CA2234246A1 - Water dispersible blocked isocyanates - Google Patents
Water dispersible blocked isocyanatesInfo
- Publication number
- CA2234246A1 CA2234246A1 CA002234246A CA2234246A CA2234246A1 CA 2234246 A1 CA2234246 A1 CA 2234246A1 CA 002234246 A CA002234246 A CA 002234246A CA 2234246 A CA2234246 A CA 2234246A CA 2234246 A1 CA2234246 A1 CA 2234246A1
- Authority
- CA
- Canada
- Prior art keywords
- group
- water dispersible
- dispersible blocked
- blocked isocyanates
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
- C08G18/8048—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/34
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/8064—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
Abstract
A water dispersible blocked polyisocyanate of formula (I) R-Y m, where R is an m valent group comprising an aliphatic, cycloaliphatic, heterocyclic or aromatic group and comprising at least three consecutive ethylene oxide groups or at least one residue of a polyhydroxy carboxylic acid, and each group Y, which may be the same or different, is a group of formula (II), where each R1 is the same or different when n is more than 1 and each R1 is an alkyl, alkenyl, aralkyl, N-substituted carbamyl, phenyl, NO2, halogen or a group -C(O)-O-R2, where R2 is hydrogen or an alkyl group; n is 0, 1, 2 or 3; and m is an integer of 2 or more.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9520317.0 | 1995-10-05 | ||
GBGB9520317.0A GB9520317D0 (en) | 1995-10-05 | 1995-10-05 | Water dispersable blocked isocyanates |
PCT/GB1996/002440 WO1997012924A1 (en) | 1995-10-05 | 1996-10-04 | Water dispersible blocked isocyanates |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2234246A1 true CA2234246A1 (en) | 1996-10-04 |
CA2234246C CA2234246C (en) | 2007-01-23 |
Family
ID=10781800
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002234246A Expired - Fee Related CA2234246C (en) | 1995-10-05 | 1996-10-04 | Water dispersible blocked isocyanates |
Country Status (15)
Country | Link |
---|---|
US (1) | US6063860A (en) |
EP (1) | EP0853639B1 (en) |
JP (1) | JP3970926B2 (en) |
KR (1) | KR100447491B1 (en) |
AT (1) | ATE187973T1 (en) |
AU (1) | AU703953B2 (en) |
CA (1) | CA2234246C (en) |
DE (1) | DE69605814T2 (en) |
DK (1) | DK0853639T3 (en) |
ES (1) | ES2142092T3 (en) |
GB (1) | GB9520317D0 (en) |
GR (1) | GR3032857T3 (en) |
PT (1) | PT853639E (en) |
WO (1) | WO1997012924A1 (en) |
ZA (1) | ZA968395B (en) |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU757895B2 (en) * | 1997-08-27 | 2003-03-13 | Rhodia Chimie | Method for masking polyisocyanates in emulsion |
FR2772385B1 (en) * | 1997-08-27 | 2000-01-21 | Rhodia Chimie Sa | SYNTHESIS IN EMULSION OF (POLY) ISOCYANATES MASKS, EMULSION SO OBTAINED, USE OF EMULSIONS WITH A VIEW TO MAKING COMPOSITIONS USEFUL FOR COATING AND COATING THUS OBTAINED |
FR2770846B1 (en) * | 1997-11-07 | 2000-01-28 | Rhodia Chimie Sa | POLYISOCYANATE EMULSION MASKING PROCESS |
DE19810660A1 (en) | 1998-03-12 | 1999-09-16 | Bayer Ag | Aqueous polyisocyanate crosslinker with hydroxypivalic acid and dimethylpyrazole blocking |
ES2248987T3 (en) | 1998-04-09 | 2006-03-16 | Clariant Finance (Bvi) Limited | BLOCKED OLIGOMER ISOCIANATES, ITS PRODUCTION AND USE. |
DE19914885A1 (en) * | 1999-04-01 | 2000-10-05 | Bayer Ag | Polyurethane and/or polyurea resin dispersions, useful for the coating of glass fibers, wood, metal, plastic, leather and textiles, are modified with dimethylpyrazole |
WO2001062863A1 (en) * | 2000-02-22 | 2001-08-30 | Sunyx Surface Nanotechnologies Gmbh | Polymer dispersion-based ultrahydrophobic lacquers |
KR100648556B1 (en) * | 2000-02-28 | 2006-11-24 | 바이엘 악티엔게젤샤프트 | Aqueous coating agents for baking enamels with a high solid content and the use thereof |
DE10052875A1 (en) * | 2000-08-14 | 2002-02-28 | Bayer Ag | Aqueous dispersions |
