CA2228738A1 - Three step process for producing light olefins from methane and/or ethane - Google Patents

Three step process for producing light olefins from methane and/or ethane Download PDF

Info

Publication number
CA2228738A1
CA2228738A1 CA002228738A CA2228738A CA2228738A1 CA 2228738 A1 CA2228738 A1 CA 2228738A1 CA 002228738 A CA002228738 A CA 002228738A CA 2228738 A CA2228738 A CA 2228738A CA 2228738 A1 CA2228738 A1 CA 2228738A1
Authority
CA
Canada
Prior art keywords
produced
light olefins
production
methanol
oxygenate conversion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002228738A
Other languages
French (fr)
Other versions
CA2228738C (en
Inventor
Terry L. Marker
Bipin V. Vora
Henning R. Nilsen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Norsk Hydro ASA
Honeywell UOP LLC
Original Assignee
Norsk Hydro ASA
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US08/513,242 priority Critical patent/US5714662A/en
Priority to NZ329645A priority patent/NZ329645A/en
Priority to CNB981061923A priority patent/CN1174945C/en
Priority to AU52747/98A priority patent/AU744933B2/en
Priority to NO19980381A priority patent/NO311714B1/en
Priority to EP98300641A priority patent/EP0933345B1/en
Priority to DE69801643T priority patent/DE69801643T2/en
Priority to ZA98735A priority patent/ZA98735B/en
Application filed by Norsk Hydro ASA, UOP LLC filed Critical Norsk Hydro ASA
Priority to RU98103428/04A priority patent/RU2165955C2/en
Priority to CA002228738A priority patent/CA2228738C/en
Publication of CA2228738A1 publication Critical patent/CA2228738A1/en
Application granted granted Critical
Publication of CA2228738C publication Critical patent/CA2228738C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Abstract

Light olefins are produced from a hydrocarbon gas stream by a combination of steam reforming, oxygenate production, and oxygenate conversion to olefin wherein a crude methanol stream - produced in the production of oxygenates and comprising methanol, light ends, and heavier alcohols - is passed directly to the oxygenate conversion zone for the production of light olefins. Furthermore, the combination provides the synergy for increased catalyst life and reduced water treatment costs by recycling by-product water produced in the oxygenate conversion zone to provide water to the steam reforming zone. The advantage of this integration is the elimination of costly methanol separation and purification steps which result in the overall reduction in the costs of producing the light olefins.
In addition, a portion of the by-product water can be combined with a propylene stream to provide a high octane blending component for gasoline. The propylene and butylene fractions produced by the above integrated scheme are further converted to high octane ether and other high value products.
CA002228738A 1995-08-10 1998-02-02 Three step process for producing light olefins from methane and/or ethane Expired - Fee Related CA2228738C (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
US08/513,242 US5714662A (en) 1995-08-10 1995-08-10 Process for producing light olefins from crude methanol
CNB981061923A CN1174945C (en) 1995-08-10 1998-01-27 Three step process for producing light olefins from methane and/or ethane
AU52747/98A AU744933B2 (en) 1995-08-10 1998-01-27 Three step process for producing light olefins from methane and/or ethane
NZ329645A NZ329645A (en) 1995-08-10 1998-01-27 Process for producing light olefins from feed having methane and/or ethane using methanol plant combined with oxygenate conversion processing
NO19980381A NO311714B1 (en) 1995-08-10 1998-01-28 Process for the preparation of light olefins of methane and / or ethane
DE69801643T DE69801643T2 (en) 1995-08-10 1998-01-29 Three-step process for the production of light olefin from rough methane and / or ethane
EP98300641A EP0933345B1 (en) 1995-08-10 1998-01-29 Three step process for producing light olefins from crude methane and/or ethane
ZA98735A ZA98735B (en) 1995-08-10 1998-01-29 Three step process for producing light olefins from methane and/or ethane
RU98103428/04A RU2165955C2 (en) 1995-08-10 1998-02-02 Three-stage method for production of light olefins from methane and/or ethane
CA002228738A CA2228738C (en) 1995-08-10 1998-02-02 Three step process for producing light olefins from methane and/or ethane

