CA2255702A1 - Surfactant-containing acetoacetoxy-functional and enamine-functional polymers - Google Patents
Surfactant-containing acetoacetoxy-functional and enamine-functional polymersInfo
- Publication number
- CA2255702A1 CA2255702A1 CA002255702A CA2255702A CA2255702A1 CA 2255702 A1 CA2255702 A1 CA 2255702A1 CA 002255702 A CA002255702 A CA 002255702A CA 2255702 A CA2255702 A CA 2255702A CA 2255702 A1 CA2255702 A1 CA 2255702A1
- Authority
- CA
- Canada
- Prior art keywords
- surfactant
- functional
- polymers
- enamine
- acetoacetoxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/283—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing one or more carboxylic moiety in the chain, e.g. acetoacetoxyethyl(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/902—Core-shell
Abstract
Surfactant-containing acetoacetoxy-functional polymers (SAAPs) are described.
The acetoacetoxy-functional polymer may be a surfactant-containing enamine-functional polymer and more preferably a surfactant-containing, polymeric (polyamino)enamine (PPAE). The PPAE is the reaction product of a surfactant-containing acetoacetoxy-functional polymer (SAAP) and a poly(alkylenimine).
The polymers may be prepared as waterborne polymer compositions, such as latexes. The waterborne polymer compositions can be prepared with high solids content while maintaining low viscosity. Waterborne polymer compositions containing the polymers of the inventions are useful in a variety of coating formulations such as, for example, paints, inks, sealants, and adhesives. When used in coating formulations, the polymers of the invention provide adhesion and crosslinking in the final film or coating. The film or coating may be cured at ambient temperatures or may be thermally cured.
The acetoacetoxy-functional polymer may be a surfactant-containing enamine-functional polymer and more preferably a surfactant-containing, polymeric (polyamino)enamine (PPAE). The PPAE is the reaction product of a surfactant-containing acetoacetoxy-functional polymer (SAAP) and a poly(alkylenimine).
The polymers may be prepared as waterborne polymer compositions, such as latexes. The waterborne polymer compositions can be prepared with high solids content while maintaining low viscosity. Waterborne polymer compositions containing the polymers of the inventions are useful in a variety of coating formulations such as, for example, paints, inks, sealants, and adhesives. When used in coating formulations, the polymers of the invention provide adhesion and crosslinking in the final film or coating. The film or coating may be cured at ambient temperatures or may be thermally cured.
Applications Claiming Priority (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US1842396P | 1996-05-28 | 1996-05-28 | |
US1842496P | 1996-05-28 | 1996-05-28 | |
US60/018,424 | 1996-05-28 | ||
US60/018,423 | 1996-05-28 | ||
US2844496P | 1996-10-10 | 1996-10-10 | |
US60/028,444 | 1996-10-10 | ||
US08/861,433 | 1997-05-21 | ||
US08/861,433 US6028155A (en) | 1997-05-21 | 1997-05-21 | Surfactant-containing acetoacetoxy-functional and enamine-functional polymers |
PCT/US1997/008808 WO1997045468A1 (en) | 1996-05-28 | 1997-05-28 | Surfactant-containing acetoacetoxy-functional and enamine-functional polymers |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2255702A1 true CA2255702A1 (en) | 1997-12-04 |
CA2255702C CA2255702C (en) | 2003-06-17 |
Family
ID=27486751
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002255702A Expired - Fee Related CA2255702C (en) | 1996-05-28 | 1997-05-28 | Surfactant-containing acetoacetoxy-functional and enamine-functional polymers |
Country Status (9)
Country | Link |
---|---|
US (1) | US6297328B1 (en) |
EP (1) | EP0902800B1 (en) |
JP (1) | JP3727663B2 (en) |
CN (1) | CN1226260A (en) |
AU (1) | AU729319B2 (en) |
CA (1) | CA2255702C (en) |
DE (1) | DE69715404T2 (en) |
ES (1) | ES2179349T3 (en) |
WO (1) | WO1997045468A1 (en) |
Families Citing this family (43)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6649679B1 (en) * | 1997-09-18 | 2003-11-18 | Eastman Chemical Company | Stable waterborne polymer compositions containing poly(alkylenimines) |
US6005035A (en) * | 1997-09-18 | 1999-12-21 | Eastman Chemical Company | Stable waterborne polymer compositions containing poly(alkylenimines) |