DE10134238A1 (en) | 2001-07-13 | 2003-01-23 | Bayer Ag | An aqueous and/or water dilutible blocked polyisocyanate crosslinking agent, useful for preparation of stoving enamels and automobile finishing, comprises polyisocyante, diisopropylamine, hydrophilizing agent and chain lengthening agent |
US7026428B2 (en) * | 2002-06-17 | 2006-04-11 | Bayer Aktiengesellschaft | Blocked polyisocyanates |
DE10226925A1 (en) * | 2002-06-17 | 2003-12-24 | Bayer Ag | Blocked polyisocyanates |
DE10226927A1 (en) * | 2002-06-17 | 2003-12-24 | Bayer Ag | Blocked polyisocyanates |
JP4433661B2 (en) * | 2002-08-08 | 2010-03-17 | 関西ペイント株式会社 | Light-colored water-based intermediate coating |
DE10308105A1 (en) * | 2003-02-26 | 2004-09-09 | Bayer Aktiengesellschaft | Polyurethane coating systems |
DE10308104A1 (en) * | 2003-02-26 | 2004-09-09 | Bayer Ag | Polyurethane coating systems |
DE10328064A1 (en) * | 2003-06-23 | 2005-01-13 | Bayer Materialscience Ag | Blocked polyisocyanates |
DE10328993A1 (en) | 2003-06-27 | 2005-01-20 | Bayer Materialscience Ag | Blocked polyisocyanates |
DE10328994A1 (en) * | 2003-06-27 | 2005-01-13 | Bayer Materialscience Ag | Blocked polyisocyanates |
EP1664161A1 (en) * | 2003-09-12 | 2006-06-07 | Teijin Twaron B.V. | Two-step method for dipping synthetic fiber |
DE102004057916A1 (en) * | 2004-11-30 | 2006-06-01 | Bayer Materialscience Ag | Blocked polyisocyanate for dual-cure coating, contains radiation-curable group(s) and specific structural unit(s) |
DE102005057683A1 (en) | 2005-12-01 | 2007-06-06 | Basf Ag | Radiation curable water emulsifiable polyisocyanates |
DE102006025313A1 (en) * | 2006-05-31 | 2007-12-06 | Bayer Materialscience Ag | Low-solvent or solvent-free crosslinker dispersion with pyrazole-blocked isocyanate groups |
JP2008248237A (en) * | 2007-03-08 | 2008-10-16 | Kansai Paint Co Ltd | Water-based one-package coating and method for forming multilayer coating film |
EP2058355A1 (en) | 2007-11-08 | 2009-05-13 | Bayer MaterialScience AG | Polysiloxane modified polyisocyanate |
FR2923834B1 (en) | 2007-11-20 | 2011-01-21 | Rhodia Operations | NOVEL HYDRODISPERSIBLE POLYSICOCYANATE COMPOSITIONS. |
EP2236532A1 (en) | 2009-03-31 | 2010-10-06 | Bayer MaterialScience AG | Nanoparticle modified hydrophilic polyisocyanate |
JP5620831B2 (en) * | 2011-01-12 | 2014-11-05 | 日華化学株式会社 | Curable aqueous resin composition, aqueous coating agent and aqueous adhesive |
US8940853B2 (en) | 2011-03-16 | 2015-01-27 | Asahi Kasei Chemicals Corporation | Cationic blocked polyisocyanate and aqueous composition comprising the same |
KR101593855B1 (en) | 2011-10-25 | 2016-02-12 | 아사히 가세이 케미칼즈 가부시키가이샤 | Blocked polyisocyanate water dispersion, fiber processing agent composition, and fabric |
MX2014014042A (en) | 2012-05-24 | 2015-02-12 | Bayer Materialscience Ag | Aqueous blocked polyurethane-urea dispersion. |
JP6328875B2 (en) * | 2012-09-26 | 2018-05-23 | 旭化成株式会社 | Aqueous block polyisocyanate, fiber treating agent composition, and fiber |
TR201906000T4 (en) * | 2015-05-06 | 2019-05-21 | Basf Se | Method for the production of composite materials. |
CN114127150A (en) * | 2019-07-18 | 2022-03-01 | 巴斯夫欧洲公司 | Allophanate-based dispersants |
US11827795B2 (en) | 2019-08-13 | 2023-11-28 | Purdue Research Foundation | Cellulose nanomaterial (CN) based waterborne polyurethane coating |
EP3875511A1 (en) | 2020-03-05 | 2021-09-08 | Covestro Deutschland AG | High temperature cross-linking dispersion |
EP3875512A1 (en) | 2020-03-05 | 2021-09-08 | Covestro Deutschland AG | Nonionically hydrophilicized crosslinker dispersion with thermolatently bonded urethane / urea groups |
WO2022224927A1 (en) | 2021-04-21 | 2022-10-27 | 旭化成株式会社 | Blocked isocyanate composition, aqueous dispersion, coating composition and coating film |