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US08/513,242 US5714662A (en) 1995-08-10 1995-08-10 Process for producing light olefins from crude methanol
CNB981061923A CN1174945C (en) 1995-08-10 1998-01-27 Three step process for producing light olefins from methane and/or ethane
AU52747/98A AU744933B2 (en) 1995-08-10 1998-01-27 Three step process for producing light olefins from methane and/or ethane
NZ329645A NZ329645A (en) 1995-08-10 1998-01-27 Process for producing light olefins from feed having methane and/or ethane using methanol plant combined with oxygenate conversion processing
NO19980381A NO311714B1 (en) 1995-08-10 1998-01-28 Process for the preparation of light olefins of methane and / or ethane
EP98300641A EP0933345B1 (en) 1995-08-10 1998-01-29 Three step process for producing light olefins from crude methane and/or ethane
ZA98735A ZA98735B (en) 1995-08-10 1998-01-29 Three step process for producing light olefins from methane and/or ethane
RU98103428/04A RU2165955C2 (en) 1995-08-10 1998-02-02 Three-stage method for production of light olefins from methane and/or ethane
CA002228738A CA2228738C (en) 1995-08-10 1998-02-02 Three step process for producing light olefins from methane and/or ethane

Publications (2)

Publication Number Publication Date
CA2228738A1 true CA2228738A1 (en) 1999-08-02
CA2228738C CA2228738C (en) 2006-09-26

Family

ID=31950988

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002228738A Expired - Fee Related CA2228738C (en) 1995-08-10 1998-02-02 Three step process for producing light olefins from methane and/or ethane

Country Status (10)

Country Link
US (1) US5714662A (en)
EP (1) EP0933345B1 (en)
CN (1) CN1174945C (en)
AU (1) AU744933B2 (en)
CA (1) CA2228738C (en)
DE (1) DE69801643T2 (en)
NO (1) NO311714B1 (en)
NZ (1) NZ329645A (en)
RU (1) RU2165955C2 (en)
ZA (1) ZA98735B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011006594A1 (en) 2009-07-14 2011-01-20 Lurgi Gmbh Method and apparatus for producing synthetic fuels
US9938217B2 (en) 2016-07-01 2018-04-10 Res Usa, Llc Fluidized bed membrane reactor
US9981896B2 (en) 2016-07-01 2018-05-29 Res Usa, Llc Conversion of methane to dimethyl ether
US10189763B2 (en) 2016-07-01 2019-01-29 Res Usa, Llc Reduction of greenhouse gas emission