US6201048B1 (en) * | 1997-09-18 | 2001-03-13 | Eastman Chemical Company | Stable waterborne polymer compositions containing poly(alkyleneimines) |
ATE307149T1 (en) † | 1998-08-07 | 2005-11-15 | Reichhold Inc | NEW LATEX COMPOSITION FOR COATING VARIOUS SUBSTRATES |
DE19850363A1 (en) | 1998-11-02 | 2000-05-04 | Basf Ag | Polymers for cosmetic formulations |
US6355720B1 (en) * | 2000-05-12 | 2002-03-12 | Johnson Polymer, Inc. | Latex formulations with reduced yellowing |
GB0015245D0 (en) * | 2000-06-22 | 2000-08-16 | Avecia Ltd | Composition and process |
US6593412B1 (en) * | 2000-09-27 | 2003-07-15 | Air Products Polymers, L.P. | Water based emulsion copolymers incorporating vinyl ethylene carbonate |
US7812079B2 (en) * | 2001-02-22 | 2010-10-12 | Valspar Sourcing, Inc. | Coating compositions containing low VOC compounds |
US20030134973A1 (en) * | 2002-01-15 | 2003-07-17 | Chen Robert Gow-Sheng | Waterborne latexes for anti-corrosive and solvent-resistant coating compositions |
US6893722B2 (en) | 2002-04-29 | 2005-05-17 | Exxonmobil Oil Corporation | Cationic, amino-functional, adhesion-promoting polymer for curable inks and other plastic film coatings, and plastic film comprising such polymer |
US7195818B2 (en) * | 2002-05-01 | 2007-03-27 | Exxonmobil Oil Corporation | Sealable multi-layer opaque film |
US7148265B2 (en) * | 2002-09-30 | 2006-12-12 | Rohm And Haas Electronic Materials Llc | Functional polymer |
US20040063809A1 (en) * | 2002-09-30 | 2004-04-01 | Zhenwen Fu | Polymeric binders for inkjet inks |
US7323290B2 (en) * | 2002-09-30 | 2008-01-29 | Eternal Technology Corporation | Dry film photoresist |
US20040105994A1 (en) * | 2002-12-03 | 2004-06-03 | Pang-Chia Lu | Thermoplastic film structures with a low melting point outer layer |
EP1577331A1 (en) * | 2002-12-19 | 2005-09-21 | Tokyo University of Science, Educational Foundation | Latex particles and process for producing the same |
WO2004056894A1 (en) * | 2002-12-19 | 2004-07-08 | Nanocarrier Co., Ltd. | Latex polymer particles containing fluorescent substance or contrast medium and process for producing the same |
GB0413630D0 (en) | 2004-06-18 | 2004-07-21 | Avecia Ltd | Process |
US8609762B2 (en) * | 2004-12-17 | 2013-12-17 | Valspar Sourcing, Inc. | Aqueous coating compositions containing acetoacetyl-functional polymers, coatings, and methods |
US9803045B2 (en) * | 2004-12-17 | 2017-10-31 | Valspar Sourcing, Inc. | Aqueous coating compositions containing acetoacetyl-functional polymers, coatings, and methods |
KR100838973B1 (en) * | 2005-06-08 | 2008-06-17 | 주식회사 엘지화학 | Acrylic pressure sensitive adhesive compositions |
US20070048249A1 (en) | 2005-08-24 | 2007-03-01 | Purdue Research Foundation | Hydrophilized bactericidal polymers |
CA2661486C (en) | 2006-08-24 | 2013-04-23 | Mallard Creek Polymers, Inc. | Cationic latex as a carrier for bioactive ingredients and methods for making and using the same |
CN101622321B (en) * | 2007-04-04 | 2013-06-26 | 电气化学工业株式会社 | Primer composition for acrylic adhesive, bonding method, and bonded body |
JP2010222382A (en) * | 2007-07-20 | 2010-10-07 | Daikin Ind Ltd | Fluorine-containing fiber processing agent having soil release property |
CN101747465B (en) * | 2009-12-17 | 2011-11-23 | 上海华明高技术(集团)有限公司 | Method for preparing polyhydroxy auxiliary agent for fly ash fiber papermaking |
US9102848B2 (en) | 2011-02-28 | 2015-08-11 | Basf Se | Environmentally friendly, polymer dispersion-based coating formulations and methods of preparing and using same |
WO2012134695A1 (en) * | 2011-03-29 | 2012-10-04 | Exxonmobil Oil Corporation | Film coatings based on polyalkylimine condensation polymers |
US20130084437A1 (en) | 2011-09-29 | 2013-04-04 | Dennis E. McGee | Film Coatings Based on Polyalkylimine Condensation Polymers |
CN104039837B (en) | 2011-10-24 | 2016-10-19 | 罗门哈斯公司 | Reduce the method for poisonous scent of residual monomer in emulsion |
EP2748237A1 (en) | 2012-05-01 | 2014-07-02 | Jindal Films Americas, LLC | Epoxylated polyalkyleneimine film coatings |
KR20150087399A (en) * | 2012-11-22 | 2015-07-29 | 케미라 오와이제이 | Polymer and its preparation and use |
EP2945994B1 (en) | 2013-01-18 | 2018-07-11 | Basf Se | Acrylic dispersion-based coating compositions |