WO2024069154A1 (en) | 2022-09-26 | 2024-04-04 | Fujifilm Speciality Ink Systems Limited | Printing ink |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4008247A (en) * | 1973-11-02 | 1977-02-15 | The B. F. Goodrich Company | Ethylenically unsaturated blocked aromatic diisocyanates |
DE2456469C2 (en) * | 1974-11-29 | 1983-01-13 | Bayer Ag, 5090 Leverkusen | Process for the preparation of water-soluble or water-dispersible blocked polyisocyanates and their use as coating agents |
JPS5215596A (en) * | 1975-07-28 | 1977-02-05 | Kao Corp | Process for preparing cationic polyuretane emulsion |
DE2729704A1 (en) * | 1977-07-01 | 1979-01-11 | Veba Chemie Ag | METHOD FOR PRODUCING BLOCKED POLYISOCYANATE |
US4322327A (en) * | 1979-10-19 | 1982-03-30 | Mitsubishi Petrochemical Co., Ltd. | Slow-curing water-curable urethane prepolymer composition |
US4522851A (en) * | 1982-09-30 | 1985-06-11 | Mobay Chemical Corporation | Process for coating aqueous dispersion of epoxy resin and blocked polyisocyanate containing chemically incorporated anionic hydrophilic groups |
DE3326188A1 (en) * | 1983-07-20 | 1985-01-31 | Bayer Ag, 5090 Leverkusen | METHOD FOR THE PRODUCTION OF ORGANIC POLYISOCYANATES WITH AT LEAST PARTLY BLOCKED ISOCYANATE GROUPS, THE COMPOUNDS AVAILABLE AFTER THE METHOD AND THE USE THEREOF FOR THE PRODUCTION OF POLYURETHANES, BURNING LACQUES OR WATER POWDERED POLYURATES. -DISPERSIONS |
GB8405320D0 (en) * | 1984-02-29 | 1984-04-04 | Baxenden Chem | Blocked isocyanates |
EP0500495A3 (en) * | 1991-02-21 | 1993-04-07 | Ciba-Geigy Ag | Thermosetting composition |
DE4221924A1 (en) * | 1992-07-03 | 1994-01-13 | Bayer Ag | Water-soluble or dispersible polyisocyanate mixtures and their use in stoving lacquers |
PT691993E (en) * | 1993-03-31 | 2002-07-31 | Rhodia Chimie Sa | PROCESS FOR THE PREPARATION OF AQUEOUS EMULSES OF OLEOS AND / OR GUMS AND / OR RESIN (POLY) ISANIANLY MADE MASKED AND EMULSES OBTAINED |
WO1995006674A1 (en) * | 1993-09-03 | 1995-03-09 | Olin Corporation | Isocyanate-crosslinked coatings having reduced yellowing |
-
1995
- 1995-10-05 GB GBGB9520317.0A patent/GB9520317D0/en active Pending
-
1996
- 1996-10-04 KR KR10-1998-0702541A patent/KR100447491B1/en not_active IP Right Cessation
- 1996-10-04 EP EP96932724A patent/EP0853639B1/en not_active Expired - Lifetime
- 1996-10-04 JP JP51408097A patent/JP3970926B2/en not_active Expired - Fee Related
- 1996-10-04 CA CA002234246A patent/CA2234246C/en not_active Expired - Fee Related
- 1996-10-04 DE DE69605814T patent/DE69605814T2/en not_active Expired - Lifetime
- 1996-10-04 US US09/051,218 patent/US6063860A/en not_active Expired - Lifetime
- 1996-10-04 ZA ZA968395A patent/ZA968395B/en unknown
- 1996-10-04 AT AT96932724T patent/ATE187973T1/en not_active IP Right Cessation
- 1996-10-04 PT PT96932724T patent/PT853639E/en unknown
- 1996-10-04 DK DK96932724T patent/DK0853639T3/en active
- 1996-10-04 ES ES96932724T patent/ES2142092T3/en not_active Expired - Lifetime
- 1996-10-04 WO PCT/GB1996/002440 patent/WO1997012924A1/en active IP Right Grant
- 1996-10-04 AU AU71400/96A patent/AU703953B2/en not_active Ceased
-
2000
- 2000-03-03 GR GR20000400549T patent/GR3032857T3/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CA2234246C (en) | 2007-01-23 |
KR19990064062A (en) | 1999-07-26 |
GB9520317D0 (en) | 1995-12-06 |
ES2142092T3 (en) | 2000-04-01 |
ATE187973T1 (en) | 2000-01-15 |
DK0853639T3 (en) | 2000-05-08 |
GR3032857T3 (en) | 2000-07-31 |
ZA968395B (en) | 1997-05-13 |
JP3970926B2 (en) | 2007-09-05 |
DE69605814T2 (en) | 2000-05-25 |
PT853639E (en) | 2000-05-31 |
WO1997012924A1 (en) | 1997-04-10 |
EP0853639A1 (en) | 1998-07-22 |
JPH11512772A (en) | 1999-11-02 |
AU703953B2 (en) | 1999-04-01 |
US6063860A (en) | 2000-05-16 |
KR100447491B1 (en) | 2005-01-15 |
DE69605814D1 (en) | 2000-01-27 |
AU7140096A (en) | 1997-04-28 |
EP0853639B1 (en) | 1999-12-22 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20141006 |
|
MKLA | Lapsed |
Effective date: 20141006 |