Families Citing this family (143)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE37142E1 (en) 1995-02-08 2001-04-24 Millennium Fuels Usa Llc Refining process and apparatus
USRE37089E1 (en) 1995-02-08 2001-03-13 Millennium Fuels Usa Llc Refining process and apparatus
US6436869B1 (en) 1996-05-29 2002-08-20 Exxonmobil Chemical Patents Inc. Iron, cobalt and/or nickel containing ALPO bound SAPO molecular sieve catalyst for producing olefins
US6538167B1 (en) 1996-10-02 2003-03-25 Exxonmobil Chemical Patents Inc. Process for producing light olefins
US5960643A (en) 1996-12-31 1999-10-05 Exxon Chemical Patents Inc. Production of ethylene using high temperature demethanization
US6455747B1 (en) 1998-05-21 2002-09-24 Exxonmobil Chemical Patents Inc. Method for converting oxygenates to olefins
US6023005A (en) * 1997-07-03 2000-02-08 Exxon Chemicals Patents Inc. Process for converting oxygenates to olefins using molecular sieve catalysts comprising desirable carbonaceous deposits
US6552240B1 (en) 1997-07-03 2003-04-22 Exxonmobil Chemical Patents Inc. Method for converting oxygenates to olefins
US6162415A (en) * 1997-10-14 2000-12-19 Exxon Chemical Patents Inc. Synthesis of SAPO-44
US6137022A (en) * 1997-12-03 2000-10-24 Exxon Chemical Patents Inc Process for increasing the selectivity of a reaction to convert oxygenates to olefins
US6049017A (en) * 1998-04-13 2000-04-11 Uop Llc Enhanced light olefin production
US6046373A (en) * 1998-04-29 2000-04-04 Exxon Chemical Patents Inc. Catalytic conversion of oxygenates to olefins
US6121504A (en) * 1998-04-29 2000-09-19 Exxon Chemical Patents Inc. Process for converting oxygenates to olefins with direct product quenching for heat recovery
US6482998B1 (en) 1998-04-29 2002-11-19 Exxonmobil Chemical Patents, Inc. Process for converting oxygenates to olefins with direct product quenching for heat recovery
US6245703B1 (en) * 1998-04-29 2001-06-12 Exxon Mobil Chemical Patents Inc. Efficient method using liquid water to regenerate oxygenate to olefin catalysts while increasing catalyst specificity to light olefins
US6187983B1 (en) 1998-04-29 2001-02-13 Exxon Chemical Patents Inc Converting oxygenates to olefins in the presence of electromagnetic energy
KR100293531B1 (en) * 1998-12-24 2001-10-26 윤덕용 Hybrid Catalysts for Hydrocarbon Generation from Carbon Dioxide
US6482999B2 (en) 1999-02-17 2002-11-19 Exxonmobil Chemical Patents, Inc. Method for improving light olefin selectivity in an oxygenate conversion reaction
US6444868B1 (en) 1999-02-17 2002-09-03 Exxon Mobil Chemical Patents Inc. Process to control conversion of C4+ and heavier stream to lighter products in oxygenate conversion reactions
US6559428B2 (en) * 2001-01-16 2003-05-06 General Electric Company Induction heating tool
US6395674B1 (en) 1999-06-07 2002-05-28 Exxon Mobil Chemical Patents, Inc. Heat treating a molecular sieve and catalyst
US6225254B1 (en) 1999-06-07 2001-05-01 Exxon Mobil Chemical Patents Inc. Maintaining acid catalyst sites in sapo molecular sieves
US6316683B1 (en) 1999-06-07 2001-11-13 Exxonmobil Chemical Patents Inc. Protecting catalytic activity of a SAPO molecular sieve
US6205957B1 (en) * 1999-09-16 2001-03-27 Eaton Corporation Natural gas engine with in situ generation of an autoignition product
US6437208B1 (en) 1999-09-29 2002-08-20 Exxonmobil Chemical Patents Inc. Making an olefin product from an oxygenate
WO2001060746A1 (en) 2000-02-16 2001-08-23 Exxonmobil Chemical Patents Inc. Treatment of molecular sieves with silicon containing compounds
US6531639B1 (en) 2000-02-18 2003-03-11 Exxonmobil Chemical Patents, Inc. Catalytic production of olefins at high methanol partial pressures
US6743747B1 (en) 2000-02-24 2004-06-01 Exxonmobil Chemical Patents Inc. Catalyst pretreatment in an oxgenate to olefins reaction system
US6506954B1 (en) 2000-04-11 2003-01-14 Exxon Mobil Chemical Patents, Inc. Process for producing chemicals from oxygenate
US7102050B1 (en) 2000-05-04 2006-09-05 Exxonmobil Chemical Patents Inc. Multiple riser reactor
US6613950B1 (en) * 2000-06-06 2003-09-02 Exxonmobil Chemical Patents Inc. Stripping hydrocarbon in an oxygenate conversion process
AU783766B2 (en) * 2000-06-23 2005-12-01 Jgc Corporation Process for the preparation of lower olefins
US6441261B1 (en) 2000-07-28 2002-08-27 Exxonmobil Chemical Patents Inc. High pressure oxygenate conversion process via diluent co-feed
US6486219B1 (en) 2000-09-27 2002-11-26 Exxonmobil Chemical Patents, Inc. Methanol, olefin, and hydrocarbon synthesis process
US6444712B1 (en) 2000-09-28 2002-09-03 Exxonmobil Chemical Patents, Inc. Methanol, olefin, and hydrocarbon synthesis process
US6593506B1 (en) 2000-10-12 2003-07-15 Exxonmobil Chemical Patents Inc. Olefin recovery in a polyolefin production process
US6495609B1 (en) 2000-11-03 2002-12-17 Exxonmobil Chemical Patents Inc. Carbon dioxide recovery in an ethylene to ethylene oxide production process
US6538162B2 (en) 2001-01-30 2003-03-25 Exxonmobil Chemical Patents Inc. Method for converting alkanes to oxygenates
US20020103406A1 (en) * 2001-02-01 2002-08-01 Georges Mathys Production of olefin dimers and oligomers
US6875899B2 (en) * 2001-02-01 2005-04-05 Exxonmobil Chemical Patents Inc. Production of higher olefins
US6441262B1 (en) 2001-02-16 2002-08-27 Exxonmobil Chemical Patents, Inc. Method for converting an oxygenate feed to an olefin product
US6518475B2 (en) 2001-02-16 2003-02-11 Exxonmobil Chemical Patents Inc. Process for making ethylene and propylene
EP1421044B1 (en) * 2001-07-02 2007-03-07 Exxonmobil Chemical Patents Inc. Inhibiting catalyst coke formation in the manufacture of an olefin
US6855858B2 (en) * 2001-12-31 2005-02-15 Exxonmobil Chemical Patents Inc. Method of removing dimethyl ether from an olefin stream
US6660682B2 (en) * 2001-11-30 2003-12-09 Exxon Mobil Chemical Patents Inc. Method of synthesizing molecular sieves
AU2002367007A1 (en) 2002-01-03 2003-07-30 Exxon Mobil Chemical Patents Inc. Stabilisation of acid catalysts
US20030147604A1 (en) * 2002-02-01 2003-08-07 Tapia Alejandro L. Housing assembly for providing combined electrical grounding and fiber distribution of a fiber optic cable
US7208442B2 (en) * 2002-02-28 2007-04-24 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalyst thereof, their making and use in conversion processes
US7319178B2 (en) * 2002-02-28 2008-01-15 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalysts thereof, their making and use in conversion processes
US6906232B2 (en) * 2002-08-09 2005-06-14 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalysts thereof, their making and use in conversion processes
US6995111B2 (en) 2002-02-28 2006-02-07 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalysts thereof, their making and use in conversion processes
US7307196B2 (en) * 2002-02-28 2007-12-11 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalyst thereof, their making and use in conversion processes
US7271123B2 (en) * 2002-03-20 2007-09-18 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion process
US6872680B2 (en) * 2002-03-20 2005-03-29 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
US6759360B2 (en) * 2002-03-29 2004-07-06 Exxonmobil Chemical Patent Inc. Interior surface modifications of molecular sieves with organometallic reagents and the use thereof for the conversion of oxygenates to olefins
US20030191200A1 (en) * 2002-04-08 2003-10-09 Jianhua Yao Synthesis gas conversion and novel catalysts for same
US6638892B1 (en) 2002-04-18 2003-10-28 Conocophillips Company Syngas conversion and catalyst system employed therefor
US7238846B2 (en) * 2002-08-14 2007-07-03 Exxonmobil Chemical Patents Inc. Conversion process
WO2004016574A1 (en) 2002-08-14 2004-02-26 Exxonmobil Chemical Patents Inc. Process for preparing olefins from oxygenates
US7030284B2 (en) * 2002-08-20 2006-04-18 Exxonmobil Chemical Patents Inc. Method and reactor system for converting oxygenate contaminants in an MTO reactor system product effluent to hydrocarbons
US7122160B2 (en) * 2002-09-24 2006-10-17 Exxonmobil Chemical Patents Inc. Reactor with multiple risers and consolidated transport
US7238848B2 (en) 2002-09-30 2007-07-03 Exxonmobil Chemical Patents Inc. Method for separating dimethyl ether from an olefin-containing product stream
US20040064007A1 (en) * 2002-09-30 2004-04-01 Beech James H. Method and system for regenerating catalyst from a plurality of hydrocarbon conversion apparatuses
US7083762B2 (en) * 2002-10-18 2006-08-01 Exxonmobil Chemical Patents Inc. Multiple riser reactor with centralized catalyst return
US7119155B2 (en) * 2002-10-25 2006-10-10 Exxonmobil Chemical Patents Inc. Polymerized catalyst composition II
US7060865B2 (en) * 2002-11-12 2006-06-13 Exxonmobil Chemical Patents Inc. Recovery of C4 olefins from a product stream comprising C4 olefins, dimethyl ether and C5+ hydrocarbons
US7074979B2 (en) * 2002-12-31 2006-07-11 Exxonmobil Chemical Patents Inc. Processing a contaminated oxygenate-containing feed stream in an oxygenate to olefin reaction system
US6846966B2 (en) * 2002-11-26 2005-01-25 Exxonmobil Chemical Patents Inc. Method and apparatus for treating oxygenate-containing feeds and their use in conversion of oxygenates to olefins
US6899046B2 (en) * 2002-11-26 2005-05-31 Exxonmobil Chemical Patents Inc. Shipping methanol for a methanol to olefin unit in non-methanol carriers
US7214843B2 (en) * 2002-11-26 2007-05-08 Exxon Mobil Chemical Patents Inc. Treating oxygenate containing feedstreams in the conversion of oxygenates to olefins
US7102048B2 (en) * 2002-12-17 2006-09-05 Exxonmobil Chemical Patents Inc. Methanol feed for producing olefin streams
US7026267B2 (en) * 2002-12-20 2006-04-11 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its production and use in conversion processes
US20040122267A1 (en) * 2002-12-23 2004-06-24 Jaimes Sher Integrated gas to olefins process with recovery and conversion of by-products
US7151198B2 (en) * 2002-12-30 2006-12-19 Exxonmobil Chemical Patents Inc. Integration of a methanol synthesis system with a methanol to olefin reaction system
US7161051B2 (en) * 2002-12-30 2007-01-09 Exxonmobil Chemical Patents Inc. Integration of a methanol synthesis system with a methanol to olefin reaction system
US20040244279A1 (en) * 2003-03-27 2004-12-09 Briscoe Michael D. Fuel compositions comprising natural gas and dimethyl ether and methods for preparation of the same
US6951830B2 (en) * 2003-08-05 2005-10-04 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst compositions, their production and use in conversion processes
US20050033013A1 (en) * 2003-08-06 2005-02-10 Van Egmond Cornelis F. Propylene-containing composition
US20050038304A1 (en) * 2003-08-15 2005-02-17 Van Egmond Cor F. Integrating a methanol to olefin reaction system with a steam cracking system
US7626067B2 (en) 2003-09-19 2009-12-01 Exxonmobil Chemical Patents Inc. Process for recovering and reusing water in an oxygenate-to-olefin process
US7241713B2 (en) * 2003-10-02 2007-07-10 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
US7241716B2 (en) 2003-11-10 2007-07-10 Exxonmobil Chemical Patents Inc. Protecting catalytic sites of metalloaluminophosphate molecular sieves
US7304197B2 (en) * 2003-11-24 2007-12-04 Exxonmobil Chemical Patents Inc. Recycling oxygenate-rich streams in oxygenate-to-olefin processes
US7084319B2 (en) * 2003-12-05 2006-08-01 Exxonmobil Chemical Patents Inc. Catalyst fluidization in oxygenate to olefin reaction systems
US7067597B2 (en) * 2004-02-25 2006-06-27 Exxonmobil Chemical Patents Inc. Process of making polypropylene from intermediate grade propylene
US7192987B2 (en) * 2004-03-05 2007-03-20 Exxonmobil Chemical Patents Inc. Processes for making methanol streams and uses for the streams
US20050209469A1 (en) * 2004-03-22 2005-09-22 Shutt John R Converting propylene in an oxygenate-contaminated propylene stream to non-polymerization derivative products
US20050204625A1 (en) * 2004-03-22 2005-09-22 Briscoe Michael D Fuel compositions comprising natural gas and synthetic hydrocarbons and methods for preparation of same
US7375048B2 (en) 2004-04-29 2008-05-20 Basf Catalysts Llc ZSM-5 additive
US7199277B2 (en) * 2004-07-01 2007-04-03 Exxonmobil Chemical Patents Inc. Pretreating a catalyst containing molecular sieve and active metal oxide
US7199278B2 (en) * 2004-07-30 2007-04-03 Exxonmobil Chemical Patents Inc. Conversion of oxygenates to olefins
US7166757B2 (en) * 2004-07-30 2007-01-23 Exxonmobil Chemical Patents Inc. Conversion of oxygenates to olefins
US7186875B2 (en) * 2004-07-30 2007-03-06 Exxon Mobil Chemical Patents Inc. Conversion of oxygenates to olefins
US20060040821A1 (en) * 2004-08-18 2006-02-23 Pujado Peter R Treatment of air to a catalyst regenerator to maintain catalyst activity
EA011844B1 (en) * 2004-09-08 2009-06-30 Бп Корпорейшн Норт Америка Инк. Method for transporting carbon-containing feed material
US7465845B2 (en) * 2004-12-22 2008-12-16 Exxonmobil Chemical Patents Inc. Increasing ethylene and/or propylene production in an oxygenate to olefins reaction systems
US7879920B2 (en) * 2004-12-22 2011-02-01 Exxonmobil Chemical Patents Inc. Oxygenate to olefin manufacture and recovery process
WO2006083423A1 (en) 2005-01-31 2006-08-10 Exxonmobil Chemical Patents, Inc. Molecular sieve catalyst composition, its making and use in conversion processes
US20060224032A1 (en) * 2005-03-29 2006-10-05 Janssen Marcel J Protecting catalytic sites of activated porous molecular sieves
CN100430349C (en) * 2005-08-15 2008-11-05 中国石油化工股份有限公司 Method for producing propylene from methanol or dimethyl ether
WO2007021394A2 (en) * 2005-08-18 2007-02-22 Exxonmobil Chemical Patents Inc. Catalytic conversion of oxygenates to olefins
US20070203384A1 (en) * 2005-12-22 2007-08-30 Pujado Peter R Oxygenate conversion to olefins with metathesis
US20070155999A1 (en) * 2005-12-30 2007-07-05 Pujado Peter R Olefin production via oxygenate conversion
US7592496B2 (en) * 2005-12-30 2009-09-22 Uop Llc Light olefin production via dimethyl ether
US20080039670A1 (en) * 2006-08-10 2008-02-14 Miller Lawrence W Methanol-Water Mixtures in Olefin Production Via Oxygenate Conversion
US7744746B2 (en) 2006-03-31 2010-06-29 Exxonmobil Research And Engineering Company FCC catalyst stripper configuration
EP2004776A1 (en) 2006-03-31 2008-12-24 ExxonMobil Chemical Patents Inc. Product recovery in gas-solids reactors