WO2017112816A1 (en) * | 2015-12-21 | 2017-06-29 | Jindal Films Americas Llc | Printable coatings for films and labels |
CA3047842C (en) * | 2016-12-22 | 2024-02-20 | Dow Global Technologies Llc | Method for producing aqueous polymer compositions with less yellowing |
CN108720180A (en) * | 2017-04-25 | 2018-11-02 | 欧利速精密工业股份有限公司 | Improvement type shoemaking assembly method and the amendment solution of application |
US20180340046A1 (en) | 2017-05-27 | 2018-11-29 | Poly Group LLC | Dispersible antimicrobial complex and coatings therefrom |
US20180362678A1 (en) | 2017-06-16 | 2018-12-20 | Poly Group LLC | Polymeric antimicrobial surfactant |
CN111808228B (en) * | 2020-07-15 | 2022-07-12 | 万华化学集团股份有限公司 | Hyperbranched polyethyleneimine doped modified acrylic emulsion and preparation method thereof |
CN113372479B (en) * | 2021-07-20 | 2023-04-28 | 安徽工程大学 | Crosslinked acetoacetate-based ethyl methacrylate copolymer prepared by using functionalized amide dynamic covalent bond and preparation method thereof |
WO2023094376A1 (en) * | 2021-11-23 | 2023-06-01 | Basf Se | Process for preparing an aqueous polymer dispersion |
WO2023213742A1 (en) * | 2022-05-06 | 2023-11-09 | Basf Se | Coating composition and preparation for the same |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB886984A (en) * | 1959-11-16 | 1962-01-10 | Revertex Ltd | Improvements in or relating to the preparation of aqueous emulsions of polyvinyl acetate or vinyl acetate copolymers |
JP2777732B2 (en) * | 1989-06-16 | 1998-07-23 | ヘキスト合成株式会社 | Method for producing aqueous composition comprising acetoacetyl group-containing water-soluble polymer compound and aqueous medium |
DE3942592A1 (en) | 1989-12-22 | 1991-06-27 | Basf Lacke & Farben | RELATED NETWORK COPOLYMERIZES BASED ON VINYL REAGENTS, VINYAROMAT AND ACRYLATE MONOMERES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE IN COATING AGENTS |
US5288804A (en) | 1992-01-03 | 1994-02-22 | Reichhold Chemicals, Inc. | Acetoacetate aromatic aldimine resin composition |
US5296530A (en) | 1992-07-28 | 1994-03-22 | Rohm And Haas Company | Method for light-assisted curing of coatings |
US5767199A (en) | 1992-07-29 | 1998-06-16 | Rohm And Hass Company | Shelf stable compositions containing acetoacetate functional polymer and polyformal |
US5525662A (en) | 1993-07-14 | 1996-06-11 | Rohm And Haas Company | Functionalization of polymers via enamine of acetoacetate |
US5414041A (en) | 1994-04-08 | 1995-05-09 | Rohm And Haas Company | Waterborne coating composition |
US5534310A (en) | 1994-08-17 | 1996-07-09 | Rohm And Haas Company | Method of improving adhesive of durable coatings on weathered substrates |
ES2122695T3 (en) | 1994-11-29 | 1998-12-16 | Vianova Kunstharz Ag | PROCEDURE FOR THE PREPARATION IN TWO STAGES OF AQUEOUS, SELF-CROSS-COOLYMER DISPERSIONS AND THE USE OF THE SAME FOR LACQUERES. |
US5783626A (en) | 1995-04-12 | 1998-07-21 | Taylor; James Wayne | Waterborne polymers with pendant crosslinkable groups |
US5672379A (en) | 1995-09-22 | 1997-09-30 | Rohm And Haas Company | Method of producing wear resistant traffic markings |
-
1997
- 1997-05-28 ES ES97927732T patent/ES2179349T3/en not_active Expired - Lifetime
- 1997-05-28 WO PCT/US1997/008808 patent/WO1997045468A1/en not_active Application Discontinuation
- 1997-05-28 CA CA002255702A patent/CA2255702C/en not_active Expired - Fee Related
- 1997-05-28 JP JP54278897A patent/JP3727663B2/en not_active Expired - Lifetime
- 1997-05-28 AU AU32122/97A patent/AU729319B2/en not_active Ceased
- 1997-05-28 DE DE69715404T patent/DE69715404T2/en not_active Expired - Lifetime
- 1997-05-28 EP EP97927732A patent/EP0902800B1/en not_active Expired - Lifetime
- 1997-05-28 CN CN97196842A patent/CN1226260A/en active Pending
-
1998
- 1998-03-31 US US09/050,973 patent/US6297328B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0902800A1 (en) | 1999-03-24 |
ES2179349T3 (en) | 2003-01-16 |
DE69715404T2 (en) | 2003-01-09 |
EP0902800B1 (en) | 2002-09-11 |
JP2002502442A (en) | 2002-01-22 |
CN1226260A (en) | 1999-08-18 |
AU3212297A (en) | 1998-01-05 |
DE69715404D1 (en) | 2002-10-17 |
JP3727663B2 (en) | 2005-12-14 |
CA2255702C (en) | 2003-06-17 |
AU729319B2 (en) | 2001-02-01 |
US6297328B1 (en) | 2001-10-02 |
WO1997045468A1 (en) | 1997-12-04 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |