injection molding products. |
| CH710339A1 (en) | 2014-11-06 | 2016-05-13 | Fostag Formenbau Ag | Co-injection nozzle with integrated check valve for an injection molding apparatus for manufacturing multi-layer injection molding products. |
| US10807298B2 (en) | 2015-12-29 | 2020-10-20 | Whirlpool Corporation | Molded gas barrier parts for vacuum insulated structure |
| CA3017986C (en) * | 2016-04-06 | 2023-08-01 | Amcor Group Gmbh | Multi-layer preform and container |
| US10220559B2 (en) * | 2016-05-18 | 2019-03-05 | Axel Werner Van Briesen | Method and apparatus for making form-in-place gaskets |
| US11009662B2 (en) * | 2017-09-05 | 2021-05-18 | Facebook Technologies, Llc | Manufacturing a graded index profile for waveguide display applications |
| US11298861B2 (en) | 2017-11-21 | 2022-04-12 | Silgan Specialty Packaging Llc | Multi-layer injection molded container |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3894823A (en) * | 1971-09-07 | 1975-07-15 | Robert Hanning | Apparatus for injection molding of parts of synthetic material |
| US4035466A (en) * | 1972-09-27 | 1977-07-12 | Erhard Langecker | Method for central injection molding |
| US4174413A (en) | 1976-07-27 | 1979-11-13 | Asahi-Dow Limited | Multi-layered molded articles |
| US4956143A (en) | 1981-09-16 | 1990-09-11 | Taut, Inc. | Method and apparatus for the multi-unit production of thin-walled tubular products utilizing an injection molding technique |
| US4611987A (en) | 1984-07-23 | 1986-09-16 | Cosden Technology, Inc. | Apparatus for forming multilayer thermoplastic resin extrusions |
| GB8616460D0 (en) * | 1986-07-05 | 1986-08-13 | Metal Box Plc | Manufacture of articles |
| US4781572A (en) | 1987-10-09 | 1988-11-01 | Sonoco Products Company | Self-regulating gate valve assembly for injection molding apparatus |
| US5131830A (en) * | 1987-10-30 | 1992-07-21 | Nissei Asb Machine Co., Ltd. | Multi-layer molding nozzle |
| DE3831836A1 (en) * | 1988-09-20 | 1990-03-22 | Kautex Maschinenbau Gmbh | METHOD AND DEVICE FOR PRODUCING HOLLOW BODIES FROM THERMOPLASTIC PLASTIC |
| US5156857A (en) * | 1988-11-23 | 1992-10-20 | American National Can Company | Extrusion die for extrusion blow molding equipment |
| US5556582A (en) | 1995-02-17 | 1996-09-17 | Stanford University | Injection molding gate flow control |
-
1996
- 1996-09-27 US US08/720,385 patent/US5914138A/en not_active Expired - Lifetime
- 1996-12-06 DE DE69622763T patent/DE69622763T2/en not_active Expired - Lifetime
- 1996-12-06 HU HU9904276A patent/HU222153B1/en not_active IP Right Cessation
- 1996-12-06 PT PT96939250T patent/PT929390E/en unknown
- 1996-12-06 IL IL12906996A patent/IL129069A/en not_active IP Right Cessation
- 1996-12-06 ES ES96939250T patent/ES2183015T3/en not_active Expired - Lifetime
- 1996-12-06 CA CA002266381A patent/CA2266381C/en not_active Expired - Fee Related
- 1996-12-06 PL PL96332507A patent/PL182365B1/en unknown
- 1996-12-06 AU AU76374/96A patent/AU719376B2/en not_active Ceased
- 1996-12-06 SK SK404-99A patent/SK40499A3/en unknown
- 1996-12-06 DK DK96939250T patent/DK0929390T3/en active
- 1996-12-06 CZ CZ19991059A patent/CZ292815B6/en not_active IP Right Cessation
- 1996-12-06 KR KR10-1999-7002590A patent/KR100443136B1/en not_active IP Right Cessation
- 1996-12-06 JP JP51543898A patent/JP3544992B2/en not_active Expired - Fee Related
- 1996-12-06 BR BR9612791-0A patent/BR9612791A/en not_active IP Right Cessation
- 1996-12-06 WO PCT/IB1996/001369 patent/WO1998013187A1/en active IP Right Grant
- 1996-12-06 CN CN96180483A patent/CN1082875C/en not_active Expired - Lifetime
- 1996-12-06 RU RU99108733/12A patent/RU2175288C2/en not_active IP Right Cessation
- 1996-12-06 EP EP96939250A patent/EP0929390B1/en not_active Expired - Lifetime
-
1998
- 1998-05-14 US US09/079,084 patent/US6187241B1/en not_active Expired - Lifetime
-
2000
- 2000-04-26 HK HK00102468A patent/HK1023308A1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| IL129069A (en) | 2002-07-25 |
| DK0929390T3 (en) | 2002-11-04 |
| CZ105999A3 (en) | 1999-10-13 |
| HUP9904276A3 (en) | 2000-05-29 |
| KR100443136B1 (en) | 2004-08-04 |
| AU719376B2 (en) | 2000-05-11 |
| BR9612791A (en) | 2000-02-01 |
| ES2183015T3 (en) | 2003-03-16 |
| HK1023308A1 (en) | 2000-09-08 |
| JP3544992B2 (en) | 2004-07-21 |
| PT929390E (en) | 2002-12-31 |
| EP0929390B1 (en) | 2002-07-31 |
| WO1998013187A1 (en) | 1998-04-02 |
| AU7637496A (en) | 1998-04-17 |
| CN1234763A (en) | 1999-11-10 |
| CN1082875C (en) | 2002-04-17 |
| SK40499A3 (en) | 2000-03-13 |
| CZ292815B6 (en) | 2003-12-17 |
| RU2175288C2 (en) | 2001-10-27 |
| JP2001504763A (en) | 2001-04-10 |
| DE69622763T2 (en) | 2003-03-20 |
| US6187241B1 (en) | 2001-02-13 |
| PL182365B1 (en) | 2001-12-31 |
| EP0929390A1 (en) | 1999-07-21 |
| HU222153B1 (en) | 2003-04-28 |
| HUP9904276A2 (en) | 2000-04-28 |
| DE69622763D1 (en) | 2002-09-05 |
| IL129069A0 (en) | 2000-02-17 |
| US5914138A (en) | 1999-06-22 |
| KR20000048647A (en) | 2000-07-25 |
| PL332507A1 (en) | 1999-09-13 |
| CA2266381A1 (en) | 1998-04-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |