CA2221996A1 - Robust spectroscopic optical probe - Google Patents
Robust spectroscopic optical probeInfo
- Publication number
- CA2221996A1 CA2221996A1 CA002221996A CA2221996A CA2221996A1 CA 2221996 A1 CA2221996 A1 CA 2221996A1 CA 002221996 A CA002221996 A CA 002221996A CA 2221996 A CA2221996 A CA 2221996A CA 2221996 A1 CA2221996 A1 CA 2221996A1
- Authority
- CA
- Canada
- Prior art keywords
- tip
- probe
- terminal surface
- optical
- optical probe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/24—Coupling light guides
- G02B6/42—Coupling light guides with opto-electronic elements
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/24—Coupling light guides
- G02B6/36—Mechanical coupling means
- G02B6/38—Mechanical coupling means having fibre to fibre mating means
- G02B6/3807—Dismountable connectors, i.e. comprising plugs
- G02B6/3833—Details of mounting fibres in ferrules; Assembly methods; Manufacture
- G02B6/3855—Details of mounting fibres in ferrules; Assembly methods; Manufacture characterised by the method of anchoring or fixing the fibre within the ferrule
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/84—Systems specially adapted for particular applications
- G01N21/85—Investigating moving fluids or granular solids
- G01N21/8507—Probe photometers, i.e. with optical measuring part dipped into fluid sample
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/24—Coupling light guides
- G02B6/241—Light guide terminations
Abstract
Disclosed is a spectroscopic probe apparatus useful for Raman, near infrared, luminescence, ultraviolet or visible spectroscopies that is formed with a robust method of construction using a molten metal soldering technique. The disclosed method and apparatus provides an optical probe that is easy to manufacture yet able to withstand drastic environmental conditions without damage and produce useful spectroscopic results under such conditions. In a preferred embodiment of the present invention, optical probe (100) comprises a housing (101), closed at one end by tip (102). Two optical fibers (103 and 104), one serving as an excitation channel for radiation from a source to a composition to be analyzed, the other comprising a collection channel for transmitting radiation from the irradiated composition to remotely situated detector means, extend from the terminal surface (105) of the tip through the length of the housing. On the terminal surface (105) of tip (102) is formed a cavity (106), which is filled with molten metal solder that solidifies on cooling to a solder plug. This plug comprises means for securing and sealing the ends of the optical fibre at the terminal surface of the probe tip.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/450,597 US5657404A (en) | 1995-05-25 | 1995-05-25 | Robust spectroscopic optical probe |
US08/450,597 | 1995-05-25 | ||
PCT/US1996/006528 WO1996037794A1 (en) | 1995-05-25 | 1996-05-11 | Robust spectroscopic optical probe |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2221996A1 true CA2221996A1 (en) | 1996-11-28 |
CA2221996C CA2221996C (en) | 2001-04-03 |
Family
ID=23788743
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002221996A Expired - Fee Related CA2221996C (en) | 1995-05-25 | 1996-05-17 | Robust spectroscopic optical probe |
Country Status (25)
Country | Link |
---|---|
US (2) | US5657404A (en) |
EP (1) | EP0829027B1 (en) |
JP (1) | JPH11505927A (en) |
KR (1) | KR19990021967A (en) |
CN (1) | CN1100276C (en) |
AR (1) | AR002091A1 (en) |
AT (1) | ATE176335T1 (en) |
AU (1) | AU697241B2 (en) |
BR (1) | BR9609110A (en) |
CA (1) | CA2221996C (en) |
CO (1) | CO4480727A1 (en) |
CZ (1) | CZ372997A3 (en) |