US20070244348A1 (en) * 2006-04-13 2007-10-18 Michel Molinier Process for producing olefin product from syngas
CA2648630A1 (en) * 2006-04-13 2008-04-24 Max M. Tirtowidjojo Mixed alcohol synthesis with enhanced carbon value use
US7335621B2 (en) * 2006-04-19 2008-02-26 Exxonmobil Chemical Patents Inc. Catalyst compositions and preparation thereof
US7595275B2 (en) * 2006-08-15 2009-09-29 Exxonmobil Chemical Patents Inc. Catalyst compositions and their synthesis
CN101148383B (en) * 2006-09-20 2011-03-23 中国石油化工股份有限公司上海石油化工研究院 Method for preparing ethylene and propylene from methanol and dimethyl ether
US20080081936A1 (en) * 2006-09-29 2008-04-03 Bozzano Andrea G Integrated processing of methanol to olefins
BRPI0605173A (en) * 2006-12-05 2008-07-22 Braskem Sa process of producing one or more olefins, olefin, and polymer
CA2783154C (en) * 2006-12-13 2014-08-12 Haldor Topsoee A/S Process for the synthesis of hydrocarbon constituents of gasoline
US20080161616A1 (en) * 2006-12-27 2008-07-03 Miller Lawrence W Oxygenate to olefin processing with product water utilization
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
US20090005624A1 (en) * 2007-06-27 2009-01-01 Bozzano Andrea G Integrated Processing of Methanol to Olefins
EP2022565A1 (en) * 2007-07-06 2009-02-11 Casale Chemicals S.A. Process for preparing silicoaluminoposphate (SAPO) molecular sieves, catalysts containing said sieves and catalytic dehydration processes using said catalysts
US7923261B2 (en) * 2007-07-12 2011-04-12 Exxonmobil Chemical Patents Inc. Method for determining a carbon source of a product
AU2009239950A1 (en) * 2008-04-24 2009-10-29 Shell Internationale Research Maatschappij B.V. Process to prepare an olefin-containing product or a gasoline product
WO2010045516A2 (en) * 2008-10-16 2010-04-22 Range Fuels, Inc. Methods and apparatus for synthesis of alcohols from syngas
US8344188B2 (en) 2008-10-16 2013-01-01 Maverick Biofuels, Inc. Methods and apparatus for synthesis of alcohols from syngas
EP2373602B1 (en) 2008-12-22 2013-08-21 Shell Internationale Research Maatschappij B.V. Process to prepare methanol and/or dimethylether
AT508355B1 (en) * 2009-06-29 2011-01-15 Trumpf Maschinen Austria Gmbh METHOD AND DEVICE FOR BENDING A WORKPIECE
FR2959749B1 (en) 2010-05-06 2012-06-01 Inst Francais Du Petrole FLEXIBLE PROCESS FOR TRANSFORMING ETHANOL TO MEDIUM DISTILLATES
DE102010022138A1 (en) * 2010-05-20 2011-11-24 Lurgi Gmbh Process and plant for the production of low-oxygen-content olefin streams
JP5745041B2 (en) * 2010-06-23 2015-07-08 トタル リサーチ アンド テクノロジー フエリユイ Dehydration of alcohol over acid catalyst
US9096804B2 (en) 2011-01-19 2015-08-04 P.D. Technology Development, Llc Process for hydroprocessing of non-petroleum feedstocks
US8981165B2 (en) * 2011-09-14 2015-03-17 Enerkem, Inc. Production of alcohols having three carbon atoms from carbonaceous materials
US8987530B2 (en) * 2011-09-14 2015-03-24 Enerkem, Inc. Production of alcohols having at least four carbon atoms from carbonaceous materials
WO2013113754A1 (en) * 2012-01-31 2013-08-08 Basf Se Method for the conversion of synthesis gas into olefins
CN104437511B (en) * 2013-09-24 2017-01-11 中国石油化工股份有限公司 Catalyst for producing light olefins by fixed bed and preparation method for catalyst for producing light olefins by fixed bed
EP3018113A1 (en) * 2014-11-06 2016-05-11 BP p.l.c. Process and apparatus for the production of ethylene from carbon monoxide and hydrogen
WO2016094171A1 (en) * 2014-12-11 2016-06-16 Uop Llc Elevated pressure 'high value' mto process for improved sapo performance
BR112018006841B1 (en) * 2015-10-30 2020-12-15 Dow Global Technologies Llc PROCESS FOR PREPARING A LOWER HYDROCARBON MIXTURE
EP3219697B1 (en) * 2016-03-16 2018-06-13 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude The synthesis of methanol from synthesis gases with hydrogen mangle
AR110362A1 (en) * 2016-12-22 2019-03-20 Dow Global Technologies Llc PROCESS FOR CONVERTING SYNTHESIS GAS IN OLEFINS USING A CROMOZINC OXIDE BIFUNCTIONAL CATALYST - SAPO-34
US11925930B2 (en) 2018-12-03 2024-03-12 Furukawa Electric Co., Ltd. Apparatus for producing lower olefin-containing gas and method for producing lower olefin-containing gas
CN114026056A (en) * 2019-06-12 2022-02-08 埃克森美孚化学专利公司 Methods and systems for C3+ monoolefin conversion
CN114377620B (en) * 2020-10-16 2024-03-19 中国科学院大连化学物理研究所 Fluidized bed reactor, device and method for preparing low-carbon olefin by oxygen-containing compound
CN114377624B (en) * 2020-10-16 2024-03-19 中国科学院大连化学物理研究所 Coke regulation reactor, device for preparing low-carbon olefin from oxygen-containing compound and application
KR102564294B1 (en) * 2021-01-12 2023-08-07 한국화학연구원 Additives for Dehydration Reaction of 1―Alcohol and Method for Preparing 1―Olefin Using the Same