DE (1) | DE69601464T2 (en) |
ES (1) | ES2127019T3 (en) |
HU (1) | HUP0303374A2 (en) |
IL (1) | IL118408A (en) |
MX (1) | MX9709071A (en) |
MY (1) | MY132185A (en) |
NO (1) | NO975410L (en) |
PL (1) | PL323596A1 (en) |
SK (1) | SK158797A3 (en) |
TR (1) | TR199701399T1 (en) |
TW (1) | TW293878B (en) |
WO (1) | WO1996037794A1 (en) |
ZA (1) | ZA964205B (en) |
Families Citing this family (60)
Publication number | Priority date | Publication date | Assignee | Title |
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US6100975A (en) * | 1996-05-13 | 2000-08-08 | Process Instruments, Inc. | Raman spectroscopy apparatus and method using external cavity laser for continuous chemical analysis of sample streams |
US6028667A (en) * | 1996-05-13 | 2000-02-22 | Process Instruments, Inc. | Compact and robust spectrograph |
DE19626785A1 (en) * | 1996-07-03 | 1998-01-08 | Basf Ag | Process and device for the continuous color measurement of plastic molding compounds |
US5971629A (en) * | 1996-07-12 | 1999-10-26 | Bloom; Cary | Apparatus and method bonding optical fiber and/or device to external element using compliant material interface |
US6000858A (en) * | 1996-07-12 | 1999-12-14 | Bloom; Cary | Apparatus for, and method of, forming a low stress tight fit of an optical fiber to an external element |
US5815619A (en) * | 1996-12-10 | 1998-09-29 | Bloom; Cary | Fiber optic connector hermetically terminated |
US5805757A (en) * | 1996-12-10 | 1998-09-08 | Bloom; Cary | Apparatus and method for preserving optical characteristics of a fiber optic device |
US5754715A (en) * | 1996-11-12 | 1998-05-19 | Melling; Peter J. | Mid-infrared fiber-optic spectroscopic probe |
US6074101A (en) * | 1996-12-10 | 2000-06-13 | Bloom; Cary | Apparatus for, and method of, forming a low stress tight fit of an optical fiber to an external element |
DE19882224T1 (en) | 1997-03-14 | 2000-03-23 | Rosemount Analytical Inc | Method and device for improved control of Rayleigh backscatter |
WO1998041848A1 (en) * | 1997-03-14 | 1998-09-24 | Rosemount Analytical Inc. | Improved low noise raman analyzer system |
DE69819136T2 (en) * | 1997-03-14 | 2004-07-15 | Rosemount Analytical Inc., La Habra | "DEVICE AND METHOD FOR CONTROLLING RAYLEIGH BACKFLOW" |
US5850623A (en) * | 1997-03-14 | 1998-12-15 | Eastman Chemical Company | Method for standardizing raman spectrometers to obtain stable and transferable calibrations |
DE19716252A1 (en) * | 1997-04-18 | 1998-10-22 | Conducta Endress & Hauser | Optical sensor |
CA2212776A1 (en) * | 1997-08-08 | 1999-02-08 | Andrzej Barwicz | A spectrometric micro-sensor/transducer and procedure for interpretation of spectrometric data |
US5835649A (en) * | 1997-06-02 | 1998-11-10 | The University Of British Columbia | Light directing and collecting fiber optic probe |
KR100248054B1 (en) * | 1997-08-14 | 2000-03-15 | 윤종용 | Fiber array module using the soldering process fabrication method thereof |
US7084974B1 (en) | 1998-05-19 | 2006-08-01 | Measurement Microsystems A-Z, Inc. | Apparatus and method for light spectrum measurement |
US6141095A (en) * | 1998-06-10 | 2000-10-31 | New Chromex, Inc. | Apparatus for measuring and applying instrumentation correction to produce a standard Raman spectrum |
US6349160B2 (en) | 1998-07-24 | 2002-02-19 | Aurora Biosciences Corporation | Detector and screening device for ion channels |
US6608671B2 (en) * | 1998-07-17 | 2003-08-19 | Vertex Pharmaceuticals (San Diego) Llc | Detector and screening device for ion channels |
US6115528A (en) * | 1998-09-21 | 2000-09-05 | The United States Of America As Represented By The United States Department Of Energy | Raman fiber optic probe assembly for use in hostile environments |
US6678541B1 (en) | 1998-10-28 | 2004-01-13 | The Governmemt Of The United States Of America | Optical fiber probe and methods for measuring optical properties |
US6313917B1 (en) | 1999-07-02 | 2001-11-06 | Ncr Corporation | Produce data collector and produce recognition system |
US6479597B1 (en) | 1999-07-30 | 2002-11-12 | Exxonmobil Chemical Patents Inc. | Raman analysis system for olefin polymerization control |
NL1015440C2 (en) * | 2000-06-14 | 2001-12-17 | Vma Vlastuin Mest Applicaties | Chemical analysis device for liquid waste products, especially manure, comprises sensor located in outlet for liquid holding vessel |
US6474879B1 (en) * | 2000-08-08 | 2002-11-05 | Stratos Lightwave, Inc. | Post assembly metallization of a device to form hermetic seal |
FI111191B (en) * | 2000-10-12 | 2003-06-13 | Valtion Teknillinen | Optical probe and method for manufacturing optical probe |
US6723804B1 (en) * | 2000-11-03 | 2004-04-20 | Chevron Phillips Chemical Company, Lp | Monitoring and control of slurry processes for polymerizing olefins |
US6892012B2 (en) * | 2001-05-18 | 2005-05-10 | Fujikura, Ltd. | Optical fiber bundle unit for transmitting ultraviolet light |
DE10130862A1 (en) * | 2001-06-28 | 2003-01-23 | Conducta Endress & Hauser | Process measuring point |
US6809817B2 (en) * | 2001-08-24 | 2004-10-26 | General Electric Company | Method and apparatus for in situ determination of molten polycarbonate composition using electronic absorption spectroscopy |
CA2466318A1 (en) | 2001-11-09 | 2003-05-22 | Exxonmobil Chemical Patents Inc. | On-line measurement and control of polymer properties by raman spectroscopy |
US7126690B2 (en) * | 2002-09-23 | 2006-10-24 | Therma-Wave, Inc. | Modulated reflectance measurement system using UV probe |
US20060136149A1 (en) * | 2002-10-15 | 2006-06-22 | Long Robert L | On-line measurement and control of polymer properties by raman spectroscopy |
AU2003302739A1 (en) * | 2003-01-06 | 2004-08-10 | Exxonmobil Chemical Patents Inc. | On-line measurement and control of polymer product properties by raman spectroscopy |
US6897951B2 (en) * | 2003-02-14 | 2005-05-24 | Raman Systems, Inc. | Probe assemblies for Raman spectroscopy |
US7400941B2 (en) * | 2004-01-14 | 2008-07-15 | Chrevron Phillips Chemical Company Lp | Method and apparatus for monitoring polyolefin production |
DE102004023178B4 (en) * | 2004-05-07 | 2006-06-29 | Hellma Gmbh & Co. Kg | Apparatus for analysis or absorption measurement on a small amount of liquid medium by means of light |
US7198549B2 (en) * | 2004-06-16 | 2007-04-03 | Cabot Microelectronics Corporation | Continuous contour polishing of a multi-material surface |
US7651851B2 (en) * | 2005-01-27 | 2010-01-26 | Prescient Medical, Inc. | Handheld Raman body fluid analyzer |
US7524671B2 (en) * | 2005-01-27 | 2009-04-28 | Prescient Medical, Inc. | Handheld raman blood analyzer |
US7688440B2 (en) * | 2005-01-27 | 2010-03-30 | Prescient Medical, Inc. | Raman spectroscopic test strip systems |
JP4982386B2 (en) * | 2005-02-11 | 2012-07-25 | ナノドロップ・テクノロジーズ・リミテッド・ライアビリティ・カンパニー | Apparatus and measurement method for measuring signal from fluorescent nanodrop held at surface tension |
EP1736756A1 (en) * | 2005-06-20 | 2006-12-27 | Bp Oil International Limited | Development of disposable/Sealable tips for near infra-red (NIR) spectroscopic probes |
US7505129B2 (en) | 2005-07-22 | 2009-03-17 | Exxonmobil Chemical Patents Inc. | On-line analysis of polymer properties for control of a solution phase reaction system |
US7505127B2 (en) * | 2005-07-22 | 2009-03-17 | Exxonmobil Chemical Patents Inc. | On-line raman analysis and control of a high pressure reaction system |