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3326956A (en) * 1962-06-08 1967-06-20 Ici Ltd Production of oxygenated hydrocarbons
US4076761A (en) * 1973-08-09 1978-02-28 Mobil Oil Corporation Process for the manufacture of gasoline
US4052479A (en) * 1973-08-09 1977-10-04 Mobil Oil Corporation Conversion of methanol to olefinic components
US3928483A (en) * 1974-09-23 1975-12-23 Mobil Oil Corp Production of gasoline hydrocarbons
US4025575A (en) * 1975-04-08 1977-05-24 Mobil Oil Corporation Process for manufacturing olefins
FR2519335B1 (en) * 1982-01-04 1986-05-02 Azote & Prod Chim PRODUCTION OF HYDROCARBONS FROM METHANOL IN THE PRESENCE OF ZEOLITE TYPE CATALYSTS
US4499314A (en) * 1982-03-31 1985-02-12 Imperial Chemical Industries Plc Methanol conversion to hydrocarbons with zeolites and cocatalysts
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4677242A (en) * 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins
US4677243A (en) * 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins from aliphatic hetero compounds
US4496786A (en) * 1983-09-30 1985-01-29 Chevron Research Company Selective conversion of methanol to low molecular weight olefins over high silica SSZ-13 zeolite
JPS6147421A (en) * 1984-08-15 1986-03-07 Satoyuki Inui Production of olefinic hydrocarbon from methanol
US4547616A (en) * 1984-12-28 1985-10-15 Mobil Oil Corporation Conversion of oxygenates to lower olefins in a turbulent fluidized catalyst bed
US4973792A (en) * 1987-07-07 1990-11-27 Uop Chemical conversion process
US4861938A (en) * 1987-07-07 1989-08-29 Uop Chemical conversion process
US4849575A (en) * 1987-11-25 1989-07-18 Uop Production of olefins
US5041690A (en) * 1989-04-28 1991-08-20 Mobil Oil Corporation Conversion of alcohols to ether-rich gasoline
US5130101A (en) * 1989-04-28 1992-07-14 Mobil Oil Corporation Reactor system for conversion of alcohols to ether-rich gasoline
US5095163A (en) * 1991-02-28 1992-03-10 Uop Methanol conversion process using SAPO catalysts
US5126308A (en) * 1991-11-13 1992-06-30 Uop Metal aluminophosphate catalyst for converting methanol to light olefins
US5191141A (en) * 1991-11-13 1993-03-02 Uop Process for converting methanol to olefins using an improved metal aluminophosphate catalyst
NO174341B1 (en) * 1991-12-23 1994-04-21 Polymers Holding As Prepare foremost crystalline microporosis SiAl phosphates with controlled Si content, crystalline microporosis SiAl phosphates with improved stability against deactivation and use thereof in the preparation of olefins from methanol