US7483129B2 (en) * | 2005-07-22 | 2009-01-27 | Exxonmobil Chemical Patents Inc. | On-line properties analysis of a molten polymer by raman spectroscopy for control of a mixing device |
US20080064120A1 (en) * | 2006-02-06 | 2008-03-13 | Clarke Richard H | Raman spectroscopic lateral flow test strip assays |
DE102006035996A1 (en) * | 2006-08-02 | 2008-02-07 | Bayer Technology Services Gmbh | Optical measuring probe for process monitoring |
DE102006052210B3 (en) * | 2006-11-01 | 2007-12-06 | Loptek Glasfasertechnik Gmbh & Co. Kg | Fiber optic probe for optical analysis of fluid, has shaft and guide tube dimensioned such that temperatures of shaft and tube drop from temperature of head piece to temperature of output in continuous manner without heat transmission |
DE102006052208B3 (en) * | 2006-11-01 | 2007-12-06 | Loptek Glasfasertechnik Gmbh & Co. Kg | Fiber-optic retro reflex sensor for measuring absorption characteristic of light, has optical fibers arranged in area of cover such that front surfaces lie in plane, which limits measuring section at end of shank |
US7675616B1 (en) | 2007-09-19 | 2010-03-09 | The United States Of America As Represented By The Secretary Of The Navy | Combustion plume absorption gauge |
DE102008056559B4 (en) | 2008-11-10 | 2011-07-07 | Faudi Aviation GmbH, 35260 | sensor arrangement |
JP5903893B2 (en) * | 2010-06-25 | 2016-04-13 | コニカミノルタ株式会社 | probe |
JP6129014B2 (en) * | 2013-08-01 | 2017-05-17 | 日本板硝子株式会社 | Fluorescence detection apparatus and fluorescence detection method |
US10006000B2 (en) * | 2013-10-01 | 2018-06-26 | Owl biomedical, Inc. | Particle manipulation system with out-of-plane channel using axial light loss |
FR3048240B1 (en) * | 2016-02-29 | 2018-04-13 | Cordouan Tech | DEVICE FOR CHARACTERIZING PARTICLES DISPERSE IN A LIQUID MEDIUM |
CN114110524B (en) * | 2018-06-27 | 2023-12-22 | 深圳市绎立锐光科技开发有限公司 | Light source device and car lamp |
WO2024028482A1 (en) * | 2022-08-04 | 2024-02-08 | Merck Patent Gmbh | Reduction of stray light noise in optical raman probe sensors |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2424549A1 (en) * | 1973-05-23 | 1974-12-12 | John Michael Prof Thompson | FLUID ANALYZER |
US4033668A (en) * | 1976-04-08 | 1977-07-05 | Bell Telephone Laboratories, Incorporated | Solderable glass splices, terminations and hermetic seals |
US4488773A (en) * | 1982-12-23 | 1984-12-18 | United Technologies Corporation | Optical fiber position sensor |
US4573761A (en) * | 1983-09-14 | 1986-03-04 | The Dow Chemical Company | Fiber-optic probe for sensitive Raman analysis |
US4707134A (en) * | 1984-12-04 | 1987-11-17 | The Dow Chemical Company | Fiber optic probe |
US4802761A (en) * | 1987-08-31 | 1989-02-07 | Western Research Institute | Optical-fiber raman spectroscopy used for remote in-situ environmental analysis |
US5402241A (en) * | 1989-03-30 | 1995-03-28 | The Foxboro Company | Optical probe for fluid light transmission properties |
US5015092A (en) * | 1989-05-05 | 1991-05-14 | Spectra-Tech, Inc. | Sampling probe for optical analyzation of a sample |
US4988155A (en) * | 1989-06-22 | 1991-01-29 | The Dow Chemical Company | In-line fiber optic probe interface |
US5112127A (en) * | 1989-11-28 | 1992-05-12 | Eic Laboratories, Inc. | Apparatus for measuring Raman spectra over optical fibers |
US5046854A (en) * | 1990-02-01 | 1991-09-10 | The Dow Chemical Company | Photometric cell and probe having windows fusion sealed to a metallic body |
US5061035A (en) * | 1990-09-27 | 1991-10-29 | Hughes Aircraft Company | Hermetically sealed optical fiber arrays and method for forming same |