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011006594A1 (en) 2009-07-14 2011-01-20 Lurgi Gmbh Method and apparatus for producing synthetic fuels
DE102009032915A1 (en) 2009-07-14 2011-03-31 Lurgi Gmbh Process and plant for the production of synthetic fuels
US9028567B2 (en) 2009-07-14 2015-05-12 Lurgi Gmbh Method and apparatus for producing synthetic fuels
US9938217B2 (en) 2016-07-01 2018-04-10 Res Usa, Llc Fluidized bed membrane reactor
US9981896B2 (en) 2016-07-01 2018-05-29 Res Usa, Llc Conversion of methane to dimethyl ether
US10189763B2 (en) 2016-07-01 2019-01-29 Res Usa, Llc Reduction of greenhouse gas emission

Also Published As

Publication number Publication date
AU5274798A (en) 1999-08-26
NO311714B1 (en) 2002-01-14
NO980381D0 (en) 1998-01-28
EP0933345A1 (en) 1999-08-04
CN1174945C (en) 2004-11-10
AU744933B2 (en) 2002-03-07
EP0933345B1 (en) 2001-09-12
NZ329645A (en) 1999-06-29
ZA98735B (en) 1998-09-30
CA2228738C (en) 2006-09-26
CN1224705A (en) 1999-08-04
NO980381L (en) 1999-07-29
DE69801643T2 (en) 2002-07-04
DE69801643D1 (en) 2001-10-18
RU2165955C2 (en) 2001-04-27
US5714662A (en) 1998-02-03

Similar Documents

Publication Publication Date Title
CA2228738A1 (en) Three step process for producing light olefins from methane and/or ethane
EP0020141B1 (en) Conversion of synthesis gas to hydrocarbon mixtures utilizing dual reactors
EP0269297B1 (en) Process for the production of aromatic hydrocarbons incorporating by-product utilisation
US6713657B2 (en) Condensation of olefins in fischer tropsch tail gas
AU2004267251B2 (en) Process for synthesising hydrocarbons
WO1991012224A3 (en) Circulating bed cofeed conversion reactor and method for converting light hydrocarbons to olefins, gasoline and methanol
CA2281850A1 (en) Olefin plant recovery system employing catalytic distillation
WO2004048299A3 (en) Process for olefin production
ATE325785T1 (en) METHOD FOR CONVERTING A FEED CONTAINING OXYGEN COMPOUNDS INTO OLEFINS
US4046830A (en) Method for upgrading Fischer-Tropsch synthesis products
CA2305795A1 (en) Method for increasing light olefin yield by conversion of a heavy hydrocarbon fraction of a product to light olefins
RU98103428A (en) A THREE-STAGE METHOD FOR GETTING LIGHT OLEFINES FROM METHANE AND / OR ETHANE
ZA81982B (en) Process for the production of olefins from synthesis gas,in particular ethylene and propene
JP2005501139A5 (en)
MY116750A (en) Hydrocarbon conversion
NZ226970A (en) Process for converting methanol to gasoline and distillate
GC0000088A (en) Process for the preparation of hydrocarbons from carbon monoxide and hydrogen.
RU2001125422A (en) METHOD FOR PRODUCING HYDROCARBONS FROM CARBON AND HYDROGEN MONOOXIDE
RU2009116235A (en) INTEGRATED METHANOL PROCESSING IN OLEFINS
EP0123338B1 (en) Process for the preparation of methyl tertiary butyl ether
AU2001287563A1 (en) Method for producing hydroformylation products of olefins with 2 to 8 carbon atoms
MY122134A (en) Three step process for producing light olefins from crude methane and/or ethane
EA199900546A2 (en) Process for producing of motor fuels from hydrocarbons
JPH0765057B2 (en) Process for producing synthesis gas from hydrocarbon-containing feedstock
KR930702474A (en) Processes and devices for producing liquid fuels and basic chemicals

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20130204