US5157753A (en) * | 1990-09-27 | 1992-10-20 | Hughes Aircraft Company | Hermetically sealed optical fiber arrays and method for forming same |
WO1994020014A1 (en) * | 1993-03-05 | 1994-09-15 | Sahagen Armen N | Probe for monitoring a fluid medium |
US5402508A (en) * | 1993-05-04 | 1995-03-28 | The United States Of America As Represented By The United States Department Of Energy | Fiber optic probe having fibers with endfaces formed for improved coupling efficiency and method using same |
DE9414467U1 (en) * | 1994-07-15 | 1994-11-10 | Bruker Analytische Messtechnik | Raman spectrometer with a measuring probe |
-
1995
- 1995-05-25 US US08/450,597 patent/US5657404A/en not_active Expired - Fee Related
-
1996
- 1996-05-07 MY MYPI96001713A patent/MY132185A/en unknown
- 1996-05-11 WO PCT/US1996/006528 patent/WO1996037794A1/en not_active Application Discontinuation
- 1996-05-11 BR BR9609110A patent/BR9609110A/en not_active IP Right Cessation
- 1996-05-11 HU HU0303374A patent/HUP0303374A2/en unknown
- 1996-05-11 ES ES96920159T patent/ES2127019T3/en not_active Expired - Lifetime
- 1996-05-11 JP JP8535700A patent/JPH11505927A/en active Pending
- 1996-05-11 KR KR1019970708442A patent/KR19990021967A/en not_active Application Discontinuation
- 1996-05-11 SK SK1587-97A patent/SK158797A3/en unknown
- 1996-05-11 PL PL96323596A patent/PL323596A1/en unknown
- 1996-05-11 TR TR97/01399T patent/TR199701399T1/en unknown
- 1996-05-11 AT AT96920159T patent/ATE176335T1/en not_active IP Right Cessation
- 1996-05-11 MX MX9709071A patent/MX9709071A/en unknown
- 1996-05-11 EP EP96920159A patent/EP0829027B1/en not_active Expired - Lifetime
- 1996-05-11 CN CN96195519A patent/CN1100276C/en not_active Expired - Fee Related
- 1996-05-11 DE DE69601464T patent/DE69601464T2/en not_active Expired - Fee Related
- 1996-05-11 CZ CZ973729A patent/CZ372997A3/en unknown
- 1996-05-15 TW TW085105745A patent/TW293878B/zh active
- 1996-05-17 AU AU58553/96A patent/AU697241B2/en not_active Ceased
- 1996-05-17 CA CA002221996A patent/CA2221996C/en not_active Expired - Fee Related
- 1996-05-23 IL IL11840896A patent/IL118408A/en active IP Right Grant
- 1996-05-23 AR ARP960102694A patent/AR002091A1/en active IP Right Grant
- 1996-05-23 CO CO96026134A patent/CO4480727A1/en unknown
- 1996-05-24 ZA ZA964205A patent/ZA964205B/en unknown
- 1996-06-17 US US08/664,721 patent/US5678751A/en not_active Expired - Fee Related
-
1997
- 1997-11-25 NO NO975410A patent/NO975410L/en unknown
Also Published As
Publication number | Publication date |
---|---|
KR19990021967A (en) | 1999-03-25 |
ATE176335T1 (en) | 1999-02-15 |
TW293878B (en) | 1996-12-21 |
AR002091A1 (en) | 1998-01-07 |
AU697241B2 (en) | 1998-10-01 |
BR9609110A (en) | 1999-02-02 |
AU5855396A (en) | 1996-12-11 |
US5657404A (en) | 1997-08-12 |
CA2221996C (en) | 2001-04-03 |
CN1100276C (en) | 2003-01-29 |
CO4480727A1 (en) | 1997-07-09 |
IL118408A (en) | 1998-10-30 |
CZ372997A3 (en) | 1998-06-17 |
TR199701399T1 (en) | 1998-03-21 |
ES2127019T3 (en) | 1999-04-01 |
NO975410L (en) | 1998-01-08 |
CN1191022A (en) | 1998-08-19 |
NO975410D0 (en) | 1997-11-25 |
IL118408A0 (en) | 1996-09-12 |
JPH11505927A (en) | 1999-05-25 |
SK158797A3 (en) | 1998-12-02 |
US5678751A (en) | 1997-10-21 |
DE69601464T2 (en) | 1999-10-07 |
MY132185A (en) | 2007-09-28 |
ZA964205B (en) | 1996-12-04 |
EP0829027A1 (en) | 1998-03-18 |
WO1996037794A1 (en) | 1996-11-28 |
EP0829027B1 (en) | 1999-01-27 |
HUP0303374A2 (en) | 2004-01-28 |
MX9709071A (en) | 1998-02-28 |
PL323596A1 (en) | 1998-04-14 |
DE69601464D1 (en) | 1999-03-11 |
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Legal Events
Date | Code | Title | Description |
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EEER | Examination request | ||
MKLA | Lapsed |